Operation of a Pilot-Scale CO 2 Capture Process with a New Energy-E ﬃ cient Polyamine Solvent

: A new blending recipe of a polyamine-based solvent for capturing post-combustion CO 2 was proposed, and its performance and characteristics were investigated using a pilot-scale carbon capture process (PCCP). The proposed solvent is a blend of three types of amines and was designed to separate the solvent roles into those of a main amine, auxiliary amine, and reaction-rate-enhancing amine. Polyamine 3,3 (cid:48) -iminobis (N, N-dimethylpropylamine) was selected as the main amine given its ability to capture large amounts of CO 2 . 2-Amino-2-methyl-1-propanol was used as the auxiliary amine, with piperazine added as the reaction-rate-enhancing amine. This solvent was tested in a PCCP that can handle 150 Nm 3 / h of ﬂue gas. The proposed solvent was found to operate stably while consuming substantially lower reboiler duty than the monoethanolamine (MEA) 30 mass% solvent.


Introduction
Humankind faces an unprecedented challenge with regard to achieving climate objectives. Without carbon capture and storage (CCS), this challenge becomes infinitely greater [1]. CCS is a technology capable of capturing CO 2 from large-scale CO 2 emission sources and storing it in the ground. Post-combustion capture processes can be classified into three types: absorption, adsorption, and membrane technologies. The most commercially available technique is absorption, which typically uses various amine solvents [2][3][4]. The types of amines used in the solvents are divided into primary, secondary, and tertiary amines [5]. In general, CO 2 absorption is achieved with primary and secondary amines through a carbamate reaction and with tertiary amines through a bicarbonate reaction [6]. Primary and secondary amines can also form bicarbonate but only a small amount after the carbamate reaction is completed. In the past, a single amine such as monoethanolamine (MEA) and water were mixed and used commercially as a CO 2 capture solvent, but researchers have investigated the blending of various amines to improve the performance of the solvent. A typical example is the BASF's aMDEA ® , a blend of methyl diethanolamine (MDEA) and piperazine (PZ), and research on the optimal mixing ratio of two amines is also being conducted through various methods [7].
In this study, we attempted to develop a solvent with low reboiler heat duty by blending several types of amines. For high CO 2 loading, we decided through a literature review and by reviewing existing Table 1 shows four individual amines associated with this research. IBD is a polyamine containing one secondary and two tertiary amines, known to have a large working capacity and relatively small heat of reaction [11]. MEA is the most representative primary amine with the akanolamine structure. A relatively fast CO 2 absorption rate and low price are advantages. AMP is a sterically hindered amine that has high absorption capacity [12,13]. BAE has a molecular structure of an alkanolamine including a secondary amine; the working capacity is relatively high, and the heat of reaction is low compared to MEA [11]. PZ is a representative amine species that can increase the CO 2 absorption speed when mixed with other amine solvents [14]. 3,3 -Iminobis (N,N-dimethyl propylamine) (IBDMPA or IBD) Appl. Sci. 2020, 10, x FOR PEER REVIEW 2 of 13 research on the optimal mixing ratio of two amines is also being conducted through various methods [7]. In this study, we attempted to develop a solvent with low reboiler heat duty by blending several types of amines. For high CO2 loading, we decided through a literature review and by reviewing existing experiments to use polyamine 3,3′-iminobis (N, N-dimethylpropylamine) (IBDMPA), a polyamine, as the main amine. Hereafter, we use IBD to denote IBDMPA for simplicity of presentation. As a triamine, one mole of IBD can react with up to two moles of CO2 which is four times that of one mole of MEA reacting with 0.5 mole of CO2 [8,9]. Like aMDEA ® , PZ was selected as the reaction rate enhancer. Research on increasing the reaction rate by blending PZ with IBD was conducted by Aronu et al. [10] and Kim et al. [11]. The use of a high concentration of IBD leads to high viscosity of the solvent. Therefore, supplementing IBD and PZ with a non-high viscosity auxiliary amine was considered. MEA, 2-(butylamino)ethanol (BAE), and 2-amino-2-methyl-1propanol (AMP) were chosen as auxiliary amine candidates.
Comparing CO2 solubility, absorption rate, and viscosity measurements in the laboratory, we finally chose a blend, IBD-AMP-PZ of 40:6:6 mass%, as a new recipe, and test operations were conducted in a pilot-scale carbon capture process (PCCP) that can normally handle 150 Nm 3 /h of flue gas. These tests sought to investigate the stability of operation, the reboiler heat duty, the CO2 loading, and the temperature profile in the absorber column at a constant flue gas flow rate. To compare the performance of the proposed solvent, a baseline evaluation was conducted first using MEA 30 mass% solvent. Table 1 shows four individual amines associated with this research. IBD is a polyamine containing one secondary and two tertiary amines, known to have a large working capacity and relatively small heat of reaction [11]. MEA is the most representative primary amine with the akanolamine structure. A relatively fast CO2 absorption rate and low price are advantages. AMP is a sterically hindered amine that has high absorption capacity [12,13]. BAE has a molecular structure of an alkanolamine including a secondary amine; the working capacity is relatively high, and the heat of reaction is low compared to MEA [11]. PZ is a representative amine species that can increase the CO2 absorption speed when mixed with other amine solvents [14]. research on the optimal mixing ratio of two amines is also being conducted through various methods [7]. In this study, we attempted to develop a solvent with low reboiler heat duty by blending several types of amines. For high CO2 loading, we decided through a literature review and by reviewing existing experiments to use polyamine 3,3′-iminobis (N, N-dimethylpropylamine) (IBDMPA), a polyamine, as the main amine. Hereafter, we use IBD to denote IBDMPA for simplicity of presentation. As a triamine, one mole of IBD can react with up to two moles of CO2 which is four times that of one mole of MEA reacting with 0.5 mole of CO2 [8,9]. Like aMDEA ® , PZ was selected as the reaction rate enhancer. Research on increasing the reaction rate by blending PZ with IBD was conducted by Aronu et al. [10] and Kim et al. [11]. The use of a high concentration of IBD leads to high viscosity of the solvent. Therefore, supplementing IBD and PZ with a non-high viscosity auxiliary amine was considered. MEA, 2-(butylamino)ethanol (BAE), and 2-amino-2-methyl-1propanol (AMP) were chosen as auxiliary amine candidates.

