Improving Mechanical Properties of Mg–Sc Alloy by Surface AZ31 Layer

: Building a gradient structure inside the Mg alloy structure can be expected to greatly improve its comprehensive mechanical properties. In this study, AZ31/Mg–Sc laminated composites with gradient grain structure were prepared by hot extrusion. The microstructure and mechanical properties of the Mg–1Sc alloy with different extrusion temperatures and surface AZ31 ﬁne-grain layers were investigated. The alloy has a more obvious gradient microstructure when extruded at 350 ◦ C. The nanoscale hardness value of Mg–1Sc alloy was improved through ﬁne-grain strengthening and solution strengthening of the surface AZ31 ﬁne-grain layer. The strength of Mg–1Sc alloy was improved due to the ﬁne-grain strengthening and dislocation strengthening of the surface AZ31 ﬁne-grain layer, and the elongation of Mg–1Sc alloy was increased by improving the distribution of the microstructure.


Introduction
Magnesium (Mg) alloys have the advantages of low density, high specific strength, good damping capacity, machinability, and retrievability, which have broad application prospects in the fields of transportation, aerospace, the military industry, and so on [1][2][3][4]. However, due to the close-packed hexagonal crystal structure of Mg alloys, insufficient slipping systems can be activated at lower temperatures, resulting in poor ductility and low strength [5,6]. Therefore, in order to improve their mechanical properties, much research work has been carried out.
The mechanical properties of Mg alloys depend on grain size and orientation to a great extent. Controlling texture and refining the grain by proper processing technology is an important method to improve the mechanical properties of Mg alloys [7]. Grain refinement can improve the strength of Mg alloys obviously, but the ductility of Mg alloys is sacrificed to some extent, so that the relationship between strength and ductility is always inverted [8]. Previous studies [9,10] showed that the introduction of a gradient structure in metal materials can break the original coupled material properties and allow one or more properties to be improved independently, which provides a new idea and development direction for the preparation of high strength and high ductility materials.
A Mg-1.0 wt.% Sc (Mg-1Sc) alloy ingot was prepared from pure Mg and Mg-10 wt.% Sc, and AZ31 alloy ingots were prepared from pure Mg, Al, Zn, and Mg-10 wt.% Mn master alloys by an induction melting furnace under the protection of CO 2 + SF 6 atmosphere. The ingots were homogenized at 400 • C for 24 h and the ingots were air-cooled. The as-cast AZ31 alloy was firstly extruded as plates of 2 mm at 320 • C (or 350 • C) with an extrusion ratio of 50.6. At this time, part of the AZ31 alloy remained in the extrusion cylinder. Subsequently, the Mg-Sc alloy was extruded under the same conditions. Since the high temperature hardness of AZ31 alloy is much higher than that of Mg-Sc binary alloy, during the extrusion process of the Mg-Sc alloy AZ31 alloy adhered to the surface of the Mg-Sc alloy, forming the Mg-Sc alloy with AZ31 alloy on both upper and lower surfaces. After several extrusion tests at different temperatures, it was found that the surface quality of the sheet was better when extruded at 320 • C and 350 • C, without edge cracks, and the AZ31 sheet could adhere to the surface of the Mg-Sc alloy. Therefore, these two extrusion temperatures were selected. The schematic diagram of the extrusion processes is shown in Figure 1. The Mg-Sc alloys (MS) were defined as MS-320 and MS-350 with an extrusion temperature of 320 • C and 350 • C, respectively. The Mg-Sc alloys with an AZ31 surface layer (MSAZ) were defined as MSAZ-320 and MSAZ-350 with extrusion temperature of 320 • C and 350 • C, respectively. The actual chemical composition of the alloys was detected using a plasma-atomic emission spectrometer (ICP-AES) and the results are given in Table 1.

