Performance of Date Palm Ash as a Cementitious Material by Evaluating Strength, Durability, and Characterization

Cement manufacturing is indeed a major contributor to global warming that involves energy-intensive production processes along with emitting huge greenhouse gasses into the atmosphere. To adopt sustainable construction practices, agro-industrial waste materials as supplementary cementitious materials (SCMs) have been used by numerous researchers to partially replace conventional ordinary Portland cement (OPC) with SCMs by evaluating its optimum replacement dosage. This study aims to: (1) highlight the background of the date palm tree and the application of date palm waste as a construction material; (2) optimizing the dosage of date palm ash (DPA) as a cementitious material, at the replacement level of 10%, 20%, and 30%; and (3) understand the reaction kinetics by way of characterization techniques. DPA-based binary mixes were compared with each other and with the control (100% OPC mix) through fresh, mechanical, durability, and microstructural properties. The mechanism of reaction at earlyand long-term period of curing was studied by characterization tests on paste, including nitrogen adsorption test (BET), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR). The outcome revealed 10% DPA as a strong and durable substitute to OPC, by formation of more Calcium Silicate Hydrate (C-S-H) and Calcium Aluminosilicate Hydrate (C-A-S-H) gel, whereas up to 30% DPA replacement can further maximize clinker replacement with reasonable performance, together with enhanced sustainability and reduced construction cost.


Introduction
The demand of cement is continuously increasing worldwide due to the construction boom. Production of cement is considered as environmentally unfriendly because of its energy-intensive process and drawback of releasing high CO 2 into the atmosphere. According to the Cement Sustainability Initiative (CSI), global cement production has reached from 500 Mt in 1990 to 900 Mt in 2015 [1]. It is reported that 2% world energy and 5% world industrial energy is consumed by the cement sector, which is responsible for emitting 5% of world CO 2 emissions [2]. If CO 2 emissions are not controlled below 50 Gt, it is likely to endanger global warming risk by exceeding the 2 • C Earth temperature limit [3]. CO 2 emissions can be minimized by adopting the following approaches: (1) using supplementary cementitious materials (SCMs) as partial replacement of traditional cement from agro-industrial and natural waste material, including palm oil fuel ash, rice husk ash, fly ash, ground steel slag, natural pozzolan, and metakaolin; (2) developing geopolymer concrete (OPC-free); (3) carbon capturing; and Type I-ordinary Portland cement (OPC) was utilized in all mixtures. The specific gravity and maximum particle size of OPC was 3.44 and 0.075 mm, respectively. Date palm ash (DPA) was procured from a farm located in Eastern Saudi Arabia, where a farmer collects the palm waste from nearby farms and recycles them to form firewood and charcoal, while using same waste as a fuel material. The by-product of burning waste is called date palm ash. About 3 tons of firewood and 1.5 tons of coal is daily produced, which generates 10%-20% of the DPA at a plant. Figure 1 shows the stages of the production of valuable products and waste generation at the recycling plant as follows: (a) dried date palm tree fronds are trimmed, (b) raw date palm tree waste is dried in open air and sun for one day and transported to the plant, (c) raw material is grinded, passing through a 8 mm diameter sieve, using a hammer mill, (d) crushed raw material is passed to the compression machine and shaped, (e) fire wood is produced, (f) wood is placed in an environmental friendly oven and burnt up to 700 °C for 6 h using raw material as fuel, (g) wood is transformed into charcoal, and (h) fuel material is converted into ash (DPA). The specific gravity and maximum particle size of DPA was 2.43 and 0.150 mm, respectively.

Fine Aggregate and Coarse Aggregate
Dune sand was incorporated as fine aggregate (FA) having bulk specific gravity, absorption, and maximum particle size of 2.82, 0.7%, and 0.425 mm, respectively. Crushed limestone was utilized as coarse aggregate (CA) having bulk specific gravity, absorption, and maximum particle size of 2.6, 1.1%, and 19 mm, respectively. The grading requirement of CA was fulfilled as per ASTM C 33.

