Effect of Chemical Corrosion and Axial Compression on the Dynamic Strength Degradation Characteristics of White Sandstone under Cyclic Impact

: Both chemical corrosion and axial compression impose critical inﬂuences on the internal microstructure of rock. Meanwhile, chemical corrosion can change a rock’s mineral composition, which in turn affects the physical and mechanical properties of the rock. To investigate the dynamic strength characteristics of white sandstone under the coupling effect of axial load and chemical corrosion, a dynamic and static combined loading test device was adopted for performing cyclic impact tests on white sandstone immersed in chemical solution. The results show that with the increasing number of cycles under the same load, the peak strength of the rock presented a trend of ‘strengthening ﬁrst and then weakening’. The strength of rock resistance to impact failure reached its maximum when the solution of pH was 7 and axial pressure was 12.6 MPa. Under the same axial pressure, the effect of solution pH on the initial dynamic strength of white sandstone is a normal distribution. Acidic and alkaline environments are harmful to rocks during the initial impact, while neutral environments exert little effect and the pH of the solution inﬂuences the particle size of impact crushing particles. In addition, the chemical solution has a signiﬁcant effect on the deterioration of rock strength during the process of initial impact, and the effect is inconspicuous in the later period.


Introduction
Certain large-scale infrastructure construction and mining projects are inseparable from geotechnical engineering. These include projects such as large-section tunnel excavation [1], resource exploitation [2,3], subgrade blasting [4], directional damming and interception projects [5,6]. The rock not only bears the static stress of structure during construction but also experiences the erosion of the chemical environment for a long time. In the process of blasting excavation, the stability of rock is inevitably influenced by frequent drilling and blasting vibrations [7]. The coupling of force and chemical corrosion has a critical influence on the stability of engineering rock mass in the long term [8].
Over the last decades, many scholars have performed a lot of research on investigating rock dynamic mechanical properties under various conditions. Li et al. [9] conducted a uniaxial cyclic impact compression test on granite through an improved split Hopkinson pressure bar (SHPB). The results show that the damage accumulation of the rock increased with the number of cyclic impacts. Gong et al. [10] carried out a one-dimensional experimental study on the dynamic characteristics of rock under combined dynamic and static loading, revealing that the impact strength is maximally strengthened with an axial compression ratio of 0.6~0.7. Zhou et al. [11] studied the dynamic mechanical behavior and failure characteristics of mudstone using the split Hopkinson pressure bar test device, and proposed a criterion for the dynamic strength of mudstone. Jin et al. [12] discussed the effects of different static loads on the failure pattern of rock subjected to cyclic impact and concluded that rock with an axial static load had extremity effects in the process of destruction. Ding et al. [13] investigated the failure process and the mechanical properties of limestone under different chemical solutions, finding that the strength of limestone decreased due to the chemical solutions. Xie et al. [14] conducted in situ stress restoration tests on cores of different burial depths and obtained rock behaviors under the action of in-situ stress, temperature, and pore pressure. Siddiqua et al. [15] explored the saturated mechanical behavior of light backfill and dense backfill, which clarified the strengthening effect of pore fluid chemistry on shear strength, stiffness, and yield behavior. Han et al. [16] compared microstructure, deformation characteristics, and the mechanical behavior of rock by chemical solutions with different pH, different concentrations, and different compositions, revealing that rock had a conversion trend of brittle to ductile after chemical corrosion. Xia et al. [17] conducted the whole process of compression failure of multi-crack limestone and limestone under different chemical solutions by adopting a self-developed micro loading instrument, which obtained the deformation characteristics of rock specimens, the mode of crack initiation, propagation and penetration as well as the different overlapping modes of rock bridges when they were damaged. Li et al. [18] studied the main components of calcareous cemented feldspar rock under different pH, and a rock damage model that could be applied to acidic solutions was put forward. Through scanning electron microscope (SEM) and X-ray diffraction (XRD) technology, Cui et al. [19] analyzed the mechanical and corrosion damage of the surface and mineral components of rock after the action of 0.01 mol/L NaOH solution with a pH of 12 and revealed internal changes in the rock under that solution.
Scholars both at home and abroad have conducted in-depth studies on the mechanical properties of rocks in static or quasi-static conditions [20][21][22][23][24]. Currently, studies on the mechanical properties of rock have mainly focused on a single factor, such as axial static load [25], impact load [26], and chemical corrosion [27]. However, there is less investigation on the rock cyclic impact failure and damage accumulation under the coupling of axial pressure and chemical corrosion. Based on split Hopkinson pressure bar (SHPB) test technology combined with one-dimensional stress wave theory, cyclic impact experiments were carried out on white sandstone immersed in chemical solutions with different pH and axial pressures, which explored fatigue damage mechanism and the characteristics of strength weakening of white sandstone under multi-factor coupling. The mechanism of strength and fatigue failure also provides a theoretical basis for the safe and effective construction management of blasting engineering under complex geological conditions.

