Frequency Analysis of Transients in Electrochemical Noise of Superalloys Waspaloy and Ultimet

: Nickel or Cobalt-based superalloys represent an important class of engineering materials, ﬁnding widespread application in critical components within the gas turbine engines used for jet propulsion and electricity generation. This research aimed at the frequency analysis of transients in electrochemical noise of Waspaloy and Ultimet superalloys, immersed in 3.5 wt.% in H 2 SO 4 and NaCl solutions at two different temperatures, 25 and 60 ◦ C. Localized corrosion behavior of superalloys was assessed using the electrochemical noise technique (EN) according to ASTM-G199 standard. Three different statistical methods ﬁltered the EN signal, and the polynomial method was employed to obtain the noise resistance ( R n ), the localization index ( LI ), skew and kurtosis, and the power spectral density analysis (PSD). Results indicate that the current and potential noise transients have a better behavior with better clarity when a polynomial is used to show a localized corrosion kurtosis for both superalloys.


Introduction
The superalloys are high-temperature materials that display excellent resistance to mechanical and chemical degradation at temperatures close to their melting points [1,2].
Since they first emerged in the first half of the twentieth century, these alloys have had an extraordinary impact. Consider the aero-engines which power the modern civil aircraft. The superalloys are employed in the very hottest sections of the turbines, under the heaviest loads, with the utmost importance placed on assuring the integrity of the components fabricated from them. Indeed, the development of superalloys has been intrinsically linked to the history of the jet engine for which they were designed. A modern jet airplane could not fly without them. Further improvements in temperature capability are now actively sought, e.g., the engines can power the two-decked Airbus A380 and the Boeing 787 Dreamliner [1,[3][4][5][6][7].
Materials used in hot parts of jet engines must retain high performances and structural stability for prolonged periods under service conditions involving high mechanical stresses and corrosive agents [1,4]. the time-frequency domain. The statistical analysis includes parameters such as noise resistance (R n ), skewness, kurtosis, localization index (LI), chaos analysis, recurrence quantification analysis, and fractal analysis. The fast Fourier transform includes power spectral density, noise impedance, etc., and the time-frequency domains methods include the analysis of Hilbert-Huang transform, discrete wavelet transform, Stockwell transform, and others [26][27][28][29][30][31][32]. LI, skewness, and kurtosis values have been reported as values related to different corrosion types and values referring to the asymmetry of EN data's distribution and shape [32][33][34][35][36][37].
Very few experiments with these conditions and with this electrochemical technique have been developed. L.O Osoba et al. [3] researched Ni-based superalloys using the potentiodynamic polarization technique in HCl at 1 M. The results showed a passivation trend. Moreover, the differences among corrosion rates in an acid environment for based-Ni superalloys depends on Cr and Mo content.
Electrochemical characterization of superalloys could find potential in the aeronautical industry applications, such as turbine blades and aircraft landing gears. The structural components of aircraft made with superalloys are exposed to different atmospheres: industrial (acid rain (H 2 SO 4 )) and marine (NaCl). Las superalloys may be susceptible to low temperature pitting corrosion when aircraft are on the ground.
This research aimed was Frequency Analysis of Transients in Electrochemical Noise of Waspaloy and Ultimet superalloys, immersed in 3.5 wt.% in H 2 SO 4 and NaCl solutions at two different temperatures, 25 and 60 • C. The localized corrosion behavior of superalloys was studied using the electrochemical noise technique (EN) according to ASTM-G199 standard.

Materials
The materials used in this work were superalloys, Waspaloy (Nickel-based) and Ultimet (Cobalt-based), used in the received condition. The chemical composition of these superalloys was obtained by X-ray fluorescence (Olympus DELTA XRF. Richmond, TX, USA). Table 1 shows the chemical composition of each superalloy.

Microstructural Characterization
The specimens were polished using metallographic techniques. The polishing was done using different SiC grit papers until 4000 grades, followed by ultrasonic cleaning in ethanol (C 2 H 5 OH) and deionized water for 10 min each. Etching of polished samples was elaborated with a solution composed of HNO 3 2.5 mL, FeCl 3 32.5 g, and HCl 10 mL, according to ASTM E3 and E407 standards [38,39].
The microstructural analysis was carried out by optical microscopy (OM, Olympus, Hamburg, Germany) for identifying the microstructure of samples at a magnification of 100×.

