Energy, Environmental, Economic, and Technological Analysis of Al-GnP Nanoﬂuid- and Cryogenic LN 2 -Assisted Sustainable Machining of Ti-6Al-4V Alloy

: The quest for advanced cooling/lubrication approaches for energy-efﬁcient, eco-benign, and cost-effective sustainable machining processes is garnering attention in academia and industry. Electrical and embodied energy consumption plays an important role in reducing CO 2 emissions. In the present study, new empirical models are proposed to assess sustainable indicators. The embodied energy, environmental burden, and cost of coolant/lubricant have been added in the proposed models. Initially, optimal levels of minimum quantity lubrication (MQL) oil ﬂow rate, liquid LN 2 ﬂow rate, air pressure, and nanoparticle concentration were found. Based on optimal technological parameters, experiments were performed under the same cutting conditions (machining parameters) for MQL and cryogenic LN 2 -assisted external turning of Ti6-Al-4V titanium alloy. The electric power and energy consumption, production time/cost, and CO 2 emissions were assessed for a unit cutting-tool life. Later, speciﬁc responses were measured and compared between both cooling and lubrication approaches. Results showed that hybrid Al-GnP nanoﬂuid consumed 80.6% less speciﬁc cumulative energy and emitted 88.7% less total CO 2 emissions. However, cryogenic LN 2 extended tool life by nearly 70% and incurred 4.12% less speciﬁc costs with 11.1% better surface quality. In summary, after Energy–Economy–Ecology–Engineering technology (4E)-based analysis, cryogenic LN 2 is sustainable economically but not environmentally and there is a need to improve the sustainable production of LN 2 at an industrial scale to achieve environmental sustainability. The present study provides useful information to establish clean machining processes.


Introduction
With the increasing population and higher demand for industrial products, energy consumption is increasing. Due to the depletion of natural resources, oil prices are increasing over time. However, the negative oil prices in the USA are an exceptional case due to COVID-19. The manufacturing sector plays an essential role in fulfilling the world demand for discrete products. Although energy prices in China did not increase significantly and the energy cost fluctuates at around CNY 0.723/kWh for the industrial sector, the carbon footprints of Chinese electric grids are very high as compared to electric grids in Europe [1]. In the world, a 56% growth in electricity demand is expected between 2010 and 2040. Consequently, CO 2 emissions will increase by 46% in the next 30 years [2]. Most of the

Literature Review
The present section will deal with a brief literature review about energy consumption, CO 2 emissions, and production cost.

Energy Consumption
As the electrical power consumption for different components of a machine tool varies, it is difficult to determine the energy consumption demand for each component and each stage. The electrical power structures in the machining process change with the change in the machining stage.
Cooling and lubrication approaches have a significant effect on the electrical energy consumption of machine tools [7]. However, the investigation of electrical energy consumption is not enough to evaluate the sustainability of the machining processes. Thus, in recent years, researchers have included the embodied energy of consumed resources [8].
In their study, the machine tool energy was decomposed into three components, which is not enough to provide information about the energy consumption of each component and stage. Cumulative energy demand (CED) consists of two parts, i.e., direct electrical energy demand and indirect embodied energy demand. Indirect energy is associated with the cutting tool, workpiece, lubricant, lubricant preparation, cleaning, and disposal activities.
In the life cycle assessment (LCA) methodology, CED is an essential key indicator to assess total energy [9].

Environmental Burden
Assessment of CO 2 emissions under holistic system boundaries is a fundamental step to reduce the environmental burden of mechanical machining processes. Carbon emission can be estimated by adopting different methods. GaBi Software [10]-the commercial software used for the life cycle costing, life cycle working environment, and life cycle assessment of products-needs a lot of accurate data for a satisfactory analysis. Ic et al. [11] conducted an experimental study to measure CO 2 emission and surface finish during the turning of 7075 aluminum alloys. Optimal cutting parameters were found considering minimal CO 2 emission and surface roughness. In another study, Yi et al. [12] studied the environmental impacts of consumed resources. The authors added the carbon footprints of the cutting-tool workpiece and coolant consumed during the machining process.
The machining process transforms raw material into useful mechanical products, and during the production of parts, CO 2 is emitted due to electrical energy consumption and utilization of cutting tools, coolants, and workpiece material. The electrical energy consumed during machining stages (direct) and embodied energy used by consumed resources (indirect) are responsible for CO 2 emission. As such, during the machining process, each machining stage and consumed resource contributes to CO 2 emissions depending upon the corresponding process time. The CO 2 emissions for disposal activities are considered zero as both MQL and cryogenic LN 2 require no disposal-related activity. The footprints of electrical energy consumption are very low as compared to the embodied energy of consumed resources [13]. Thus, for the holistic environmental sustainability of cooling/lubrication approaches, it is necessary to include the footprints of coolants and lubricants.

Production Cost
In the past, the production cost for machining products was calculated using the Taylor cost model [14]. The proposed model was only useful for dry cutting conditions and did not include the influence of coolant and lubricant on the production cost. Later, Kalpakjian and Serope [15] also worked on the assessment of production cost. The authors calculated the total sum of cutting tool cost, machining cost, and cost incurred due to change of cutting tool. With the advancement of manufacturing processes, there is a need to propose the microeconomics-level cost model. Thus, Branker et al. [16] proposed the first cost model at the microeconomics level. The author included all the traditional (tooling cost, material cost, overhead cost, and material cost) and non-traditional (energy and environmental cost) components of cost in the model. Jamil et al. [17] developed cost models for dry, minimum quantity lubrication (MQL), and cryogenic cooling approaches in the machining of titanium alloy. The results showed that the cryogenic cooling approach reduced production cost by 34% and 39% as compared to the dry and MQL approaches, respectively. Priarone et al. [6] employed a bottom-up approach (BUA) to develop cost models for the dry and wet turning of Ti-6Al-4V alloys. Optimal cutting parameters were found for the minimum specific cost, production time, CO 2 emission, and energy consumption. Recently, Khan et al. [13] calculated the production cost of the nanofluid-assisted machining process and provided a break-down of the production cost into sub-components. The authors observed that cost of consumed resources was a significant portion of the total cost. Various cooling and lubrication approaches possess their pros and cons. Thus, it is necessary to investigate and compare the holistic economic sustainability assessment of cooling/lubrication approaches.