Preparation of Specimens
Total of 4 mixtures were cast, each of paste, mortar, and concrete, by replacing OPC with DPA (0%-30%) with an interval of 10%. Water to cementitious material ratio and FA to CA ratio was kept invariant as 0.4 and 0.7, respectively. Cubic paste specimens 25 mm in size were prepared for

Fine Aggregate and Coarse Aggregate
Dune sand was incorporated as fine aggregate (FA) having bulk specific gravity, absorption, and maximum particle size of 2.82, 0.7%, and 0.425 mm, respectively. Crushed limestone was utilized as coarse aggregate (CA) having bulk specific gravity, absorption, and maximum particle size of 2.6, 1.1%, and 19 mm, respectively. The grading requirement of CA was fulfilled as per ASTM C 33.

Preparation of Specimens
Total of 4 mixtures were cast, each of paste, mortar, and concrete, by replacing OPC with DPA (0%-30%) with an interval of 10%. Water to cementitious material ratio and FA to CA ratio was kept invariant as 0.4 and 0.7, respectively. Cubic paste specimens 25 mm in size were prepared for analytical tests, mortar was prepared for the flow table test, and 50 mm cubic mortar specimens were prepared for compressive strength test, while 100 mm diameter × 200 mm high cylindrical concrete specimens were prepared for the sorptivity test. The constituent of mortar (cementitious material, FA and water) and paste (mortar excluded FA) was proportioned as per the guidelines of ASTM C 109. The typical mixture proportion of concrete specimen consisted: cementitious material = 350 kg/m 3 , FA = 733 kg/m 3 , CA = 1099 kg/m 3 and water = 167 kg/m 3 . First, dry materials were introduced in the mixer followed by mixing water and/or superplasticizer. The ingredients were mixed for a total duration of 6 to 8 min. The dough was placed in oiled molds in two layers, consolidated for 15 s on vibration table, and the top surface finished by trowel. The molds were plastic-wrapped and placed at room temperature at 25 ± 3 • C for 24 h. Thereafter, molds were opened and specimens were placed under water until the test ages. Table 1 shows the chemical composition of OPC and DPA evaluated through X-ray fluorescence (XRF) technique using the PANalytic apparatus. OPC has major oxides of Si, Ca, and Al and minor traces of Fe and Mg, whereas DPA constituted major oxides of Si, Ca, Mg, and K and minor traces of Fe and Al. The sum of the oxides of Si, Ca, Mg, and K in DPA was above 80%. By partial replacement of OPC by DPA in binary binders, Si, Mg, and K content increased while Ca content decreased. Surface area and pore volume was measured on paste binders using B.E.T-Nitrogen adsorption test by means of Quantachrome instrument.

Flow
The flow of fresh mortar was measured by flow table as per ASTM C 1437, right after mixing operation. The flow was measured in four directions and average values were reported.

Compressive Strength
Compressive strength was evaluated on 50 mm cubic mortar specimens for the water cured ages of up to 360 days, using compression testing machine applying a uniform load. This test was conducted as per ASTM C 109. The average of three test specimens (whose standard deviation was within the allowable limit) were reported as compressive strength.

Rate of Water Absorption
Rate of water absorption or sorptivity test was conducted on concrete specimens at 28 and 360 days, as per ASTM C1585. Cylindrical specimens (100 × 200 mm) were first sliced using a saw cutter in order to obtain 50 mm thick and 100 mm diameter disks. The sides and top surface of the Buildings 2019, 9, 6 5 of 13 disks were wrapped by strong sticky tape and plastic sheet, respectively. Three disk specimens from each mix were partially immersed in water and the weight gain was recorded at different intervals of time and up to 8 days. The reported results' standard deviation was within the allowable limit.
2.2.6. Thermogravimetric Analysis (TGA) Thermogravimetric analysis was carried out on paste specimens at the ages of 28 and 360 days to study the weight loss (WL) at important phases. A SDT-Q600 model was used to get the readings.
2.2.7. X-ray Diffraction (XRD) Analysis X-ray diffraction analysis was carried out on the paste specimens at the age of 28 days to study the mineralogy of the developed matrix. The main parameters input for the analysis in the Rikagu D8 machine included source of Cu-K, scanning velocity of 2.5 deg/min, and voltage of 20 kV.

