Prospects for the Development of High Energy Density Dielectric Capacitors

: In this paper, the design of high energy density dielectric capacitors for energy storage in vehicle, industrial, and electric utility applications have been considered in detail. The performance of these devices depends primarily on the dielectric constant and breakdown strength characteristics of the dielectric material used. A review of the literature on composite polymer materials to assess their present dielectric constants and the various approaches being pursued to increase energy density found that there are many papers in which materials having dielectric constants of 20–50 were reported, but only a few showing materials with very high dielectric constants of 500 and greater. The very high dielectric constants were usually achieved with nanoscale metallic or carbon particles embedded in a host polymer and the maximum dielectric constant occurred near the percolation threshold particle loading. In this study, an analytical method to calculate the dielectric constant of composite dielectric polymers with various types of nanoparticles embedded is presented. The method was applied using an Excel spreadsheet to calculate the characteristics of spiral wound battery cells using various composite polymers with embedded particles. The calculated energy densities were strong functions of the size of the particles and thickness of the dielectric layer in the cell. For a 1000 V cell, an energy density of 100–200 Wh/kg was calculated for 3–5 nm particles and 3–5 µ thick dielectric layers. The results of this study indicate that dielectric materials with an effective dielectric constant of 500–1000 are needed to develop dielectric capacitor cells with battery-like energy density. The breakdown strength would be 300–400 V/ µ in a reverse sandwich multilayer dielectric arrangement. The leakage current of the cell would be determined from appropriate DC testing. These high energy density dielectric capacitors are very different from electrochemical capacitors that utilize conducting polymers and liquid electrolytes and are constructed much like batteries. The dielectric capacitors have a very high cell voltage and are constructed like conventional ceramic capacitors.


Introduction
The most common and simplest electrical energy storage device is the ceramic capacitor that uses a very thin dielectric layer between two metal plates to separate positive and negative charge.The energy stored is proportional to the capacitance C of the dielectric layer and the square of the voltage difference between the metal plates.The capacitance of the dielectric layer depends on its dielectric constant ε r , thickness δ, and area A. The capacitance C and energy E stored are given by the following simple formulae.The energy stored per unit area is The energy density of the capacitor is Wh/L = 1/2 ε 0 ε r (V/δ) 2   A key material parameter is ε r , the effective dielectric constant of the material from which the capacitor is assembled.The energy density of all dielectric capacitor devices is proportional to the voltage squared, but the maximum voltage is limited by the breakdown strength of the dielectric material V/µ.Hence the key material property is ε r (V/δ) 2 .In most cases, attempts to increase the effective dielectric constant have resulted in a significant decrease in breakdown strength.This report is focused on increasing the effective dielectric constant of a polymer composite, but consideration of the breakdown strength of the composite is at least of equal importance.
The general approach discussed in this paper to increase the effective dielectric constant of a polymer composite has its roots in Dr. Burke's familiarity [1][2][3][4] with electrochemical supercapacitors (ECSCs)-carbon/carbon electric double-layer capacitors (EDLCs) and hybrid ECSCs that utilize microporous carbon and a liquid electrolyte.The charge separation in the electrodes occurs in the double-layer formed in the micro-pores of the carbon at the interface between the liquid electrolyte and the carbon.The capacitance of the electrode is proportional to the specific capacitance (F/g) of the microporous material used to form the electrodes in the cell.In order to increase the energy density of EDLCs (5-10 Wh/kg for a device), hybrid ECSCs have been developed that consist of carbon in one electrode and the second electrode formed from nanoporous carbon coated with metal oxides or conducting polymers that have much higher specific capacitance than the carbon.The charge transport in electrochemical capacitors is due to the diffusion of ions in the electrolyte.The high capacitance of the ECSC is due to the sum of the capacitance of millions of micro-capacitors formed in and around the nano-carbon particles.The dielectric, in this case, is the liquid electrolyte with a rather high dielectric constant , and the maximum voltage (1-4 V) of the cell depends on the decomposition of the electrolyte.The high capacitance of the cell is due to the distributed charge separation in the double-layer on the surface of the electrically conductive porous carbon and/or its coatings.This charge separation is very much larger (>10 6 ) than it could be on the surface of the metal current collector of the cell.The source/sink of the electrical current through the ECSC is by way of the current collector as in a battery.The concept of distributed charge separation and millions of micro-capacitors in a host dielectric can be used as the approach to achieve a high effective dielectric constant in a dielectric cell.ECSC devices are characterized in terms of their capacitance C and resistance R. The charge stored is given by Q = CV and the energy stored is E = 1/2 CV r 2 , where V r is the rated voltage of the device.The response time of the ECSC is RC.These are the same relationships given previously to describe the performance of a dielectric capacitor.
Energy storage in a dielectric material is much different than in the electrode of an EC in which there is a physical transport of ions through the liquid electrolyte.In the dielectric material, the material becomes polarized in response to an electric field generated between two electrical conducting surfaces on which surface charge forms.There is no physical movement of atomic material as the dielectric cell is charged and discharged.In the case of the dielectric cells analyzed in this paper, the distance between the conducting surfaces is the spacing of the carbon particles and it is the host dielectric material that is polarized.The maximum electric field possible between the particles depends on the effective breakdown strength characteristics of the host dielectric material.In the dielectric cell, there is no need for a separator because the dielectric material has an extremely low electrical conductivity.It acts as an insulator.In principle, the calculation of performance of the cell is straightforward after its capacitance is known.
This paper consists of several sections.Section 2 is a review of recent research on approaches to achieving significant increases in the dielectric constants of polymer composites for use in energy storage devices.Section 3 is the analytical basis of the present proposed approach for increasing the effective dielectric constant of polymer composites using various embedded elements, including carbon in various forms.Section 4 is the application of the results of Section 3 to the design of high energy density dielectric cells via an Excel spreadsheet model.Section 5 discusses the DC testing of the dielectric cells and the metrics used to describe their performance.Section 6 is a review of selected research on the development of high voltage, film capacitors.Section 7 is a review of recent electrochemical supercapacitor research dealing with carbon, graphene, and polymers to increase the specific capacitance (F/g) of their electrodes.Section 8 is a summary of the paper and important aspects of the development of high energy density dielectric capacitors that make their development uncertain.

