A Novel Method of Laser Coating Process on Worn-Out Cutter Rings of Tunnel Boring Machine for Eco-Friendly Reuse

: Cutter rings form an integral part of tunnel boring machines (TBM). These cutters are deployed in various hard rock tunneling projects. The life of the cutter rings governs the economics of tunneling signiﬁcantly. This paper presents a novel methodology to enhance hardness and wear resistance of used worn out disc cutters in TBM for eco-friendly reuse. Disc cutters are mainly made of H13 tool steel. To improve the hardness and wear resistance, a layer of tungsten carbide is coated on the used cutter rings. Considering the long operating hours of TBM, cutter rings get worn out due to severe interaction with the hard rock both in compression and rolling mode. Replacement of the cutter-ring is costly, and quite a time consuming and cumbersome job. Refurbishment is always a better option and laser cladding is a novel technique for enhanced life of cutters. It increases the hardness and wear resistance of the cutters to a considerable extent. Cladding is carried out with the help of a laser beam. In this method, a layer of nanoparticles of tungsten carbide powder is deposited on the worn-out surface of the cutters. For carrying out the investigation, di ﬀ erent coating parameters are selected based on the central composite design (CCD). With di ﬀ erent capacities of laser, a total of 13 samples were prepared at various scanning speeds varying between 200 to 300 mm / min and a level of laser power varying between 100 to 200 W. The coating is critically inspected by various means such as an optical microscope, FESEM, and EDS. Hardness testing was accomplished by Vicker’s hardness testing machine. Wear testing was carried out with the aid of pin on disc setup. The results shows an asymmetrical behavior between the yield parameters (hardness and wear rate) and process parameters (scanning speed and laser power). The hardness values increased from 16% to 95%. A correlation test was conducted between the hardness and wear rate. The results depict a clear negative correlation between them, indicating the advantage of laser coating for reducing cutter ring wear in TBM. These results show that coating of an reuse and refurbishment of worn out rings for enhanced cutter life. This has direct economic beneﬁts in deploying TBM technologies for tunneling projects.