Fourier Transform Infrared Spectroscopy (FT-IR) Analysis
Fourier Transform Infrared Spectroscopy was performed on paste specimens after 28 days to study the molecular behavior and formation of functional groups using Thermo Fisher spectrometer. Figure 2 shows the variation in mortar flow with addition of DPA dosages. The flow of mortar in all mixtures were within the plastic range (140 to 200 mm), as per BS EN 1015 [15]. Maximum flow was measured in 100% OPC mortar, and flow tended to decrease with addition of DPA content. The mortar flow in 100% OPC was 180 mm, which was about 5.5%, 12.7%, and 16.1% higher than mortar prepared with 10%, 20%, and 30% DPA, respectively. The drop in flow values with DPA addition was due to its coarser and irregular particles, in nature, than OPC, which resists mortar flow. Rate of water absorption or sorptivity test was conducted on concrete specimens at 28 and 360 days, as per ASTM C1585. Cylindrical specimens (100 × 200 mm) were first sliced using a saw cutter in order to obtain 50 mm thick and 100 mm diameter disks. The sides and top surface of the disks were wrapped by strong sticky tape and plastic sheet, respectively. Three disk specimens from each mix were partially immersed in water and the weight gain was recorded at different intervals of time and up to 8 days. The reported results' standard deviation was within the allowable limit.

Thermogravimetric Analysis (TGA)
Thermogravimetric analysis was carried out on paste specimens at the ages of 28 and 360 days to study the weight loss (WL) at important phases. A SDT-Q600 model was used to get the readings.

X-Ray Diffraction (XRD) Analysis
X-ray diffraction analysis was carried out on the paste specimens at the age of 28 days to study the mineralogy of the developed matrix. The main parameters input for the analysis in the Rikagu D8 machine included source of Cu-K, scanning velocity of 2.5 deg/min, and voltage of 20 kV.

