Timing and Metamorphic Evolution of the Ross Orogeny in and around the Mountaineer Range, Northern Victoria Land, Antarctica

: The Ross(–Delamerian) Orogeny signiﬁcantly impacted the formation of the tectonic structure of the Paciﬁc Gondwana margin during the early Paleozoic era. Northern Victoria Land (NVL) in Antarctica preserves the aspect of the Ross Orogeny that led to the union of the Wilson (WT)–Bowers (BT)–Robertson Bay Terrane. The aspect of the Ross Orogeny in the NVL is characterized by subduction of oceanic domains toward the continental margin (continental arc) and the accretion of the associated marine–continental substances from 530–480 Ma. In the Mountaineer Range in NVL, the Ross Orogeny strain zone is identiﬁed at the WT / BT boundary regions. In these areas, fold and thrust shear zones are observed and aspects of them can be seen at Mt. Murchison, the Descent Unit and the Black Spider Greenschist zone. The Dessent Unit corresponds to a tectonic slice sheared between the WT and BT. The metamorphic evolution phase of the Dessent Unit is summarized in the peak pressure (M 1 ), peak temperature (M 2 ) and retrograde (M 3 ). The sensitive high-resolution ion microprobe (SHRIMP) zircon U–Pb ages of 514.6 ± 2.0 Ma and 499.2 ± 3.4 Ma obtained from the Dessent Unit amphibolite are comparable to the M 1 and M 2 stages, respectively. The Dessent Unit underwent intermediate pressure (P) / temperature (T)-type metamorphism characterized by 10.0–10.5 kbar / ~600 ◦ C (M 1 ) and ~7 kbar / ~700 ◦ C (M 2 ) followed by 4.0–4.5 kbar / ~450 ◦ C (M 3 ). Maﬁc to intermediate magmatism (497–501 Ma) within the WT / BT boundary region may have given rise to the M 2 stage of the Dessent Unit, and this magmatism is synchronous with the migmatization period of Mt. Murchison (498.3 ± 3.4 Ma). This indicates that a continuous process of fold-shearing–magmatic intrusion–partial melting, which is typically associated with a continental arc orogeny, occurred before and after c. 500 Ma in the Mountaineer Range. During the Ross Orogeny, the Dessent unit was initially subducted underneath the WT at depth (10.0–10.5 kbar, ~35 km) and then thrust into the shallow (~7 kbar, ~23 km), hot ( ≥ 700 ◦ C) magmatic arc docking with the Mt. Murchison terrain, where migmatization prevailed. for pyrope (pyp) and grossular (grs). The P–T path was identiﬁed by the garnet–biotite / garnet–biotite–plagioclase–quartz (GB / GBPQ) geothermobarometry, garnet isopleths and garnet–hornblende / garnet–hornblende–plagioclase–quartz (GH / GHPQ) geothermobarometry. Mineral abbreviations: ab, albite; anth, anthophyllite; ilm, ilmenite; ru, rutile; zo, zoisite. Other abbreviations are explained in the text. kyanite; sill, sillimanite; and, andalusite. Other mineral abbreviations are the same as those in Figure 7.


Field Occurrence and Relationship
This study presents the results of research activities in the Mountaineer Range that comprises Mt. Murchison (WT margin), the Dessent Unit (tectonic slice) and the BSG zone (BT margin), all of which correspond to the areas around the WT/BT boundary, as well as the Tiger Gabbro Complex (TGC) ( Figure 2). Moreover, the aspects of the Cambro-Ordovician Ross Orogeny in the Mountaineer Range are discussed.
The Mt. Murchison region is located on the WT's eastern margin and is mainly composed of gneisses and granites. The gneisses occur as migmatitic gneiss and sub-magmatic migmatite that consists primarily of leucosome, and in some areas, hornblende gneisses are observed. The dominant rock type is migmatitic gneiss, which shows at least two deformation stages (D 1 and D 2 ). Moreover, the migmatitic gneiss underwent two stages of migmatization (i.e., partial melting; Figure 3a). The migmatitic gneiss underwent regional, dynamothermal metamorphism, including the D 1 gneiss formation stage, partial melting (migmatitic gneiss formation), folding (D 2 ) and second stage partial melting, and, finally, was intruded by granites. Gneissosity, including leucosome of the migmatitic gneiss, was transformed into an isoclinal recumbent fold. Several fold structure components appear to be destroyed by the second stage of migmatization, indicating that a regional compressive force deformed the Mt. Murchison region during granulite facies metamorphism (Figure 3a). The strike of the fold axial plane of the recumbent fold is dominantly (sub)parallel to that of the Lanterman Fault, with the NW-SE direction gently dipping towards the SW, indicating that the Mt. Murchison area and the adjacent area were under a regional compression in the NE-SW direction during the Ross Orogeny. As the migmatitic gneiss (SBM173 including leucosome) shows a metamorphic age of 498.3 ± 3.4 Ma (U-Pb zircon age of this study), the peak metamorphic and migmatization ages of the Mt. Murchison area can be inferred to be c. 500 Ma. In addition, the c. 500 Ma thermal event indicates post-or pre-D 2 migmatization. The GHI (granite and granodiorite) related to the Ross Orogeny has been reported at Mt. Murchison and its western region [46]. Several types of granites crosscut the gneissosity of the Mt. Murchison gneiss at right angles, suggesting that they are post-Ross orogenic intrusions. deformed the Mt. Murchison region during granulite facies metamorphism (Figure 3a). The strike of the fold axial plane of the recumbent fold is dominantly (sub)parallel to that of the Lanterman Fault, with the NW−SE direction gently dipping towards the SW, indicating that the Mt. Murchison area and the adjacent area were under a regional compression in the NE−SW direction during the Ross Orogeny. As the migmatitic gneiss (SBM173 including leucosome) shows a metamorphic age of 498.3 ± 3.4 Ma (U−Pb zircon age of this study), the peak metamorphic and migmatization ages of the Mt. Murchison area can be inferred to be c. 500 Ma. In addition, the c. 500 Ma thermal event indicates post-or pre-D2 migmatization. The GHI (granite and granodiorite) related to the Ross Orogeny has been reported at Mt. Murchison and its western region [46]. Several types of granites crosscut the gneissosity of the Mt. Murchison gneiss at right angles, suggesting that they are post-Ross orogenic intrusions.  [43,44]) with zircon U-Pb ages. The profile (A−B) structure crosscutting Mt. Murchison was adopted and modified from Capponi et al. [43,44]. The Mountaineer Range is located in the WT/BT boundary region and includes Mt. Murchison (WT), the Tonalite Belt (WT), the Dessent Unit, the Black Spider Greenschist (BT), the Tiger Gabbro Complex (TGC) and the Bowers Supergroup (BT). The Lanterman Fault zone borders the WT and the BT. Structural measurements (mylonitic foliation and mineral stretching lineation) and metamorphic P (pressure)−T (temperature) conditions of the Dessent Unit are presented. For the zircon U-Pb ages, igneous and protolith ages are marked in red and metamorphic ages in blue. Literature zircon U-Pb data include those of Estrada et al. [39], Kim et al. [48] and Tiepolo and Tribuzio [65]. FP, Frank Point.  [43,44]) with zircon U-Pb ages. The profile (A-B) structure crosscutting Mt. Murchison was adopted and modified from Capponi et al. [43,44]. The Mountaineer Range is located in the WT/BT boundary region and includes Mt. Murchison (WT), the Tonalite Belt (WT), the Dessent Unit, the Black Spider Greenschist (BT), the Tiger Gabbro Complex (TGC) and the Bowers Supergroup (BT). The Lanterman Fault zone borders the WT and the BT. Structural measurements (mylonitic foliation and mineral stretching lineation) and metamorphic P (pressure)-T (temperature) conditions of the Dessent Unit are presented. For the zircon U-Pb ages, igneous and protolith ages are marked in red and metamorphic ages in blue. Literature zircon U-Pb data include those of Estrada et al. [39], Kim et al. [48] and Tiepolo and Tribuzio [65]. FP, Frank Point.
