The Mineral Chemistry of Chlorites and Its Relationship with Uranium Mineralization from Huangsha Uranium Mining Area in the Middle Nanling Range , SE China

The Huangsha uranium mining area is located in the Qingzhangshan uranium-bearing complex granite of the Middle Nanling Range, Southeast China. This uranium mining area contains three uranium deposits (Liangsanzhai, Egongtang, and Shangjiao) and multiple uranium occurrences, showing favorable mineralization conditions and prospecting potential for uranium mineral resources. Chloritization is one of the most important alteration types and prospecting indicators in this mining area. This study aims to unravel the formation environment of chlorites and the relationship between chloritization and uranium mineralization, based on detailed field work and petrographic studies of the wallrock and ore samples from the Huangsha uranium mining area. An electron probe microanalyzer (EPMA) was used in this study to analyze the paragenetic association, morphology, and chemical compositions of chlorite, to classify chemical types and to calculate formation temperatures and n(Al)/n(Al + Mg + Fe) values of chlorite. The formation mechanism and the relationship with uranium mineralization of the uranium mining area are presented. Some conclusions from this study are: (1) There are five types of chlorites, including the chlorite formed by the alteration of biotite (type-I), by the metasomatism of feldspar with Fe–Mg hydrothermal fluids (type-II), chlorite vein/veinlet filling in fissures (type-III), chlorite closely associated with uranium minerals (type-IV), and chlorite transformed from clay minerals by adsorbing Mgand Fe-components (type-V). (2) The chlorite in the Huangsha uranium mining area belongs to iron-rich chlorite and is mainly composed of chamosite, partly clinochlore, which are the products of multiple stages of hydrothermal action. The original rocks are derived from argillite, and their formation temperatures vary from 195.7 ◦C to 283.0 ◦C, with an average of 233.2 ◦C, suggesting they formed under a medium to low temperature conditions. (3) The chlorites were formed under reducing conditions with low oxygen fugacity and relatively high sulfur fugacity through two formation mechanisms: dissolution–precipitation and dissolution–migration–precipitation; (4) The chloritization provided the required environment for uranium mineralization, and promoted the activation, migration, and deposition of uranium.


Introduction
Chlorite (a group which consists of 13 mineral species) is widely distributed in different rock and geological environments.It is one of the common minerals formed in rocks with low-medium temperature metamorphism, diagenesis, and in the process of hydrothermal alteration of copper, uranium, and gold deposits [1][2][3][4][5][6][7].Through the study of chlorites in various geothermal and hydrothermal systems, many scholars have summarized the empirical formulas for estimating the physical and chemical formation conditions of chlorite by using the composition and structural change characteristics of chlorite, and established a series of quantitative research models [7][8][9][10][11][12][13][14].For example, MacDowell and Elders (1980) [15] show that Si IV -Al IV in chlorite is negatively correlated with diagenetic depth.Cathelineau (1988) [8] found that there is a positive correlation between Al IV -T (Temperature) in chlorite by analyzing the relationship between composition and temperature of chlorite in the geothermal systems of Los Azufres and Salton Sea in Mexico and a chlorite solid solution geothermometer was proposed.However, some controversies still exist; Caritat et al. (1993) [2] performed a systematic comparative study of four chlorite geothermometers, which are proposed by Hayes (1970) [16], Walshe (1986) [17], Cathelineau (1988) [8], and Hutcheon (1990) [18].The chemical composition of chlorite varies greatly in different geological environments, and the main physical and chemical parameters (such as the temperature, oxygen fugacity, pH value of the aqueous solution, Fe/(Fe + Mg) of the whole rock, etc.) affect its chemical composition.Thus, these four methods of chlorite geothermometry have certain applicable conditions and limitations and should be used in combination with alternative methods to estimate paleotemperatures [2].In this regard, Rause-Colom et al. (1991) [19], Nieto (1997) [20], and Battaglia et al. (1999) [11] have revised the original chlorite geothermometer, which has been more widely recognized and applied by geologists.
The North Guangdong-South Jiangxi province is one of the most typical granite-type uranium ore fields in China.It is also an important part of the W-Sn-Mo-Be-REE-(Pb-Zn-Au) polymetallic metallogenic belt in the Middle Nanling Range [21][22][23][24][25]. Huangsha uranium mining area is located in the south-central part of Qingzhangshan uranium-bearing complex granites in the Middle Nanling Range.The mining area contains three uranium deposits (Liangsanzhai, Egongtang, and Shangjiao uranium deposits in the north-west, middle, and south-west of the mining area, respectively).Over the past half century, researchers have carried out relevant studies on the geological characteristics, metallogenic conditions, ore-controlling factors, metallogenic mechanisms, and metallogenic prediction of the Huangsha uranium mining area [26][27][28].There are few studies on wallrock alteration in this area, which are mainly concentrated on the major and trace element geochemical characteristics.For example, Mou et al. (2016) [29] analyzed major and trace elements in rock samples with different alteration types (chloritization, hydromica, fluorination, and hematitization), and discussed the geochemical characteristics of hydrothermal alteration and the law of element migration in the mining area.Wu et al. (2018) [30] performed a comparative study of the geochemical characteristics of trace elements and rare earth elements for various rocks (granites, dolerites, and uranium ores) from Shangjiao uranium deposit, and established a metallogenic model.
The hydrothermal uranium deposits are characterized by intense hydrothermal alteration, in which chloritization is an important alteration type before and during the metallogenic stage, which is closely related to uranium mineralization [4,5].Chloritization is a very important prospecting indicator for uranium deposits, especially in the Huangsha uranium mining area.A thorough study of the relationship between chloritization and uranium mineralization will help better understand the genetic mechanism of the deposit in this mining area.The representative chlorite samples of different occurrences and genesis in Huangsha uranium mining area were collected.On the basis of detailed rock-mineral identification, the chemical compositions of chlorites were analyzed by EPMA (Electron probe microanalyzer).The formation environment of chlorites and the relationship between chloritization and uranium mineralization were discussed.