Cooling and Lubrication Approaches
Higher material removal rates (MRR) should be practiced for lesser costs. However, a higher MRR leads to severe wear of cutting tools [18]. Each metal-processing industry has a requirement to achieve higher productivity without compromising cutting-tool life. For this purpose, advanced lubrication/cooling (lubricooling) approaches have been introduced. Nanofluid MQL (NFMQL)-assisted machining technology is garnering fame in industry and academia. Researchers enhanced the productivity of the machining process without compromising the life of the cutting tool [19]. Recently, nanoparticles have been used with conventional lubricants to obtain enhanced thermo-physical properties and achieve a reduction in friction and wear. Nanoparticles are also found to enhance heat transfer capabilities improving the efficiency of machine tools. It is a fact that cost and emission incurred by cutting tools are just a small fraction of the total cost and emissions per part [20].
Mostly, straight, soluble, semi-synthetic, and synthetic oils are either used separately or as in a hybrid cooling agent. Besides dry machining processes, some cooling/lubricationassisted machining such as the flood cooling approach, near dry lubrication, high-pressure cooling, solid lubrication integrated with sprayed cooling, oil-water emulsion, nanofluid and hybrid nanofluids approaches are employed at machining workshops to machine hard and difficult-to-cut materials [21]. In another study, Khan et al. [22] developed new energy-integrated cost models for nanofluid-assisted machining. The authors holistically investigated the 3E-based (Energy, Environment, Economy) sustainability of the hybrid Al-GnP nanofluid-assisted machining process. In another study, Khanafer et al. [23] worked on the machinability and sustainability analysis of multi-walled carbon nanotubes (MWCNTs) and alumina oxide-based nanofluid-assisted machining. Though the authors claimed to have the lowest power using MWCNTs, neither the cost model nor the energy consumption models were formulated. The selection of nanoparticles and preparation of nanofluids are essential aspects before the application of nanofluids in the machining process. Likewise, during nanofluid preparation, the selection of base fluid and the size of nanoparticles are the two most important factors [24]. The quality of nanofluids is evaluated by investigating their important properties, such as their thermo-physical properties and their tribology (wear and coefficient of friction).
Apparently, cryogenic fluids such as CO 2 and LN 2 remove heat in the cutting zone and fluid evaporates as nitrogen gas, which is already 79% of the atmosphere. This makes cryogenic cooling (LN 2 ) the most eco-benign and clean approach for application in machining processes. However, it is essential to consider the embodied energy required to synthesize the unit liter of LN 2 and the corresponding environmental burden of LN 2 . Damir et al. [25] developed a single score indicator evaluation method to investigate the environmental impact of cryogenic cooling assisted turning of Ti-6Al-4V. Lu et al. [26] are the first authors who investigated the effect of including embodied energy of LN 2 on the Metals 2021, 11, 88 5 of 23 total energy consumption and compared it with the conventional emulsion approach. A state-of-art review paper published by Jawahir et al. [27], is considered as the Bible of the cryogenic assisted mechanical machining processes. The manuscript consisted of a holistic investigation of the application of cryogenics in the manufacturing process. The authors discussed the effect of LN 2 on process mechanism, material properties, quality of products produced, tribological interface interactions and thermal aspects, surface and sub-surface modification, performance enhancement, predictive model development, and economic aspects. However, the effect of LN 2 on machine tool power consumption and the cost of LN 2 was not discussed.

Empirical Models for Sustainable Indicators
In the past, researchers worked on the empirical modeling of a sustainable indicator. They employed the black box approach (BBA) to develop empirical models. This approach is relatively simple and it involves empirical models without considering the footprints of consumed resources. Consequently, in the BBA-based modelling approach, machine tools are considered as a black-box entity. Thus, this approach is not suitable for the holistic modeling of sustainable machining processes. However, the bottom-up approach (BUA) is holistic in nature and it considers both direct and indirect resource consumption.
In the present study, empirical models for energy, CO 2 emissions, and cost are developed using the BUA approach. Cycle time was obtained under the new system boundaries and power consumption was measured for various functionality states of a machine tool. Energy consumption was obtained based on data of cycle time and power consumption. cryogenic cooling (LN2) the most eco-benign and clean approach for application in machining processes. However, it is essential to consider the embodied energy required to synthesize the unit liter of LN2 and the corresponding environmental burden of LN2. Damir et al. [25] developed a single score indicator evaluation method to investigate the environmental impact of cryogenic cooling assisted turning of Ti-6Al-4V. Lu et al. [26] are the first authors who investigated the effect of including embodied energy of LN2 on the total energy consumption and compared it with the conventional emulsion approach. A state-of-art review paper published by Jawahir et al. [27], is considered as the Bible of the cryogenic assisted mechanical machining processes. The manuscript consisted of a holistic investigation of the application of cryogenics in the manufacturing process. The authors discussed the effect of LN2 on process mechanism, material properties, quality of products produced, tribological interface interactions and thermal aspects, surface and sub-surface modification, performance enhancement, predictive model development, and economic aspects. However, the effect of LN2 on machine tool power consumption and the cost of LN2 was not discussed.

Empirical Models for Sustainable Indicators
In the past, researchers worked on the empirical modeling of a sustainable indicator. They employed the black box approach (BBA) to develop empirical models. This approach is relatively simple and it involves empirical models without considering the footprints of consumed resources. Consequently, in the BBA-based modelling approach, machine tools are considered as a black-box entity. Thus, this approach is not suitable for the holistic modeling of sustainable machining processes. However, the bottom-up approach (BUA) is holistic in nature and it considers both direct and indirect resource consumption.
In the present study, empirical models for energy, CO2 emissions, and cost are developed using the BUA approach. Cycle time was obtained under the new system boundaries and power consumption was measured for various functionality states of a machine tool. Energy consumption was obtained based on data of cycle time and power consumption.  Cycle time was defined as the total time required to complete a unit path from the workpiece ( Figure 1). It includes idle time, air cutting time, cutting time, tool change time, and cooling/lubrication time.
Cycle time : The idle time consist of standby time, material handling time, and setup time.
Idle time :  (1) and (2) and the subsequent equations in this section (Equations (3)- (12)) are given in the nomenclature and Table 2.
Power consumption was considered due to various states of machine tool and it can be modelled as in Equation (3).
Energy consumption during the cycle time was measured and expressed as in Equation (4).
MRR means material removal rate and MRV stands for material removal volume; both MRR and MRV are calculated according to Equations (5) and (6), respectively.
Cumulative energy demand (CED) is the sum of total energy obtained from electrical energy consumption and embodied energy of resources consumed. It can be defined as in Equation (7).
The specific CED (S_CED) can be defined as the unit amount of energy consumption removed per mm 3 of material removed.
Carbon emission was calculated from both electrical energy consumption and embodied energy.
Specific carbon emission is the amount of carbon emission released per unit amount of material removed.
Cost per part consists of energy cost, cutting cost, and resource consumption cost. It is worth mentioning that machining experiments were performed for a unit tool. Thus, for comparison purposes, the cost of the cutting tool was neglected.
Similarly, for the comparison, the specific cost was calculated

Experimentation
The present section will focus on the experimental setup, measurement of responses, and data inventory collection.

