Investigation on Mechanical Characteristics and Microstructure of Cemented Whole Tailings Backﬁll

: A paste backﬁll performance can be primarily evaluated through the mechanical and physical characteristics of the components involved. In this study, the effects of solid components’ tailings, binders and waters contents on microstructural evolution and mechanical properties of uncemented whole tailings backﬁll (CWTB) mixtures were investigated. Different mixtures of ordinary Portland cement of 1, 3 and 5 wt. % and solid concentrations at 72 wt. %, 74 wt. % and 75 wt. % were selected and rheological test was conducted to deﬁne the slump ﬂuidity and yield stress. The microstructure of the solid component before and after the preparation and chemical composition were analyzed by the Scanning electron microscope and XRD analysis, respectively. The results show that a positive correlation between yield stress and slump values of CWTB paste slurries, the decrease of ﬂow consistence leads to the reduction of the water content on the CWTB mixtures and the ﬂow resistance of the paste. With the highest solids content, unconﬁned compressive strength (UCS) of CWTB varies between 0.1–0.9 MPa. Increasing the solid content affects the porosity and improves the strength resistance of CWTB mixtures. The ﬁndings in this study can therefore lead us to a statement that CWTB chemical components seem to be an important factor in cemented paste backﬁll (CPB) design and mine operations.


Introduction
In China, a total surface waste of 14.6 billion tons and about 1.28 billion m 3 of goafs are left underground, which brings out serious environmental and security problems [1][2][3]. As perceived by some observers, 28 provinces, including districts and cities, are affected and show direct and side effects on the surrounding environment, allowing us to keep in mind that environmental protection and security of resources are national policy needs and concerns. Cemented paste backfill in China is undergoing significant development in the mining industry [4]. Cemented paste backfill has been considered a green technique, which can solve the subsidence of surface and underground mines to protect the environment and improve mining resource recovery [1,5]. As described in many studies, the cemented paste backfills are a type of mixed material composite made with a combination of crushed mineral tailings (70-85 wt. % solids) from an ore plant extractive operation, mixed with water (fresh or mine processed water) and hydraulic binders (slag, Portland cement, fly ash, etc.) [6][7][8]. To obtain the required mechanical resistance properties of cemented backfill, the proportion of each component involved needs to be determined. As mentioned in other studies, the tailings ratio could be approximately between 80%-85%, the water percentage ranges from 15% to 25% by solid weight, and the portion of the hydraulic binder added could range from 3 to 7 wt. % in all mixtures [9,10].
The variation among those parameters associated with environmental condition such as curing age and temperature during preparation of the cemented paste backfill can affect the mechanical strength and stability of the overall paste backfill desired [7]. Generally, the physicochemical characteristic of the crushed mineral tailing, such as particle size, pore structure, moisture and the chosen cements (binders, superplasticizer and admixture flocculants) are the most influencing factors. Research studies conducted by Yin, et al. (2012) [6] on the effect of ultra-fine grained tailings on paste backfill performance suggest that well-graded tailings can optimize the microstructural and mechanical properties of cementitious paste back-fill [11][12][13]. Ouellet et al. [14] has recommended that the paste backfill should contain a minimum of 15% to 20% solids finer than 20 µm. Additionally, Benzaazoua, et al. [15] have provided some guidance to better control the hardening phenomena of paste backfills. Furthermore, Rheology and geomechanical stability reflect the quality and performance of the cemented paste backfill [16]. Rheology is explained in terms of slump, the solid content, shear yield strength and the uniaxial compressive strength [16][17][18][19].
To better understand this phenomenon and quality of the paste backfill, this study has been conducted by using various required percentages of solid concentration to prepare a cemented paste backfill. To achieve this, three solid contents and three binder dosages of ordinary Portland cement were used for investigating mechanical characteristics and microstructural of paste backfill. In addition, major factors, such as solid contents, binder dosages, water content and curing time, were mainly considered for slump tests, yield stress and unconfined compressive strength (UCS), and the relationship between those parameters with UCS of cemented whole tailings backfill (CWTB) samples were studied. Further, the scanning electron microscopy (SEM) technique was used to evaluate at 14, 28 and 42 days the cured CWTB samples containing 1 wt. % binder dosage with different solid contents. We expected that the results of this research study will provide good knowledge on the rheological properties of the required CWTB, which will give an efficient performance on the behavior of the above-mentioned material, under comparable situations.