Geological Background
Huangsha uranium mining area is located in the south-central part of Qingzhangshan granitic pluton in the middle of Nanling metallogenic belt (Figure 1A,B) [31,32].The belt is in the southwestern border of the Cathaysia paleocontinent, adjacent to the joint zone of the Hercynian-Indosinian sink of the Hunan-Guangxi-North Guangdong provinces and the Caledonian rise of the Fujian-Jiangxi-Guangdong provinces.The Qingzhangshan granitic pluton formed in the Middle Triassic-Late Jurassic.It has a north-south distribution area of about 500 km 2 (Figure 1B,C) [32,33].The main body of Qingzhangshan granitic pluton formed at the Middle Triassic (medium-coarse to medium-grained porphyritic biotite granite with a formation age of about 241.0 Ma) [34][35][36][37]; Late Jurassic granite (medium-fine grained two-mica granite with a formation age of about 156.0 Ma) [33][34][35][36][37] and Late Jurassic syenite (medium-grained quartz syenite with a formation age of about 149.4 Ma and features of A-type granite) [33] occur with stocks and dikes.The granitic pluton intruded into Cambrian-Jurassic slate, phyllite, and carbonaceous argillaceous shale, and hornfels developed widely at the contact segment.Dolerite veins and silicified fault zones have developed in the granitic pluton.
Minerals 2019, 9, x FOR PEER REVIEW 3 of 24 southwestern border of the Cathaysia paleocontinent, adjacent to the joint zone of the Hercynian-Indosinian sink of the Hunan-Guangxi-North Guangdong provinces and the Caledonian rise of the Fujian-Jiangxi-Guangdong provinces.The Qingzhangshan granitic pluton formed in the Middle Triassic-Late Jurassic.It has a north-south distribution area of about 500 km 2 (Figure 1B,C) [32,33].
The main body of Qingzhangshan granitic pluton formed at the Middle Triassic (medium-coarse to medium-grained porphyritic biotite granite with a formation age of about 241.0 Ma) [34][35][36][37]; Late Jurassic granite (medium-fine grained two-mica granite with a formation age of about 156.0 Ma) [33][34][35][36][37] and Late Jurassic syenite (medium-grained quartz syenite with a formation age of about 149. 4 Ma and features of A-type granite) [33] occur with stocks and dikes.The granitic pluton intruded into Cambrian-Jurassic slate, phyllite, and carbonaceous argillaceous shale, and hornfels developed widely at the contact segment.Dolerite veins and silicified fault zones have developed in the granitic pluton.The uranium deposits in the Huangsha uranium mining area are of typical postmagmatic hydrothermal origin and are hydrothermal vein type uranium deposits.The Middle Triassic pale red medium-coarse to medium-grained porphyritic biotite granite and the Late Jurassic medium-finegrained two-mica granite are widely exposed in the area.Medium-coarse to medium-grained porphyritic biotite granites with pink feldspar phenocrysts are the main host rock in the Huangsha uranium mining area (Figure 2A).Late basic magma intruded along faulted structures, forming NW, NE, and EW trending dolerite veins with a width of 0.5-20 m.The veins extend hundreds to thousands of meters toward the trend of dolerite veins, with the characteristics of expansion, contraction, thinning-out, and recurrence, and are densely integrated into an oblique, equidistant group distribution.The nearly EW-trending Huangsha and Shangzhukeng fault zones are large in scale, parallel to each other, and in opposition to the trend across the uranium area, which both comprise the EW-trending Huangsha fault depression zone and control the distribution of uranium deposits (uranium occurrences) in the Huangsha uranium mining area.The uranium deposits in the Huangsha uranium mining area are of typical postmagmatic hydrothermal origin and are hydrothermal vein type uranium deposits.The Middle Triassic pale red medium-coarse to medium-grained porphyritic biotite granite and the Late Jurassic medium-fine-grained two-mica granite are widely exposed in the area.Medium-coarse to medium-grained porphyritic biotite granites with pink feldspar phenocrysts are the main host rock in the Huangsha uranium mining area (Figure 2A).Late basic magma intruded along faulted structures, forming NW, NE, and EW trending dolerite veins with a width of 0.5-20 m.The veins extend hundreds to thousands of meters toward the trend of dolerite veins, with the characteristics of expansion, contraction, thinning-out, and recurrence, and are densely integrated into an oblique, equidistant group distribution.The nearly EW-trending Huangsha and Shangzhukeng fault zones are large in scale, parallel to each other, and in opposition to the trend across the uranium area, which both comprise the EW-trending Huangsha fault depression zone and control the distribution of uranium deposits (uranium occurrences) in the Huangsha uranium mining area.The ore bodies are veined, reticulated, lenticular, and pod-like in the Huangsha uranium mining area, most of which occur at the intersection of silicified faults and dolerite veins (Figure 2B).Their mineralization characteristics are similar to those of Xiazhuang "intersection" type uranium mineralization.The uranium deposits (uranium occurrences) occur at the intersection between the WNW-trending dolerite dykes and the NNE-trending faults within the Triassic granites of the eastern Guidong batholith, Southeast China [38][39][40].The electron microprobe U-Th-Pb pitchblende dating yields about 97 Ma and 72 Ma (data will be published in another article), which suggests that there have been at least two uranium metallogenic events in the Huangsha uranium mining area.Ores are grape-like, kidney-like, and have microcrystalline texture with fine veins, stockwork, and blocky structure.The ore minerals are mainly pitchblende, followed by coffinite.Metallic minerals are pyrite, galena, and sphalerite.Gangue minerals are chalcedony, microcrystalline quartz, fine-grained quartz, fluorite, and calcite.The secondary uranium minerals are uranotile, chalcolite, and calcouranite.Near-ore alterations are mainly hematization, silicification, and fluoritization, while far-ore alterations are mainly hydromicazation, chloritization, pyritization, and carbonation.From the center of the ore body outward, silicification, hematitization, fluoritization, chloritization, and hydromicazation are gradually weakened (Figure 3).The ore bodies are veined, reticulated, lenticular, and pod-like in the Huangsha uranium mining area, most of which occur at the intersection of silicified faults and dolerite veins (Figure 2B).Their mineralization characteristics are similar to those of Xiazhuang "intersection" type uranium mineralization.The uranium deposits (uranium occurrences) occur at the intersection between the WNW-trending dolerite dykes and the NNE-trending faults within the Triassic granites of the eastern Guidong batholith, Southeast China [38][39][40].The electron microprobe U-Th-Pb pitchblende dating yields about 97 Ma and 72 Ma (data will be published in another article), which suggests that there have been at least two uranium metallogenic events in the Huangsha uranium mining area.Ores are grape-like, kidney-like, and have microcrystalline texture with fine veins, stockwork, and blocky structure.The ore minerals are mainly pitchblende, followed by coffinite.Metallic minerals are pyrite, galena, and sphalerite.Gangue minerals are chalcedony, microcrystalline quartz, fine-grained quartz, fluorite, and calcite.The secondary uranium minerals are uranotile, chalcolite, and calcouranite.Near-ore alterations are mainly hematization, silicification, and fluoritization, while far-ore alterations are mainly hydromicazation, chloritization, pyritization, and carbonation.From the center of the ore body outward, silicification, hematitization, fluoritization, chloritization, and hydromicazation are gradually weakened (Figure 3).The representative altered rocks and their petrographic characteristics in Huangsha uranium mining area are as follows.
The medium-grained porphyritic biotite adamellite is grayish-white and pink, with porphyritic texture and massive structure (Figure 4A).The phenocryst is mainly composed of plagioclase, potassium feldspar, and quartz.The groundmass has the same mineral components as the phenocryst with fine particle structure, the dark minerals are mainly biotites, and the accessory minerals are mainly zircon, sphene, and apatite (Figure 4B).Potassium feldspar is strongly clayed and weakly sericitized, plagioclase has obvious zonal structure, with strong sericitization in the inner zone (Figure 4C).The biotite is subhedral-anhedral, light brown-dark brown, with strong chloritization, and opaque Fe-components are precipitated along the edges and the cleavage cracks of biotite.Some accessory minerals are encapsulated by biotite, such as zircon, apatite, and sphene (Figure 4B).
The hydromicatized granite is grayish-white and yellowish green, with porphyritic texture and massive structure (Figure 4D).It is mainly composed of feldspar, quartz, muscovite, and hydromica, and some opaque minerals are found in groundmass minerals.Quartz is anhedral and irregularly granular, which is mostly transformed from microcrystalline quartz by recrystallization (Figure 4E,F).The muscovite is subhedral-anhedral, flake-like, and has scaly, high-birefrengent aggregates, and some crystals are deformed by tectonic stress (Figure 4E).Feldspar is mainly plagioclase, which is anhedral, irregular plate-like, with strong sericitization, hydromicazation and clayzation.Some feldspar crystals have been altered completely and display feldspar pseudomorphism.Hydromicazation is a hydrothermal alteration widely developed in the mining area, which is mainly formed by the hydration of mica and feldspar.Some hydromica interweaves with sericite, and a small amount of sericite transforms into fine-scale muscovite by recrystallization.
Altered granite-type uranium ore is brownish yellow, with unequigranular texture and massive structure (Figure 4G).It is mainly composed of quartz, fluorite, pyrite, biotite, and a small amount of hematite.The ore is strongly altered by pyritization, fluoritization, silicification, and hematitization.Quartz is anhedral granular and locally distributed as vein-like in hand specimens, which may be attributed to silicic veins being interpenetrated at the post-ore stage (Figure 4G).Fluorite is violet black, mostly anhedral, and irregular granular.Intragranular cracks are widespread in the fluorite, and black, opaque Fe-components are filled along the cracks (Figure 4H).Pyrite is widely distributed in the ore, and its reflection color is bright yellow.There are biotite and microcrystalline quartz around the pyrite particles.The biotite is anhedral, scale-like, and radial-like with a yellowish green color, which is locally replaced by dark green chlorite.Pitchblende has a brownish-grey reflection color, filling around the gangue minerals in veinlet and colloid forms, and hematite is mainly distributed in mineral fissures in the form of powders (Figure 4I).
The microcrystalline quartz-type uranium ore is brownish red, has a cryptocrystallinemicrocrystalline texture, and has massive structure.There are pores on the ore surface filled with yellowish-green secondary uranium mineral (autunite); silicification and hematitization are obviously strongly developed (Figure 4J).Cross-polarized transmitted microscopy shows that the ore The representative altered rocks and their petrographic characteristics in Huangsha uranium mining area are as follows.
The medium-grained porphyritic biotite adamellite is grayish-white and pink, with porphyritic texture and massive structure (Figure 4A).The phenocryst is mainly composed of plagioclase, potassium feldspar, and quartz.The groundmass has the same mineral components as the phenocryst with fine particle structure, the dark minerals are mainly biotites, and the accessory minerals are mainly zircon, sphene, and apatite (Figure 4B).Potassium feldspar is strongly clayed and weakly sericitized, plagioclase has obvious zonal structure, with strong sericitization in the inner zone (Figure 4C).The biotite is subhedral-anhedral, light brown-dark brown, with strong chloritization, and opaque Fe-components are precipitated along the edges and the cleavage cracks of biotite.Some accessory minerals are encapsulated by biotite, such as zircon, apatite, and sphene (Figure 4B).
The hydromicatized granite is grayish-white and yellowish green, with porphyritic texture and massive structure (Figure 4D).It is mainly composed of feldspar, quartz, muscovite, and hydromica, and some opaque minerals are found in groundmass minerals.Quartz is anhedral and irregularly granular, which is mostly transformed from microcrystalline quartz by recrystallization (Figure 4E,F).The muscovite is subhedral-anhedral, flake-like, and has scaly, high-birefrengent aggregates, and some crystals are deformed by tectonic stress (Figure 4E).Feldspar is mainly plagioclase, which is anhedral, irregular plate-like, with strong sericitization, hydromicazation and clayzation.Some feldspar crystals have been altered completely and display feldspar pseudomorphism.Hydromicazation is a hydrothermal alteration widely developed in the mining area, which is mainly formed by the hydration of mica and feldspar.Some hydromica interweaves with sericite, and a small amount of sericite transforms into fine-scale muscovite by recrystallization.
Altered granite-type uranium ore is brownish yellow, with unequigranular texture and massive structure (Figure 4G).It is mainly composed of quartz, fluorite, pyrite, biotite, and a small amount of hematite.The ore is strongly altered by pyritization, fluoritization, silicification, and hematitization.Quartz is anhedral granular and locally distributed as vein-like in hand specimens, which may be attributed to silicic veins being interpenetrated at the post-ore stage (Figure 4G).Fluorite is violet black, mostly anhedral, and irregular granular.Intragranular cracks are widespread in the fluorite, and black, opaque Fe-components are filled along the cracks (Figure 4H).Pyrite is widely distributed in the ore, and its reflection color is bright yellow.There are biotite and microcrystalline quartz around the pyrite particles.The biotite is anhedral, scale-like, and radial-like with a yellowish green color, which is locally replaced by dark green chlorite.Pitchblende has a brownish-grey reflection color, filling around the gangue minerals in veinlet and colloid forms, and hematite is mainly distributed in mineral fissures in the form of powders (Figure 4I).
The microcrystalline quartz-type uranium ore is brownish red, has a cryptocrystallinemicrocrystalline texture, and has massive structure.There are pores on the ore surface filled with yellowish-green secondary uranium mineral (autunite); silicification and hematitization are obviously strongly developed (Figure 4J).Cross-polarized transmitted microscopy shows that the ore has a microcrystalline texture, mainly composed of microcrystalline quartz, cryptocrystalline chalcedony, and uranium minerals, as well as accessory minerals such as hematite, etc. Cryptocrystalline chalcedony transforms into microcrystalline quartz by recrystallization (Figure 4K).Uranium minerals are mainly pitchblende with brownish-grey reflection color and irregular shape.There are many microcrystalline quartz and hematite particles around the uranium minerals, of which hematite particles have brownish-red internal reflection color (Figure 4L).has a microcrystalline texture, mainly composed of microcrystalline quartz, cryptocrystalline chalcedony, and uranium minerals, as well as accessory minerals such as hematite, etc. Cryptocrystalline chalcedony transforms into microcrystalline quartz by recrystallization (Figure 4K).Uranium minerals are mainly pitchblende with brownish-grey reflection color and irregular shape.There are many microcrystalline quartz and hematite particles around the uranium minerals, of which hematite particles have brownish-red internal reflection color (Figure 4L).