Work Material and Tooling
A rod (Ø 40 mm) of titanium alloy was used in the external turning process undercooling and lubrication conditions. A standard heat treatment procedure was performed on the workpiece before machining. The work material, after carrying out the heat treatment process [28], possessed an ultimate tensile strength, yield strength (0.2% proof stress), and elongation of 1003.48 MPa, 927.35 MPa, and 15.05 MPa respectively. The chemical composition of the material is shown in Table 1. It contains the primary alpha and inter-granular beta phase. The hardness of the workpiece was 348 ± 4 HV. The microstructure of the workpiece is shown in Figure 2. A universal testing machine (UTM) (Haida, China) was used to test the tensile strength and compressive strength of Ti-6Al-4V alloy. Table 1. Chemical composition of (in mass percentage) of workpiece alloys [29]. The experiments were performed on a Computer Numerical Control CNC lathe machine (BOOHI SK50P, Baoji Zhongcheng, Shanghai, China) with an input power of 5.7 kW and a maximum spindle speed of 160-1200 rpm. Uncoated carbide inserts with tool geometry (rake angle of 0 • and the relief angle of 11 • ) were procured from Zhuzhou Cemented Carbide Cutting Tools Co., Ltd., Shanghai, China.

Experimentation
The present section will focus on the experimental setup, measurement of responses, and data inventory collection.

Work Material and Tooling
A rod (Ø 40 mm) of titanium alloy was used in the external turning process undercooling and lubrication conditions. A standard heat treatment procedure was performed on the workpiece before machining. The work material, after carrying out the heat treatment process [28], possessed an ultimate tensile strength, yield strength (0.2% proof stress), and elongation of 1003.48 MPa, 927.35 MPa, and 15.05 MPa respectively. The chemical composition of the material is shown in Table 1. It contains the primary alpha and inter-granular beta phase. The hardness of the workpiece was 348 ± 4 HV. The microstructure of the workpiece is shown in Figure 2. A universal testing machine (UTM) (Haida, China) was used to test the tensile strength and compressive strength of Ti-6Al-4V alloy. Table 1. Chemical composition of (in mass percentage) of workpiece alloys [29].
The experiments were performed on a Computer Numerical Control CNC lathe machine (BOOHI SK50P, Baoji Zhongcheng, Shanghai, China) with an input power of 5.7 kW and a maximum spindle speed of 160-1200 rpm. Uncoated carbide inserts with tool geometry (rake angle of 0° and the relief angle of 11°) were procured from Zhuzhou Cemented Carbide Cutting Tools Co., Ltd., Shanghai, China.

Hybrid Cooling and Lubrication Approaches
Experiments were performed under two types of cooling-and lubrication-assisted machining processes. Hybrid nanofluids (prepared by the two-step method) were procured from Sigma-Aldrich [30]. Hybrid nanofluid was impinged in the cutting zone through cutting Unilube micro lubrication systems (CH8280, Unist, NY, USA). Nanofluids were prepared with different volumetric concentrations and used immediately after preparation. It is worth mentioning that the thermal conductivity, viscosity, and coefficient of friction of the hybrid nanofluid (Al-GnP) were measured before application [22]. The Zeta potential of the Al-GnP nanoparticle was found to be 45 mV, which showed the good stability of the nanofluid.
The MQL system (applied alone) only provides efficient lubrication effects. It does not provide cooling effects at higher cutting conditions. On the other hand, cryogenic LN2

Hybrid Cooling and Lubrication Approaches
Experiments were performed under two types of cooling-and lubrication-assisted machining processes. Hybrid nanofluids (prepared by the two-step method) were procured from Sigma-Aldrich [30]. Hybrid nanofluid was impinged in the cutting zone through cutting Unilube micro lubrication systems (CH8280, Unist, NY, USA). Nanofluids were prepared with different volumetric concentrations and used immediately after preparation. It is worth mentioning that the thermal conductivity, viscosity, and coefficient of friction of the hybrid nanofluid (Al-GnP) were measured before application [22]. The Zeta potential of the Al-GnP nanoparticle was found to be 45 mV, which showed the good stability of the nanofluid.
The MQL system (applied alone) only provides efficient lubrication effects. It does not provide cooling effects at higher cutting conditions. On the other hand, cryogenic LN 2 provides good cooling and poor lubrication effects. Thus, both approaches work differently. A cylinder of liquid nitrogen (Dewar tank YD-50) was used to deliver the cryogenic medium with nozzles of various diameters (procure from Huilin company in Guangzhou, China). The extremely low temperature of −195°C was measured at the exit of the nozzle with the help of a thermal camera. A special tube (DN20-DN2000, Huilin company, Guangzhou, China) which can bear sub-zero temperatures was used to carry LN 2 from the tank and deliver it to, a nozzle. The experimental setup with both hybrid cooling/lubrication approaches has been shown in Figure 3. It can be seen that nanofluid impinged from the MQL system. provides good cooling and poor lubrication effects. Thus, both approaches work differently. A cylinder of liquid nitrogen (Dewar tank YD-50) was used to deliver the cryogenic medium with nozzles of various diameters (procure from Huilin company in Guangzhou, China). The extremely low temperature of −195 ℃ was measured at the exit of the nozzle with the help of a thermal camera. A special tube (DN20-DN2000, Huilin company, Guangzhou, China) which can bear sub-zero temperatures was used to carry LN2 from the tank and deliver it to, a nozzle. The experimental setup with both hybrid cooling/lubrication approaches has been shown in Figure 3. It can be seen that nanofluid impinged from the MQL system.