Introduction
The tunnel boring machine is a game-changer in mechanized tunneling technology. It is used for boring tunnels for various purposes such as irrigation, metro, subway, hydel, canals, and sewage [1]. The cutter head is located in front of the TBM structure and it rotates at a very slow rpm (2 to 8 rpm). It cuts the rocks by chipping and causes advancement of the tunnel face. Disc cutters are positioned on Cutter rings are costly and their replacement is quite time-consuming. Refurbishment happens to be a much acceptable option for ease of operation. Different types of rapid prototyping (RP) technologies are used for the refurbishment of material such as stereolithography (SLA), fused deposition modeling (FDM) and laminated object manufacturing (LOM) [3]. In SLA, parts are contrived by a fluid photosensitive resin within sight of laser radiation. The FDM method is used for fabricating layered surfaces. In this method, a thermoplastic filament is used in a supply head, and then this fused material is extruded from the head for making layers. In LOM, layers are formed with the help of paper, plastics, and metals with glued together. These layers are cut by a laser cutter. However, RP technologies are used for developing the functional parts directly from the metals without the aid of binders or other activities. Laser surface cladding (LSC) meets this challenging requirement. It is widely utilized for producing metal parts by metal powders with higher productivity. In this strategy, the materials are bolstered on the substrate under the laser beam by various means such as powder paste, powder blowing and wire feed [4]. In a comparatively short time, a laser beam interacts with them and thus, chemical and microstructural changes are observed [5]. The laser power, scanning speed, and beam diameter are the deciding factors for the thickness of the coating [6]. Different types of surface treatment and the composite coating is done using LSC. It is widely used for non-porous and crack-free surface treatment.
In mining and heavy engineering, failure due to the wear of cutting tools is a frequent phenomenon [7]. It affects the production, operation and economic strategies of the company [8]. Enhancement of the wear resistance of the machine cutting tools can be obtained by hard facing or coating of abrasion-resistant material [9]. A common method for the production of this hard facing is by using metal matrix composites (MMC). It is a mixture of hard ceramic phase and a ductile metal matrix. Ni-and Co-based compounds are frequently used with tungsten carbide (WC) for the hard facing of material [10]. WCs are usually supplied in the form of alloy powder, in which bindingagglomerates of WC particles are included and its hardness is in the range of 1500-2000 HV. Cermets of WC-Co are also used as abrasion-resistant materials in the industries. Using a CO2 laser, the coating of 83% WC on the surface of AISI 1043 presents less porosity, a high coating hardness and a very good adhesive layer substrate [11,12]. The other benefits of the coatings are erosion resistance, corrosion and oxidation barrier, reclamation of worn-out parts, enhanced electrical and thermal property [13,14]. Cutter rings are costly and their replacement is quite time-consuming. Refurbishment happens to be a much acceptable option for ease of operation. Different types of rapid prototyping (RP) technologies are used for the refurbishment of material such as stereolithography (SLA), fused deposition modeling (FDM) and laminated object manufacturing (LOM) [3]. In SLA, parts are contrived by a fluid photosensitive resin within sight of laser radiation. The FDM method is used for fabricating layered surfaces. In this method, a thermoplastic filament is used in a supply head, and then this fused material is extruded from the head for making layers. In LOM, layers are formed with the help of paper, plastics, and metals with glued together. These layers are cut by a laser cutter. However, RP technologies are used for developing the functional parts directly from the metals without the aid of binders or other activities. Laser surface cladding (LSC) meets this challenging requirement. It is widely utilized for producing metal parts by metal powders with higher productivity. In this strategy, the materials are bolstered on the substrate under the laser beam by various means such as powder paste, powder blowing and wire feed [4]. In a comparatively short time, a laser beam interacts with them and thus, chemical and microstructural changes are observed [5]. The laser power, scanning speed, and beam diameter are the deciding factors for the thickness of the coating [6]. Different types of surface treatment and the composite coating is done using LSC. It is widely used for non-porous and crack-free surface treatment.
In mining and heavy engineering, failure due to the wear of cutting tools is a frequent phenomenon [7]. It affects the production, operation and economic strategies of the company [8]. Enhancement of the wear resistance of the machine cutting tools can be obtained by hard facing or coating of abrasion-resistant material [9]. A common method for the production of this hard facing is by using metal matrix composites (MMC). It is a mixture of hard ceramic phase and a ductile metal matrix. Ni-and Co-based compounds are frequently used with tungsten carbide (WC) for the hard facing of material [10]. WCs are usually supplied in the form of alloy powder, in which binding-agglomerates of WC particles are included and its hardness is in the range of 1500-2000 HV. Cermets of WC-Co are also used as abrasion-resistant materials in the industries. Using a CO 2 laser, the coating of 83% WC on the surface of AISI 1043 presents less porosity, a high coating hardness and a very good adhesive layer substrate [11,12]. The other benefits of the coatings are erosion resistance, corrosion and oxidation barrier, reclamation of worn-out parts, enhanced electrical and thermal property [13,14]. This paper reports the investigations carried out on the usage of WC coating on the worn-out cutter rings of disc cutters used in tunnel boring machine. The coating has been made with the help of a fiber laser in the presence of N 2 shielding gas. WC nanopowder has been used as a coating material and H13 tool steel as a substrate. Initially, a 5 mm thick plate of H13 was made with the help of an abrasive cutter and wire electric discharge machining (WEDM). A 1 mm thick layer of WC paste has been formed with the help of polyvinyl alcohol (PVA) solution. A laser beam with different process parameters has been passed over the paste of WC. In situ formation of coating has been investigated by an optical microscope, FESEM and EDS. Hardness testing was done by the Vicker's hardness testing machine. Wear testing has been performed on a pin on disc setup. ANOVA was employed to analyze the impact of laser processing-related parameters (laser speed, scanning speed) on the yields (hardness and wear rate) of the coating. A desirability test was performed to get the correlation of input and output parameters. A correlation test has also been carried out between the hardness and wear rate of coating, with the help of R-software.

