Interlayer-Confined Cu(II) Complex as an Efficient and Long-Lasting Catalyst for Oxidation of H 2 S on Montmorillonite

: Removal of highly toxic H 2 S for pollution control and operational safety is a pressing need. For this purpose, a montmorillonite intercalated with Cu(II)-phenanthroline complex [Cu[(Phen)(H 2 O) 2 ] 2+ (Mt-CuPhen) was prepared to capture gaseous H 2 S under mild conditions. This hybrid material was simple to obtain and demonstrated an outstanding ability to entrap H 2 S at room temperature, retaining high efficiency for a very long time (up to 36.8 g of S/100 g Mt-CuPhen after 3 months of exposure). Sorbent and H 2 S uptake were investigated by elemental analysis, X-ray powder diffraction measurements, diffuse reflectance (DR) UV–Vis and infrared spectroscopy, thermal analysis and evolved gas mass spectrometry, scanning electron microscopy equipped with energy-dispersive X-ray spectrometer, and X-ray absorption spectroscopy. The H 2 S capture was studied over time and a mechanism of action was proposed. The entrapping involves a catalytic mechanism in which [Cu[(Phen)(H 2 O) 2 ] 2+ acts as catalyst for H 2 S oxidation to S 0 by atmospheric oxygen. The low cost and the long-lasting performance for H 2 S removal render Mt-CuPhen an extremely appealing trap for H 2 S removal and a promising material for many technological applications.


Introduction
Expandable layered aluminosilicate minerals, due to properties such as surface acidity, particle size and shape, high surface area, ion exchange, hydration, swelling, plasticity, rheological behavior, and reactivity towards organic and inorganic compounds, are widely used for many industrial applications as sorbents, catalysts, ion-exchangers, additives [1,2]. Among the various layered aluminosilicates, montmorillonite (Mt,), which is a 2:1 dioctahedral smectite [1], received great attention because of its surface properties, swelling, and ion exchange features that can be further enhanced by exchanging natural inorganic cations in the interlayer space (mostly Ca 2+ and Na + ) with other organic or inorganic species [3][4][5]. Because of their unique structure, low cost, natural abundance, and environment friendliness, both natural and exchanged Mt were proposed as adsorbent materials for removing multiple contaminants from aquatic systems [6], and more recently, also to capture airborne pollutants such as CO2, SO2, NOx, H2S, and volatile organic compounds (VOCs) [7][8][9][10][11][12].
Hydrogen sulfide, a common waste product of industrial processes, is a highly toxic, colorless, and smelly pollutant that occurs in several hydrocarbon sources such as natural gas, biogas, and crude oil. H2S is harmful to animals and human beings, and is also dangerous to industrial facilities in the gaseous form or in solution. Combustion of fuels containing H2S releases toxic sulfur oxides into the atmosphere that yield acid rain by reaction with water molecules. Therefore, removal of industrially derived H2S for pollution control and operational safety is a pressing need. To remove H2S effectively, several approaches were developed, such as adsorption, scrubbing, hydrodesulfurization, biological treatment, and catalytic oxidation [13].
Recently, porous materials (e.g., activated carbon, porous metal oxides, mesoporous silica, metal-organic and zeolite-like frameworks) with high sulfur removal capacity and selectivity, thermal durability, and good reproducibility attracted great attention for use in H2S adsorptive removal processes, particularly at low temperature, as they grant cost-effective approaches with deep H2S removal [13]. Usually the surface of these porous materials is functionalized with organic or inorganic functional groups to enhance and/or modify physical and chemical surface properties and reactivity. Amine grafting, heteroatom (nitrogen) doping, alkaline impregnation, and metal oxide incorporation are the most widely applied approaches for the surface functionalization of these porous structures [13].
Layered aluminosilicate microporous structures, such as pillared clays doped with metallic cations (usually Fe 3+ , Zn 2+ , and Cu 2+ ) and/or clays intercalated with metal-organic functional groups were also tested for selective catalytic oxidation of H2S [13]. Recent studies dealing with the removal of sulfur gaseous compounds by means of different types of metal-organic functionalized Mt demonstrated that this mineral intercalated with Fe(III)-phenanthroline complex is one of the best performing materials [9,14]. The H2S trapping process involves a redox reaction between Fe 3+ and a first S 2− ion, followed by the binding of a second S 2− ion to the metal center. It occurs at room temperature, is reversible, and does not require pretreatment [14].
Based on these premises, these materials deserve further investigation to explore new possible applications and developments. In this work, we studied the adsorption mechanism of H2S by montmorillonite intercalated with a Cu(II)-phenanthroline complex (Cu(II)Phen). Cu oxides are commonly used to catalytically oxidize adsorbed H2S gas, thus suggesting that H2S trapping efficiency of Mt intercalated with cation-phenanthroline complexes can be improved by employing copper instead of iron.
The same chemicals and procedures described by the authors in a previous study were used [11]. Specifically, CuSO4·5H2O was dissolved at room temperature in a well-stirred phenanthroline (Phen) solution in order to obtain a 6 mM solution of Cu(II)Phen; Mt (50 mg) was dispersed in 10 mL of this solution, shaken for 1 h at 250 rpm at room temperature, and then separated from the liquid phase via centrifugation at 14,000 for 1 min. The final powder was washed several times with distilled water and then dried at 30 °C overnight. The resulting material, Mt-CuPhen, contains large amounts of Cu ions in the interlayer, 0.651 Cu 2+ moles/kg. An extensive characterization of Mt-CuPhen material was described in detail elsewhere [11].