The NW-SE-trending Tonalite Belt developed between the Mt. Murchison gneisses and the Dessent Unit ( Figure 2). Tonalitic rocks in this belt are predominantly foliated, occur on the west side of the Lanterman Fault zone and are assigned to the GHI [33,34,44]. The age-dated tonalite in this study is weakly sheared (N-S strike; Figure 3b), with an intrusion age of 499.3 ± 2.1 Ma (U-Pb zircon), consistent with the metamorphic age of the Mt. Murchison migmatitic gneiss and also similar to the igneous age of gabbroic pegmatite in the TGC (see Section 5). This suggests that a distinct tonalitic to gabbroic intrusion occurred in the WT/BT boundary and its adjacent area c. 500 Ma ago, causing anatexis and peak metamorphism in the Mt. Murchison region. The mylonitic foliation in the tonalites indicates that crystal-plastic deformation continued in the Lantermann Fault zone after peak metamorphism (c. 500 Ma). consistent with the metamorphic age of the Mt. Murchison migmatitic gneiss and also similar to the igneous age of gabbroic pegmatite in the TGC (see Section 5). This suggests that a distinct tonalitic to gabbroic intrusion occurred in the WT/BT boundary and its adjacent area c. 500 Ma ago, causing anatexis and peak metamorphism in the Mt. Murchison region. The mylonitic foliation in the tonalites indicates that crystal-plastic deformation continued in the Lantermann Fault zone after peak metamorphism (c. 500 Ma).  The Dessent Unit is characterized by mylonitic rock bodies that developed between the WT and the BT and consists of the Dessent Ridge unit in the south of the Meander Glacier and the northern unit between the Gair Glacier and the Meander Glacier (Gair/Meander block). The Dessent Unit is visible as elongated bodies trending NW-SE. The bodies are in contact with the Tonalite Belt/Mt. Murchison gneiss (WT) to the west and the BSG (BT) to the east ( Figure 2). This unit is considered a tectonic slice with different characteristics from both the Wilson and Bowers terrane lithologies [33,34,43,44,59]. The Dessent Unit is represented by a predominant amphibolite lithology with amphibole biotite schist, mafic granulites, quartzite, marble/calcsilicate rocks, metapelites and metaconglomerates, depending on the location (this study) [33,43,44,62,66,67]. This unit distinctly retains amphibolite Minerals 2020, 10, 908 7 of 32 facies mineral assemblage, such as hornblende + garnet + plagioclase, with overprints of retrograde minerals (greenschist facies), such as chlorite + epidote + muscovite. The occurrence of retrograde greenschist facies mineral assemblage is pronounced in the northern unit (within the Gair/Meander block). In Frank Point, north of the Meander Glacier, granulite facies metamorphism (clinopyroxene + garnet + plagioclase) is preserved [62]. Most of the Dessent Unit amphibolites were mylonitized, and the retrogressed (greenschist facies) samples predominantly retain S-C fabric and extensional crenulation cleavage (ECC) (Figure 4a). Several amphibolites are characterized by alternate hornblendeand garnet-rich layers. The hornblendes are typically strongly aligned or form fine-grained aggregates, while the garnets appear in elongated bands (Figures 3c and 4b). Mylonitic foliations developed parallel (NW-SE strike) or subparallel (N-S strike) to the Lanterman Fault that is considered to be a tectonic boundary. Mineral stretching lineations generally plunge towards 220-230 • directions, which are slightly oblique to the down-dip direction of mylonitic foliations ( Figure 2). Macroscopic folds are identified locally and their fold axial plane is generally subparallel to the regional mylonitic foliation.

Analytical Methods
For zircon U−Pb age dating, five metamorphic and igneous rocks were crushed for conventional density and magnetic separations. Zircons were separated from the selected heavy minerals using tweezers and were then mounted using epoxy along with standard zircons. Zircon cathodoluminescence (CL) and back scattered electron (BSE) images were obtained using a scanning electron microscope (JEOL 6610LV model) at the Ochang Center of the Korea Basic Science Institute (KBSI), Republic of Korea. We based our analytical zircon U−Pb dating procedures on the methods To the east of the Dessent Unit, the BSG crops out, occurring as narrow and elongated rock bodies trending NW-SE parallel to the Dessent Unit. The BSG corresponds to the western margin of the BT [33,43,44,55,68]. In this schist zone, greenschist/phyllite and metadiabase (hornblende gabbro precursor) alternate repetitively and have a deformation structure along with (meta)granite porphyry/(meta)granodiorite. The greenschist/phyllite shows a predominant mylonitic texture, whereas a distinct, dynamic recrystallization texture is absent in the meta-igneous rocks, which display a metasomatic overprint of secondary minerals (chlorite + epidote). All the BSG rocks appear to have undergone greenschist facies metamorphism and have been deformed into tight to isoclinal folds and partially mylonitized. Their fold axial planes are sub-parallel to the Dessent Unit's mylonitic foliation.
The TGC is located in the easternmost part (southeast) of the study area and within the BT. This complex consists of cumulative mafic-ultramafic igneous rocks, such as various gabbroic rocks, anorthosites, pyroxenites and hornblendites, which generally crop out as undeformed and unmetamorphosed. A narrow (~10 cm width) local shear zone has been identified on Apostrophe Island (this study) [69,70]. The relationship between the TGC and the BT metasedimentary rock is interpreted as either an intrusive contact [70,71] or a shear contact [33]. Based on this study's field survey, the TGC's cumulate piles were intruded by hornblende gabbro and hornblende gabbro pegmatite at the Complex margin. U-Pb zircon dating indicates a hornblende gabbro pegmatite (i.e., frozen melt) intrusion age of c. 497 Ma (this study). The outcrop arrangement of the hornblende gabbro (pegmatite) intrusive bodies shows an E-W trend and differs from the strikes (NW-SE) of the TGC's dominant igneous bedding. This suggests that the boundary between the TGC's main body and the BT metasedimentary rock is obscured by the late intrusive nature of hornblende gabbro pegmatite. Furthermore, it indicates that the formation age of the complex's cumulate piles exceeds c. 497 Ma. A coarse-grained gabbro sample from the TGC cumulates, which hosts the Ediacaran-age zircons as well as the Paleoproterozoic to Neoarchean xenocrystic zircons, has been reported [72]. A geochronological comparison between the age of the Tiger Gabbro cumulates and the hornblende gabbro pegmatite and the number of different chronological units comprising the igneous complex has not yet been established.

Analytical Methods
For zircon U-Pb age dating, five metamorphic and igneous rocks were crushed for conventional density and magnetic separations. Zircons were separated from the selected heavy minerals using tweezers and were then mounted using epoxy along with standard zircons. Zircon cathodoluminescence (CL) and back scattered electron (BSE) images were obtained using a scanning electron microscope (JEOL 6610LV model) at the Ochang Center of the Korea Basic Science Institute (KBSI), Republic of Korea. We based our analytical zircon U-Pb dating procedures on the methods of Williams [73] and Ireland and Williams [74]. The analyses were conducted using SHRIMP IIe at the Ochang Center of the KBSI. A primary ion (O 2− ) beam was used for analyses, and the size and current of the beam were 20-25 µm and 4-6 nA, respectively. The standard zircon SL13 was used to measure the U concentration [75], and the U-Pb isotope ratios were calibrated using the FC1 zircon [76]. Each U-Th-Pb analysis of zircons consisted of five scans throughout the mass range. Ages were calculated using the decay constants of Steiger and Jäger [77]. Data reduction, age calculation and common Pb correction were performed using SQUID v. 2.5 and Isoplot/Ex 3.41 [78]. The U-Th-Pb isotope ratios and ages of each analysis are at the 1σ uncertainty level. The uncertainty levels for the calculated concordia age and the weighted mean age are 1σ and 2σ, respectively.