Materials
Comparing CO2 solubility, absorption rate, and viscosity measurements in the laboratory, we finally chose a blend, IBD-AMP-PZ of 40:6:6 mass%, as a new recipe, and test operations were conducted in a pilot-scale carbon capture process (PCCP) that can normally handle 150 Nm 3 /h of flue gas. These tests sought to investigate the stability of operation, the reboiler heat duty, the CO2 loading, and the temperature profile in the absorber column at a constant flue gas flow rate. To compare the performance of the proposed solvent, a baseline evaluation was conducted first using MEA 30 mass% solvent. Table 1 shows four individual amines associated with this research. IBD is a polyamine containing one secondary and two tertiary amines, known to have a large working capacity and relatively small heat of reaction [11]. MEA is the most representative primary amine with the akanolamine structure. A relatively fast CO2 absorption rate and low price are advantages. AMP is a sterically hindered amine that has high absorption capacity [12,13]. BAE has a molecular structure of an alkanolamine including a secondary amine; the working capacity is relatively high, and the heat of reaction is low compared to MEA [11]. PZ is a representative amine species that can increase the CO2 absorption speed when mixed with other amine solvents [14].  [7]. In this study, we attempted to develop a solvent with low reboiler heat duty by blending several types of amines. For high CO2 loading, we decided through a literature review and by reviewing existing experiments to use polyamine 3,3′-iminobis (N, N-dimethylpropylamine) (IBDMPA), a polyamine, as the main amine. Hereafter, we use IBD to denote IBDMPA for simplicity of presentation. As a triamine, one mole of IBD can react with up to two moles of CO2 which is four times that of one mole of MEA reacting with 0.5 mole of CO2 [8,9]. Like aMDEA ® , PZ was selected as the reaction rate enhancer. Research on increasing the reaction rate by blending PZ with IBD was conducted by Aronu et al. [10] and Kim et al. [11]. The use of a high concentration of IBD leads to high viscosity of the solvent. Therefore, supplementing IBD and PZ with a non-high viscosity auxiliary amine was considered. MEA, 2-(butylamino)ethanol (BAE), and 2-amino-2-methyl-1propanol (AMP) were chosen as auxiliary amine candidates.