Rock Preparation
The rock material used in the present study was white sandstone that was taken from Kunming, Yunnan, China. These rock blocks are off-white, with good integrity and homogeneity as the research objects. Sandstone samples were subjected to professional elemental analysis and mineral identification, as shown in Figure 1. They were composed primarily of quartz, feldspar (e.g., potassium feldspar, sodium feldspar, and calcium feldspar), clay, calcite and a small number of hematite, quick lime and other minerals. The sandstone's quartz was identified as SiO 2 . Feldspar was identified as a collection of KAlSi 3   According to the size and accuracy requirements of the relevant guidelines of ISRM [28], the size of cylindrical white sandstone specimens is Φ50 mm × 50 mm, and that of unevenness and verticality are less than 0.05 mm by means of carefully grinding both ends of the rock specimens. The processed rock specimens are displayed in Figure 2. The rock specimens were dried and evacuated for 8 h, divided into eight groups, and sealed immersed in the chemical solutions presented in Table 1 for 240 days.

Experimental Apparatus
In this study, based on the split Hopkinson pressure bar (SHPB) system established previously [29], an experiment system of SHPB is shown in Figure 3, using the laboratory dynamic cyclic impact compression experiment that was performed. The experiment facilities are mainly composed of a dynamic loading system (gas gun, launch cavity and shaped puncher), a test system (CS-1D strain instrument, DL-750 oscilloscope, and laser speedometer), a delivery system and an axial compression system. The delivery system mainly includes an incident bar, transmission bar, and buffer bar, the lengths of which are 2000 mm, 1500 mm, and 500 mm, respectively. All of the elastic bars were made of highstrength 40 Cr alloy steel, a wave velocity of 5400 m/s, a density of 7.81 g/cm 3 , and a wave impedance of 4.2 × 10 7 MPa. The special-shaped punch is applied to eliminate PC oscillation and realize half-sine wave loading with constant strain rate loading [30][31][32]. According to the size and accuracy requirements of the relevant guidelines of ISRM [28], the size of cylindrical white sandstone specimens is Φ50 mm × 50 mm, and that of unevenness and verticality are less than 0.05 mm by means of carefully grinding both ends of the rock specimens. The processed rock specimens are displayed in Figure 2. The rock specimens were dried and evacuated for 8 h, divided into eight groups, and sealed immersed in the chemical solutions presented in Table 1 for 240 days. According to the size and accuracy requirements of the relevant guidelines of ISRM [28], the size of cylindrical white sandstone specimens is Φ50 mm × 50 mm, and that of unevenness and verticality are less than 0.05 mm by means of carefully grinding both ends of the rock specimens. The processed rock specimens are displayed in Figure 2. The rock specimens were dried and evacuated for 8 h, divided into eight groups, and sealed immersed in the chemical solutions presented in Table 1 for 240 days.

Experimental Apparatus
In this study, based on the split Hopkinson pressure bar (SHPB) system established previously [29], an experiment system of SHPB is shown in Figure 3, using the laboratory dynamic cyclic impact compression experiment that was performed. The experiment facilities are mainly composed of a dynamic loading system (gas gun, launch cavity and shaped puncher), a test system (CS-1D strain instrument, DL-750 oscilloscope, and laser speedometer), a delivery system and an axial compression system. The delivery system mainly includes an incident bar, transmission bar, and buffer bar, the lengths of which are 2000 mm, 1500 mm, and 500 mm, respectively. All of the elastic bars were made of highstrength 40 Cr alloy steel, a wave velocity of 5400 m/s, a density of 7.81 g/cm 3 , and a wave impedance of 4.2 × 10 7 MPa. The special-shaped punch is applied to eliminate PC oscillation and realize half-sine wave loading with constant strain rate loading [30][31][32].