Microstructure Characterization
X-ray diffraction (XRD) was performed to identify the phase precipitated in the alloys at a glancing angle of 1.5° using a Cu target (40 kV, 150 mA), within the range of 2θ = 10-90° and at a scanning rate of 4° min −1 . Optical microscopy (OM) was performed for optical grain size observations. Specimens were firstly polished by SiC paper and were then etched with a solution composed of 14 mL ethanol, 2 mL acetic acid, and 2.5 g picric acid to reveal the grain boundaries. Electron backscatter diffraction (EBSD) was performed on a JEOL JSM-7800F (JEOL, Tokyo, Japan) for microstructure characterization. Specimens were mechanically polished with 4000# SiC paper and electropolished in an AC2 solution (800 mL ethanol + 100 mL propanol + 18.5 mL distilled water + 10 g hydroxyquinoline + 75 g citric acid + 41.5 g sodium thiocyanate + 15 mL perchloric acid) at 20 V for 2 min at −20 °C. The EBSD experiments were accomplished at 25 kV with a step size of 0.5 μm.

Hardness and Tensile Tests
The nanoindentation behavior was investigated using the Agilent G200 (Agilent, Santa Clara, CA, USA) and Hysitron TI950 (Hysitron, Minneapolis, MN, USA). The extrusion direction-transverse direction (ED-TD) plane of the specimens was detected with a compression depth of 300 nm at 20 ± 2 °C. The specimens with dimensions of 10 × 10 × 2 mm 3 were prepared by mechanical polishing with SiC paper, followed by polishing by w0.25 diamond polishing agent. Tensile specimens were prepared from the extruded sheets along the ED, with a 24 mm gauge length, and a 4 mm gauge width. The tensile tests were carried out on a uniaxial tensile testing machine (SUST, Zhuhai, China) at an initial strain rate of 10 −3 s −1 at ambient temperature, and three parallel specimens were used to obtain representative results. Figure 2 shows XRD patterns of the MS and MSAZ alloys. There was only a peak of α-Mg in the four alloys without a peak of the second phase, indicating that the alloys under various conditions have very little or no second phase. As such, to a great extent, the mechanical properties of the alloys are determined by the α-Mg matrix phase. Figure 3 shows the optical microstructure of MSAZ-320 and MSAZ-350 alloys. The AZ31 alloy adhered to the surface of the Mg-Sc alloy to form a composite alloy in the process of hot extrusion at 320 °C or 350 °C. At the two different extrusion temperatures,

Microstructure Characterization
X-ray diffraction (XRD) was performed to identify the phase precipitated in the alloys at a glancing angle of 1.5 • using a Cu target (40 kV, 150 mA), within the range of 2θ = 10-90 • and at a scanning rate of 4 • min −1 . Optical microscopy (OM) was performed for optical grain size observations. Specimens were firstly polished by SiC paper and were then etched with a solution composed of 14 mL ethanol, 2 mL acetic acid, and 2.5 g picric acid to reveal the grain boundaries. Electron backscatter diffraction (EBSD) was performed on a JEOL JSM-7800F (JEOL, Tokyo, Japan) for microstructure characterization. Specimens were mechanically polished with 4000# SiC paper and electropolished in an AC2 solution (800 mL ethanol + 100 mL propanol + 18.5 mL distilled water + 10 g hydroxyquinoline + 75 g citric acid + 41.5 g sodium thiocyanate + 15 mL perchloric acid) at 20 V for 2 min at −20 • C. The EBSD experiments were accomplished at 25 kV with a step size of 0.5 µm.