Sample Characteristics and Analytical Methods
In order to understand the role of chloritization in the metallogenic process, representative chloritic granite and ore samples of different occurrences and genesis were collected.The samples' properties and location are shown in Table 1 and Figure 2A.Representative chloritic granite and ore samples collected from different occurrences and genesis were prepared into thin sections and EPMA sections.The chemical composition from the micro-area analysis of chlorites were completed in the EPMA laboratory of the National Key Laboratory of Nuclear Resources and Environment of East China University of Technology (Nanchang, China).The instruments used were a JXA-8100 Electron probe microanalyzer and an Inca Energy Spectrometer.The test conditions are as follows: the acceleration voltage is 15 kV, the probe beam is 2.0 × 10 −8 A, and the electron beam spot diameter is 2 µm.The testing process was carried out according to the national standard for quantitative analysis of silicate minerals (GB/T15617-2002) [41].In the selection of standard minerals, chlorite was used as standard sample for Mg, Fe, Al, and Si, and jadeite, potassium feldspar, apatite, rutile, chromium oxide, and rhodonite were used as standard samples of Na, K, Ca, Ti, Cr, and Mn elements, respectively.
As the electron probe cannot detect Fe 3+ , Zheng (1983) [42] proposed that the value of Fe 3+ can be calculated by the method of valence difference.The FeO value in EPMA data used Fe 3+ as Fe 2+ , and the total cation electrovalence in the molecular formula is lower than the theoretical electrovalence.Therefore, the content of Fe 3+ can be calculated according to the principle of equilibrium of the summation of cation positive and anion negative valences of the mineral.The lining, inclusion, mixed layer structure, and complex symbiosis of minerals can lead to errors in EPMA data of chlorite.According to Foster (1962) [43], Hillier and Velde (1991) [44], Zang and Fyfe (1995) [45], the criterion of w(Na 2 O + K 2 O + CaO) < 0.5% is proposed as a criterion to judge whether chlorite is contaminated or not (w < 0.5% indicate that chlorite is not contaminated, w > 0.5% indicate that chlorite is contaminated).According to this criterion, inconsistent data were removed in this paper.