Tailings Characteristics Based on Elements Collected through Jinchuan Nickel Mine Site
The tailings materials used in this study were sulfides-rich tailings. These wet tailings samples were the underflow of overburden thickener in the concentrator, taken from the tailings treatment plant of Jinchuan nickel mine deposit located in the Northwest area of Gansu province, (China). These raw tailings were kept wet and transported to the laboratory in sealed plastic bags to prevent oxidation and/or evaporation. Before the experimental analysis, the mills tailings were placed in a drying box furnace and naturally cooled to prepare the paste tailings samples. Particle size distribution (PSD) of the tailings specimens was determined ( Figure 1) using the size analysis and determination of soil constants procedure (ASTM D421) [20] and Malvern top sizer laser particle size analyzer (Shanghai, China) [21]. Many paste tailings were used wet in order to conduct a set of experimental tests needed for material characterization. The tailings samples were determined to contain 12% sulfur (S), and the analysis confirms the presence of pyrite in mineral wastes. Minerals 2021, 11, x FOR PEER REVIEW 3 of 16 The results of the physical characterization of the tailings presented in Table 1 and Figure 1 illustrated that the tailings material used has an apparent porosity around 36%, a specific gravity of 2.8, a bulk density of 2.3 g/cm 3 and a specific surface area (SSA) of 630.036 m 2 /kg. The measurements cover a range of 0.1 to 750 μm with 1% precision. It was observed that the contents of 0.075 mm and 0.025 mm in the tailings account, respectively, for 83.18% and 36%. Still, the content of 0.038 mm particles accounts for 64.24%, and that of 0.02 mm particles accounts for 47.03%, as demonstrated by Yin et al. [6] on the particle size of fine sandy aggregates. The obtained GSD based on the ASTM standard [22] shows the tailings sample is well-graded sand with a coefficient curvature Cc (Equation (1)) and a coefficient of uniformity Cu (Equation (2) (Cc) expressed the coefficient of curvature, which is the grading ratio of square D30 to D60 and D10. D10, D30 and D60 are effective particle size with 10%, 30% and 60% of finer particles in the total soil, respectively. The calculated Cc was 1.3.
(Cu) expressed the particle size ratio of D60 to D10. D10 and D60 are respectively effective particle size with 10% and 60% of finer particles in the total soil. The calculated Cu was 8.5 and is summarized in Table 1.
As the results showed, the tailings could be respectively classified as silty sand tailings. The chemical composition of the waste made through X-ray fluorescence analysis allowed the list of the results presented in Table 2. As displayed in Table 2, the dominant chemical elements are silicon dioxide (42.2%), magnesium oxide (32.7%) and ferric oxide (12.14%), aluminum oxide (4.04%), calcium oxide (3.73%) with lower amounts of potassium oxide (0.39%) titanium dioxide (0.33%), sulfur (1.25%), copper (0.26%), chlorite (0.057%) and nickel (0.28%), same compositions of sulfur and nickel are conferred to [11,12] Looking at the loss-on-ignition, it was apparent that organic substances and volatile compounds made up about 4.22% of the tailings. The mineralogical composition obtained using A Ultima IV X-ray diffractometer equipped with a copper anticathode (Rigaku,Tokyo,Japan), X-ray analyses specified in Figure 2a that the abundant silicate The results of the physical characterization of the tailings presented in Table 1 and Figure 1 illustrated that the tailings material used has an apparent porosity around 36%, a specific gravity of 2.8, a bulk density of 2.3 g/cm 3 and a specific surface area (SSA) of 630.036 m 2 /kg. The measurements cover a range of 0.1 to 750 µm with 1% precision. It was observed that the contents of 0.075 mm and 0.025 mm in the tailings account, respectively, for 83.18% and 36%. Still, the content of 0.038 mm particles accounts for 64.24%, and that of 0.02 mm particles accounts for 47.03%, as demonstrated by Yin et al. [6] on the particle size of fine sandy aggregates. The obtained GSD based on the ASTM standard [22] shows the tailings sample is well-graded sand with a coefficient curvature Cc (Equation (1)) and a coefficient of uniformity Cu (Equation (2)) (Cc) expressed the coefficient of curvature, which is the grading ratio of square D 30 to D 60 and D 10 . D 10 , D 30 and D 60 are effective particle size with 10%, 30% and 60% of finer particles in the total soil, respectively. The calculated Cc was 1.3.
(Cu) expressed the particle size ratio of D 60 to D 10 . D 10 and D 60 are respectively effective particle size with 10% and 60% of finer particles in the total soil. The calculated Cu was 8.5 and is summarized in Table 1. As the results showed, the tailings could be respectively classified as silty sand tailings. The chemical composition of the waste made through X-ray fluorescence analysis allowed the list of the results presented in Table 2. As displayed in Table 2, the dominant chemical elements are silicon dioxide (42.2%), magnesium oxide (32.7%) and ferric oxide (12.14%), aluminum oxide (4.04%), calcium oxide (3.73%) with lower amounts of potassium oxide (0.39%) titanium dioxide (0.33%), sulfur (1.25%), copper (0.26%), chlorite (0.057%) and nickel (0.28%), same compositions of sulfur and nickel are conferred to [11,12] Looking at the loss-on-ignition, it was apparent that organic substances and volatile compounds made up about 4.22% of the tailings. The mineralogical composition obtained using A Ultima IV X-ray diffractometer equipped with a copper anticathode (Rigaku, Tokyo, Japan), X-ray analyses specified in Figure 2a (112) and (204)     The particle size distribution and the physical properties (density, specific surface area, etc.) of the binders are shown in Figure 1 and Table 1, respectively. The specific den-

