The Activation Energy of Viscous Flow and Liquid–Liquid Structure Transition in Co-B Alloys

: The temperature dependences of the kinematic viscosity during heating and cooling have been investigated in Co-B melts with a boron content of up to 30.8 at. A liquid–liquid structural transition was found, which is accompanied by an increase in the activation energy and cluster size, as well as a signiﬁcant decrease in the density of the melt. The liquid–liquid structural transition was associated with the formation of clusters with a short-range order of Co 23 B 6 in the intermediate temperature region. At low and high temperatures, clusters of the order of an atomic size are active participants in the viscous ﬂow. It was shown that with an increase in the cluster size, the activation energy increases and the viscosity of melts decreases. The formation of large Co 23 B 6 clusters during the cooling of melt with low boron content leads to undercooling and the appearance of the transition temperature region with high activation energy, although this region does not exist during the heating stage.


Introduction
The activation of atoms (molecules and clusters) in a liquid is associated with the transfer of energy sufficient to overcome the energy barrier by the atoms.The activation theory of a viscous fluid represents the temperature dependence of the kinematic viscosity in the form of an Arrhenius equation, which includes the activation energy.Liquid multicomponent alloys have a microheterogeneous structure [1].The difference in the energy of interatomic bonds is the reason for the formation of clusters of different composition, structure, and size that have different stability.The composition and cluster size change with temperature.Most often, in liquid metals, the cluster size decreases with increasing temperature.
A liquid can have several thermodynamic states, the transition between which is a liquid-liquid transition [2].Liquid-liquid structure transition (LLST) is accompanied by structural transformations [3].LLST is revealed as anomalies in the temperature dependence of structurally sensitive properties such as density [4], viscosity [5], electrical resistivity [6], internal friction [7], and magnetization [8].The discontinuous change in the structure during the heating of the melt is accompanied by an endothermic peak [9] as well as a decrease in the coordination number [10].
Co-B alloys are the subject of numerous studies.These alloys served as the basis for the creation of amorphous soft magnetic materials with high permeability, in which boron contributes to the formation of an amorphous structure [11,12].Co-B alloys are used as hydrogen storage materials [13] and as transducers to detect acoustic propagation and heat transport at the interface [14].During the manufacturing process, most materials go through a melting stage.In ref. [15], the temperature dependences of the kinematic viscosity and density of Co-B melts with different boron contents were studied.Upon cooling, a stable Co 2 B phase [16] or metastable phases Co 3 B and Co 23 B 6 [17] are formed in an alloy with a boron content of less than 35 at.%.The phase composition of the alloy after solidification strongly depends on the overheating temperature of the melt [18] and solidification pathways [19,20].
In this work, we studied the activation energy of viscous flow and LLST in Co-B melts with a boron content of up to 30.8 at.%.

Materials and Methods
Master alloy Co 61 B 39 was melted in a vacuum arc furnace from a pressed briquette of electrolytic cobalt and amorphous boron.Alloy samples were obtained by melting the master alloy with cobalt.The chemical composition was determined using a DFS-500 Optical Emission Spectrometer, OKB Spectr, Saint-Petersburg, Russia.We studied Co 100−x B x alloys with a boron content of x = 4.4, 8.7, 18.6, 25.6, and 30.8 at.%.The Co 81.4 B 18.6 alloy is eutectic, while the Co 74.4 B 25.6 alloy corresponds to the metastable Co 3 B compound.The kinematic viscosity was measured using oscillating cup viscometer in an atmosphere of pure helium at a pressure of 10 5 Pa [21].The samples were placed in a beryllium oxide cup suspended by a torsion wire.The oscillation of the cup was dampened by the frictional force between the layers of the liquid.The melt was kept at a predetermined temperature for 5 min to stabilize the structural state.During heating and cooling, the temperature of the melt was changed by a step of 30 K. The kinematic viscosity was calculated from the results of measuring the decrement based on the Shvidkovskiy algorithm.The activation energy E a was calculated from the temperature dependence of the viscosity in the linear sections of the Arrhenius plot.The error in measuring the kinematic viscosity was 3%.The melt density was measured by the sessile drop method in a helium atmosphere.The error in measuring the density did not exceed 3%.

