Energy and Exergy Analyses of an Existing Solar-Assisted Combined Cycle Power Plant

: Solar-assisted combined cycle power plants (CCPPs) feature the advantages of renewable clean energy with e ﬃ cient CCPPs. These power plants integrate a solar ﬁeld with a CCPP. This integration increases the e ﬃ ciency of solar power plants while decreasing the CO 2 emissions of the CCPPs. In this paper, energy and exergy analyses were performed for an existing solar-assisted CCPP. The overall thermal e ﬃ ciency and the exergetic e ﬃ ciency of each component in the power plant were calculated for di ﬀ erent solar ﬁeld capacities. Also, a parametric study of the power plant was performed. The analysis indicated that the exergetic e ﬃ ciency of the power plant components has its lowest value in the solar ﬁeld while the condenser has the lowest exergetic e ﬃ ciency in the combined cycle regime of operation. Further, a parametric study revealed that the thermal e ﬃ ciency and the exergetic e ﬃ ciency of the power plant as a whole decrease with increasing ambient temperature and have their highest values in the combined cycle regime of operation. Owing to these results, an investigation into the sources of exergy destruction in the solar ﬁeld was conducted. of ISCC power di ﬀ erent The originality of this the parametric study of the an existing ISCC plant as a in to identify the sites of major exergy destruction, the for exergy destruction in these to clarify how to decrease the exergy destruction in this type of power plant.


Introduction
The world society actively supports measures aimed at facilitating flexible and low-carbon energy economy. These actions mainly include the promotion of renewable energy sources for power generation with possible electrification of the heating and transport sectors.
Concentrated solar power (CSP) plants use steam to produce energy, similar to the conventional steam power plants. They consist of a solar field and a power block, and they may have an energy storage system (optional).
Many types of collectors have been developed to be used in CSP technology. Parabolic trough collectors (PTCs) have been used in many CSP plants. Parabolic trough power plants are ready for use today because they were tested on a commercial basis [1]. This has been proven in California since 1985 with parabolic trough power plants, with 354 MW of installed capacity [2], which have succeeded in commercial operation and generate electricity using a steam turbine connected to a generator as conventional power plants.
However, the increasing share of renewables is raising awareness of a critical challenge. Renewables normally provide fluctuating feed-in into the electricity grid so that energy reserves, e.g., energy storage systems or conventional thermal power plants such as nuclear power plants and combined cycle power plants (CCPPs), are required to achieve a balance between current electricity supply and this, given the challenges for the electricity market with the continuing expansion of intermittent renewables, in this work, we investigate the operational flexibility of ISCC power plants.
In this paper, we start with a description of the ISCC power plant under investigation, and we provide the method and the equation for the calculation of energy and exergy parameters. Then, we show the influence of ambient temperature and solar heat input on the plant performance. Finally, on the basis of these results, we investigate the sources of exergy destruction in the solar field and the combustion chamber to identify the possibility to enhance the performance of these components.

Plant Description
The ISCC power plant in Kureimat, Egypt is located at a northern latitude of 29 • 16 and eastern longitude of 31 • 15 . It has 135 MW total power capacity, comprising a solar field with an electrical output of 20 MW and a combined cycle field with a power of 115 MW [19]. The integration of a combined cycle with the solar field ensures the delivery of the required electricity contribution to the grid regardless of solar radiation conditions.

Solar Field
The solar field comprises parallel rows of solar collector arrays and typical glass mirrors of 61 MW installed thermal capacity. The solar field comprises 40 loops, each loop having four parabolic trough collectors (type Skal-ET 150 designed by TSK Flagsol Engineering GmbH), and each collector has an aperture area of 817.15 m 2 .
The solar heat transfer from the solar field collectors (PTCs) to the steam cycle uses a heat transfer fluid (HTF) system. The HTF is Therminol VP-1 from Solutia (ultra-high-temperature, liquid/vapor phase fluid) and operates between 12 • C and 400 • C (54-750 • F) [20,21]. The HTF system is designed for an HTF mass flow of 250 kg/s at full load (61 MW of solar field thermal power output). Hot HTF returning from the solar field at 393 • C is pumped through the solar heat exchanger. The HTF leaves the solar heat exchanger at 293 • C and is pumped back into the solar field, as shown in Table 1.

