Uranium Mineralogical and Chemical Features of the Na-Metasomatic Type Uranium Deposit in the Longshoushan Metallogenic Belt, Northwestern China

: The Longshoushan Metallogenic Belt (northwestern China) is known for its word-class Jinchuan Ni-Cu sulfide (Pt) deposit and is also an important uranium metallogenic belt. The Jiling uranium deposit in this belt is a typical Na-metasomatic uranium deposit, which rarely occurs in China. pitchblende was formed at a low temperature, during ore stage II. According to the petrographic observations and their chemical compositions, coffinite A and B resulted from the alterations of uraninite and pitchblende, respectively.

The Paleoproterozoic Longshoushan Group in this area represents the oldest strata, a highly deformed terrane that suffered from amphibolite-facies metamorphism. The Longshoushan Group is overlain unconformably by the Mesoproterozoic Dunzigou Group, and then by the Neoproterozoic Hanmushan Group ( Figure 1C) [10,38]. Only a few Late Paleozoic strata unconformably overlay the Hanmushan Group. Mesozoic and Cenozoic strata are rarely present in this area. The magmatic activity was intense in this metallogenetic belt with intrusion ages ranging from Paleoproterozoic to Caledonian [33,39,40].  [41]. (C) A regional geological map of Longshoushan Metallogenic Belt (LMB), showing the locations of the two sodium metasomatic type deposits (the Jiling and Xinshuijing uranium deposits) and pegmatite uranium deposit (Hongshiquan uranium deposit) (modified after [42]).
The Jiling uranium deposit occurs in the southeastern part of the Jiling intrusive complex, and the ore bodies are typically associated with Na-metasomatic alteration. The NW-trending Malugou Fault zones (F 101 and F 102 ), the main ore-controlling structure, developed to the north of the Paleoproterozoic Longshoushan Group, along nearly EW-trending structures that are the main structures controlling the ore bodies [14,39]. NE-trending and nearly SN-trending post mineralization faults cut both the NW-trending and nearly EW-trending structures (Figure 2A). F 101 and F 102 are a pair of parallel structures, with the same occurrence as 220 • -230 • NW trend and 60 • -70 • dip angle. The EW-trending secondary structures and some brittle deformation zones are favorable to uranium mineralization. The F 105 developed to the south of the Paleoproterozoic Longshoushan Group (Figure 2A), has a 30 • -35 • NW trend and 70 • -75 • dip angle. The F 105 is a right strike-slip fault that formed after the mineralization, crosscutting the F 101 and F 102 faults and displacing the extension trend of the ore bodies to the northwest ( Figure 2B) [14].  [39]). (B) A cross-section of the Jiling uranium deposit (modified after [39]).
In the Jiling uranium deposit, the common type of alteration is represented by albitization developed at the expense of Jiling granites. Na metasomatic zones are generally massive or brecciated rocks strongly controlled by faults. The primary textures of granites are generally preserved but may also be modified during later alterations. The alteration characteristics of the Jiling uranium deposit have been already described [10,14,44]. In this study, we identified three zones (I, II, III) defined by their mineralogical assemblage as developed in Jiling granite ( Figure 3). Zone I corresponds to the least altered host granites, part of biotite, feldspars, magnetite, and local allanite were replaced by chlorite and ilmenite. These minerals probably formed later compared to quartz dissolution and albitization, which have to occur at high temperatures according to the crystallization of Th-REE-rich uraninite as discussed thereafter, with a limited new formation of quartz. Zone II corresponds to the Na-metasomatic zone, in which quartz is extensively dissolved and the feldspars are replaced by albite leading to the formation of an albitic episyenite. Zone III corresponds to the major uranium mineralized zone, where uraninite crystals are paragenetically associated to magnetite, with a small amount of thorite crystals, in ore stage I at high temperature. Pitchblende crystals are paragenetically associated to pyrite, chlorite, calcite, and galena in ore stage II at lower temperatures. Coffinite has been identified in this zone, and it occurs as disseminations, veinlets, or crystal aggregates frequently as replacements of uraninite and pitchblende during the post ore stage. The ore bodies are concealed. They have lenticular to irregular-shapes but are almost parallel to the Malugou Fault zones (F 101 and F 102 ), and they occur in highly fractured and brecciated zones.