A Review of the Literature on Energy Storage Using Dielectric Materials
There is extensive literature available dealing with the use of dielectric materials for energy storage.Most of that literature is concerned with increasing the dielectric constant of polymer materials.Most of the research involves the analysis and testing of composite polymers consisting of a host polymer with nano-structured molecular or solid particles dispersed as nano-charge storage elements.Since this is the approach suggested in Sections 3 and 4 to develop high energy density capacitors, it is appropriate to survey that literature to determine the present state-of-the-art of high dielectric materials using various techniques to increase their dielectric constant.About least 200 papers were surveyed to assess the present state-of-the-art.There are also a number of recent books [5-9] that discuss in detail various aspects of the development and applications of dielectric polymer nanocomposites.Each of the books written in the last ten years treats in detail aspects of polymer nanocomposite technology and its importance in the capacitor industry.
The technical literature is extensive and detailed.It can be divided into the following categories: 1.
Analytical papers dealing primarily with theory and polymer mixing rules 2.
Composites of mixtures of different polymers 3.
Nanocomposites using core-shell coated ceramic particles and metal inserts 4.

Breakdown strength characteristics of polymer composites and films
The literature indicates that many approaches [10][11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29] have been used to increase the dielectric constant of polymer composites with some success.However, the magnitude of the increase in dielectric constant achieved varied greatly from paper to paper, even for the same approach.Many of the increases achieved were less than a factor of ten which is much less than the goal of at least 500-1000 needed to develop the devices of interest in the present paper.In addition, the increase in dielectric constant is needed at high voltage (>1000 V) with a breakdown strength to sustain that voltage with very small leakage current.
The papers were surveyed to identify studies with large increases in the magnitude of the dielectric constant, very high DC resistance and low loss tangent, and some evidence of high voltage capability.These are difficult requirements to meet, but there were some studies that provided data that indicated they have met some of the target requirements.One of the problems with evaluating the various studies is that the authors do not always specify the dimensions of the elements inserted into the host polymer and the thickness of the material layers being tested.Both factors can have a large influence on the useable dielectric properties of the composites being tested.

Analytical Papers Dealing Primarily with Theory and Polymer Mixing Rules
The papers [10][11][12][13][14][15] of most interest in this area deal with mixing rules and explanations of why polymer nanocomposites can have high dielectric constants.Key phenomena are the displacement effects (induced electric fields) with high ε ceramic particles and percolation effects with conducting particles.The mixing rules (11,12) are of most interest as applied to mixing two polymers of different dielectric characteristics.

Composites of Mixtures of Different Polymers
There have been many studies [16][17][18][19] of combining two or more polymers with the objective of attaining a composite with properties more optimum for energy storage.That is a higher dielectric constant, lower loss tangent, and more linear behavior at high voltages.As an example [16], PDVF, which has a high dielectric constant, but relatively high losses and limited voltage linearity, is usually combined with other polymers to obtain a composite polymer with improved loss and voltage linearity than PDVF.Mixing/blending of polymers is not as simple a process as the term would imply as the mixing takes place on a nanoscale with the configuration/spacing of the different polymer molecules being difficult to predict and measure [17][18][19].Most host polymers are likely to be mixes of several polymers [15,16].Both of these papers involve the mixing of PVDF with several other polymers to increase the dielectric constant and reduce the conduction losses.Examples of mixing polymers are shown in Figure 1, indicating significant increases in dielectric constant in the composites.

Composites of Mixtures of Different Polymers
There have been many studies [16][17][18][19] of combining two or more polymers with the objective of attaining a composite with properties more optimum for energy storage.That is a higher dielectric constant, lower loss tangent, and more linear behavior at high voltages.As an example [16], PDVF, which has a high dielectric constant, but relatively high losses and limited voltage linearity, is usually combined with other polymers to obtain a composite polymer with improved loss and voltage linearity than PDVF.Mixing/blending of polymers is not as simple a process as the term would imply as the mixing takes place on a nanoscale with the configuration/spacing of the different polymer molecules being difficult to predict and measure [17][18][19].Most host polymers are likely to be mixes of several polymers [15,16].Both of these papers involve the mixing of PVDF with several other polymers to increase the dielectric constant and reduce the conduction losses.Examples of mixing polymers are shown in Figure 1, indicating significant increases in dielectric constant in the composites.In order to meet the requirements for high dielectric constant, low losses, high voltage, multilayer systems in which the layers have every distinct and different properties and only one of the layers has a high dielectric constant.Reviews of multilayer, high energy density systems are given in [20][21][22].The multilayer arrangement combines one or two layers having a high dielectric constant with or two layers with very high resistance, high breakdown strength, and relatively low dielectric constant.The layer(s) with very high resistance are intended to block leakage current and increase the effective breakdown voltage of the multilayer system.Research has been done on both the sandwich-type in which the high energy density layer is in the middle with two outside blocking layers and the reverse sandwich-type with the blocking layer in the middle and two high ε layers on the outside.There has been a large variation in the thickness of the layers in the multilayer systems analyzed.The effective dielectric constant of the layered system is less than that of the high ε layers, but the increased breakdown voltage results in an increased energy density of the layered system.

Percolation Effect
In all the analyses in Section 3, it will be assumed that the particles are uniformly distributed in the host polymer and the charge transfer to the polymer is unimpeded by any surface layer between the particle and the polymer.In other words, the analysis assumes an ideal arrangement that is not likely to occur in practice.Deviations from the ideal are well known from testing of polymer composites and are termed percolation In order to meet the requirements for high dielectric constant, low losses, high voltage, multilayer systems in which the layers have every distinct and different properties and only one of the layers has a high dielectric constant.Reviews of multilayer, high energy density systems are given in [20][21][22].The multilayer arrangement combines one or two layers having a high dielectric constant with or two layers with very high resistance, high breakdown strength, and relatively low dielectric constant.The layer(s) with very high resistance are intended to block leakage current and increase the effective breakdown voltage of the multilayer system.Research has been done on both the sandwich-type in which the high energy density layer is in the middle with two outside blocking layers and the reverse sandwich-type with the blocking layer in the middle and two high ε layers on the outside.There has been a large variation in the thickness of the layers in the multilayer systems analyzed.The effective dielectric constant of the layered system is less than that of the high ε layers, but the increased breakdown voltage results in an increased energy density of the layered system.