Experimental Apparatus
In this study, based on the split Hopkinson pressure bar (SHPB) system established previously [29], an experiment system of SHPB is shown in Figure 3, using the laboratory dynamic cyclic impact compression experiment that was performed. The experiment facilities are mainly composed of a dynamic loading system (gas gun, launch cavity and shaped puncher), a test system (CS-1D strain instrument, DL-750 oscilloscope, and laser speedometer), a delivery system and an axial compression system. The delivery system mainly includes an incident bar, transmission bar, and buffer bar, the lengths of which are 2000 mm, 1500 mm, and 500 mm, respectively. All of the elastic bars were made of high-strength 40 Cr alloy steel, a wave velocity of 5400 m/s, a density of 7.81 g/cm 3 , and a wave impedance of 4.2 × 10 7 MPa. The special-shaped punch is applied to eliminate PC oscillation and realize half-sine wave loading with constant strain rate loading [30][31][32].

Experimental Method
Before conducting the cyclic impact test, a physico-mechanical parameters test was

Experimental Method
Before conducting the cyclic impact test, a physico-mechanical parameters test was carried out on the white sandstone specimens by adopting the RMT-150 electro-hydraulic servo control material testing machine. The results of this test are shown in Table 2. In order to ensure that cyclic impact test on the white sandstone with the chemical corrosion and axial pressure could be carried out successfully, the experimental method was designed as follows. Four solutions of pH at 2, 7, 9, and 12 were designed. According to the research conducted by Sun et al. [33], in the process of cyclic impact, rock specimens did not show the palpable end effect failure mode when there was no static load. Combined with the value of uniaxial compressive strength test, axial compression was set to four levels of uniaxial compressive strength of 20%, 40%, 65%, 85%, which were respectively 6.3 MPa, 12. 6 MPa, 20.5 MPa and 26.8 MPa. In addition, due to the existence of a threshold value in the cyclic impact load experiment [34], multiple pre-impact tests were required to determine the fixed air pressure in the high-pressure gas chamber of 0.8 MPa. The impact speed of the punch was 4.5 m/s.
The following conditions must be satisfied during the test process: (1) The incident bar, transmission bar and buffer bar should be kept level.
(2) The magnitude of the axial load should be equal to the axial load value set in advance.
(3) To fix the impact load, it is necessary to strictly ensure that the pressure in the highpressure air chamber is equal to the value set before each impact, and that the position of the punch in the launching chamber remains unchanged. (4) The white sandstone specimens were sandwiched between the incident bar and the transmission bar, with petroleum jelly coated on both ends of the specimen to ensure good contact.