Analytical Methods
All samples were collected from exploration drill holes performed in the Jiling uranium deposit by the No. 203 Research Institute of Nuclear Industry. The mineralogical study was conducted at the State Key Laboratory of Nuclear Resources and Environment of East China University of Technology (China) using an optical microscope (transmitted and reflected light), a Nova Nano-SEM 450 scanning electron microscope (SEM), and a JEOL JXA 8100 electron microprobe analyzer (EMPA) (Tokyo, Japan). More detailed mappings were obtained using a Nova Nano-SEM 450 scanning electron microscope, backscattered electron (BSE) images were used, to select the targets for EMPA according to variations of grey intensity of uranium minerals [45]. A JEOL JXA 8100 electron microprobe analyzer (EMPA) was used for quantitative analyses.
Major, trace and rare earth elements were obtained by the EMPA and expressed in weight percent oxides. The analytical conditions were 15 KV accelerating voltage, and a 2.0 × 10 −8 A beam current with a 2 µm beam diameter for the analysis of uranium minerals. EMPA U-Th-Pb chemical dating of uraninite was initially proposed by Holmes [46], and has been widely used by various workers over the last decades [18,24,25,47]. This method is based on the assumption that non-radiogenic Pb has not been incorporated in the structure of U-oxides during crystallization, and no Pb loss or reintroduction has occurred after the original crystallization [45].
The equation is solved using an iteration procedure as follows: The contents of k 0 , k 1 , and k 2 are 0.848485, 0.816367, and 0.0059475, respectively.

Petrography and Mineral Assemblage of Uranium Mineralization
Three kinds of uranium minerals have been found in the Jiling uranium deposit, including uraninite, pitchblende, and coffinite. These three uranium minerals have different mineralogical and paragenetic characteristics.

Uraninite
Uraninite usually occurs as single-cubic crystals, which are partly replaced by pitchblende or coffinite ( Figure 4A-D). Based on the uraninite petrographical features and composition variation, most of the uraninite grains underwent different types of alterations. Except for the best preserved uraninite (BP uraninite) crystals, which show insignificant alteration, the altered uraninite grains are divided into two types (altered uraninite A and B). The BP uraninite crystals are rare and exhibit typically euhedral cubic crystals, 6 µm × 10 µm in size ( Figure 4A). Most of these uraninite grains occur as inclusions in magnetite; itself included in albite crystals. These uraninite crystals are preserved from alteration likely due to their smaller size and inclusion in magnetite.
Altered uraninite A grains usually occur as euhedral to subhedral single crystals. They have a larger size (30 to 70 µm large) with a diverse range of morphology, including irregular, cubic, and rhombus. They are included in albite and partly replaced by pitchblende ( Figure 4B,C). They are heterogeneous and present some cavities ( Figure 4B). Apatite, pyrite, and barite can also be observed in the vicinity of altered uraninite A ( Figure 4B,C).
Altered uraninite B grains usually occur either as single-crystals in the core or at the edge of coffinite aggregates ( Figure 4D). Altered uraninite B probably represents relics of the primary uraninite crystals during a later alteration stage. The galena can also be found as small disseminated crystals nearby altered uraninite B.

Pitchblende
Pitchblende usually occurs along fractures or as inter-mineral veinlet infilling (tens of microns wide) and as disseminated grains (reaching up to 0.15 mm large), with different mineral associations.
Pitchblende often displays micro-fractures along which the mineral was subjected to different degrees of alteration. Two types of altered pitchblende were distinguished according to the different intensity of gray in BSE images and the different chemical composition described thereafter. Altered pitchblende A showed a brighter gray color in BSE images and with lower SiO 2 content than B. Although these two types of altered pitchblende can be divided, they have similar occurrence features.