Percolation Effect
In all the analyses in Section 3, it will be assumed that the particles are uniformly distributed in the host polymer and the charge transfer to the polymer is unimpeded by any surface layer between the particle and the polymer.In other words, the analysis assumes an ideal arrangement that is not likely to occur in practice.Deviations from the ideal are well known from testing of polymer composites and are termed percolation effects [23][24][25][26][27].
Most analyses indicate that the increase in the dielectric constant is linear with the volume loading factor f v .In those cases involving percolation, change in the dielectric constant is very non-linear of the form.
where f vc is the percolation threshold loading and p is the exponent in the percolation effect relationship.The f vc and p values are determined experimentally by varying f v and measuring the effect on ε.Typical experimental data for a polymer composite using carbon nanotubes (MWCNT) are shown in Figure 2.For this test, the threshold value f cv is about 14% and the maximum ε is very high being about 8000.The conductivity of the composite increases over many orders of magnitude as f v is changed, indicating the arrangement of the particles is undergoing large changes.The threshold value can range from a few % to 40-50%, depending on the materials in the device being tested and its thickness.There seems to be a linear zone before the rapid increase of ε in the percolation zone.Incorporating a better understanding of the percolation effects and how to optimize them in developing materials for high energy density dielectric devices will be very important.
Appl.Sci.2021, 11, x FOR PEER REVIEW 5 of 22 effects [23][24][25][26][27].Most analyses indicate that the increase in the dielectric constant is linear with the volume loading factor fv.In those cases involving percolation, change in the dielectric constant is very non-linear of the form.
where fvc is the percolation threshold loading and p is the exponent in the percolation effect relationship.The fvc and p values are determined experimentally by varying fv and measuring the effect on Ɛ.Typical experimental data for a polymer composite using carbon nanotubes (MWCNT) are shown in Figure 2.For this test, the threshold value fcv is about 14% and the maximum Ɛ is very high being about 8000.The conductivity of the composite increases over many orders of magnitude as fv is changed, indicating the arrangement of the particles is undergoing large changes.The threshold value can range from a few % to 40-50%, depending on the materials in the device being tested and its thickness.There seems to be a linear zone before the rapid increase of Ɛ in the percolation zone.Incorporating a better understanding of the percolation effects and how to optimize them in developing materials for high energy density dielectric devices will be very important.

Nanocomposites Using Core-Shell Coated Particles and Metal Inserts
There have been many studies of embedding nanocomposites mixing ceramic, ferroelectric particles into a host polymer to attain an increase in dielectric constant [28][29][30][31][32][33][34].Most of the studies have been done using BaTiO3 particles as they have a very high dielectric constant of 3000-5000.If BaTiO3 particles are deposited in a very thin film (less than 1µ), the dielectric constant of the film can be 600-800 [25] with a low loss tangent.However, when BaTiO3 particles are mixed into a host polymer, the dielectric constant of the composite [29][30][31] is in the range of 30-40 even at high loadings (30-40%).Higher dielectric constants can be achieved using CCTO particles [29] but with a large percolation effect after 25% loading.Coating the particles and changing their shape can result in modest increases in dielectric constant and a modest percolation effect [33,34], resulting in a dielectric constant of 400-500.
There have been some studies with particles embedded in a host polymer that have resulted in large increases in the dielectric constant.One study [35] used Ni and BaTiO3 particles in PVDF.With only the BaTiO3 particles, the maximum dielectric constant achieved was about 50, but by adding the Ni particles, a dielectric constant of 800 was achieved for a 20% loading of both the BaTiO3 and Ni particles including percolation effects.In another study [36] with PVDF, carbon particles coated with silica were embedded in the host polymer.For a particle loading of about 9%, a dielectric constant of 1000 was achieved with an AC conductivity of 5 × 10 −4 Ohm-cm.These data indicate that embedding

Nanocomposites Using Core-Shell Coated Particles and Metal Inserts
There have been many studies of embedding nanocomposites mixing ceramic, ferroelectric particles into a host polymer to attain an increase in dielectric constant [28][29][30][31][32][33][34].Most of the studies have been done using BaTiO 3 particles as they have a very high dielectric constant of 3000-5000.If BaTiO 3 particles are deposited in a very thin film (less than 1 µ), the dielectric constant of the film can be 600-800 [25] with a low loss tangent.However, when BaTiO 3 particles are mixed into a host polymer, the dielectric constant of the composite [29][30][31] is in the range of 30-40 even at high loadings (30-40%).Higher dielectric constants can be achieved using CCTO particles [29] but with a large percolation effect after 25% loading.Coating the particles and changing their shape can result in modest increases in dielectric constant and a modest percolation effect [33,34], resulting in a dielectric constant of 400-500.
There have been some studies with particles embedded in a host polymer that have resulted in large increases in the dielectric constant.One study [35] used Ni and BaTiO 3 particles in PVDF.With only the BaTiO 3 particles, the maximum dielectric constant achieved was about 50, but by adding the Ni particles, a dielectric constant of 800 was achieved for a 20% loading of both the BaTiO 3 and Ni particles including percolation effects.In another study [36] with PVDF, carbon particles coated with silica were embedded in the host polymer.For a particle loading of about 9%, a dielectric constant of 1000 was achieved with an AC conductivity of 5 × 10 −4 Ohm-cm.These data indicate that embedding conducting particles in the host polymer is a promising approach to achieve large increases in dielectric constant.

Nanocomposites Using Carbon and Graphene Particles and Nano-Sheets
There have been many studies [37][38][39][40][41] of the application of nano-carbon and graphene in the study of polymer nanocomposites.The carbons in different forms act as conducting elements embedded in the host polymer and thus can act as charge collectors in the microcapacitors formed throughout the host polymer.The size (µ or nm) of the carbon elements is critical in determining the dielectric constant resulting from their use.Unfortunately, the dimensions of the carbon elements and films used to test the composites are often not given in papers.
The use of graphene nano-sheets to increase the dielectric constant in composite polymers is of particular interest.The research seems to have been successful in significantly increasing the dielectric constants of composite polymers.It does not seem difficult to produce composites with graphene nano-sheets of a few nm in thickness oriented parallel to a surface.The research in [39,41] is directly related to the approaches analyzed in Section 3 of this report.Ref. [37] dealt with graphene nano-sheets in PVDF. Figure 3 shows 2-6 nm nano-sheets in PVDF as the host polymer at a volume fraction of 0.0177.This volume fraction is low, but the film prepared is thick.From Figure 3, the spacing of graphene sheets is relatively uniform.The polymer composite was hot pressed into disks 9 mm in diameter and 5 mm in thickness.This is a very thick film and is clearly not suitable for a film capacitor.The Excel spreadsheet model in Section 3 predicted a very high effective dielectric constant (over 10 5 ) for a 5 mm thickness and 0.018 loading.The measured characteristics of the 5 mm thick disk are shown in Figure 4 taken from [39].The maximum dielectric constant measured was about 10 4 .The dielectric constant of the host polymer is about 8.Even at a volume fraction loading of 0.0177, both the conductivity and dielectric loss of the film were high.This research [39] was not done to meet energy storage objectives, but it does seem to indicate that the proposed approach of embedding nm carbon elements in a host polymer can make sense as a way to develop high energy density, high voltage film capacitors.
Appl.Sci.2021, 11, x FOR PEER REVIEW 6 of 22 conducting particles in the host polymer is a promising approach to achieve large increases in dielectric constant.