Fourier Transform Infrared Spectroscopy (FT-IR) Analysis
Fourier Transform Infrared Spectroscopy was performed on paste specimens after 28 days to study the molecular behavior and formation of functional groups using Thermo Fisher spectrometer. Figure 2 shows the variation in mortar flow with addition of DPA dosages. The flow of mortar in all mixtures were within the plastic range (140 to 200 mm), as per BS EN 1015 [15]. Maximum flow was measured in 100% OPC mortar, and flow tended to decrease with addition of DPA content. The mortar flow in 100% OPC was 180 mm, which was about 5.5%, 12.7%, and 16.1% higher than mortar prepared with 10%, 20%, and 30% DPA, respectively. The drop in flow values with DPA addition was due to its coarser and irregular particles, in nature, than OPC, which resists mortar flow.    Figure 3 displays the compressive strength values in 100% OPC, 10% DPA, 20% DPA, and 30% DPA mortar specimens with curing period up to 360 days. The results showed that the optimum mix, yielding high compressive strength at all test ages, was 10% DPA plus 90% OPC. At the early age of 3 days, the compressive strength of optimum mix was 43 MPa, which was 38%, 30%, and 50% higher than those achieved by 100% OPC, 20% DPA, and 30% DPA mixtures, respectively. The later and long-term age strength development was found to be comparable among 100% OPC and 10% DPA mixes, as well as among 20% DPA and 30% DPA mixtures. The 28-day compressive strength of 10% DPA specimens was about 57 MPa, which was 3%, 24%, and 29% higher than those attained by 100% OPC, 20% DPA, and 30% DPA mixtures, respectively. Similarly, long-term strength of 10% DPA was 85.5 MPa, which was 4%, 27%, and 28% more than the strength of 100% OPC, 20% DPA, and 30% DPA mixtures, respectively. The strength increment in the 10% DPA mix could be explained by the ability of DPA to produce higher secondary Calcium Silicate Hydrate (C-S-H), due to the presence of optimum lime content, as observed in TGA and XRD analysis. Figure 3 displays the compressive strength values in 100% OPC, 10% DPA, 20% DPA, and 30% DPA mortar specimens with curing period up to 360 days. The results showed that the optimum mix, yielding high compressive strength at all test ages, was 10% DPA plus 90% OPC. At the early age of 3 days, the compressive strength of optimum mix was 43 MPa, which was 38%, 30%, and 50% higher than those achieved by 100% OPC, 20% DPA, and 30% DPA mixtures, respectively. The later and long-term age strength development was found to be comparable among 100% OPC and 10% DPA mixes, as well as among 20% DPA and 30% DPA mixtures. The 28-day compressive strength of 10% DPA specimens was about 57 MPa, which was 3%, 24%, and 29% higher than those attained by 100% OPC, 20% DPA, and 30% DPA mixtures, respectively. Similarly, long-term strength of 10% DPA was 85.5 MPa, which was 4%, 27%, and 28% more than the strength of 100% OPC, 20% DPA, and 30% DPA mixtures, respectively. The strength increment in the 10% DPA mix could be explained by the ability of DPA to produce higher secondary Calcium Silicate Hydrate (C-S-H), due to the presence of optimum lime content, as observed in TGA and XRD analysis.  Figure 4 shows the rate of water absorption in 100% OPC, 10% DPA, 20% DPA, and 30% DPA concrete specimens with respect to square root of time. An excellent correlation was noted both during initial (upto 6 h of immersion in water) and secondary (every 24 h upto 8 days) rate of water absorption, such that R-square value of approximately 0.9 was obtained. Figure 5 summarizes the maximum value of initial and secondary rate of water absorption in all concrete batches. It can be observed that 10% DPA-based concrete specimens resulted in minimum rate of water absorption, both at initial and final stages, followed by concrete containing 20% DPA, 100% OPC, and 30% DPA, respectively. At 28 days, the maximum initial rate of water absorption was 0.54 mm in optimum (10% DPA-based) concrete, which was about 35%, 27%, and 41% lesser than 100% OPC, 20% DPA, and 30% DPA samples, respectively. Likewise, the maximum secondary rate of water absorption was recorded as 1.92 mm in 10% DPA-based concrete, which was about 20%, 19.5%, and 31% lower than 100% OPC, 20% DPA, and 30% DPA specimens, respectively. It was also noticed that percentage increment of maximum rate of water absorption among each concrete mixture, from its initial to secondary absorption, was smallest and highest, respectively, in 10% and 20% DPA-based concrete samples. The difference in maximum initial and secondary absorption values was about 66%, 72%, 69%, and 67% in 100% OPC, 10% DPA, 20% DPA, and 30% DPA-based concrete specimens, respectively. Similar pattern of water penetration was noted at 360 days, while reduction in absorption value is understandably due to higher binder maturity and strength with time.   Figure 4 shows the rate of water absorption in 100% OPC, 10% DPA, 20% DPA, and 30% DPA concrete specimens with respect to square root of time. An excellent correlation was noted both during initial (upto 6 h of immersion in water) and secondary (every 24 h upto 8 days) rate of water absorption, such that R-square value of approximately 0.9 was obtained. Figure 5 summarizes the maximum value of initial and secondary rate of water absorption in all concrete batches. It can be observed that 10% DPA-based concrete specimens resulted in minimum rate of water absorption, both at initial and final stages, followed by concrete containing 20% DPA, 100% OPC, and 30% DPA, respectively. At 28 days, the maximum initial rate of water absorption was 0.54 mm in optimum (10% DPA-based) concrete, which was about 35%, 27%, and 41% lesser than 100% OPC, 20% DPA, and 30% DPA samples, respectively. Likewise, the maximum secondary rate of water absorption was recorded as 1.92 mm in 10% DPA-based concrete, which was about 20%, 19.5%, and 31% lower than 100% OPC, 20% DPA, and 30% DPA specimens, respectively. It was also noticed that percentage increment of maximum rate of water absorption among each concrete mixture, from its initial to secondary absorption, was smallest and highest, respectively, in 10% and 20% DPA-based concrete samples. The difference in maximum initial and secondary absorption values was about 66%, 72%, 69%, and 67% in 100% OPC, 10% DPA, 20% DPA, and 30% DPA-based concrete specimens, respectively. Similar pattern of water penetration was noted at 360 days, while reduction in absorption value is understandably due to higher binder maturity and strength with time.          Figures 6 and 7 show the weight loss (WL) with respect to temperature exposure at the age of 28 and 360 days. Tables 2 and 3 summarize the WL data, wherein hydrated gel phase and remnants of portlandite were calculated. Temperatures between 110 and 300 • C (Phase 1) indicate the decomposition of Calcium Silicate Hydrate (C-S-H) and Calcium Aluminosilicate Hydrate (C-A-S-H) gel, while sample exposure to temperature between 450 and 550 • C (Phase 2) gives information of CH or Ca (OH) 2 availability [16]. The 28-day TGA results demonstrate that WL increases with increase in DPA replacement, as compared to 100% OPC pastes. This shows that more hydrated gel products are present in DPA-based binary paste than OPC paste. About 5%, 7%, and 23% more hydration products were formed in the mixes containing 30%, 20%, and 10% DPA content, respectively. Moreover, 30%-45% lesser portlandite was available in the DPA-based paste matrix, as compared to the control mix, which is possibly consumed in the secondary hydration and pozzolanic reaction while reacting with silica, leading to additional hydrated gel and strength. After 360 days of curing, the control and 10% DPA mixes show approximately similar WL in phase 1; understandably OPC paste undergoes steady and long-term strength development. Additionally, 10% DPA paste still constitute 13% extra portlandite, which can react with active silica in DPA and Al in OPC to form further gel products. The results further indicate that with more than 10% increment in DPA dosage there is no significant improvement in the hydration products. However, beside technical advantage, high DPA replacement could be encouraged for a sustainability and economy point of view. Both 28-and 360-day TGA results corroborate the strength results.  