Coffinite
According to the morphological features, two different types of coffinite can be found in the Jiling deposit. Coffinite A occurs as independent crystals irregularly disseminated in the host rocks ( Figure 6A) or crystal aggregates filling fractures ( Figure 6B). Most of the coffinite A crystals exhibit euhedral or subhedral shapes with a size varying from a few microns to tens of micrometers. Coffinite B occurs as colloidal cement around some gangue minerals or infilling in microfractures of albite ( Figure 6C,D). As observed in the BSE images, coffinite A replaced uraninite C during a late alteration episode. Some residual domains of uraninite B occur in the core or at the rim of coffinite A aggregates ( Figure 4D). Coffinite A usually coexists with galena, hematite, chlorite, and uraninite B. Coffinite B was generally deposited around the zircon, pyrite, apatite, and galena. Some residual pitchblende B was also identified within the coffinite B. Pyrite and zircon crystals are cemented by pitchblende, with coffinite B replacing pitchblende during a late alteration stage, and a new formation of galena. Traces of pitchblende B were observed on the surface of coffinite B ( Figure 6C).

Results
The major and minor element chemical compositions of uraninite, pitchblende, and coffinite in the Jiling uranium deposit are presented in Table 1 and Supplementary Materials A.

Composition of Uraninite
The chemical composition of the BP uraninite crystals in the Jiling uranium deposit was relatively constant. The analytical totals (n = 10) ranged from 97.08 wt.% to 99.69 wt.% indicating significant oxidation and/or hydration of the mineral. The UO 2 contents ranged from 72.07 wt.% to 78.08 wt.% with a median value of 76.82 wt.%. The PbO contents were relatively homogeneous with values ranging from 4.58 wt.% to 4.96 wt.% with a median value of 4.77 wt.%. The ThO 2 , Y 2 O 3 , and total REE 2 O 3 contents were elevated and more variable: 6.51 wt.% to 12.59 wt.% ThO 2 , with a median value of 9.81 wt.%; 0.95 wt.% to 2.51 wt.% Y 2 O 3 with a median value of 1.71 wt.%; and 3.01 wt.% to 6.32 wt.% total REE 2 O 3 with a median value of 3.73 wt.% ( Table 1). The contents of FeO, SiO 2 , and CaO in uraninite A were low, and the Al 2 O 3 content was below the detection limit.
In comparison to the BP uraninite crystals, altered uraninite A (n = 18) and B (n = 19) had lower ThO 2 , PbO, and total REE 2 O 3 contents, and higher SiO 2 and CaO contents. The Al 2 O 3 contents in altered uraninite A and B were slightly higher than the detection limit. In comparison to the altered uraninite A, altered uraninite B had higher SiO 2 , ThO 2 , and total REE 2 O 3 , and lower CaO, UO 2 , PbO, and Y 2 O 3 contents (Table 1).

Composition of Pitchblende
As described above, two types of altered pitchblende were distinguished in the Jiling uranium deposit. Only three analysis spots of fresh pitchblende were obtained during the EMP analyses.
The These variations reflect the strong metamictisation of this mineral associated with the relative migration of these elements leading to non-stoechimetric compositions. In comparison to coffinite A, coffinite B had slightly higher UO 2 contents and obvious lower ThO 2 contents, but their CaO and total REE 2 O 3 contents remained relatively constant.

