Seawater-Neutralized Bauxite Residue–Polyester Composites as Insulating Construction Materials

: Bauxite residue (BR) is one of the most commonly generated industrial wastes in the world. Thus, novel techniques for its proper utilization must be urgently developed. Herein, seawater-neutralized BR–unsaturated polyester resin (UPR) composites are presented as insulating construction materials with promising mechanical performance. Composites with different BR content (0–60 vol.%) were prepared to evaluate the inﬂuence of BR content on the compressive, tensile, and ﬂexural strengths as well as the moduli of BR–UPR composites. Experimental results revealed that adding BR particles to the polyester matrix increased the compressive properties (strength, modulus, and strain). The composites containing 20 vol.% BR showed the maximum compressive strength (108 MPa), while the composites with 30 vol.% BR exhibited the maximum compressive modulus (1 GPa). Moreover, the reduction in tensile and ﬂexural strengths with an increase in the BR content may be attributed to the lower efﬁciency of stress transfer between the BR particle–polyester interface due to weak adhesion at the interface, direct contact between particles, and presence of voids or porosity. Although the tensile strength and failure stress decreased with increasing ﬁller content, the produced composites showed outstanding tensile strength (4.0–19.3 MPa) compared with conventional insulating materials. In addition, the composite with 40 vol.% BR demonstrated a ﬂexural strength of 15.5 MPa. Overall, BR–UPR composites showed excellent compatibility with promising mechanical properties as potential insulating construction materials.


Introduction
Exploring recycling alternatives is highly desired for industrial waste management. Several recycling procedures have been adopted through legislation or as a means of eliminating disposal costs and avoiding soil and water pollution. Recycling waste materials is an environmentally friendly step in the construction industry, where they can be reused as raw materials in engineering applications. Industrial waste often involves mostly inorganic ingredients, such as silicon, aluminum, calcium, and iron oxides, which are suitable for reuse in various applications [1].
Bauxite residue (BR) is a solid waste byproduct of the Bayer process of alumina production by alkaline extraction from bauxite ore [2]. Aluminum hydroxide precipitation from a pregnant sodium aluminate solution is described by the Bayer process, which involves the hydrothermal digestion of bauxite with caustic soda. To produce a sodium aluminate solution, aluminum hydroxides in bauxite are dissolved in NaOH [3,4]. BR is the residue formed by the insoluble fraction of bauxite and can be separated from the sodium aluminate solution using thickeners, filters, or a pressure decanter. BR is further thickened, washed, and filtered to recover alkalinity and the sodium aluminate used in the Bayer cycle to rise the solid residue fraction after aluminate solution is cooled down and seeded for the production of aluminum hydroxides [3]. BR contains five main oxides, i.e., SiO 2 , Fe2O 3 , of BR as raw materials in the construction industry fulfills these requirements. At a higher level, an EU-wide circular economy action plan proposed by the European Commission stresses the importance of getting secondary raw materials fed back into the economy and commits to formulating innovative industrial processes in which the waste generated in one industry is reused in another [12].
Modern materials can be developed to effectively contribute to BR management. For example, BR can be applied to composite fabrication to mitigate its environmental impact. Thus, cleaner production, sustainable development, and environmental safety can be accomplished [8]. Polymer composites fabricated using filler reinforcements are encouraging alternatives to conventional construction materials. Applying industrial wastes as fillers in polymer composites contributes to industrial waste management [13]. BR has been applied as a reinforcement filler in several material systems, such as in metal matrix fabrication [14], self-compacting concrete [15], geopolymer fabrication [16], and hybrid polymer composites [17]. These studies illustrate that considerable research has been conducted for evaluating the application prospects of BR [8].