Binder Characteristics and Water
The particle size distribution and the physical properties (density, specific surface area, etc.) of the binders are shown in Figure 1 and Table 1, respectively. The specific density (2.92 g/cm 3 ) and the specific surface area (2067.94 m 2 /kg) of OPC are typical of cementitious materials. Besides, it was observed that the finer particles of ordinary Portland cement (OPC) shown in Table 1 are poor and unrecorded; it implies that OPC particles were poorly graded. Furthermore, the coefficient of uniformity of OPC shows uneven particle gradation. According to the Chinese standard (GB 175-2007), ordinary Portland cement used as a binder for this study is silica cement [23]. X-ray fluorescence (XRF) carried out to analyze the principal chemical constituents are presented in Table 2. In the components of OPC (32.5R) [7], the main chemical was CaO (65.10%), SiO 2 (23%) and Al 2 O 3 (5.18%) and a small amount of K 2 O, MgO. As shown in Figure 2b, mineralogical analysis of XRD diffraction patterns of ordinary Portland cement presents evidence of crystallized phases

Experimental Methods
Wet tailing samples were directly collected from the total tailing pump station, which were slurry and sealed in plastic barrels. A consolidation test is carried out to explore the strength of the tailings under the condition of different ratio of consolidation agent to find the appropriate consolidation agent and ratio. The proportion and the mixing elements used are presented in Table 3. The experimental technical route of cemented whole tailings backfill recipes are presented scheme in Figure 3. As displayed, the main steps of the CWTB's preparation begin, with choosing material to each process which include mixing of all CWTB recipes, slump test, pouring the CWTB's samples on triplicate square molds, curing box, servo compression testing machine for the unconfined strength compressive and scanning electronic microscopic for microstructure analysis of CWTB's samples.

Experimental Methods
Wet tailing samples were directly collected from the total tailing pump station, which were slurry and sealed in plastic barrels. A consolidation test is carried out to explore the strength of the tailings under the condition of different ratio of consolidation agent to find the appropriate consolidation agent and ratio. The proportion and the mixing elements used are presented in Table 3. The experimental technical route of cemented whole tailings backfill recipes are presented scheme in Figure 3. As displayed, the main steps of the CWTB's preparation begin, with choosing material to each process which include mixing of all CWTB recipes, slump test, pouring the CWTB's samples on triplicate square molds, curing box, servo compression testing machine for the unconfined strength compressive and scanning electronic microscopic for microstructure analysis of CWTB's samples.

