Mechanical Properties of Green Synthesized Graphene Nano-Composite Samples

: Graphene quantum dots are zero-dimensional nanoparticles that are used widely in ad-vanced composite materials such as ﬁltration membranes, adsorbent materials, optical devices, biomedical applications (especially biosensors), ﬂame retardancy, and automotive, aerospace, agri-cultural and environmental applications. In this article, the mechanical properties (ﬂexural strength, ﬂexural strain and elastic modulus) of polymer-based nanocomposites will be investigated. The main novelty of the current work is the green synthesis of graphene quantum dots which were extracted from lemon juice. XRD and FTIR tests have been conducted to determine the composition of the prepared powder. The polyester resin and graphene quantum dots were mixed with different weight percentages (0.25%, 0.5% and 1% wt. graphene) and processed to fabricate nanocomposite samples. The mechanical properties of the prepared samples were measured according to the ASTM D790-17 standard testing method. The experimental results show that the strength increased from 80 MPa to about 112 MPa (40% increase in strength) by adding 0.25% wt. graphene quantum dots. The ﬂexural modulus decreased from 2.70 GPa to 2.06 GPa by adding 1% wt. graphene content (23% decrease). The ﬂexural strain increased considerably (up to 14.2%) by adding 1% wt. graphene quantum dots. Consequently, the ductility of the nanocomposites increased by adding green synthesized graphene quantum dots. The fracture behavior changed from brittle fracture mode to ductile fracture mode by adding the graphene quantum dots. Additionally, a ﬂame retardancy test has been carried out by implementing the UL-94 test. The fabricated nanocomposites showed ﬁre retardancy due to char barrier formation on the surface of the nanocomposites. sonicator (Hielscher UP400S) at an output power of 200 W and a frequency of 24 kHz. The solution was left in the room environment for 40 min (debubbling). The 0.350 g of cobalt additive (0.5% wt.) was added to the mixture of styrene and graphene quantum dots and mechanically stirred for 3 min at an 80-rpm rotational speed. The solution was left again for 15 min. The last step was adding methyl ethyl ketone peroxide (hardener) to the mixture. The 0.423 g of methyl ethyl ketone peroxide (0.6 % wt.) was added to the mixture and stirred for 3 min at an 80-rpm rotational speed. Then, the mixture was transferred to the sample preparation die, cured at room temperature for 40 h and post-cured at 80 ◦ C for 8 h in an oven. Figure 3 shows the graphene nanocomposite mixture after stirring and the prepared samples with and without graphene quantum dots. growth are three main mechanisms of failure in nanocomposites The crack growth direction changes when it receives the nanoparticles, and the micro-void coalescence is retarded. The error bar of the ﬂexural modulus, ﬂexural strength and ﬂexural strain was considerably low. Several pieces of research have been published about the improvement of the mechanical properties of composites by adding nanoparticles. As a special case, Shokrieh et al. [36,37] improved the ﬂexural strength of polyester nanocomposites by about 18% using multi-wall carbon nanotubes (CNT). Additionally, various carbon-based nano-additives were applied in the polymer nanocomposites, but to the best knowledge of the present authors, this article is the ﬁrst attempt at using green synthesized graphene quantum dots to enhance the mechanical properties of nanocomposites. As the results show, considerable enhancement in the ﬂexural behavior and strain at failure was obtained.