Electrochemical Techniques
The electrochemical noise (EN) technique was used to evaluate corrosion behavior of Waspaloy and Ultimet superalloys, immersed in 3.5 wt.% in H 2 SO 4 and NaCl solutions at two different temperatures, 25 and 60 • C. Each test was carried out in duplicate (test 1 and 2). The electrochemical noise measurements were recorded simultaneously using a Gill-AC potentiostat/galvanostat/ZRA (Zero Resistance Ammeter) from ACM Instruments (Manchester, UK). EN measurements were carried out according to ASTM G199-09 standard, which allows the noise resistance (R n ) and corrosion rate evaluation to be determined in distinctive corrosive media. For each experiment (Figure 1), two nominally identical specimens were used as the working electrodes (WE1 and WE2) and a saturated calomel electrode as the reference electrode (RE) [25]. Electrochemical current noise (ECN) was measured with a galvanic coupling current between two identical working electrodes. Simultaneously, electrochemical potential noise (EPN) was measured linking one of the working electrodes and a reference electrode. The current and potential electrochemical noise was monitored concerning each electrodes electrolyte combination under open circuit condition. For each EN measurement set, 1024 data points were obtained with a scanning rate of 1 datum/s. The current and potential time series were visually analyzed to interpret the signal transients and define the behavior of the frequency and amplitude of fluctuations as a function of time [40].
EN measurements were carried out according to ASTM G199-09 standard, which allows the noise resistance (Rn) and corrosion rate evaluation to be determined in distinctive corrosive media. For each experiment (Figure 1), two nominally identical specimens were used as the working electrodes (WE1 and WE2) and a saturated calomel electrode as the reference electrode (RE) [25]. Electrochemical current noise (ECN) was measured with a galvanic coupling current between two identical working electrodes. Simultaneously, electrochemical potential noise (EPN) was measured linking one of the working electrodes and a reference electrode. The current and potential electrochemical noise was monitored concerning each electrodes electrolyte combination under open circuit condition. For each EN measurement set, 1024 data points were obtained with a scanning rate of 1 datum/s. The current and potential time series were visually analyzed to interpret the signal transients and define the behavior of the frequency and amplitude of fluctuations as a function of time [40].
The DC trend signal was removed from the original EN signal by the polynomial method, and from signal without DC, statistical data (Rn, kurtosis, and skewness) were obtained. For PSD (power spectral density) data, a Hann window was applied before being transformed to the fast Fourier transform (FFT) frequency domain. Data analysis was processed with a program made in MATLAB 2018a software (Math Works, Natick, MA, USA).

OM Microstructural Analysis
The initial samples microstructures were analyzed by optical microscope (OM). Ultimet ® is a commercial alloy of Co-26Cr-9Ni wt. %. It has high tensile strength combined with excellent impact toughness, ductility, and resistance to wear and corrosion. HAYNES International, Inc. developed this superalloy. Figure 2a shows the microstructure of Ultimet alloy in the as-received condition exhibited a single face-centered-cubic phase with relatively fine, uniform grains and annealing twins. As shown in Figure 2b, Waspaloy has a microstructure with a gamma (γ) austenitic matrix with a face-centered cubic (FCC) and twinned structure. There are also some gamma precipitates (γ′) coherent precipitation phase, as carbides located on the grain boundaries [41,42].
The grain size measurement was done using interception method in accordance with ASTM G112-13 standard [43]. The analysis of the interception method was using image analysis program (OLYMPUS STREAM ESSENTIALS version 1.9). In Figure 2c,d, the The DC trend signal was removed from the original EN signal by the polynomial method, and from signal without DC, statistical data (R n , kurtosis, and skewness) were obtained. For PSD (power spectral density) data, a Hann window was applied before being transformed to the fast Fourier transform (FFT) frequency domain. Data analysis was processed with a program made in MATLAB 2018a software (Math Works, Natick, MA, USA).