To determine the major element concentrations of metamorphic rocks, we conducted a whole-rock analysis using an X-ray fluorescence (XRF) spectrometer. Fresh samples were leached in a dilute acid solution and pulverized to <150 mesh (105 µm) powder in a tungsten carbide mill bowl (Niand Cr-free). Dried sample powders were weighed in a ceramic crucible and ignited in a muffle furnace for 20 min at 1000 • C. Loss on ignition (LOI) was determined by comparing the weights before and after the ignition. Glass beads were prepared by mixing 0.6 g of powdered sample and 6.0 g of the alkali flux (lithium tetraborate, Li 2 B 4 O 7 ). The mixture was put into a platinum Minerals 2020, 10, 908 9 of 32 crucible (5% gold) with 0.05 g of exfoliation agent (lithium bromide, Liberia). Fusing and agitation were conducted with an automated high-frequency bead sampler (SPEX, K-2 PRIME) at 300 s of prefusion (c. 1050 • C) and 60 s of fusion (c. 1080 • C). The analysis was performed using a wavelength dispersive XRF spectrometer (Pananalytical Axios Max) at the Korea Polar Research Institute (KOPRI), Incheon, Republic of Korea. The XRF spectrometer was equipped with a Philips 4 kW Rh anode Super Sharp X-ray tube. Calibration and analysis were automatically performed with a SuperQ software package (v. 5.2B, Malvern Panalytical, Almelo, The Netherlands) attached to the spectrometer. The instrumental drift was corrected by measuring the synthetic monitor samples.
We determined the metamorphic mineral compositions using a JEOL JXA-8530F field emission (FE) electron probe micro-analyzer (EPMA) at the KOPRI. The accelerating voltage, beam current and probe diameter were 15 kV, 10 nA and 5 µm, respectively. Count times of the peak and background were 20 s and 10 s, respectively. Certified natural minerals and synthetic oxides were used as standards, and matrix correction was processed using the conventional PhiRhoZ (PRZ) method.

Zircon U-Pb Geochronology
We established the tectonic evolution of the Mountaineer Range during the Ross Orogeny by SHRIMP zircon U-Pb dating. Samples of migmatitic gneiss (SBM173) from Mt. Murchison (WT), tonalite (SB1713A) from the Tonalite Belt, amphibolite (SB176) from the Dessent Unit and pegmatitic hornblende gabbros (M1722 and M1719) from the outer part of the TGC (BT) were analyzed. The analytical results are presented in Table S1.
A total of 168 zircon spots were analyzed in the migmatitic gneiss (SBM173). In this sample, various types of anhedral, subhedral and euhedral zircons with lengths of approximately 100-250 µm were identified. The zircons exhibit predominantly oscillatory growth zoning in the CL images, suggesting an igneous origin. The zircon cores reveal Paleoproterozoic to Neoproterozoic ages, indicating that these igneous zircons are detrital and that sample SBM173 is a paragneiss. A number of zircon grains exhibit dark rims in the CL image due to metamorphism and several display metamorphic overgrowth textures. Euhedral, unzoned zircons exhibit a low CL emission and reveal metamorphic ages ( Figure 5a). The zircon metamorphic zones show a predominantly low Th/U ratio of less than 0.1, with a lower Th/U ratio and a higher U content than the detrital igneous cores. The Th/U ratio of a few metamorphic zones is relatively high, ranging from 0.3 to 0.5. The metamorphic age of the zircons shows a broad apparent age ( 206 Pb/ 238 U age), varying from 530 Ma to 460 Ma. Among these, a predominant concordant age of 498.3 ± 3.4 Ma (weighted mean of 206 Pb/ 238 U age: n = 17, mean squared weighted deviation (MSWD) = 0.87) possibly indicates the timing of migmatization ( Figure 6a). The detrital zircon age of the migmatitic gneiss (SBM173) is characterized by the predominant Grenville age of 900-950 Ma and 1000-1100 Ma, with an evident late Neoproterozoic age of 562.4 ± 6.0 Ma (weighted mean of 206 Pb/ 238 U age: n = 11, MSWD = 0.57) as the youngest detrital age. Other detrital ages, such as 600-650 Ma, c. 800 Ma, c. 1400 Ma, c. 1670 Ma, c. 2250 Ma and c. 2450 Ma were also identified (Figure 6a,b). Thus, it can be interpreted as that the protolith of the migmatitic gneiss (SBM173) was formed in the late Neoproterozoic (Ediacaran, c. 560 Ma) to early Paleozoic (early Cambrian, c. 530 Ma) and underwent a peak temperature metamorphism (i.e., migmatization) at c. 500 Ma. In addition, the dispersion of the metamorphism age from 530 Ma to 460 Ma indicates that metamorphism continued before and after 500 Ma. Several metamorphic zircons have a discordant age shifting towards the Mesozoic era, indicating that the migmatitic gneiss (SBM173) underwent a Mesozoic thermal event after the Ross Orogeny ( Figure 6a).
Twenty-eight zircon spots were analyzed in the deformed tonalite (SB1713A). In the sample, euhedral zircons, with a length of 100-200 µm, exhibit oscillatory growth zoning in the CL images ( Figure 5b). Neither an inherited core nor an apparent metamorphic rim was observed in these zircons. The zircon Th/U ratios range from 0. 13  Twenty-eight zircon spots were analyzed in the deformed tonalite (SB1713A). In the sample, euhedral zircons, with a length of 100−200 μm, exhibit oscillatory growth zoning in the CL images ( Figure 5b). Neither an inherited core nor an apparent metamorphic rim was observed in these zircons. The zircon Th/U ratios range from 0.13 to 0.95. The apparent 206 Pb/ 238 U ages are distributed between 507 Ma and 481 Ma, and the weighted mean of 206 Pb/ 238 U age for 23 concordant spots is 499.3 ± 2.1 Ma (MSWD = 0.75) corresponding to the intrusion age of the tonalite (SB1713A). Three younger concordant spots reveal a 206 Pb/ 238 U age of 481−484 Ma (±4 or 5 Ma), possibly suggesting a younger igneous event (Figure 6c).  Table S1. One backscattered electron (BSE) image of the amphibolite (SB176) (c) is compared with its CL image.