Nanocomposites Using Carbon and Graphene Particles and Nano-Sheets
There have been many studies [37][38][39][40][41] of the application of nano-carbon and graphene in the study of polymer nanocomposites.The carbons in different forms act as conducting elements embedded in the host polymer and thus can act as charge collectors in the micro-capacitors formed throughout the host polymer.The size (µ or nm) of the carbon elements is critical in determining the dielectric constant resulting from their use.Unfortunately, the dimensions of the carbon elements and films used to test the composites are often not given in papers.
The use of graphene nano-sheets to increase the dielectric constant in composite polymers is of particular interest.The research seems to have been successful in significantly increasing the dielectric constants of composite polymers.It does not seem difficult to produce composites with graphene nano-sheets of a few nm in thickness oriented parallel to a surface.The research in [39,41] is directly related to the approaches analyzed in Section 3 of this report.Ref [37] dealt with graphene nano-sheets in PVDF. Figure 3 shows 2-6 nm nano-sheets in PVDF as the host polymer at a volume fraction of 0.0177.This volume fraction is low, but the film prepared is thick.From Figure 3, the spacing of graphene sheets is relatively uniform.The polymer composite was hot pressed into disks 9 mm in diameter and 5 mm in thickness.This is a very thick film and is clearly not suitable for a film capacitor.The Excel spreadsheet model in Section 3 predicted a very high effective dielectric constant (over 10 5 ) for a 5 mm thickness and 0.018 loading.The measured characteristics of the 5 mm thick disk are shown in Figure 4 taken from [39].The maximum dielectric constant measured was about 10 4 .The dielectric constant of the host polymer is about 8.Even at a volume fraction loading of 0.0177, both the conductivity and dielectric loss of the film were high.This research [39] was not done to meet energy storage objectives, but it does seem to indicate that the proposed approach of embedding nm carbon elements in a host polymer can make sense as a way to develop high energy density, high voltage film capacitors.

Breakdown Strength Characteristics of Polymer Composites and Films
The energy stored in a dielectric storage device is given by where V/δ is the effective breakdown strength(bds) of the device.The unit of bds is MV/m or V/µ.Bds depends on materials in the device and the thicknesses of the dielectric material layers.Bds ranges from 100-400 V/µor even higher for high quality polymer materials, but bds is usually much lower for composite polymers [42][43][44][45].Developing composite polymers with high dielectric constant ε and bds values relatively close to that of uniform polymers is key to the use of dielectrics in high energy storage devices.The effect of the bds on the dielectric constant required for 300 V and 800 V cells having energy densities of 100 and 200 Wh/l is shown in Table 1.The cells are film capacitors requiring very thin films, but the dielectric constant of the films seems to be in a reasonable range using the dielectric materials discussed in this paper.

Breakdown Strength Characteristics of Polymer Composites and Films
The energy stored in a dielectric storage device is given by where V/δ is the effective breakdown strength(bds) of the device.The unit of bds is MV/m or V/µ.Bds depends on materials in the device and the thicknesses of the dielectric material layers.Bds ranges from 100-400 V/µ or even higher for high quality polymer materials, but bds is usually much lower for composite polymers [42][43][44][45].Developing composite polymers with high dielectric constant ε and bds values relatively close to that of uniform polymers is key to the use of dielectrics in high energy storage devices.The effect of the bds on the dielectric constant required for 300 V and 800 V cells having energy densities of 100 and 200 Wh/L is shown in Table 1.The cells are film capacitors requiring very thin films, but the dielectric constant of the films seems to be in a reasonable range using the dielectric materials discussed in this paper.