However, there are a limited number of investigations showing that the addition of BR as a filler in polymer composites can improve their mechanical performance. Vigneshwaran et al. [8] showed that the increase in BR content (up to 20%) increases the tensile and impact strengths of a hybrid composite fabricated using BR as a filler and sisal fiber as the reinforcement in a polyester matrix. The composite demonstrated excellent resistance against crack development and propagation under tensile and impact loadings. Another study revealed that the addition of BR along with sisal and banana fiber-reinforced polyester composite enhanced impact and flexural strength, making it suitable for applications that require high load-bearing capacity [18]. An investigation by Ganeshan et al. [19] showed that the addition of BR to natural fiber-polyester composite considerably increased the flexural strengths of the polyester composites while decreasing their tensile strengths. In addition, the flexural strength of coir polyester composites increased upon addition of BR to a certain limit and then decreased [20].
This work aims to evaluate the utilization of the seawater-neutralized BR in the development of composite materials that can be used for thermal insulation and in construction applications. We have investigated the physical and thermal characteristics of seawater-neutralized BR-unsaturated polyester resin (BR-UPR) composites in our previous studies [21]. Due to the promising results obtained therein (Table 1), in this work, we aimed to study the mechanical properties of the developed BR-UPR composites. The successful production of the BR-based insulating materials will serve as a gateway for the utilization of the millions of tons of toxic waste available worldwide. Compared with other composites, the BR composites can be used as a thermal insulation material with promising mechanical properties, which is one of the main drawbacks associated with the traditional thermal insulators.

Material
Seawater-neutralized BR with particle size < 300 µm ( Figure 1) was obtained from Virotec Global Solutions (Arundel, Australia). It is commercially known as Bauxsol™, which is produced by treating the alkaline residue of the Bayer process with seawater, resulting in the conversion of soluble hydroxides and carbonates into less-soluble layered hydroxides, carbonates and hydroxyl carbonates of the base metals and producing a less-alkaline liquor that can be safely utilized.
studies [21]. Due to the promising results obtained therein (Table 1), in this work, we aimed to study the mechanical properties of the developed BR-UPR composites. The successful production of the BR-based insulating materials will serve as a gateway for the utilization of the millions of tons of toxic waste available worldwide. Compared with other composites, the BR composites can be used as a thermal insulation material with promising mechanical properties, which is one of the main drawbacks associated with the traditional thermal insulators.

Material
Seawater-neutralized BR with particle size < 300 µm ( Figure 1) was obtained from Virotec Global Solutions (Arundel, Australia). It is commercially known as Bauxsol™, which is produced by treating the alkaline residue of the Bayer process with seawater, resulting in the conversion of soluble hydroxides and carbonates into less-soluble layered hydroxides, carbonates and hydroxyl carbonates of the base metals and producing a lessalkaline liquor that can be safely utilized. The polyester, i.e., methyl ethyl ketone peroxide (MEKP), was obtained from Reichhold Norpol Company, Dubai (UAE). Special characteristics of the polyester used in this study include low water absorption, low cost, rapid curing with no gases evolved, and ease of handling. The polyester, i.e., methyl ethyl ketone peroxide (MEKP), was obtained from Reichhold Norpol Company, Dubai (UAE). Special characteristics of the polyester used in this study include low water absorption, low cost, rapid curing with no gases evolved, and ease of handling.