Hardness and Tensile Tests
The nanoindentation behavior was investigated using the Agilent G200 (Agilent, Santa Clara, CA, USA) and Hysitron TI950 (Hysitron, Minneapolis, MN, USA). The extrusion direction-transverse direction (ED-TD) plane of the specimens was detected with a compression depth of 300 nm at 20 ± 2 • C. The specimens with dimensions of 10 × 10 × 2 mm 3 were prepared by mechanical polishing with SiC paper, followed by polishing by w0.25 diamond polishing agent. Tensile specimens were prepared from the extruded sheets along the ED, with a 24 mm gauge length, and a 4 mm gauge width. The tensile tests were carried out on a uniaxial tensile testing machine (SUST, Zhuhai, China) at an initial strain rate of 10 −3 s −1 at ambient temperature, and three parallel specimens were used to obtain representative results. Figure 2 shows XRD patterns of the MS and MSAZ alloys. There was only a peak of α-Mg in the four alloys without a peak of the second phase, indicating that the alloys under various conditions have very little or no second phase. As such, to a great extent, the mechanical properties of the alloys are determined by the α-Mg matrix phase. extrusion temperature made the pressure in the extrusion cylinder larger and the deformation of the top layer of the alloy larger. Therefore, when the extrusion temperature is 320 °C, a thick and abnormally coarse grain structure was produced. It is worth noting that the AZ31 fine-grain layer appeared on the surface of the Mg-Sc alloys at both extrusion temperatures. When extruded at 320 °C, the AZ31 fine-grain layer on the surface was about 150 μm, and when extruded at 350 °C, the AZ31 fine-grain layer on the surface was about 120 μm.    5 show the microstructure and corresponding energy dispersive X-ray spectroscopy (EDS) mapping of the transition region of MSAZ-320 and MSAZ-350, respectively. It is interesting that there was a transition layer between the surface AZ31 and the core Mg-Sc alloy in both two alloys. According to the results of EDS, the transition layer of the two alloys was the Mg-Sc alloy and the thickness was about 30 μm. At two extrusion temperatures, the grain size of the Mg-Sc alloy in the transition layer is obviously different from that in the core region, especially at 350 °C. It is worth noting that the grain size between these two regions is not a gradual change, but rather a sudden change in grain size.  Figure 3 shows the optical microstructure of MSAZ-320 and MSAZ-350 alloys. The AZ31 alloy adhered to the surface of the Mg-Sc alloy to form a composite alloy in the process of hot extrusion at 320 • C or 350 • C. At the two different extrusion temperatures, abnormal coarse AZ31 grains appeared on the topmost surface of the alloy. This is because the deformation of the topmost surface was large and the storage energy was the highest during extrusion, which resulted in abnormal grain growth during extrusion and subsequent cooling. When extruded at 320 • C, the coarse grain layer of AZ31 is about 70 µm. When extruded at 350 • C, the surface AZ31 coarse-grain layer is about 25 µm. The lower extrusion temperature made the pressure in the extrusion cylinder larger and the deformation of the top layer of the alloy larger. Therefore, when the extrusion temperature is 320 • C, a thick and abnormally coarse grain structure was produced. It is worth noting that the AZ31 fine-grain layer appeared on the surface of the Mg-Sc alloys at both extrusion temperatures. When extruded at 320 • C, the AZ31 fine-grain layer on the surface was about 150 µm, and when extruded at 350 • C, the AZ31 fine-grain layer on the surface was about 120 µm. abnormal coarse AZ31 grains appeared on the topmost surface of the alloy. This is because the deformation of the topmost surface was large and the storage energy was the highest during extrusion, which resulted in abnormal grain growth during extrusion and subsequent cooling. When extruded at 320 °C, the coarse grain layer of AZ31 is about 70 μm. When extruded at 350 °C, the surface AZ31 coarse-grain layer is about 25 μm. The lower extrusion temperature made the pressure in the extrusion cylinder larger and the deformation of the top layer of the alloy larger. Therefore, when the extrusion temperature is 320 °C, a thick and abnormally coarse grain structure was produced. It is worth noting that the AZ31 fine-grain layer appeared on the surface of the Mg-Sc alloys at both extrusion temperatures. When extruded at 320 °C, the AZ31 fine-grain layer on the surface was about 150 μm, and when extruded at 350 °C, the AZ31 fine-grain layer on the surface was about 120 μm.  show the microstructure and corresponding energy dispersive X-ray spectroscopy (EDS) mapping of the transition region of MSAZ-320 and MSAZ-350, respectively. It is interesting that there was a transition layer between the surface AZ31 and the core Mg-Sc alloy in both two alloys. According to the results of EDS, the transition layer of the two alloys was the Mg-Sc alloy and the thickness was about 30 μm. At two extrusion temperatures, the grain size of the Mg-Sc alloy in the transition layer is obviously different from that in the core region, especially at 350 °C. It is worth noting that the grain size between these two regions is not a gradual change, but rather a sudden change in grain size.   5 show the microstructure and corresponding energy dispersive Xray spectroscopy (EDS) mapping of the transition region of MSAZ-320 and MSAZ-350, respectively. It is interesting that there was a transition layer between the surface AZ31 and the core Mg-Sc alloy in both two alloys. According to the results of EDS, the transition layer of the two alloys was the Mg-Sc alloy and the thickness was about 30 µm. At two extrusion temperatures, the grain size of the Mg-Sc alloy in the transition layer is obviously different from that in the core region, especially at 350 • C. It is worth noting that the grain size between these two regions is not a gradual change, but rather a sudden change in grain size.  To obtain more accurate statistics on the grain size of the three different regions, EBSD data of the three regions of the two alloys were collected in a certain area. Figure 6 shows the microstructure and statistical histogram of the grain size of MSAZ-320 and MSAZ-350. The equiaxed grains with relatively uniform size were observed in the three different regions of MSAZ-320 and MSAZ-350. When the extrusion temperature was 320 °C, the difference between the grain size of the AZ31 fine-grain layer and the Mg-Sc transition layer was small, and the grain size of the former was slightly larger than that of the latter, which was also caused by the larger deformation and higher storage energy of the surface layer when the extrusion temperature was 320 °C. Similarly, the grain size of the Mg-Sc region in the core was higher than that in the transition layer. When the extrusion temperature was 350 °C, the grain size of the three regions showed a gradient increasing trend. With the increase in extrusion temperature, the difference of grain size of the two alloys between the Mg-Sc transition layer was not significant, but the grain size difference between the core of Mg-Sc alloy was great. The average grain size (AG) of the core of MSAZ-350 (5.05 μm) was about twice that of the core of MSAZ-320 (2.51 μm).  