Analysis of Dielectric Cells Using Nanoparticles Embedded in a Host Polymer
The general background for this modeling can be found in [46,47].The polymer composite capacitor is modeled as an assembly of nm scale micro-capacitors consisting of carbon elements.Uniformly distributed in the host polymer.It is assumed that the carbon elements form a highly regular structure functioning as micro-capacitors that store the electrical charge displaced from the host polymer molecules that are electronically insulating having a dielectric constant ε 1 .A schematic of the polymer composite structure is shown in Figure 5.The microcaps are shown using both platelet and spherical shaped carbon elements.The characteristic dimensions r p and r h of the spherical and platelet elements are defined in the figure.The elements are of nm scale.The loading of the conducting elements is given in terms of its volume fraction f v .The weight fraction f w can be calculated from the following relation.
Considering the case of the spherical elements, the number N p of elements is given by N p = (VL) f v /(4/3Π r p 3 ), where VL is the volume of the dielectric space.The distance ∆ between the centers of the elements is L/∆x W/∆ × δ/∆ = N p where L, W, δ are the dimensions of the dielectric space.
Solving for ∆, ∆ = (4/3Π/f v ) 1/3 r p The length between the elements δ c , which is the separation distance between the electrodes in the microcaps, is given by The capacitance C c of individual microcaps is given by where k c is shape factor for the capacitor The charge on the microcap is Q c = C c ∆V = C c (V/δ) ∆, where V is the voltage across the dielectric space (see Figure 1) assuming V is linear and 2D uniform.
The energy density using spherical carbon elements is (Wh/L) = ½ (ε2 ε0/3600) (V/δ) 2 × 10 −3 (conversion to L from m 3 ) Now consider the case of disk-type/platelet elements.In this case the number of elements Nd is given by Nd = (VL) fv/(ld wd δd), where VL is the volume of the dielectric space.lp, wp, and δp are the length, width and thickness of the disk-type element.The spacing of the elements Δd is given by Δd = (ld wd δd/fv) 1/3   The spacing between the element δcd, which is the separation distance between the electrodes in the microcaps, is given by δcd = Δd − δd = k1d δd where k1d = (ld wd/δd 2 fv) 1/3 − 1 The capacitance Ccd of the individual disk-type microcaps is given by Substituting for C c , The total charge displaced in the dielectric space is Q total , which is given by The effective dielectric constant ε 2 of the composite dielectric space is where k 1 = (4/3Π) 1/3 − 2, k 2 = (4/3Π) 1/3 .A maximum value for f v = (4/3Π)/8 = 0.52.The capacitance C 2 of the composite polymer capacitor is and the energy stored E 2 is given by The energy density using spherical carbon elements is ( Now consider the case of disk-type/platelet elements.In this case the number of elements N d is given by N d = (VL) f v /(l d w d δ d ), where VL is the volume of the dielectric space.l p , w p , and δ p are the length, width and thickness of the disk-type element.The spacing of the elements ∆ d is given by The spacing between the element δ cd , which is the separation distance between the electrodes in the microcaps, is given by where k 1d = (l d w d /δ d 2 f v ) 1/3 − 1 The capacitance C cd of the individual disk-type microcaps is given by where k cd is the shape factor for the capacitor.
The charge on a microcap is where V is the voltage across the dielectric space (see Figure 5).
Substituting for C cd , The total charge displaced in the dielectric space is Q total , which is given by The effective dielectric constant ε 2 of the composite dielectric space is where and the energy stored E 2 is given by The energy density for the dielectric cell with platelet elements is It is of interest to look at the voltage change due to charging the carbon elements and infer the effective resistance of a dielectric cell.The resistivity r cb of carbon is 10 −4 to 10 −5 ohm-cm.The elements are arranged such that there are δ/∆ elements in series and LW/∆ 2 in parallel.The resistance of each carbon element is The effective resistance of charging the elements is R charg = R elem N series /N parallel where N series = δ/∆ and N parallel = LW/∆ 2 , ∆ = (4/3Π/f v ) 1 /r p R charg = r cb / ∏ r p (δ/∆)/(LW/∆ 2 ) = r cb / ∏ (δ)(4/3Π/f v ) 1/3 )/LW LW depends on the geometry of the cell.For a spiral wound cell, LW = ∏r cell × height cell × N t .N t is the number turns in winding the cell.For a typical cell, LW = 3.14 × 5 × 15 × 8000 = 1.88 × 10 5 .For δ = 0.0004 cm, f v = 0.2, R charg = 10 −4 × 0.32 × 3 × 10 −4 × (1.33 × 3.14/0.2) 333 /1.88 × 10 5 = 1.4 × 10 −13 Hence the effective resistance due to charging the carbon elements is very small.Note also that the resistance is independent of the particle size.
Next consider the effect of the microcaps on the breakdown characteristics of the composite polymer.The voltage difference across the microcaps is (V/δ) × δ c , but the distance between the plates in the microcap is also δ c .Since the material between the plates is the host polymer, the breakdown characteristics of the composite should be essentially the same as the host polymer.In addition, the thickness of the potential breakdown layer is very thin, which is a favorable situation.

Polymer Composites Using High Dielectric Constant Particles
In this section of the paper, the case of a polymer composite using high dielectric constant particles is analyzed.In practice, ceramic particles like BaTiO 3 are used.These particles are not conductors, but charge and energy are stored in the particles due to polarization of the molecules in the applied electric field.The same approach as used in the previous analyzes will be used in this analysis.
The first step will be to analysis the response of a spherical particle in the field E 0 .This a classic problem in electrostatics and the solution is shown in most text books [44].A key aspect of obtaining the solution is the boundary condition (b.c.) at the interface between the particle and the host polymer.The b.c. is (D 2 − D 1 ).n = 0 at r = r p for dielectrics D is a vector and is equal εE.Hence ε 2 E 2n = ε 1 E 1n at r = r p , n is the normal component of E Applying the b.c. to the general solution for the potential function U inside the particle U = A 2 r cosθ, θ is the angle between r and E 0 One finds And the electric field E 2 inside the particle is constant and in the direction of E 0 .
Hence, the electric field inside the particle is greatly reduced.Now we can analyze the effect of the particles on the effective dielectric constant ε 3 of the composite.The capacitance C p of the particle is given by The total charge stored by polarization of the particles is The charge of the composite polymer is given by Consider the example: f v = 0.2, δ = 2µ, r p = 2 nm, ε 2 = 3000, ε 1 = 8, e f = 0.008.For this case, ε 3 /ε 2 = 0.015 and ε 3 = 45.
If the high dielectric constant particles and conducting particles were used to form a polymer composite, the effects of the two types of particles would be multiple.The dielectric constant of the composite is projected to be

Multilayer Device Analysis
The dielectric devices analyzed consist of three layers.The first device treated has a high ε layer between two lower ε outside layers which have very high resistivity and high breakdown strength.This arrangement is termed the sandwich configuration.The electric fields in the layers are related to their dielectric constants.

Application of the Analysis to Capacitor Design
The analysis in Section 3 has been applied to prepare an Excel model for the design of dielectric capacitors having specific characteristics.The Excel model permits the rapid calculation of cell characteristics for any inputs of interest.Models were prepared for both spherical and platelet carbon elements.The first step in the model preparation was to calculate the characteristics of a 1 m 2 section of the cell for which the characteristics of a spiral wound cell was desired.The second step was to determine the characteristics of a spiral wound cell (Figure 6) of a specific size (diameter and height).The voltage of the cell was an input and, in most cases, was 1000 V. Examples of the model calculations and cell characteristics for both spherical and platelet carbon elements are shown in Table 2. Spiral wound cell characteristic for a range of cell design inputs are shown in Tables 3 and 4.   The outputs of the Excel models indicate that the spiral wound dielectric cell can have an energy density close to that of lithium batteries if the carbon elements are 1-3 nm and the thickness of the dielectric cell winding is 3-4 µ for a cell voltage of 1000 V.The power of the cell will be very high (MW/L) at very high efficiency (99%).The resistance of the cell will be due mainly to the thin aluminum layers (100 nm) distributing the electrical current to the dielectric winding.The detailed characteristics of two cell designs are shown in Table 2.The performance results shown in Tables 3 and 4 indicate the energy density is a strong function of the carbon element and cell winding dimensions.The dielectric constant ratio (ε 2 /ε 1 ) is proportional to δ/r p .The host polymer should have a high dielectric constant (ε 1 ) and breakdown strength (V/µ).Polvinylidene Fluoride (PVDF) seems like a good choice for the host polymer.According to a plastics spec sheet [9], ε 1 = 7.5-13.2and the dielectric strength = 260-950 V/µ.Data for other polymers are given Table 5 taken from [48].It is clear from Table 5 that selection of a host polymer will involve the trade-off of several performance characteristics (dielectric constant, conductivity, loss tangent, and breakdown strength).The design results shown in Tables 3 and 4 indicate that the dielectric capacitors are especially well suited for electric utility applications because of their high cell voltage (1000 V) and very high power capability.They should have long cycle life, low maintenance, and be very safe along with energy densities like batteries.Cost ($/MWh) should be reasonable when produced in high volume when the manufacture the composite dielectric material with embedded carbon becomes mature.