Typical Stress-Strain Curve during Cyclic Impact
Using a split Hopkinson pressure bar (SHPB), Jin et al. [35]. conducted a series of cyclic impact loading tests on sandstone under different static loading conditions, obtaining a typical dynamic stress-strain curve of sandstone during cyclic impact. The results of the experiments reveal that the sandstone's dynamic strength and the characteristics of deformation were affected by axial compression and the number of cycles. In this study, the cyclic impact test of white sandstone soaked in NaCl with pH of 9 and axial pressure of 6.3 MPa was taken as an example for analyzing the different stages of the test. Figure 4 presents an overlay chart of the typical waveform recorded during the cycle impact test. It can be observed from the figure that the amplitude of the incident wave has not changed significantly and that the superposition of waveform basically coincides, achieving the requirements of the constant-amplitude cyclic impact test. The reflected wave amplitude of the specimen increases and the transmitted wave amplitude decreases gradually with the increasing number of impacts, and the change of cyclic impact is obvious in the middle and later periods. This phenomenon occurs regardless of axial compression and pH. Since the size of the white sandstone specimen tested is small, the homogeneity hypothesis is introduced, satisfying the expression ε l (t) + ε r (t) = ε t (t) [36]. According to one-dimensional stress wave theory, the collected voltage signal is processed. Stress, strain, and average strain rate can be calculated using the following formula.
In these Equations, As and Ls are the cross-sectional area and length of the specimen, respectively; Ae, Ee and Ce represent elastic rod cross-sectional area, elastic modulus and longitudinal wave velocity, respectively; ε l , ε R and ε T denote the incident, reflection and transmission wave signals, respectively.
introduced, satisfying the expression ε l ( t) + ε r ( t) = ε t ( t) [36]. According to one-dimensional stress wave theory, the collected voltage signal is processed. Stress, strain, and average strain rate can be calculated using the following formula.
In these Equations, As and Ls are the cross-sectional area and length of the specimen, respectively; Ae, Ee and Ce represent elastic rod cross-sectional area, elastic modulus and longitudinal wave velocity, respectively; , and denote the incident, reflection and transmission wave signals, respectively. The typical stress-strain curves of the white sandstone under cyclic impact loading tests are shown in Figure 5. It can be observed from the figure that the stress-strain curve of the whole cyclic impact test can be divided into three types. The initial stress-strain curve (one to five impacts) is a semi-elliptic high flat curve. In addition, the elastic modulus, peak stress, and maximum strain have not changed significantly. The stress in the loading stage increases sharply with the increase of strain. The slope is steep, and the elastic modulus value is large. The maximum stress at this stage represents the maximum impact stress value that the specimen can withstand during the entire impact process, which is called the peak strength. However, the stress in the unloading stage drops sharply with the increasing strain. The typical stress-strain curves of the white sandstone under cyclic impact loading tests are shown in Figure 5. It can be observed from the figure that the stress-strain curve of the whole cyclic impact test can be divided into three types. The initial stress-strain curve (one to five impacts) is a semi-elliptic high flat curve. In addition, the elastic modulus, peak stress, and maximum strain have not changed significantly. The stress in the loading stage increases sharply with the increase of strain. The slope is steep, and the elastic modulus value is large. The maximum stress at this stage represents the maximum impact stress value that the specimen can withstand during the entire impact process, which is called the peak strength. However, the stress in the unloading stage drops sharply with the increasing strain. In the mid-term (sixth to eighth impacts), there exists a gradient parabola. The changes in elastic modulus, peak stress, and maximum strain are more prominent than those in the initial stage. Besides, the change of stress with strain is larger than that of the initial stage in the loading section and unloading section. It shows that the micro-cracks In the mid-term (sixth to eighth impacts), there exists a gradient parabola. The changes in elastic modulus, peak stress, and maximum strain are more prominent than those in the initial stage. Besides, the change of stress with strain is larger than that of the initial stage in the loading section and unloading section. It shows that the micro-cracks in white sandstone are compacted and closed, resulting in small changes in modulus. Owing to the medium-term impact load, pore cracks begin to gradually expand and penetrate, and the bearing capacity suddenly decreases.
The later stage (the ninth impact) is a low flat parabolic curve, the peak stress is small, and the strain at the tail of the curve tends to decrease, which is consistent with the research results of the rock impact failure test under the one-dimensional dynamic and static combination determined by the literature [22]. This demonstrates that the white sandstone has not been completely destroyed and still possesses a certain load-bearing capacity, though it's capacity is weak. Therefore, it cannot be loaded under the same axial compression conditions.