Slump Test Preparation
According to Clayton [24], a paste's rheological behavior properties can be estimated with a slump test. The slump technique is convenient to evaluate the flow properties of a different paste. In this study, the experimental slump procedure was made following the American standard test method (ASTM) C143/C143M-17 [25]. The effect of solids content, tailings and low binder content on CWTB performance were studied. A total of 9 paste backfills samples were prepared by mixing the tailings, tap water and binder with an immersion mixer at a selected homogeneous consistency. Each paste backfill was tamped 25 times with an iron rod to remove most of the sample's air pockets [26]. Depending on the different chosen concentrations of solids, the CWTB contained 79-85 wt. % residues by a dry mass of the total mixes. Initial porosity contents for all whole tailings was set at 36%. Water-cement (w/c) ratios of 26, 8.3 and 5 corresponded to binder proportions of 1, 3 and 5 wt. %, respectively. As an empirical measure of consistency, the slump height depends on both the density of the material and the plastic yield strength, which in turn depends on the particle size, specific gravity, size and chemical composition. To achieve the height of the slump desired, Equation (3) below has been used: where τ 0 is plastic yield stress of paste, ρ: density of paste material, V: volume of water of paste tailings. R: Radius of paste material, g is the conventional gravitational acceleration due to the gravity of material expresses by standard formula 9.80 m/s 2 . Following Equation (4), the slump consistency was determined in Equation (4).
The paste material tested using the Abram cone reached 10, 9 and 7 inches for different solids concentrations. Immediately after the slump test, the samples were mixed again once and then poured into molds of the same size (7.05 × 7.05 × 7.05 cm) and the resulting CWTB specimens were left at ambient room temperature for five days, to remove the excess of water.
According to Equations (3) and (4), the plastic yield stress (τ 0 ) and slump heights of CWTBs samples at different solids content were calculated and the values are reported in Table 4. The resulting paste backfill squares were then stored and cured in a controlled humidity chamber with 95% relative humidity and a temperature of 27 • C during the desired curing times of 14, 28 and 42 days [26] to simulate typical curing conditions in operation mines [27].

Unconfined Strength Test
Unconfined compression tests are frequently used for cemented soils and concrete, and much experience regarding them has been reported. Additionally, the unconfined compression strength (UCS) is the main strength index used to evaluate CWTB's strength performance [28]. According to ASTM C39/C39M [29], the UCS and the total porosity of CWTB samples were determined. For this study, a Servo compression testing machine with a single axis press made by Sanyu was used. The range of the press is 0~50 kN. The loading speed and size of the test block were adjusted by the support of a software. The loading speed was set at 0.1 kN/s. The height, length and width of the test block manually entered into the single axis press computer is 7.07 cm, and for each group a number of 3 blocks were tested. For accuracy, each curing time test was carried out in triplicate, and only the maximum average strength was considered [5]. The porosity test was performed for each mass concentration at different binder proportions.
To predict the mechanical strength of CWTB, the formula (Equation (5)) held to: where K is the constant, Bw is the cement ratio; V w , the water content of each CWTB recipe and e is the void ratio of CWTB sample ad different curing time.

Microstructural Test
The microstructure of CWTB's was examined under a ZEISS EVO 18 (SEM, Jena, Germany) scanner electron microscope. Before carrying out the SEM analysis, the samples were dried 3 times with the MC1000 Ion Sputter Coater at 50 • C, until they reached good stability for microscopic observation. This makes it easier to cover smaller diameter particles at a high granularity and to minimize damage to the sample irradiation for rapidly moving.  [30]. After that the slump value rapidly reduces, showing the hydration of cement. [31,32]. This experiment suggests that OPC binder and water contents of CWTB samples speed up cement's hydration process.