Chlorites Morphology
According to field investigation, hand specimens, and detailed microscopic characteristics, chlorites in Huangsha uranium mining area can be classified into five types: biotite alteration type (type-I chlorite from biotites), feldspar alteration type (type-II chlorite from the metasomatism of feldspar with Fe-Mg hydrothermal fluids), fissure filling type (type-III chlorite occurred in vein/veinlet), closely associated with uranium minerals type (type-IV uranium-associated chlorite), and transformation type from clay minerals by adsorbing Mg-and Fe-components (type-V chlorite transformed from clay minerals).Among them, type-I chlorite is the most widely distributed, with obvious polychromatism under plane-polarized transmitted microscopy, yellowish green, ink-blue, subhedral-anhedral with hypo-edge angle, and leaf-shaped.It is formed by biotite alteration at the premetallogenic stage.It often partially or completely metasomatizes biotite and retains biotite pseudomorphism.The cleavage cracks and interstices of chlorite often contain minerals such as apatite, zircon, and magnetite (Figure 5A,B).Type-II chlorite is green to brown, closely related to feldspar, usually irregularly distributed in feldspar with small and fragmented particles, and often coexists with quartz, zircon, apatite, and magnetite.It is formed by the metasomatism of feldspar with Fe-Mg hydrothermal fluids during pre-metallogenic stage (Figure 5C,D).Type-III chlorite is generally formed by vein/veinlet filling between the fissures and crystals of feldspar and quartz at the early metallogenic stage (Figure 5E).Type-IV chlorite is closely associated with pitchblende, which is vein-like and disseminated, and is often accompanied by a small amount of zircon, uranothorite, sericite or illite/hydromica, pyrite, and rare earth minerals.It is formed by filling and precipitation of ore-forming fluid at the main metallogenic stage (Figure 5F,G).Among them, zircon and chlorite are paragenetic in space, and these very small bright veinlets (pitchblende) and the slightly dark uranothorite occur in chlorite with the occurrence state of dispersive adsorption and are closely associated with pyrite and sericite (Figure 5F).Type-V chlorite is yellowish green and dark green, with no obvious pleochroism, and takes on an irregular granular structure under plane-polarized transmitted microscopy.It is similar to leaf-shaped and pinnate-shaped chlorite.It is formed by a large number of clay minerals adsorbing Mg-and Fe-components in ore-forming fluids at the main metallogenic stage and is then transformed to chlorite and biotite.A small amount of uranium minerals, hematite, and magnetite are often adsorbed around the type-V chlorite (Figure 5H,I).

Mineral Chemistry of Chlorite
The chemical composition of chlorites with different types were analyzed by EPMA (Table 2).The results showed that the type-I chlorite w(SiO2) ranged from 22.19% to 25.28%, with an average of 23.58%; w(Al2O3) ranged from 16.98% to 20.74%, with an average of 19.80%; w(FeO) ranged from 26.17% to 38.53%, with an average of 30.97%; w(MgO) ranged from 5.29% to 13.06%, with an average of 9.52%.Type-II chlorite w(SiO2) ranged from 22.62% to 26.04%, with an average of 24.01%; w(Al2O3) ranged from 17.12% to 20.75%, with an average of 19.41%; w(FeO) ranged from 27.55% to 35.90%, with an average of 31.98%,w(MgO) ranged from 6.37% to 12.75%, with an average of 9.53%.Type-III Overall, the variation range of MgO and FeO contents in chlorite from Huangsha uranium mining area is relatively large, and there are growth-decline relationships between them, indicating that the replacement of Mg and Fe in chlorite is common.The changes of Na, K, and Ca contents (the contents of CaO, Na 2 O, and K 2 O are very low and almost completely migrate-most of Ca, Na, and K are lost during chloritization) indicates the degree of chloritization of the wall rock.The chemical composition is obviously different between different types of chlorite.Type-I, II, and V chlorite are relatively rich in Fe and poor in Mg, while type-III and IV chlorite (especially type-IV chlorite, which is closely associated with uranium minerals) is characterized by the addition of Mg and the depletion of Fe, which suggests the substitutional relationship of the material composition between uranium minerals and chlorites during mineralization [5,46,47].Based on a large number of substitute relationships of chlorite, previous researchers proposed a complex classification and nomenclature method, i.e., the classification diagram of Fe-Si components of chlorite [1,43,48].This method has been abolished by the International Association for the Study of Clays (AIPEA), because there is neither genetic significance nor structural information for chlorite.Tables 3 and 4 show the cation numbers and characteristic parameters of chlorites from Huangsha uranium mining area, which is calculated on the basis of 28 oxygen atoms.Based on the (Al + Q)-Mg-Fe compositional classification diagram which was proposed by Zane and Weiss (1998) [49], chlorites were classified and named in Figure 6.It shows that the chlorites in Huangsha uranium mining area are mainly trioctahedral-chamosite, partly trioctahedral-clinochlore, and most of them belong to iron-rich chlorite.Among them, type-I type-II, and type-V chlorites are all composed of trioctahedral-chamosite; type-III and type-IV chlorites are mainly composed of trioctahedral-chamosite, and a few are composed of trioctahedral-clinochlore. This is obviously different from the Fe-Mg chlorite in unconformity-type uranium deposits in Canada (uranium deposits in the Asabaska Basin) and North Australia (Jabiluka uranium deposit) (Figure 6).Inoue (1995) [50] show that iron-rich chlorite is formed more easily in relatively acidic reduction environments, and the formation of iron-rich chlorite may be related to the boiling of the metallogenic fluid.The chlorite (especially type-IV chlorite, which is closely associated with uranium minerals) in Huangsha uranium mining area shows iron-rich potential, which indicates that the uranium deposits in this area were formed in a relatively acidic reduction environment, and the reduction environment is conducive to uranium mineralization.This is consistent with the results of Guo et al. (2012) [51] and Zhang et al. (2017) [52] on the metallogenesis of uranium deposits of North Guangdong in the Middle Nanling Range.Nutt (1989) [53] studied chlorite from the Jabiluka uranium deposit and suggested that Mg-rich chloritization was the product of alteration by a Mg-rich fluid, perhaps a brine, at high values of the fluid-rock ratio.

Structural Characteristics of Chlorite
The structural formula of chlorite is (R 2+ μ , R 3+ y , Qz) VI (Si4−x Alx) IV O10 + w(OH)8 − w, in which IV and VI represent four-coordinate and six-coordinate centers, respectively; R 2+ represents Mg 2+ , Fe 2+ , Mn 2+ , Zn 2+ , Ni 2+ , etc; R 3+ represents Al 3+ , Fe 3+ , Cr 3+ , etc.; Q represents structure vacancies, μ + y + z=6, z = (yw − x)/2, w is usually equal to 0 or very small [2,56].Chlorite formed at different temperatures has different ion substitution relationships and space occupying capacity, which is also the basis for chlorite to be used as a geothermometer.Therefore, the structural characteristics of chlorite are often explained by the correlation between the main cations of chlorite.