Introduction
Graphene is a one-atom-thick 2D honeycomb structure of carbon atoms with extra high in-plane elastic stiffness and electrical and thermal conductivities. Graphene's density equals 2.1 g/cm 3 , and it has been investigated widely by researchers since 2004. Graphene-based nanocomposites can be used in different industries. Graphene is one of the more exciting materials in the composite sectors. The graphene material shows considerably high mechanical strength (Young's modulus:~1000 GPa), high thermal conductivity (3000-5000 W/(m·K)) and good optical transparency (~97.7%) [1]. Because of the good mechanical, electrical and physical properties of graphene, it can be used in various industrial applications, such as solar cells, energy storage devices, sensors, photocatalysis, electrocatalysis, electronic panels, lightweight composites, lubrication, LEDs and so on [1,2]. and rice husks [22]. Several studies have been conducted for reducing graphene oxide and improving the production process of graphene on a large scale [23,24]. Graphene quantum dots are environmentally friendly due to their nontoxic and biologically inert properties. Graphene quantum dots are stable chemically and physically because of their intrinsic inert carbon properties. Tian et al. [25] published a review paper. They discussed different methods of graphene quantum dot preparation such as the hydrothermal method, microwave-assisted hydrothermal method, soft template method, liquid exfoliation method, metal-catalyzed method and electron beam lithography method. Yan et al. [26] also published a review paper, and the differences between graphene quantum dots and other nanomaterials, including nano carbons, were discussed. Good mechanical, electrical and photosensitive applications can be obtained using graphene quantum dots by fabricating nanocomposite polymers. Gobi et al. studied the effect of adding graphene quantum dots to epoxy resin. The results showed that the tensile strength, Young's modulus and nominal strain at break increased by 125%, 153.4% and 18.1%, respectively [27]. The graphene-based nanocomposites will be a starting point for new and more sophisticated composite materials.
The literature survey shows different aspects of using graphene in nanocomposite fabrication. Graphene was used as nanoplatelets and nanosheets at first. Then, by introducing graphene quantum dots, new ways for using this type of carbon atom were found. Several studies have been carried out on lemon extract to reduce the graphene oxide and graphene quantum dot synthesis. However, the synthesis of graphene quantum dots directly from the lemon extract is very novel. In this article, the effect of different weight percentages of graphene quantum dots on polyester nanocomposite fabrication will be investigated. The main difference between the current work and other implemented research is the way of preparing graphene quantum dots: green synthesis and the usage of graphene quantum dots to enhance the mechanical properties of polymer-based nanocomposites. The flexural strength, strain at the failure point and elastic modulus of the nanocomposites were measured and discussed. The flame retardancy of fabricated nanocomposites will be carried out against fire.

Green Synthesized Graphene Quantum Dots
For the preparation of carbon graphene particles, 10 mL of lemon juice (0.01 mol of citric acid extract) and 0.01 mol of ethylenediamine were added to 200 mL water. The lemon juice is prepared from natural fruit. Then, the dispersion was transferred into a Teflon-lined stainless autoclave (volume: 250 mL, manufactured in the workshop of arak university of technology, Arak, Iran) at 220 • C for 72 h. The precipitated product was centrifuged (15,000 rpm for 30 min) and washed with ethanol and deionized water. Table 1 shows the volumes of the reagents used in the green synthesis of graphene quantum dots. All of reagents prepared from products of Merck company, Darmstadt, Germany. After that, the quantum dot product (1 g) was dispersed in 200 mL of a deionized water solvent under ultrasonic waves (150 W for 60 min). The ultrasonic machine provided by FAPAN company, Tehran, Iran. After the sonochemical reaction, the graphene product was centrifuged and dried in an oven (70 • C for 24 h). The oven was provided by Sci Finetech Co., Seoul, Korea. Figure 1 shows the schematic procedure of the green synthesis of lemon juice to produce graphene quantum dots. Figure 2 shows the chemical reaction during production of the graphene quantum dots. The citric acid (HOC(CO 2 H) (CH 2 CO 2 H) 2 , 0.1 mol) and ethylenediamine (C 2 H 4 (NH 2 ) 2 , 0.01 mol) under a higher pressure and temperature produced graphene quantum dots. There are a lot of hydroxyl and carboxyl functional groups on the surface of graphene quantum dots. Strong hydrogen bonding will be made between them and the carbonyl and ester functional groups in the polyester. The dispersion will be obtained because of the mechanical stirring, ultrasound vibration and too many branches of carbonyls, esters and hydroxyls. In the next step, different percentages of the graphene quantum dots are added to the polyester and make nanocomposite samples.

