Grain Refinement Mechanism of the As-Cast and As-Extruded Mg – 14 Li Alloys with Al or Sn Addition

The microstructures of the as-cast and as-extruded Mg–14 wt. % Li–1 wt. % Al (LA141) and Mg–14 wt. % Li–2 wt. % Sn (LT142) were observed by optical and scanning electron microscope (SEM), X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The effects of Al and Sn on the grain refinement on the Mg–14Li alloy were investigated. In addition, the mechanism of grain refinement on the as-cast and as-extruded alloys was discussed from the view of the solute effect and heterogeneous nucleation effect via edge-to-edge matching model. The results showed that the average grain sizes of the as-cast LA141 and LT142 alloys were similar due to the close solute effect of 1.1 wt. % Al and 1.8 wt. % Sn, while, in the as-extruded alloys, the average grain size of LT142 was over two times finer than that of LA141. This was attributed to the reason that Li2MgSn particles can serve as heterogeneous nucleation sites for the β-Li matrix during the process of dynamic recrystallization (DRX), but LiMgAl2 cannot serve the same way. Therefore, Sn can act as a more effective grain refiner for the Mg–14Li alloy compared to Al.


Introduction
Conventional Mg alloys, such as AZ31, AZ61, and ZK60, exhibited poor formability at room temperatures, which was caused by the limited number of active slip systems in the hexagonal close-packed (HCP) structures [1,2].Compared to the Mg alloys with an HCP structure, the alloys with a body-centered cubic (BCC) structure have more active slip planes and slip directions [3].
The lithium (Li) additions to Mg alloys cause the transformation of the crystal structure.After Li contents increase to 5.5 wt.%, a β-Li phase with BCC structure appear.Then, with the increase of the Li contents, the proportion of the β-Li phase in Mg-Li alloy increases.When Li content is beyond 10.5 wt.%, the phase composition in the Mg-Li alloy will be the single β-Li phase [4,5].BCC structure possesses much more available slip systems, and the cubic Mg alloys are less prone to develop disadvantageous deformed textures [6].Therefore, the Mg-Li alloys with the Li contents beyond 10.5 wt.% exhibited excellent formability and ductility or even super-plasticity [7][8][9].However, the binary Mg-Li alloys cannot meet the industrial strength requirements [10].The addition of alloying elements to Mg-Li alloys was considered as an effective method to improve the strength of Mg-Li alloys due to its easy operation and cost-saving [11][12][13].
In recent years, the Mg-14Li-1Al (LA141) alloy was developed as a commercial alloy due to its low density and good plasticity [14][15][16].The addition of Al could refine the grains of the Mg-Li alloys.The Li 2 MgAl particles, precipitating from the LA141 molten alloy, could strengthen the β-phase matrix in the Mg-Li-Al system [17].However, Li 2 MgAl was metastable and would be decomposed at 66 • C or even at room temperature [14].Therefore, ideal candidates need to be explored for the improvement of the Mg-14Li alloys.
Many researchers have found that Sn was a favorable element for addition to Mg-Li alloys.With Sn addition to Mg-Li alloys, the lamellar Mg 2 Sn presented in the dendritic crystal boundary and a tiny granular Mg 2 Sn existed inside the grains, resulting in the significant refinement of the secondary dendrite arm spacing of the α-Mg phase [18][19][20].Furthermore, Zeng et al. [21] and Yin et al. [22] have studied the effect of Sn on the grain refinement of Mg-Li alloys.It was found that the precipitates Mg 2 Sn or Li 2 MgSn could act as heterogeneous nucleation sites for the Mg matrix in the process of solidification, leading to a grain refinement in Mg-Li alloys.Nevertheless, the specific refinement mechanism of Sn on Mg-14Li alloys, especially on the as-extruded Mg-14Li alloys, was rarely covered in those studies.
In this work, Al and Sn were added into the Mg-14Li alloy followed by extrusion to investigate the effect of Al and Sn addition on the grain refinement of the as-cast and as-extruded Mg-14Li alloy.As part of the rssearch on Mg-Li based alloys in our study [15,23], this paper aims to explore the different grain refinement effect, which was raised by different intermetallics (Li 2 MgSn and LiMgAl 2 ) in β-based Mg-Li alloys.Meanwhile, the distinctions of grain refinement mechanism between the as-cast and as-extruded alloys were also discussed.