Materials
The materials that have been used in the experimental work are H13 tool steel (worn out cutter ring) and WC nanopowder of 60 nm with 99.5% assay (as given by the manufacturer). PVA has been used as a solution for mixing WC nanopowder properly and for making a paste of that. The compositions of the materials used as substrate are given in Table 1.

Experimental Setup
The cladding was done on the fiber laser setup. Initially, the surface of the substrate was cleaned with acetone. WC nanoparticles were mixed with PVA solution and a paste was prepared. This paste was placed on the substrate and it was dried in the furnace at 80 • C for 2-3 h till moisture gets vaporized from the paste. The laser setup comprised of a continuous wave (CW) fiber laser with a power ranging from 100 to 400 W [15]. The laser head installed along the z-axis controls beam diameter and the table adjusts the scanning speed of the laser beam. The cladding chamber is in cuboid shape and made up of perspex material with a dimension (100 × 100 × 40 mm). It is put on the CNC table as shown in Figure 2. The cladding chamber is furnished with two openings, one for inlet of shielding gas (N 2 ) and other for exhaust [16]. A quartz plate of dimension (50 × 50 × 2 mm) is set on the top center position of the cladding chamber to pass a laser beam [17]. The laser setup and its schematic diagram were shown in Figure 2. diameter and the table adjusts the scanning speed of the laser beam. The cladding chamber is in cuboid shape and made up of perspex material with a dimension (100 × 100 × 40 mm). It is put on the CNC table as shown in Figure 2. The cladding chamber is furnished with two openings, one for inlet of shielding gas (N2) and other for exhaust [16]. A quartz plate of dimension (50 × 50 × 2 mm) is set on the top center position of the cladding chamber to pass a laser beam [17]. The laser setup and its schematic diagram were shown in Figure 2.

Design of Experiment
The experiment was designed using the central composite method, with the two levels of each input parameter with 13 runs of the experiment [18]. The low and high levels of parameters were selected based on some pilot tests conducted earlier, taking into consideration the limitations of the available experimental setup (shown in Table 2). Thus, a completely randomized experimental design with 13 experimental runs was generated using Minitab 17.0 software (shown in Table 3). Figure 3 is shown the substrate with tungsten carbide paste and coated samples.

Design of Experiment
The experiment was designed using the central composite method, with the two levels of each input parameter with 13 runs of the experiment [18]. The low and high levels of parameters were selected based on some pilot tests conducted earlier, taking into consideration the limitations of the available experimental setup (shown in Table 2). Thus, a completely randomized experimental design with 13 experimental runs was generated using Minitab 17.0 software (shown in Table 3). Figure.3 is shown the substrate with tungsten carbide paste and coated samples.

Equipment
The composition of the coating was checked by Zeiss energy-dispersive X-ray spectroscopy (EDS) [19]. The coating was verified by an Olympus optical microscope with the highest resolution of 50× and Zeiss field emission scanning electron microscope (FESEM). Hardness testing was carried out by the Chennai Metco Vicker's hardness testing machine. Wear testing was executed with the

Equipment
The composition of the coating was checked by Zeiss energy-dispersive X-ray spectroscopy (EDS) [19]. The coating was verified by an Olympus optical microscope with the highest resolution of 50× and Zeiss field emission scanning electron microscope (FESEM). Hardness testing was carried out by the Chennai Metco Vicker's hardness testing machine. Wear testing was executed with the help of a pin on disc setup (wear and friction monitoring machine TR-20).