To obtain more accurate statistics on the grain size of the three different regions, EBSD data of the three regions of the two alloys were collected in a certain area. Figure 6 shows the microstructure and statistical histogram of the grain size of MSAZ-320 and MSAZ-350. The equiaxed grains with relatively uniform size were observed in the three different regions of MSAZ-320 and MSAZ-350. When the extrusion temperature was 320 °C, the difference between the grain size of the AZ31 fine-grain layer and the Mg-Sc transition layer was small, and the grain size of the former was slightly larger than that of the latter, which was also caused by the larger deformation and higher storage energy of the surface layer when the extrusion temperature was 320 °C. Similarly, the grain size of the Mg-Sc region in the core was higher than that in the transition layer. When the extrusion temperature was 350 °C, the grain size of the three regions showed a gradient increasing trend. With the increase in extrusion temperature, the difference of grain size of the two alloys between the Mg-Sc transition layer was not significant, but the grain size difference between the core of Mg-Sc alloy was great. The average grain size (AG) of the core of MSAZ-350 (5.05 μm) was about twice that of the core of MSAZ-320 (2.51 μm). To obtain more accurate statistics on the grain size of the three different regions, EBSD data of the three regions of the two alloys were collected in a certain area. Figure 6 shows the microstructure and statistical histogram of the grain size of MSAZ-320 and MSAZ-350. The equiaxed grains with relatively uniform size were observed in the three different regions of MSAZ-320 and MSAZ-350. When the extrusion temperature was 320 • C, the difference between the grain size of the AZ31 fine-grain layer and the Mg-Sc transition layer was small, and the grain size of the former was slightly larger than that of the latter, which was also caused by the larger deformation and higher storage energy of the surface layer when the extrusion temperature was 320 • C. Similarly, the grain size of the Mg-Sc region in the core was higher than that in the transition layer. When the extrusion temperature was 350 • C, the grain size of the three regions showed a gradient increasing trend. With the increase in extrusion temperature, the difference of grain size of the two alloys between the Mg-Sc transition layer was not significant, but the grain size difference between the core of Mg-Sc alloy was great. The average grain size (AG) of the core of MSAZ-350 (5.05 µm) was about twice that of the core of MSAZ-320 (2.51 µm).  Figure 7 shows the inverse pole figures (IPF) and pole figures corresponding to the three regions of MSAZ-320. The surface AZ31 region of MSAZ-320 presented a strong basal texture with the maximum strength of 33.81, and the basal planes of most grains were parallel to the ED-TD plane of the sheet. Compared with the surface AZ31 fine-grain layer, the texture of the Mg-Sc transition layer was deflected from normal direction (ND) to ED and TD, and the texture was more divergent, with an intensity of 9.37. The texture in the Mg-Sc core layer still deflected from ND to ED and TD, and the texture strength was smaller than that in the transition layer, which was 8.61. In other words, the texture of MSAZ-320 gradually diverged from the surface to the center, showing a trend of gradually decreasing the texture strength. Figure 8 shows IPF and pole figures corresponding to the three regions of MSAZ-350. Similarly, the surface AZ31 fine-grain layer of MSAZ-350 also presented a strong basal texture, the maximum strength of which was 46.85, and the basal planes of almost all grains were parallel to the ED-TD plane of the sheet. The texture of the Mg-Sc transition layer also deflected from Nd to ED and TD, with an intensity of 13.16. The texture strength of the Mg-Sc core layer was 9.20. The texture strength of the MSAZ-350 alloy also decreased gradually from the surface to the center. The texture strength of each region of MSAZ-350 was higher than MSAZ-320. Figure 9 shows IPF and pole figures of the transition region of the two alloys, and also represents the fact that the texture strength of the transition region of MSAZ-350 alloy was higher than that of MSAZ-320.  Figure 7 shows the inverse pole figures (IPF) and pole figures corresponding to the three regions of MSAZ-320. The surface AZ31 region of MSAZ-320 presented a strong basal texture with the maximum strength of 33.81, and the basal planes of most grains were parallel to the ED-TD plane of the sheet. Compared with the surface AZ31 fine-grain layer, the texture of the Mg-Sc transition layer was deflected from normal direction (ND) to ED and TD, and the texture was more divergent, with an intensity of 9.37. The texture in the Mg-Sc core layer still deflected from ND to ED and TD, and the texture strength was smaller than that in the transition layer, which was 8.61. In other words, the texture of MSAZ-320 gradually diverged from the surface to the center, showing a trend of gradually decreasing the texture strength. Figure 8 shows IPF and pole figures corresponding to the three regions of MSAZ-350. Similarly, the surface AZ31 fine-grain layer of MSAZ-350 also presented a strong basal texture, the maximum strength of which was 46.85, and the basal planes of almost all grains were parallel to the ED-TD plane of the sheet. The texture of the Mg-Sc transition layer also deflected from Nd to ED and TD, with an intensity of 13.16. The texture strength of the Mg-Sc core layer was 9.20. The texture strength of the MSAZ-350 alloy also decreased gradually from the surface to the center. The texture strength of each region of MSAZ-350 was higher than MSAZ-320. Figure 9 shows IPF and pole figures of the transition region of the two alloys, and also represents the fact that the texture strength of the transition region of MSAZ-350 alloy was higher than that of MSAZ-320.     GPa, respectively. However, at the same extrusion temperature, whether there was AZ31 alloy on the surface of Mg-Sc alloy or not resulted in a great difference. For example, when the extrusion temperature was 320 °C, the hardness value of the Mg-Sc alloy with AZ31 alloy was about twice than that of the alloy without AZ31. As such, when the extrusion temperature was 350 °C, the hardness value of the Mg-Sc alloy with AZ31 alloy was about twice than that of the alloy without AZ31. This indicates that the Mg-Sc alloy surface composite AZ31 alloy was beneficial to improving the hardness value of the alloy.   15 GPa, respectively. However, at the same extrusion temperature, whether there was AZ31 alloy on the surface of Mg-Sc alloy or not resulted in a great difference. For example, when the extrusion temperature was 320 • C, the hardness value of the Mg-Sc alloy with AZ31 alloy was about twice than that of the alloy without AZ31. As such, when the extrusion temperature was 350 • C, the hardness value of the Mg-Sc alloy with AZ31 alloy was about twice than that of the alloy without AZ31. This indicates that the Mg-Sc alloy surface composite AZ31 alloy was beneficial to improving the hardness value of the alloy.   GPa, respectively. However, at the same extrusion temperature, whether there was AZ31 alloy on the surface of Mg-Sc alloy or not resulted in a great difference. For example, when the extrusion temperature was 320 °C, the hardness value of the Mg-Sc alloy with AZ31 alloy was about twice than that of the alloy without AZ31. As such, when the extrusion temperature was 350 °C, the hardness value of the Mg-Sc alloy with AZ31 alloy was about twice than that of the alloy without AZ31. This indicates that the Mg-Sc alloy surface composite AZ31 alloy was beneficial to improving the hardness value of the alloy.   Figure 11 shows true stress-strain curves and related mechanical properties of the alloys. At the two different extrusion temperatures, the tensile strength of the Mg-1Sc alloy sheet extruded at 320 • C was 34 MPa higher than that of the alloy extruded at 350 • C, but the elongation was 7.2% lower than that of the alloy extruded at 350 • C. For the Mg-1Sc alloy with AZ31 on the surface, when the extrusion temperature was 320 • C, the tensile strength of the alloy was 82 MPa higher than that of the alloy extruded at 350 • C, and the elongation was 3.8% lower than that of the alloy extruded at 350 • C. That is, for the same alloy, the higher the extrusion temperature, the lower the tensile strength, but the higher the elongation. However, at the same extrusion temperature, both the tensile strength and elongation of Mg-1Sc alloys with AZ31 on the surface were higher than those of the Mg-1Sc alloys without AZ31. This indicates that the AZ31 composite on the Mg-1Sc alloy surface is not only beneficial to improving the tensile strength, but also to improving the elongation.