Experimental Results and Discussion
This study lists the physical parameters and test data of a representative set of specimens, as listed in Table 3. Note: σ as is the axial pressure, ρ is density, σ fd is initial impact stress peak, σ md is the maximum stress peak of the cyclic impact, and σ cs is the combined static-dynamic strength. Figure 6 shows the relationship between the pH of the solution, the axial pressure, and the number of cyclic shocks. The number of cyclic impacts decreases with the increase of the axial pressure, and the number of impacts that can be endured under the axial pressure of 6.3 MPa is the most. As shown in the analysis, when the axial pressure is within a certain lower limit range, with the same load repeatedly repeating the impact, the original void inside the specimens will be closed first, and the ability and frequency of the sample to resist impact will be accordingly enhanced [37]. However, when the axial pressure is within a certain higher limit range, the secondary microcracks grow into pore cracks that penetrate the entire cross-section. During this process, the damage expands and the ability of the sample to resist external damage decreases sharply. In the middle and later stages of the impact stages, the whole rock specimen is finally damaged by tensile shear. Furthermore, this is similar to the dynamic characteristics of the cumulative damage evolution during excavation of underground jointed rock under repeated seismic load that is mentioned in Ref. [38]. With the pH of the solution, the number of shocks is normally distributed. The pH of the solution deviates from neutral, which indicates that the lower the number of shocks, the more obvious the corrosion effect of the solution.

The Trend of Cyclic Impact Number
void inside the specimens will be closed first, and the ability and frequency of the to resist impact will be accordingly enhanced [37]. However, when the axial pre within a certain higher limit range, the secondary microcracks grow into pore cra penetrate the entire cross-section. During this process, the damage expands and th of the sample to resist external damage decreases sharply. In the middle and late of the impact stages, the whole rock specimen is finally damaged by tensile she thermore, this is similar to the dynamic characteristics of the cumulative damage tion during excavation of underground jointed rock under repeated seismic load mentioned in Ref. [38]. With the pH of the solution, the number of shocks is n distributed. The pH of the solution deviates from neutral, which indicates that th the number of shocks, the more obvious the corrosion effect of the solution.

Relationship between Initial Peak Stress and Axial Pressure
The peak strength of the rock represents the maximum stress caused by the resistance of the white sandstone specimens during impact. The strength of the sp gradually weakens when the number of cyclic impacts increases. Although the peak deterioration law is similar, there also exist noticeable differences. As shown ure 7, with the increasing number of cycles under the axial pressure of 6.3 MPa a

Relationship between Initial Peak Stress and Axial Pressure
The peak strength of the rock represents the maximum stress caused by the impact resistance of the white sandstone specimens during impact. The strength of the specimen gradually weakens when the number of cyclic impacts increases. Although the overall peak deterioration law is similar, there also exist noticeable differences. As shown in Figure 7, with the increasing number of cycles under the axial pressure of 6.3 MPa and 12.6 MPa, the peak strength of the rock shows a trend of 'strengthening first and then weakening', which was different from the axial pressure of 20.5 MPa and 26.8 MPa. There exists no strength reinforcement at high pre-axial pressure.
The peak stresses of the initial impact under the axial pressure of 12.6 MPa are 42.03 MPa, 51.56 MPa, 49.61 MPa and 47.01 MPa, which are greater than the other three axial pressure conditions. When the number of impacts increases, the magnitude of peak stress degradation in the middle and later stages of this axial compression is more rapid than that of the other three axial compressions. This phenomenon occurs under any pH. This indicates that the dynamic strength of white sandstone at the initial stage is strengthened by 40% axial compression during cyclic impact. However, the axial compression at the middle and later stages will also aggravate the accumulation of internal damage of white sandstone specimens during impact. MPa, the peak strength of the rock shows a trend of 'strengthening first and then weakening', which was different from the axial pressure of 20.5 MPa and 26.8 MPa. There exists no strength reinforcement at high pre-axial pressure. The peak stresses of the initial impact under the axial pressure of 12.6 MPa are 42.03 MPa, 51.56 MPa, 49.61 MPa and 47.01 MPa, which are greater than the other three axial pressure conditions. When the number of impacts increases, the magnitude of peak stress degradation in the middle and later stages of this axial compression is more rapid than that of the other three axial compressions. This phenomenon occurs under any pH. This indicates that the dynamic strength of white sandstone at the initial stage is strengthened by 40% axial compression during cyclic impact. However, the axial compression at the middle and later stages will also aggravate the accumulation of internal damage of white sandstone specimens during impact.