Coating
The cladding was done with the aid fiber laser at different settings. The major process control parameters are laser power and scanning speed with different combinations of the experiment. It was done based on the central composite method [20]. For testing of the deposited coating, an optical microscope was used in the presence of proper etchant (Murakami reagent). Figure 4a shows the interaction zone of the substrate and coating, and Figure 4b,c manifests the coating of tungsten carbide on the substrate. A needle and dendrite type of microstructure clearly showed the presence of tungsten carbide on the substrate in Figure 4b,c. The bonding strength between the coating and substrate is very high and homogeneous. Acute martensite was formed in the heat-affected zone (HAZ) and more uniform distribution of reinforcement particles is shown in Figure 4b, where martensites are predominantly of needle shape. This formation of micro constitutes has been found to determine the high hardness values. This happens due to the rapid cooling at room temperature [21]. The large heat energy evolved in the coating, joined with the favorable thermal gradients environment of the cladding core manifested slow rates of solidification. It provides adequate excitation and time for the WC particles to mix in the metallic matrix, at the portion of the coating outskirts, where thermal gradients are comparatively higher due to the fast cooling by convection to the surroundings and conduction at the cladding-substrate interface. One case, denoted by Figure 4c, is rich in mixed carbides with a dendritic growth [7]. The cladding was done with the aid fiber laser at different settings. The major process control parameters are laser power and scanning speed with different combinations of the experiment. It was done based on the central composite method [20]. For testing of the deposited coating, an optical microscope was used in the presence of proper etchant (Murakami reagent). Figure 4a shows the interaction zone of the substrate and coating, and Figure 4b,c manifests the coating of tungsten carbide on the substrate. A needle and dendrite type of microstructure clearly showed the presence of tungsten carbide on the substrate in Figure 4b,c. The bonding strength between the coating and substrate is very high and homogeneous. Acute martensite was formed in the heat-affected zone (HAZ) and more uniform distribution of reinforcement particles is shown in Figure 4b, where martensites are predominantly of needle shape. This formation of micro constitutes has been found to determine the high hardness values. This happens due to the rapid cooling at room temperature [21]. The large heat energy evolved in the coating, joined with the favorable thermal gradients environment of the cladding core manifested slow rates of solidification. It provides adequate excitation and time for the WC particles to mix in the metallic matrix, at the portion of the coating outskirts, where thermal gradients are comparatively higher due to the fast cooling by convection to the surroundings and conduction at the cladding-substrate interface. One case, denoted by Figure  4c, is rich in mixed carbides with a dendritic growth [7].

Microstructure Analysis
Microstructure analysis was critically analyzed by FESEM of the laser cladding at different parametric settings. There is a straight impact of the laser power on the morphology of the coating. It can be observed from Figure 5a, that WC nanoparticles are evenly distributed and micro-holes are presented on the surface. Different levels of laser power produce a different coating thickness. When the laser power was low, "mess" type coating occurs. Two reasons may be responsible for this. The first one is due to a lack of energy. The refractory phase was not completely melted thus, gases are probably entrapped and form micro holes and cracks. The second is that the rapid heating and cooling forms thermal stresses which generate micropores in the coating. At moderate laser power, a good metrological bonding is obtained between the coatings. Some pores sporadically remain there but microstructures are comparatively finer in comparison to the earlier cases. At higher power, the coating is in more favorable condition; fishbone microstructures are formed with a less number of holes. At low scanning speed, the cladding is a mixture of the amorphous and crystalline regions, and at moderate scanning speed it is full of block grain structure. At a higher speed, it is full of