Combined Cycle
The combined cycle field consists of one MS6001FA heavy-duty gas turbine with a generator of a rated electric power output of 70 MW at 20 • C ambient dry bulb temperature. It has one HRSG that receives about 206 kg/s flue gas at about 600 • C from the gas turbine at full load operation. The flue gas leaves the HRSG at about 100 • C. Under the rated conditions of the gas turbine and HRSG, full load operation and solar heat input of 50 MW and 20 • C ambient dry bulb temperature, the steam turbine generator output is about 65 MW.
The HRSG of the ISCC power plant in Kureimat comprises three high-pressure economizers (HP ECO), a high-pressure evaporator (HP EV), a high-pressure steam drum (HP Drum at a pressure about 80 bar), and five high-pressure superheaters (HP SH) for a feed of the high-pressure section of the steam turbine, as shown in Figure 1. Besides this, it includes a low-pressure evaporator (LP EV), low-pressure steam drum (LP Drum at a pressure about 11 bar), and low-pressure superheater (LP SH) for a feed of the steam turbine low-pressure section. The solar-generated steam is injected into the high-pressure drum.

Thermodynamic Analysis
The ISCC was evaluated assuming steady-state operation, with no accounting for thermal capacitance. This assumption works fairly well through the majority of the operating day but creates some problems in the morning when the solar field is warming up.

Energy Balance
The net rate of heat input to the ISCC (̇, ) is given by where ̇ is the rate of heat addition to the ISCC from the fuel combustion and ̇ is the absorbed incident solar radiation. The heat from the fuel combustion (̇) as a function of the fuel flow rate (̇) and the fuel heating value ( ) is given by ̇=̇ * (2) and the heat from the absorbed incident solar radiation (̇) as a function of the direct normal insolation ( ), incidence angle ( ), incidence angle modifier ( ), and solar collectors' aperture area ( ) is given by Here, the incidence angle modifier ( ) is the correlation of the losses from the collectors due to additional reflection and absorption by the glass envelope, and it can be calculated as follows: and the solar collectors' aperture area ( ) is calculated from the number of solar field collectors ( ) and the width ( ) and length ( ) of the collectors as follows:

Thermodynamic Analysis
The ISCC was evaluated assuming steady-state operation, with no accounting for thermal capacitance. This assumption works fairly well through the majority of the operating day but creates some problems in the morning when the solar field is warming up.

Energy Balance
The net rate of heat input to the ISCC ( . Q ISCC,in ) is given by where . Q f uel is the rate of heat addition to the ISCC from the fuel combustion and . Q inc is the absorbed incident solar radiation. The heat from the fuel combustion ( . Q f uel ) as a function of the fuel flow rate ( . m f uel ) and the fuel heating value (H v ) is given by and the heat from the absorbed incident solar radiation ( . Q inc ) as a function of the direct normal insolation (DNI), incidence angle (θ), incidence angle modifier (IAM), and solar collectors' aperture area (A mirrors ) is given by Here, the incidence angle modifier (IAM) is the correlation of the losses from the collectors due to additional reflection and absorption by the glass envelope, and it can be calculated as follows: and the solar collectors' aperture area (A mirrors ) is calculated from the number of solar field collectors (N collectors ) and the width (W collector ) and length (L collector ) of the collectors as follows: The electric power output of the ISCC ( As a result, the overall first law efficiency of the ISCC power plant is

Exergetic Efficiencies
Exergy-based performance analysis is the performance study of a system based on the second law of thermodynamics, which overcomes the limitations of studying the system based on the first law of thermodynamics. Exergy is a measure of the maximum useful work of a system as it proceeds to a specified final state in equilibrium with its surroundings (dead state). Exergy is destroyed in the system, not conserved as energy is.
Two different approaches are generally used to calculate the exergy efficiency of a system, one is called "brute force", while the other is called "functional" [16].
The brute force form of exergy efficiency is used in this paper. The brute force form requires accuracy and an explicit definition of each input and output exergy term before calculating the exergy efficiency as shown in Table 2. The input exergy terms of the ISCC represent the chemical exergy of the fuel and the exergy associated with the solar thermal energy input. Table 2. Definitions of the exergy destruction and second law efficiency.