Composite Fabrication
BR-UPR composites with various BR contents (0-60 vol.%) were produced at room temperature using a high-viscosity mixer, see Table 2. The mixing conditions were as follows. A particular amount of BR was gradually added to the polyester mixture, and when the mixture became homogenous (after approximately 5 min), MEKP was added to the mixture for the thermosetting process. While the mixture was being prepared, the inner surface of three types of stainless-steel molds was coated with paraffin wax and polyvinyl acetate to prevent the sample from sticking to the mold. After that, the mixture was poured into the molds, which had specific shapes and sizes based on the ASTM standards to perform compression, tensile, and flexural strength tests on the prepared composites. Figure 2 illustrates the procedure of composite fabrication. The dumbbell-shaped tensile specimen had a total length of 100 mm, gauge length of 30 mm, and thickness of 4 mm, while the flexural specimen had a length of 75 mm, width of 14 mm, and thickness of 4 mm ( Figure 3). Three to six specimens of each BR content were fabricated. The produced specimens were then tested for compressive, tensile, and flexural strengths according to ASTM D695-15, ASTM D638-14, and ASTM D790 specifications, respectively. the mixture became homogenous (after approximately 5 min), MEKP was added mixture for the thermosetting process. While the mixture was being prepared, th surface of three types of stainless-steel molds was coated with paraffin wax and po acetate to prevent the sample from sticking to the mold. After that, the mixtu poured into the molds, which had specific shapes and sizes based on the ASTM sta to perform compression, tensile, and flexural strength tests on the prepared comp Figure 2 illustrates the procedure of composite fabrication. The dumbbell-shaped specimen had a total length of 100 mm, gauge length of 30 mm, and thickness of while the flexural specimen had a length of 75 mm, width of 14 mm, and thickne mm ( Figure 3). Three to six specimens of each BR content were fabricated. The pro specimens were then tested for compressive, tensile, and flexural strengths accor ASTM D695-15, ASTM D638-14, and ASTM D790 specifications, respectively.   (a) A particular amount of BR was gradually added to the UPR resin; (b) when the mixture became homogenous (after approximately 5 min), MEKP was added to the mixture for the thermosetting process (c) the inner surface of three types of stainless-steel molds was coated with paraffin wax (d) and polyvinyl acetate to prevent the sample from sticking to the mold; (e) the mixture was poured into the molds.

Mechanical Testing
Universal testing machines (MTS Model MH/20 with a load capacity of 100 kN) were used to perform compression tests. The samples were compressed between the upper (movable) and lower (fixed) plates of the instrument. The loading persisted either until

Mechanical Testing
Universal testing machines (MTS Model MH/20 with a load capacity of 100 kN) were used to perform compression tests. The samples were compressed between the upper (movable) and lower (fixed) plates of the instrument. The loading persisted either until specimen fracture occurred or a predetermined minimum value was reached for the gap between the upper and lower plates. Using the same compression test machine, both the tensile and flexural curves were obtained. The sample was placed between the movable and fixed jaws of the machine. The test proceeded until sample failure occurred. All tests were performed at room temperature with an overhead speed of 2 mm/min.

Characterization
The morphology and microstructure of the BR particles and BR-UPR composites were investigated via scanning electron microscopy (SEM, Quanta 200 with the Inica EDX system, Hillsboro, OR, USA). The elemental compositions of MEKP and BR-UPR composites were analyzed using energy-dispersive X-ray spectroscopy (EDX). To ensure conductivity, all samples were sputtered with gold and the images were collected at various resolutions.

Compression Properties
The compression test curves for the pure polyester and composite samples are shown in Figure 4, in which the x-axis represents strain and the y-axis represents stress. For the sake of contrast, the curve of pure unsaturated polyester is also included. Initially, stress increased as the strain increased. Then, strain softening occurred at strains between 8% and 15%. The minimum stress value obtained during strain softening was 34.4 MPa. Moreover, prior to failure at 65.2 MPa and 40% elongation, pure polyester experienced orientation hardening. The addition of BR to the polyester matrix typically decreased the orientation of the strain hardening of pure polyester. Table 3 reveals that the increase in BR content typically led to a decline in the elongation (strain%). However, the addition of BR (up to 30 vol.%) increased the elongation compared with that of pure polyester. This may be attributed to the proper transfer of stress with a slow propagation rate along the matrix as the filler (BR) content increases, thus causing the composite to break at a higher strain [22]. Additionally, this strain enhancement reflects higher BR homogeneity within the composite matrix as well as good interfacial adhesion between BR and the polyester matrix [23].
(up to 30 vol.%) increased the elongation compared with that of pure polyester. This m be attributed to the proper transfer of stress with a slow propagation rate along the mat as the filler (BR) content increases, thus causing the composite to break at a higher stra [22]. Additionally, this strain enhancement reflects higher BR homogeneity within t composite matrix as well as good interfacial adhesion between BR and the polyester m trix [23].  The effect of BR content on the compressive strength and modulus of the composites is shown in Figure 5. The maximum compressive strength (108.7 MPa) was reached at 20% BR. Initially, the adding of 10% BR reduced slightly the compressive strength of the composite which can attributed to the interfering of the filler in the crosslinking process of the UPR. The compressive strength of the polyester was 65.2 MPa, indicating that the presence of 20% BR increased the compressive strength by 66%. This improvement in compressive strength is due to the deposition of BR particles within the pores of the polymer matrix, which plug the pores within the polyester [24], and the presence of heavy mineral oxides in BR [8]. Above 20 vol.% BR, the compressive strength slightly decreased with the increase in BR vol.%. The poor interfacial bonds between the polyester and BR particles could be responsible for the slight decrease in the compressive strength of the composites above 20 vol.% BR, which in turn decreased the degree of crosslinking between BR and the polymer matrix [25].