Microstructure Analysis
Microstructure analysis was critically analyzed by FESEM of the laser cladding at different parametric settings. There is a straight impact of the laser power on the morphology of the coating. It can be observed from Figure 5a, that WC nanoparticles are evenly distributed and micro-holes are presented on the surface. Different levels of laser power produce a different coating thickness. When the laser power was low, "mess" type coating occurs. Two reasons may be responsible for this. The first one is due to a lack of energy. The refractory phase was not completely melted thus, gases are probably entrapped and form micro holes and cracks. The second is that the rapid heating and cooling forms thermal stresses which generate micropores in the coating. At moderate laser power, a good metrological bonding is obtained between the coatings. Some pores sporadically remain there but microstructures are comparatively finer in comparison to the earlier cases. At higher power, the coating is in more favorable condition; fishbone microstructures are formed with a less number of holes. At low scanning speed, the cladding is a mixture of the amorphous and crystalline regions, and at moderate scanning speed it is full of block grain structure. At a higher speed, it is full of dendritic microstructure. It could be observed that the cladding layers were dense and clear interface lines are visible at different scanning speeds. Cracks have been formed in some cladding layers (Figure 5b). The curvature of the interface decreased as heat input increased, indicating the change in dilution rates. The width and height varied with scanning speed. When scanning speed is high, these values are low (less time of solidification) and weaker due to the "heat-shielding effect". The substrate under the interface exhibited a martensite structure and columnar crystal zone. Strip-shaped precipitates could be identified between columnar grains [22]. The laser beam, coating material and material interaction time are the root cause of the primary carbide phase in the metal matrix. This mainly depends on the primary WC particle dissolution decree and the quantity fraction in their compound size and overall content. The conditions of processing ought to be optimized to minimize the disruption of primary carbides. Decreased laser strength and increased scanning speed resulted in high porosity levels and layers cracking shown in  The laser beam, coating material and material interaction time are the root cause of the primary carbide phase in the metal matrix. This mainly depends on the primary WC particle dissolution decree and the quantity fraction in their compound size and overall content. The conditions of processing ought to be optimized to minimize the disruption of primary carbides. Decreased laser strength and increased scanning speed resulted in high porosity levels and layers cracking shown in Figure 5e. The good quality coatings were achieved at 220 W laser power and 250 mm/s scanning speed in combination. The amount of volume fraction of WC particles determines the surface roughness and structure of the coating. The lesser and harder the phase content is, the better the liquefied material flow will be, resulting in the formation of a smooth surface of coating [23]. A laser-clad layer can be classified into three parts, i.e., build-up, dilution, and heat-affected area. The dilution area is a melted mixture of deposited material and substrate. The heat affected area is just below the dilution zone in which the elevated temperature is less than the melting point [24]. Build-up and dilution areas are seriously affected by scanning speed. As the laser ray moves faster, the mass of volume and build-up becomes smaller. Nevertheless, reducing the scanning speed could minimize the dilution zones or in some cases, it gets completely disappeared [25]. The presence of porosity and globules was obtained in the coatings. This can be described by trapped gases present because of large liquid viscosity actuated by WC particles in the melt pool, as shown in Figure 5d. The thickness of the coating was also inspected and the average thickness of the coating found to be 680 µm, as shown in Figure 5f. The interface fusion line was irregular and non-linear in nature [26].

EDS Analysis
The scanning results of elements for sample using a spectrometer (EDS) are shown in Figure 6a. Figure 6b depicts the spectrum 1 elemental analysis of the coating side and Figure 6c shows the spectrum 2 elemental parts of the non-coating side. Detailed elements of coated and non-coated sides are shown in Table 4. It is revealed that Fe has the highest parts at 88.59% in the substrate. Other elements, such as C, Cr, and Mn, were lower but they also play a significant effect in enhancing the strength and hardness of the remelting layer by forming a substitutional solid solution. Based on the analysis, it was observed that the grain refinement and the solid-liquid shrinkage in the liquid pool increased due to the addition of nano-WC particles. Heat transfer capabilities of the coating surface improved during remelting, resulting in intimate coating combined with the matrix material.
Symmetry 2020, 12, x FOR PEER REVIEW 7 of 15 dilution area is a melted mixture of deposited material and substrate. The heat affected area is just below the dilution zone in which the elevated temperature is less than the melting point [24]. Buildup and dilution areas are seriously affected by scanning speed. As the laser ray moves faster, the mass of volume and build-up becomes smaller. Nevertheless, reducing the scanning speed could minimize the dilution zones or in some cases, it gets completely disappeared [25]. The presence of porosity and globules was obtained in the coatings. This can be described by trapped gases present because of large liquid viscosity actuated by WC particles in the melt pool, as shown in Figure 5d. The thickness of the coating was also inspected and the average thickness of the coating found to be 680 µm, as shown in Figure 5f. The interface fusion line was irregular and non-linear in nature [26].