Geochemical Evolution of Uranium Mineralization
Several minor and trace elements can be incorporated into uranium oxide lattice at the time of its crystallization, like Th, REEs, and Ca [50]. Furthermore, uraninite is extremely sensitive to alteration and can exchange elements or recrystallize easily during later hydrothermal to supergene alteration events [23,45,51]. This may lead to more of less intense modifications of the composition of the primary uranium oxides. Heterogeneity in the composition of uranium oxides caused by later hydrothermal fluid alteration is common in natural environments [23,45]. In a deposit that was subjected to multiple events of hydrothermal activity and supergene alterations, the characteristics of the hydrothermal or meteoric fluids can be deduced from the chemical variations of uraninite composition (e.g., [24]).
Compared to the BP uraninite crystals, the altered uraninite A and B typically exhibited low contents of ΣThO 2 + UO 2 + REE 2 O 3 + Y 2 O 3 + PbO and high contents of ΣCaO + SiO 2 ( Figure 7A). Low contents of ΣCaO + SiO 2 in BP uraninite suggested that these elements were not significantly incorporated into the crystal structure of uraninite during its crystallization and that the crystals have not been significantly altered. There was a negative correlation between these three types of uraninite groups in the plot of ΣThO 2 + REE 2 O 3 + Y 2 O 3 vs. UO 2 ( Figure 7B). These correlations support that these elements lost the form of the altered uraninite A and B during the hydrothermal alteration and the altered uraninite A underwent more intense alteration than the altered uraninite B. The SiO 2 compositional gap and different contents of CaO between the altered uraninite A and B ( Figure 7C,D) indicated that the primary uraninite may have experienced at least two events of hydrothermal fluid alteration. One was more enriched in silica (altered uraninite B) and one was more enriched in calcium (altered uraninite A).
The three fresh pitchblende analyses also had low SiO 2 and CaO contents, and relatively high and constant PbO contents. Based on the textures and compositions, most of the pitchblende in the Jiling uranium deposit also underwent post mineralization hydrothermal alteration with two types. Compared to fresh pitchblende, altered pitchblende A and B had slightly lower contents of ΣThO 2 + UO 2 + REE 2 O 3 + Y 2 O 3 + PbO and clearly higher contents of ΣCaO + SiO 2 ( Figure 8A). Altered pitchblende B had lower ΣThO 2 + UO 2 + REE 2 O 3 + Y 2 O 3 + PbO, UO 2 and higher ΣCaO + SiO 2 , ΣThO 2 +REE 2 O 3 +Y 2 O 3 contents than altered pitchblende A ( Figure 8A,B), suggesting that altered pitchblende B has underwent more intense alteration than altered pitchblende A. The difference of SiO 2 contents and the almost same range of CaO contents between altered pitchblende A and B ( Figure 8C,D), suggested that pitchblende in the Jiling uranium deposit also experienced at least two separate events of hydrothermal fluid alteration. The hydrothermal fluid that modified altered pitchblende B had a higher SiO 2 content than the fluid that modified altered pitchblende A, but about the same CaO content. In a closed system, the radioactive decay of U and Th leads to the production of radiogenic Pb, and, thus, should lead to a negative correlation between the PbO and UO 2 + ThO 2 contents in uraninite. However, Pb and U should have a positive correlation in the uraninite formed at the same time, as shown in the study of Kempe [45]. In this study, PbO and UO 2 + ThO 2 also showed a positive correlation in the BP uraninite crystals (Figure 9a). The low contents of ΣSiO 2 + CaO in both BP uraninite and fresh pitchblende, and the homogeneity of the chemical ages suggested that these minerals do not seem to have suffered significant Pb loss. The altered uraninite and pitchblende had much lower PbO contents than the best-preserved uraninite and fresh pitchblende, illustrating the Pb loss during the post mineralization alteration. Several mechanisms have been postulated to illustrate the Pb loss in uraninite/pitchblende. The major ideas that have been discussed include (1) U and Pb-loss by coffinitization; (2) U and Pb-loss by leaching; and (3) Pb-loss by diffusion, or recrystallization [52]. The pristine uraninite and pitchblende suffered two episodes of alteration, one with a Ca-rich fluid and one with a Si-rich fluid leading to the two types of altered uraninite and pitchblende. Coffinitization of these minerals resulted from further interaction with Si-rich fluids (e.g., [52]).