Thirty-two zircon spots were analyzed in the Dessent Unit amphibolite sample (SB176). The anhedral and subhedral zircons were approximately 100 μm long and hosted inclusions of biotite, garnet, plagioclase and iron oxide. Although the core and rim of the zircons are not distinguishable  Table S1. One backscattered electron (BSE) image of the amphibolite (SB176) (c) is compared with its CL image.
in the zircon rim reveal a younger age of 499.2 ± 3.4 Ma (weighted mean of 206 Pb/ 238 U age: n = 7, MSWD = 1.2), corresponding to the metamorphic age of the amphibolite sample (SB176) (Figure 6d). The presence of garnet inclusions and the migmatitic gneiss's metamorphic age range suggest that the dominant age obtained for the zircon core and rim (514.6 ± 2.0 Ma) indicates the metamorphic age of the amphibolite (SB176). Thus, the amphibolite (SB176) ages (514.6 ± 2.0 Ma and 499.2 ± 2.0 Ma) are presumed to indicate the ages of the first and second metamorphic stages.  Thirty-two zircon spots were analyzed in the Dessent Unit amphibolite sample (SB176). The anhedral and subhedral zircons were approximately 100 µm long and hosted inclusions of biotite, garnet, plagioclase and iron oxide. Although the core and rim of the zircons are not distinguishable due to their unzoned and low CL emissions, these are relatively distinct in the BSE image (Figure 5c). The zircon Th/U ratios range from 0.64 to 3.05 and, except for one spot (spot no. 30: rim position, Th/U = 0.01), showed no core-rim position distinction. The dominant age of the zircon core and rim is calculated as 514.6 ± 2.0 Ma (weighted mean of 206 Pb/ 238 U age: n = 26, MSWD = 1.14). Several spots in the zircon rim reveal a younger age of 499.2 ± 3.4 Ma (weighted mean of 206 Pb/ 238 U age: n = 7, MSWD = 1.2), corresponding to the metamorphic age of the amphibolite sample (SB176) (Figure 6d). The presence of garnet inclusions and the migmatitic gneiss's metamorphic age range suggest that the dominant age obtained for the zircon core and rim (514.6 ± 2.0 Ma) indicates the metamorphic age of the amphibolite (SB176). Thus, the amphibolite (SB176) ages (514.6 ± 2.0 Ma and 499.2 ± 2.0 Ma) are presumed to indicate the ages of the first and second metamorphic stages.
It is estimated that pegmatitic hornblende gabbros (M1722 and M1719) intrude the boundary between the TGC and BT metasedimentary rock. Zircons of sample M1722 are dominated by euhedral grains with lengths of 200-400 µm. They all show oscillatory growth zoning in the CL image and do not have an inherited core (Figure 5d). Twenty-eight spots were analyzed for these zircons. Th/U ratios of the analyzed zircons range from 0. 16  In summary, the WT and BT's primary lithologies developed around the Dessent Unit are highlighted by the intrusion of mafic to intermediate igneous rocks and associated migmatization around 500 Ma. This corresponds to the Ross Orogeny's prominent thermal peak in the Mountaineer Range, which occurred between 520 Ma and 480 Ma.

Amphibolite (SB173B) from the Dessent Unit
Sample SB173B is a mylonitic amphibolite ( Figure 4c) and is geochemically equivalent to andesite. Pseudosection modeling of the amphibolite (SB173B) in a pressure range of 1-12 kbar reveals a clinoamphibole stability temperature lower than~760 • C and a solidus (melt-in) temperature of~700 • C. The thermal peak assemblage of the amphibolite (SB173B) is hornblende + plagioclase + garnet + biotite + quartz + ilmenite ± melt, which is stable at a P-T range of 630-710 • C and 6.0-9.5 kbar (Figure 7a). The compositional isopleths of garnet were applied to specify metamorphic P-T conditions. Garnet porphyroblasts are almandine-rich (X alm = 0.65-0.73) and spessartine-poor (X sps = 0.02-0.06). The core of the garnet porphyroblast has X pyp values of~0.16 and X grs values of~0. 13, showing a slight, rim-ward compositional increase in X pyp (~0.20) and a rim-ward decrease in X grs (~0.07) (Figure 8a). The modeled metamorphic P-T conditions of the porphyroblastic garnet core and rim correspond to 610-630 • C (~6 kbar) and~630 • C (~5 kbar), respectively, which are slightly lower than the P-T range inferred from the phase assemblage. However, GB and GBPQ geothermobarometry calculation of the pyrope-rich garnet rim reveals P-T conditions consistent with the low-pressure limit (650-720 • C and 6.3-7.5 kbar) of the stable P-T range of main mineral assemblage. This is considered to be a thermal peak metamorphic condition of the amphibolite (SB173B). The three lowered P-T conditions identified by GB/GBPQ and GH/GHPQ geothermobarometry calculations probably indicate a retrograde process ( Figure 7b).  (Figure 8a). The modeled metamorphic P−T conditions of the porphyroblastic garnet core and rim correspond to 610−630 °C (~6 kbar) and ~630 °C (~5 kbar), respectively, which are slightly lower than the P−T range inferred from the phase assemblage. However, GB and GBPQ geothermobarometry calculation of the pyrope-rich garnet rim reveals P−T conditions consistent with the low-pressure limit (650−720 °C and 6.3−7.5 kbar) of the stable P−T range of main mineral assemblage. This is considered to be a thermal peak metamorphic condition of the amphibolite (SB173B). The three lowered P−T conditions identified by GB/GBPQ and GH/GHPQ geothermobarometry calculations probably indicate a retrograde process (Figure 7b).

Amphibolite (SB174B) from the Dessent Unit
Sample SB174B is a mylonitic amphibolite and is geochemically equivalent to basaltic andesite. The amphibolite (SB174B) is characterized by alternating hornblende-and garnet-rich layers in which hornblendes are strongly aligned or form fine-grained aggregates and garnets form elongated bands. Recrystallized plagioclase and quartz ribbons are mainly observed (Figures 3c and 4b). Pseudosection modeling of the amphibolite (SB174B) in a pressure range of 1−11 kbar reveals a clinoamphibole stability temperature lower than ~730 °C and a solidus (melt-in) temperature of ~700 °C. The thermal peak assemblage of the amphibolite (SB173B) is hornblende + plagioclase + garnet + biotite + quartz + ilmenite ± melt, which is stable at a P−T range of 600−680 °C and 5.3−11.0 kbar (Figure 9a). The in Xpyp (0.14−0.15) and a rim-ward decrease in Xgrs (0.11−0.14) (Figure 8b). The garnet core composition records a slightly higher P condition (~600 °C and ~10.2 kbar) compared to the P−T range inferred from the peak mineral assemblage. The P−T conditions of garnet rims converge to the P−T range inferred from the main mineral assemblage, yielding a peak temperature P−T condition of 650−670 °C and 7−8 kbar. The GH and GHPQ geothermobarometry P−T conditions of the garnet rim, which is relatively spessartine-rich, are most likely those of retrograde processes (Figure 9b).  Figure 4 and Table S3, respectively.  Figure 4 and Table S3, respectively.