Results
The temperature dependence of the kinematic viscosity can be represented by the Arrhenius equation: where ν is the kinematic viscosity (m 2 •s −1 ), ν 0 is a pre-exponential factor with the dimen- sion of the kinematic viscosity, E a is the activation energy of the viscous flow (J•mol −1 ), R is the gas constant (J•K −1 •mol −1 ), and T is the absolute temperature (K).After taking the logarithm of Equation (1), we obtain the Arrhenius plot: where E a •(RT) −1 is the reduced activation energy, which compares the activation energy E a with the thermal energy RT.At constants ν 0 and E a , the logarithm of the kinematic viscosity is a linear function of the inverse absolute temperature.
Figure 1 shows Arrhenius plots as the dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 when Co 100−x B x alloys are heated to a temperature of 1914 K.The vertical dashed lines show the liquidus temperature T liq , the value of which is taken from [16].The color of the dashed lines matches the color of the temperature curves for alloys with the same boron content.At a temperature above T liq , the alloy is in a liquid state, and the viscosity of the melt naturally decreases with increasing temperature.Points below the liquidus temperature are highlighted in gray.In an oscillating cup viscometer, the decrement is related to the mass of fluid that is in contact with the solid surface of the oscillating body.Therefore, the steep rise of gray dots during heating in this temperature range indicates an increase in the fraction of the liquid phase in the solid-liquid state upon melting.From Figure 1, it follows that in alloys with high boron content, when heated, Arrhenius plots have linear sections at low and high temperatures.At intermediate temperatures, there is a transition region in which the slope of the Arrhenius plots is noticeably greater.In alloys with low boron content, there is no transition temperature region.In addition, viscosity increases with increasing boron content.A minor exception is alloys with boron content between 8.7 and 4.4 at.%.
cometer, the decrement is related to the mass of fluid that is in contact with the solid surface of the oscillating body.Therefore, the steep rise of gray dots during heating in this temperature range indicates an increase in the fraction of the liquid phase in the solid-liquid state upon melting.From Figure 1, it follows that in alloys with high boron content, when heated, Arrhenius plots have linear sections at low and high temperatures.At intermediate temperatures, there is a transition region in which the slope of the Arrhenius plots is noticeably greater.In alloys with low boron content, there is no transition temperature region.In addition, viscosity increases with increasing boron content.A minor exception is alloys with boron content between 8.7 and 4.4 at.%.In general, from Figures 1 and 2, it follows that the kinematic viscosity increases with increasing boron content.Linear segments can be distinguished by the dependence of lnν on T −1 .In the intermediate temperature range from 1650 to 1850 K, the slope of the linear segments is noticeably greater.During heating In general, from Figures 1 and 2, it follows that the kinematic viscosity increases with increasing boron content.Linear segments can be distinguished by the dependence of lnν on T −1 .In the intermediate temperature range from 1650 to 1850 K, the slope of the linear segments is noticeably greater.During heating (Figure 1) in alloys with a low boron content of 4.4 and 8.7 at.%, there is no transition temperature region.With an increase in the boron content, the transition region shifts towards a high temperature.On cooling (Figure 2), the intermediate region shrinks with increasing boron content.
Figure 3 shows the effect of the boron content on the liquidus temperature T liq [16], as well as on the temperatures T heat and T cool .The quantities T heat and T cool indicate the temperature below which the calculated viscosities drop steeply upon heating and cooling, respectively, and the difference between these temperatures, ∆T = T heat − T cool can be taken as the undercooling temperature.It can be seen that alloys with a low boron content have the highest undercooling.In general, from Figures 1 and 2, it follows that the kinematic viscosity in creases with increasing boron content.Linear segments can be distinguished b the dependence of lnν on T −1 .In the intermediate temperature range from 1650 t 1850 K, the slope of the linear segments is noticeably greater.During heatin (Figure 1) in alloys with a low boron content of 4.4 and 8.7 at.%, there is no tran sition temperature region.With an increase in the boron content, the transitio region shifts towards a high temperature.On cooling (Figure 2), the intermediat region shrinks with increasing boron content.
Figure 3 shows the effect of the boron content on the liquidus temperatur Tliq [16], as well as on the temperatures Theat and Tcool.The quantities Theat and Tc indicate the temperature below which the calculated viscosities drop steepl upon heating and cooling, respectively, and the difference between these tem peratures, ΔT = Theat − Tcool can be taken as the undercooling temperature.It can b seen that alloys with a low boron content have the highest undercooling.Figure 4 shows the effect of the activation energy E a on the boron content during heating and cooling near a temperature of 1900 K.It can be seen that the activation energy increases with increasing boron content, although in the alloy with the lowest boron content, Co 95.6 B 4.4 , there is a trend towards an increase in the activation energy.
Figure 5 shows Arrhenius plots of the dependence of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the eutectic Co 81.4 B 18.6 alloy.The numbers next to the curves represent the activation energy E a in the corresponding temperature interval.It can be seen that the activation energy is minimal in the high-temperature region and slightly higher in the low-temperature region, and the highest activation energy falls in the intermediate region.If, at high and low temperatures, the heating and cooling curves are combined, then there is a discrepancy in forming a hysteresis loop in the intermediate region.The constancy of the activation energy in a certain temperature interval allows us to assume that the structure of the melt in this interval is almost unchanged.
Figure 4 shows the effect of the activation energy Ea on the boron co during heating and cooling near a temperature of 1900 K.It can be seen tha activation energy increases with increasing boron content, although in the with the lowest boron content, Co95.6B4.4,there is a trend towards an increa the activation energy.