OM Microstructural Analysis
The initial samples microstructures were analyzed by optical microscope (OM). Ultimet ® is a commercial alloy of Co-26Cr-9Ni wt.%. It has high tensile strength combined with excellent impact toughness, ductility, and resistance to wear and corrosion. HAYNES International, Inc. developed this superalloy. Figure 2a shows the microstructure of Ultimet alloy in the as-received condition exhibited a single face-centered-cubic phase with relatively fine, uniform grains and annealing twins. As shown in Figure 2b, Waspaloy has a microstructure with a gamma (γ) austenitic matrix with a face-centered cubic (FCC) and twinned structure. There are also some gamma precipitates (γ ) coherent precipitation phase, as carbides located on the grain boundaries [41,42].
The grain size measurement was done using interception method in accordance with ASTM G112-13 standard [43]. The analysis of the interception method was using image analysis program (OLYMPUS STREAM ESSENTIALS version 1.9). In Figure 2c Careful control and optimization of the chemical composition permit developed microstructures with small and uniform grain limits to achieve maximum performance. Alloying elements affect the grain boundary as a function of manufacturing route or adopted heat treatment. This substantially implies the resulting microstructural array, and consequently attained properties, e.g., mechanical behavior, corrosion resistance, and other ones [44][45][46]. Grain boundary elements refer to carbides and borides, which form particles along the grain boundaries and cause strengthening [47].

Electrochemical Noise (EN)
The EN signal was composed of random, stationary, and DC variables. It is necessary to separate DC from random and stationary components to analyze EN data because DC creates false frequencies and interferes in visual, statistical, and PSD analysis. In this way, when DC is removed, corrosion data presented at low frequencies are conserved [43][44][45][46][47][48][49]. In the EN time series, there are three components: DC signal, Random, and Stationary. The latter are the components that define the corrosion system [41]. The polynomial method defines the noise signal and polynomial of a grade at term in time to obtain a signal without trend [40,[50][51][52]. Figure 3 shows EN signal from tests 1 and 2 of the superalloys in 3.5 wt. % NaCl solution at 25 °C. Figure 3a,b presents the signal with the trend. Here, 3a shows EPN signal, Ultimet presents nobler potential than Waspaloy, but in the time function, Ultimet potential goes to active potential, while Waspaloy goes to noble potential. In Figure 3b, the ECN Ultimet shows the fluctuation in current demand, and Waspaloy presents highfrequency anodic transients. Figure 3c,d present the signal with trend removal by the polynomial method. In Figure 3c, Ultimet T1/T2 shows fluctuations of 16 mV (−1 to 5 mV) Careful control and optimization of the chemical composition permit developed microstructures with small and uniform grain limits to achieve maximum performance. Alloying elements affect the grain boundary as a function of manufacturing route or adopted heat treatment. This substantially implies the resulting microstructural array, and consequently attained properties, e.g., mechanical behavior, corrosion resistance, and other ones [44][45][46]. Grain boundary elements refer to carbides and borides, which form particles along the grain boundaries and cause strengthening [47].