Materials and Methods
The raw materials used in preparing the Mg-14 wt.% Li-1 wt.% Al (LA141) and Mg-14 wt.% Li-2 wt.% Sn (LT142) alloys were commercial pure magnesium (99.9 wt.%), pure lithium (99.9 wt.%), pure aluminum (99.9 wt.%), and high pure tin (99.99 wt.%).For LA141 alloy, before being melting, the pure Mg, pure Li and pure Al metals were put into a stainless steel crucible (90 mm in diameter, 250 mm in height, Jinfa Stainless Steel, Chongqing, China), placing in an induction furnace (Yuantong Power Apparatus Ltd., Jinzhou, China).Then, the materials were heated to 700 • C under a protective atmosphere of pure argon.After isothermal holding for 10 min, the crucible with the melt was cooled in the furnace under the argon atmosphere, and an LA141 cast ingot was obtained.The LT142 alloy was prepared under the same conditions.Before the extrusion, the cylindrical cast ingots were homogenized at 250 • C for 8 h with air-cooling, followed by milling to remove the oxide layer and casting defects on the surface.Then, the ingots were extruded at 250 • C with an extrusion ratio of 28 and an extrusion speed of 20 mm•s −1 .Finally, the extruded bars with a diameter of 16 mm were obtained.In our whole study, other alloys with different Al and Sn contents were also prepared.However, in this study, two specific alloys of LA141 and LT142 were chosen for discussion due to their meaningful observed results.
The compositions of the studied alloys were measured by inductively coupled plasma atomic emission spectroscopy (ICP-AES), and the measured compositions of the LA141 and LT142 alloys were Mg-14.3Li-1.1Aland Mg-14.4Li-1.8Sn,respectively.All the samples used in the following characterization were cut from the center of the ingots or extruded bars.The optical microscopy and scanning electron microscopy (SEM, TESCAN VEGA 3LMH, BrNo, Czech Republic) were applied to characterize the microstructures after etching by picric acid solution (5 g picric, 10 mL acetic acid, 100 mL ethanol and 10 mL distilled water).The differential scanning calorimetry (DSC) of NETZSCH STA 449C system (NETZSCH, Selb, Germany) was used to analyze the solidification behavior of the experimental alloys.The as-cast samples for DSC measurement were heated from 20 to 700 • C at a rate of 5 • C•min −1 .The grain size was measured by the linear intercept method at the center of the transverse sections.The phases of the alloys were identified by X-ray diffraction (XRD, Rigaku D/MAX-2500PC, Rigaku Corporation, Tokyo, Japan) by a Cu Kα radiation (λ = 1.5418Ǻ) operating at the speed of 4 • /min and a 2θ ranging from 10 • to 90 • .

Results
The average grain size of the typical as-cast Mg-14Li alloy was ~784 µm [24].After adding Al or Sn to the Mg-14Li alloy, as shown in Figure 1a,b, the grain size decreases to 591 and 608 µm, respectively.The similar decrease rate of grain sizes in the LA141 and LT142 alloys implies that the effect of 1.1 wt.% Al and 1.8 wt.% Sn on the grain refinement in the as-cast Mg-14Li might be similar.However, after extrusion, the grains of the as-extruded LT142 alloy appear to be much finer than those of the LA141 alloy.As shown in Figure 1c,d, the average grain sizes of the as-extruded LA141 and LT142 alloys are 64.2 and 29.8 µm, respectively.