Exposure of Mt-CuPhen to H2S Gas Stream
The reaction tests were carried out in a continuous flow reactor made with a glass box covered by layer of aluminum foil, hosting an inner and outer gas hose. One hundred mg of Mt-CuPhen were dispersed on the bottom of the glass box. A mixture of H2S/air (samples exposed in aerobic conditions) and H2S/Ar (samples exposed in anaerobic conditions) was fluxed into the box at a constant H2S partial pressure of 250 Pa, controlled by calibrated mass flow controllers (Alltech Digital Flow Check-HR) and gas mixing valves. H2S adsorption tests were completed at different times (up to 3 months). The S content of Mt-CuPhen samples exposed to H2S (Mt-CuPhen-exp H2S) was determined by elemental analysis; measurements were repeated three times to obtain mean values with a statistical significance.

Characterization of Mt-CuPhen Exposed to H2S Gas Stream
The elemental analyses (C, N, and S) were performed using a Carlo Erba 1106 Elemental Analyzer. UV-Vis and diffuse-reflectance (DR) UV-Vis analyses were carried out by the Jasco V-570 Instrument equipped with an integrating sphere attachment (JASCO model ISN-470) to analyze the powder samples. BaSO4 was used as reference. X-ray powder diffraction (XRPD) measurements were performed by an analytical X'Pert PRO powder diffractometer equipped with an X'Celerator detector on standard glass slides in the 2°-50° 2θ range. Analytical conditions were: incident beam, Cu Kα radiation (λ = 1.54184 Å) at 40 kV and 40 mA (nickel filtered); Soller slits, 0.04 rad; antiscatter mask, 20 mm; antiscatter slit, 1/4°; divergence slit, 1/4°. Diffracted beam: antiscatter mask, 5.0 mm; Soller slits, 0.04 rad; integration time, 30 s in continuous scanning (PSD length of 2.12° 2θ corresponding to a step size of 0.0170° 2θ per s). Quartz was used as calibration standard.
The morphology and elemental composition of samples were characterized by scanning electron microscopy (SEM) by using an FEI Quanta 200 ESEM and an energy-dispersive X-ray spectrometer attached to the Quanta 200 ESEM (X-EDS Oxford INCA-350 system EDX).
A Seiko SSC 5200 thermal analyzer equipped with a quadrupole mass spectrometer (ESS, GeneSysQuadstar 422) was employed in the thermal studies. The powdered samples (10 mg) were heated from 25 to 1050 °C in helium flowing. Gas analyses were carried out in multiple ion detection mode (MID) and different m/z ratios were considered (17 and 18 for H2O; 28 and 44 for CO2; 30 for NO and NO2; 33 and 34 for H2S; 46 for NO2; 48, 64, and 66 for SO2). Experimental conditions were: heating rate = 10°/min; heating range = 25-1050 °C; data measurement = every 0.5 s; purging gas = ultrapure helium, flow rate = 100 µL/min. Before starting measurements, samples were equilibrated for 15 min using a 100 μL/min flow of ultrapure helium [14].
X-ray absorption spectroscopy (XAS) spectra were measured at the Spanish CRG beamline BM25-Spline at the European Synchrotron Radiation Facility (ESRF), Grenoble (France). XAS spectra were collected at the Cu K-edge (8979 eV) in both transmission and fluorescence mode at room temperature on pellets prepared by mixing uniformly the powered samples and cellulose. The fluorescence signal was collected using a nitrogen cooled 13-element Si (Li) solid state detector (e2v Scientific Instruments) located at 90° with respect to the incoming X-ray beam, while the transmitted photons were measured with an ionization chamber gas-filled with 50% N2 and 50% Ar. The incident beam intensity was also monitored by using an ionization chamber with 100% N2. For all spectra, a metallic Cu foil was employed to provide an energy calibration for the monochromator. As reference materials, pure Cu2O, CuO, CuS, CuSO4x5H2O, and Cu3(CO3)2(OH)2 compounds were used. The XAS spectra were recorded over a wide energy range across the Cu K-absorption edge with 0.25 eV energy step in the X-ray absorption near-edge structure (XANES) region and 0.04 Å −1 in the extended X-ray absorption fine structure (EXAFS) region up to 15 Å −1 . The X-ray absorption data were analyzed with a standard procedure using ATHENA software [16].