Sample Preparation
After the production of graphene quantum dots by green synthesis, the polymer-based nanocomposites should be prepared. For this purpose, first, it is necessary to prepare the matrix (resin). Polyesters are a category of polymers that contain the ester functional group in their main chain. Polyesters are usually transparent, flammable and brittle materials. The prepared polyester resin from Boytec company (made in Turkey) was a thermoset polymer, which was polymerized by adding a hardener. Two different samples with and without nanoparticles should be prepared for investigation of the mechanical properties. For the preparation of samples without nanoparticles, 70 g of polyester resin was poured into a beaker, and 0.350 g of a cobalt additive (0.5% wt.) was added to it. A mechanical stirrer was utilized to stir the solution for 5 min at an 80-rpm rotational speed. The solution was left in a room environment for 15 min (debubbling). The last step was adding methyl ethyl ketone peroxide (usually called acid or hardener) to the mixture. The 0.423 g of methyl ethyl ketone peroxide (0.6% wt.) was added to the mixture and stirred for 3 min at an 80-rpm rotational speed. The polymerization started, and after 6 min, the mixture viscosity increased such that pouring of the die was impossible. Therefore, before ending the gelation time, the mixture would be transferred to the die. After pouring the nanocomposite mixture into the die, the die was left at room temperature for 40 h and then post-cured at 80 • C for 8 h in an oven according to the resin producer's instructions.
For the preparation of samples with nanoparticles, a similar procedure was repeated. The green synthesized graphene quantum dots were added to the resin (70 ± 0.001 g) with different weight percentages (0.25%, 0.5% and 1% wt.). The mixture of resin and graphene was mechanically stirred for 30 min at a 1500-rpm rotational speed. The mixture was sonicated for 15 min by a 14 mm in diameter probe sonicator (Hielscher UP400S) at an output power of 200 W and a frequency of 24 kHz. The solution was left in the room environment for 40 min (debubbling). The 0.350 g of cobalt additive (0.5% wt.) was added to the mixture of styrene and graphene quantum dots and mechanically stirred for 3 min at an 80-rpm rotational speed. The solution was left again for 15 min. The last step was adding methyl ethyl ketone peroxide (hardener) to the mixture. The 0.423 g of methyl ethyl ketone peroxide (0.6 % wt.) was added to the mixture and stirred for 3 min at an 80-rpm rotational speed. Then, the mixture was transferred to the sample preparation die, cured at room temperature for 40 h and post-cured at 80 • C for 8 h in an oven. Figure 3 shows the graphene nanocomposite mixture after stirring and the prepared samples with and without graphene quantum dots.

Sample Preparation
After the production of graphene quantum dots by green synthesis, the polymerbased nanocomposites should be prepared. For this purpose, first, it is necessary to prepare the matrix (resin). Polyesters are a category of polymers that contain the ester functional group in their main chain. Polyesters are usually transparent, flammable and brittle materials. The prepared polyester resin from Boytec company (made in Turkey) was a thermoset polymer, which was polymerized by adding a hardener. Two different samples with and without nanoparticles should be prepared for investigation of the mechanical properties. For the preparation of samples without nanoparticles, 70 g of polyester resin was poured into a beaker, and 0.350 g of a cobalt additive (0.5% wt.) was added to it. A mechanical stirrer was utilized to stir the solution for 5 min at an 80-rpm rotational speed. The solution was left in a room environment for 15 min (debubbling). The last step was adding methyl ethyl ketone peroxide (usually called acid or hardener) to the mixture. The 0.423 g of methyl ethyl ketone peroxide (0.6% wt.) was added to the mixture and stirred for 3 min at an 80-rpm rotational speed. The polymerization started, and after 6 min, the mixture viscosity increased such that pouring of the die was impossible. Therefore, before ending the gelation time, the mixture would be transferred to the die. After pouring the nanocomposite mixture into the die, the die was left at room temperature for 40 h and then post-cured at 80 °C for 8 h in an oven according to the resin producer's instructions.