Amphibolite (SB174B) from the Dessent Unit
Sample SB174B is a mylonitic amphibolite and is geochemically equivalent to basaltic andesite. The amphibolite (SB174B) is characterized by alternating hornblende-and garnet-rich layers in which hornblendes are strongly aligned or form fine-grained aggregates and garnets form elongated bands. Recrystallized plagioclase and quartz ribbons are mainly observed (Figures 3c and 4b). Pseudosection modeling of the amphibolite (SB174B) in a pressure range of 1-11 kbar reveals a clinoamphibole stability temperature lower than~730 • C and a solidus (melt-in) temperature of~700 • C. The thermal peak assemblage of the amphibolite (SB173B) is hornblende + plagioclase + garnet + biotite + quartz + ilmenite ± melt, which is stable at a P-T range of 600-680 • C and 5.3-11.0 kbar (Figure 9a). The compositional isopleths of garnet were applied to the pseudosection. The garnet layers are mostly almandine-rich (X alm = 0.66-0.73) and spessartine-poor (X sps = 0.01-0.04). The elongated garnet shows X pyp values of~0.13 and X grs values of 0. 16-0.19 in the core, with a rim-ward compositional increase in X pyp (0.14-0.15) and a rim-ward decrease in X grs (0.11-0.14) (Figure 8b). The garnet core composition records a slightly higher P condition (~600 • C and~10.2 kbar) compared to the P-T range inferred from the peak mineral assemblage. The P-T conditions of garnet rims converge to the P-T range inferred from the main mineral assemblage, yielding a peak temperature P-T condition of 650-670 • C and 7-8 kbar. The GH and GHPQ geothermobarometry P-T conditions of the garnet rim, which is relatively spessartine-rich, are most likely those of retrograde processes (Figure 9b). an elongated band or polygonal granoblastic fabric (Figure 4d,e). The peak metamorphic assemblage of the amphibolite is considered to be hornblende + plagioclase + garnet + biotite + quartz + ilmenite + magnetite. Pseudosection modeling of the amphibolite in a pressure range of 1−11 kbar reveals a clinoamphibole stability temperature lower than ~750 °C and a solidus (melt-in) temperature of ~700 °C. The stable metamorphic condition estimated by the thermal peak mineral assemblage corresponds to a P−T range of 570−670 °C and 5.5−11.0 kbar (Figure 10a). Garnet porphyroblasts are mostly almandine-rich (Xalm = 0.74−0.83) and spessartine-poor (Xsps = 0.01−0.05). The core of the garnet porphyroblast shows Xpyp values of 0.08−0.10 and Xgrs values of 0.09−0.12. Xpyp (~0.11) increases marginally rim-ward, while Xgrs (0.05−0.07) decreases (Figure 8a). The P−T conditions of the garnet porphyroblast cores estimated by a compositional isopleth method are 570−600 °C and 5.3−6.8 kbar, which are close to the lower limit of the P−T range inferred from the phase assemblage. The geothermobarometry (GH and GHPQ)-calculated metamorphic conditions of the garnet rim, which is relatively spessartine-rich, suggests several retrograde P−T conditions converging to the P−T condition of ~420 °C and 4.5 kbar (Figure 10b).
Summing up the metamorphic P−T conditions of the three amphibolite samples, the Dessent Unit underwent metamorphism during the Ross Orogeny. This process consists of the higher pressure M1 (~600 °C and 10.0-10.5 kbar) and the thermal peak M2 (~700 °C and 7.0-7.5 kbar), followed by the retrograde M3 (~450 °C and 4.0-4.5 kbar) ( Figure 11).

Amphibolite (SB176B) from the Dessent Unit
Sample SB176B is a mylonitic amphibolite and is geochemically equivalent to dacite. In this sample, the stretching lineation of hornblendes is well developed, and the recrystallized quartz forms an elongated band or polygonal granoblastic fabric (Figure 4d,e). The peak metamorphic assemblage of the amphibolite is considered to be hornblende + plagioclase + garnet + biotite + quartz + ilmenite + magnetite. Pseudosection modeling of the amphibolite in a pressure range of 1-11 kbar reveals a clinoamphibole stability temperature lower than~750 • C and a solidus (melt-in) temperature of~700 • C. The stable metamorphic condition estimated by the thermal peak mineral assemblage corresponds to a P-T range of 570-670 • C and 5.5-11.0 kbar (Figure 10a). Garnet porphyroblasts are mostly almandine-rich (X alm = 0.74-0.83) and spessartine-poor (X sps = 0.01-0.05). The core of the garnet porphyroblast shows X pyp values of 0.08-0.10 and X grs values of 0.09-0.12. X pyp (~0.11) increases marginally rim-ward, while X grs (0.05-0.07) decreases (Figure 8a). The P-T conditions of the garnet porphyroblast cores estimated by a compositional isopleth method are 570-600 • C and 5.3-6.8 kbar, which are close to the lower limit of the P-T range inferred from the phase assemblage. The geothermobarometry (GH and GHPQ)-calculated metamorphic conditions of the garnet rim, which is relatively spessartine-rich, suggests several retrograde P-T conditions converging to the P-T condition of~420 • C and 4.5 kbar (Figure 10b).       [59]. The P-T paths from the literature data are inferred by this study. Reference reaction curves: Plyusnina [99], Ernst [100], Spear [101] and Bucher and Frey [102]. Petrogenetic grid: Oh and Liu [103]. Abbreviations: BS, blueschist facies; EG, eclogite facies; EA, epidote amphibolite facies; GS, greenschist facies; LG, low-pressure granulite facies; jd, jadeite; gln, glaucophane; omp, omphacite; pg, paragonite; cal, calcite; act, actinolite; ky, kyanite; sill, sillimanite; and, andalusite. Other mineral abbreviations are the same as those in Figure 7.

Discussion
The Ross-Delamerian Orogen had a profound impact on the formation of the Paleozoic eastern Gondwana (i.e., East Antarctica-TAM, eastern Australia, Tasmania and southern Zealandia). In addition, Antarctica and Australia shared a variety of geological events in the Precambrian. These are represented by the Archean to Paleoproterozoic Mawson Craton (an amalgam comprising the Gawler, Terre Adélie, Nimrod and Shackelton components), its right-hand side (RHS in Figure 1d co-ordinates: VL direction) Nimrod-Kimban Belt (c. 1.7 Ga) and left-hand side (LHS in Figure 1d co-ordinates: Prince Charles Mts. direction) Kararan (1.64-1.55 Ga), Albany-Fraser (1.34-1.14 Ga) and Pinjarra-Grenville (1080-990 Ma) orogenic belts. The middle Paleozoic Lachlan Orogeny also influenced the formation of West Antarctica, eastern Australia, Tasmania and southern Zealandia (Figure 1d). Geological similarities between Antarctica and adjacent regions have led to various studies related to the assembly and breakup of Gondwana [3,14,42,53,[104][105][106].
The amount of rock exposure in Antarctica is extremely limited. Thus, the detrital zircon ages, identified in (meta)sedimentary rocks have helped greatly with the interpretation of the provenance of detritus as well as with the possible lithology under the currently obscured glaciers and the development of the paleocurrent pattern and paleogeographic linkage. In the following sections, we infer the origin of the sediments of Mt. Murchison (para-)gneiss, and then, we discuss the protolith formation process of the gneiss, the metamorphic evolution in the Mountaineer Range and tectonic model for the Ross Orogeny in NVL. The Neoproterozoic passive margin formed in RHS of the Mawson Craton. These regions can be interpreted as rift basins associated with the breakup of Rodinia, and their main rifting period is predicted to be 750-650 Ma [5,26,107]. Although the detected continental rift-related U-Pb zircon crystallization age in the outcrop is limited to 670 Ma (central TAM [108]) and 650 Ma (southern VL [109]), it is expected that more 750-650 Ma-age rocks obscured by glaciers could be present in the estimated rift basin. These ages can cover the 800-650 Ma detrital zircon age within Mt. Murchison. The outcrop record for the early Ross Orogeny in the TAM region, including the study area, is a zircon U-Pb age of 550 Ma. In addition, the zircon U-Pb ages obtained from glacial clasts or detrital materials makes it possible to estimate the Ross Orogeny activity during the period 590-550 Ma, and the c. 615 Ma metamorphism (garnet Lu-Hf date) retained by the central TAM basement rock leads to inference of the initiation period of 615-590 Ma for the Ross Orogeny [26,107,110]. The mentioned early Ross orogenic ages are most frequent in Mt. Murchison's detrital zircons and also are equivalent to the youngest detrital zircon age of the gneiss sample (SBM173) (Figure 6a,b and Figure 12). Thus, the protolith of the Mt. Murchison paragneiss is expected to be a sedimentary rock formed during the early Ross Orogenic process. Syn-orogenic forearc deposition associated with the Ross Orogeny has been predicted throughout VL and in the central TAM region [3,26,28,41,111]. The youngest detrital zircon age of the Mt. Murchison gneiss (SBM173B) is 562.4 ± 6.0 Ma, and the metamorphism is interpreted to have lasted for a period of 530-480 Ma (see Section 5 and Figure 6a,b). This indicates that the protolith of the Mt. Murchison (para)gneiss was formed between 560-530 Ma. Furthermore, the protolith could be formed in the forearc during this period, and it can be considered that old detritus originating from the interior of East Antarctica was introduced into the forearc (Figure 13).