Results
The average grain size of the typical as-cast Mg-14Li alloy was ~784 μm [24].After adding Al or Sn to the Mg-14Li alloy, as shown in Figure 1a,b, the grain size decreases to 591 and 608 μm, respectively.The similar decrease rate of grain sizes in the LA141 and LT142 alloys implies that the effect of 1.1 wt.% Al and 1.8 wt.% Sn on the grain refinement in the as-cast Mg-14Li might be similar.However, after extrusion, the grains of the as-extruded LT142 alloy appear to be much finer than those of the LA141 alloy.As shown in Figure 1c,d, the average grain sizes of the as-extruded LA141 and LT142 alloys are 64.2 and 29.8 μm, respectively.According to the binary Mg-Li phase diagram, the microstructures of Mg-14 wt.% Li alloy at room temperature mainly consists of β-Li [25].Figure 2 demonstrates the XRD patterns taken from the as-cast alloys.It is shown that Li2MgSn or LiMgAl2 phases are formed with the addition of Al or Sn.It was reported that Li2MgAl precipitated from the matrix during the solidification process in the LA141 alloy [26].However, in our study, the LiMgAl2 peaks were indexed in LA141 alloy.This can be attributed to the reason that Li2MgAl phase was metastable and easy to resolve to Li2MgAl or AlLi phases [14].Moreover, Sn can also be found in the LT142 alloy due to its low solubility in β-Li.Figure 3 shows the SEM images of the as-cast and as-extruded alloys.The phase compositions were analyzed with EDS and marked in the SEM images.As shown in Figure 3a, in the as-cast LA141 alloy, the granular LiMgAl2 phases are distributed in the matrix, while, in the as-cast LT142 alloy, as According to the binary Mg-Li phase diagram, the microstructures of Mg-14 wt.% Li alloy at room temperature mainly consists of β-Li [25].Figure 2 demonstrates the XRD patterns taken from the as-cast alloys.It is shown that Li 2 MgSn or LiMgAl 2 phases are formed with the addition of Al or Sn.It was reported that Li 2 MgAl precipitated from the matrix during the solidification process in the LA141 alloy [26].However, in our study, the LiMgAl 2 peaks were indexed in LA141 alloy.This can be attributed to the reason that Li 2 MgAl phase was metastable and easy to resolve to Li 2 MgAl or AlLi phases [14].Moreover, Sn can also be found in the LT142 alloy due to its low solubility in β-Li.