which plug the pores within the polyester [24], and the presence of heavy mineral oxides in BR [8]. Above 20 vol.% BR, the compressive strength slightly decreased with the increase in BR vol.%. The poor interfacial bonds between the polyester and BR particles could be responsible for the slight decrease in the compressive strength of the composites above 20 vol.% BR, which in turn decreased the degree of crosslinking between BR and the polymer matrix [25]. Notably, the compressive strength at 20 vol.% BR was 108.7 MPa, and beyond that the compressive strengths of the prepared composites varied from 92.6 to 62.1 MPa for 30 and 60 vol.% BR, respectively. Nevertheless, Figure 6a shows that compared with other composites used in building walls, ceilings, and roofs, such as lightweight construction materials comprising cement, sand, and fibers of coconut and durian waste (2.4-3.3 MPa) the produced UPR-BR composites exhibited greater compressive strengths [26]. In addition, the compressive strength at 50 vol.% BR was 53.0 MPa, which is higher than that of 50 vol.% cement-rubber composite (10.5 MPa) reported by Benazzouk et al. [27]. Moreover, the compressive strength of the composite with 60 vol.% BR (62.1 MPa) is higher than the strength of the limestone-polyester composite (50 MPa) [28] and higher than the strength of sisal-cattail hybrid-reinforced polyester composites (25 MPa) [29]. It should be also mentioned that the UPR-BR composites showed greater compressive strength com- Notably, the compressive strength at 20 vol.% BR was 108.7 MPa, and beyond that, the compressive strengths of the prepared composites varied from 92.6 to 62.1 MPa for 30 and 60 vol.% BR, respectively. Nevertheless, Figure 6a shows that compared with other composites used in building walls, ceilings, and roofs, such as lightweight construction materials comprising cement, sand, and fibers of coconut and durian waste (2.4-3.3 MPa), the produced UPR-BR composites exhibited greater compressive strengths [26]. In addition, the compressive strength at 50 vol.% BR was 53.0 MPa, which is higher than that of 50 vol.% cement-rubber composite (10.5 MPa) reported by Benazzouk et al. [27]. Moreover, the compressive strength of the composite with 60 vol.% BR (62.1 MPa) is higher than the strength of the limestone-polyester composite (50 MPa) [28] and higher than the strength of sisal-cattail hybrid-reinforced polyester composites (25 MPa) [29]. It should be also mentioned that the UPR-BR composites showed greater compressive strength compared to the traditional insulation materials used currently in construction applications like expanded polystyrene (0.035-0.414 MPa), extruded polystyrene (0.104-0.690 MPa) and rigid cellular polyurethane (0.104-0.414 MPa) [30]. The addition of BR enhanced the compressive strength at a relatively high BR content (40 vol.%) compared with that of the pure polyester.