For the preparation of samples with nanoparticles, a similar procedure was repeated. The green synthesized graphene quantum dots were added to the resin (70 ± 0.001 g) with different weight percentages (0.25%, 0.5% and 1% wt.). The mixture of resin and graphene was mechanically stirred for 30 min at a 1500-rpm rotational speed. The mixture was sonicated for 15 min by a 14 mm in diameter probe sonicator (Hielscher UP400S) at an output power of 200 W and a frequency of 24 kHz. The solution was left in the room environment for 40 min (debubbling). The 0.350 g of cobalt additive (0.5% wt.) was added to the mixture of styrene and graphene quantum dots and mechanically stirred for 3 min at an 80-rpm rotational speed. The solution was left again for 15 min. The last step was adding methyl ethyl ketone peroxide (hardener) to the mixture. The 0.423 g of methyl ethyl ketone peroxide (0.6 % wt.) was added to the mixture and stirred for 3 min at an 80-rpm rotational speed. Then, the mixture was transferred to the sample preparation die, cured at room temperature for 40 h and post-cured at 80 °C for 8 h in an oven. Figure 3 shows the graphene nanocomposite mixture after stirring and the prepared samples with and without graphene quantum dots.

Flexural Test
After preparation of the composite mixture, it was transferred to a die. The die consisted of cavities 100 mm in length and 20 mm wide. The mixture was poured to prepare an 8-mm thick composite sample. After post-curing, the surfaces of the hardened samples were polished with soft sandpaper. The sample was placed in a three-point bending fixture with a span length of 80 mm. The bending test was carried out at a 3 mm/min speed, and the force-displacement data was logged. Three samples were prepared and tested for each weight percentage of green synthesized nanocomposites. Figure 4 shows the implementation of the three-point bending test with a universal tensile testing machine.
where σ f is the flexural bending stress at the outer surface of the beam at the midpoint, P is the load at a given point on the load-deflection curve, L, b and d are the fixture span, width and depth of the tested beam, respectively, and D is the deflection of the centerline of the specimen at the middle of the fixture span.

Flexural Test
After preparation of the composite mixture, it was transferred to a die. The die consisted of cavities 100 mm in length and 20 mm wide. The mixture was poured to prepare an 8-mm thick composite sample. After post-curing, the surfaces of the hardened samples were polished with soft sandpaper. The sample was placed in a three-point bending fixture with a span length of 80 mm. The bending test was carried out at a 3 mm/min speed, and the force-displacement data was logged. Three samples were prepared and tested for each weight percentage of green synthesized nanocomposites. Figure 4 shows the implementation of the three-point bending test with a universal tensile testing machine.
where σf is the flexural bending stress at the outer surface of the beam at the midpoint, P is the load at a given point on the load-deflection curve, L, b and d are the fixture span, width and depth of the tested beam, respectively, and D is the deflection of the centerline of the specimen at the middle of the fixture span. The flexural strain and tangent modulus of elasticity (which is usually called the modulus of elasticity) are two main three-point bending test parameters used to assess the beam's behavior in bending. The flexural strain (εf) and modulus of elasticity (EB) can be calculated by Equations (2) and (3) [28]: where m is the slope of the tangent to the initial straight line portion of the load-deflection curve. The flexural strain and tangent modulus of elasticity (which is usually called the modulus of elasticity) are two main three-point bending test parameters used to assess the beam's behavior in bending. The flexural strain (ε f ) and modulus of elasticity (E B ) can be calculated by Equations (2) and (3) [28]: where m is the slope of the tangent to the initial straight line portion of the load-deflection curve.