Nanoindentation and Mechanical Properties
Metals 2021, 11, x FOR PEER REVIEW 9 o Figure 11 shows true stress-strain curves and related mechanical properties of alloys. At the two different extrusion temperatures, the tensile strength of the Mgalloy sheet extruded at 320 °C was 34 MPa higher than that of the alloy extruded at °C, but the elongation was 7.2% lower than that of the alloy extruded at 350 °C. For Mg-1Sc alloy with AZ31 on the surface, when the extrusion temperature was 320 °C, tensile strength of the alloy was 82 MPa higher than that of the alloy extruded at 350 and the elongation was 3.8% lower than that of the alloy extruded at 350 °C. That is, the same alloy, the higher the extrusion temperature, the lower the tensile strength, the higher the elongation. However, at the same extrusion temperature, both the ten strength and elongation of Mg-1Sc alloys with AZ31 on the surface were higher than th of the Mg-1Sc alloys without AZ31. This indicates that the AZ31 composite on the M 1Sc alloy surface is not only beneficial to improving the tensile strength, but also to proving the elongation.

Effect of AZ31 Surface Fine Layer on Microstructure
It can be seen from the microstructure figures (Figures 3-5) that the surface AZ31 a Mg-1Sc alloy are completely bonded and have good interfacial bonding quality. This r resents a good metallurgical bond, mainly due to the large strain during the extrus deformation process, which facilitates the bonding of the sheet interface [21]. When truded at 320 °C, the thickness of AZ31 fine-grain layer on the surface is about 150 μ and the thickness of AZ31 in the upper and lower layers accounts for 15% of the com sition of the whole alloy. The grain size of the alloy increases from 1.88 μm to 2.51 from the surface region to the core region. When extruded at 350 °C, the thickness of AZ fine-grain layer on the surface is about 120 μm, and the AZ31 on the upper and low layers accounts for 12% of the composition of the whole alloy. The grain size of the al increases from 1.32 μm to 5.05 μm from the surface region to the core region. That is, Mg-1Sc alloy and AZ31 composites with gradient structure were formed by the hot trusion.
The dynamic recrystallization was found in the three regions of the two alloys Figure 6. With the increase in extrusion temperature, the grains in the transition layer Mg-1Sc grow slightly, and the grains in the core layer of Mg-1Sc grow obviously, wh the grain size of AZ31 on the surface decreases. This is because when the extrusion te perature is lower and more deformation heat and friction heat are generated in the ext sion process, resulting in the static recrystallization of AZ31 on the surface under resid heat, finally leading to obvious grain growth on the surface [22]. With the increase of trusion temperature, the grain size of the transition layer and core layer Mg-1Sc increa due to the increase in extrusion temperature which promotes the growth of recrystalliz grain [23,24].