Discrimination of the Original Rock Types of Chlorite
The diagram of the n(Mg)/n(Fe + Mg) − n(Al)/n(Al + Mg + Fe) relationship proposed by Laird (1988) [57] has been widely used to distinguish the relationship between chlorite and its parent rock.Generally, chlorite formed by alteration of argillite is more than 0.35 in n(Al)/n(Al + Mg + Fe), while chlorite transformed from mafic rock is less than 0.35 in n(Al)/n(Al + Mg + Fe).Table 3 shows that the n(Al)/n(Al + Mg + Fe) values of chlorites of various types from Huangsha uranium mining area range from 0.32 to 0.41, with an average of 0.36.Most of them are more than 0.35, and only a small number of them are less than 0.35.This indicates that different types of chlorite are derived from argillite in the mining area, and a small number of them may be affected by mantle fluids (rich in ferromagnesium), resulting in n(Al)/n(Al + Mg + Fe) value less than 0.35, which coincides with the intrusion of a large number of basic dikes in Huangsha uranium mining area.The diagram of the n(Mg)/n(Fe + Mg) − n(Al)/n(Al + Mg + Fe) relationship of chlorite shows a weak negative correlation (Figure 7A) and its linear equation is n(Al)/n(Al + Mg + Fe) = −0.0823n(Mg)/n(Fe+ Mg) + 0.3039.The ratio, diagram, and equation reflect that the different types of chlorite are derived from argillite, which is consistent with the results of Sun Tao et al. (2005) [58] on the origin of Mesozoic granite from argillite in the Middle-East Nanling Range.

Structural Characteristics of Chlorite
The structural formula of chlorite is (R 2+ µ , R 3+ y , Q z ) VI (Si 4−x Al x ) IV O 10 + w (OH) 8 − w , in which IV and VI represent four-coordinate and six-coordinate centers, respectively; R 2+ represents Mg 2+ , Fe 2+ , Mn 2+ , Zn 2+ , Ni 2+ , etc; R 3+ represents Al 3+ , Fe 3+ , Cr 3+ , etc.; Q represents structure vacancies, µ + y + z=6, z = (y -w − x)/2, w is usually equal to 0 or very small [2,56].Chlorite formed at different temperatures has different ion substitution relationships and space occupying capacity, which is also the basis for chlorite to be used as a geothermometer.Therefore, the structural characteristics of chlorite are often explained by the correlation between the main cations of chlorite.

Discrimination of the Original Rock Types of Chlorite
The diagram of the n(Mg)/n(Fe + Mg) − n(Al)/n(Al + Mg + Fe) relationship proposed by Laird (1988) [57] has been widely used to distinguish the relationship between chlorite and its parent rock.Generally, chlorite formed by alteration of argillite is more than 0.35 in n(Al)/n(Al + Mg + Fe), while chlorite transformed from mafic rock is less than 0.35 in n(Al)/n(Al + Mg + Fe).Table 3 shows that the n(Al)/n(Al + Mg + Fe) values of chlorites of various types from Huangsha uranium mining area range from 0.32 to 0.41, with an average of 0.36.Most of them are more than 0.35, and only a small number of them are less than 0.35.This indicates that different types of chlorite are derived from argillite in the mining area, and a small number of them may be affected by mantle fluids (rich in ferromagnesium), resulting in n(Al)/n(Al + Mg + Fe) value less than 0.35, which coincides with the intrusion of a large number of basic dikes in Huangsha uranium mining area.The diagram of the n(Mg)/n(Fe + Mg) − n(Al)/n(Al + Mg + Fe) relationship of chlorite shows a weak negative correlation (Figure 7A) and its linear equation is n(Al)/n(Al + Mg + Fe) = −0.0823n(Mg)/n(Fe+ Mg) + 0.3039.The ratio, diagram, and equation reflect that the different types of chlorite are derived from argillite, which is consistent with the results of Sun Tao et al. (2005) [58] on the origin of Mesozoic granite from argillite in the Middle-East Nanling Range.

Correlation of Main Cations in Chlorites
The substitution relationship between tetrahedral and octahedral positions of chlorite is usually analyzed by using n(Al IV ) and n(Al VI ) values and the relationship diagrams between n(Fe + Al IV ) and n(Mg) of chlorite.The study of Xie et al. (1997) [59] shows that the ratio of n(Al IV ) to n(Al VI ) has a linear relationship of nearly 1:1 (correlation coefficient is 0.95) when the ionic substitution of the tetrahedral position is completely tschermakite-type.The n(Al IV ) value of chlorite in Huangsha uranium mining area ranges from 1.92 to 3.01, the n(Al VI ) value ranges from 2.18 to 3.20, and the value of n(Al IV )/n(Al VI ) ranges from 0.62 to 1.23, with a wide fluctuation range.The diagram of the n(Al IV ) − n(Al VI ) relationship of chlorite shows a weak negative correlation (Figure 7B) and its linear equation is n(Al IV ) = −0.5048n(AlVI ) + 3.8952.Therefore, the tetrahedral position of chlorite in Huangsha uranium mining area is not a purely tschermakite-type substitution.The charge generated by the replacement of Si 4+ by Al IV needs to be supplemented by the replacement of Fe or Mg by Al VI in order to achieve charge balance [60].The variation of n(Al IV )/n(Al VI ) (from 0.62 to 1.23, with a wide fluctuation range) also indicates that the low Fe 3+ content of chlorite of any type may be due to the replacement of Fe or Mg by Al VI .
The n(Al VI +Fe) − n(Mg) relationship diagram can indicate the substitution relationship of the octahedral position of chlorite [59].From Figure 7C, it can be seen that the projection points of chlorite show a good linear negative correlation, and its linear equation is n(Al VI + Fe) = 0.9282n(Mg) + 11.344, which indicates that the octahedral position of chlorite is mainly occupied by three elements; Al VI , Fe, and Mg, and that both Al VI and Fe can replace Mg in this position.
The study of Xie et al. (1997) [59] shows that the diagrams of the relationship between the main cations and magnesium can reflect the alteration process of the original rock.There is a good linear relationship between the main cations and magnesium ions on the condition that chlorite is formed by hydrothermal alteration.The diagrams of the relationship between the main cations and magnesium of chlorite in Huangsha uranium mining area (Figure 7D-G), n(Mg) − n(Fe) (Figure 7D), shows a significant negative correlation and good linear relationship, and its linear equation is n(Fe)= −0.8385 n(Mg) + 8.3577; n(Mg) − n(Al VI ) (Figure 5E) shows a weak negative correlation, and the linear equation is n(Al VI ) = −0.0897n(Mg)+ 2.9865, while there is no linear relationship between n(Mg) − n(Si)(Figure 7F) and n(Mg) − n(Al IV )(Figure 7G).This suggests that chlorite in Huangsha uranium mining area is the product of multiple stages of hydrothermal action.
The diagrams of the relationship between n(Al IV ) − n(Mg)/n(Fe + Mg) and n(Al IV ) − n(Fe)/n(Fe + Mg) in Huangsha uranium mining area are shown in Figure 7H,I.Among them, the relationship diagram of n(Al IV )-n(Mg)/n(Fe + Mg) of chlorites (Figure 7H) shows a weak negative correlation, and the linear equation is n(Al IV ) = −0.4726n(Mg)/n(Fe+ Mg) + 2.652.The relationship diagram of n(Al IV ) − n(Fe)/n(Fe + Mg) of chlorites (Figure 7I) shows a weak positive correlation, and the linear equation is n(Al IV ) = 0.4726n(Fe)/n(Fe + Mg) + 2.1795.These suggest that with the replacement of Si by Al IV in the tetrahedral position, Mg is also replaced by Fe in the octahedral position, which makes the content of Fe increase and the content of Mg decrease.Owing to the process of replacement of Mg by Fe, the internal structure of chlorite is changed, which promotes the replacement of Si by Al IV [59].