Discussion
Equation ( 1) can be written as:

Discussion
Equation ( 1) can be written as: In the hole model [22], the space available for the motion of atoms and clusters is a free volume.The motion of one liquid layer relative to another is associated with the transition of atoms or clusters from an equilibrium state to a free hole.This mechanism of particle motion in the theory of transition states gives the pre-exponential factor ν 0 as [5,22]: where V f /V is the relative free volume, V is the specific volume (m −3 •kg), ρ is the density (kg•m −3 ), a is the atom or cluster size (m), and k B is the Boltzmann constant (J•K −1 ).Then, at a fixed temperature, Equation (3) can be represented as: where C(T) is the constant that depends on the temperature.Thus, at a constant temperature, the activation energy increases with an increase in the size of the clusters involved in the viscous flow.An increase in the activation energy with an increase in the cluster size is typical not only for viscous flow but also for other transport phenomena [23,24].From Equation (4), it is possible to estimate the size of the particles involved in the viscous flow: Density ρ and pre-exponential factor v 0 will be found from experimental data.The relative free volume V f /V was determined from the Batschinski equation [25,26]: which demonstrates that the kinematic viscosity is inversely proportional to the relative free volume: In Equations ( 7) and ( 8), the specific volume V = ρ −1 , c is the constant with the dimension of kinematic viscosity, the value ω corresponds to the specific volume of liquid with infinitely high viscosity, and the difference (V − ω) represents the specific free volume V f .From Equations ( 7) and ( 8), it follows that the inverse kinematic viscosity is a linear function of the density: The value ω = 1.25 × 10 −7 m 3 •kg −1 for the Co 81.4 B 18.6 melt was found from Equation ( 9) in the low-temperature region.The relative free volume V f /V can now be determined using formula (8).
Table 1 shows the calculated parameters of the liquid eutectic Co 81.4 B 18.6 alloy and cluster sizes involved in viscous flow at the cooling stage.At low and high temperatures, the clusters have a size close to the atomic size of 0.1 nm, and the cluster size is larger in the low-temperature region.In the intermediate region, the size of the clusters is much larger.It can be assumed that, at low temperatures, the melt viscosity is mainly associated with the movement of individual atoms or small clusters.With an increase in temperature, large clusters are involved in the flow, which then break up into atoms.1 also shows the reduced activation energy E a •(RT) −1 , which compares the activation energy E a with the thermal energy RT.Thermal energy is a source that accelerates the movement of clusters and lowers the energy barrier.An increase in the reduced activation energy to 4.6 at 1720 K indicates a decrease in the number of moved clusters.But the movement of one cluster is accompanied by the displacement of a significant number of atoms, and the number of atoms in a cluster grows non-linearly with an increase in its size [27].Thus, large clusters move a larger number of atoms, and this will lead to a decrease in the melt viscosity.Previously, it was shown [28] that the viscosity decreases with increasing cluster size.A similar dependence takes place in a nanofluid [29].
Electronegativities on the Luo-Benson scale for Co and B are 1.83 and 3.66, respectively [30].Boron atoms are most strongly associated with cobalt atoms since this pair of elements has distinct electronegativity.In the Co 50 B 50 alloy, all cobalt atoms are bonded to boron atoms, and the stable CoB compound has the highest liquidus temperature (Table 2).With an increase in boron content, when excess cobalt atoms appear, they will still tend to move closer to the boron atoms.An increase in temperature increases the mobility of atoms, and this simultaneously weakens the Co-B bond but increases the probability that free cobalt atoms will approach boron atoms.At a sufficiently high temperature, borides begin to accumulate free cobalt atoms, forming short-range order Co 2 B. When the