Minerals 2020, 10, x FOR PEER REVIEW 18 of 31 Figure 12. A comparison of detrital zircon (xenocrystic zircon for granite) ages from the major Rossorogenic lithologies of NVL. Relative probability distribution-frequency histograms for concordant (less than 10% discordance) U-Pb ages. All three terranes (WT, BT and RBT) exhibit a similar detrital age distribution featuring the Grenvillian and Ross/Pan-African ages. The BT and RBT are especially characterized a prominent Ross-orogenic detritus. Literature data include Estrada et al. [39] and Kim et al. [48].

Figure 12.
A comparison of detrital zircon (xenocrystic zircon for granite) ages from the major Ross-orogenic lithologies of NVL. Relative probability distribution-frequency histograms for concordant (less than 10% discordance) U-Pb ages. All three terranes (WT, BT and RBT) exhibit a similar detrital age distribution featuring the Grenvillian and Ross/Pan-African ages. The BT and RBT are especially characterized a prominent Ross-orogenic detritus. Literature data include Estrada et al. [39] and Kim et al. [48].
been predicted throughout VL and in the central TAM region [3,26,28,41,111]. The youngest detrital zircon age of the Mt. Murchison gneiss (SBM173B) is 562.4 ± 6.0 Ma, and the metamorphism is interpreted to have lasted for a period of 530−480 Ma (see Section 5 and Figure 6a,b). This indicates that the protolith of the Mt. Murchison (para)gneiss was formed between 560−530 Ma. Furthermore, the protolith could be formed in the forearc during this period, and it can be considered that old detritus originating from the interior of East Antarctica was introduced into the forearc (Figure 13). The Pan-African Orogen is a Gondwana-building tectonic process that completes the assembly of eastern and western Gondwana. This orogeny is detected around the Crohn Craton in Antarctica and has an orogenic age range from 580 to 490 Ma (up to 700 Ma in the East African Orogen) [2,4,5,12,112]. In other words, the Pan-African Orogeny occurred at nearly the same time as the Ross(−Delamerian) Orogen, and it corresponds to the Ediacaran detrital zircon age in the Mt. The Pan-African Orogen is a Gondwana-building tectonic process that completes the assembly of eastern and western Gondwana. This orogeny is detected around the Crohn Craton in Antarctica and has an orogenic age range from 580 to 490 Ma (up to 700 Ma in the East African Orogen) [2,4,5,12,112]. In other words, the Pan-African Orogeny occurred at nearly the same time as the Ross(-Delamerian) Orogen, and it corresponds to the Ediacaran detrital zircon age in the Mt. Murchison area. However, considering the distance between the Pan-African belts and the study area and the relationship between the study area and the Ross Orogeny, it is expected that the Pan-African Orogen-related detritus did not have much of an impact on the formation of the proto-Mt. Murchison basin (Figures 1d and 13). Yet, the relationship between the Pan-African Orogen and the formation of VL should be discussed in more depth in the future.
Possible source materials mentioned above could be interpreted as being directly deposited into the protolith sedimentary basin of the modern Mt. Murchison through the Neoproterozoic to early Paleozoic currents. However, if the existence of the Ediacaran (590-550 Ma) Ross igneous province is acknowledged, the magmatic arc mountains (e.g., the modern equivalent could be the Cascade Range or Andes Mts.) of this igneous process can be expected to act as a barrier to paleocurrents. That is, it can be interpreted that the sedimentary basins of the Mt. Murchison protolith do not receive Proterozoic detritus directly from the East Antarctic interior, but rather receive them from late Neoproterozoic (Ediacaran) arc mountains hosting reworked (Paleo-to Neo-)Proterozoic sediments as well as early Ross orogenic material ( Figure 13).
To summarize, the above discussion indicates that protoliths of the Mt. Murchison gneisses are sedimentary rocks formed at a certain period between 560 and 530 Ma and that the detrital source of the protoliths could be a Neoproterozoic crust hosting Paleoproterozoic, Grenvillian and 750-565 Ma age materials (possibly including the early Ross orogenic materials). This Neoproterozoic crust could be a marginal supracrustal province (i.e., platform) reworking of initial sources from the East Antarctic interiors (i.e., shield). Thus, possibly a Proterozoic shield (hosting an Archean lithology) and platform-late Neoproterozoic to Paleozoic magmatic arc association during the Paleozoic era can be specified as a geological architecture in East Antarctica and the TAM region, including NVL.

Early Paleozoic Metamorphic Phase (Ross Orogeny) in the Mountaineer Range
The metamorphic evolution and P-T conditions of the Ross Orogeny in the Mountaineer Range have been presented by several studies [59,62,97,98]. The metamorphic P-T conditions were obtained in the Dessent Unit and the WT margin gneisses. This section discusses the metamorphic P-T condition of the Dessent Unit obtained in this study and the published data. As mentioned in Section 6, the metamorphic conditions established in the Dessent Unit are divided into three stages: higher P (M 1 ), peak T (M 2 ) and retrograde (M 3 ). Palmeri et al. [59] presented the peak P-T condition comparable to the metamorphic condition of the middle path between M 1 and M 2 . In addition, the P-T conditions presented by Capponi et al. [97] are similar to those obtained for the amphibolite sample (SB176B). Moreover, the conditions of Scambelluri et al. [62] show a metamorphic P-T path similar to that of M 2 -M 3 in this study, although the metamorphic pressure of Scambelluri et al. [62] is relatively lower. Based on this, we can infer that the Dessent Unit has undergone an intermediate P/T-type metamorphism characterized by M 1 (~600 • C and 10.0-10.5 kbar), M 2 (~700 • C and 7.0-7.5 kbar) and M 3 (~450 • C and 4.0-4.5 kbar) ( Figure 11). This clockwise P-T path of the Ross Orogeny tends to appear differently at each location within the unit. This can be attributed to local differences in thermal effects associated with mafic to intermediate intrusions in the Mountaineer Range.
Based on the results of Sections 5 and 6, the Ross Orogeny is highlighted by dynamothermal metamorphism and the intrusion of igneous rocks from 520 Ma to 480 Ma ( Figure 6). This study determined that within this period, c. 515 Ma and c. 500 Ma possibly represent the M 1 and M 2 stages of the Dessent Unit, respectively. That is, the high-T metamorphism (a boundary P-T condition between the amphibolite and granulite facies) of the M 2 stage is only recognized in some areas of the Dessent Unit, and this pattern is likely to be attributed to the local distribution of identified or hidden c. 500 Ma intrusives. In this study, several samples with partial melting can be identified ( Figure 11). In addition, the clinopyroxene-bearing granulite recovered at Frank Point [62] indicates that some parts of the Dessent Unit underwent granulite facies metamorphism, which is related to the major intrusion period of igneous rocks and is the result of the Dessent Unit M 2 metamorphic phase.