Relationship between Peak Stress and Chemical Corrosion
The macroscopic manifestation of the water-rock reaction is the deterioration of the physical and mechanical properties of rock [39]. Figure 8 shows the relationship between the peak stress of the specimen and the chemical solution. Followed by the pH = 12 alkaline solution immersion test piece, the initial impact strength of the specimen is the lowest pH = 2 acid solution immersion. The maximum initial strength of the test piece is in a neutral solution at pH = 7. Complex physical and chemical reactions occur when rocks are immersed in a chemical solution. The physical interaction between water and rock mainly causes sandstone minerals to be dissolved in water. Changes in rock composition and structure are mainly due to the corrosion of minerals in chemical solutions. With the increase of acidity and alkalinity, the damage of rock in solution is mainly determined by chemical reactions. Mineral particles and the ion exchange reaction in the solution generate a new secondary mineral, changing the original mineral chemical composition, the generated secondary mineral composition and molecular weight. Density is very different

Relationship between Peak Stress and Chemical Corrosion
The macroscopic manifestation of the water-rock reaction is the deterioration of the physical and mechanical properties of rock [39]. Figure 8 shows the relationship between the peak stress of the specimen and the chemical solution. Followed by the pH = 12 alkaline solution immersion test piece, the initial impact strength of the specimen is the lowest pH = 2 acid solution immersion. The maximum initial strength of the test piece is in a neutral solution at pH = 7. Complex physical and chemical reactions occur when rocks are immersed in a chemical solution. The physical interaction between water and rock mainly causes sandstone minerals to be dissolved in water. Changes in rock composition and structure are mainly due to the corrosion of minerals in chemical solutions. With the increase of acidity and alkalinity, the damage of rock in solution is mainly determined by chemical reactions. Mineral particles and the ion exchange reaction in the solution generate a new secondary mineral, changing the original mineral chemical composition, the generated secondary mineral composition and molecular weight. Density is very different from the original mineral. Inherent internal cementation way and structure characteristics change accordingly, eventually degrading sandstone in terms of its macro mechanical performance.
In acidic solution, alkaline cations on the surface of feldspar exchange with hydrogen ion in the solution, forming a weak acidic silicon-rich complex. Potassium, sodium, and calcium in feldspar detach from the rock mass skeleton and enter the solution [40].  (6) generated secondary mineral composition and molecular weight. Density is very different from the original mineral. Inherent internal cementation way and structure characteristics change accordingly, eventually degrading sandstone in terms of its macro mechanical performance.
(a) (b) In acidic solution, alkaline cations on the surface of feldspar exchange with hydrogen ion in the solution, forming a weak acidic silicon-rich complex. Potassium, sodium, and calcium in feldspar detach from the rock mass skeleton and enter the solution [40].
Fe2O3 + 6H + →2Fe 3+ + 3H2O CaCO3 + 2H + →Ca 2+ + H2O + CO2↑ (8) In the neutral solution, the solubility of sandstone components is low. Besides, it is difficult to react violently with the aqueous solution. Only a small amount of feldspar and quicklime participate in the chemical reaction and are stable.
In alkaline solution, hematite, calcite, quicklime, and other minerals in sandstone remain relatively stable. However, quartz and feldspar in sandstone are easy to react with hydroxide ion in alkaline solution.
SiO2 + 2OH − →SiO The failure mode of white sandstone is shown in Figure 9a-p under cyclic impact. White sandstone specimens mainly experience conjugate hyperbolic tensile shear failure, which was characterized by destructive body flaking around the hyperbola due to interfacial friction. Corrosion by acid and alkaline solutions of sandstone fragments' impact degree is more than with the neutral solution, with a smaller average size of fragments. In addition to the chemical reactions listed earlier, small amounts of hematite, and calcite in the mineral composition of sandstone also react with hydrogen ions in solution.
In the neutral solution, the solubility of sandstone components is low. Besides, it is difficult to react violently with the aqueous solution. Only a small amount of feldspar and quicklime participate in the chemical reaction and are stable.
In alkaline solution, hematite, calcite, quicklime, and other minerals in sandstone remain relatively stable. However, quartz and feldspar in sandstone are easy to react with hydroxide ion in alkaline solution.
The failure mode of white sandstone is shown in Figure 9a-p under cyclic impact. White sandstone specimens mainly experience conjugate hyperbolic tensile shear failure, which was characterized by destructive body flaking around the hyperbola due to interfacial friction. Corrosion by acid and alkaline solutions of sandstone fragments' impact degree is more than with the neutral solution, with a smaller average size of fragments. In an acidic solution, the sandstone is completely disintegrated with a high proportion of fine particle size. Feldspar, clay, hematite, calcite and other minerals in sandstone are captured by solution, resulting in an increase in small particle size fragments. Structural cavities make rock structures become looser and more fragile. In an alkaline solution, the quartz particles on the surface of the specimen will be exfoliated by the solution, thereby increasing the number of fine particles. In neutral solutions, the solubility of mineral components is low, and the degree of fragmentation is mainly dependent on the cyclic shock load.
By testing the broken samples, it has been found that the solution corroded the sandstone and caused the internal cavity of the sandstone to produce structural defects. During cyclic impact, the rock exhibits a low-cycle fatigue damage and strength degradation. Repeated impact causes the rock particles to loosen and fall off. As the number of cycles increases, this phenomenon gradually penetrates into the interior of the sandstone. Meanwhile, the porosity of the internal structure allows the chemical solution to further penetrate into the interior of the sandstone. This interaction improves exposure between chemical solutions and mineral particles, thus allowing for a more thorough chemical reaction between water and rock. Therefore, the hydration solution and the cyclic shock influence the rate and degree of rock metamorphism while promoting each other in the process of rock metamorphism.
In an acidic solution, the sandstone is completely disintegrated with a high proportion of fine particle size. Feldspar, clay, hematite, calcite and other minerals in sandstone are captured by solution, resulting in an increase in small particle size fragments. Structural cavities make rock structures become looser and more fragile. In an alkaline solution, the quartz particles on the surface of the specimen will be exfoliated by the solution, thereby increasing the number of fine particles. In neutral solutions, the solubility of mineral components is low, and the degree of fragmentation is mainly dependent on the cyclic shock load. By testing the broken samples, it has been found that the solution corroded the sandstone and caused the internal cavity of the sandstone to produce structural defects. During cyclic impact, the rock exhibits a low-cycle fatigue damage and strength degradation. Repeated impact causes the rock particles to loosen and fall off. As the number of cycles increases, this phenomenon gradually penetrates into the interior of the sandstone. Meanwhile, the porosity of the internal structure allows the chemical solution to further penetrate into the interior of the sandstone. This interaction improves exposure between chemical solutions and mineral particles, thus allowing for a more thorough chemical reaction between water and rock. Therefore, the hydration solution and the cyclic shock influence the rate and degree of rock metamorphism while promoting each other in the process of rock metamorphism. e Figure 9. The destructed forms of white sandstone (a-p).