Formation Temperature of Chlorites
The relationship between the formation temperature, the structure, chemical composition, and polymorphism of chlorite has been deeply studied and widely recognized [9,19,20].Rause-Colom et al. (1991) [19] studied the linear relationship between chlorite composition and d001, and proposed the corresponding formula, modified by Nieto (1997) [20], as d001/0.1nm= 14.339 − 0.115n(Al IV ) − 0.0201n(Fe 2+ ).Based on this formula, the value of interplanar spacing d001 is calculated in this paper.The formation temperature of chlorite is calculated according to the equation t/°C = [14.379− (d001/0.1nm)]/0.001,which was proposed by Battaglia et al. (1999) [11].The formation temperature of chlorites in Huangsha uranium mining area (Table 3 and Figure 8A) ranges from 195.7 °C to 283.0 °C, with an average value of 233.2 °C.Among the chlorite types, the formation temperature of type-I chlorite is the highest, ranging from 224.9 °C to 283.0 °C, with an average value of 253.3 °C; type-II chlorite ranges from 224.5 °C to 268.7 °C, with an average value of 251.8 °C; type-III chlorite ranges from 201.1 °C to 258.4 °C, with an average value of 226.0 °C; type-IV chlorite is the lowest, ranging from 198.1 °C to 239.9 °C, with an average value of 214.3 °C; type-V chlorite ranges from 195.7 °C to

Formation Temperature of Chlorites
The relationship between the formation temperature, the structure, chemical composition, and polymorphism of chlorite has been deeply studied and widely recognized [9,19,20].Rause-Colom et al. (1991) [19] studied the linear relationship between chlorite composition and d 001 , and proposed the corresponding formula, modified by Nieto (1997) [20], as d 001 /0.1nm = 14.339 − 0.115n(Al IV ) − 0.0201n(Fe 2+ ).Based on this formula, the value of interplanar spacing d 001 is calculated in this paper.The formation temperature of chlorite is calculated according to the equation t/ • C = [14.379− (d 001 /0.1nm)]/0.001,which was proposed by Battaglia et al. (1999) [11].The formation temperature of chlorites in Huangsha uranium mining area (Table 3 and Figure [61] and Guo et al. (2012) [51] used fluid inclusion thermometry and a chlorite geothermometer to research the metallogenic temperature of No.302 uranium deposit (a well-known granite-type uranium deposit, located about 150 km north-west of Huangsha uranium mining area), respectively.The results of these two methods show very similar metallogenic temperature, about 210 • C. The temperature of ore-forming fluids decreases continuously from the early metallogenic stage to the main metallogenic stage.The temperature measurement results of Huangsha uranium mining area by chlorite geothermometer are very close to those of No.302 uranium deposit.

Formation Oxygen Fugacity and Sulfur Fugacity of Chlorites
The formation oxygen fugacity [lg(ƒO 2 /10 −5 Pa)] and sulfur fugacity [lg(ƒS 2 /10 −5 Pa)] of chlorite can effectively indicate the physicochemical formation conditions.Walshe (1986) [17], Bryndzia and Scott (1987) [9] calculated the formation oxygen fugacity, sulfur fugacity, temperature, and pressure of chlorite according to its composition.In this paper, the calculation method proposed by Walshe (1986) [17] is used to calculate the formation oxygen fugacity and sulfur fugacity of chlorite by using the functional relationship between reaction equilibrium constant and temperature, which is fitted by Zhang et al. (2014) [62].The calculation process and method refer to Li et al. (2017) [47] and Zhang et al. (2014) [62].The calculated results (Table 3, Figure 8B,C) show that the lg(ƒO 2 /10 −5 Pa) value of chlorite ranges from −48.0 to −41.7, with an average value of −44.2, and the lg(ƒS 2 /10 −5 Pa) value of chlorite ranges from −7.9 to −0.1, with an average value of −3.4, which suggests an environment of low oxygen fugacity.Figure 9A  with average values of −44.1 and −2.7, respectively.Type-IV chlorite ranges from −48.0 to −44.0 and −7.9 to −1.7, with average values of −45.1 and −4.9, respectively.Type-V chlorite ranes from −45.3 to −42.7 and −6.9 to −2.2, with average values of −43.5 and −3.7, respectively.The oxygen fugacity and sulfur fugacity of various types of chlorite generally decrease in the order of premetallogenic stage (type-I and type-II chlorite, the average values of oxygen fugacity and sulfur fugacity are −43.8 and −2.4,respectively) → early metallogenic stage (type-III chlorite, with a values of oxygen fugacity and sulfur fugacity −44.1 and −2.7, respectively) →main metallogenic stage (type-IV and type-V chlorite, the average values of oxygen fugacity and sulfur fugacity are −44.3 and −4.3, respectively), which suggests the hydrothermal metasomatic alteration process of Huangsha uranium mining area is gradually evolving towards low oxygen fugacity and relatively high sulfur fugacity, that is, hydrothermal fluids are becoming more and more reductive.Ling (2011) [63] reviewed the oxygen fugacity characteristics of granite-type uranium deposits in South China.It is considered that the original rocks were derived from argillite, and then formed sedimentary rocks enriched with U 4+ and Fe 2+ (e.g., pyrite) in the reductive environment.The oxygen fugacity of uranium-bearing granite formed by these sedimentary rocks melts partially, which is lower than that of uranium-barren granite (uranium-bearing granite is below the NiO-Ni buffer line, uranium-barren granite is between the Hm-Mt and NiO-Ni buffer line).These characteristics are consistent with the results of using chlorite to research the metallogenic environment of Huangsha uranium mining area.The distribution range of oxygen fugacity and sulfur fugacity of chlorite in unconformity-type uranium deposits (Asabaska Basin and Jabiluka) are wider than those in Huangsha uranium deposit (Figure 9A,B), which may be attributed to the chlorite in unconformity-type uranium deposit often metasomatizing minerals such as biotite, garnet, amphibole, cordierite, and tourmaline.Retrograde alteration and epigenetic alteration also developed obvious chloritization, silicification, and carbonation (such as magnesite mineralization and dolomitization) [53,54,64].Compared with the granite-type uranium deposits, their metamorphism is more intense and the formation environment is more complex.
Minerals 2019, 9, x FOR PEER REVIEW 18 of 24 developed obvious chloritization, silicification, and carbonation (such as magnesite mineralization and dolomitization) [53,54,64].Compared with the granite-type uranium deposits, their metamorphism is more intense and the formation environment is more complex.

Formation Mechanisms of Chlorites
The formation process of chlorite is a water-rock reaction process controlled by reaction kinetics, which is restricted by temperature, pressure, water/rock ratio, fluid, and petrochemical composition [5].The chloritization of Huangsha uranium mining area is widespread.At the premetallogenic stage, biotite and feldspar are often partially or completely metasomatized by hydrothermal fluids (contains Fe and Mg), and form chlorite with the characteristics of pseudomorphism (Figure 5A,B) and metasomatic alteration structure (Figure 5C,D).At the early metallogenic stage, hydrothermal fluid fills in the interstices and fissures of feldspar, quartz, and other minerals to form vein/veinlet chlorite (Figure 5E).At the main metallogenic stage, chlorite is closely associated with pitchblende, zircon, developed obvious chloritization, silicification, and carbonation (such as magnesite mineralization and dolomitization) [53,54,64].Compared with the granite-type uranium deposits, their metamorphism is more intense and the formation environment is more complex.