Component
Exergy Destruction Second Law Efficiency (η II )
W net,out .

X cycle,in
So, the second law efficiency (η II ) (exergetic efficiency) is given by The net exergy transfer by heat ( . X heat ) at the source temperature (T s ) and dead state temperature (T 0 ) is given by . Q s (9) and the specific exergy (Ψ) is given by where h, h 0 , s, and s 0 are the specific enthalpy, the specific enthalpy under the dead state condition, the specific entropy, and the specific entropy under the dead state condition, respectively. Then, the total exergy rate associated with a fluid stream ( . X) at the mass flow rate ( The exergy destruction rate in the ISCC as a whole (

The Exergetic Efficiency of the Solar Field
The solar heat input from the HTF ( . Q HTF ) to the water in the solar field heat exchanger is given by .
The exergy destruction rate in the solar field ( . . where T sun is the sun temperature, which equals 5777 K. The exergetic efficiency of the solar field (η II,SF ) is given by

The Exergetic Efficiency of the ISCC
The fuel chemical exergy per unit time ( where ζ is the ratio of the chemical exergy to the net calorific value, which equals 1.04 for natural gas [23]. The exergetic efficiency of the ISCC (η II,Cycle ) is given as .

Results and Discussion
The performance of the ISCC power plant was analyzed under different design conditions. The analyses were performed for different solar field thermal outputs (0 MW, 50 MW, and 75 MW) and different ambient temperatures (5, 20, and 35 • C). All calculations were made based on design condition data.
The energy efficiency (first law efficiency) and the exergetic efficiency (second law efficiency) were calculated based on the heat input to the plant by the fuel and the sun.

The Overall Thermal Efficiency of the ISCC Power Plant
The overall thermal efficiency of the ISCC power plant in Kureimat at different ambient temperatures for solar heat inputs of 0 MW, 50 MW, and 75 MW is shown in Figure 2. The overall thermal efficiency of the power plant at different ambient temperatures for solar heat input equal to 0 MW, which represents the combined cycle regime, is shown in Figure 2. At no solar heat input (combined cycle regime), the thermal efficiency of the plant was reduced from 51.14% at ambient temperature 5 °C to 48.67% at 35 °C . Figure 2 shows that the overall thermal efficiency of the ISCC decreases with increasing ambient temperature at different solar heat inputs (0, 50, 75 MW), and that appears most distinctly at ambient temperature 35 °C . This may be due to the direct effect of the ambient temperature increase on the efficiency of the condenser and the gas turbine: the condenser and gas turbine efficiency decreases with increasing ambient temperature.
The overall thermal efficiency of the ISCC is lower than the overall thermal efficiency of the plant in the combined cycle regime in all cases (different solar heat inputs and ambient temperatures). Figure 2 shows that the integration of the solar field with the combined cycle (i.e., ISCC) reduced the thermal efficiency of the power plant at all ambient temperatures. This may be because the target of the ISCC is not to increase the overall thermal efficiency of the Brayton cycle, like the combined cycle, but to increase the economic feasibility of the solar power plants. Elimination of the thermal storage system reduces the cost of the power plant [24][25][26]. The overall thermal efficiency of the power plant at different ambient temperatures for solar heat input equal to 0 MW, which represents the combined cycle regime, is shown in Figure 2. At no solar heat input (combined cycle regime), the thermal efficiency of the plant was reduced from 51.14% at ambient temperature 5 • C to 48.67% at 35 • C. Figure 2 shows that the overall thermal efficiency of the ISCC decreases with increasing ambient temperature at different solar heat inputs (0, 50, 75 MW), and that appears most distinctly at ambient temperature 35 • C. This may be due to the direct effect of the ambient temperature increase on the efficiency of the condenser and the gas turbine: the condenser and gas turbine efficiency decreases with increasing ambient temperature.