Materials
Comparing CO2 solubility, absorption rate, and viscosity measurements in the laboratory, we finally chose a blend, IBD-AMP-PZ of 40:6:6 mass%, as a new recipe, and test operations were conducted in a pilot-scale carbon capture process (PCCP) that can normally handle 150 Nm 3 /h of flue gas. These tests sought to investigate the stability of operation, the reboiler heat duty, the CO2 loading, and the temperature profile in the absorber column at a constant flue gas flow rate. To compare the performance of the proposed solvent, a baseline evaluation was conducted first using MEA 30 mass% solvent. Table 1 shows four individual amines associated with this research. IBD is a polyamine containing one secondary and two tertiary amines, known to have a large working capacity and relatively small heat of reaction [11]. MEA is the most representative primary amine with the akanolamine structure. A relatively fast CO2 absorption rate and low price are advantages. AMP is a sterically hindered amine that has high absorption capacity [12,13]. BAE has a molecular structure of an alkanolamine including a secondary amine; the working capacity is relatively high, and the heat of reaction is low compared to MEA [11]. PZ is a representative amine species that can increase the CO2 absorption speed when mixed with other amine solvents [14]. The main amine employed in the present work was IBD, supplied by Huntsman Co., with a purity rating of >98%. MEA, AMP, and PZ were purchased from Sigma Aldrich, all with purity levels of >99%. Carbon dioxide and oxygen were supplied by Daechung Co., Korea with purity levels of 99.9%.

Solvent Formulation
Amine types and concentrations of the new blends are shown in Table 2. The first consists of IBD, MEA, and PZ with a ratio of 30:20:6 mass% and was named IMP using the initials of the three constituent amines. In addition, purified water was used as the formulation solvent. The second and third ones include AMP and BAE instead of MEA and were named IAP and IBP, respectively. The amine concentrations of IAP and IBP are different from those of IMP. In formulating IAP and IBP, we attempted to increase the total amine concentration by increasing IBD first and then increasing The main amine employed in the present work was IBD, supplied by Huntsman Co., with a purity rating of >98%. MEA, AMP, and PZ were purchased from Sigma Aldrich, all with purity levels of >99%. Carbon dioxide and oxygen were supplied by Daechung Co., Korea with purity levels of 99.9%.

Solvent Formulation
Amine types and concentrations of the new blends are shown in Table 2. The first consists of IBD, MEA, and PZ with a ratio of 30:20:6 mass% and was named IMP using the initials of the three constituent amines. In addition, purified water was used as the formulation solvent. The second and third ones include AMP and BAE instead of MEA and were named IAP and IBP, respectively. The amine concentrations of IAP and IBP are different from those of IMP. In formulating IAP and IBP, we attempted to increase the total amine concentration by increasing IBD first and then increasing the auxiliary amine using the guideline that the maximum viscosity should not exceed 30 cP at 40 °C. The main amine employed in the present work was IBD, supplied by Huntsman Co., with a purity rating of >98%. MEA, AMP, and PZ were purchased from Sigma Aldrich, all with purity levels of >99%. Carbon dioxide and oxygen were supplied by Daechung Co., Korea with purity levels of 99.9%.

Solvent Formulation
Amine types and concentrations of the new blends are shown in Table 2. The first consists of IBD, MEA, and PZ with a ratio of 30:20:6 mass% and was named IMP using the initials of the three constituent amines. In addition, purified water was used as the formulation solvent. The second Appl. Sci. 2020, 10, 7669 3 of 11 and third ones include AMP and BAE instead of MEA and were named IAP and IBP, respectively. The amine concentrations of IAP and IBP are different from those of IMP. In formulating IAP and IBP, we attempted to increase the total amine concentration by increasing IBD first and then increasing the auxiliary amine using the guideline that the maximum viscosity should not exceed 30 cP at 40 • C. For the solvent viscosity screen, the existing literature has proposed less than 20 cP at 40 • C [15]. However, in this study, the viscosity criteria for solvent selection were determined to be less than 30 cP at rich load at 40 • C. In fact, it was confirmed that operation is possible when it is less than 30 cP in the PCCP.

Experimental Methods
The blended solvents were investigated in the lab first. The probed properties were CO 2 solubility, CO 2 absorption rate, and solvent viscosity, and one between IAP and IBP was selected together with IMP on the basis of the probed properties for the next stage pilot process test.
The CO 2 solubility was measured using a continuous flow bubbling reactor (CFBR). Different experimental methods were used with the CFBR depending on the equilibrium CO 2 partial pressure above and below 1 kPa. More details on the CFBR method can be found in Kim et al. [11].
A modified wetted wall column (m-WWC) was used to measure both the CO 2 absorption rate and the solvent viscosity by continuously increasing the CO 2 loading of the solvent. More details on the m-WWC device are described in Kim et al. [16].