H2S Capture by Mt-CuPhen.
The S amounts measured by elemental analysis on Mt-CuPhen exposed to H2S vapors for different times are plotted in Figure 1. Mt-CuPhen captures a great amount of sulfur (up to 1.15 S moles/100 g Mt-CuPhen after 3 months of exposure) and its immobilization ability lasts for a very long time. The H2S capture proceeds without reaching completion, following a pathway that differs from that reported for Mt intercalated with the µ-oxo binuclear Fe(III)-phenanthroline 1:1 complex ([(H2O)3PhenFe-O-FePhen(H2O)3] 4+ , FePhen hereafter) [14]. For the latter, the H2S removal process occurs into two distinct steps: the former, lasting for about 20 h, is fast in the first 4 hours and then slows down, while the latter is completed within about 110 h. Overall, the process lasts 110 h; eventually the exhaust material must be regenerated by a thermal treatment at 295 °C for reuse.
The larger maximum amount of S captured by Mt-CuPhen compared to Mt-FePhen (up to 1.15 moles (36.8 g) of S/100g vs. 0.12 moles (3.8 g) of S/100g, respectively) and the longer uptime of the material indicate a radical change in the entrapping mechanism [14].
When Mt-CuPhen is exposed to H2S, its spectrum changes dramatically (Figure 2). A well-defined shoulder at about λ = 520 nm appears, while the absorption band at λ = 780 nm drops down. Both bands, however, coexist in the spectra recorded at different exposure times (from 10 min to three months), although a change in the absorbance ratio occurs. The new band at λ = 520 nm can be confidently attributed to Cu(I)Phen complexes, suggesting that the capture of H2S involves a Cu(II) reduction step. The spectra are very similar to those for Cu(II)Phen intercalated in Mt reduced with ascorbic acid and then exposed to heptanethiol vapors. In addition, for this case, an absorption band related to Cu(I)Phen-thiolate complex appears at about 530 nm [17,18]. Likewise, the profiles of the DR UV-Vis spectra previously obtained for Mt-FePhen exposed to H2S gaseous streams show an intensity decrease for the band at λ = 374 nm, attributed O 2− (bridge) → Fe(III) charge-transfer transition, typical of the µ-oxo ferric complexes, together with a concomitant increase in the band at λ = 520 nm, due to a d → π* metal-to-ligand charge transfer of [Fe(II)Phen] 2+ type complex, suggesting a Fe(III) to Fe(II) reduction [14]. Diffuse-reflectance (DR) UV-Vis spectra of Mt-CuPhen and of Mt-CuPhen exposed to H2S for different times. Curves were shifted on the y-axis for sake of clarity. Lines at λ = 520 nm and λ = 780 nm mark features discussed in the text.

Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectrometry (EDX)
SEM images (Figure 3) show the formation on the Mt surface of crystals with a size of about 5-10 µm (Figure 3a) and about 10-50 µm (Figure 3b) for Mt-CuPhen exposed to H2S for 3 days and 3 months, respectively. The polyhedral shape of the crystals becomes well defined and the size increases with increasing the exposure time. As shown by EDX, these crystals are mainly constituted by elemental S; minor signals related to Al and Si are probably due to the Mt substrate. Therefore, the final product of the interaction of Mt-CuPhen with H2S is well-crystallized sulfur. Figure 3. Scanning electron microscopy (SEM) images of Mt-CuPhen exposed to H2S for different times: (a) 3 days; (b) 3 months. The energy dispersive X-ray spectrometry (EDX) spectra reported refer to crystals indicated by arrows.