Effect of AZ31 Surface Fine Layer on Microstructure
It can be seen from the microstructure figures (Figures 3-5) that the surface AZ31 and Mg-1Sc alloy are completely bonded and have good interfacial bonding quality. This represents a good metallurgical bond, mainly due to the large strain during the extrusion deformation process, which facilitates the bonding of the sheet interface [21]. When extruded at 320 • C, the thickness of AZ31 fine-grain layer on the surface is about 150 µm, and the thickness of AZ31 in the upper and lower layers accounts for 15% of the composition of the whole alloy. The grain size of the alloy increases from 1.88 µm to 2.51 µm from the surface region to the core region. When extruded at 350 • C, the thickness of AZ31 fine-grain layer on the surface is about 120 µm, and the AZ31 on the upper and lower layers accounts for 12% of the composition of the whole alloy. The grain size of the alloy increases from 1.32 µm to 5.05 µm from the surface region to the core region. That is, the Mg-1Sc alloy and AZ31 composites with gradient structure were formed by the hot extrusion.
The dynamic recrystallization was found in the three regions of the two alloys in Figure 6. With the increase in extrusion temperature, the grains in the transition layer of Mg-1Sc grow slightly, and the grains in the core layer of Mg-1Sc grow obviously, while the grain size of AZ31 on the surface decreases. This is because when the extrusion temperature is lower and more deformation heat and friction heat are generated in the extrusion process, resulting in the static recrystallization of AZ31 on the surface under residual heat, finally leading to obvious grain growth on the surface [22]. With the increase of extrusion temperature, the grain size of the transition layer and core layer Mg-1Sc increases due to the increase in extrusion temperature which promotes the growth of recrystallized grain [23,24].