Solvent Selection
The CO 2 solubility data for the three amine blends are presented in Figure 1. The CO 2 solubility curves for IAP and IBP almost overlapped. The cyclic CO 2 loading capacity at 40 • C based on the equilibrium CO 2 partial pressures of 0.05 and 5 kPa is 65 g-CO 2 /kg-solvent for IMP and about 54 g-CO 2 /kg-solvent for IAP and IBP.
Appl. Sci. 2020, 10, x FOR PEER REVIEW 4 of 13 equilibrium CO2 partial pressures of 0.05 and 5 kPa is 65 g-CO2/kg-solvent for IMP and about 54 g-CO2/kg-solvent for IAP and IBP.      Figure 2b shows viscosity of the three solvent candidates at 40 °C. All three solvent candidates show similar values and patterns of the overall mass transfer coefficient with CO2 loading. However, IBP was found to have the slowest CO2 absorption among the three. The viscosity increased with increasing CO 2 loading. IMP showed a viscosity increase up to 34 cP at rich loading (corresponding to 5 kPa), while IAP and IBP exhibited lower viscosity values than IMP over the working CO 2 loading range. In the rich loading, IAP slowed the trend of increasing viscosity, showing 24 cP, while IBP accelerated the increasing trend and reached 30 cP. Table 3 lists the average CO 2 absorption rates and rich loading viscosities at 40 • C of the three amine blends. Based on the selection criteria, the authors decided to operate with IAP, the solvent with the lowest viscosity and relatively fast reaction rate performance, in a pilot process.

Description of the Pilot Process
The pilot CO 2 capture process (PCCP) was built at the site of the 2MW coal-fired power plant of the Korea Institute of Energy Research and could be tested with actual real flue gas or with a simulated gas. The PCCP was designed to normally treat 150 Nm 3 /h of flue gas with a CO 2 capture rate exceeding 90% using the MEA 30 mass% solvent, though it can also be operated with various other solvents. In consideration of corrosion, all major equipment and piping were manufactured with stainless steel (SUS316). The stripper column and reboiler were designed to be able to operate at up to 7 barg, as some solvents can be regenerated under pressure. A schematic of the PCCP is shown in Figure 3, which also presents a photograph of the PCCP.

Description of the Pilot Process
The pilot CO2 capture process (PCCP) was built at the site of the 2MW coal-fired power plant of the Korea Institute of Energy Research and could be tested with actual real flue gas or with a simulated gas. The PCCP was designed to normally treat 150 Nm 3 /h of flue gas with a CO2 capture rate exceeding 90% using the MEA 30 mass% solvent, though it can also be operated with various other solvents. In consideration of corrosion, all major equipment and piping were manufactured with stainless steel (SUS316). The stripper column and reboiler were designed to be able to operate at up to 7 barg, as some solvents can be regenerated under pressure. A schematic of the PCCP is shown in Figure 3, which also presents a photograph of the PCCP.  Key units in the PCCP are described in the following: Pre-scrubber: This unit removes SO 2 together with dust in the flue gas. It was designed as a packed column with CMR(CASCADE MINI-RINGS) ® random packing materials. An aqueous solution of NaOH is used to reduce the concentration of SO 2 to less than 2 ppm. The gas treated in the pre-scrubber passes through a dust removal drum for further removal of dust. The bed dimensions and packing materials of the packed columns are described in detail in Table 4. Absorber columns: Two absorber columns were installed for a flexible configuration. The inner diameter of each column is 25 cm and the total height is 835 cm with two 250 cm packing beds. An intercooler was installed in the middle of each column. The two columns were each filled with different packing materials of TPT 350X structure packing, similar to Mellapak 350X and CMR random packing. The absorber columns can be operated in series by changing the order, or each absorber column can be operated independently.
Stripper column: The inner diameter of the stripper column is 20 cm, and the height is 790 cm, of which 410 cm is accounted for by the packing bed. The bed was filled with CMR random packing materials. The top of the stripper column was equipped with gauze-type structure packing to reduce the entrainment during feed flash. The exhausting vapor from the column is cooled to recover the solvent and water vapor by a shell and tube condenser. The reboiler was designed as a kettle-type.
Cross-heat exchanger: A plate heat exchanger was installed to efficiently recover the thermal energy in the hot lean loading solvent to the cold rich loading solvent.
Analysis: Table 5 shows on-line gas sensors installed in the PCCP. In addition to these sensors, gas and liquid samples were taken periodically and analyzed in the lab to measure CO 2 loading, solvent decomposition products, heat stable salts, and selected components in the absorber exhaust gas.