Evaluation/Testing of Dielectric Cells
This paper is concerned with the development of dielectric materials and cells for batteries for vehicles, industrial, and electric utility applications.These applications require the storage of many kWh of energy and power levels of many kWs and system response times of fractions of seconds.In other words, the dielectric devices would be used much like lithium batteries are currently used.Hence testing of dielectric materials and cells should be done using procedures and data interpretation consistent with those applications.Nearly all the testing of dielectric materials and devices in the literature is for power electronics applications and most of the data available were taken over wide ranges of AC frequencies (10 2 -10 6 ).Hence the responses of the dielectric devices were measured for response times of ms and shorter.
There has been experience testing electrochemical supercapacitors (EDLCs) that has relevance to testing the dielectric devices (DLCDs) of interest in this paper.The voltage change of both types of devices in charging and discharging is dominated by their capacitance (∆V = ∆Q/C).The energy stored in both types of devices is 1/2 CV 2 for ideal, no loss devices.Test procedures and typical data for testing electrochemical supercapacitors are given in [49,50].That testing is directed to measuring C, R, Wh/L, W/L, and energy efficiencies for ranges of currents and powers.Similar testing will be required of DLCDs.
There are, of course, major differences between EDLCs and DLCDs.First and foremost, the charge in the DLCDs is bound to the layered dielectric material and in the EDLCs, it is free to move through the device.Hence EDLCs have a resistance in the classic sense and DLCDs do not.Most of the losses in the DLDCs are associated with rapid changes in the polarization of the molecules in the dielectric layer as the device is charged and discharged.In addition, EDLCs are low voltage devices with rated (maximum) voltage fixed by the electrolyte.DLCD are high voltage devices with their maximum operating voltage determined by the breakdown strength (MV/m) of the layered dielectric material and its thickness.These differences will influence significantly how DDLCs are tested compared to EDLCs.
There seems to be little discussion of DC testing of DLCDs in the literature.One source is a chapter in [9], which discusses both DC and high frequency testing of DLCDs.The testing should determine the characteristics of both the dielectric layer and the device as a function of current, power, SOC, temperature, and voltage (MV/m).The key parameters to be determined are the dielectric constant of the dielectric layer and the Wh/L, W/L, chargedischarge efficiency, effective parallel resistance, leakage current, and thermal stability of the devices.Varying the thickness of dielectric layer will permit investigation of the effects of high MV/m.Special test equipment will be needed to measure the very low currents expected to be encountered in testing small DLDC cells.

Review of Research on High Voltage, Film Capacitors
The analysis and calculations in Sections 3 and 4 indicate that dielectric cells assembled using a host polymer with nm size carbon elements embedded can have high energy density and very high power.The dielectric layer will be thin (1-5 µ) and the carbon particles must be arranged very uniformly and have very good contact with the host polymer.In other words, the calculated results correspond to an ideal dielectric cell.In addition, the dielectric layers in the devices are very thin films.There are clearly serious questions regarding how closely the ideal assembly of the cells can be approached in practice even after extensive development.
A survey of the literature has not found research using carbon elements in composite polymers to increase their dielectric constant at high voltage (1000 V), but there has been successful research [51][52][53][54] using other types of particles for that purpose in thin films.Also, there has been much research on electrochemical capacitors [52][53][54][55][56] using particulate carbon and graphene sheets/plates to increase the specific capacitance (F/g) of electrodes.In this section, a review of some of the relevant research is presented, and its relevance to the development of the proposed dielectric devices indicated.
Some relevant high voltage research can be found in [51][52][53][54][55]. Ref. [51] is a recent review of the properties of polymer composites used in high voltage applications.It treats many of the same filler particles at high voltage that were considered at lower voltages in Section 2. In [16], a study is described in detail of mixed polymers of various properties to yield a composite with high dielectric constant and high breakdown strength.Thin films of the composite were tested up to 4 kV.The results of the testing are shown in Figure 7, which indicate an energy density of the film of about 6 Wh/L (22 J/cm 3 ) at 370 V/µ.The thickness of the film is not given in [51], but the breakdown value of 4 kV indicates a thickness of 10-15 µ.
the dielectric layers in the devices are very thin films.There are clearly serious questions regarding how closely the ideal assembly of the cells can be approached in practice even after extensive development.
A survey of the literature has not found research using carbon elements in composite polymers to increase their dielectric constant at high voltage (1000 V), but there has been successful research [51][52][53][54] using other types of particles for that purpose in thin films.Also, there has been much research on electrochemical capacitors [52][53][54][55][56] using particulate carbon and graphene sheets/plates to increase the specific capacitance (F/g) of electrodes.In this section, a review of some of the relevant research is presented, and its relevance to the development of the proposed dielectric devices indicated.
Some relevant high voltage research can be found in [51][52][53][54][55]. Ref. [51] is a recent review of the properties of polymer composites used in high voltage applications.It treats many of the same filler particles at high voltage that were considered at lower voltages in Section 2. In [16], a study is described in detail of mixed polymers of various properties to yield a composite with high dielectric constant and high breakdown strength.Thin films of the composite were tested up to 4 kV.The results of the testing are shown in Figure 7, which indicate an energy density of the film of about 6 Wh/L (22 J/cm 3 ) at 370 V/µ.The thickness of the film is not given in [51], but the breakdown value of 4 kV indicates a thickness of 10-15 µ.
Ref [53] is a good review of the state-of-the-art of thin film plastic capacitors and a discussion of the characteristics of available dielectric polymer materials.The paper is concerned with spiral wound capacitors developed using a new polymer HED (modified polyethylene terephthalate).Test data for the new capacitors are shown in Table 6 and Figure 8.The data indicate an energy density of 1.3 Wh/L (4.7 J/cm 3 ).Ref. [53] is a good review of the state-of-the-art of thin film plastic capacitors and a discussion of the characteristics of available dielectric polymer materials.The paper is concerned with spiral wound capacitors developed using a new polymer HED (modified polyethylene terephthalate).Test data for the new capacitors are shown in Table 6 and Figure 8.The data indicate an energy density of 1.3 Wh/L (4.7 J/cm 3 ).Ref [54] is a presentation by General Electric of the development of a DC bus film capacitor on a DOE contract.That work utilized polyetherimide (PEI) as the polymer dielectric.The film thicknesses were 3-5µ with a breakdown strength of 500-600 V/µ.The results of the development are summarized in Table 7.The energy density of the 800 µF film capacitor shown in the table is 1.5 Wh/L tested at about 1600 V.
Ref [55] involves the fabrication of spiral wound capacitors from flexible alkali glass (Ɛ = 5.7) ribbons of thickness 50µ.The capacitance of the device was only 70 nF with energy density of 1.2 Wh/L, but as shown in Figure 9, it was tested to 1000 V with no change in capacitance.
The references cited indicate that thin film devices with thicknesses of 2-4 µ can be fabricated and tested to 1000-2000 V corresponding to breakdown strength of 300-600 V/µ.Using uniform single polymers, the energy densities of the films are only about 1 Wh/L.Using a composite of two different polymers, a thin dielectric film with an energy density of about 6 Wh/L was tested at 370 V/µ.Ref. [54] is a presentation by General Electric of the development of a DC bus film capacitor on a DOE contract.That work utilized polyetherimide (PEI) as the polymer dielectric.The film thicknesses were 3-5µ with a breakdown strength of 500-600 V/µ.The results of the development are summarized in Table 7.The energy density of the 800 µF film capacitor shown in the table is 1.5 Wh/L tested at about 1600 V. Capacitor weight (g) 800-900 700 Overall weight (g) ≤1000 1800 Ref. [55] involves the fabrication of spiral wound capacitors from flexible alkali glass (ε = 5.7) ribbons of thickness 50 µ.The capacitance of the device was only 70 nF with energy density of 1.2 Wh/L, but as shown in Figure 9, it was tested to 1000 V with no change in capacitance.
The references cited indicate that thin film devices with thicknesses of 2-4 µ can be fabricated and tested to 1000-2000 V corresponding to breakdown strength of 300-600 V/µ.Using uniform single polymers, the energy densities of the films are only about 1 Wh/L.Using a composite of two different polymers, a thin dielectric film with an energy density of about 6 Wh/L was tested at 370 V/µ.