Green Synthesis of Graphene Quantum Dots
The morphology and size of carbon graphene quantum dots were investigated using a scanning electron microscopy (SEM) machine. The SEM image of the green synthesized graphene quantum dots is shown in Figure 5. The results confirm that the monodispersed nanoparticles were synthesized with an average particle size of 20 nm (spherical dots). The SEM images of the fractured surface of the graphene nanocomposites are shown in Figure 6. As can be seen in Figure 6, the presence of nanoparticles on the surface of the polymer matrix increased by increasing the concentration of graphene quantum dots in the polyester matrix. The graphene quantum dots were prepared in green synthesis. The morphology of the graphene was spherical dots (20 nm average size). Figure 7 shows the XRD pattern of the carbon graphene quantum dots. The pattern matched the standard peaks of JCPDS card No. 00-08-0415 and confirmed the graphene production.
The Fourier-transform infrared (FTIR) spectrum of the as-prepared carbon graphene dots is shown in Figure 8 pl. Sci. 2021, 11, x FOR PEER REVIEW

Green Synthesis of Graphene Quantum Dots
The morphology and size of carbon graphene quantum dots were a scanning electron microscopy (SEM) machine. The SEM image of the graphene quantum dots is shown in Figure 5. The results confirm that nanoparticles were synthesized with an average particle size of 20 n The SEM images of the fractured surface of the graphene nanocompo Figure 6. As can be seen in Figure 6, the presence of nanoparticles on polymer matrix increased by increasing the concentration of graphen the polyester matrix. The graphene quantum dots were prepared in g morphology of the graphene was spherical dots (20 nm average size).    The Fourier-transform infrared (FTIR) spectrum of the as-prepared carbon gra dots is shown in Figure 8, with a broad and strong absorption band of about 342 attributed to vibration stretching in the hydroxyl group. Absorptions at 2812, 28 2918 cm -1 were due to the C-H stretching vibrations. The bands at 1633 cm -1 were r to the stretching vibration in C=O. The bands at 1383 and 1576 cm -1 were attributed C=C bonds. The absorption band at 1042 cm -1 was for stretching vibrations in C-O the bands obtained at 798 and 760 cm -1 were attributed to yjr stretching vibration [29][30][31]. The influence of graphene quantum dot additives on the fire retardancy of th mer resin was examined applying the UL-94 test (a sample of 130 × 13 × 1.6 mm was A flame (1.5 cm) was applied to the specimen (time: 10 s) twice. When the sample guished in less than 10 s after fire ignition, it was in a V-0 class (drips are allowed a as they are not inflamed). A V-1 type is for a sample with a fire time of less than 30 s  The Fourier-transform infrared (FTIR) spectrum of the as-prepared carbon gra dots is shown in Figure 8, with a broad and strong absorption band of about 342 attributed to vibration stretching in the hydroxyl group. Absorptions at 2812, 28 2918 cm -1 were due to the C-H stretching vibrations. The bands at 1633 cm -1 were r to the stretching vibration in C=O. The bands at 1383 and 1576 cm -1 were attributed C=C bonds. The absorption band at 1042 cm -1 was for stretching vibrations in C-O the bands obtained at 798 and 760 cm -1 were attributed to yjr stretching vibration [29][30][31]. The influence of graphene quantum dot additives on the fire retardancy of th mer resin was examined applying the UL-94 test (a sample of 130 × 13 × 1.6 mm was A flame (1.5 cm) was applied to the specimen (time: 10 s) twice. When the sample guished in less than 10 s after fire ignition, it was in a V-0 class (drips are allowed a as they are not inflamed). A V-1 type is for a sample with a fire time of less than 30 s are like those in the V-0 class). The V-2 class has a fire time like the V-1 class while fl drips are permitted. When the total flaming time is above 50 s, it is not classified Finally, horizontal burning with a rate of less than 76 mm/min is HB [29][30][31].
The UL-94 test for the pure polymer was NC, while the nanocomposites wer firmed for V-1 classification (Figure 9). Fire retardancy of the nanocomposites was The influence of graphene quantum dot additives on the fire retardancy of the polymer resin was examined applying the UL-94 test (a sample of 130 × 13 × 1.6 mm was used). A flame (1.5 cm) was applied to the specimen (time: 10 s) twice. When the sample extinguished in less than 10 s after fire ignition, it was in a V-0 class (drips are allowed as long as they are not inflamed). A V-1 type is for a sample with a fire time of less than 30 s (drips are like those in the V-0 class). The V-2 class has a fire time like the V-1 class while flaming drips are permitted. When the total flaming time is above 50 s, it is not classified (NC). Finally, horizontal burning with a rate of less than 76 mm/min is HB [29][30][31].