Exergy Destruction in Each Component of the ISCC as a Percentage of the Total Exergy
The overall thermal efficiency of the ISCC is lower than the overall thermal efficiency of the plant in the combined cycle regime in all cases (different solar heat inputs and ambient temperatures). Figure 2 shows that the integration of the solar field with the combined cycle (i.e., ISCC) reduced the thermal efficiency of the power plant at all ambient temperatures. This may be because the target of the ISCC is not to increase the overall thermal efficiency of the Brayton cycle, like the combined cycle, but to increase the economic feasibility of the solar power plants. Elimination of the thermal storage system reduces the cost of the power plant [24][25][26].

Exergy Destruction in Each Component of the ISCC as a Percentage of the Total Exergy Destruction in the Whole ISCC
The exergy destruction in each component of the ISCC and the exergy destruction in the whole ISCC were calculated for different solar heat inputs and ambient temperatures 5 • C, 20 • C, and 35 • C.
The  However, Figure 3 shows that the exergy destruction in the combustion chamber decreases slightly with the increase of the ambient temperature under the combined cycle regime (0 MW solar heat input).   It can be observed from Figures 4 and 5 that the exergy destruction in the combustion chamber decreases significantly with the increase of the ambient temperature in the case of ISCC. This may account for the weight of exergy destruction in the solar field. Also, the exergy destruction in the solar field increases with increasing ambient temperature, in contrast to the exergy destruction in the combustion chamber. Figures 3-5 show that the combustion chamber and the solar field have the highest exergy destruction among all the subsystems. This is valid for all cases of solar heat input. It was also revealed from the values at different ambient temperatures that the exergy destruction of the solar field decreases with increasing solar thermal input.

The Exergetic Efficiency of the Main Components of the ISCC
The exergetic efficiency of different components of the ISCC at different ambient temperatures for solar heat inputs 0 MW, 75 MW, and 50 MW is shown in Figures 6-8, respectively. Figure 6 depicts the exergetic efficiency of different components of the ISCC at different ambient temperatures in the absence of the solar field (solar heat input equal to 0 MW), i.e., under the combined cycle regime. Under the combined cycle regime, the condenser has the lowest exergetic efficiency except at ambient temperature 5 °C . That may be due to the decrease in the lowtemperature reservoir which increases the heat dissipated to the condenser cooling water. It is revealed in Figure 3 that the combustion chamber (CC) has the highest percentage of exergy destruction, and this value is higher in the combined cycle regime than in the ISCC regime. This may ensure that the solar field has high irreversibility weight, which affects the percentage of exergy destruction in the combustion chamber compared to its value in the combined cycle regime. However, Figure 3 shows that the exergy destruction in the combustion chamber decreases slightly with the increase of the ambient temperature under the combined cycle regime (0 MW solar heat input).
It can be observed from Figures 4 and 5 that the exergy destruction in the combustion chamber decreases significantly with the increase of the ambient temperature in the case of ISCC. This may account for the weight of exergy destruction in the solar field. Also, the exergy destruction in the solar field increases with increasing ambient temperature, in contrast to the exergy destruction in the combustion chamber. Figures 3-5 show that the combustion chamber and the solar field have the highest exergy destruction among all the subsystems. This is valid for all cases of solar heat input. It was also revealed from the values at different ambient temperatures that the exergy destruction of the solar field decreases with increasing solar thermal input.