As can be seen from Figure 5, the trend for the composites is different from that of pure polyester. The overall enhancement in the failure stress value of the composites can be seen in Table 3. Moreover, the elastic modulus (E), which represents temporary deformation, increased with the increase in BR content up to 40 vol.% ( Figure 5). Compared with pure polyester, a 28% increase in the elastic modulus was achieved at 40 vol.% BR. The reason for this enhancement may be attributed to the fact that BR addition increases the aggregate volume of the mixture and consequently lowers the stiffness of the system [5].  As can be seen from Figure 5, the trend for the composites is different from that of pure polyester. The overall enhancement in the failure stress value of the composites can be seen in Table 3. Moreover, the elastic modulus (E), which represents temporary deformation, increased with the increase in BR content up to 40 vol.% ( Figure 5). Compared

Tensile Properties
The tensile stress-strain curves for the prepared samples of pure polyester and BR-UPR composites are shown in Figure 7. It can be seen that the stress value of pure polyester increases almost linearly with strain, particularly in the first part of the curve. Further, for pure polyester, the elongation at break is higher than those for the composites. In addition, with increasing filler content, the linear pattern of stress-strain variation in pure polyester does not change. However, the load-bearing capacity, fracture stress, and fracture strain are reduced. This is an anticipated development as BR content increases. The same behavior was noticed by Abu-Jdayil et al. [31] for polyester scrap tire composites. The addition of BR particles seems to allow cracks to propagate, leading to a reduction in composite toughness compared with pure polyester [18].
The effects of BR content on the tensile strength, failure stress, and modulus of the composites are shown in Figure 8. It can be seen that as the BR content increases, the tensile strengths and failure stresses of the unsaturated polyester composites decrease. The maximum failure stress and elastic modulus of the neat unsaturated polyester sample were 28.85 MPa and 0.944 GPa, respectively, whereas BR-reinforced polyester composites had lower failure stress values, as presented in Table 3 and Figure 8. However, a significant enhancement in the tensile modulus was observed upon the addition of BR. The reason for this improvement in the modulus of elasticity may be attributed to the fact that BR addition leads to an increase in aggregate volume in the mixture [5]. Moreover, the enhancement in tensile modulus could be due to the decrease in the viscosity of the composite with increasing BR content. Hence, fewer voids were likely produced during the fabrication process, which reduced the mechanical properties of the composites [23]. Figure 6b shows that the modulus of elasticity at 40 vol.% BR (1.2 GPa) is higher than or similar to the moduli of some polyester composites that have been studied for construction applications. For instance, Abu-Jdayil et al. [31] found that the moduli of elasticity at 40 vol.% fineand coarse-crumb rubbery/polyester composites were 0.16 and 0.063 GPa, respectively. Moreover, the maximum modulus of elasticity value of clay-polyester composites was reported to be 0.017 GPa, which is also lower than that of the BR-UPR composites [32]. Furthermore, it was found that the cement-stabilized base, which is the most used semirigid base material used in construction, has a modulus value of 1.36 GPa [33]. In addition, Okonkwo et al. [34] found that the modulus of elasticity for a polyester-clay-Bambara nut shell composite was 1.3 GPa.
Buildings 2021, 11, x FOR PEER REVIEW 9 of 1 with pure polyester, a 28% increase in the elastic modulus was achieved at 40 vol.% BR The reason for this enhancement may be attributed to the fact that BR addition increase the aggregate volume of the mixture and consequently lowers the stiffness of the system [5].

Tensile Properties
The tensile stress-strain curves for the prepared samples of pure polyester and BR UPR composites are shown in Figure 7. It can be seen that the stress value of pure polyes ter increases almost linearly with strain, particularly in the first part of the curve. Furthe for pure polyester, the elongation at break is higher than those for the composites. In ad dition, with increasing filler content, the linear pattern of stress-strain variation in pur polyester does not change. However, the load-bearing capacity, fracture stress, and frac ture strain are reduced. This is an anticipated development as BR content increases. Th same behavior was noticed by Abu-Jdayil et al. [31] for polyester scrap tire composite The addition of BR particles seems to allow cracks to propagate, leading to a reduction i composite toughness compared with pure polyester [18]. The effects of BR content