During the 38th General Conference of UNESCO, the Member States ratified the creation of the International Geoscience and Geoparks Programme (IGGP) expressing governmental recognition of the importance of managing outstanding geological sites and landscapes in a holistic manner. In this context, the importance of human interactions with the natural environment to promote healthy lifestyles was primarily a response to the need to preserve and enhance the value of the UNESCO Global Geoparks as well as highlighting their usefulness for the sustainable development of local populations. The aim of this paper is to suggest an interdisciplinary approach to be applied to UNESCO Global Geoparks for a standardized survey and grading methodology that can be used to assess the ability to provide and promote healthy lifestyles, which is called the Ecosystem’s Health Provision Spectrum (EHPS) on an ecological scale. The suggested EHPS is in line with UNESCO’s priorities, in particular with the IGGP and its motto of “Geosciences in the Service of Society”. Therefore, the EHPS on an ecological scale will be another important tool for the UNESCO Global Geoparks, facilitating efficient management and promoting economic development, wellbeing and health. Full article

Worldwide studies have been done about the toxicity and carcinogenicity of asbestos minerals occurring in ophiolitic rocks. Inhalation of asbestos due to environmental exposure could cause malignant mesothelioma and lung cancers. In particular, the ophiolitic rocks in Tethyan realm represents a serious enivironmental concern due to both the presence of asbestos-like minerals and the large Cr abundance that is prone to solubilisation as CrVI. At the Pollino Geopark (southern Apennines, Italy), serpentinites-rich ophiolite rocks and sediments of the Frido Unit crop-out. In these rocks, tremolite, an asbestos-like mineral, is typically intergrown with fibrous antigorite and chrysotile. Tremolite shows acicular, friable, fibrous, and elongated habitus, can be easily released into the environment as a result of both natural processes and anthropogenic activities. In the analyzed rocks, tremolite is present mainly in veins as much as in the matrix and forms crowns around clinopyroxene porphyroclasts. The different analytical techniques showed the recognition of the amphibole-like minerals (actinolite and tremolite) that are the dominant phases, with a small percentage of Fe²⁺. The presence of Fe in the “ideal” tremolite asbestos could cause pathological effects for the human living in the Pollino Geopark. This study has several environmental relevant implications, including, for example, the realization of national health protecting programs and the mapping of natural sites characterized by the presence of asbestos minerals in Pollino Geopark and in others area where outcrop asbestos bearing ophiolitic rocks. Full article

This article analyzes the lanthanum, cerium, samarium, europium, terbium, ytterbium, lutetium, uranium, and thorium content in humic acids within soil and paleosol surface horizons from the southern steppe in the Southern Urals. Research demonstrates similar accumulation levels of these elements in paleosols isolated from both the active medium between 3.6 and 3.3 thousand years ago and in recent background soils. Despite the lack of significant differences, research has shown a growing content among the rarest metals in the series “the buried paleosols–man-modified paleosols of settlement–recent background soils”. Research has detected the lowest content of La, Ce, Sm, Eu, Yb, Lu, and Th in preparations of humic acids of recent background soils. This reveals a close content to most elements in humic acids of paleosols buried under barrows and ancient settlement paleosols. Additionally, it indicates the virtual absence of anthropogenic impact on binding lanthanides and actinides by humic acids in ancient times. The contribution of humic acids into the common pool for each element was evaluated using a special approach. Research showed that there was less than half the share of elements associated by humic acids of paleosols than in the recent background chernozems in the total pool of lanthanides and actinides. This article considers the prospects of using humic acids of recent and ancient soils in identifying behavioral patterns of metal complexes through time. Full article

This study presents the combined use of field mapping, remote sensing data analysis, mineralogy, spectroscopy and GIS techniques for the geological mapping of Antiparos Island. Antiparos is part of the Cyclades Blueschist Belt located in central Aegean, where gneisses, schists and Pliocene volcanic rocks occurred. During the extended field work, a number of volcanic rock samples were collected from the southern part of Antiparos. The sampling strategy was to collect samples from the primary as well as the altered rocks in specific areas in which they were previously located from the remote sensing data processing. In this study, high resolution satellite images have been carried out in order to detect, allocate and separate the different geological formations. Furthermore, the existing geological map was georeferenced and all the tectonic lines and boundaries were digitized. All these features were implemented in a Mobile Mapper CE GPS using Arcpad GIS and checked in situ. The collected samples were analyzed in the laboratory using various techniques including XRD, Petrographic Microscopy and SEM. The qualitative mineralogical analyses were conducted by using XRD. The study was supplemented by the petrographic observations providing a detailed characterization of rock textures. In addition, SEM study and SEM-EDS analyses of the samples were emphasized on the genetic relations of the minerals. The laboratory results revealed that specific corrections should be made in the previous geological map of Antiparos concerning the volcanic rocks, especially at the southern part of the island. A significant conclusion is that the rock described as volcanic in the previous map proved to be a fossiliferous limestone which includes micritic matrix of calcite with an insignificant amount of fossils. All the analogical and digital data and the results of the petrographic analysis were imported in a geodatabase specially designed for geological data. After the necessary topological control and corrections, the data were unified and processed in order to create the final layout at 1/25.000 scale. Full article