ratio of the number of cobalt atoms to boron atoms is 2:1, a stable Co 2 B compound with a high local liquidus temperature is formed.With a further increase in the cobalt content, the same mechanism should lead to the formation of a short-range order, first Co 3 B and then Co 23 B 6 .In the series of compounds CoB, Co 2 B, Co 3 B, and Co 23 B 6 , the fraction of cobalt bound to boron increases successively.It follows from Table 2 that an increase in the fraction of cobalt Metals 2023, 13, 1954 8 of 12 in the compound leads to a decrease in formation energy, liquidus temperature, and an increase in mole volume, which indicates a weakening of the bond between atoms.The as-cast Co 81.4 B 18.6 eutectic alloy consists of Co and the orthogonal Co 3 B phase, with a small amount of the tetragonal Co 2 B phase [18].Therefore, when melting the Co 81.4 B 18.6 alloy, the clusters in the low-temperature region have mostly a short-range order of Co 3 B. The structure of the low-temperature melt is dominated by small clusters and free atoms, which confirms the small cluster size (Table 1) and low activation energy (Figure 5).In the low-temperature region, it is quite expected that the size of the particles that participate in viscous flow is close to the atom size.In the region just below the melting point, most atoms vibrate around equilibrium positions in the crystal lattice.In the liquid state, just above the melting point, there are more free atoms that can move a considerable distance.As the temperature increases, the number of free atoms increases, but they are not isolated from each other and continue to interact, gathering into clusters.
In Figure 5, the heating and cooling Arrhenius plots form a hysteresis loop.The nature of hysteresis is always associated with the presence of a large number of metastable states in the material.As a result, the trajectory of changes in the melt structure with temperature can vary greatly.Thus, a supercooled alloy can have a different structure during cyclic heating and cooling (see [17,19]).We thermally cycled our melts.In general, the characteristic temperatures on the viscosity curves are repeated, but the paths through the heating-cooling cycles are somewhat different.In magnetic hysteresis, it is necessary to make at least 10 cycles to reach a stable loop trajectory.
As the temperature rises, the bond between atoms weakens, and this can facilitate the transition to the short-range order of Co 23 B 6 .The stimulus for LLST in the eutectic Co 81.4 B 18.6 melt is the desire to have a uniform distribution of cobalt and boron atoms at high temperatures.A uniform distribution can be obtained in the Co 79.4 B 20.6 alloy, in which the ratio of cobalt and boron atoms exactly corresponds to the Co 23 B 6 compound.The transition to a short-range order of Co 23 B 6 confirms the large cluster size (Table 1) and high activation energy (Figure 5), as well as a sharp decrease in melt density (Figure 6).Table 2 shows that the Co 23 B 6 compound has a high molar volume.It was previously noted that when the eutectic melt is heated above 1650 K, the undercooling ∆T increases significantly, and the metastable Co 23 B 6 phase is formed [18,20].The boundary temperature of 1650 K just coincides with the onset temperature of LLST in the eutectic alloy in Figure 5.
In the high-temperature region, the reduced activation energy is close to 1 (Table 1), so the energy barrier for cluster movement is very low.An estimate of the cluster size (Table 2) shows that at high temperatures, the viscous flow is associated with individual atoms.