on the tensile strength, failure stress, and modulus of th composites are shown in Figure 8. It can be seen that as the BR content increases, the ten sile strengths and failure stresses of the unsaturated polyester composites decrease. Th maximum failure stress and elastic modulus of the neat unsaturated polyester sampl were 28.85 MPa and 0.944 GPa, respectively, whereas BR-reinforced polyester composite had lower failure stress values, as presented in Table 3 and Figure 8. However, a signif cant enhancement in the tensile modulus was observed upon the addition of BR. The rea son for this improvement in the modulus of elasticity may be attributed to the fact that B addition leads to an increase in aggregate volume in the mixture [5]. Moreover, the en hancement in tensile modulus could be due to the decrease in the viscosity of the compo site with increasing BR content. Hence, fewer voids were likely produced during the fab rication process, which reduced the mechanical properties of the composites [23]. Figur 6b shows that the modulus of elasticity at 40 vol.% BR (1.2 GPa) is higher than or simila to the moduli of some polyester composites that have been studied for construction ap plications. For instance, Abu-Jdayil et al. [31] found that the moduli of elasticity at 40 vol.% fine-and coarse-crumb rubbery/polyester composites were 0.16 and 0.063 GPa, respec tively. Moreover, the maximum modulus of elasticity value of clay-polyester composite was reported to be 0.017 GPa, which is also lower than that of the BR-UPR composite The relatively higher values of tensile strength at lower BR content can be due to strong interfacial bonding, better filler dispersion in the matrix, and lack of voids or porosity. By contrast, the reduction in tensile strength with the increase in BR content may be attributed to the lower efficiency of stress transfer between the BR particle-polyester interface due to the weak adhesion force at the interface, direct contact between particles, and the presence of voids or porosity. These were confirmed by the SEM micrographs of 20 and 60 vol.% BR (Figure 9a,b, respectively); the BR particles were well embedded in the polyester matrix. Moreover, the degree of detachment between the filler particles and the polymer, which causes the formation of small voids or gaps, was at the minimum for 20 vol.% BR. This demonstrates the strong compatibility of BR particles with the polyester matrix reflected by the significant enhancement in tensile strength at 20 vol.% BR compared with that at 60 vol.% BR. SEM images show some kind of particles agglomeration that is expected to increase with increasing filler content. semirigid base material used in construction, has a modulus value of 1.36 GPa [33]. In addition, Okonkwo et al. [34] found that the modulus of elasticity for a polyester-clay-Bambara nut shell composite was 1.3 GPa. The relatively higher values of tensile strength at lower BR content can be due to strong interfacial bonding, better filler dispersion in the matrix, and lack of voids or porosity. By contrast, the reduction in tensile strength with the increase in BR content may be attributed to the lower efficiency of stress transfer between the BR particle-polyester interface due to the weak adhesion force at the interface, direct contact between particles, and the presence of voids or porosity. These were confirmed by the SEM micrographs of 20 and 60 vol.% BR (Figure 9a,b, respectively); the BR particles were well embedded in the polyester matrix. Moreover, the degree of detachment between the filler particles and the polymer, which causes the formation of small voids or gaps, was at the minimum for 20 vol.% BR. This demonstrates the strong compatibility of BR particles with the polyester matrix reflected by the significant enhancement in tensile strength at 20 vol.% BR compared with that at 60 vol.% BR. SEM images show some kind of particles agglomeration that is expected to increase with increasing filler content.  The relatively higher values of tensile strength at lower BR content can be due to strong interfacial bonding, better filler dispersion in the matrix, and lack of voids or porosity. By contrast, the reduction in tensile strength with the increase in BR content may be attributed to the lower efficiency of stress transfer between the BR particle-polyester interface due to the weak adhesion force at the interface, direct contact between particles, and the presence of voids or porosity. These were confirmed by the SEM micrographs of 20 and 60 vol.% BR (Figure 9a,b, respectively); the BR particles were well embedded in the polyester matrix. Moreover, the degree of detachment between the filler particles and the polymer, which causes the formation of small voids or gaps, was at the minimum for 20 vol.% BR. This demonstrates the strong compatibility of BR particles with the polyester matrix reflected by the significant enhancement in tensile strength at 20 vol.