Electrochemical Noise (EN)
The EN signal was composed of random, stationary, and DC variables. It is necessary to separate DC from random and stationary components to analyze EN data because DC creates false frequencies and interferes in visual, statistical, and PSD analysis. In this way, when DC is removed, corrosion data presented at low frequencies are conserved [43][44][45][46][47][48][49]. In the EN time series, there are three components: DC signal, Random, and Stationary. The latter are the components that define the corrosion system [41]. The polynomial method defines the noise signal and polynomial of a grade at term in time to obtain a signal without trend [40,[50][51][52]. Figure 3 shows EN signal from tests 1 and 2 of the superalloys in 3.5 wt.% NaCl solution at 25 • C. Figure 3a,b presents the signal with the trend. Here, 3a shows EPN signal, Ultimet presents nobler potential than Waspaloy, but in the time function, Ultimet potential goes to active potential, while Waspaloy goes to noble potential. In Figure 3b, the ECN Ultimet shows the fluctuation in current demand, and Waspaloy presents highfrequency anodic transients. Figure 3c,d present the signal with trend removal by the polynomial method. In Figure 3c, Ultimet T1/T2 shows fluctuations of 16 mV (−1 to 5 mV) amplitude, but it is not periodic. Waspaloy T1/T2 amplitude increase in time function with a maximum amplitude of 4 mV (−2 to 2 mV). For Figure 3d, Ultimet T1/T2 shows aggressive fluctuations of 2 µA/cm 2 (−0.5 to 1.5), meaning an increase in current demand. Waspaloy T1/T2 presents anodic transients in all time-series of 1 µA/cm 2 (0 to 1), which indicate the localization of corrosion phenomena. amplitude, but it is not periodic. Waspaloy T1/T2 amplitude increase in time function with a maximum amplitude of 4 mV (−2 to 2 mV). For Figure 3d, Ultimet T1/T2 shows aggressive fluctuations of 2 µA/cm 2 (−0.5 to 1.5), meaning an increase in current demand. Waspaloy T1/T2 presents anodic transients in all time-series of 1 µA/cm 2 (0 to 1), which indicate the localization of corrosion phenomena.   Figure 4a shows that Ultimet T1/T2 is continuously presenting nobler potential (1250 to 1300 mV) than Waspaloy with 350 mV. In the ECN signal with the trend (4b), Ultimet and Waspaloy T1/T2 decrease current demand, but Waspaloy presents high amplitude transients. EPN (4c) shows that Waspaloy T1/T2 has fluctuations of −8 mV (−4 to 4) amplitude in the polynomial method's signal filter. ECN (4d), Waspaloy T1/T2 presents anodic high amplitude transients 0.9 µA/cm 2 (0.1 to 0.8). Meanwhile, Ultimet presents low amplitude fluctuations.   Figure 4a shows that Ultimet T1/T2 is continuously presenting nobler potential (1250 to 1300 mV) than Waspaloy with 350 mV. In the ECN signal with the trend (4b), Ultimet and Waspaloy T1/T2 decrease current demand, but Waspaloy presents high amplitude transients. EPN (4c) shows that Waspaloy T1/T2 has fluctuations of −8 mV (−4 to 4) amplitude in the polynomial method's signal filter. ECN (4d), Waspaloy T1/T2 presents anodic high amplitude transients 0.9 µA/cm 2 (0.1 to 0.8). Meanwhile, Ultimet presents low amplitude fluctuations. Figure 5 shows EN signal from tests 1 and 2 of the superalloys in 3.5 wt.% H 2 SO 4 solution at 25 • C, Figure 5a,b present trend signal. In the EPN signal of Figure 4a Ultimet T1/T2 presents nobler potential, and along time it is continuously increasing potential values, but anodic transients occur in time series. Waspaloy presents more active potential (−57 mV), and the trend is to go to active potentials. Figure 5b shows the ECN signal, Ultimet current demand is reduced in time function with the anodic transient. Meanwhile, Waspaloy shows a trend to increase current demand. Figure 5c,d show the time-series with trend removal by the polynomial method. Ultimet T1/T2 shows anodic transients in EPN and ECN signals, presenting a reciprocal behavior between potential and current. Potential transients are 30 mV (−25 to 15 mV) maximum, and the current is 2 µA/cm 2 (−1 to 1). Waspaloy T1/T2 shows fluctuations of −0.7 to 2 µA/cm 2 .    Figure 4a Ultime T1/T2 presents nobler potential, and along time it is continuously increasing potentia values, but anodic transients occur in time series. Waspaloy presents more active potentia (−57 mV), and the trend is to go to active potentials. Figure 5b shows the ECN signal Ultimet current demand is reduced in time function with the anodic transient. Meanwhile Waspaloy shows a trend to increase current demand. Figure 5c,d show the time-serie with trend removal by the polynomial method. Ultimet T1/T2 shows anodic transients in EPN and ECN signals, presenting a reciprocal behavior between potential and current Potential transients are 30 mV (−25 to 15 mV) maximum, and the current is 2 µ A/cm 2 (− to 1). Waspaloy T1/T2 shows fluctuations of −0.7 to 2 µ A/cm 2 . Figure 6 shows the EN signal from tests 1 and 2 of the superalloys in 3.5 wt. % H2SO4 Electrochemical current and potential noise-time series with DC figures (a) and (b) Ultimet T1/T2 have a nobler potential value than Waspaloy (from 30 to 630 mV respectively) in