The UL-94 test for the pure polymer was NC, while the nanocomposites were confirmed for V-1 classification (Figure 9). Fire retardancy of the nanocomposites was due to the high surface-to-volume ratio, which dispersed into the matrix homogeneously, and the formation of a char barrier during combustion. This barrier decreased the evaporation of organic components and reduced the oxygen and flame reaching the sample. the high surface-to-volume ratio, which dispersed into the matrix homogeneously, and the formation of a char barrier during combustion. This barrier decreased the evaporation of organic components and reduced the oxygen and flame reaching the sample. Limiting oxygen index (LOI) analysis of the 0.25, 0.5 and 1% wt. graphene quantum dots was implemented and is shown in Table 2. The results showed that by increasing the nanoparticle concentration, the LOI value increased from 17 to 22 (29.4% enhancement), and fire retardancy was also improved. In addition, other investigations on adding nanoparticles (carbon nanostructure, multi-walled carbon nanotubes (MWCNT) to polyester showed that the flame retardancy of the nanocomposites improved, and thermal decomposition of the nanocomposites was shifted toward higher temperatures [32][33][34].

Sample
Limiting Oxygen Index (LOI) Pure polyester resin 17 Polyester resin, 0.25% wt. of graphene 18 Polyester resin, 0.5% wt. of graphene 20 Polyester resin, 1% wt. of graphene 22 Figure 10 shows the load-displacement curve for the different prepared samples. The slope of the tangent to the initial straight line is the m coefficient in Equation (3). Figure  11a,b shows the modulus of elasticity (flexural modulus), flexural strength and flexural strain (strain at failure point) for different weight percentages of the graphene quantum dots. The results showed that adding 0.25% wt. of the graphene quantum dots increased the strength from 80 MPa to about 112 MPa (40% increase in strength). Adding a greater percentage of graphene quantum dots would not increase the flexural strength meaningfully. The flexural modulus decreased from 2.70 GPa to 2.39, 2.38 and 2.06 GPa by adding 0.25, 0.5 and 1% wt. graphene content, respectively. The flexural modulus decreased up to 23% for the 1% wt. graphene. Figure 11c shows the flexural strain (strain at failure point) for the different tested samples. The flexural strain increased considerably. The neat polyester deformed to 3.11% strain, which shows a brittle fracture in the materials. By adding Limiting oxygen index (LOI) analysis of the 0.25, 0.5 and 1% wt. graphene quantum dots was implemented and is shown in Table 2. The results showed that by increasing the nanoparticle concentration, the LOI value increased from 17 to 22 (29.4% enhancement), and fire retardancy was also improved. In addition, other investigations on adding nanoparticles (carbon nanostructure, multi-walled carbon nanotubes (MWCNT) to polyester showed that the flame retardancy of the nanocomposites improved, and thermal decomposition of the nanocomposites was shifted toward higher temperatures [32][33][34].  Figure 10 shows the load-displacement curve for the different prepared samples. The slope of the tangent to the initial straight line is the m coefficient in Equation (3).  Figure 11c shows the flexural strain (strain at failure point) for the different tested samples. The flexural strain increased considerably. The neat polyester deformed to 3.11% strain, which shows a brittle fracture in the materials. By adding the 0.25, 0.5 and 1% wt. graphene, the strain increased to 7.81, 8.35 and 14.20%, respectively. The stress-strain behavior of the three-point bending test shows that adding green synthesized graphene quantum dots increased the strength and ductility of the nanocomposites, and the fracture behavior changed from brittle to ductile. By increasing the flexural strength and flexural strain and decreasing the modulus of elasticity, the composite samples could absorb significantly higher energy before failure (ductility). Cracks propagated with a lower growth rate. This was mainly because the nanoparticles decreased the crack growth rate. Crack deflection, particle debonding and plastic void growth are three main mechanisms of failure in nanocomposites [35]. The crack growth direction changes when it receives the nanoparticles, and the micro-void coalescence is retarded. The error bar of the flexural modulus, flexural strength and flexural strain was considerably low. Several pieces of research have been published about the improvement of the mechanical properties of composites by adding nanoparticles. As a special case, Shokrieh et al. [36,37] improved the flexural strength of polyester nanocomposites by about 18% using multi-wall carbon nanotubes (CNT). Additionally, various carbon-based nano-additives were applied in the polymer nanocomposites, but to the best knowledge of the present authors, this article is the first attempt at using green synthesized graphene quantum dots to enhance the mechanical properties of nanocomposites. As the results show, considerable enhancement in the flexural behavior and strain at failure was obtained.