Review of Electrochemical Capacitor Research using Carbon/Graphene and Polymers
As discussed in previous sections of the paper, the approach taken to increase the dielectric of the composite polymer is to embed nm size spherical particles or nanosheets/platelets of carbon in the host polymer.Some of the research on using carbons in electrochemical supercapacitors is related to their use in developing polymer composites.
There has been research done to generate spherical carbon particles for use in electrodes for supercapacitors.Since the objective of the supercapacitor research is to prepare carbons with high specific capacitance (F/g), the pore size distribution in the carbon and not the geometric size of particles was of prime interest.As shown in Figure 10-12, the particles appear to be nicely spherical, but their diameter is 100-500 nm in most cases [56][57][58].The smallest diameter carbon spheres found in the literature was 50 nm, which is much larger than needed for the dielectric capacitors.Further work is needed to determine how spherical carbon particles having a diameter of 3-4 nm can be generated.

Review of Electrochemical Capacitor Research Using Carbon/Graphene and Polymers
As discussed in previous sections of the paper, the approach taken to increase the dielectric of the composite polymer is to embed nm size spherical particles or nanosheets/platelets of carbon in the host polymer.Some of the research on using carbons in electrochemical supercapacitors is related to their use in developing polymer composites.
There has been research done to generate spherical carbon particles for use in electrodes for supercapacitors.Since the objective of the supercapacitor research is to prepare carbons with high specific capacitance (F/g), the pore size distribution in the carbon and not the geometric size of particles was of prime interest.As shown in Figures 10-12, the particles appear to be nicely spherical, but their diameter is 100-500 nm in most cases [56][57][58].The smallest diameter carbon spheres found in the literature was 50 nm, which is much larger than needed for the dielectric capacitors.Further work is needed to determine how spherical carbon particles having a diameter of 3-4 nm can be generated.