Statistical Analysis
To determine noise resistance (Rn) is necessary to obtain standard deviation from time series values. These statistical values give corrosion kinetics and mechanism information. Cottis and Turgoose [37] found a relationship between the increase of variance and standard deviation with an increase in corrosion rate. For standard deviation, (σ) evaluation applying Equation (1) is required, by which Rn can be obtained (Equation (2)) from EN time series (EPN and ECN): where R n and R p are related, and the Stern-Geary equation (Equation (3)) can be applied as an analog relation between them to determine corrosion kinetically. B is a constant with a recommended value of 0.026 V for active and 0.052 V for the passive corrosion [14,15,50]: Some authors related the EN signal's statistical analysis with the metal surface's corrosion process [30]. The I rms is obtained by Equation (4), where X is the average of EN data, n the data number, and σ the standard deviation: With standard deviation and I rms , localization index can be calculated: Values obtained can be associated with the system's corrosion type (see Table 2) [19,[51][52][53]. This research will take more parameters to determine the corrosion type. This research employed kurtosis and skewness to try to define the corrosion type. Localization index (LI) was not considered because Mansfeld and Sun [54] in 1995 concluded that LI can present limitations and should be used with discretion. In 2001, Reid and Eden [55] developed a patent where they identified corrosion type based on statistical moments with skewness and kurtosis (Equations (6) and (7)), which are the 3rd and 4th statistical moments [54][55][56][57][58][59][60][61]: Statistical calculations have a standard error (SE) that generates uncertainty in the results. The following equation can be provided, where N is the number of data studied [61]. Hence, when the data number is significant, the standard error will be lower than when the data number is high.
SE is 0.153; values obtained will take SE as a parameter of uncertainty. Corrosion type determined by kurtosis and skewness is shown in Table 3: Kurtosis and skewness were applied to the ECN signal to determine the corrosion mechanism based on corrosion kinetic. Table 4 shows R n , i corr , skewness, and kurtosis from EN signal filtered with a 9th-grade polynomial to remove DC signal.  Table 4 presents statistical results, with duplicates results (tests 1 and 2), where Waspaloy showed higher Rn values at 25 • C than at 60 • C. This means that resistance to corrosion of Waspaloy is lower when the temperature increases. Ultimet presents the same behavior in H 2 SO 4 , but in NaCl Rn increase with temperature, meaning that corrosion resistance increase. Ultimet alloy presented higher R n values at 60 • C than Waspaloy in both electrolytes. However, at 25 • C, Waspaloy has higher R n values than Ultimet. For LI, only Waspaloy at 60 • C in NaCl presented uniform corrosion, but kurtosis value corresponds to pitting corrosion (as in all samples). However, skewness present values corresponding to uniform corrosion. Ultimet at 25 • C shows the same behavior in both electrolytes with mixed corrosion, but skewness shows pitting corrosion.
Nevertheless, considering that SE was 0.153, skewness values of 1.04 and 1.01 are in-side of uncertain error, which can be considered a uniform process. This meaning that uniform and localized processes are occurring on the Ultimet surface. Waspaloy in NaCl at 60 • C presents the behavior previously described.
High kurtosis values can indicate instability or high amplitude transients in different distribution, provoking different processes on the metal surface [59].

Power Spectral Density Analysis
For power spectral density (PSD) analysis, it is necessary to transform the time-domain EN to frequency-domain by applying FFT, since there is a correlation with EN signal (with a polynomial filter applied), after which spectral density is calculated with Equations (9) and (10) [60].
The interpretation of PSD is based on limit frequency to cut frequency, with the cut frequency indicates when to begin and end a slope. A slope could be helpful to find the corrosion mechanism. Cut frequency gives information about sample representation after pitting [35,36]. The slope is defined by βx and is represented by Equation (11): The frequency zero limit (Ψ 0 ) gives material dissolution information because PSD is related to the total energy present in the system [22]. It is essential to clarify that material dissolution is only present in the current PSD [56,57]. The following table was proposed by Mansfeld et al. [54] in 1999 to determine the corrosion phenomena occurring on the material surface. This table is adapted to decibels (see Table 5) [60,61]. Results of Table 6 show the parameters obtained from the first test because experiments have not presented many variations.   Figure 7d). The values of Ψ 0 show similar values for Ultimet and Waspaloy at both temperatures. However, at 60 • C, the dissolution of the material is higher (see Table 6).
higher (see Table 6). Figure 8 shows PSD plots in H2SO4 for both superalloys. Here, 7a Ultimet and Waspaloy present B values of −22.9 and 20.4 dB (V) respectively (see Table 6), where such values are related with passive and pitting values that accord with  6 dB (A)). Meanwhile, Waspaloy shows a slope of 1.5, and positive values are associated with passivation. Waspaloy presents a lower Ψ 0 value of -91 dBi, and Ultimet has −72.2 dBi. Those results indicate that Ultimate presents a higher material dissolution than Waspaloy in NaCl at 25 °C.
At 60 °C in NaCl (Figure 8c,d) Table 6), where such values are related with passive and pitting values that accord with Table 5 The results concerning type and corrosion mechanisms presented some uncertainty for slope analysis [60][61][62]. For that reason, slope values present limitations to determine the type of corrosion in superalloys.