Operating Conditions
To compare the performance of the new amine blends, a baseline evaluation was conducted first using MEA 30mass%. For simplicity, MEA 30mass% will be indicated hereafter as MEA when there is no possibility of confusion. Table 6 presents the operating conditions covered during the test of the MEA and the new amine blend, IAP. In this operation, a simulation gas with the same CO 2 concentration in flue gas of a coal-fired power plant was used. Actual coal-fired flue gas is not used here in order to keep the concentration of CO 2 constant for reboiler heat duty measurement. The solvent circulation rate was varied over a range to find an optimum condition that required minimum reboiler heat duty. At each solvent circulation rate, the reboiler temperature was adjusted to achieve 88-92% of CO 2 capture.  Figure 4 shows the trajectory of feed gas flow rate and CO 2 capture rate for 1000 h of continuous operation. During the entire operating period, the feed gas flow rate was stably maintained at 150 Nm 3 /h. The CO 2 capture rate was relatively well controlled around 90% except around 200 h, when a sensor malfunction occurred. Overall, the average CO 2 capture rate was 89.6%. solvent circulation rate, the reboiler temperature was adjusted to achieve 88-92% of CO2 capture.  Figure 4 shows the trajectory of feed gas flow rate and CO2 capture rate for 1000 h of continuous operation. During the entire operating period, the feed gas flow rate was stably maintained at 150 Nm 3 /h. The CO2 capture rate was relatively well controlled around 90% except around 200 h, when a sensor malfunction occurred. Overall, the average CO2 capture rate was 89.6%.   Figure 5 shows the rich and lean loading outcomes for IAP at various solvent circulating flow rates. For the IAP, CO 2 -rich loading was measured from 84 to as high as 133 g-CO 2 /kg-solvent at a 150 Nm 3 /h flue gas flow rate. The CO 2 working capacity at L/G = 1.7 L/Nm 3 , the lowest energy operating condition, was analyzed to be 126 g-CO 2 /kg-solvent. The working capacity of the IAP is calculated to be 268% greater than that of MEA 30 mass% at optimum operating conditions of each solvent. The IAP was measured to have a significantly lower CO 2 lean loading value of 4 g-CO 2 /kg-solvent under optimum operating conditions. rates. For the IAP, CO2-rich loading was measured from 84 to as high as 133 g-CO2/kg-solvent at a 150 Nm 3 /h flue gas flow rate. The CO2 working capacity at L/G = 1.7 L/Nm 3 , the lowest energy operating condition, was analyzed to be 126 g-CO2/kg-solvent. The working capacity of the IAP is calculated to be 268% greater than that of MEA 30 mass% at optimum operating conditions of each solvent. The IAP was measured to have a significantly lower CO2 lean loading value of 4 g-CO2/kgsolvent under optimum operating conditions.

Reboiler Heat Duty
The reboiler heat duty of IAP was measured at various solvent flow rates, and the minimum reboiler heat duty was 3.3 GJ/t-CO2 at L/G of 1.7 as shown in Figure 6. This is lower than the value for MEA by 0.7 GJ/t-CO2. The optimum L/G of 1.7 for IAP indicates that the same amount of CO2 could be captured with only about 40% of the solvent flow rate compared to the optimum L/G of 4.3 for MEA at a 150 Nm 3 /h flue gas flow rate.

Reboiler Heat Duty
The reboiler heat duty of IAP was measured at various solvent flow rates, and the minimum reboiler heat duty was 3.3 GJ/t-CO 2 at L/G of 1.7 as shown in Figure 6. This is lower than the value for MEA by 0.7 GJ/t-CO 2 . The optimum L/G of 1.7 for IAP indicates that the same amount of CO 2 could be captured with only about 40% of the solvent flow rate compared to the optimum L/G of 4.3 for MEA at a 150 Nm 3 /h flue gas flow rate.
150 Nm 3 /h flue gas flow rate. The CO2 working capacity at L/G = 1.7 L/Nm 3 , the lowest energy operating condition, was analyzed to be 126 g-CO2/kg-solvent. The working capacity of the IAP is calculated to be 268% greater than that of MEA 30 mass% at optimum operating conditions of each solvent. The IAP was measured to have a significantly lower CO2 lean loading value of 4 g-CO2/kgsolvent under optimum operating conditions.