Influence of the Solids Content on the on the Slump Values of Cemented Whole Tailings Backfill
Further, higher mass fraction of tailings leads to the consistency of slump desired. Figure 5 confirmed Figure 4 with the reduction of slumps' heights whilst the solids content increased. This is due to the fact that the strength of particles at different solids content increased with the ratio of tailings, which reduced water and then enhanced the compaction of the paste and characterized the filling of void ration included on the tailings.
The relationship between slump values and yield stress of CWTB's mixtures at 1 wt. % OPC was discussed in Figure 6. It showed that the variation of fluidity of CWTB's mixtures set up higher yield stress with the increase of mass concentration. It is due to the reduction in water content resulting in a decrease in porosity caused by the reduction in the void ratio between particles, which results in colloidal interaction between particles caused by the hydration products used. In addition, free water migration is reduced between paste particles, optimizing the slump fluidity and improving the yield strength of different CWTB mixtures at different mass concentrations. Thus, by binding the hydration of the OPCs and particles in direct contact, this network structure increases the lubricating film thickness and improves the yield stress of the CWTB mixtures [4,33].   [30]. After that the slump value rapidly reduces, showing the hydration of cement. [31,32]. This experiment suggests that OPC binder and water contents of CWTB samples speed up cement's hydration process.

Influence of the Solids Content on the on the Slump Values of Cemented Whole Tailings Backfill
Further, higher mass fraction of tailings leads to the consistency of slump desired. Figure 5 confirmed Figure 4 with the reduction of slumps' heights whilst the solids content increased. This is due to the fact that the strength of particles at different solids content increased with the ratio of tailings, which reduced water and then enhanced the compaction of the paste and characterized the filling of void ration included on the tailings.
The relationship between slump values and yield stress of CWTB's mixtures at 1 wt. % OPC was discussed in Figure 6. It showed that the variation of fluidity of CWTB's mixtures set up higher yield stress with the increase of mass concentration. It is due to the reduction in water content resulting in a decrease in porosity caused by the reduction in the void ratio between particles, which results in colloidal interaction between particles caused by the hydration products used. In addition, free water migration is reduced between paste particles, optimizing the slump fluidity and improving the yield strength of different CWTB mixtures at different mass concentrations. Thus, by binding the hydration of the OPCs and particles in direct contact, this network structure increases the lubricating film thickness and improves the yield stress of the CWTB mixtures [4,33].       [34]. Indeed, the percentage of ordinary Portland cement has increased in the formulation of paste backfill mixtures. There is an increase in the mechanical strength of CWTB samples due to the activation of secondary C-S-H gels such as ettringite, C3S gypsum contained in ordinary Portland cement. Besides, adding Portland cement is very effective in reducing metal mobility. The hydration age of 14 days at 75 wt. % solids content with 5 wt. % binder dosage is presented in Figure 7a,b. From these figures, we have the confirmation of the increase in hydration products reveals by the X-ray diffraction test. The increased dose of OPC allows direct particle-to-particle contact, which improves the microstructure of CWTB samples and leads to CSH gel, ettringite and gypsum formation. So, the use of OPC binder leads to a reduced permeability of the paste at solids content of 75 wt. %. In Figure 7c,d, after the hydration age of 28 days at 75 wt. % solids content with 3 wt. % binder dosage, there are a glassy phase and some lower hydration products that bond to the cemented particles. We can observe the tailings, quartz and some lower presence of voids.

Effect of Solid Content on the Microstructural Properties of CWTB
However, Figure 7e,f shows that after hydration age of 42 days at 75 wt. % solids content with 1 wt. % of binder dosage, there is a high porosity (presence of voids) and insufficient quantity of hydration products to bond to the cemented. Note that X-ray  Figure 7 shows scanning electron microscope (SEM) images of different binder dosages 1, 3 and 5 wt. % at a solid content of 75 wt. %. The tailings had a rough and uneven surface, while the natural sand had a smoother surface [34]. Indeed, the percentage of ordinary Portland cement has increased in the formulation of paste backfill mixtures. There is an increase in the mechanical strength of CWTB samples due to the activation of secondary C-S-H gels such as ettringite, C 3 S gypsum contained in ordinary Portland cement. Besides, adding Portland cement is very effective in reducing metal mobility. The hydration age of 14 days at 75 wt. % solids content with 5 wt. % binder dosage is presented in Figure 7a,b. From these figures, we have the confirmation of the increase in hydration products reveals by the X-ray diffraction test. The increased dose of OPC allows direct particle-to-particle contact, which improves the microstructure of CWTB samples and leads to CSH gel, ettringite and gypsum formation. So, the use of OPC binder leads to a reduced permeability of the paste at solids content of 75 wt. %. In Figure 7c,d, after the hydration age of 28 days at 75 wt. % solids content with 3 wt. % binder dosage, there are a glassy phase and some lower hydration products that bond to the cemented particles. We can observe the tailings, quartz and some lower presence of voids.