Noise Impedance (Z n )
The noise impedance, Z n (f ), also called spectral noise resistance, is defined as [63,64]: Z n is calculated by the square root of the PSD division of potential and current [56,64]. The electrochemical noise impedance is related to the corrosion resistance, and the inverse is related to conductance and corrosion rate [65,66]. The results concerning type and corrosion mechanisms presented some uncertainty for slope analysis [60][61][62]. For that reason, slope values present limitations to determine the type of corrosion in superalloys.

Noise Impedance (Zn)
The noise impedance, Zn (f), also called spectral noise resistance, is defined as [63,64]: Zn is calculated by the square root of the PSD division of potential and current [56,64]. The electrochemical noise impedance is related to the corrosion resistance, and the inverse is related to conductance and corrosion rate [65,66]. Figure 9 shows the spectral noise resistance for each media. Table 7 presents results of spectral noise resistance for each media and different temperatures. All samples presented a reduction of Zn when frequency increases. Some researchers associated the Zn with corrosion rate, associated with Ψ 0 , and Rn [49,61]. In this research, Ψ 0 values presented more relation with Zn. Moreover, systems where they are divergent occur where Ψ 0 are nearly values (H2SO4 at 60 °C). Waspaloy presented a passivation behavior in the spectral noise resistance (as well as in potential slope).  Figure 9 shows the spectral noise resistance for each media. Table 7 presents results of spectral noise resistance for each media and different temperatures. All samples presented a reduction of Zn when frequency increases. Some researchers associated the Z n with corrosion rate, associated with Ψ 0 , and Rn [49,61]. In this research, Ψ 0 values presented more relation with Zn. Moreover, systems where they are divergent occur where Ψ 0 are nearly values (H 2 SO 4 at 60 • C). Waspaloy presented a passivation behavior in the spectral noise resistance (as well as in potential slope).

Discussion
Jing mentioned in further research [41,42,[67][68][69] that Ultimet presents a single facecentered-cubic phase with relatively fine, uniform grains (size from 50 to 250 µm) and annealing twins. At higher magnification, it presents a widmanstatten morphology. It was related to the heat-treated condition of material and partial dislocations provoking misorientation [69][70]. Kelekanjeri et al. [71] reported that the Waspaloy surface's porosities were due to chemical attack and not by precipitates presence. This indicates that the material has been aging.
The critical aspect of superalloys is their microstructure. The high-temperature strength is based on a stable face-centered cubic (FCC) matrix combined with either precipitation strengthening (age-hardenable) and/or solid solution hardening. In age hardenable nickel-based superalloys, the γ′ intermetallic (Ni3, Al, Ti) is generally present for strengthening. The non-hardenable nickel-, cobalt-, and iron-based superalloys rely on solid-solution strengthening of the FCC (γ) matrix. Cobalt-based superalloys may develop some precipitation strengthening from carbides (Cr7C3, M23C6). No intermetallic phase is strengthening equal to γ′ strengthening in nickel-base alloys [72,73].