Experimental Procedure and Measurements
The experiments were performed under the same cutting conditions under hybrid nanofluid and cryogenic LN2 conditions. Preliminarily experiments were performed to find the optimal flow rate, air pressure, and nanofluid concentration. A new cutting insert was used for each experiment, all experiments were performed twice, and average values were recorded to avoid errors. For the selection of optimal levels of input parameters, a cutting speed of 70 m/min, a depth of cut of 0.8 mm, and a feed rate of 0.1 mm/rev were adjusted for all experiments. However, for response measurement analysis (from Sections 5.2-5.5), cutting speed values were varied. Experiments were performed at four cutting speed values, i.e., 30, 70, 110, and 150 m/min.
Power consumption was measured for various functionality states of the machine tool. Initially, fixed standby power was measured when the machine tool was switched on but spindle and feed motors were switched off. Later, the machine tool spindle was rotated with no cutting at various speeds and power consumption was measured. Finally, air cutting power was deducted from the total machine tool power to find the cutting

Experimental Procedure and Measurements
The experiments were performed under the same cutting conditions under hybrid nanofluid and cryogenic LN 2 conditions. Preliminarily experiments were performed to find the optimal flow rate, air pressure, and nanofluid concentration. A new cutting insert was used for each experiment, all experiments were performed twice, and average values were recorded to avoid errors. For the selection of optimal levels of input parameters, a cutting speed of 70 m/min, a depth of cut of 0.8 mm, and a feed rate of 0.1 mm/rev were adjusted for all experiments. However, for response measurement analysis (from Sections 5.2-5.5), cutting speed values were varied. Experiments were performed at four cutting speed values, i.e., 30, 70, 110, and 150 m/min.
Power consumption was measured for various functionality states of the machine tool. Initially, fixed standby power was measured when the machine tool was switched on but spindle and feed motors were switched off. Later, the machine tool spindle was rotated with no cutting at various speeds and power consumption was measured. Finally, air cutting power was deducted from the total machine tool power to find the cutting power. The cutting power was multiplied by the corresponding times to obtain electrical energy consumption. The power consumption was measured by using a load controls power meter. This power meter consisted of two isolated analogue outputs (0-10 V DC, 4-20 Milliamp DC). The specification of the power-measuring sensor was suitable to obtain precise data, i.e., the response time (0.015-10 s) and frequency range (1000 Hz). An optical microscope named ARTCAM and with the model 130-MT-WOM (Olympus Corporation, Tokyo, Japan) was used to measure the flank wear of the cutting inserts. When the cutting insert reached its required flank wear, cutting time was calculated to determine the life of the cutting insert. An air compressor with model number DDW30/8A (Denair company, Shanghai, China) with rated power of 800 W and a capacity of storing 30 L air was used to deliver MQL mist in the cutting region. The carbon emission signature (CES) of the Nanjing power grid station was found to be 258.2 kg CO 2 /MJ. The procedure for the calculation of CO 2 emission has been adopted from ref [1].

Data Inventory
Cycle time, power, and energy consumption data were calculated, and well-known companies such as ANHO and Walter Tools from Wuxi, China were visited for validating embodied energy data related to the cutting tools. The constant values are mentioned in Table 2.

Results and Discussion
This section deals with the selection of optimal levels of input parameters, the surface quality of the workpiece, energy consumption, CO 2 emission, and cost per part produced.