% BR compared with that at 60 vol.% BR. SEM images show some kind of particles agglomeration that is expected to increase with increasing filler content. Although the tensile strength and failure stress decreased with increasing filler content, the produced composites showed outstanding tensile strengths (4.0-19.3 MPa) compared with currently used insulating materials. The reported tensile strengths for foam glass, mineral fibers, and polystyrene are 0.689, 0.069, and 0.310 MPa, respectively [35]. Moreover, Abu-Jdayil et al. [31] reported tensile strength values of 4.35 and 1.25 MPa for 40 vol.% fine-and coarse-crumb rubber-polyester composites, respectively. In addition, the tensile strength value (13.07 MPa) of the 20 vol.% BR-UPR composite is higher than that (0.4 MPa) of the 20% BR lightweight concrete reported by Nikbin et al. (2018) [5]. Moreover, the tensile strength (19.3 MPa) of 10 vol.% BR-UPR is higher than that (17.5 MPa) of the hemp fiber-reinforced polyester composite reported by Neves et al. [36] (Figure 6c). The same trend can be noticed in Figure 7, where the strain decreased with increasing BR content. This strain (or elongation) decrease could be due to the defects generated by the addition of BR, which was not well distributed throughout the polyester matrix. Figure 10 shows the flexural stress-strain curves for the prepared pure polyester and BR-UPR composites. Table 3 reveals that the elongation at break (strain%) for pure polyester is higher than those for the BR-UPR composites. In addition, the results indicate that the load-bearing capacity, fracture stress, and fracture strain typically decrease with increasing BR content. As shown in Figure 10, the increase in BR content decreases the composite flexural strength. The same behavior was observed by Ohama et al. [37]. However, up to 30 vol.% BR, the flexural strength exhibited almost a constant value of 24 MPa. The addition of BR particles seems to allow cracks to propagate, resulting in such reduction in the composite toughness compared with that of pure polyester [37]. Nevertheless, as Figure 6d shows, the presented composites with the maximum flexure strength (24 MPa) performed better than other types of composites, such as sisal-jute-glass-fiber-reinforced polyester composite, which had a maximum flexural strength of 13 MPa as reported by Tang [38]. ure 6c). The same trend can be noticed in Figure 7, where the strain decreased with increasing BR content. This strain (or elongation) decrease could be due to the defects generated by the addition of BR, which was not well distributed throughout the polyester matrix. Figure 10 shows the flexural stress-strain curves for the prepared pure polyester and BR-UPR composites. Table 3 reveals that the elongation at break (strain%) for pure polyester is higher than those for the BR-UPR composites. In addition, the results indicate that the load-bearing capacity, fracture stress, and fracture strain typically decrease with increasing BR content. As shown in Figure 10, the increase in BR content decreases the composite flexural strength. The same behavior was observed by Ohama et al. [37]. However, up to 30 vol.% BR, the flexural strength exhibited almost a constant value of 24 MPa. The addition of BR particles seems to allow cracks to propagate, resulting in such reduction in the composite toughness compared with that of pure polyester [37]. Nevertheless, as Figure 6d shows, the presented composites with the maximum flexure strength (24 MPa) performed better than other types of composites, such as sisal-jute-glass-fiber-reinforced polyester composite, which had a maximum flexural strength of 13 MPa as reported by Tang [38]. The results in Figure 11 show that adding BR to the composites results in increased modulus or stiffness compared with those of neat unsaturated polyester, as reported by Zainudin et al. [39] and Tang [38]. Nikbin et al. [5] showed the same trend for flexural The results in Figure 11 show that adding BR to the composites results in increased modulus or stiffness compared with those of neat unsaturated polyester, as reported by Zainudin et al. [39] and Tang [38]. Nikbin et al. [5] showed the same trend for flexural strength with increased BR content as cement replacement. This behavior could be due to the inclusion of BR, which increased the rigidity of the materials [40].  Table 4 show the surface compositions of the polyester and BR-UPR composites characterized by EDX. Figure 12a shows that the highest content is that of carbon (C), followed by oxygen (O), in addition to trace amounts of magnesium (Mg) and calcium (Ca). For the BR-UPR composite (Figure 12b), the C and O contents are the highest. As can be observed from Figure 12b and Table 3, besides Mg and a lot of C, O, considerable amounts of iron (Fe), aluminum (Al), silicon (Si), and sodium (Na) were present upon addition of 40 vol.