Discussion
Jing mentioned in further research [41,42,[67][68][69] that Ultimet presents a single facecentered-cubic phase with relatively fine, uniform grains (size from 50 to 250 µm) and annealing twins. At higher magnification, it presents a widmanstatten morphology. It was related to the heat-treated condition of material and partial dislocations provoking misorientation [69,70]. Kelekanjeri et al. [71] reported that the Waspaloy surface's porosities were due to chemical attack and not by precipitates presence. This indicates that the material has been aging.
The critical aspect of superalloys is their microstructure. The high-temperature strength is based on a stable face-centered cubic (FCC) matrix combined with either precipitation strengthening (age-hardenable) and/or solid solution hardening. In age hardenable nickel-based superalloys, the γ intermetallic (Ni3, Al, Ti) is generally present for strengthening. The non-hardenable nickel-, cobalt-, and iron-based superalloys rely on solid-solution strengthening of the FCC (γ) matrix. Cobalt-based superalloys may develop some precipitation strengthening from carbides (Cr 7 C3, M 23 C 6 ). No intermetallic phase is strengthening equal to γ strengthening in nickel-base alloys [72,73].
The mechanical, thermal, and microstructure stability of superalloys depend on alloying elements and their concentrations. The design strategy is stabilizing the compositions, microstructures, and thermal-mechanical properties [74,75]. Some alloying elements stabilize the control of the microstructural and mechanical properties of superalloys. These elements are divided into four categories according to their main effects on these properties: comprising base elements, mechanical strengthening elements, long-term stability elements, and the oxidation resistance elements (for example, Al and Cr may strengthen the alloy matrix and improve oxidation resistance).
The corrosion behavior of a Cobalt-Tungsten-Carbon alloy using potentiodynamic and potentiostatic polarization techniques in 0.5 M sulfuric acid, at room temperature, was studied by Hume et al. [76]. They demonstrated that the additions of Tungsten (>8 wt.%) and Carbon (>0.15 wt.%) influence the corrosion behavior of the alloy. With increasing additions of tungsten and carbon, the corrosion current density and the critical current density were reduced. The corrosion potential shifted to more positive values with increasing additions. In this type of study, it can be observed how the alloying elements influence.
Some research [25][26][27][28][29][30]36,37,[53][54][55][56][57][58] indicates that Several EN procedures correlating time-dependent fluctuation of current and potential during the corrosion process have been used to indicate the type of corrosion occurring. For instance, it is well recognized that the primary source of electrochemical noise is the passive film breakdown process and repassivation process. This is crucial to superalloy behavior with aeronautical applications. Since this type of structural component is exposed to different industrial and marine atmospheres.
Electrochemical noise cathodic and anodic reactions cause changes in material surfaces: when superalloys are exposed to aqueous solutions, independently of the mix, the hydrogen will react by an evolution reaction, given by the following chemical reaction: Less information about the behavior of superalloys at 25 and 60 • C degree has been developed. Almost all information employs potentiodynamic polarization and Tafel analysis. In EN, the transients amplitude is related to the size of the pitting nucleation of the pitting and the frequency with localized corrosion.
Some other workers have attributed the transients to the reduction of some species present in the solution. The transients presented in time series of potential and current characteristics of pitting nucleation or metastable pitting [19,24,36,52,53].
Kup [77] analyzed the alloying effect on several superalloys' corrosion behavior with Mo, Ni, and Al. They used the potentiodynamic polarization technique in 3 wt.% NaCl solution. Their conclusions were the percentage of Mo, Al, and Ni play an essential role in inhibiting corrosion. In the linear sweep, voltammograms showed that the free corrosion potentials become more hostile as de Mo content increases. Ting [78] applied an aging treatment to a 718 nickel-base alloy with previous finishing treatments. The finishing process modifies the pitting corrosion resistance because it affects the surface the stresses condition.
Electrochemical noise gives mechanistic information about corrosion systems employing statistical methods. However, authors as Mansfeld and Eden [52,54] suggest that LI should be used with discretion to determine the type of corrosion. For that reason, this research employed different methods to determine the corrosion type. Eden and various researchers [35,36,50,51] propose kurtosis and skewness to analyze corrosion systems. Xia et al. [28] mentioned that kurtosis and skewness could be used to determine the shape of the distribution and transients' peaks. The skewness helps determine the phenomenon of the corrosion system. If it is positive (for ECN), this indicates a predominance of anodic transients, whereas if it is negative, this indicates a predominance of cathodic transients. Moreover, Xia [29] mentioned that it presents a higher standard error. This error can be reduced by increasing the number of data acquired.
Similar results to those previously presented were shown, and these converged with LI and skewness results. Razavi et al. [79] founded that Waspaloy in 3.5 wt.% NaCl with PPC presented pitting corrosion but with a passivation tendency between 0 and 473 mV. Pan et al. [80] concluded that K38C Ni-based superalloy presents passivation, but pitting occurs at the final stage. Pan's results accord with results obtained here and in Razavi's research and given Ni superalloys behavior, the work of Zhang and Ma [81,82] The importance of analyzing the current and potential transients using high polynomials allows obtaining better results in superalloys behavior. Gaona et al. [25,30] study localized corrosion in Ni-based superalloys at room temperature using electrochemical noise (localization index (LI) and noise resistance), in 10 wt.% H 2 SO 4 and CH 3 COOH solutions. The difference in results could be attributed to acid concentration and type of data processing. The employment of a low polynomials grade to filter signals or not using a filter provokes a variation in standard deviation, and results could be uncertain. Nickel-based superalloys have an excellent response to low-temperature corrosion but tend to localize corrosion in the electrolyte tested.
The study of superalloys electrochemical behavior at room temperature is important, and even more so, few works are using the electrochemical noise technique. Klein and Virtanen [83] studied a new γ/γ'-strengthened Co-based superalloy in comparison with pure Co at room temperature in 1 M Na 2 SO 4 (pH 5.9) and 0.1 M NaOH (pH 12.8) aqueous solutions. Electrochemical impedance spectroscopy and potentiodynamic polarization determine that electrochemical behavior presented passivation in acid environments, and Si as alloying element considerably increases the corrosion resistance.
PSD gives essential information about material dissolution that could be compared with Rn results. The Ψ 0 showed similar results in that Rn, Ultimet showed in NaCl higher values of resistance at 60 • C than at 25 • C (2.12 × 10 4 and 7.58 × 10 3 Ω·cm 2 ), indicating that corrosion resistance is higher at 60 • C. This result is related with Ψ 0 where Ultimet showed −72.2 dBi at 25 • C and −78.7 dBi at 60 • C, so that dissolution will be higher at 25 • C in NaCl. This behavior is present in other research with different materials [24,55], denoting that Rn and Ψ 0 can be considered counterpart parameters to determine corrosion resistance. However, to analyze the type of corrosion, slope parameters divergent from statistical parameters, they cannot be considered mechanistic [84,85]. For this type of alloy, slope parameters should be employed with discretion.
This research agrees with diverse authors in Z n use and relation with R n and corrosion kinetics [27,28,55,86,87]. Moreover, Z n results can be associated with Ψ 0 (material degradation), so all parameters can be related to corrosion rate.