Conclusions
To conclude, this study introduces the cyclic impact test of white sandstone specimens under chemical corrosion and axial compression, as well as stress-strain and dynamic strength variation characteristics. Several vital conclusions are presented as follows: (1) The stress-strain curve during the cyclic impact test of white sandstone can be divided into three types: an early semi-elliptic high flat curve, a mid-gradient parabola, and low flat parabolic curve. (2) With the increase of the number of cycles under the same load, the peak strength of the rock shows a trend of 'strengthening first and then weakening'. The strength of stone resistance to impact failure reached its maximum at pH of 7 and axial pressure of 12.6 MPa. (3) Under the same axial pressure, the effect of solution pH on the initial dynamic strength of white sandstone is a normal distribution. The acidic and alkaline environment damage is harmful to rocks, while neutral environment generates little effect. The influence of solution pH on the dynamic strength of white sandstone is not apparent during the middle and late periods. (4) Through carrying out a series of studies, the proper proportion of loading will make the micro-fractures in the white sandstone tend to be tight, and the impact strength of the white sandstone will be strengthened in the early stage. Overloading will aggravate the deterioration of the strength of the white sandstone under the impact and further intensify the damage in the middle and later stages. When the loading ratio exceeds a certain limit, the micro-cracks of the white sandstone will increase due to the increasing loading ratio. Furthermore, the structure of rock will be destroyed.