Effect of AZ31 Surface Fine Layer on Hardness
According to the results of the hardness tests, the nano-indentation hardness value of MS-320 is slightly higher than that of MS-350. This is because when the extrusion temperature is low, the larger deformation degree of the alloy leads to the reduction of the grain size, and the fine grain size is conducive to the increase in the alloy hardness. When a layer of AZ31 alloy is bonded on the surface of Mg-1Sc alloy, its nano-hardness is significantly improved, because the grain size of AZ31 on the surface is small, and AZ31 alloy contains Al, Zn, Mn, and other elements. The hardness value can be improved by grain refinement and solution strengthening [25,26]. In addition, the nano-hardness of MSAZ-350 is slightly higher than that of MSAZ-320, which is also related to the finer grain size on the surface of MSAZ-350. In short, due to the relatively coarse grain size of Mg-1Sc and the small variety and content of alloying elements in the alloy, it cannot play a good role in improving the hardness. The surface AZ31 with fine grain and solution strengthening effect is beneficial to improving the hardness value of Mg-1Sc alloy and expanding its application range.

Effect of Temperature on Mechanical Properties
The strength of MS alloy and MSAZ alloy obtained at 320 • C is higher than that of MS alloy and MSAZ alloy obtained at 350 • C. This is related to the fact that the deformation degree of the alloy is different with different extrusion temperatures. When the extrusion temperature is lower, the deformation degree of the alloy is larger, and the grain size is smaller. Previous studies [27][28][29] pointed out that in Mg alloys, there is a close relationship between material strength and grain size, which satisfies the Hall-Petch formula: where σ s is the yield strength, σ 0 is the frictional resistance of dislocation movement in a single crystal, K is a constant related to the material, and d is the average grain size. It can be seen that the yield strength of Mg alloy has a linear relationship with d −1/2 [28], that is, the yield strength increases with the decrease in grain size. In addition, Zhang et al. [30,31] also pointed out that grain refinement can increase the number of dislocation motion disorders and reduce the length of dislocation groups inside the grain, resulting in an increase in the yield strength of Mg alloys. Figure 12 shows kernel average misorientation (KAM) mapping of the transition region of MSAZ-320 and MSAZ-350. It can be seen that the dislocation density of the alloy at 320 • C is significantly higher than that at 350 • C through the dislocation maps of the transition region at two kinds of extrusion temperatures. That is, when the extrusion temperature is lower, the strength of the alloy is higher.

Effect of AZ31 Surface Fine Layer on Mechanical Properties
The mechanical properties of the Mg-Sc alloy with an AZ31 surface fine-grain layer are better than those without the AZ31 surface fine-grain layer at different extrusion temperatures. On the one hand, the surface AZ31 improves the strength of Mg-Sc alloy. Figure 6 shows that AZ31 at both extrusion temperatures has a relatively fine grain size on the surface, which can improve the strength of the alloy through fine-grain strengthening. However, the elongation of MS alloys obtained at 320 • C is lower than that obtained at 350 • C. This is mainly related to the texture of the alloy. With the increase in extrusion temperature, the basal poles of MS deflected towards ED, and finally a double peaked basal texture occurred, which is beneficial to improving the fracture elongation of the alloy [32]. The elongation of the MSAZ alloy obtained at 320 • C is lower than that of MSAZ alloy obtained at 350 • C. This is mainly related to the distribution of microstructure, which will be explained in detail in the next section.