EDS Analysis
The scanning results of elements for sample using a spectrometer (EDS) are shown in Figure 6a. Figure 6b depicts the spectrum 1 elemental analysis of the coating side and Figure 6c shows the spectrum 2 elemental parts of the non-coating side. Detailed elements of coated and non-coated sides are shown in Table 4. It is revealed that Fe has the highest parts at 88.59% in the substrate. Other elements, such as C, Cr, and Mn, were lower but they also play a significant effect in enhancing the strength and hardness of the remelting layer by forming a substitutional solid solution. Based on the analysis, it was observed that the grain refinement and the solid-liquid shrinkage in the liquid pool increased due to the addition of nano-WC particles. Heat transfer capabilities of the coating surface improved during remelting, resulting in intimate coating combined with the matrix material.

Hardness Testing
Hardness testing was done by Vicker's hardness testing machine at 200 gm load for 10 dual seconds. The metal elements Fe, Mn, V, Si, Cr, WC, and the non-metallic element C appeared (EDS analysis) to diffuse and there was strong bonding among the elements. The higher the laser power,

Hardness Testing
Hardness testing was done by Vicker's hardness testing machine at 200 gm load for 10 dual seconds. The metal elements Fe, Mn, V, Si, Cr, WC, and the non-metallic element C appeared (EDS analysis) to diffuse and there was strong bonding among the elements. The higher the laser power, the smaller the microstructure characteristics and the fewer the number of micro holes. As the laser power increased, hardness also increased from 16% to 95%. The microhardness increased with depth from the bonding interface to the coating surface. The scanning speed has a significant effect on the resulted coating hardness. Smaller the grain size, the higher will be the hardness (hall patch formula). As the scanning speed increases, the hardness and wear resistance of the coating gradually decrease due to change in microstructure. The hardness distribution in the thickness direction is shown in Figure 5a,b. It increased from the substrate to the interface zone and then to the cladding zone. Overall, the hardness of the cladding layer has significantly increased and the values are repeatable.
The hardness of coated layers ranged from 580 to 870 HV0.2. It is much higher than that of the substrate (400-460 HV0.2). However, there is a significant difference in hardness among the coatings and it is shown in Table 5. Hardness profile as a function of cladding depth was measured for all prepared samples. Profiles of the samples are shown in Figure 7. The high hardness values of the WC particles in laser coating are manifested. The reason may be the minimal heat damage during laser cladding. Overall, the hardness of the cladding layer has significantly increased and the values are repeatable. The hardness of coated layers ranged from 580 to 870 HV0.2. It is much higher than that of the substrate (400-460 HV0.2). However, there is a significant difference in hardness among the coatings and it is shown in Table 5. Hardness profile as a function of cladding depth was measured for all prepared samples. Profiles of the samples are shown in Figure 7. The high hardness values of the WC particles in laser coating are manifested. The reason may be the minimal heat damage during laser cladding.  ANOVA analysis helped in finding the influence and contribution of process parameters in the study [27]. This analysis of laser speed, scanning speed and hardness of the coating was done with the help of Minitab 17.0 and are shown in Table 6.   ANOVA analysis helped in finding the influence and contribution of process parameters in the study [27]. This analysis of laser speed, scanning speed and hardness of the coating was done with the help of Minitab 17.0 and are shown in Table 6.  Table 6, it can be viewed that the p-value of the ANOVA is <0.001 [28]. This establishes the significance of the laser power and scanning speed on the variance of the hardness of the coating. The regression equation gives the relation between the input process parameter and yield parameter. The surface plot of hardness, laser speed, and scanning speed is shown in Figure 8a. The fit plot depicts that with the increasing scanning speed, hardness decreases ( Figure 8b) and with increasing laser power, it increases (Figure 8c).  Table 6, it can be viewed that the p-value of the ANOVA is <0.001 [28]. This establishes the significance of the laser power and scanning speed on the variance of the hardness of the coating. The regression equation gives the relation between the input process parameter and yield parameter. The surface plot of hardness, laser speed, and scanning speed is shown in Figure 8a. The fit plot depicts that with the increasing scanning speed, hardness decreases ( Figure 8b) and with increasing laser power, it increases (Figure 8c).