U-Th-Pb Chemical Dating of Uraninite and Pitchblende
Estimation of the crystallization age of uraninite from chemical dating are given in Table 2, with a 1σ uncertainty. As described above, the BP uraninite crystals showed extremely low Si and Ca contents, high and relatively homogeneous Pb contents, illustrating that BP uraninite crystal did not suffer significant alteration since its crystallization. The U-Th-Pb chemical ages obtained from these uraninite ranged from 426 Ma to 445 Ma (Table 2), with a weighted mean age of 435.9 ± 3.3 Ma (n = 10, MSWD = 1.1) (Figure 9b).
Three analyses from the freshest pitchblende displayed low SiO 2 and CaO contents, indicating that these three analyses may have retained the original chemistry of the primary pitchblende. The corresponding U-Th-Pb chemical ages were: 358 Ma, 357 Ma, and 368 Ma, with an average age of 361 Ma.

Origin of Uranium Mineralization
The ionic radius of Th, Y, and REE were close to that of U 4+ in eightfold coordination [53]. These elements can be easily incorporated into the structure of uraninite and pitchblende during their deposition. The parameters controlling the incorporation of these elements into the uraninite and pitchblende lattice were essentially the temperature of crystallization and the availability of these elements in the fluids or the silicate melt. In general, low-temperature hydrothermal uraninite or pitchblende was essentially free of Th, whereas those formed at high temperatures were characterized by variable Th + REE + Y concentrations [15,19,24,25,54]. The BP uraninite crystals showed high REEs, Y 2 O 3 , and ThO 2 contents. This indicated crystallization at high temperatures, such as during magmatic, magmatic-hydrothermal, and metamorphic processes [19,24,45]. Later deposited pitchblende had lower REEs, Y 2 O 3 , and ThO 2 contents indicating a deposition at a lower temperature than uraninite in the Jiling uranium deposit [19,25].
The REE patterns are an efficient tool for constraining geological models and can reflect the condition of deposit genesis [15,17,55]. The size of the uranium mineral grains of the Jiling uranium deposit were too small to be analyzed by LA-ICP-MS, so REE analyses by EMPA were tentatively used to define the general shape of the REE patterns. The irregularities of uranium mineral REE patterns (chondrite normalized from Sun and McDonough [56]), presented as Supplementary Materials B, resulted from the low accuracy of EMPA analyses, for REE with the lowest abundance, which were below the detection limit. The BP uraninite globally exhibited high REE contents with weak fractionation between the LREE and HREE [15]. As the Eu content was too low to be detected, it was impossible to determine the Eu anomaly. The REE patterns of BP uraninite were similar to uraninite from magmatic uranium deposits, possibly with still higher REE concentrations [15].
Uraninite occurs mainly in high fractionated peraluminous leucogranite and related pegmatites, such as the granites host hydrothermal-vein-type uranium deposit in South China [57,58], high-Ca metaluminous granites, low-Ca peraluminous granites, peralkaline granites, and in weakly peraluminous anatectic pegmatoids resulting from a low degree of partial melting of metasedimentary rocks [59,60]. However, the fresh host-granitoids in the Jiling uranium deposit were metaluminous to peraluminous without magmatic uraninite [30]. The chemical ages of the BP uraninite varied from 426 Ma to 445 Ma as discussed above, which is similar to the age range of crystallization of the granitoid intrusions in the area around the Jiling uranium deposit (from 427 to 441 Ma, U-Pb isotopic system on zircons by LA-ICP-MS) [30]. These age similarities together with the elevated REE, Th, and Y contents in the uraninite, and the weak fractionation of the whole REE patterns (Supplementary Materials B) are all in favor of a crystallization of the uraninite in the Jiling uranium deposit from magmatic-hydrothermal fluid.