Conclusions
After studying the frequency analysis of transients by electrochemical noise of two superalloys (Waspaloy and Ultimet), immersed at 3.5 wt.% in H 2 SO 4 and NaCl solutions at two different temperatures, 25 and 60 • C:

•
Results indicated that, after trend removal, EN signals conserved transients and fluctuation behavior and gave practical corrosion information for removing DC. The standard deviation of ECN and the noise resistance have direct relationships with the corrosion rate. • Statistical analysis (time-domain) and PSD (frequency domain) results showed that NaCl Ultimet presents higher corrosion resistance at 60 • C than at 25 • C.

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In NaCl at 25 • C, Ultimet and Waspaloy presented localized corrosion, and at 60 • C mixed. Furthermore, in H 2 SO 4 at 60 • C, Waspaloy presented uniform corrosion by LI evaluation parameter. Skewness showed the same result. • When skewness is negative, it indicates a significant predominance of cathodic transients. • EN results show that R n and Ψ 0 parameters should be considered as a counterpart to calculate the corrosion resistance of materials. • For this type of superalloy, LI and skewness are more practical to determine corrosion than PSD slope.

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High kurtosis values are associated with a chaotic system. • The discordance of statistical results could be related to developing a different corrosion process on the surface. When LI indicates mixed corrosion and skewness uniform corrosion, it suggests that localized and uniform corrosion occurs on the surface, but uniform corrosion is the predominant system. • To reduce uncertainty created by a standard error in the calculation of kurtosis and skewness, it is necessary to increase the number of data acquired for EN characterization.  Institutional Review Board Statement: Not applicable.
Informed Consent Statement: Not applicable.

Data Availability Statement:
The data presented in this study are available on request from the corresponding author.