Effect of AZ31 Surface Fine Layer on Mechanical Properties
The mechanical properties of the Mg-Sc alloy with an AZ31 surface fine-grain layer are better than those without the AZ31 surface fine-grain layer at different extrusion temperatures. On the one hand, the surface AZ31 improves the strength of Mg-Sc alloy. Figure 6 shows that AZ31 at both extrusion temperatures has a relatively fine grain size on the surface, which can improve the strength of the alloy through fine-grain strengthening. It can be seen from the dislocation map of the transition region at two extrusion temperatures that the dislocation density of the AZ31 layer is significantly higher than that of Mg-1Sc alloy, which is also conducive to the improvement of alloy strength. In addition, Figure 13 depicts the distribution maps of Schmid Factor (SF) for the basal slip of the alloys. It shows that the average SF of the surface fine-grain layer, the transition layer, and the core layer is 0.22, 0.18, and 0.21, respectively, at 320 • C. It is difficult to distinguish the intensity characteristics of the three regions from the distribution of SF. When extruded at 350 • C, the SF of the surface region reaches a peak in the range of 0-0.2, and a lower SF is continuously distributed in the range of 0.2-0.4. The SF of the core region is intermittently distributed with low SF in the range of 0-0.2, and reaches the peak in the range of 0.2-0.5. The average SF increased from 0.13 to 0.27 from the surface region to the core region. The lower SF is not conducive to start the base slip and the improvement of the yield strength. Therefore, this is also one of the reasons why the surface AZ31 improves the strength of Mg-Sc alloy.

Conclusions
The effect of an AZ31 surface fine-grain layer on the microstructure and mechanical properties of Mg-Sc alloy were investigated. It was found that: (1) AZ31/Mg-Sc composites with gradient grain structure were prepared by hot extrusion. The thickness of AZ31 accounts for 15% and 12% of the composition of the Figure 13. Quantitative analysis of (0001)/<11-20> basal slip Schmid factor (SF) of (a,d) surface fine-grain layer, (b,e) transition layer, and (c,f) core layer of MSAZ-320. Quantitative analysis of (0001)/<11-20> basal slip Schmid factor (SF) of (g,j) surface fine-grain layer, (h,k) transition layer, and (i,l) core layer of MSAZ-350.
On the other hand, the surface AZ31 fine-grain layer also improves the elongation of Mg-Sc alloy. Besides the texture composition and grain size, the distribution of the microstructure is also an important parameter affecting the strength and plasticity of Mg alloys. Research [33,34] shows that the construction of gradient structure in metal materials can effectively inhibit the early deformation localization of metal in the process of plastic deformation, alleviate the internal stress concentration, and hinder the occurrence of cracks, so as to achieve a better strength plastic ratio. Therefore, the surface AZ31 fine-grain layer is beneficial to improving the mechanical properties of Mg-Sc alloy.

Conclusions
The effect of an AZ31 surface fine-grain layer on the microstructure and mechanical properties of Mg-Sc alloy were investigated. It was found that: (1) AZ31/Mg-Sc composites with gradient grain structure were prepared by hot extrusion. The thickness of AZ31 accounts for 15% and 12% of the composition of the whole alloy when extruded at 320 • C and 350 • C, respectively; (2) The nanoscale hardness value of Mg-1Sc alloy is increased more than two times through fine-grain strengthening and solution strengthening of the surface AZ31 fine-grain layer; (3) The surface AZ31 fine-grain layer improves the strength of the Mg-1Sc alloy through fine-grain strengthening and dislocation strengthening, and increases the elongation by improving the distribution of microstructure; (4) Different extrusion temperatures have different control effects on the microstructure of the AZ31/Mg-Sc composites. In this paper, the alloy has a more obvious gradient microstructure when extruded at 350 • C.