Selection of Optimal Levels of Input Parameters
The establishment of an economical cryogenic system is inevitable for the production of sustainable products. In the past, Mia et al. [35] used a very high flow rate of 20 L/min while impinging LN 2 in the cutting zone. Similarly, Sartori et al. [36] also used a cryogenic medium at 4 L/min for finishing machining the Ti6-Al-4V titanium alloy. In this study, the effect of LN 2 flow rate on cutting and machining energy was investigated and compared with dry cutting (Figure 4). It can be seen that the highest amount of power (885 W) was consumed under the dry cutting condition. Compared with dry cutting, 9.60% less cutting power and machining energy were consumed at a flow rate of 0.4 L/min. Increasing the flow rate of LN 2 from 0.4 L/min to 5 L/min results in an increase in cutting power. This phenomenon can be explained by the fact that as the LN 2 flow increases, it increases the work hardness of workpiece material. It is a well-known fact that higher cutting forces are generated while machining harder materials [37].
Metals 2021, 11, x FOR PEER REVIEW 10 of 23 the work hardness of workpiece material. It is a well-known fact that higher cutting forces are generated while machining harder materials [37]. Similar to the LN2 flow rate, the optimal flow rate for MQL was also found. Figure 5 demonstrates the effect of MQL flow rate on cutting power and machining energy. As the MQL flow rate increases from 50 to 200 mL/h, both cutting power and machining energy decrease. However, a further increase in MQL flow rate did not affect the power. Thus, the flow rate of 200 mL/h was selected as an economical and optimal flow rate. At this flow rate, 10.6% and 2.8% less cutting power and machining energy were consumed, respectively, when compared with dry cutting (flow rate = 0 mL/h). The flow rate of 200 mL/h is optimal where the MQL system provides an effective lubrication system. Thus, a further increase in flow rate does not improve the lubrication; rather, it only adds economic burdens [38].
Besides, the structure of Blaser cutting oil consists of octadecanoic (C17H35COOH), oleic (C17H33COOH), and linoleic fatty acids (C17H31COOH). This structure helps the oil to react with workpiece metal and to develop a strong boundary lubrication layer because of its excellent adsorption capacity.
Finding the optimal mist pressure is essential for better performance of the cutting process. Keeping all cutting parameters constant and an MQL flow rate of 200 mL/h, as can be observed from Figure 6, the increase in air pressure of the MQL system also resulted in a reduction in SCE. The obtained findings are in good agreement with published research [39]. The high pressure also provides better effects in terms of enhancing the convective heat transfer which helps in chip curling. Machining energy decreases as the MQL flow rate increases. However, an MQL flow rate of more than 200 mL/h has no significant effect on the machining energy. Thus, it was found that 200 mL/h is the optimal value of flow rate for minimal energy consumption. Similar to the LN 2 flow rate, the optimal flow rate for MQL was also found. Figure 5 demonstrates the effect of MQL flow rate on cutting power and machining energy. As the MQL flow rate increases from 50 to 200 mL/h, both cutting power and machining energy decrease. However, a further increase in MQL flow rate did not affect the power. Thus, the flow rate of 200 mL/h was selected as an economical and optimal flow rate. At this flow rate, 10.6% and 2.8% less cutting power and machining energy were consumed, respectively, when compared with dry cutting (flow rate = 0 mL/h). The flow rate of 200 mL/h is optimal where the MQL system provides an effective lubrication system. Thus, a further increase in flow rate does not improve the lubrication; rather, it only adds economic burdens [38].
Besides, the structure of Blaser cutting oil consists of octadecanoic (C17H35COOH), oleic (C17H33COOH), and linoleic fatty acids (C17H31COOH). This structure helps the oil to react with workpiece metal and to develop a strong boundary lubrication layer because of its excellent adsorption capacity.
Finding the optimal mist pressure is essential for better performance of the cutting process. Keeping all cutting parameters constant and an MQL flow rate of 200 mL/h, as can be observed from Figure 6, the increase in air pressure of the MQL system also resulted in a reduction in SCE. The obtained findings are in good agreement with published research [39]. The high pressure also provides better effects in terms of enhancing the convective heat transfer which helps in chip curling. Machining energy decreases as the MQL flow rate increases. However, an MQL flow rate of more than 200 mL/h has no significant effect on the machining energy. Thus, it was found that 200 mL/h is the optimal value of flow rate for minimal energy consumption.   Figure 7 shows the schematic view of small drops and large drops due to variation in air pressure. In addition, Balan et al. [40] conducted fundamental research on the effect of air pressure in the MQL system on energy consumption in the grinding process. The authors noted that the increase in cutting pressure reduces the size of the droplets from 24.0 to 2.77 μm. In another study, it was stated that the Reynolds number significantly increases with the increase in air pressure of the MQL system, and this phenomenon further enhances the flux density at the cutting zone [41]. However, in our study, it was noted that when increasing further air pressure from 0.5 to 0.6 MPa, there was negligible change in cutting power. With the increase in pressure, energy consumption (Em) initially increases; however, it starts decreasing at the highest level of pressure.   Figure 7 shows the schematic view of small drops and large drops due to variation in air pressure. In addition, Balan et al. [40] conducted fundamental research on the effect of air pressure in the MQL system on energy consumption in the grinding process. The authors noted that the increase in cutting pressure reduces the size of the droplets from 24.0 to 2.77 μm. In another study, it was stated that the Reynolds number significantly increases with the increase in air pressure of the MQL system, and this phenomenon further enhances the flux density at the cutting zone [41]. However, in our study, it was noted that when increasing further air pressure from 0.5 to 0.6 MPa, there was negligible change in cutting power. With the increase in pressure, energy consumption (Em) initially increases; however, it starts decreasing at the highest level of pressure.  Figure 7 shows the schematic view of small drops and large drops due to variation in air pressure. In addition, Balan et al. [40] conducted fundamental research on the effect of air pressure in the MQL system on energy consumption in the grinding process. The authors noted that the increase in cutting pressure reduces the size of the droplets from 24.0 to 2.77 µm. In another study, it was stated that the Reynolds number significantly increases with the increase in air pressure of the MQL system, and this phenomenon further enhances the flux density at the cutting zone [41]. However, in our study, it was noted that when increasing further air pressure from 0.5 to 0.6 MPa, there was negligible change in cutting power. With the increase in pressure, energy consumption (E m ) initially increases; however, it starts decreasing at the highest level of pressure. The quality of nanofluid is highly influenced by the concentration of nanofluid [22]. The effect of nanofluids with various fractions of nanoparticles on cutting power and machining energy is shown in Figure 8. It can be noted that an increase in nanoparticle concentration decreases the cutting power and machining energy. This is because increasing the nanoparticle volume percentage could lead to better frictional and heat transfer behavior. In terms of frictional behavior, increasing the nanoparticle volume percentage means there are more nanoparticles in the tool-workpiece interface zone. These nanoparticles act as rollers and accordingly decrease the induced friction. Furthermore, using a higher nanoparticle volume percentage could increase the overall heat transfer coefficient and accordingly decrease the machining and cutting power, as presented in the open literature [42,43]. The lowest cutting power was consumed at vol.% of 1.2. At this concentration, when compared with dry cutting, cutting power and machining energy were reduced by 15.2% and 3.4%, respectively.

Mechanism of Nanofluid and Cryogenic Cooling
Numerous researchers have mentioned the potential of hybrid nanofluids regarding the improvement of machining characteristics in the cutting of difficult-to-cut materials The quality of nanofluid is highly influenced by the concentration of nanofluid [22]. The effect of nanofluids with various fractions of nanoparticles on cutting power and machining energy is shown in Figure 8. It can be noted that an increase in nanoparticle concentration decreases the cutting power and machining energy. This is because increasing the nanoparticle volume percentage could lead to better frictional and heat transfer behavior. In terms of frictional behavior, increasing the nanoparticle volume percentage means there are more nanoparticles in the tool-workpiece interface zone. These nanoparticles act as rollers and accordingly decrease the induced friction. Furthermore, using a higher nanoparticle volume percentage could increase the overall heat transfer coefficient and accordingly decrease the machining and cutting power, as presented in the open literature [42,43]. The quality of nanofluid is highly influenced by the concentration of nanofluid [22]. The effect of nanofluids with various fractions of nanoparticles on cutting power and machining energy is shown in Figure 8. It can be noted that an increase in nanoparticle concentration decreases the cutting power and machining energy. This is because increasing the nanoparticle volume percentage could lead to better frictional and heat transfer behavior. In terms of frictional behavior, increasing the nanoparticle volume percentage means there are more nanoparticles in the tool-workpiece interface zone. These nanoparticles act as rollers and accordingly decrease the induced friction. Furthermore, using a higher nanoparticle volume percentage could increase the overall heat transfer coefficient and accordingly decrease the machining and cutting power, as presented in the open literature [42,43]. The lowest cutting power was consumed at vol.% of 1.2. At this concentration, when compared with dry cutting, cutting power and machining energy were reduced by 15.2% and 3.4%, respectively.