Tables 2 and 3 summarize the WL data, wherein hydrated gel phase and remnants of portlandite were calculated. Temperatures between 110 and 300 °C (Phase 1) indicate the decomposition of Calcium Silicate Hydrate (C-S-H) and Calcium Aluminosilicate Hydrate (C-A-S-H) gel, while sample exposure to temperature between 450 and 550 °C (Phase 2) gives information of CH or Ca (OH)2 availability [16]. The 28-day TGA results demonstrate that WL increases with increase in DPA replacement, as compared to 100% OPC pastes. This shows that more hydrated gel products are present in DPA-based binary paste than OPC paste. About 5%, 7%, and 23% more hydration products were formed in the mixes containing 30%, 20%, and 10% DPA content, respectively. Moreover, 30%-45% lesser portlandite was available in the DPA-based paste matrix, as compared to the control mix, which is possibly consumed in the secondary hydration and pozzolanic reaction while reacting with silica, leading to additional hydrated gel and strength. After 360 days of curing, the control and 10% DPA mixes show approximately similar WL in phase 1; understandably OPC paste undergoes steady and long-term strength development. Additionally, 10% DPA paste still constitute 13% extra portlandite, which can react with active silica in DPA and Al in OPC to form further gel products. The results further indicate that with more than 10% increment in DPA dosage there is no significant improvement in the hydration products. However, beside technical advantage, high DPA replacement could be encouraged for a sustainability and economy point of view. Both 28and 360-day TGA results corroborate the strength results.      Table 3. Weight loss in paste mixtures at the age of 360 days.   Figures 8 and 9 show the pore size volume and surface area distribution with respect to pore radius, respectively, in control and DPA-based binary paste mixtures at the age of 28 days. Table 4 summarizes the pore size and surface area results. It can be observed that 100% OPC and 10% DPA pastes have similar total pore volume of about 0.046 mL/g. However, an increase in DPA content, up to 30%, will lead to an increase in the total pore volume, up to 0.063 mL/g. This is most likely due to the high compatibility between OPC particles and DPA dosage, up to 10%, that yields good packing effect, enabling high strength and low water permeability. Unexpectedly, the surface area of 100% OPC mix was minimum and it tended to increase with coarser DPA replacement level, which requires further investigation and correlation with other gas pycnometry and porosity techniques, like mercury intrusion porosimetry (MIP).     Figure 10 shows the X-ray diffractogram of 100% OPC and DPA-based binary paste binders. High amorphous and semi-crystalline structure was observed between the range of 15 and 40 degree 2-theta. The identified peaks in XRD spectrum included: (1) portlandite, (2) stratlingite, (3) quartz, (4) garronite, (5) Calcium Silicate Hydrate (C-S-H), (6) wollastonite, (7) hydrotalcite, and (8) Calcium Aluminosilicate Hydrate (C-A-S-H). As silica content in XRF results (Table 1)  3.6. X-ray Diffraction (XRD) Analysis Figure 10 shows the X-ray diffractogram of 100% OPC and DPA-based binary paste binders. High amorphous and semi-crystalline structure was observed between the range of 15 and 40 degree 2-theta. The identified peaks in XRD spectrum included: (1) portlandite, (2) stratlingite, (3) quartz, (4) garronite, (5) Calcium Silicate Hydrate (C-S-H), (6) wollastonite, (7) hydrotalcite, and (8) Calcium Aluminosilicate Hydrate (C-A-S-H). As silica content in XRF results (Table 1) increases with increase in DPA dosages, the quartz peaks in the binder becomes shorter, imparting the amorphousness. On contrary, the lime content is decreasing with increase in DPA content, leading to weak C-S-H, C-A-S-H gel, and phases like wollastonite and stratlingite in the hydrated matrices of binary binder, having more than 10% DPA. Thus, the role of calcium is more vital than silica in the formation of gel crystals and in the strength development of 100% OPC and 10% DPA-based mortar. Such finding was also reported in natural pozzolan, fly ash, and slag-based binders [17][18][19]. Other notable phases contributing to minor strength were identified as garronite and hydrotalcite, due to the presence of Mg and Al. S-H gel, and phases like wollastonite and stratlingite in the hydrated matrices of binary binder, having more than 10% DPA. Thus, the role of calcium is more vital than silica in the formation of gel crystals and in the strength development of 100% OPC and 10% DPA-based mortar. Such finding was also reported in natural pozzolan, fly ash, and slag-based binders [17][18][19]. Other notable phases contributing to minor strength were identified as garronite and hydrotalcite, due to the presence of Mg and Al.  Figure 11 displays the FT-IR spectrum of as received DPA and hydrated paste binders. As expected, significant change in molecular behavior occurred in paste samples, as compared to pure DPA after the hydraulic and pozzolanic reaction. Peaks between wavelength number 500-600 cm −1 Figure 10. XRD spectra of binders at 28 days. Phases at peak IDs: 1-portlandite, 2-stratlingite, 3-quartz, 4-garronite, 5-C-S-H, 6-wollastonite, 7-hydrotalcite, and 8-C-A-S-H. Figure 11 displays the FT-IR spectrum of as received DPA and hydrated paste binders. As expected, significant change in molecular behavior occurred in paste samples, as compared to pure DPA after the hydraulic and pozzolanic reaction. Peaks between wavelength number 500-600 cm −1 represents vibrating molecules of Si-O, and its capable of transforming the reactivity from raw DPA to the paste binders. Symmetric vibrating band at 690 cm −1 in pure DPA is due to Si-O-Al and Si-O-Si covalent bonds, which enables the formation of C-A-S-H gel in the paste binders [20]. Bending peak at 875 cm −1 corresponds to the carbonation band [21], which was shifted to lower bands in the form of double wavy peaks at 775-795 cm −1 . Presence of asymmetric band at 1430 cm −1 confirms the carbonation group in raw DPA [22]. This indicates that development of OPC-based binder significantly resists possibility of carbonation from the pure DPA. Symmetric band with medium intensity at 900-1100 cm −1 is a characteristic band that usually exists in Portland cement-based binder, and depends on the ratio of Si and Al in the form of Si-O-T (T = Si/Al) [23]. Stretching peaks at 1740 and 3385 cm −1 depict H-O-H bonds, due to interlayer water in the paste. These bands were not detected in the 100% OPC and 10% DPA-based binder, indicating that the mix water was completely utilized in the hydraulic and pozzolanic reaction, enabling these binders to achieve higher strengths. Such finding is in compliance with a study based on geopolymer binder [24].