Review of Electrochemical Capacitor Research using Carbon/Graphene and Polymers
As discussed in previous sections of the paper, the approach taken to increase the dielectric of the composite polymer is to embed nm size spherical particles or nanosheets/platelets of carbon in the host polymer.Some of the research on using carbons in electrochemical supercapacitors is related to their use in developing polymer composites.
There has been research done to generate spherical carbon particles for use in electrodes for supercapacitors.Since the objective of the supercapacitor research is to prepare carbons with high specific capacitance (F/g), the pore size distribution in the carbon and not the geometric size of particles was of prime interest.As shown in Figure 10-12, the particles appear to be nicely spherical, but their diameter is 100-500 nm in most cases [56][57][58].The smallest diameter carbon spheres found in the literature was 50 nm, which is much larger than needed for the dielectric capacitors.Further work is needed to determine how spherical carbon particles having a diameter of 3-4 nm can be generated.Over the years, much research has been done to use various forms of carbon to increase the energy density of electric double-layer capacitors (EDLCs).The use of graphene and its derivatives in various forms can significantly increase the specific capacitance of electrode materials [59][60][61][62][63][64].Nanoscale graphene (particles and atomic scale layers) also enhance electron and thermal conductivity of the electrode, which improves the power capability and capacitance.Skeleton Technology [59] has developed large EDLC devices (3200 F) with an energy density of 8.9 Wh/kg using graphene combined with activated carbon in the electrodes.If used properly, graphene can improve the specific capacitance of carbon electrodes as its theoretical specific capacitance is 550 F/g.El-Kady et al. [60,61] demonstrated cells with very high energy density while maintaining high power density by laser reduction of graphene oxide.Electrochemical capacitor devices with graphene-based electrodes show excellent cycle stability (all-solid-state LSG-EC: >97% after 10000 cycles) in addition to very high energy density and power density.The laser scribed grapheneelectrochemical capacitors have high potentiality for commercial applications due to their superior electrode structure.Supercapacitor research [63,64] has also included combining conducting polymers with the nano-carbon to improve the specific capacitance (F/g) of the electrodes.In most cases, the conducting polymers have been used to coat carbon particles, nanotubes, or nanoplatelets.Over the years, much research has been done to use various forms of carbon to increase the energy density of electric double-layer capacitors (EDLCs).The use of graphene and its derivatives in various forms can significantly increase the specific capacitance of electrode materials [59][60][61][62][63][64].Nanoscale graphene (particles and atomic scale layers) also enhance electron and thermal conductivity of the electrode, which improves the power capability and capacitance.Skeleton Technology [59] has developed large EDLC devices (3200 F) with an energy density of 8.9 Wh/kg using graphene combined with activated carbon in the electrodes.If used properly, graphene can improve the specific capacitance of carbon electrodes as its theoretical specific capacitance is 550 F/g.El-Kady et al. [60,61] demonstrated cells with very high energy density while maintaining high power density by laser reduction of graphene oxide.Electrochemical capacitor devices with graphenebased electrodes show excellent cycle stability (all-solid-state LSG-EC: >97% after 10000 cycles) in addition to very high energy density and power density.The laser scribed graphene-electrochemical capacitors have high potentiality for commercial applications due to their superior electrode structure.Supercapacitor research [63,64] has also included  Over the years, much research has been done to use various forms of carbon to increase the energy density of electric double-layer capacitors (EDLCs).The use of graphene and its derivatives in various forms can significantly increase the specific capacitance of electrode materials [59][60][61][62][63][64].Nanoscale graphene (particles and atomic scale layers) also enhance electron and thermal conductivity of the electrode, which improves the power capability and capacitance.Skeleton Technology [59] has developed large EDLC devices (3200 F) with an energy density of 8.9 Wh/kg using graphene combined with activated carbon in the electrodes.If used properly, graphene can improve the specific capacitance of carbon electrodes as its theoretical specific capacitance is 550 F/g.El-Kady et al. [60,61] demonstrated cells with very high energy density while maintaining high power density by laser reduction of graphene oxide.Electrochemical capacitor devices with graphenebased electrodes show excellent cycle stability (all-solid-state LSG-EC: >97% after 10000 cycles) in addition to very high energy density and power density.The laser scribed graphene-electrochemical capacitors have high potentiality for commercial applications due to their superior electrode structure.Supercapacitor research [63,64] has also included

Summary and Conclusions
In this paper, the design of high energy density dielectric capacitors for energy storage in vehicle, industry, and electric utility applications has been considered in detail.The literature on composite polymer materials was reviewed to assess the present state-of-theart of the dielectric constant of dielectric materials being developed to increase energy density.It was found that there were a number of papers in which dielectric materials having dielectric constants of 20-30 were reported, but only a few showing materials with very high dielectric constants of 500 and greater.The very high dielectric constants were usually achieved with nanoscale metallic or carbon particles embedded in a host polymer and the maximum dielectric constant occurring near the percolation threshold particle loading.Unfortunately, the tangent loss associated with the high dielectric constant was high.In general, the breakdown strength of the composite polymer was significantly less than the host polymer.All the dielectric material testing was done at relatively high frequency and no DC data was available.For some composite polymer materials, the dielectric constant was nearly independent of frequency, but for most materials, the dielectric constant decreased markedly with frequency.
The second step in the study was to develop an analytical method to calculate the dielectric constant of composite polymers with various types of nanoparticles embedded in the host polymer.In the analysis, it was assumed the particles were arranged uniformly and that the effects of the interfaces between the host polymer and the particles were negligible.The analytical results were used in an Excel spreadsheet to calculate the characteristics of spiral wound battery cells using various composite polymers with embedded particles.The calculated energy densities were strong functions of the size of the particles and thickness of the dielectric layer in the cell, but for a 1000 V cell, an energy density of 100-200 Wh/kg was calculated for 3-5 nm particles and 3-5µ thick layers.The analytical method and calculations did not include the effects of percolation and any losses related to changes in molecular polarizability with electric field.Nonetheless, the calculations indicated that the development of dielectric capacitor cells with battery-like energy density may be possible.These devices will be especially useful for electric utility energy storage because of their high cell voltage, long cycle life, and solid-state construction.
The results of this study indicate that dielectric materials with a dielectric constant of 500-1000 are needed to design dielectric capacitor cells with battery-like energy density.These cells would likely use a mix of polymers as the host polymer with nm size carbon and/or graphene particles embedded and a voltage of 800-1000 V.The breakdown strength would be 300-400 MV/m in reverse sandwich multilayer dielectric arrangements.The leakage current of the cell would be determined from appropriate DC testing.

Figure 2 .
Figure 2. The percolation effect on the dielectric constant [23].(a)Dielectric Permittivity; (b) electricalconductivity of CNT/elastomer composites as a function of CNT loadings.

Figure 2 .
Figure 2. The percolation effect on the dielectric constant [23].(a)Dielectric Permittivity; (b) electricalconductivity of CNT/elastomer composites as a function of CNT loadings.

Figure 5 .
Figure 5. Geometric configurations of the microcaps.Substituting for Cc,

Figure 6 .
Figure 6.Schematic of a spiral wound d dielectric cell.Figure 6.Schematic of a spiral wound d dielectric cell.

Figure 6 .
Figure 6.Schematic of a spiral wound d dielectric cell.Figure 6.Schematic of a spiral wound d dielectric cell.

Figure 7 .
Figure 7. Energy density and breakdown data for mixed-polymer thin films.(a) The energy density of PVDF-TrFE-CFE/ArPTU composite films with different composite ratios; (b) Comparing of discharge energy density of our works with reported works [16].

Figure 7 .
Figure 7. Energy density and breakdown data for mixed-polymer thin films.(a) The energy density of PVDF-TrFE-CFE/ArPTU composite films with different composite ratios; (b) Comparing of discharge energy density of our works with reported works [16].

Table 1 .
The effect of breakdown strength on the required dielectric constant for cells of high energy density. 1/3

Table 2 .
Spreadsheet design results for spiral wound cells.

Table 3 .
Dielectric cell Wh/L using spherical carbon elements and host polymer.

Table 4 .
Dielectric cell Wh/L using platelet graphene carbon elements and host polymer.

Table 7 .
[51]ary of the characteristics of the film capacitor being developed by General Electric[51].

Table 7 .
[51]ary of the characteristics of the film capacitor being developed by General Electric[51].