Results
The average grain size of the typical as-cast Mg-14Li alloy was ~784 μm [24].After adding Al or Sn to the Mg-14Li alloy, as shown in Figure 1a,b, the grain size decreases to 591 and 608 μm, respectively.The similar decrease rate of grain sizes in the LA141 and LT142 alloys implies that the effect of 1.1 wt.% Al and 1.8 wt.% Sn on the grain refinement in the as-cast Mg-14Li might be similar.However, after extrusion, the grains of the as-extruded LT142 alloy appear to be much finer than those of the LA141 alloy.As shown in Figure 1c,d, the average grain sizes of the as-extruded LA141 and LT142 alloys are 64.2 and 29.8 μm, respectively.According to the binary Mg-Li phase diagram, the microstructures of Mg-14 wt.% Li alloy at room temperature mainly consists of β-Li [25].Figure 2 demonstrates the XRD patterns taken from the as-cast alloys.It is shown that Li2MgSn or LiMgAl2 phases are formed with the addition of Al or Sn.It was reported that Li2MgAl precipitated from the matrix during the solidification process in the LA141 alloy [26].However, in our study, the LiMgAl2 peaks were indexed in LA141 alloy.This can be attributed to the reason that Li2MgAl phase was metastable and easy to resolve to Li2MgAl or AlLi phases [14].Moreover, Sn can also be found in the LT142 alloy due to its low solubility in β-Li.Figure 3 shows the SEM images of the as-cast and as-extruded alloys.The phase compositions were analyzed with EDS and marked in the SEM images.As shown in Figure 3a, in the as-cast LA141 alloy, the granular LiMgAl2 phases are distributed in the matrix, while, in the as-cast LT142 alloy, as Figure 3 shows the SEM images of the as-cast and as-extruded alloys.The phase compositions were analyzed with EDS and marked in the SEM images.As shown in Figure 3a, in the as-cast LA141 alloy, the granular LiMgAl 2 phases are distributed in the matrix, while, in the as-cast LT142 alloy, as depicted in Figure 3b, the lamellar Li 2 MgSn phases are mainly located at the grain boundaries.After extrusion, as demonstrated in Figure 3c,d, intermetallics both in the LA141 or LT142 alloys are well distributed in the matrix with a granular structure.It was reported that the wetting transitions of second phase particles with the grain boundaries contributed to the morphologic and distributed transitions [27,28].Therefore, it can be speculated that the different morphology and distribution of precipitates in LA141 and LT142 alloys, as shown in Figure 3, was caused by the different wetting effect of LiMgAl 2 and Li 2 MgSn with the grain boundaries.
Metals 2017, 7, 172 4 of 9 depicted in Figure 3b, the lamellar Li2MgSn phases are mainly located at the grain boundaries.After extrusion, as demonstrated in Figure 3c,d, intermetallics both in the LA141 or LT142 alloys are well distributed in the matrix with a granular structure.It was reported that the wetting transitions of second phase particles with the grain boundaries contributed to the morphologic and distributed transitions [27,28].Therefore, it can be speculated that the different morphology and distribution of precipitates in LA141 and LT142 alloys, as shown in Figure 3, was caused by the different wetting effect of LiMgAl2 and Li2MgSn with the grain boundaries.

Discussion
Easton et al. [29,30] and Fu et al. [31] studied the grain refinement of the alloying in metallic materials and found that the grain refinement was mainly related to two factors.One is the segregation power of the solute elements, defining as the solute effect, and the other is the heterogeneous nucleation effect.

Mechanism of Grain Refinement in the As-Cast Alloys
To figure out which factor dominates the refinement in the as-cast alloys, the solidification route should be analyzed at first.DSC curves are obtained to reflect the formation temperature of each phase in the solidification process.As shown in Figure 4a, at the beginning of the solidification of the LA141 alloy, β-Li phase forms preferentially from the melted alloy at a temperature of 600 °C.The phase analysis results, as shown in Figures 2 and 3, indicated that MgLiAl2 existed in the LA141 alloy.Thus, after the formation of the β-Li matrix, MgLiAl2 phase precipitates at 385 °C.Then, the melt continues cooling until complete solidification.Therefore, the solidification path of the LA141 alloy is depicted as follows: Liquid → (600 °C) β-Li phase → (385 °C) LiMgAl2.
Similarly, the solidification path of the LT142 alloy is determined: Liquid → (600 °C) β-Li phase → (362 °C) Li2MgSn.The solidification process of the LA141 and LT142 alloys indicates that the formation temperature of the intermetallics (LiMgAl2 and Li2MgSn) is lower than that of the β-Li matrix.It means that these intermetallics cannot be the heterogeneous nucleation sites for the matrix.Thus, the mechanism of grain refinement in the as-cast alloys might be dominated by the solute effect.

Discussion
Easton et al. [29,30] and Fu et al. [31] studied the grain refinement of the alloying in metallic materials and found that the grain refinement was mainly related two factors.One is the segregation power of the solute elements, defining as the solute effect, and the other is the heterogeneous nucleation effect.