Effect of Solid Content on the Microstructural Properties of CWTB
However, Figure 7e,f shows that after hydration age of 42 days at 75 wt. % solids content with 1 wt. % of binder dosage, there is a high porosity (presence of voids) and insufficient quantity of hydration products to bond to the cemented. Note that X-ray diffraction (XRD) analyses performed on the weathered zone did not show any secondary minerals. This was unexpected, as secondary minerals are often poorly crystallized or amorphous and therefore ignored by the XRD analysis [35]. Moreover, the quantity of secondary minerals could often be under the detection limit of the XRD analysis.
From the SEM image, it can be seen that with the increase of the slurry concentration, the porosity of the paste at 14, 28 and 42 days of curing decreases, which is due to the hydration products gradually covering the original pores, and the decrease of porosity. The paste at 28 days of curing at four concentrations rarely saw a single calcium acicular stone and C-S-H column, which is due to the continuous development of hydration products. The results show that the porosity of CWTB decreases with increasing curing time [17,31].
The results show that when the concentration of the slurry is 75 wt. %, with the increase of curing time at different times, the hydration reaction is gradually carried out, and the hydration products gradually fill the pores, which makes the strength of the paste backfill gradually increase [18]. main reason for the low strength of the paste backfill. In SEM images, the pore size of 75 wt. % concentration was the smallest, and the porosity was also the smallest. Although the pore size of 74 wt. % concentration was larger than that of 72 wt. % concentration group, the porosity was smaller than that of 74 wt. % concentration group and the pore size and porosity of 72 wt. % concentration was the largest. This also verifies the previous test results of porosity and explains the reason why the strength changes with the concentration from the perspective of porosity and hydration products [4,28,35] Minerals 2021, 11, x FOR PEER REVIEW 11 of 16 For better optimization of CWTB's microstructures, another SEM-EDS analysis was carried out with a Brunker JEOL JSM 7610F used for its high performance. Figure 8 displays the microstructures at 10 μm and 1 μm. SEM micrograph of the CWTB samples containing different binder dosages at 75 wt. % solids contents was analyzed after the testing of UCS. It was observed that the voids between the matrix of CTWB's samples reduced from those in Figure 8a-d [19]. In addition, the chemical composition revealed by the EDS graph (Figure 8e) shows the persistence of the calcium element, followed by the sulfate element. This finding is in accordance with the initial composition of the tailings before CWTB mixtures [36,37]. However, the compounds of CWTB mixtures hinder the hydration reaction of cement, there are large pores in the 42 days of curing, and the existence of large pores is the main reason for the low strength of the paste backfill. In SEM images, the pore size of 75 wt. % concentration was the smallest, and the porosity was also the smallest. Although the pore size of 74 wt. % concentration was larger than that of 72 wt. % concentration group, the porosity was smaller than that of 74 wt. % concentration group and the pore size and porosity of 72 wt. % concentration was the largest. This also verifies the previous test results of porosity and explains the reason why the strength changes with the concentration from the perspective of porosity and hydration products [4,28,35] For better optimization of CWTB's microstructures, another SEM-EDS analysis was carried out with a Brunker JEOL JSM 7610F used for its high performance. Figure 8 displays the microstructures at 10 µm and 1 µm. SEM micrograph of the CWTB samples containing different binder dosages at 75 wt. % solids contents was analyzed after the testing of UCS. It was observed that the voids between the matrix of CTWB's samples reduced from those in Figure 8a-d [19]. In addition, the chemical composition revealed by the EDS graph (Figure 8e) shows the persistence of the calcium element, followed by the sulfate element. This finding is in accordance with the initial composition of the tailings before CWTB mixtures [36,37]. For better optimization of CWTB's microstructures, another SEM-EDS analysis was carried out with a Brunker JEOL JSM 7610F used for its high performance. Figure 8 displays the microstructures at 10 μm and 1 μm. SEM micrograph of the CWTB samples containing different binder dosages at 75 wt. % solids contents was analyzed after the testing of UCS. It was observed that the voids between the matrix of CTWB's samples reduced from those in Figure 8a-d [19]. In addition, the chemical composition revealed by the EDS graph (Figure 8e) shows the persistence of the calcium element, followed by the sulfate element. This finding is in accordance with the initial composition of the tailings before CWTB mixtures [36,37].