Conclusions
The primary objective of this study was to investigate the effect of date palm ash (DPA) replacement levels into ordinary Portland cement (OPC). Representative fresh, mechanical and durability properties were carried out to establish the optimum DPA dosage. Analytical tests were conducted to study the reaction mechanism of DPA in the binary system. All test properties revealed that the 10% DPA and 90% OPC-based binder was optimum. However, up to 30% OPC could be beneficially replaced with DPA for reasonable strength and durability, as well as to cut the construction cost and enhance sustainability. Based on the experimental outcomes, the following conclusions can be drawn: 1. Flow decreased with increase in DPA dosage due to its coarser nature, as compared to OPC, while the flow was found to be within plastic range, up to 30% DPA content. 2. Compressive strength of mortar increased with DPA dosage, up to 10%, and thereafter was

Conclusions
The primary objective of this study was to investigate the effect of date palm ash (DPA) replacement levels into ordinary Portland cement (OPC). Representative fresh, mechanical and durability properties were carried out to establish the optimum DPA dosage. Analytical tests were conducted to study the reaction mechanism of DPA in the binary system. All test properties revealed that the 10% DPA and 90% OPC-based binder was optimum. However, up to 30% OPC could be beneficially replaced with DPA for reasonable strength and durability, as well as to cut the construction