The low-boron as-cast alloys consist of Co and the orthogonal Co 3 B phase [32], with a significant proportion of free cobalt.Therefore, during the heating of the Co 91.3 B 8.7 melt, the movement of individual atoms and small clusters dominates, which corresponds to a low activation energy (Figure 7).An excess of cobalt in this melt prevents the formation of large Co 23 B 6 clusters, and upon heating, a transition region with a high activation energy is not observed in Figure 7. Upon reaching a high temperature of 1914 K, the activation energy decreases to 14 kJ/mol.Thus, the cooling of the melt begins in the state in which individual atoms predominate.The Co 91.3 B 8.7 alloy has a significant undercooling ∆T.Undercooling is associated with the formation of clusters with icosahedral short-range order [33], which have fivefold symmetry and inhibit the growth of the nuclei of regular crystals.Experimentally, the icosahedral short-range order was found in undercooled Co melts [34].Fe 23 B 6 -type quasicrystal-like structures were found in Fe-based metallic glass [35].Undercooling of the Co 91.3 B 8.7 melt expands the temperature range of the liquid state, and an intermediate region appears at the cooling stage.Thus, the formation of large Co 23 B 6 clusters leads to the undercooling of the alloy.In the intermediate region, the activation energy of 47 kJ/mol is lower than in the eutectic melt, which can be explained by an increase in the fraction of unbound cobalt atoms.
Upon reaching a high temperature of 1914 K, the activation energy decreases to 14 kJ/mol.Thus, the cooling of the melt begins in the state in which individual atoms predominate.The Co91.3B8.7 alloy has a significant undercooling ΔT.Undercooling is associated with the formation of clusters with icosahedral short-range order [33], which have fivefold symmetry and inhibit the growth of the nuclei of regular crystals.Experimentally, the icosahedral short-range order was found in undercooled Co melts [34].Fe23B6-type quasicrystal-like structures were found in Fe-based metallic glass [35].Undercooling of the Co91.3B8.7 melt expands the temperature range of the liquid state, and an intermediate region appears at the cooling stage.Thus, the formation of large Co23B6 clusters leads to the undercooling of the alloy.In the intermediate region, the activation energy of 47 kJ/mol is lower than in the eutectic melt, which can be explained by an increase in the fraction of unbound cobalt atoms.In the Co79.4B20.6 melt, the ratio of cobalt and boron atoms corresponds to the Co23B6 compound.In alloys with a boron content of less than 20.6 at%, that is, with an excess cobalt content compared to Co23B6, the kinematic viscosity during cooling is higher than during heating.The hysteresis loop in Figure 5 shows the premature LLST during heating and cooling.Premature LLST indicates that the short-range order of Co23B6 is more preferable in low-boron alloys.
In the as-cast alloys with a high boron content, the tetragonal Co2B phase predominates [32].Figure 8 shows the dependence of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the Co69.2B30.8alloy.This alloy has an excess boron content compared to In the Co 79.4 B 20.6 melt, the ratio of cobalt and boron atoms corresponds to the Co 23 B 6 compound.In alloys with a boron content of less than 20.6 at%, that is, with an excess cobalt content compared to Co 23 B 6 , the kinematic viscosity during cooling is higher than during heating.The hysteresis loop in Figure 5 shows the premature LLST during heating and cooling.Premature LLST indicates that the short-range order of Co 23 B 6 is more preferable in low-boron alloys.
In the as-cast alloys with a high boron content, the tetragonal Co 2 B phase predominates [32].Figure 8 shows the dependence of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the Co 69.2 B 30.8 alloy.This alloy has an excess boron content compared to Co 23 B 6 , and the kinematic viscosity when cooled is lower than when heated.High boron content in the melt promotes the preservation of a stable short-range order of Co 2 B and inhibits the formation of a shortrange order of Co 23 B 6 .The wide hysteresis loop in Figure 8 shows the delay in the onset of LLST, which occurs in a narrow temperature range.The onset temperature of LLST at the stage of heating and cooling differs by 100 K.
Co23B6, and the kinematic viscosity when cooled is lower than when heated.High boron content in the melt promotes the preservation of a stable short-range order of Co2B and inhibits the formation of a short-range order of Co23B6.The wide hysteresis loop in Figure 8 shows the delay in the onset of LLST, which occurs in a narrow temperature range.The onset temperature of LLST at the stage of heating and cooling differs by 100 K.