Uranium Mineralization Process
During the Paleozoic, during the transition from a compressional to an extensional tectonic regime, an upwelling asthenospheric mantle heated up the lithospheric, and induced the generation of mafic and felsic magmas [30]. Granitoids and syenite were formed with different ratios of mixing between the felsic and mafic magmas. Granitoid emplacement ages range from 442 to 435 Ma [30], and the syenite at 427 Ma [29]. During the late-magmatic stage, a magmatic-hydrothermal fluid exsolved from the crystallizing magmas percolated along the Malugou fault zones and developed extensive Na-metasomatic alteration zones in the Jiling granitoids.
During Na-metasomatism, early deformation occurred under a ductile regime, at temperatures higher than 450-500 • C, as evidenced by the granoblastic recrystallization of albite [5,61]. Quartz dissolution, albitization of K-feldspar and anorthite, led to enrichments in Na, U, and Th, and depletion in Si, K, and Ca in the Na-metasomatized granitoid [42,62]. The Jiling granitoid had 1.08 to 11.80 ppm U and Th/U ratios of 2.56 to 10.63 (Table 3), respectively, with data from Wang et al. [30] and Zhao [63]. Compared to the bulk earth ratio (Th/U = 3.9 ± 0.1), the relatively high Th/U ratios of many of the samples (Figure 10) from the Jiling granitoid indicate that these rocks lost significant U content during magmatic-hydrothermal fluid exsolution to crystallize uraninite in the metasomatic zones.

Hydrothermal Alteration of Primary Uraninite
After the formation of uraninite in ore stage I, the later hydrothermal activity led to second stage of mineralization in the Jiling uranium deposit. According to the previous studies on the fluid inclusion of calcite, which formed simultaneously with pitchblende [13,44], during ore stage II, the relatively lower temperature meteoric water percolated along the Malugou Fault zones and its secondary structures. Uranium was extracted from U-rich accessory minerals and uraninite formed in ore stage I through the fluid-rock interaction. Then, the extensive hematitization of albitite and the appearance of pink calcite indicate the oxidation of Fe 2+ in magnetite and/or biotite (e.g., [44]), and suggest that the oxidation of Fe 2+ may be responsible for the reduction of the carbonate uranyl complex transported by the ore fluids in the ore stage II.
Coffinite is a common mineral in some types of uranium deposits and is mostly deposited at low-temperatures and under reducing conditions. Coffinite can (a) form as a result of changing redox, aSiO 2 , pH, temperature, or pressure conditions, which induce coffinite precipitation [64,65]; (b) result from the alteration of previously crystallized uranium oxides through the uptake of silica under reducing conditions [66].
According to the presence of residual uraninite and altered pitchblende B found in the rim or core of coffinite A and B, respectively ( Figures 4D and 6C), and the high Th and REE contents of coffinite A, and the low Th content of coffinite B, we can conclude that coffinite A essentially resulted from the alteration of Th-rich uraninite and coffinite B from low Th pitchblende. The interpretation of the origin of coffinite A is further supported by the fact that high Th contents in coffinite from the Witwatersrand quartz pebble conglomerates, has been interpreted as resulting from an interaction between a Si-rich fluid and detrital Th-bearing uraninites [67] The different types of coffinites have REE pattern fractionation that is similar to BP uraninite (Supplementary Materials B), confirming that they derive from the alteration of BP uraninite. Combined coffinite B was formed from pitchblende during a later alteration, indicating that the pitchblende and coffinite may also derive from the remobilization of the primary uraninite in the Jiling uranium deposit. Compared to the altered uraninite A and altered pitchblende A, which formed underwent hydrothermal alteration enriched in Ca, the altered uraninite B and altered pitchblende B, which formed underwent hydrothermal alteration enriched in Si, have relatively higher LREE content. And the coffinite formed by the interaction between a Si-rich fluid and BP uraninite, pitchblende shows high LREE too. This may due to that the Si-rich fluid have relatively high content of LREE, because of the LREE can dissolve and mobile during fluid-rock interaction at low temperature [68,69].