Influence of the Solids Content on the Mechanical Strength of Fresh Cementitious Materials
The unconfined compressive strength (UCS) and the total porosity of CWTB samples were determined, according to ASTM C39 [7]. Figure 9 shows that CWTB with higher solids content presented higher UCS values for each curing time, and with lower solids content-lower UCS values for each curing time; UCS increased with curing time for each CWTB formulation. For example, at 28 days of curing, CWTB at Cw of 72 wt. % and 74 wt. % showed the same UCS of 0.2 MPa, but at Cw of 72 wt. % of 28 days curing, there is

Influence of the Solids Content on the Mechanical Strength of Fresh Cementitious Materials
The unconfined compressive strength (UCS) and the total porosity of CWTB samples were determined, according to ASTM C39 [7]. Figure 9 shows that CWTB with higher solids content presented higher UCS values for each curing time, and with lower solids content-lower UCS values for each curing time; UCS increased with curing time for each CWTB formulation. For example, at 28 days of curing, CWTB at Cw of 72 wt. % and 74 wt. % showed the same UCS of 0.2 MPa, but at Cw of 72 wt. % of 28 days curing, there is a relative increase of UCS value corresponding to 0.9 MPa. Similar results of UCS values increase with the rise CWTB Cw concentrations from 74% to 80% and 75% to 80% were found by Yin et al., 2012 andOuattara et al. 2018, respectively [6,30]. The paste sample with an initial solid concentration of 72 wt. % has a higher porosity than 75 wt. %. It implies that the water content of CWTB decreased while the solids content increased. The water content also indicated that the pore size decreased only with the addition of 1 wt. % of binder (after 42 days of curing). It concludes that the binder's reduction does not influence the paste's threshold diameter until the proportion reaches approximately 1 wt. %. In the unconfined compressive strength of cemented tailings backfill, moisture content reduction increases the proportion of solid content in the backfill, increasing its compactness and reducing its porosity.
The results also reveal that the mechanical properties of CWTB are positively related to its microstructure [14,38]. The CWTB microstructure performance is affected by the primary phenomenon, namely secondary mineral precipitation and cement hydration [6].
For cemented whole tailings backfill samples, the UCS increases as the binder dosage increases. At 75 wt. % solids content and 5 wt. % binder dry mass dosage, UCS increases, whilst UCS decreases as the solids content and binder dosage decreases. The porosity of the CWTB then becomes significant as a function of the evolution of curing time. Additionally, the increase of cement ratio and the water reduce rate positively affects the cement hydration [16]. However, cemented whole tailings backfill mixtures, as in this study, made from fine aggregates, lose strength faster than those made from coarse aggregates. The volume of voids between the tailings particles to be filled by cement hydration product is very large in paste fill specimens made from fine tailings (higher porosity) than those made from coarser tailings material.
The migration rate of free water leads to the increase of water content in the filling body. As the self-water migration is close to the end, the migration rate also decreases, and the consumption rate of the hydration degree is greater than that of free water, which makes the internal acoustic water in the filling body. Due to the decrease of concentration, the free water in the early migration increases, which leads to the extension of the initial acoustic water upper segment [16].
In this stage (Figure 10), due to the water consumption of solidification and evaporation, the water contents in CWTB decreases, and the matrix suction also increases, but the change is relatively slow, which is the stage of slow increase of CWTB strength.
makes the internal acoustic water in the filling body. Due to the decrea the free water in the early migration increases, which leads to the ext acoustic water upper segment [16].
In this stage (Figure 10), due to the water consumption of solidifi tion, the water contents in CWTB decreases, and the matrix suction al change is relatively slow, which is the stage of slow increase of CWTB Based on the analysis of the correlation mechanism of the paste field performance, the paste solidification is divided into three stages: t ture content, the rapid consolidation and the slow increase of strength internal changes of CWTB in these three stages are analyzed. The influence of porosity on different solids contents of CWTB s ratio illustrate in Figure 11 were discussed. Figure 11 demonstrates rosity and cement ratio on the mechanical characteristics of fresh CW the basis of this graph, it can be obviously discovered that a higher v 14 28 42 Based on the analysis of the correlation mechanism of the paste filling force's multi field performance, the paste solidification is divided into three stages: the increase of moisture content, the rapid consolidation and the slow increase of strength. The reasons for the internal changes of CWTB in these three stages are analyzed.
The influence of porosity on different solids contents of CWTB samples and cement ratio illustrate in Figure 11 were discussed. Figure 11 demonstrates the influence of porosity and cement ratio on the mechanical characteristics of fresh CWTB specimens. On the basis of this graph, it can be obviously discovered that a higher value of UCS results in the increase of fresh CWTB mixtures. That is to say, a higher cement ratio value implies stronger cement hydration process, which generates larger amount of hydration products to raise the viscosity and shear stress of fresh CWTB slurries. in the increase of fresh CWTB mixtures. That is to say, a higher cement ratio value implies stronger cement hydration process, which generates larger amount of hydration products to raise the viscosity and shear stress of fresh CWTB slurries. Figure 11. Effect of porosity on different solids contents and cement ratio.