In this work, in order to study the release, migration, sorption, and (re)precipitation of uranium (U) during alteration under oxidizing conditions, we carried out a systematic study using scanning electron microscopy, X-ray maps, and electron microprobe analyses on uranium minerals—such as uraninite, coffinite, saleeite, meta-saleeite, and thorite—and U-bearing minerals—such as xenotime, monazite, apatite, and zircon—from unaltered and altered Variscan peraluminous granites and related hydrothermal brecciated uranium–quartz veins. The paragenetic sequence of the granite and the mineralized quartz veins from Vale the Abrutiga is presented. Uraninite is magmatic in origin and occurs mainly in unaltered granite; it is rare in altered granite, and was not found in the mineralized quartz veins. Uraninite from the altered granite was fractured and hydrated; it had radioactive damage halos filled with late pyrite, U–S-bearing phases, and Fe oxyhydroxides; its analytical totals were also lower than in the uraninite from the unaltered granite. The alteration zones and crystal rims were poorer in U (86.7 wt.% UO₂) than in the cores and unaltered zones (90.2 wt.% UO₂), and some uraninite crystals were replaced by coffinite, which resulted from uraninite alteration. The U contents in the coffinite crystals ranged between 65.0 wt.% UO₂ in the rims to 84.0 wt.% UO₂ in the cores of the crystals. Thorite was found in all of the granite samples, and its composition was variable from 0.5 wt.% UO₂ to 10.4 wt. % UO₂. Some thorite seemed to be primary, whereas the other thorite was related to the granite alteration, replaced apatite and monazite, was associated with xenotime, and filled the fractures of several minerals. In the altered granite, thorite had low UO₂ contents (0.46 wt. %) in the fractured crystal zones. Monazite from the altered granite had a pervasive porosity; some crystals were formed by the alteration of apatite, and were frequently replaced by thorite. Monazite and xenotime from the altered granite and hydrothermal veins had lower U contents than these minerals from the unaltered granite. In the altered granite, xenotime crystals were zoned, and their cores were richer in U than the rims. Apatite from the altered granite was fractured, showed dissolution, and had lower U and P contents than the apatite from the unaltered granite. In the quartz veins, apatite crystals were replaced by uranium phosphates and had high U contents (~1.1 wt. % UO₂). In the quartz veins, zircon rims had an extraordinary U enrichment (up to 18 wt. % UO₂). The most altered rims of chlorite and anatase from the quartz veins were partially replaced by U-bearing Fe oxyhydroxides containing up to 5.7 wt. % UO₂. Meteoric water warmed by deep circulation through granite faults, shear zones, and quartz veins became enriched in U, P, and Mg due to the solubilization of mainly uraninite, coffinite, thorite, monazite, apatite, and chlorite. Uranium from these solutions was later adsorbed on Fe oxyhydroxides and the weathered surfaces of anatase, zircon, and apatite, or precipitated as saleeite and meta-saleeite on the surface of Fe minerals and the apatite-weathered surface due to local saturation. Full article

High resolution remotely sensed bathymetric data is rapidly increasing in volume, but analyzing this data requires a mastery of a complex toolchain of disparate software, including computing derived measurements of the environment. Bathymetric gradients play a fundamental role in energy transport through the seascape. Benthic Terrain Modeler (BTM) uses bathymetric data to enable simple characterization of benthic biotic communities and geologic types, and produces a collection of key geomorphological variables known to affect marine ecosystems and processes. BTM has received continual improvements since its 2008 release; here we describe the tools and morphometrics BTM can produce, the research context which this enables, and we conclude with an example application using data from a protected reef in St. Croix, US Virgin Islands. Full article