Mechanism of Grain Refinement in the As-Cast Alloys
To figure out which factor dominates the refinement in the as-cast alloys, the solidification route should be analyzed at first.DSC curves are obtained to reflect the formation temperature of each phase in the solidification process.As shown in Figure 4a, at the beginning of the solidification of the LA141 alloy, β-Li phase forms preferentially from the melted alloy at a temperature of 600 • C. The phase analysis results, as shown in Figures 2 and 3, indicated that MgLiAl 2 existed in the LA141 alloy.Thus, after the formation of the β-Li matrix, MgLiAl 2 phase precipitates at 385 • C.Then, the melt continues cooling until complete solidification.Therefore, the solidification path of the LA141 alloy is depicted as follows: Liquid → (600 Greer et al. [32,33] suggested that the final grain size and phase structure was determined by the nucleation and growth conditions prevailing during phase transformation.The solute effect raised by alloying elements was often quantified by the growth restriction factor (GRF) and is defined as [29,30]: where mi denotes the liquid gradient of the binary phase diagram, co,i is the solid original content, and ki is the solute distribution coefficient [3].A solute with a higher value of GRF is expected to have a stronger grain growth restriction impact.
Combining Equation ( 1) with the Li-Al (Sn) phase diagram [25], the per unit GRF values of Al and Sn in Li can be calculated, and they are 6.2 and 4.3, respectively.It can be seen that the contents of Sn is 1.5 times more than that of Al, while the GRF value of Al is 1.6 times higher than that of Sn.Therefore, the grain growth restriction impact between the 1.1 wt.% Al and 1.8 wt.% Sn in Li should be close, which leads to the similar grain sizes of the as-cast LA141 and LT142 alloys, as confirmed in Figure 1a,b.From the above analysis, it can be deduced that the main reason of grain refinement in the solidification process of the LA141 and LT142 alloys should be the solute effect of Al and Sn in the melted alloys.

Mechanism of Grain Refinement in the As-Extruded Alloys
Both the grains in the LA141 and LT142 alloys were gained refinement after extrusion, as shown in Figure 1.It was known that this refinement was due to the effect of dynamic recrystallization (DRX) during the extrusion process [34].However, the grains in the as-extruded LT142 were two times finer than those in LA141.Classical theory about the particle stimulated nucleation suggested that particles which do not deform will produce additional strain in the surrounding matrix and thus generate a fine dense substructure suitable for nucleation, stimulating the nucleation of DRX in metal alloys [35,36].Besides, Zhang et al. [37][38][39] raised an edge-to-edge matching model for the heterogeneous nucleation effect in metal alloys.It was speculated that the particles, which have a good crystallographic relationship with the matrix, are most likely to serve as the nucleation sites for the matrix in the DRX process.According to this model, the particles with a proper size and the lowest mismatch with the metal matrix tend to serve as the nucleation sites for the metal matrix during the solidification process or dynamic recrystallization.From the perspective of quantification, if the particles can act as the grain refiner for the matrix, there should be at least one pair of close-packed atomic rows.The close-packed atomic rows were defined as matching rows, whose interatomic spacing misfit (fr) is less than 10% between this pair rows.In addition, the matching rows should be contained in at least one pair of close-packed planes, defined as matching planes, with interplanar spacings (d-values) showing a mismatch (fd) of less than 10%, while the strict critical value is 6%.
Therefore, the key point to understand the grain refinement mehanism of Al or Sn addition on the as-extruded Mg-14Li alloy is to identify the matching planes and matching directions of the Similarly, the solidification path of the LT142 alloy is determined: Liquid → (600 • C) β-Li phase → (362 • C) Li 2 MgSn.The solidification process of the LA141 and LT142 alloys indicates that the formation temperature of the intermetallics (LiMgAl 2 and Li 2 MgSn) is lower than that of the β-Li matrix.It means that these intermetallics cannot be the heterogeneous nucleation sites for the matrix.Thus, the mechanism of grain refinement in the as-cast alloys might be dominated by the solute effect.
Greer et al. [32,33] suggested that the final grain size and phase structure was determined by the nucleation and growth conditions prevailing during phase transformation.The solute effect raised by alloying elements was often quantified by the growth restriction factor (GRF) and is defined as [29,30]: where m i denotes the liquid gradient of the binary phase diagram, c o,i is the solid original content, and k i is the solute distribution coefficient [3].A solute with a higher value of GRF is expected to have a stronger grain growth restriction impact.
Combining Equation ( 1) with the Li-Al (Sn) phase diagram [25], the per unit GRF values of Al and Sn in Li can be calculated, and they are 6.2 and 4.3, respectively.It can be seen that the contents of Sn is 1.5 times more than that of Al, while the GRF value of Al is 1.6 times higher than that of Sn.Therefore, the grain growth restriction impact between the 1.1 wt.% Al and 1.8 wt.% Sn in Li should be close, which leads to the similar grain sizes of the as-cast LA141 and LT142 alloys, as confirmed in Figure 1a,b.From the above analysis, it can be deduced that the main reason of grain refinement in the solidification process of the LA141 and LT142 alloys should be the solute effect of Al and Sn in the melted alloys.