Mechanism of Nanofluid and Cryogenic Cooling
Numerous researchers have mentioned the potential of hybrid nanofluids regarding the improvement of machining characteristics in the cutting of difficult-to-cut materials The lowest cutting power was consumed at vol.% of 1.2. At this concentration, when compared with dry cutting, cutting power and machining energy were reduced by 15.2% and 3.4%, respectively.

Mechanism of Nanofluid and Cryogenic Cooling
Numerous researchers have mentioned the potential of hybrid nanofluids regarding the improvement of machining characteristics in the cutting of difficult-to-cut materials as high cutting conditions require superior thermal conductivity, lubrication, and sustainabil-ity. Biodegradable ester oil-based nano-additives extended the heat transfer, limited the friction tool edge wear. The following mechanism played a key role in heat dissipation and the resulting high-performance machining: • Hybrid nanofluids (variable-sized nano-additives) enhanced the performance of nanofluids behaving as spacers between the tool-workpiece contact interface. • Hybrid nanofluids atomized through the MQL mist containing nano-additives and air mixture formed a thin tribo-film on the tool and workpiece surface to enhance the tribological characteristics. • Hybrid nanofluids have the capability to penetrate well inside narrow surfaces, preventing rubbing of two surfaces [44].
Some complexities are also associated with the preparation of hybrid nanofluids: • Fine dissolution of nano-additives is a challenging task. • Nanoparticles enter our skin, cause allergies, and have a negative impact on plant growth and seeds.

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Nanoparticles are difficult to detect if opened in the air. Therefore, a hazard appraisal should also be reported to underscore the danger associated with the particles.
The cryogenic approach has phase change properties to dissipate heat from the cutting zone due to a huge difference in temperature between the cryogenic material and the surroundings. Spray cooling of cryogenic materials has the key advantage of changing phase and evaporating quickly without leaving a residue. The following characteristics or mechanisms highlight their importance in machining: • Cryogenic materials having extremely low temperature touch the workpiece and evaporate without leaving a residue.

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The self-generated high pressure does not require external pressure. • Quick evaporation also keeps the workpiece cold and does not affect the surrounding, creating space for the new coolant. • Furthermore, cryogenic coolants are sustainable in machining and also improve machining under harsh cutting conditions [45].

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The Leidenfrost effect of cryogenic nitrogen also helps to improve the process efficiency.

Surface Quality
It is very necessary to keep the excellent quality of the workpiece machined surface. Average surface roughness (Ra) is an important metric of surface integrity evaluation. Center-line average (CLA) or the arithmetic average height parameter is mostly used to quantify the surface roughness of a workpiece and is denoted as R a . For a specific length of sample, the average irregularities/deviations from the mean line are named as an average surface roughness (Ra). Figure 9 demonstrates the effect of increasing MRR on the surface quality of the workpiece. The feed rate and depth of cut and technological parameters for MQL and cryogenic systems were kept constant and only cutting speed was increased from 30 to 150 m/min. It can be observed in both cutting environments that surface quality improved as the MMR increased. However, cryogenic LN 2 machining produced better surface quality as compared to hybrid nanofluid machining. At the highest cutting parameters, a 6.61% better surface roughness was achieved in the cryogenic LN 2 approach when compared with the hybrid nanofluid approach. The results are in good agreement with previous literature [46].

Power and Energy Consumption
In the preliminary experiments, the optimal flow rates of LN2 and MQL mist were found to be 0.3 L/min and 200 mL/h, respectively. Keeping technological parameters at optimal values, experiments were performed under the same cutting conditions to investigate and compare the power and energy consumed by a machine tool in a cycle time [47].
Saving electrical energy consumption means saving energy cost. From Figure 10, it can be seen that the machine tool consumes more cutting and total power under aggressive cutting conditions (MRR = 3000 mm 3 ). At the lowest cutting conditions, cryogenicassisted machining consumed 10.7% more cutting power. However, as the cutting condition increased, cryogenic LN2-assisted cutting consumed less power. This can be explained since as the cutting speed was increased, cycle time decreased drastically. The decrease in cycle time keeps the workpiece interacting less with LN2 spray and it caused less workpiece hardening [48].

Power and Energy Consumption
In the preliminary experiments, the optimal flow rates of LN 2 and MQL mist were found to be 0.3 L/min and 200 mL/h, respectively. Keeping technological parameters at optimal values, experiments were performed under the same cutting conditions to investigate and compare the power and energy consumed by a machine tool in a cycle time [47].
Saving electrical energy consumption means saving energy cost. From Figure 10, it can be seen that the machine tool consumes more cutting and total power under aggressive cutting conditions (MRR = 3000 mm 3 ). At the lowest cutting conditions, cryogenic-assisted machining consumed 10.7% more cutting power. However, as the cutting condition increased, cryogenic LN 2 -assisted cutting consumed less power. This can be explained since as the cutting speed was increased, cycle time decreased drastically. The decrease in cycle time keeps the workpiece interacting less with LN 2 spray and it caused less workpiece hardening [48].

Power and Energy Consumption
In the preliminary experiments, the optimal flow rates of LN2 and MQL mist were found to be 0.3 L/min and 200 mL/h, respectively. Keeping technological parameters at optimal values, experiments were performed under the same cutting conditions to investigate and compare the power and energy consumed by a machine tool in a cycle time [47].
Saving electrical energy consumption means saving energy cost. From Figure 10, it can be seen that the machine tool consumes more cutting and total power under aggressive cutting conditions (MRR = 3000 mm 3 ). At the lowest cutting conditions, cryogenicassisted machining consumed 10.7% more cutting power. However, as the cutting condition increased, cryogenic LN2-assisted cutting consumed less power. This can be explained since as the cutting speed was increased, cycle time decreased drastically. The decrease in cycle time keeps the workpiece interacting less with LN2 spray and it caused less workpiece hardening [48].  Specific energy consumption (SEC) reciprocates the trends of machining power consumption. Cumulative energy demand (CED) is the total sum of electrical energy and embodied energy of used resources. From Figure 11, it is observed that as the MRR increases, SEC drastically decreases. This can be due to a one-third decrease in cutting time. Compared with the lowest MRR, the highest MRR had a nearly 80% lower SEC. The lower SEC for cryogenic LN 2 is due to the lower power consumption. Specific energy consumption (SEC) reciprocates the trends of machining power consumption. Cumulative energy demand (CED) is the total sum of electrical energy and embodied energy of used resources. From Figure 11, it is observed that as the MRR increases, SEC drastically decreases. This can be due to a one-third decrease in cutting time. Compared with the lowest MRR, the highest MRR had a nearly 80% lower SEC. The lower SEC for cryogenic LN2 is due to the lower power consumption. Similar to SEC, S_CED also decreased with the increase in MRR. However, at all cutting conditions, the hybrid Al-GnP-assisted process consumed much less S_CED as compared to the cryogenic LN2-assisted process. The processing of liquid nitrogen is a highly energy-intensive process. Nearly 2.6 million Joules of energy is required for the synthesis of one liter of LN2. Due to the unsustainable production of LN2, cryogenic LN2 consumed 447.02% more S_CED at the lowest MRR. However, at the highest MRR (vc = 150 mm/min), cryogenic LN2 produces a longer tool life. Thus, at the highest MRR, cryogenic LN2 consumed 72.5% more S_CED when compared with the lowest MRR.