Most of the rocks in the Dessent Unit were mylonitized. Chlorite and epidote developed along the mylonitic foliation with S-C fabric and ECC (Figure 4a). This indicates that the unit was predominantly mylonitized under a greenschist facies metamorphic condition ((post-)M 3 ). However, garnet deformation from brittle to crystal-plastic transition, the development of garnet bands, alternating garnet and hornblende layers and the presence of granoblastic polygonal quartz and quartz ribbon in several samples indicate that the mylonitization of these rocks occurred under an amphibolite facies metamorphic condition (pre-M 3 : Figures 3c and 4b,e). Furthermore, since most of the prograde and retrograde metamorphic P-T conditions of the Dessent Unit obtained in this study correspond to the amphibolite facies condition (Figure 11), it can be interpreted that the mylonitization of the unit also started to occur under the amphibolite facies P-T condition (pre-M 3 stage). That is, the greenschist facies mylonitization ((post-)M 3 ), which is predominant in the outcrops, may correspond to a secondary metamorphic event that overprinted the amphibolite facies mylonitization related to the peak metamorphism of the Dessent Unit (M 1-2 ). Thus, the first mylonitization may have occurred during the peak metamorphic process (amphibolite facies) in the geologically deeper location of the Dessent Unit (M 1-2 ). Then, the unit may have undergone extension-related shearing (e.g., ECC) during the retrograde process (greenschist facies: (post-)M 3 ).
The metamorphic P-T condition of gneisses from the WT margin is similar to that of the Dessent Unit. However, the WT margin gneisses have a relatively lower pressure condition than most of the Descent Unit amphibolites ( Figure 11) [62,97]. Given the Wilson Terrane margin and the Dessent Unit's proximity, these two zones appear to have experienced the same metamorphic process during the Dessent Unit M 2 -M 3 phase. It is assumed that the migmatization of the Wilson gneisses (c. 500 Ma) is associated with the M 2 phase of the Dessent Unit, which was activated by igneous activity in the regions adjacent to the Dessent Unit (i.e., tectonic boundary) at approximately 500 Ma.
The Tonalite Belt developed between the WT and the Dessent Unit. The igneous ages of the tonalite are 499.3 ± 2.1 Ma (SB1713A: Figure 6c, this study) and 489 ± 4 Ma [65], with a slight age difference locally. A weak mylonitic fabric that appears in the tonalite (SB1713A) indicates that the Tonalite Belt was ductilely deformed even after 500 Ma.
The Husky Ridge intrusion was reported in contact with the WT gneisses and the Tonalite Belt ( Figure 2) [65]. The Husky Ridge intrusion consists of mafic intrusive rocks, typically with amphibole as the characteristic mineral. These rocks have an ambiguous contact relationship with the WT gneisses and the Tonalite Belt. The igneous age of the Husky Ridge quartz diorite (or hornblende gabbro) was reported as 516 ± 3 Ma [65]. This intrusion is found in an undeformed or weakly deformed nature. Considering the peak metamorphism at c. 500 Ma identified in this area and the location of the intrusion, which corresponds to the tectonic boundary, the undeformed nature of the Husky Ridge Intrusion may contradict the c. 515 Ma igneous age of the quartz diorite. Similar samples of hornblende gabbro (M1722 and M1719) and tonalite (SB1713A) comprising hornblende and plagioclase minerals with igneous ages of c. 500 Ma are found in this study. Since the reported quartz diorite from the Husky Ridge also contains a number of c. 500 Ma single zircon ages, the reported igneous age of 516 ± 3 Ma has a possibility to be revised. If the Husky Ridge intrusion is a local intact rock of hornblende gneiss of the WT, which survived the Ross-dynamothermal metamorphism, the c. 515 Ma age could also be interpreted as the protolith age of the hornblende gneiss.
The BSG zone comprises greenschist/phyllite and (meta)igneous rocks consisting of subvolcanic hornblende gabbro and granite porphyry/granodiorite. They form tightly to isoclinal folds and are partially mylonitized. Their fold axial planes are generally sub-parallel to the mylonitic foliation of the Dessent Unit. A metasedimentary rock from the BSG zone contained the Ross Orogen-related detrital zircon (511 ± 15 Ma, 526 ± 13 Ma and 540 ± 8 Ma) indicative of the basin formation for this zone during the Ross Orogeny [39]. This zone appears to have undergone greenschist facies metamorphism.
Deformational structures of the Mountaineer Range are summarized as follows. The Murchison gneisses (WT) and the BSG (BT) were folded with a similar aspect by a regional compression driving into the direction of NE-SW, and the Dessent Unit between them was mylonitized by compression-related shearing. This can be explained by an orogenic process in which a regional compression juxtaposed the WT and BT, strongly shearing their tectonic boundaries (e.g., [33,34,43,44,59]). The recognition of intermediate P/T-type metamorphism and the absence of eclogite or related high-pressure mineral assemblages in the Dessent Unit indicates that the exposed unit was not significantly subducted into the deep depth (i.e., eclogite facies condition) during the union of the WT and BT. This differs from the Lanterman Range, for which high P/T-type metamorphism with eclogite facies P-T conditions are reported [58,60,61,113,114]. However, a clockwise P-T path in which a high-pressure stage at c. 515 Ma proceeded by high-temperature metamorphism at c. 500 Ma reported in the Lanterman Range [61] indicates that both the Mountaineer Range and the Lanterman Range ultimately experienced a metamorphic evolutionary path of similar timing (duration) and stages.

Possible Tectonic Model for the Ross Orogeny in the Mountaineer Range
Several tectonic models have been proposed for the Ross Orogeny that complete the formation of NVL. These are based on the model of Kleinschmidt and Tessensohn [41]. The Kleinschmidt and Tessensohn model is based on the subduction of ocean plates into the continental margin WT and the related BT and RBT accretion. This model assumes two parallel, westward-dipping subduction zones, in which an island arc (Glasgow Volcanics) formed by rear subduction and the BT was completed during the WT-arc collision process. The tectonic environment then changes to single slab subduction and the RBT began to grow (similar to Figure 14). After the Kleinschmidt and Tessensohn model, a continent (WT)-(micro)continent collision model was proposed [37,42]. The new model suggests that the Wilson continental arc developed in the convergence process of the two continents, then arc (Glasgow Volcanics) and back-arc (or forearc, BT) developed by slab roll-back, and finally, the continental-continent collision accelerated the RBT formation over the following continent that is now totally covered by the thick RBT (turbiditic) sediments. Rocchi et al. [31] predicted that subduction of the paleo-Pacific Plate into the Gondwana margin caused the development of the Wilson continental arc (WT), and during this process, the continental affinity-forearc was boudinaged into two blocks (Bowers arc and Admiralty continental ribbon). After that, the two blocks were reassembled by contraction, and the outboard island arc (Tiger arc) finally accreted to complete NVL.  Figure 2). The model and artwork are modified after Boger and Miller [3] and Kleinschmidt and Tessensohn [41].
This study and previous data from igneous rock clasts and detrital materials of VL indicate that the Ross Orogeny in NVL possibly began at least at 565 Ma. During the late Neoproterozoic era (Ediacaran), the WT was situated in the paleo-Pacific margin of East Antarctica (or eastern Gondwana), and the modern Mountaineer Range was located on the paleo-Pacific subduction zone (forearc basin) ( Figure 13). A magmatic province related to the early Ross Orogeny (c. 565 Ma) was rapidly dismantled during the continuous Rose orogenic contractional process. Then, the clastic materials from the  Figure 2). The model and artwork are modified after Boger and Miller [3] and Kleinschmidt and Tessensohn [41].