Formation Mechanisms of Chlorites
The formation process of chlorite is a water-rock reaction process controlled by reaction kinetics, which is restricted by temperature, pressure, water/rock ratio, fluid, and petrochemical composition [5].The chloritization of Huangsha uranium mining area is widespread.At the premetallogenic stage, biotite and feldspar are often partially or completely metasomatized by hydrothermal fluids (contains Fe and Mg), and form chlorite with the characteristics of pseudomorphism (Figure 5A,B) and metasomatic alteration structure (Figure 5C,D).At the early metallogenic stage, hydrothermal fluid fills in the interstices and fissures of feldspar, quartz, and other minerals to form vein/veinlet chlorite (Figure 5E).At the main metallogenic stage, chlorite is closely associated with pitchblende, zircon, apatite, hematite, and magnetite (Figure 5F-I).The chemical composition of chlorites in Huangsha

Formation Mechanisms of Chlorites
The formation process of chlorite is a water-rock reaction process controlled by reaction kinetics, which is restricted by temperature, pressure, water/rock ratio, fluid, and petrochemical composition [5].The chloritization of Huangsha uranium mining area is widespread.At the premetallogenic stage, biotite and feldspar are often partially or completely metasomatized by hydrothermal fluids (contains Fe and Mg), and form chlorite with the characteristics of pseudomorphism (Figure 5A,B) and metasomatic alteration structure (Figure 5C,D).At the early metallogenic stage, hydrothermal fluid fills in the interstices and fissures of feldspar, quartz, and other minerals to form vein/veinlet chlorite (Figure 5E).At the main metallogenic stage, chlorite is closely associated with pitchblende, zircon, apatite, hematite, and magnetite (Figure 5F-I).The chemical composition of chlorites in Huangsha uranium mining area shows that the chlorite belongs to iron-rich chlorite, which indicates that the fluids are rich in Fe or that the fluids extract Fe-components from the wallrocks during their migration.The studies of Inoue (1995) [50] suggest that the relatively acidic reduction environment is favorable for the formation of iron-rich chlorite in vein-type deposits during hydrothermal alteration.According to Liu and Cao (1987) [67], the migration medium of Fe is reductive.In conclusion, various types of chlorite in Huangsha uranium mining area are formed in a relatively acidic reducing environment.2017) [47] suggest that the formation of chlorite can be classified into two mechanisms: dissolution-precipitation and dissolution-migrationprecipitation.Based on the study of mineralogical characteristics of chlorite in Huangsha uranium mining area by electron microscope and EPMA, combined with the results of the formation environment of chlorite, it is considered that the formation mechanism of type-I chlorite (chlorite from biotite) and type-II chlorite (chlorite closely associated with feldspar) is the dissolution-precipitation mechanism, which is mainly manifested by hydrothermal fluid metasomatizing biotite and feldspar, and transformation into chlorite, retaining biotite pseudomorphism and metasomatic alteration structure, respectively.The formation mechanism of type-III chlorite (chlorite occurred in vein), type-IV chlorite (uranium-associated chlorite), and type-V chlorite (chlorite transformed from clay minerals) is the dissolution-migration-precipitation mechanism.The hydrothermal fluid dissolves some Fe-and Mg-rich minerals and forms Fe-and Mg-rich hydrothermal fluids.They precipitate and crystallize in other minerals' fissures through migration, or Fe-and Mg-components are adsorbed by a large number of clay minerals and then transformed to chlorite and biotite.

Relationship between Chlorites and Uranium Mineralization
Chloritization is one of the most important wallrock alterations associated with uranium mineralization [51].It is generally considered that chloritization at the premetallogenic stage mainly distributes in the periphery of the ore body in a planar form, such as biotite-altered chlorites, which are mainly formed by alteration of ferromagnesian silicate minerals (biotite and amphibole).In this process, the Fe-and Mg-components mainly come from the wallrock itself, with little Fe-and Mg-components brought in.With the changes of environment, the temperature of the hydrothermal fluid decreases gradually, the fluid evolves to low oxygen fugacity and high sulfur fugacity, and the composition of fluid changes accordingly.The Fe-and Mg-components extracted from the wallrock enter the fluid and fill in the fissures of minerals under appropriate conditions to form vein/veinlet chlorite.Meanwhile, the hydrothermal fluid contains a certain amount of uranium, which is enriched with the precipitation of chlorite.To sum up, the relationship between chloritization and uranium mineralization in Huangsha uranium mining area is mainly related to the following four aspects: (1) Change in the physicochemical properties of rocks.
In the process of hydrothermal alteration, such as chloritization, dolomitization, and alkali metasomatism, the interaction between hydrothermal fluids and wallrocks changes the physicochemical properties of uranium-bearing granite from hard rocks to loose and fragile rocks, and significantly increases the porosity and permeability of the rocks.This not only contributes to the reaction of hydrothermal fluids with wallrocks during the metallogenic stage, but also provides a favorable deposition environment for uranium mineralization due to the loose and fragile wallrock conditions.
(2) Indicate uranium metallogenic environment.Various types of chlorite in Huangsha uranium mining area are iron-rich chlorites and the formation temperature ranges from 195.7 • C to 283.0 • C, with an average value of 233.2 • C, oxygen fugacity ranges from −48.0 to −41.7, with an average value of −44.2, sulfur fugacity ranges from −7.9 to −0.1, with an average value of −3.42, creating a medium-low temperature, relatively low

Figure 5 .
Figure 5. Morphological features of chlorites from Huangsha uranium mining area.Note: Images.A, C, E, and H are plane-polarized transmitted microscopy photographs; Images.B, D, F, G, and I are electron back scattering patterns.A-Chlorite with obvious polychromatism under plane-polarized transmitted microscopy, yellowish green, ink-blue, subhedral-anhedral with hypo-edge angle and leaf-shaped.B-The cleavage cracks and interstices of chlorite often contain minerals such as apatite, zircon and magnetite.C,D-Chlorite is closely related to feldspar, usually irregularly distributed in feldspar with small and fragmented particles, and often coexist with quartz, zircon, apatite and magnetite.E-Chlorite is generally formed by vein/veinlet filling between the fissures and crystals of feldspar and quartz.F-Chlorite is closely associated with pitchblende, often accompanied by a small amount of zircon and uranothorite.The very small bright veinlets (pitchblende) and the slightly dark uranothorite occur in chlorite with the occurrence state of dispersive adsorption.G-Chlorite is closely associated with pitchblende, often accompanied by sericite or illite/hydromica.H-Chlorite is yellowish green and dark green, with no obvious pleochroism and takes on an irregular granular structure under plane-polarized transmitted microscopy.I-Chlorite is similar to leaf-shaped and pinnate-shaped structures.Abbreviations: Pit-pitchblende; Uth-uranothorite; Qtz-Quartz; Btbiotite; Ap-apatite; Hem-hematite; Mag-magnetite; U-uranium minerals; Zrn-zircon; Kfspotassium feldspar; Ab-albite; Chl-chlorite; Ser-sericite; Ili-illite or hydromica.