Mechanism of Grain Refinement in the As-Extruded Alloys
Both the grains in the LA141 and LT142 alloys were gained refinement after extrusion, as shown in Figure 1.It was known that this refinement was due to the effect of dynamic recrystallization (DRX) during the extrusion process [34].However, the grains in the as-extruded LT142 were two times finer than those in LA141.Classical theory about the particle stimulated nucleation suggested that particles which do not deform will produce additional strain in the surrounding matrix and thus generate a fine dense substructure suitable for nucleation, stimulating the nucleation of DRX in metal alloys [35,36].Besides, Zhang et al. [37][38][39] raised an edge-to-edge matching model for the heterogeneous nucleation effect in metal alloys.It was speculated that the particles, which have a good crystallographic relationship with the matrix, are most likely to serve as the nucleation sites for the matrix in the DRX process.According to this model, the particles with a proper size and the lowest mismatch with the metal matrix tend to serve as the nucleation sites for the metal matrix during the solidification process or dynamic recrystallization.From the perspective of quantification, if the particles can act as the grain refiner for the matrix, there should be at least one pair of close-packed atomic rows.The close-packed atomic rows were defined as matching rows, whose interatomic spacing misfit (f r ) is less than 10% between this pair rows.In addition, the matching rows should be contained in at least one pair of close-packed planes, defined as matching planes, with interplanar spacings (d-values) showing a mismatch (f d ) of less than 10%, while the strict critical value is 6%.
Therefore, the key point to understand the grain refinement mehanism of Al or Sn addition on the as-extruded Mg-14Li alloy is to identify the matching planes and matching directions of the intermetallics and the matrix.That is, in the LiMgAl 2 /Li 2 MgSn and Li system, the r-value misfit along that direction and the d-value mismatch of the matching planes should be calculated firstly [30].
For the LiMgAl 2 and Li matrix system, according to the crystallographic database and X-ray powder diffraction data [40], the crystal structure of LiMgAl 2 is face-centered cubic (FCC).Its three close packed planes are the {660}, {422} and {511} planes, while those of Li are the {110}, {211} and {200} planes.The f d values between LiMgAl 2 and the Li matrix can be calculated [23], and the possible values are listed in Table 1.Through this table, it can be seen that all the f d values of the matching planes are beyond the critical value of 6%, which means this particle is nearly impossible to be the heterogeneous nucleation site for the β-Li phase.
Table 1.Interplanar spacing mismatch (f d ) (%) along the possible matching planes between the intermetallics and Li matrix.Some pairs of close-packed planes are ignored because their f d are beyond 100%.