% BR. Fe and Si tended to reduce the fracture surfaces and thereby enhance the material strength [41], which was confirmed by the higher compressive strength of the 40 vol.% BR-UPR composite (74.7 MPa) compared with that of pure polyester (65.2 MPa). strength with increased BR content as cement replacement. This behavior could be due to the inclusion of BR, which increased the rigidity of the materials [40].  Table 4 show the surface compositions of the polyester and BR-UPR composites characterized by EDX. Figure 12a shows that the highest content is that of carbon (C), followed by oxygen (O), in addition to trace amounts of magnesium (Mg) and calcium (Ca). For the BR-UPR composite (Figure 12b), the C and O contents are the highest. As can be observed from Figure 12b and Table 3, besides Mg and a lot of C, O, considerable amounts of iron (Fe), aluminum (Al), silicon (Si), and sodium (Na) were present upon addition of 40 vol.% BR. Fe and Si tended to reduce the fracture surfaces and thereby enhance the material strength [41], which was confirmed by the higher compressive strength of the 40 vol.% BR-UPR composite (74.7 MPa) compared with that of pure polyester (65.2 MPa).   Figure 12a,b and Table 4 show the surface compositions of the polyester and BR-UPR composites characterized by EDX. Figure 12a shows that the highest content is that of carbon (C), followed by oxygen (O), in addition to trace amounts of magnesium (Mg) and calcium (Ca). For the BR-UPR composite (Figure 12b), the C and O contents are the highest. As can be observed from Figure 12b and Table 3, besides Mg and a lot of C, O, considerable amounts of iron (Fe), aluminum (Al), silicon (Si), and sodium (Na) were present upon addition of 40 vol.% BR. Fe and Si tended to reduce the fracture surfaces and thereby enhance the material strength [41], which was confirmed by the higher compressive strength of the 40 vol.% BR-UPR composite (74.7 MPa) compared with that of pure polyester (65.2 MPa).

Conclusions
The mechanical test results of BR-UPR composites revealed that the addition of BR improved the compressive properties (strength, strain, and modulus) of the prepared composites. In addition, the tensile and flexural moduli exhibited significant enhancement upon the incorporation of BR in the UPR matrix. The presence of BR up to 20 vol.% increased the compressive strength of the produced composites by 67% compared with that of pure polyester. In addition to the compressive strength enhancement, the increase in strain was also observed and increased the compression toughness. This improvement in compressive strength is due to the deposition of BR particles within the pores of the polymer matrix, which plugs the pores within the polyester. EDX analysis revealed that Fe and Si tend to reduce the fracture surfaces and hence enhance the material strength [41], which was confirmed by the higher compressive strength of 40 vol.% BR (74.7 MPa) compared to that of the polyester (65.2 MPa). Moreover, the elastic modulus, E, that represents the temporary deformation of the substance generally increased in compressive as well as tensile testing with filler contents increasing up to 40 and 60 vol.%, respectively. The reason for this enhancement in the modulus of elasticity may be attributed to the fact that BR addition increased the aggregate volume of the mixture and consequently lowered the stiffness of the system. In contrast, the reduction in tensile and flexural strengths as the BR content increases may be attributed to the lower efficiency of stress transfer between the BR particle-polyester interface due to the weak adhesion force at the interface, direct contact between particles, and presence of void or porosity. Nevertheless, it is important to note that although the tensile strength/failure stress decreased with increasing filler content, the produced composites exhibited outstanding tensile strengths compared with currently used insulating materials. In addition, the presented composites with a maximum flexural strength of 24 MPa performed well compared with other polyester-based composites. Moreover, incorporating BR (up to 30 vol.%) with UPR increased the flexure modulus and stiffness of the BR-UPR composites compared with those of the neat unsaturated polyester owing to the insertion of BR, which increased the rigidity of the materials. Overall, the produced BR-UPR composites showed great potential for use in construction applications. The energy-saving potential of the composites can help to realize sustainable development in the field. Funding: This work was supported by the Research Unit at the United Arab Emirates University (grant number SURE 31N242) and by the National Water and Energy Center at the UAE University (grant numbers 31R163).

Data Availability Statement:
The data presented in this study are available on request from the corresponding author.

Conflicts of Interest:
The authors declare no conflict of interest.