It is possible to visualize the aspect of the Ross Orogeny in the Mountaineer Range by combining the contents of Sections 7.1 and 7.2 and previous studies. The WT forms a continental margin at East Antarctica during the late Neoproterozoic to early Paleozoic. The dominant igneous activity of the Ross Orogen in the WT occurred from 530 to 480 Ma [15,31,[49][50][51], and in the Mountaineer Range of the terrane margin, from 500 to 480 Ma (this study) [48,65]. The age distribution of detrital zircon found in the Murchison gneisses is characterized by predominant ages of c. 565 Ma and 900-1200 Ma (Grenville-age), with minor age abundances of Paleoproterozoic to Neoproterozoic ages. This is similar to the distribution pattern of detrital zircon found in the Molar formation and the BSG of the BT and in the Millen Schist and the RBT (Figure 12). In addition, igneous and metamorphic ages of the Ross Orogeny identified in the Mountaineer Range outcrop are recorded in the BT-RBT as the youngest detrital zircon ages. This indicates that the deposition of clasts primarily formed the BT-RBT sediments from the WT including the Wilson continental arc [38,39]. Furthermore, the strata of these two terranes are thought to be continuously deposited and intruded (or extruded) during the Ross Orogeny and simultaneously deformed to form the present WT-BT-RBT association. Consequently, NVL is characterized by the WT (East Antarctic margin), which is continuously subducted and accreted by oceanic-continental domains (BT and RBT) on which strata and arc magmatic rocks are formed and deformed. (Meta)igneous rocks identified in the BSG zone (BT) are thought to have been formed in arc environments and deformed (or metamorphosed) by process of continent-arc collision. The lithology of the hornblende gabbros and associated amphibole-featured igneous rocks (a members of the appinite suite) found in the vicinity of the Dessent Unit (BSG, TGC, Husky Ridge and Tonalite Belt) has been reported in an arc or post-arc tectonic settings (mainly in the continental regions) [115][116][117][118][119][120]. Neoarchean to Paleoproterozoic xenocrystic zircons are found in igneous cumulates of the TGC that is thought to have intruded the BT [72]. In addition, the presence of deformed granites in the BSG zone suggests the possibility that the BT is a submarine or subaerial arc on the continental crust.
With the limited data in this study, it is difficult to establish a tectonic model for the entire NVL. However, by combining the above-mentioned discussion and the advantages of preexisting models (especially in regard to Kleinschmidt and Tessensohn's model [41]), it becomes possible to draw a tectonic model for the formation of the Mountaineer Range as in the following two paragraphs.
This study and previous data from igneous rock clasts and detrital materials of VL indicate that the Ross Orogeny in NVL possibly began at least at 565 Ma. During the late Neoproterozoic era (Ediacaran), the WT was situated in the paleo-Pacific margin of East Antarctica (or eastern Gondwana), and the modern Mountaineer Range was located on the paleo-Pacific subduction zone (forearc basin) ( Figure 13). A magmatic province related to the early Ross Orogeny (c. 565 Ma) was rapidly dismantled during the continuous Rose orogenic contractional process. Then, the clastic materials from the magmatic province were deposited in the WT margin (forearc basin) during 560-530 Ma ( Figure 13b) and subsequently underwent the Ross-dynamothermal metamorphism (530-500 Ma) to be transformed into the Mt. Murchison gneiss ( Figure 14). In other words, the protolith of the Mt. Murchison gneiss (WT) formed between the late Ediacaran (c. 560 Ma)-early Cambrian (530 Ma) dominantly sourced from early Ross (Ediacaran) magmatic arc mountains ( Figure 13).
A prominent igneous activity of the Ross Orogeny in NVL begins at distinct time in the 530-520 Ma period. This activity is predominantly identified within the WT interior [15,31,[49][50][51]. This igneous activity corresponds to arc magmatism associated with the WT-BT union. Continental arc products formed during this period are eroded and then deposited in the forearc basin, where the materials become the parent of the BT silicic clasts (Figure 14a). The BT is a submarine or subaerial arc on the continental crust (allochthonous microcontinent or WT fragment), which consists of sedimentary deposits transported from the WT and igneous rocks associated with the subduction of the RBT oceanic plate (i.e., paleo-Pacific Plate). The Dessent Unit is developed between the WT and the BT as a high-grade metamorphic rock with a dominant basalt (or basaltic andesite) lithology. The Dessent Unit is thought to be an arc-related extensional domain including back-arc and fore-arc, or it could be a part of the paleo-Pacific Plate (e.g., [31,37,59], its origin is still unclear). This rock body subducts into the lower part of the WT, and the current rock body exposed at the surface shows a subduction depth of approximately 35 km (c. 10.0-10.5 kbar) (M 1 , possibly 515 Ma). After subduction, the rock body rises to a shallow depth of approximately 23 km (c. 7 kbar) and experiences a thermal peak (M 2 , possibly 500 Ma) of the Ross Orogeny, which corresponds to the migmatization stage of the Mt. Murchison gneisses. Simultaneously, the Murchison gneisses undergo a compressive, dynamothermal metamorphism encompassing migmatization as a process of the WT-BT collision (at 500 Ma). The M 2 phase of the Descent Unit leaves a trace of the concordant deformation on the Murchison-Dessent-BSG union (Figure 14b). The migmatization at 500 Ma is related to the mafic to intermediate magmatism (within the Tonalite Belt and the TGC) around the Dessent Unit, which is thought to be arc igneous activity possibly associated with subduction of the RBT oceanic plate (paleo-Pacific Plate) into the BT. This magmatism extends to c. 480 Ma, causing the intrusion of leucocratic dykes (e.g., [48]) and the second stage of migmatization in Mt. Murchison. During the Ross Orogeny of the Mountaineer Range (530-480 Ma), the BT and RBT continue to grow and receive sediments from the WT. After the 500 Ma period, the Dessent Unit undergoes retrograde metamorphism (M 3 ) and thrusts into the shallow, where a juxtaposition with the BSG occurs (possibly <480 Ma period). Finally, the Mountaineer Range Metamorphic Complex, which consists of the Mt. Murchison gneisses-(deformed)Tonalite Belt-Dessent Unit-BSG-BT metasedimentary with TGC, is completed ( Figure 14b).

Conclusions
From the above discussion, the following conclusions can be drawn.
(1) In the Mountaineer Range of NVL, the Ross Orogenic structures such as fold and thrust shear zones formed by dynamothermal metamorphism with regional compression are identified in the Mt. Murchison, Dessent Unit and BSG zone.
(2) The protolith of paragneiss in Mt. Murchison formed during the late Ediacaran to early Cambrian (560-530 Ma), possibly sourced from the Mawson Craton interior and its surrounding orogenic belts (Paleoproterozoic to Mesoproterozoic ages) and Neoproterozoic rift margin hosting the early Ross orogenic products as well; this was transformed into a migmatitic gneiss (SBM173) during the main phase of the Ross Orogeny with a peak temperature stage at around 500 Ma (498.3 ± 3.4 Ma).
(4) During the M 2 stage of the Dessent Unit, mafic to intermediate igneous rocks intruded the WT/BT boundary regions (tonalite, 499.3 ± 3.4 Ma; hornblende gabbros, 496.2 ± 1.0 and 497.6 ± 1.0 Ma) and is synchronous with the migmatization period of Mt. Murchison (c. 500 Ma). This indicates that continuous process of fold-shearing-magmatic intrusion-partial melting, which is typically formed in a continental arc orogeny, occurred before and after c. 500 Ma in the Mountaineer Range.
(5) The Dessent Unit corresponds to a tectonic slice sheared between the WT and BT. It is presumed that during the Ross Orogeny, the unit was initially subducted underneath the WT at depth (10.0-10.5 kbar depth,~35 km) and then thrust into the shallow (~7 kbar,~23 km), hot (≥700 • C) magmatic arc, docking with the Murchison migmatite terrain.
Supplementary Materials: The following are available online at http://www.mdpi.com/2075-163X/10/10/908/s1, Table S1: SHRIMP zircon U-Pb data for igneous and metamorphic rocks from the Mountaineer Range; Table S2: P-T conditions estimated from the Dessent Unit amphibolites using conventional geothermobarometry; Table S3: Representative compositional zoning profile of garnet in the Dessent Unit amphibolites.