Intermetallics
The Mismatch between the Intermetallics and Matrix (%) As for the Li 2 MgSn and Li matrix system, Li 2 MgSn possesses a BCC structure, and its close packed planes are {111}, {220}, and {751}.Analogously, the f d values between Li 2 MgSn and the Li matrix can be obtained, and the possible matching planes of Li matrix and Li 2 MgSn are {110} β−Li /{220} Li 2 MgSn , as indicated in Table 1.The crystallographic information for Li 2 MgSn [41] shows that its lattice parameter a is 0.676 nm, belonging to the Fm3m space group, with each unit cell containing 8 Li atoms, 4 Mg atoms and 4 Sn atoms.Based on the atom positions in the unit cell and the structure factor of the planes, the atomic configurations of the {220} Li 2 MgSn plane together with the close packed direction can be identified.As shown in Figure 5, there are four close packed or nearly close packed directions of {220} Li 2 MgSn .They are < 110 > s Li 2 MgSn , < 111 > s Li 2 MgSn , < 112 > z Li 2 MgSn , and < 001 > s Li 2 MgSn , where the superscript "S" denotes straight atom rows and "Z" indicates the zigzag atom rows.Li is a simple BCC structure and there are three close packed or nearly close packed directions in the plane of (110) β−Li .They are < 001 > s β−Li , < 111 > s β−Li and < 110 > s β−Li .According to the principle [39] that zigzag atom rows match with other zigzag rows and straight rows match with other straight rows, the f r values can be calculated [23].There are three pairs f r value of matching directions below the critical value of 10%, as shown in Table 2.The calculated results implied that there was a good crystallographic matching relationship between Li2MgSn and the matrix.Therefore, compared to LiMgAl2 particles, Li2MgSn intermetallics had more potential to serve as the heterogeneous nucleation sites for the matrix in the DRX process, leading to an excellent grain refinement effect of the as-extruded LT142 alloy.

Conclusions
The as-cast and as-extruded LA141 (Mg-14Li-1Al) and LT142 (Mg-14Li-2Sn) alloys were prepared to investigate the effect of different alloying elements and intermetallics on the grain refinement in the Mg-14Li alloys.The corresponding results are summarized below.
(1) In the as-cast alloys, with Al or Sn addition to the Mg-14Li alloy, the grains of the as-cast Mg-14Li alloy were refined, and the grain size of the as-cast LA141 alloy was similar with that of LT142 alloy.The dominant driving force of grain refinement by Al or Sn in the as-cast Mg-14Li alloy was the solute effect of alloying elements.
(2) In the as-extruded alloys, the grains of the LT142 alloy with Li2MgSn particles were two times finer than those of the LA141 alloy with LiMgAl2.The better grain refinement impact of Sn in the asextruded alloys can be attributed to the obvious heterogeneous nucleation effect of the Li2MgSn in the DRX process.
(3) The crystallographic orientation relationships between LiMgAl2/Li2MgSn and matrix were calculated applying edge-to-edge matching model.They were: LiMgAl2 did not match Li matrix, while Li2MgSn exhibited an excellent matching relationship with Li matrix as The calculated results implied that there was a good crystallographic matching relationship between Li 2 MgSn and the matrix.Therefore, compared to LiMgAl 2 particles, Li 2 MgSn intermetallics had more potential to serve as the heterogeneous nucleation sites for the matrix in the DRX process, leading to an excellent grain refinement effect of the as-extruded LT142 alloy.

Conclusions
The as-cast and as-extruded LA141 (Mg-14Li-1Al) and LT142 (Mg-14Li-2Sn) alloys were prepared to investigate the effect of different alloying elements and intermetallics on the grain refinement in the Mg-14Li alloys.The corresponding results are summarized below.
(1) In the as-cast alloys, with Al or Sn addition to the Mg-14Li alloy, the grains of the as-cast Mg-14Li alloy were refined, and the grain size of the as-cast LA141 alloy was similar with that of LT142 alloy.The dominant driving force of grain refinement by Al or Sn in the as-cast Mg-14Li alloy was the solute effect of alloying elements.
(2) In the as-extruded alloys, the grains of the LT142 alloy with Li 2 MgSn particles were two times finer than those of the LA141 alloy with LiMgAl 2 .The better grain refinement impact of Sn in the as-extruded alloys can be attributed to the obvious heterogeneous nucleation effect of the Li 2 MgSn in the DRX process.