Environmental Impacts
A "clean process" means a process that produces low carbon emissions. Both Al-GnP-and cryogenic-LN2-assisted machining processes are considered as clean and sustainable in general. In this study, efforts were made to investigate the environmental impacts of cooling/lubrication approaches. S_CE is the specific carbon emission due to electrical energy consumption, and S_CE is the amount of total CO2 emitted per part produced. The study was conducted in the Advanced Cutting Technologies laboratory of Nanjing city, China. For that reason, the CES value of 258.35 kg CO2/MJ for the Nanjing power grid station was used [34]. Figure 12 illustrates the effect of increasing MRR on CO2 emission. The increase in the cutting speed decreases the S_CEe, which agrees with Ic et al. [11]. The carbon footprint of the electrical energy consumption of the Al-GnP approach is relatively higher than that of the cryogenic approach. However, the cryogenic LN2 approach produces higher CO2 emissions at all cutting conditions. At the highest MRR, cryogenic LN2 produced 415.6% more CO2 as compared to the Al-GnP approach. Similar to SEC, S_CED also decreased with the increase in MRR. However, at all cutting conditions, the hybrid Al-GnP-assisted process consumed much less S_CED as compared to the cryogenic LN 2 -assisted process. The processing of liquid nitrogen is a highly energy-intensive process. Nearly 2.6 million Joules of energy is required for the synthesis of one liter of LN 2 . Due to the unsustainable production of LN 2 , cryogenic LN 2 consumed 447.02% more S_CED at the lowest MRR. However, at the highest MRR (vc = 150 mm/min), cryogenic LN 2 produces a longer tool life. Thus, at the highest MRR, cryogenic LN 2 consumed 72.5% more S_CED when compared with the lowest MRR.

Environmental Impacts
A "clean process" means a process that produces low carbon emissions. Both Al-GnPand cryogenic-LN 2 -assisted machining processes are considered as clean and sustainable in general. In this study, efforts were made to investigate the environmental impacts of cooling/lubrication approaches. S_CE e is the specific carbon emission due to electrical energy consumption, and S_CE P is the amount of total CO 2 emitted per part produced. The study was conducted in the Advanced Cutting Technologies laboratory of Nanjing city, China. For that reason, the CES value of 258.35 kg CO 2 /MJ for the Nanjing power grid station was used [34]. Figure 12 illustrates the effect of increasing MRR on CO 2 emission. The increase in the cutting speed decreases the S_CE e , which agrees with Ic et al. [11]. The carbon footprint of the electrical energy consumption of the Al-GnP approach is relatively higher than that of the cryogenic approach. However, the cryogenic LN 2 approach produces higher CO 2 emissions at all cutting conditions. At the highest MRR, cryogenic LN 2 produced 415.6% more CO 2 as compared to the Al-GnP approach. The very high CO 2 emissions per part in the cryogenic approach are due to the unsustainable liquid nitrogen production and its larger environmental footprints. It is important to mention that for the synthesis of each 1 kg LN 2 , nearly 0.67 kg CO 2 is emitted in space. Thus, it can be said that it is imperative to improve sustainable production of LN 2 for producing earth-friendly products.

Production Cost
Production cost is the sum of electricity cost, cost of consumed resources, and environmental cost. Specific energy cost mimics the trends of energy consumption. However, specific production cost highly depends upon the cost of consumed resources. The holistic cost model was developed in a previous study [49]. However, this study mainly deals with the comparison of the economic aspects of the hybrid nanofluid (MQL lubrication) and the cryogenic LN 2 cooling approaches. Thus, the cost of the workpiece, cutting tool, and the overhead cost were considered constant.
Material removal rate (MRR) strongly influences production costs. This is because at higher MRRs, cutting tools wear quickly due to the increase in friction and heat generation in the cutting zone [50]. The production cost also highly depends on the type and composition of cutting fluid. In addition, workpiece hardness, cutting parameters, and cutting tool type also affect the production cost.
It is pertinent to mention that in the present study, two sets of experiments were performed under the same cutting conditions to compare and evaluate the economic aspects. Unlike [13], a relatively small system boundary is considered.
From Figure 13, it can be seen that as more material is removed, the costs decreased. The minimum energy cost is achieved at the highest values of MRR. At all cutting conditions, the Al-GnP approach incurred a lower specific energy cost as compared to the cryogenic approach. For specific production cost, similar (decreasing with increase in MRR) trends were observed. However, the Al-GnP approach incurred 40.5%, 36.8%, and 37.11% less specific production cost at lower, medium, and high MRRs, respectively. At a very high MRR (3000 mm 3 /min), cryogenic LN 2 -assisted machining produced 4.14% lower-price products. Even though cryogenic LN 2 -assisted machining yielded longer tool life, its higher energy consumption and the production cost of LN 2 make it expensive. Under the considered system boundary, the cost of liquid nitrogen comprises nearly one-third of the total production cost. On the other hand, the concentration of nanoparticles has the smallest effect on the cost. As discussed in our previous study [45], nanoparticles have a significant effect on tool wear and tool life. However, in the present study, since the cutting time was shorter and a minimal amount of nanoparticles was used, a lesser effect of nanoparticles' concentration has been noted on the total cost.