Comparison with Other Na-Metasomatic Uranium Deposit
Uranium deposits related to Na-metasomatism are widespread around the world [5,[70][71][72][73]. The most typical and famous uranium deposits associated with Na-metasomatism are from central Ukraine [1,5]. Compared to other Na-metasomatic deposits, such as those from with the deposits of central Ukraine. The Jiling uranium deposit present the following specific characteristics: (a) The Jiling uranium deposit is hosted only in the Jiling intrusive granitoidic complex, whereas uranium mineralization in Central Ukraine also can be hosted in iron formations, this may be because the iron formation can provide a reduction condition for U precipitation in the ore-forming fluids in Central Ukraine. The iron formation also makes a difference in the mineralogy; (b) Due to the extensive U sources there is a thermal plume in the central part of the Ukrainian Shield, the uranium mineralization is spread over a belt of about 150 km in central Ukraine. Due to the limitations of magmatic activity, the uranium mineralization occurrences extend only over several tens kilometers in the Jiling area; (c) Due to banded iron formations, the metasomatic alteration episodes are more complex in the Central Ukraine uranium deposits. The Na-metasomatic episode, which is largely predominant in the Jiling deposit, is followed in the Ukraine by an important Ca-metasomatic episode with a new formation of Ca-rich pyroxene and garnet, only represented by minor amounts of carbonates in Jiling, and a late K-potassic event with a new formation of biotite, absent in Jiling [5]; (d) In central Ukraine and many other deposits there is a time gap between granite emplacement and ore deposit formation; granites were emplaced at 2050 Ma and the mineralization was formed at 1800 Ma, whereas in Jiling, the granitoids and the uranium mineralization were formed around 430 Ma. There was no significant time gap between the first uranium mineralization and host granite emplacement. This is a complicated issue that is affected by manyfactors, such as different metallogenic geological backgrounds, different metallogenic evolution processes, and different properties of ore-forming fluids between these two places [5]; (e) Due to the different ore-forming temperatures and host-rock geochemical characteristics between these two places, the uranium minerals predominantly consists of dominantly brannerite, with lesser amounts of low Th-uraninite, U-ferropseudobrookite, and pitchblende in central Ukraine. However, in the Jiling uranium deposit, high Th-REE-Y-uraninite, pitchblende, and coffinite are the main minerals; U-Ti minerals are absent; (f) The ore fluids in the Ukraine correspond to waters of surficial or basinal origin, whereas, in the Jiling uranium deposit ore fluids for the primary mineralization are of magmatic origin.

Conclusions
Integrating new petrographical/mineralogical observations, mineral chemistry, U-Th-Pb chemical dating, and the results of previous studies in the Jiling area, the following conclusions were obtained: (1) Three kinds of uranium minerals, high Th-REE-Y-uraninite, pitchblende, and coffinite, are present in the Jiling uranium deposit, and a great deal of the uraninite and pitchblende were subjected to different degrees of hydrothermal alteration. The pitchblende was the predominant uranium mineral among these three uranium minerals.
(2) The similarity of the chemical age of the primary uraninite in the Jiling deposit at 435.9 ± 3.3 Ma, with that of the enclosing intrusions, and the high Th and REEY contents of primary uraninite suggest its crystallization at a high temperature from a magmatic-hydrothermal fluid. The primary uraninite was subjected to at least two alteration events to form altered uraninite A, mainly enriched in calcium, and B, mainly enriched in silica, and coffinite A. (3) Limited data on the chemical age of fresh pitchblende, suggested a formation age at about 361 Ma. The low Th and REEY contents of fresh pitchblende both suggested its crystallization at a low temperature and possibly from a meteoric-dominated ore fluid. According to the different chemical composition of fresh and altered pitchblende, the fresh pitchblende was also subjected to at least two alteration events to form altered pitchblende A and B, where B had more silica, but with a similar amount of calcium to A. (4) In summary, after the Jiling pluton and syenite emplacement, Na-metasomatic alteration was developed extensively along the Malugou fault and secondary structures. This Na-metasomatic alteration was associated with the uranium mineralization. Uraninite was formed at high temperature and possibly from a magmatic-hydrothermal fluid during ore stage I. It would be interesting to determine whether intrusions similar to the Jiling granitoid exist in the area, as they could represent interesting targets for further exploration. Pitchblende was formed at a low temperature, possibly of meteoric origin, essentially from the remobilization of the primary uraninite mineralization during ore stage II. Uraninite and pitchblende were finally partly altered into two types of coffinite during a late alteration episode.

Conflicts of Interest:
The authors declare no conflict of interest.