Figure 5 .
Figure 5. Morphological features of chlorites from Huangsha uranium mining area.Note: Images.A, C, E, and H are plane-polarized transmitted microscopy photographs; Images.B, D, F, G, and I are electron back scattering patterns.A-Chlorite with obvious polychromatism under plane-polarized transmitted microscopy, yellowish green, ink-blue, subhedral-anhedral with hypo-edge angle and leaf-shaped.B-The cleavage cracks and interstices of chlorite often contain minerals such as apatite, zircon and magnetite.C,D-Chlorite is closely related to feldspar, usually irregularly distributed in feldspar with small and fragmented particles, and often coexist with quartz, zircon, apatite and magnetite.E-Chlorite is generally formed by vein/veinlet filling between the fissures and crystals of feldspar and quartz.F-Chlorite is closely associated with pitchblende, often accompanied by a small amount of zircon and uranothorite.The very small bright veinlets (pitchblende) and the slightly dark uranothorite occur in chlorite with the occurrence state of dispersive adsorption.G-Chlorite is closely associated with pitchblende, often accompanied by sericite or illite/hydromica.H-Chlorite is yellowish green and dark green, with no obvious pleochroism and takes on an irregular granular structure under plane-polarized transmitted microscopy.I-Chlorite is similar to leaf-shaped and pinnate-shaped structures.Abbreviations: Pit-pitchblende; Uth-uranothorite; Qtz-Quartz; Bt-biotite; Ap-apatite; Hem-hematite; Mag-magnetite; U-uranium minerals; Zrn-zircon; Kfs-potassium feldspar; Ab-albite; Chl-chlorite; Ser-sericite; Ili-illite or hydromica.

Figure 7 .
Figure 7. Graphic diagram of main cation relations of chlorites in Huangsha uranium mining area.A-The diagram of the n(Mg)/n(Fe + Mg) − n(Al)/n(Al + Mg + Fe) relationship of chlorite.B-The diagram of the n(Al IV ) − n(Al VI ) relationship of chlorite.C-The diagram of the n(Al VI + Fe) − n(Mg) relationship of chlorite.D-The diagram of the n(Mg) − n(Fe) relationship of chlorite.E-The diagram of the n(Mg) − n(Al VI ) relationship of chlorite.F-The diagram of the n(Mg) − n(Si) relationship of chlorite.G-The diagram of the n(Mg) − n(Al IV ) relationship of chlorite.H-The diagram of the n(Al IV ) − n(Mg)/n(Fe + Mg) relationship of chlorite.I-The diagram of the n(Al IV ) − n(Fe)/n(Fe + Mg) of chlorite.I-Chlorite from biotites, II-Chlorite closely associated with feldspar, III-Chlorite occurring in veins, IV-Uranium-associated chlorite, V-Chlorite transformed from clay minerals.

Figure 7 .
Figure 7. Graphic diagram of main cation relations of chlorites in Huangsha uranium mining area.A-The diagram of the n(Mg)/n(Fe + Mg) − n(Al)/n(Al + Mg + Fe) relationship of chlorite.B-The diagram of the n(Al IV ) − n(Al VI ) relationship of chlorite.C-The diagram of the n(Al VI + Fe) − n(Mg) relationship of chlorite.D-The diagram of the n(Mg) − n(Fe) relationship of chlorite.E-The diagram of the n(Mg) − n(Al VI ) relationship of chlorite.F-The diagram of the n(Mg) − n(Si) relationship of chlorite.G-The diagram of the n(Mg) − n(Al IV ) relationship of chlorite.H-The diagram of the n(Al IV ) − n(Mg)/n(Fe + Mg) relationship of chlorite.I-The diagram of the n(Al IV ) − n(Fe)/n(Fe + Mg) of chlorite.I-Chlorite from biotites, II-Chlorite closely associated with feldspar, III-Chlorite occurring in veins, IV-Uranium-associated chlorite, V-Chlorite transformed from clay minerals.
8A) ranges from 195.7 • C to 283.0 • C, with an average value of 233.2 • C.Among the chlorite types, the formation temperature of type-I chlorite is the highest, ranging from 224.9 • C to 283.0 • C, with an average value of 253.3 • C; type-II chlorite ranges from 224.5 • C to 268.7 • C, with an average value of 251.8 • C; type-III chlorite ranges from 201.1 • C to 258.4 • C, with an average value of 226.0 • C; type-IV chlorite is the lowest, ranging from 198.1 • C to 239.9 • C, with an average value of 214.3 • C; type-V chlorite ranges from 195.7 • C to 226.7 • C, with an average value of 216.5 • C. The formation temperatures of various types of chlorite suggest the chlorite from premetallogenic stage (type-I and type-II chlorite, with an average value of 252.6 • C) → early metallogenic stage (type-III chlorite, with a value of 226.0 • C) → main metallogenic stage (type-IV and type-V chlorite, with an average value of 215.4 • C) decreases continuously, which belongs to medium-low temperature hydrothermal alteration.Guo et al. (2010) and relatively high sulfur fugacity lg(ƒS 2 /10 −5 Pa) − T projective points of all types of chlorite are above the Bn + Py − Cp buffer line, suggesting an environment of high sulfur fugacity (Figure 9B).The oxygen fugacity [lg(ƒO 2 /10 −5 Pa)] and sulfur fugacity [lg(ƒS 2 /10 −5 Pa)] of type-I chlorite range from −43.7 to −41.7 and −2.8 to −2.1, with average values of −43.1 and −2.4,respectively.Type-II chlorite ranges from −45.0 to −44.0 and −3.1 to −1.2, with average values of −44.4 and −2.4,respectively.Type-III chlorite ranges from −45.8 to −42.4 and −4.6 to −0.1,

Figure 8 .
Figure 8. Histogram of formation temperatures, oxygen fugacity, and sulfur fugacity for chlorites from Huangsha uranium mining area.A-The formation temperatures frequency distribution histogram of chlorites.B-The formation oxygen fugacity frequency distribution histogram of chlorites.C-The formation sulfur fugacity frequency distribution histogram of chlorites.I-Chlorite from biotites, II-Chlorite closely associated with feldspar, III-Chlorite occurring in veins, IV-Uranium-associated chlorite, V-Chlorite transformed from clay minerals.

Figure 8 .
Figure 8. Histogram of formation temperatures, oxygen fugacity, and sulfur fugacity for chlorites from Huangsha uranium mining area.A-The formation temperatures frequency distribution histogram of chlorites.B-The formation oxygen fugacity frequency distribution histogram of chlorites.C-The formation sulfur fugacity frequency distribution histogram of chlorites.I-Chlorite from biotites, II-Chlorite closely associated with feldspar, III-Chlorite occurring in veins, IV-Uranium-associated chlorite, V-Chlorite transformed from clay minerals.

Figure 8 .
Figure 8. Histogram of formation temperatures, oxygen fugacity, and sulfur fugacity for chlorites from Huangsha uranium mining area.A-The formation temperatures frequency distribution histogram of chlorites.B-The formation oxygen fugacity frequency distribution histogram of chlorites.C-The formation sulfur fugacity frequency distribution histogram of chlorites.I-Chlorite from biotites, II-Chlorite closely associated with feldspar, III-Chlorite occurring in veins, IV-Uranium-associated chlorite, V-Chlorite transformed from clay minerals.

Table 1 .
Sampling locations and characters of chloritic samples from Huangsha uranium mining area.

Table 2 .
Electronic microprobe analyses of chlorites from Huangsha uranium mining area.

Table 3 .
Calculated cation numbers of chlorites from Huangsha uranium mining area (at standard of 28 oxygen atoms).

Table 4 .
Characteristic parameters of chlorites from Huangsha uranium mining area (at standard of 28 oxygen atoms).