X-ray Diffraction (XRPD)
XRPD analysis was carried out on Mt-CuPhen samples before and after a three-month exposure to H2S in order to better recognize the sulfur phase.
The XRPD patterns (3 ≤ 2θ(°) ≤ 40) of Mt-CuPhen before and after exposure are shown in Figure  4. As discussed previously [11,15], the diffraction peaks of Mt-CuPhen with respect to Mt show: (i) a shift towards higher d values of d001 reflection (d001 Mt = 1.51 nm; d001 Mt-CuPhen = 1.71 nm), suggesting that CuPhen species coordinated by sulfate groups, which are about 0.71 nm thick, that occupy the interlayer positions; (ii) higher order XRD reflections, which are approximate multiples of the 2θ angle of the 001 reflection [19], suggesting the presence of more ordered domains.
The exposure of Mt-CuPhen to H2S does not affect the Mt-CuPhen d001-spacing. The d001 peak position is always at 1.71 nm. However, some additional peaks (e.g., at 0.6040, 0.3816, 0.3429, 0.3337 nm) were recognized, which can all be related to rosickyite (i.e., monoclinic sulfur), as evaluated by means of the PANalytical X'Pert HighScore software and the ICDD PDF-2 database. These results agree with the outcome of the SEM/EDX analysis, namely that the final reaction product of the interaction between Mt-CuPhen and H2S gas is crystalline sulfur.

FTIR Spectra
To expand the depth of our analysis of the mechanism of hydrogen sulfide immobilization, FTIR spectra for Mt-CuPhen before and after exposure to H2S were recorded ( Figure 5). The two samples showed the typical spectrum of montmorillonite-based material, namely an absorption band centered at 3626 cm −1 for Mt-CuPhen and 3620 cm −1 for Mt-CuPhen-exp H2S-3m due to the stretching vibration of octahedral OH, a broad band centered at about 3435 cm −1 , due to νOH modes of H2O, a band at 1630 cm −1 (δH2O for water bending vibration), at 1086 and 1042 cm −1 (Si(Al)-O bonds stretching), and between 700 and 950 cm −1 (structural OH-bending mode) [15]. Additional bands typical of Cu(II)Phen between 3000 and 3200 cm −1 (aromatic ring C-H stretching), at 1588, 1522, 1495, and 1429 cm −1 (C-C and C-N stretching of the Phen ring) and at 722 cm −1 (C-H out-of-plane bending of heterocyclic ring) are also evident [14].
The comparison of Mt-CuPhen spectra before and after exposure to H2S shows very few differences. In particular, no S-H stretching vibration characteristic of H2S is observed between 2500 and 2625 cm −1 in the Mt-CuPhen-exp H2S-3m spectrum, indicating the absence of any physisorbed H2S ( Figure 5) [20]. Of note, elemental sulfur cannot be detected with FTIR because of the absence of a distinct signature. In addition, the bands at around 1415 and 1380 cm −1 , indicative of sulfate ions, are not evidenced in the Mt-CuPhen-exp H2S-3m spectrum [14,21,22].
In both samples, changes in the bands related to ν(OH) and δH2O of water molecules, clearly visible in Mt, are observed. In particular, an intensity decrease occurs in the sample not exposed to H2S.

Thermal Analysis of Mt-CuPhen before and after Exposure to H2S
Thermogravimetric analyses (TGA), their first derivative signals (DTGA), and mass spectrometry curves of gases evolved during heating (m/z = 18 and m/z = 64) of Mt-CuPhen and Mt-CuPhen-exp H2S-25d are plotted in Figures 6 and 7.
Attention was focused on the reactions occurring in the temperature range 25 °C ≤ T ≤ 400 °C as most of the effects related to this study occurs in this range. At higher temperature, thermal tracings of Mt-CuPhen-exp H2S-25d are similar to those obtained for Mt-CuPhen discussed previously [11,18].
TGA curves of Mt-CuPhen, before and after H2S exposure, show a mass loss (Δm%) associated with a broad peak in DTGA tracing at about 80 °C (Δm% Mt-CuPhen = 3.32; Δm% Mt-CuPhen-exp H2S-25d = 3.63; Figure 6). For both samples the mass loss related to this effect, linked to the loss of outer-sphere H2O (m/z = 18, Figure 7), is lower compared to Mt (Δm% in pristine Mt = 10.6) [15]. The thermal effect at about 150 °C, that in untreated Mt is associated to the loss of inner-sphere H2O, completely disappears. The amount of water in the sample exposed to H2S is slightly larger than that prior to exposure (Figure 7), in agreement with the FTIR data.