Conclusions
Temperature dependences of the kinematic viscosity during heating and cooling have been investigated in Co-B melts with a boron content of up to 30.8 at.%.The activation energy of the viscous flow Ea and the reduced activation energy, which compares the activation energy with the thermal energy RT, were calculated from the experimental results.To estimate the size of moving clusters, we used the transition state theory and the Batschinski equation, which relate viscosity to relative free volume.As the cluster size increases, the activation energy of the viscous flow increases, and the viscosity of the melt decreases.At low and high temperatures, clusters of the order of an atomic size are active participants in the viscous flow.In the intermediate temperature region, the activation energy and cluster size increase, and the melt density sharply decreases.Corresponding changes were associated with the liquid-liquid structure transition, in which large clusters with a short-range order of Co23B6 are formed.The mechanism of the liquid-liquid structure transition is proposed, which confirms the characteristic shape of hysteresis loops on the temperature dependence of kinematic viscosity at the stage of heating and cooling.When a melt with a low boron content is heated, an intermediate-temperature region with high activation energy for viscous flow does not form on the Arrhenius plot.The formation of large Co23B6 clusters at the cooling stage after heating melts to a high temperature leads to undercooling and the appearance of the high activation energy region.

Conclusions
Temperature dependences of the kinematic viscosity during heating and cooling have been investigated in Co-B melts with a boron content of up to 30.8 at.%.The activation energy of the viscous flow E a and the reduced activation energy, which compares the activation energy with the thermal energy RT, were calculated from the experimental results.To estimate the size of moving clusters, we used the transition state theory and the Batschinski equation, which relate viscosity to relative free volume.As the cluster size increases, the activation energy of the viscous flow increases, and the viscosity of the melt decreases.At low and high temperatures, clusters of the order of an atomic size are active participants in the viscous flow.In the intermediate temperature region, the activation energy and cluster size increase, and the melt density sharply decreases.Corresponding changes were associated with the liquid-liquid structure transition, in which large clusters with a short-range order of Co 23 B 6 are formed.The mechanism of the liquid-liquid structure transition is proposed, which confirms the characteristic shape of hysteresis loops on the temperature dependence of kinematic viscosity at the stage of heating and cooling.When a melt with a low boron content is heated, an intermediatetemperature region with high activation energy for viscous flow does not form on the Arrhenius plot.The formation of large Co 23 B 6 clusters at the cooling stage after heating melts to a high temperature leads to undercooling and the appearance of the high activation energy region.

Figure 1 .
Figure 1.Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating of Co100−xBx alloys.The vertical dashed lines show the liquidus temperatures Tliq.The gray dots refer to the solid-liquid state.

Figure 2 shows
Figure 2 shows Arrhenius plots as the dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during cooling of Co100−xBx alloys at a temperature of 1914 K.At cooling, some alloys remain in the liquid state below the liquidus temperature and pass into the undercooled state.In the undercooling state, a transition temperature region appears in alloys with low boron content.

Figure 1 .
Figure 1.Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating of Co 100−x B x alloys.The vertical dashed lines show the liquidus temperatures T liq .The gray dots refer to the solid-liquid state.

Figure 2 shows 13 Figure 2 .
Figure 2 shows Arrhenius plots as the dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during cooling of Co 100−x B x alloys at a temperature of 1914 K.At cooling, some alloys remain in the liquid state below the liquidus temperature and pass into the undercooled state.In the undercooling state, a transition temperature region appears in alloys with low boron content.Metals 2023, 13, x FOR PEER REVIEW 4 of 13

Figure 2 .
Figure 2. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during cooling of Co 100−x B x alloys.The vertical dashed lines show the liquidus temperatures T liq .The gray dots refer to the solid-liquid state.

Figure 2 .
Figure 2. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciproc temperature T −1 during cooling of Co100−xBx alloys.The vertical dashed lines show the liquidu temperatures Tliq.The gray dots refer to the solid-liquid state.

Figure 3 .
Figure 3.Effect of boron content on the liquidus temperature T liq , as well as on the temperatures T heat and T cool , below which the calculated viscosities drop steeply upon heating and cooling, respectively.The undercooling ∆T = T heat − T cool .