This paper presents the basin approach to the design, development, and operation of a hydrological forecasting and early warning system in a large transboundary river basin of high flood potential, where accurate, reliable, and timely available daily water-level and reservoir-inflow forecasts are essential for water-related economic and social activities (the Amur River basin case study). Key aspects of basin-scale system planning and implementation are considered, from choosing efficient forecast models and techniques, to developing and operating data-management procedures, to disseminating operational forecasts using web-GIS. The latter, making the relevant forecast data available in real time (via Internet), visual, and well interpretable, serves as a good tool for raising awareness of possible floods in a large region with transport and industrial hubs located alongside the Amur River (Khabarovsk, Komsomolsk-on-Amur). Full article

Monitoring of potential gas seepage for CO₂ sequestration and CO₂-EOR (Enhanced Oil Recovery) in geologic storage will involve geophysical and geochemical measurements of parameters at depth and at, or near the surface. The appropriate methods for MVA (Monitoring, Verification, Accounting) are needed for both cost and technical effectiveness. This work provides an overview of some of the geochemical methods that have been demonstrated to be effective for an existing CO₂-EOR (Rangely, CA, USA) and a proposed project at Teapot Dome, WY, USA. Carbon dioxide and CH₄ fluxes and shallow soil gas concentrations were measured, followed by nested completions of 10-m deep holes to obtain concentration gradients. The focus at Teapot Dome was the evaluation of faults as pathways for gas seepage in an under-pressured reservoir system. The measurements were supplemented by stable carbon and oxygen isotopic measurements, carbon-14, and limited use of inert gases. The work clearly demonstrates the superiority of CH₄ over measurements of CO₂ in early detection and quantification of gas seepage. Stable carbon isotopes, carbon-14, and inert gas measurements add to the verification of the deep source. A preliminary accounting at Rangely confirms the importance of CH₄ measurements in the MVA application. Full article

Shelf morphology and sedimentary regimes are influenced by processes operating at different temporal and spatial scales and are important records of sea level changes and sediment supply and/or carbonate production. The northern continental shelf of Espírito Santo (Brazil) contains evidence of different sedimentary regimes that distribute diverse and complex marine habitats. Herein, seabed morphology, acoustic images of the seafloor (side scan sonar and sub-bottom profiler), and sediment samples were used to investigate the influence of sedimentary regimes on physical marine habitat distribution. Seabed mapping is also integrated with available data on fisheries to understand the influence of shelf morphology and sedimentology in the usage of distinct fishing gears. The results indicate five morpho-sedimentary facies: terrigenous mud, terrigenous sand, rhodolith beds, carbonate gravel with rhodoliths, and hardground. Through an integrated analysis of the geomorphology and sedimentary distribution, two morpho-sedimentary domains were identified: a sediment-fed shelf adjacent to the Doce River associated with a major mud depocenter and a delta front morphology characterized by gentle slopes and low terrain ruggedness, and a sediment-starved shelf dominated by carbonate sedimentation showing an irregular morphology associated with higher slopes and terrain ruggedness. These contrasting morpho-sedimentary domains are a result of sedimentary responses to sea level fluctuation during Late Quaternary, specially, during the deglaciation processes after the Last Glacial Maximum. The morphological and sedimentary contrasts along the area define the physical habitat distribution. The sediment supply regime area is associated with a terrigenous fine/muddy sedimentation bed, which control the local morphology and favors coastal and delta front progradation. This physical habitat is a well-known shrimp-fishing ground where intense trawling takes place, as well as gillnet fisheries targeting weakfish and croakers. The accommodation regime or low sediment influx area is characterized by carbonate sedimentation associated with hardgrounds and rhodolith beds. In contrast, this physical habitat with scarce sediment supply, facilitates extensive benthic colonization by crustose coralline algae (CCA), which is primarily associated to line fisheries, longlines, and spearfishing. Rhodoliths show a high diversity of CCA and the occurrence of an endemic kelp species. Long-term processes such as relative sea level fluctuations and sediment supply are a legacy for the distribution of benthic habitats, and their resulting morphology can be a surrogate for predicting fishing activities or a first-base analysis for marine spatial planning. Available low-resolution bathymetric datasets can be a powerful tool, if applied with caution and in a regional scale approach. Here, terrain variables (terrain slope and ruggedness) derived from an extensive available (low-resolution and interpolated) bathymetric dataset distinguished two contrasting morphological domains characterized by rugged and smooth/flat seabeds. Full article