Overall Comparison of Cooling/Lubrication Approaches
A holistic comparison of hybrid Al-GnP and cryogenic LN 2 approaches was plotted at higher cutting conditions. It is worth mentioning that all experiments were performed at the same higher cutting conditions (a p = 0.8 mm; f = 0.1 mm/rev; P = 0.5 MPa; v c = 150 m/min). Thus, the material removal rate was kept constant. Experiments were performed until the tool wear reached the end of its life. The Taylor tool life formula does not provide accurate results; therefore, real-time experiments were used to avoid errors. When the tool wear was very near to 300 µm, interpolation and extrapolation methods were used. The total energy consumption, total carbon emissions, and cost were calculated. However, due to different tool lives, both approaches yielded a different amount of removed material. To obtain specific energy, specific CO 2 emissions, and specific cost, the ratio of measured total response and MRV were obtained. The specific responses are necessary to estimate the processes' efficiencies.
From Figure 14, it can be seen that only two responses, tool life (TL) and material removed (MRV), are required at higher values for better outcomes, and all other sustainable metrics are required at minimal values. It is noted that the process performance of the cryogenic LN 2 approach is much better in terms of machinability. More specifically, the cryogenic LN 2 approach produced 11.1% better surface quality and 21.5% lower temperature. Additional experiments were performed to measure the temperature in the cutting zone. In addition, cryogenic LN 2 enhanced the tool life by 70.8% and removed 70.5% more material with a single cutting tool. However, cryogenic coolant production is not environmentally sustainable. That is why the Al-GnP-assisted machining emitted 88.7% less total CO 2 and 80.6% less specific CO 2. It is important to mention that cryo-LN 2 provides excellent cooling at a workpiece cutting tool interface. The Leidenfrost effect of LN 2 spray helps to reduce the cutting temperature. The highest S_CED and S_CE are the big question mark on the application of LN 2 in the machining process. From the results, it can be said the hybrid Al-GnP-assisted machining is eco-benign and environmentally friendly. The results also emphasize that sustainable production of LN 2 is imperative for the sustainable application of LN 2 in the machining process. Even though LN 2 is much more expensive than conventional MQL oil, the cryo-LN 2 approach yielded a 4.12% lower specific cost. This is because of the longer tool life and higher productivity. It is important to mention that cryo-LN2 provides excellent cooling at a workpiece cutting tool interface. The Leidenfrost effect of LN2 spray helps to reduce the cutting temperature. The highest S_CED and S_CE are the big question mark on the application of LN2 in the machining process. From the results, it can be said the hybrid Al-GnP-assisted machining is eco-benign and environmentally friendly. The results also emphasize that sustainable production of LN2 is imperative for the sustainable application of LN2 in the machining process. Even though LN2 is much more expensive than conventional MQL oil, the cryo-LN2 approach yielded a 4.12% lower specific cost. This is because of the longer tool life and higher productivity. The holistic comparison is further explained in the radar graph in Figure 15. A total of 15 metrics are compared in the radar graph. Data for operator health and safety and part cleaning were obtained from the local Chinese manufacturing industry. Figure 15 also shows that the cryo-LN2 approach is sustainable economically but not environmentally. It is pertinent to mention that in the 4E methodology, the fourth E represents engineering technology. The engineering technology used in hybrid nanofluid-MQL-assisted machining is well known and commonly used by many industries. However, efforts are needed to make more economical and efficient technology for LN2 production, storage, and transport. On the one side, nanofluids are difficult to synthesize and use. On the other side, LN2 gas can be the byproduct of the air liquefaction process. However, its production is energy-intensive, which is not environmentally friendly when it is produced for industrial application where bulk quantities are required. Thus, it is noted that both cooling (cryogenic LN2) and lubrication (Al-GnP) approaches have some limitations in terms of engineering technologies (fourth E). If these limitations are removed from engineering aspects, both cooling and lubrication approaches are the best alternatives of the conventional emulsion-assisted machining process [51].
The holistic comparison is further explained in the radar graph in Figure 15. A total of 15 metrics are compared in the radar graph. Data for operator health and safety and part cleaning were obtained from the local Chinese manufacturing industry. Figure 15 also shows that the cryo-LN 2 approach is sustainable economically but not environmentally. It is pertinent to mention that in the 4E methodology, the fourth E represents engineering technology. The engineering technology used in hybrid nanofluid-MQL-assisted machining is well known and commonly used by many industries. However, efforts are needed to make more economical and efficient technology for LN 2 production, storage, and transport. On the one side, nanofluids are difficult to synthesize and use. On the other side, LN 2 gas can be the byproduct of the air liquefaction process. However, its production is energy-intensive, which is not environmentally friendly when it is produced for industrial application where bulk quantities are required. Thus, it is noted that both cooling (cryogenic LN 2 ) and lubrication (Al-GnP) approaches have some limitations in terms of engineering technologies (fourth E). If these limitations are removed from engineering aspects, both cooling and lubrication approaches are the best alternatives of the conventional emulsion-assisted machining process [51].

Conclusions
International Standard Organization (ISO) 14995 deals with the environmental evaluation of manufacturing processes and machine tools. In the present study, a holistic sustainability assessment of lubrication (Al-GnP nanofluid) and cooling (cryogenic LN2) approaches was investigated. New empirical models have been proposed for energy, CO2 emission, and production cost. Experiments were performed under the same cutting conditions, and in both cutting environments, surface quality, energy, environmental, economic, and technological perspectives of Al-GnP nanofluid-and cryogenic LN2-assisted machining were measured and compared. Based on the obtained results, the following conclusions can be drawn.

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In conclusion, the cryogenic LN 2 cooling approach enhanced the tool life and reduced cutting power, SEC, the tool chip temperature, and specific production cost. At the same time, higher CO 2 emissions are associated with the energy-intensive nonsustainable production of LN 2 . 6.
At cutting speed v c = 150 m/min, the cryogenic approach outperformed in all sustainable metrics except specific cumulative energy demand and specific carbon emission. This was due to the extremely high embodied energy and carbon footprints associated with the production of liquid nitrogen.

Future Recommendation
In future research, a heuristic algorithm will be proposed which does not integrate the machining responses with sustainable indicators to obtain optimal cutting parameters. In addition, pressure head losses and transportation of liquid nitrogen will also be considered in a future study. Life cycle assessment (LCA) of these lubricooling approaches can be applied considering milling, drilling, and deep-hole drilling techniques. The recyclability of Al-GnP nanoparticles and personnel health and safety aspects will be addressed in the future.