Figure 4 .
Figure 4. Effect of boron content on activation energy Ea in Co100−xBx alloys during heatin cooling near 1900 K.

Figure 5 shows
Figure5shows Arrhenius plots of the dependence of the natural logar of the kinematic viscosity lnν on the reciprocal temperature T −1 during he and cooling of the eutectic Co81.4B18.6 alloy.The numbers next to the curves resent the activation energy Ea in the corresponding temperature interval.I be seen that the activation energy is minimal in the high-temperature region slightly higher in the low-temperature region, and the highest activation en falls in the intermediate region.If, at high and low temperatures, the heating cooling curves are combined, then there is a discrepancy in forming a hyste loop in the intermediate region.The constancy of the activation energy in a tain temperature interval allows us to assume that the structure of the melt in interval is almost unchanged.

Figure 4 . 13 Figure 5 .
Figure 4. Effect of boron content on activation energy E a in Co 100−x B x alloys during heating and cooling near 1900 K. Metals 2023, 13, x FOR PEER REVIEW 6 of 13

Figure 6
Figure 6 shows the dependence of the melt density ρ on the reciprocal temperature T −1 at the cooling stage of the eutectic Co81.4B18.6 alloy.Here, for comparison, the corresponding dependence of the kinematic viscosity is plotted.It follows from Figure 6 that in the intermediate region, along with an increase in the activation energy, the density of the melt sharply decreases.

Figure 5 .
Figure 5. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the eutectic Co 81.4 B 18.6 alloy.The vertical dashed lines show the liquidus temperature for Co 81.4 B 18.6 and the melting points for Co 2 B and Co 3 B compounds.The numbers next to the curves represent the activation energy E a in the corresponding temperature interval.

Figure 6
Figure 6 shows the dependence of the melt density ρ on the reciprocal temperature T −1 at the cooling stage of the eutectic Co 81.4 B 18.6 alloy.Here, for comparison, the corresponding dependence of the kinematic viscosity is plotted.It follows from Figure 6 that in the intermediate region, along with an increase in the activation energy, the density of the melt sharply decreases.

Figure 6
Figure6shows the dependence of the melt density ρ on the reciprocal temperature T −1 at the cooling stage of the eutectic Co81.4B18.6 alloy.Here, for comparison, the corresponding dependence of the kinematic viscosity is plotted.It follows from Figure6that in the intermediate region, along with an increase in the activation energy, the density of the melt sharply decreases.

Figure 6 .
Figure 6.Dependences of density ρ and natural logarithm of kinematic viscosity lnν on reciprocal temperature T −1 during cooling of eutectic Co 81.4 B 18.6 alloy.

Figure 7 .
Figure 7. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the Co91.3B8.7 alloy.The vertical dashed lines show the liquidus temperature for Co91.3B8.7 and the melting points for Co2B and Co3B compounds.The numbers next to the curves represent the activation energy Ea in the corresponding temperature interval.

Figure 7 .
Figure 7. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the Co 91.3 B 8.7 alloy.The vertical dashed lines show the liquidus temperature for Co 91.3 B 8.7 and the melting points for Co 2 B and Co 3 B compounds.The numbers next to the curves represent the activation energy E a in the corresponding temperature interval.

Figure 8 .
Figure 8. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the Co69.2B30.8alloy.The vertical dashed lines show the liquidus temperature for Co69.2B30.8 and the melting points for Co2B and Co3B compounds.The numbers next to the curves represent the activation energy Ea in the corresponding temperature interval.

Figure 8 .
Figure 8. Dependences of the natural logarithm of the kinematic viscosity lnν on the reciprocal temperature T −1 during heating and cooling of the Co 69.2 B 30.8 alloy.The vertical dashed lines show the liquidus temperature for Co 69.2 B 30.8 and the melting points for Co 2 B and Co 3 B compounds.The numbers next to the curves represent the activation energy E a in the corresponding temperature interval.

Table 1 .
Design parameters of the liquid eutectic Co 81.4 B 18.6 alloy and cluster sizes involved in viscous flow at the cooling stage.

Table 2 .
Design parameters of the compounds.