Reboiler Heat Duty
The reboiler heat duty of IAP was measured at various solvent flow rates, and the minimum reboiler heat duty was 3.3 GJ/t-CO2 at L/G of 1.7 as shown in Figure 6. This is lower than the value for MEA by 0.7 GJ/t-CO2. The optimum L/G of 1.7 for IAP indicates that the same amount of CO2 could be captured with only about 40% of the solvent flow rate compared to the optimum L/G of 4.3 for MEA at a 150 Nm 3 /h flue gas flow rate.  The PCCP has significant heat loss compared to commercial processes. In fact, during the operation of a 0.5 MW process employed by our research group, the minimum reboiler heat duty for MEA was measured as 3.6 GJ/t-CO 2 , showing a gap of 0.4 GJ/t-CO 2 compared with the result in the PCCP. Based on this observation, IAP can be assessed to have minimum reboiler heat duty lower than 2.9 GJ/t-CO 2 . Table 7 compares CO 2 loading values of the lean state, mid-rich state (after the first column), and rich state (after the second column) at optimum operating conditions for MEA and IAP. It can be seen that IAP reaches 82.5% of the working capacity in the first column and achieves the remaining Appl. Sci. 2020, 10, 7669 9 of 11 17.5% in the second column. On the other hand, MEA attains 55% and 45% of the working capacity in the first and second columns, respectively. These results show that IAP possesses a faster CO 2 absorption rate than MEA.

Column Temperature Profiles
The temperature profiles in the absorber and the stripper columns were compared under the optimum operating conditions of IAP and MEA in Figure 7. For the case of IAP, a temperature peak appeared soon after the lean solvent entered the absorber column and temperature dropped and remained relatively flat. On the other hand, temperature for MEA along the absorber bed increased slowly and remained high throughout the entire bed compared to the case of IAP. The result is obviously a manifestation of the higher CO 2 absorption rate of IAP than MEA, which is shown in Table 7.
first and second columns, respectively. These results show that IAP possesses a faster CO2 absorption rate than MEA.

Column Temperature Profiles
The temperature profiles in the absorber and the stripper columns were compared under the optimum operating conditions of IAP and MEA in Figure 7. For the case of IAP, a temperature peak appeared soon after the lean solvent entered the absorber column and temperature dropped and remained relatively flat. On the other hand, temperature for MEA along the absorber bed increased slowly and remained high throughout the entire bed compared to the case of IAP. The result is obviously a manifestation of the higher CO2 absorption rate of IAP than MEA, which is shown in Table 7.
Temperature profiles in the stripper column indicate that IAP yielded higher temperature than MEA in the bottom region but lower temperature than MEA in the upper region. In the stripper, the mass transfer rate was quite high due to high temperature.  Temperature profiles in the stripper column indicate that IAP yielded higher temperature than MEA in the bottom region but lower temperature than MEA in the upper region. In the stripper, the mass transfer rate was quite high due to high temperature.

Conclusions
In this study, a new blending recipe of a polyamine-based solvent for the capturing of post-combustion CO 2 was proposed, and its performance and characteristics were investigated using a pilot-scale carbon capture process (PCCP). The proposed solvent was derived from three different IBD-based blends. All three blends contained PZ as a reaction-rate-enhancer and one of MEA, BAE, or AMP as an auxiliary amine to increase the total amine concentration while not increasing the viscosity substantially. Comparing the experimental measurements of CO 2 solubility, CO 2 absorption rate, and viscosity in the lab, IBD-AMP-PZ, abbreviated as IAP herein, was selected as the best solvent candidate and tested in a PCCP that can handle 150 Nm 3 /h of flue gas. To determine the performance and characteristics of the PCCP, a baseline evaluation was conducted with the MEA 30 mass% solvent. The proposed IAP solvent demonstrated highly stable operation and a reboiler duty that was approximately 0.7 GJ/t-CO 2 lower than that of MEA 30 mass% solvent. Excluding the heat loss, the reboiler heat duty of IAP was estimated to be approximately 2.9 GJ/t-CO 2 . The absorber temperature profile under the optimal operating conditions indicated that the proposed solvent utilized the column more efficiently than MEA 30mass%.
Of course, the optimization ratio for IBD, AMP, and PZ must be determined through additional laboratory tests and PCCP operations. Stability analysis of IAP degradation by SO 2 should also be performed with pilot long-term demonstrations. In addition, for the commercialization of IAP, direct comparative evaluation with commercial solvents such as aMDEA ® is required. These comparative assessments should be done in a larger scale process as well as the PCCP used in this study. Nevertheless, the IAP contained in the polyamine showed its potential as a direct CO 2 capture solvent through pilot demonstration.