Conclusions
In this study, the influence of solid content, curing age and temperature on the preparation of cemented paste backfill CWTB were experimentally evaluated. Notably, a significant change in the slump value was observed with the increase of the solid content designed, which demonstrates the relative influence of the solid concentration on the

Conclusions
In this study, the influence of solid content, curing age and temperature on the preparation of cemented paste backfill CWTB were experimentally evaluated. Notably, a significant change in the slump value was observed with the increase of the solid content designed, which demonstrates the relative influence of the solid concentration on the strength properties of the required CWTB. The slump value obtained in this study according to the different solid concentration demonstrates an ideal slump as compared to the conventional value of the slump.
Regarding the proportion of binder agent, the variation of the fluidity of CWTB mixture showed a high yield stress with the increased of solid concentration. This phenomenon suggested that the addition of ordinary Portland cement in 1 wt. % proved to be very effective in reducing metals' mobility and merging the different CWTB particles. Besides, with the curing age, the strength development of the CWTB mixture at different binder dosage was intensified with the increase of solid concentration. For instance, the strength development was slow in the first 14 days and became more intense within 42 days of curing.
From the performed SEM analysis, we observed significant surrounded hydrated products, confirming the improvement of binding performance between the ordinary Portland cement and the tailings cement matrix.
Additionally, the study also revealed that the tailings particles sizes, particularly the proportions of fine tailings particles (<20 µm), significantly affected the porosity of the paste backfill and the pore size distribution within it. The CWTB's overall porosity decreased as the solid concentration increased for a given total mass of cement and tailings for fine tailings.
Therefore, the choice of binder agent depends on the need for specific environmental control and the nature of the tailings selected.
The influence of solids content, binder dosages and water-cement ratio on UCS optimization of CWTBs provides good results on the strength development of the paste backfill samples. Moreover, the curing time significantly increases the UCS of CWTBs at 75 wt. % solids content.
SEM images confirmed that within 14, 28 and 42 days of curing CWTBs specimens, there were C-S-H gels and ettringite formations, which enhanced the gain strength of CWTBs samples.
Overall, the experiments conducted have raised two main constraints based on the impact of solids content and binder dosage at first, and environmental control specificity according to the curing time. Results to be obtained seem to bring resounding progress on paste backfill process, as far as the topic is concerned. Further studies are needed to confirm the mechanism resistance of the paste backfill in real field conditions. Author Contributions: A.E.B.T. conceptualized, analyzed the experimental data, initiated the paper, reviewed and editing the paper. S.Y. validated, supervised and acquired funding the paper. L.W. revised and proofread the paper, funded acquisition. All authors have read and agreed to the published version of the manuscript.