The Exergetic Efficiency of the Main Components of the ISCC
The exergetic efficiency of different components of the ISCC at different ambient temperatures for solar heat inputs 0 MW, 75 MW, and 50 MW is shown in Figures 6-8, respectively. Figure 6 depicts the exergetic efficiency of different components of the ISCC at different ambient temperatures in the absence of the solar field (solar heat input equal to 0 MW), i.e., under the combined cycle regime. Under the combined cycle regime, the condenser has the lowest exergetic efficiency except at ambient temperature 5 • C. That may be due to the decrease in the low-temperature reservoir which increases the heat dissipated to the condenser cooling water. The exergetic efficiency of the solar field decreased from 31.3% to 14.5% when the ambient temperature increased from 5 °C to 35 °C , as shown in Figure 7. The condenser exergetic efficiency also decreased from 75.5% to 19.3% when the ambient temperature increased from 5 °C to 35 °C for solar heat input equal to 50 MW. This may be due to the decrease in the temperature difference between the exhausted steam from the low-pressure turbine and the cooling water from the cooling tower.  The exergetic efficiency of the solar field decreased from 31.3% to 14.5% when the ambient temperature increased from 5 • C to 35 • C, as shown in Figure 7. The condenser exergetic efficiency also decreased from 75.5% to 19.3% when the ambient temperature increased from 5 • C to 35 • C for solar heat input equal to 50 MW. This may be due to the decrease in the temperature difference between the exhausted steam from the low-pressure turbine and the cooling water from the cooling tower. The exergetic efficiency of the solar field decreased from 31.3% to 14.5% when the ambient temperature increased from 5 °C to 35 °C , as shown in Figure 7. The condenser exergetic efficiency also decreased from 75.5% to 19.3% when the ambient temperature increased from 5 °C to 35 °C for solar heat input equal to 50 MW. This may be due to the decrease in the temperature difference between the exhausted steam from the low-pressure turbine and the cooling water from the cooling tower.   Figure 8 shows that the exergetic efficiency of the solar field decreased from 47% to 21.7% when the ambient temperature increased from 5 • C to 35 • C. The condenser exergetic efficiency also decreased from 65.8% to 19.3% when the ambient temperature increased from 5 • C to 35 • C for solar heat input equal to 75 MW. As shown in Figures 6-8, the exergetic efficiency of the HRSG decreased with increasing ambient temperature, and this may be due to the existence of the attemperators in the HRSG which limit the steam temperature to the setpoint value. In the HRSG installed in the Kureimat power plant, attemperators were installed at the surface of the superheaters to control the temperature at the inlet of the high-pressure steam turbine. These attemperators use water directly from the main feedwater pump of the power plant. An increase in the ambient temperature may lead to an increase in the flue gas temperature of exhaust from the gas turbine into the HRSG, and the attemperators limit the effect of this temperature increase on the temperature of the superheated steam going into the steam turbine using water directly from the main feedwater pump. This may be a reason for the decreasing exergetic efficiency of the HRSG with increasing ambient temperature as shown in Figures 6-8.
Unlike the thermal efficiency [27], the exergetic efficiency of the solar field explicitly decreased with increasing ambient temperature, as shown in Figures 7 and 8. This may be due to the increase of the exergy destruction in the solar field with increasing ambient temperature, as shown in Figures  4 and 5.