Flexural Properties
posites, and the fracture behavior changed from brittle to ductile. By increasing the fl ural strength and flexural strain and decreasing the modulus of elasticity, the compo samples could absorb significantly higher energy before failure (ductility). Cracks pro gated with a lower growth rate. This was mainly because the nanoparticles decreased crack growth rate. Crack deflection, particle debonding and plastic void growth are th main mechanisms of failure in nanocomposites [35]. The crack growth direction chan when it receives the nanoparticles, and the micro-void coalescence is retarded. The er bar of the flexural modulus, flexural strength and flexural strain was considerably lo Several pieces of research have been published about the improvement of the mechan properties of composites by adding nanoparticles. As a special case, Shokrieh et al. [36, improved the flexural strength of polyester nanocomposites by about 18% using mu wall carbon nanotubes (CNT). Additionally, various carbon-based nano-additives w applied in the polymer nanocomposites, but to the best knowledge of the present autho this article is the first attempt at using green synthesized graphene quantum dots to hance the mechanical properties of nanocomposites. As the results show, considera enhancement in the flexural behavior and strain at failure was obtained.  The uniformity of dispersion of graphene quantum dots is important in composite fabrication. The agglomeration of graphene quantum dots decreases the strength of the composite by the formation of secondary bonding interactions between the graphene quantum dots rather than the primary bonding with the matrix [27]. Production of graphene quantum dots by green synthesis is a very cheap method compared with other synthesis processes. This article focuses on the feasibility of using green synthesis for the production of composite parts and studying the effect of adding graphene quantum dots on the mechanical properties of the fabricated parts. New research should be conducted to investigate different aspects of the green synthesis process parameters, including the initial material of graphene extraction (such as turmerics or potatoes), interface formation between the nanoparticles and the matrix and different sonication times, dispersions and aggregations of graphene powder, which is the ongoing project of the authors. Appl. Sci. 2021, 11, x FOR PEER REVIEW

Conclusions
Graphene nanocomposites are used widely in different industries. The production of graphene for large-scale applications is still a major challenge. In this article, graphene quantum dots were produced by green synthesis. The graphene quantum dots were extracted from lemon juice at a cheap cost. XRD and FTIR testing proved the production of graphene quantum dots. The results of the three-point bending test for 0.25, 0.5 and 1% wt. graphene showed that adding the graphene quantum dots increased the strength from 80 MPa to about 112 MPa (40% increase in strength). The flexural modulus decreased from 2.70 GPa to 2.06 GPa by adding the 1% wt. graphene content (23% decrease). The flexural strain increased considerably, and the fracture mode changed from a brittle fracture to a ductile fracture by adding the graphene quantum dots. The prepared nanocomposites showed fire retardancy. The produced graphene quantum dots showed acceptable improvement in the mechanical properties, while the graphene powder was obtained very easily and in an environmentally friendly manner. Funding: Ricardo J. Alves de Sousa acknowledges grants UID/EMS/0048 CENTRO-01-0145-FEDER-022083-Centro2020 from the European Regional Development Fund (ERDF).