a b
A second large mass loss (Δm% =13.10) is observed for Mt-CuPhen-exp H2S-25d sample between 160 and 360 °C and is associated to a strong effect centered at 235° in DTG tracing. This mass loss can be confidently attributed to the oxidation of elemental sulfur also observed by SEM/EDX and XRPD analyses. Accordingly, an associated release of SO2 was detected by mass analysis (Figure 7, m/z = 64). Pure H2S is not significantly adsorbed by Mt-CuPhen, since its release should be observed at temperatures lower than 120 °C [20,21].

XAS Analysis of Mt-CuPhen before and after H2S Exposure
The XANES study at the Cu K-edge of Mt-CuPhen before and after H2S exposure under different conditions was carried out to gain information on the Cu oxidation state, coordination symmetry, and electronic structure. XANES spectra of Mt-CuPhen and reference compounds are reported in Figure S1 and strictly resemble those already reported and discussed elsewhere [18].
In Figure S1a, Cu reference compounds with formal 2+ oxidation state display different position, intensity, and shape of the absorption edge, which can be attributed to the different nature of the ligand and to Cu local geometry [23][24][25][26][27]. Changes also occur for the Cu(II)Phen crystals and Mt-CuPhen material ( Figure S1b). The reference compounds CuO and CuSO4·5H2O, both containing Cu(II), show differences in the XANES region that can be attributed to the different Cu coordination (i.e., square planar geometry for CuO and octahedral geometry for CuSO4·5H2O) [26]. The XANES profile of Cu(II)Phen crystals ( Figure S1b) is closer to that of CuSO4·5H2O; however, it shows a pre-edge of low intensity, an absorption edge moved to higher energy with respect to CuSO4·5H2O, and a whiteline of high intensity. These features indicate that a certain distortion of the octahedral coordination of Cu(II) center occurs [11,18]. The XANES signal of Mt-CuPhen is still similar to that for Cu(II)Phen crystals, but show clear intermediate characteristics between CuO and Cu(II)Phen, probably due to an even more pronounced distortion of the octahedral coordination of Cu(II) or even a decrease in its coordination number (possibly from six to five, thus assuming a square pyramidal geometry) [26]. Figure S2 shows the evolution of Mt-CuPhen XANES spectrum at different H2S exposure times. After 12 h exposure to H2S vapors (Mt-CuPhen-exp H2S-12h), a shift of the absorption edge towards lower energies occurs, consistent with a reduction of Cu(II) to Cu(I) and a decrease of both peak intensity at the absorption edge (around 8982 eV) and of the whiteline (around 8997 eV). These features are also evident in XANES spectrum obtained on the sample exposed for 5 days to H2S (Mt-CuPhen-exp H2S-5d), afterwards the modifications of the XANES signal are slight and within the measurement resolution. The XANES signals of Mt-CuPhen samples exposed to H2S under anaerobic conditions (samples Mt-CuPhen-exp H2S ac-12h and Mt-CuPhen-exp H2S ac-1m) are closer to those of the Cu2O reference, displaying a larger shift of the absorption edge towards lower energies and a decrease in the intensity of peaks around 8982 and 8997 eV with respect to what observed in aerobic conditions, thus suggesting a large reduction of the average Cu oxidation state ( Figure S2b).
Mt-CuPhen exposed to H2S for 1 month in anaerobic conditions and then exposed to air for 2 weeks (sample Mt-CuPhen-exp H2S ac-1m-air) shows XANES features close to that of Mt-CuPhen exposed to H2S for 12 h in both anaerobic and nonanaerobic conditions. The position of absorption edge falls at higher energy compared to Mt-CuPhen-exp H2S ac-1m indicating the reoxidation of copper ion after the exposure to air.
As observed for the K edge of transition metals, the absorption edge position of XANES spectra shifts with the average copper oxidation state. Thus, in order to evaluate semiquantitatively the coexistence of Cu(II) and Cu(I) atoms when Mt-CuPhen is exposed to H2S gas, the correlation known as Kunzl's law was applied [28,29]. The linear relationship: correlating the position of the absorption edge (Ee) with the mean oxidation state (OS) was evaluated from the peak position of reference compounds. The results confirm that the Cu(II)Phen crystals and Mt-CuPhen contain Cu(II) ion (calculated oxidation state: 2.3 ± 0.3, Figure S3a). After 12 h exposure to H2S gas, the average oxidation state of Cu in Mt-CuPhen decreases to 1.3 ± 0.3, indicating partial Cu(II) reduction to Cu(I). For larger exposure times, the average oxidation state of Cu increases (1.5 ± 0.3 for 5 days and 2.0 ± 0.3 for exposure times higher than 1 month). The average oxidation state of samples exposed to H2S under anaerobic conditions was also calculated ( Figure S3b). The sample exposed for 12 h shows an average oxidation state (1.3 ± 0.3) similar to that of the material exposed under aerobic conditions (1.3 ± 0.3), but upon increasing exposure times Cu is found almost entirely in the reduced state (after 1 month the average oxidation state is 1.1 ± 0.3 and 2.0 ± 0.3 under anaerobic and aerobic conditions, respectively). The reversibility of the reduction process is confirmed by the sharp change of the oxidation state of the sample exposed anaerobically to H2S by simple eventual exposure to air (after two weeks the average oxidation state varies from 1.1 to 1.8).