The Exergetic Efficiency of the ISCC Power Plant
The exergetic efficiency of the ISCC power plant was calculated for different solar heat power inputs. The comparison was implemented at three different ambient temperatures: 5, 20, and 35 °C .
The ISCC power plant exergetic efficiency for solar heat inputs 0 MW, 50 MW, and 75 MW at different ambient temperatures is depicted in Figure 9. The exergetic efficiency of the ISCC power plant was calculated based on the design condition data for the different solar heat power inputs. Figure 9 reveals that the exergetic efficiency of the ISCC power plant is inversely proportional to the ambient temperature, where it decreased from 47.2% to 46% with increasing ambient temperature from 5 °C to 35 °C for solar heat input equal to 75 MW. In addition, it decreased from 48.2% to 46.58% when the ambient temperature increased from 5 °C to 35 °C for solar heat input equal to 50 MW. As shown in Figures 6-8, the exergetic efficiency of the HRSG decreased with increasing ambient temperature, and this may be due to the existence of the attemperators in the HRSG which limit the steam temperature to the setpoint value. In the HRSG installed in the Kureimat power plant, attemperators were installed at the surface of the superheaters to control the temperature at the inlet of the high-pressure steam turbine. These attemperators use water directly from the main feedwater pump of the power plant. An increase in the ambient temperature may lead to an increase in the flue gas temperature of exhaust from the gas turbine into the HRSG, and the attemperators limit the effect of this temperature increase on the temperature of the superheated steam going into the steam turbine using water directly from the main feedwater pump. This may be a reason for the decreasing exergetic efficiency of the HRSG with increasing ambient temperature as shown in Figures 6-8.
Unlike the thermal efficiency [27], the exergetic efficiency of the solar field explicitly decreased with increasing ambient temperature, as shown in Figures 7 and 8. This may be due to the increase of the exergy destruction in the solar field with increasing ambient temperature, as shown in Figures 4 and 5.

The Exergetic Efficiency of the ISCC Power Plant
The exergetic efficiency of the ISCC power plant was calculated for different solar heat power inputs. The comparison was implemented at three different ambient temperatures: 5, 20, and 35 • C.
The ISCC power plant exergetic efficiency for solar heat inputs 0 MW, 50 MW, and 75 MW at different ambient temperatures is depicted in Figure 9. The exergetic efficiency of the ISCC power plant was calculated based on the design condition data for the different solar heat power inputs. Figure 9 reveals that the exergetic efficiency of the ISCC power plant is inversely proportional to the ambient temperature, where it decreased from 47.2% to 46% with increasing ambient temperature from 5 • C to 35 • C for solar heat input equal to 75 MW. In addition, it decreased from 48.2% to 46.58% when the ambient temperature increased from 5 • C to 35 • C for solar heat input equal to 50 MW. Figure 9 also illustrates the exergetic efficiency of the combined cycle regime (solar heat input equal to 0 MW) at different ambient temperatures. In the absence of the solar field, the exergetic efficiency of the plant reached 49.18% and 47.21% at ambient temperatures 5 • C and 35 • C, respectively. This demonstrates that the exergetic efficiency of the ISCC power plant in Kureimat has higher efficiency under the combined cycle regime than under the ISCC regime, as shown in Figure 9. This may be due to the existence of the solar field, which needs precise design optimization of solar energy integration in a CCPP.
Like the overall thermal efficiency, the exergetic efficiency of the ISCC power plant decreased with increasing ambient temperature, mainly at ambient temperature 35 • C. This may be due to the sharp decrease in the exergetic efficiency of the condenser and the solar field with increasing ambient temperature, as shown in Figures 6-8. These figures also show that the exergetic efficiency of the gas turbine and the HRSG decreased with increasing ambient temperature, and that also affected the exergetic efficiency of the ISCC power plant, as shown in Figure 9.
Appl. Sci. 2020, 10, x FOR PEER REVIEW 12 of 16 Figure 9. ISCC power plant exergetic efficiency at different ambient temperatures for different solar heat inputs. Figure 9 also illustrates the exergetic efficiency of the combined cycle regime (solar heat input equal to 0 MW) at different ambient temperatures. In the absence of the solar field, the exergetic efficiency of the plant reached 49.18% and 47.21% at ambient temperatures 5 °C and 35 °C , respectively. This demonstrates that the exergetic efficiency of the ISCC power plant in Kureimat has higher efficiency under the combined cycle regime than under the ISCC regime, as shown in Figure  9. This may be due to the existence of the solar field, which needs precise design optimization of solar energy integration in a CCPP.
Like the overall thermal efficiency, the exergetic efficiency of the ISCC power plant decreased with increasing ambient temperature, mainly at ambient temperature 35 °C . This may be due to the sharp decrease in the exergetic efficiency of the condenser and the solar field with increasing ambient temperature, as shown in Figures 6-8. These figures also show that the exergetic efficiency of the gas turbine and the HRSG decreased with increasing ambient temperature, and that also affected the exergetic efficiency of the ISCC power plant, as shown in Figure 9.