Every spring, riverine communities throughout the Arctic face flood risk. As the river ice begins to thaw and break up, ice jams—accumulation of chunks and sheets of ice in the river channel, force melt water and ice floes to back up for dozens of kilometers and flood vulnerable communities upstream. Via a comparative analysis between two flood-prone communities in Alaska and Yakutia (Siberia), this study examines key components of flood risk—hazards, exposure, and vulnerability, and existing practices in flood risk reduction in rural Arctic. The research sites are two rural communities—Galena (Yukon River) and Edeytsy (Lena River), which sustained major ice-jam floods in May 2013. The data was acquired through a combination of direct observations on site, review of documents and archives, focus group discussions, and surveys. Five focus groups with US and Russian representatives from disaster management agencies revealed a few similar patterns as well as significant differences in flood risk reduction strategies. The main differences included higher reliance on mechanical and short-term ice jam and flood mitigation efforts (e.g., ice-jam demolition) in the Russian Arctic, and lack of a centralized flood management model in the US. Surveys conducted among population at risk during the site visits to Edeytsy (November 2015) and Galena (March 2016) revealed higher satisfaction levels with the existing flood risk reduction efforts among Edeytsy residents. Survey respondents in Galena indicated the lack of ice jam removal and other flood prevention measures as the key drawback in the existing flood management. Historical analysis, conducted via the disaster Pressure and Release (PAR) model, revealed that springtime flood risk in both regions results from complex interactions among a series of natural processes that generate conditions of hazard, and human actions that generate conditions of communities’ exposure and vulnerability. The analysis revealed colonial heritage, top-down governance, and limited inclusion of local communities in the decision-making as the driving forces of vulnerability in both regions. Seasonal weather patterns and regional river channel morphology determine the location, severity, and duration of floods. The analysis also revealed the importance of continuous communication between all stakeholders in timely and effective flood risk management in both regions. Full article

Studies dating almost a century relate clay properties with the structure of the diffuse double layer (DDL), where the charged surfaces of clay crystal behave like an electric capacitor, whose dielectric is the interstitial fluid. The intensity of the inner electric field relates to the concentration and type of ions in the DDL. Other important implications of the model are less stressed: this part of the clay soil system, energetically speaking, is conservative. External contribution of energy, work of overburden or sun driven capillarity and long exposure to border low salinity waters can modify the concentration of pore-waters, thus affecting the DDL geometry, with electric field and energy storage variations. The study of clay soils coming from various natural geomorphological and hydrogeological contexts, determining a different salinity of interacting groundwater, shows how the clay interaction with freely circulating waters at the boundaries produces alterations in the native pore water salinity, and, at the nano-scale, variations of electric field and stored energy from external work. The swelling and the shrinkage of clay soil with their volumetric and geotechnical implications should be regarded as variations of the electrostatic and mechanical energy of the system. The study is based on tests on natural clay soil samples coming from a formation of stiff blue clays, widespread in southern Italy. Geotechnical identification and oedometer tests have been performed, and pore waters squeezed out from the specimens have been analyzed. Tested samples have similar grain size, clay fraction and plasticity; sorted according to the classified geomorphological/hydrogeological contexts, they highlight good correlations among dry density, mechanical work performed in selected stages of the oedometric test, swelling and non-swelling behaviour, and electrical conductivity of the squeezed pore waters. The work performed for swelling and non-swelling samples shows well-defined differences; this endorse the relevance of pore-water salinity in determining the volumetric state of clay soils under overburden and specific hydrogeological border conditions, which together define a specific energetic state. Full article

Numerical simulations of rockfall trajectories are a standard procedure for evaluating rockfall hazards. For these simulations, corresponding software codes must be calibrated and evaluated based on field data. This study addresses methods of repeatable rockfall tests, and investigates whether it is possible to produce traceable and statistically analysable data. A testing series is described extensively covering how to conduct rockfall experiments and how certain elements of rockfall trajectories can be measured. The tests use acceleration and rotation sensors inside test blocks, a system to determine block positions over time, surveying measurements, and video recordings. All systems are evaluated regarding their usability in the field and for analyses. The highly detailed description of testing methods is the basis for sound understanding and reproducibility of the tests. This article serves as a reference for future publications and other rockfall field tests, both as a guide and as a basis for comparisons. First analyses deliver information on runout with a shadow angle ranging between 21 and 45 degrees for a slope consisting of homogeneous soft soil. A digital elevation model of the test site as well as point clouds of the used test blocks are part of this publication. Full article