Catalytic Mechanism Responsible for Oxidation of H2S to S 0
H2S capture by Mt-CuPhen reasonably occurs with a multistep process. Spectroscopic data (DR UV-Vis and XANES spectra) indicate that Cu(II)Phen intercalated in Mt undergoes reduction to Cu(I)Phen when exposed to H2S. This reaction is coupled to the oxidation of S 2-to S 0 , as shown by the presence of sulfur crystals (XRPD and SEM measurements). S 0 is produced in a molar amount much larger than that of Cu(II) present in Mt-CuPhen (after 3 months S/Cu molar ratio = 17.7). Moreover, Cu(II) and Cu(I) always coexist during the formation of S° even at very long exposure times. This indicates a catalytic process for oxidation of sulfide involving atmospheric oxygen. Based on the above results, a tentative reaction mechanism can be proposed: In such a way, [Cu(II)Phen] 2+ acts as a catalyst and makes the reaction proceed cyclically leading to the formation of elemental sulfur from H2S, the overall reaction being: 2 H2S + O2 → 2 S 0 + 2 H2O This mechanism accounts for the remarkable difference observed in the immobilization efficiency of Mt-CuPhen with respect to Mt-FePhen. In fact, the oxidation of H2S by O2 catalyzed by Mt-CuPhen allows immobilization of larger amounts of sulfur than those obtained with Mt-FePhen, whose entrapping process is based on the direct oxidation of H2S by Fe(III)Phen without the involvement of any catalytic steps and thus depending only on Fe(III) amount intercalated in Mt.
Mt-CuPhen works for a long time, but at the end of the process it cannot be easily regenerated since the resulting elemental sulfur is largely dispersed and settled on the material.

Conclusions
Our study reveals the high efficiency in H2S trapping of montmorillonite intercalated with Cu-phenanthroline complex. The replacement of FePhen with CuPhen allows for achieving the capture of H2S through a catalytic mechanism that substantially changes both the quantity of this gas that can be immobilized and the duration of the uptake process. Mt-CuPhen offers a promising performance towards gaseous H2S removal because its immobilization ability is very high, displays a long-time duration (36.8 g of S/100 g Mt-CuPhen after 3 months of exposure) and works at low (room) temperature conditions. Thus, this material provides a long-term stability and complies with the request to lower the operational costs in industrial applications.
Although the formation of sulfur crystals as final product compromises the thermal regeneration of Mt-CuPhen, the low cost of the starting material and the long-lasting adsorption performances (more than 3 months), make the process cost effective and promising for technological applications. Therefore, it is a sound alternative to montmorillonite treated with Fe(III)-phenanthroline complex. In fact, the latter, while being renewable by thermal treatment, is less effective in H2S trapping and needs to be replaced or renewed much more often.

Mt-CuPhen-exp H2S
ac-1m Mt-CuPhen exposed to H2S vapor for 1 month in anaerobic conditions Mt-CuPhen-exp H2S ac-1m-air Mt-CuPhen exposed to H2S vapor for 1 month in anaerobic conditions and then exposed to air for 2 weeks Mt-FePhen solid hybrid material obtained by Mt treated with a µ-oxo 1:1 Fe(III)-phenanthroline complex