Investigating the Sources of Exergy Destruction
From the attained results, it is clear that the amount of exergy destruction in the various components of the ISCC is altered. This variation is assumed to be due to different reasons such as the type of device, the process, etc.
Moreover, the results showed that the combustion chamber and the solar field represent the sites of highest exergy destruction in the ISCC. In this section, an attempt is made to explore and clarify the sources of exergy destruction in the solar field and the combustion chamber to identify the possibility of enhancing the performance of these components.

Irreversibility in the Solar Field
The exergy destruction in the solar field is due to heat transfer between the sun and the absorber, heat transfer between the absorber and the HTF, and the friction of the viscous HTF. The exergy loss is due to the optical efficiency (the ratio of sunlight capture to incident sunlight) and the heat transfer to the surroundings.
The solar collector is considered to be the main source of exergy destruction in the solar field

Investigating the Sources of Exergy Destruction
From the attained results, it is clear that the amount of exergy destruction in the various components of the ISCC is altered. This variation is assumed to be due to different reasons such as the type of device, the process, etc.
Moreover, the results showed that the combustion chamber and the solar field represent the sites of highest exergy destruction in the ISCC. In this section, an attempt is made to explore and clarify the sources of exergy destruction in the solar field and the combustion chamber to identify the possibility of enhancing the performance of these components.

Irreversibility in the Solar Field
The exergy destruction in the solar field is due to heat transfer between the sun and the absorber, heat transfer between the absorber and the HTF, and the friction of the viscous HTF. The exergy loss is due to the optical efficiency (the ratio of sunlight capture to incident sunlight) and the heat transfer to the surroundings.
The solar collector is considered to be the main source of exergy destruction in the solar field due to the high temperature difference in the collector. The major contribution to the exergy destruction in the solar collector is due to the heat transfer between the sun and the absorber, while the major exergy loss occurs due to optical errors [28].
It was reported that exergy destruction due to heat transfer between the sun and the absorber accounts for 35% to 40% of the total exergy destroyed. Exergy losses to the surroundings account for 5% to 10% of the total exergy destroyed [28].
It is thought that to decrease the exergy losses from the solar collector (i.e., increase the collector energetic efficiency), attention should be pointed toward improving the optical parameters of the collector (such as mirror reflectivity, transmissivity of the glass envelope, absorptivity of the heat collection element selective coating, focal length of the collectors etc.).
Regarding the exergy destruction due to heat transfer, improving that part may involve great challenges because of the existence of the finite temperature differences which are essential for the heat transfer process and cannot be avoided.

Irreversibility in the Combustion Chamber
The combustion process is complex. Thus, the entropy generation during the combustion process is rather high due to the complexity of that process. It was reported that oxidation of fuel during the combustion process utilizes around 1/3 of the usable fuel energy [29]. This feature of the combustion process causes it to have the highest exergy destruction. The combustion process includes diffusion, chemical reaction, heat transfer, friction, and mixing. To implement all of these subprocesses, a considerable amount of the available energy is consumed. Most of this energy is unreachable (combustion activation energy, mixing, and diffusion).
There are three major physicochemical subprocesses responsible for entropy production during the combustion process [29]: • Diffusion of reactants (mixing of fuel and air molecules) and chemical reaction (fuel oxidation) where energy is consumed to overcome the activation energy.

•
Heat transfer between combustion products and other neighbors of particles; this is called "internal thermal energy exchange".

•
Mixing of combustion products with other constituents.
These processes cause exergy consumption (destruction) and thus result in a reduction in the system exergy. On one hand, all these processes destroy up to 40% of the useful exergy of the fuel. On the other hand, it was found that the dominant process of exergy destruction is the internal thermal energy exchange process. It was found that more than 2/3 of the exergy destruction in the combustion process occurs at the internal thermal exergy exchange process, while fuel oxidation is responsible for up to 30% of the exergy destruction, and the exergy destruction due to the mixing process is about 3% of the total exergy destruction of the combustion process [29].
The thermodynamically irreversible combustion process is path-dependent. To get a quantitative solution for the total entropy production during the combustion process, correct information of the sequence of the combustion process and reactions must be offered.
Many factors affect the exergy destruction in the combustion chamber. For example, the exergy destruction decreases with decreasing excess air and increasing preheating temperature. Mixing at a large temperature difference leads to high exergy destruction [30]. Also, the exergy destruction of the combustion chamber is affected by the molecular structure of the fuel, where the exergy destruction of the combustion chamber increases with the increase of the hydrocarbon chain length [31].
An attempt was made to avoid this heat transfer by introducing the concept of reversible combustion, where it was proposed theoretically to preheat the reactants to the equilibrium temperature and partial pressures without a reaction, but it could not be achieved in practice [29].
The major exergy destruction in the combustion chamber occurs during the phase of the internal thermal energy exchange between the system particles [29]. The unavoidability of the internal thermal energy exchange makes reducing the exergy destruction during the combustion process very difficult.

Conclusions
The objective of this study was to investigate the performance of an existing 135 MW ISCC power plant in Kureimat. The ISCC power plant was thermodynamically studied under Kureimat climatic conditions. Energy and exergy analyses were performed for the ISCC power plant as a whole at different ambient temperatures (5, 20, and 35 • C) and different solar heat inputs (0, 50, 75 MW). Moreover, the exergy destruction and the exergetic efficiency for the main components of the ISCC power plant were calculated and investigated regarding the influence of the ambient temperature and the solar heat input to identify the causes and locations of the highest thermodynamic irreversibility. The integration of solar energy into a natural gas CCPP was analyzed as a power-boosting mode.
The main conclusions of this study are as follows: • The solar field has the lowest exergetic efficiency (17.8%), followed by the condenser (42.2%), at ambient temperature 20 • C and solar heat input 50 MW.

•
The exergy destruction in the solar field is the largest part of the exergy destruction in the ISCC power plant (52.9% at ambient temperature 20 • C and solar heat input 50 MW).

•
The thermal efficiency and the exergetic efficiency of the ISCC decrease with increasing solar field thermal input, where it has its highest values (51.14% and 49.18%, respectively) at no solar field thermal input (combined cycle regime) and ambient temperature 5 • C.

•
The thermal efficiency and the exergetic efficiency of both the ISCC and the combined cycle (i.e., at no solar field heat input) decrease with increasing ambient temperature at different solar heat inputs (0, 50, 75 MW). This is due to the decrease of the exergetic efficiency of the gas turbine, the solar field, the condenser, and the HRSG with increasing ambient temperature.

•
The integration of a solar field with a combined cycle (i.e., ISCC) reduced the thermal and exergetic efficiencies of the power plant under the combined cycle regime due to the low thermal and exergetic efficiencies of the solar field because the solar fuel cost was considered in this study.

•
The target of the ISCC power plants is not to increase the overall thermal efficiency of the Brayton cycle, like the combined cycle, but to increase the economic feasibility of solar power plants.
Elimination of the thermal storage system reduces the cost of the power plant [24][25][26]. So, this integration of a solar field is recommended regarding the given challenges for the electricity market with the continuing expansion of intermittent renewables.
Author Contributions: A.T. is responsible for the technical, analysis, writing and funding acquisition parts.
A.E. has contributed strongly to the design and preparation of the investigation. A.T., A.R., A.E., F.A., and B.E. discussed the formulation and the results and contributed to the review and editing of the manuscript. All authors have read and agreed to the published version of the manuscript.

Funding:
The authors appreciate the Technical University of Darmstadt for funding the publication costs for the article in an open-access journal. The corresponding author appreciates the Egyptian Government for offering the PhD scholarship.

Conflicts of Interest:
The authors declare no conflict of interest.