Wear Testing
Laser coated tungsten carbide has better wear resistance than the substrate. High hardness values of WC particles in laser cladding coating remains almost unchanged due to the loss of minimum heat during laser cladding. Wear testing was carried out with the help of a pin on disc setup (wear and friction monitoring machine TR-20) and is shown in Figure 9. The coated sample was attached to the rounded pin with the help of Araldite and left for 24 h. This pin was set up on the machine. This machine mainly contains a rotating disc of En 31. It is a good quality high carbon alloy steel having high hardness value with compressive strength and abrasion resistance. Compositions of En31 are C 0.9-1.2%, Si 0.1-0.35%, Mn 0.3-0.75%, S 0.05% max, P 0.05% max , Cr 1-1.6%, 0.05% max and the rest iron. A load of 1 kg was operating on the pin and disc was rotating at 350 rpm. The initial weight of the samples was recorded. All samples were tested for 1 min. After running of the pin on the disc, the weight of the pin was again noted. The differences in the weight give the wear of the samples. The substrate has the highest wear (loss in mass) 68 × 10 −5 gm/min. All coated samples were also tested. Coated samples provided better results than uncoated samples or

Wear Testing
Laser coated tungsten carbide has better wear resistance than the substrate. High hardness values of WC particles in laser cladding coating remains almost unchanged due to the loss of minimum heat during laser cladding. Wear testing was carried out with the help of a pin on disc setup (wear and friction monitoring machine TR-20) and is shown in Figure 9. The coated sample was attached to the rounded pin with the help of Araldite and left for 24 h. This pin was set up on the machine. This machine mainly contains a rotating disc of En 31. It is a good quality high carbon alloy steel having high hardness value with compressive strength and abrasion resistance. Compositions of En31 are C 0.9-1.2%, Si 0.1-0.35%, Mn 0.3-0.75%, S 0.05% max, P 0.05% max, Cr 1-1.6%, 0.05% max and the rest iron. A load of 1 kg was operating on the pin and disc was rotating at 350 rpm. The initial weight of the samples was recorded. All samples were tested for 1 min. After running of the pin on the disc, the weight of the pin was again noted. The differences in the weight give the wear of the samples. The substrate has the highest wear (loss in mass) 68 × 10 −5 gm/min. All coated samples were also tested. Coated samples provided better results than uncoated samples or substrate and it is visible in Figure 10. minimum heat during laser cladding. Wear testing was carried out with the help of a pin on disc setup (wear and friction monitoring machine TR-20) and is shown in Figure 9. The coated sample was attached to the rounded pin with the help of Araldite and left for 24 h. This pin was set up on the machine. This machine mainly contains a rotating disc of En 31. It is a good quality high carbon alloy steel having high hardness value with compressive strength and abrasion resistance. Compositions of En31 are C 0.9-1.2%, Si 0.1-0.35%, Mn 0.3-0.75%, S 0.05% max, P 0.05% max , Cr 1-1.6%, 0.05% max and the rest iron. A load of 1 kg was operating on the pin and disc was rotating at 350 rpm. The initial weight of the samples was recorded. All samples were tested for 1 min. After running of the pin on the disc, the weight of the pin was again noted. The differences in the weight give the wear of the samples. The substrate has the highest wear (loss in mass) 68 × 10 −5 gm/min. All coated samples were also tested. Coated samples provided better results than uncoated samples or substrate and it is visible in Figure 10.  ANOVA analysis of laser speed, scanning speed and wear rate of the coating. It was done with the help of Minitab 17.0. The detail report was shown in Table 7.   ANOVA analysis of laser speed, scanning speed and wear rate of the coating. It was done with the help of Minitab 17.0. The detail report was shown in Table 7.  ANOVA analysis of laser speed, scanning speed and wear rate of the coating. It was done with the help of Minitab 17.0. The detail report was shown in Table 7. The p-value of the ANOVA is <0.001, which confirms the significant effect of laser power and scanning speed have on the wear of the coating [29]. The surface plot of hardness, laser speed, and scanning speed was shown in Figure 11a. Wear of the cladding decreases with respect to an increase in laser power. It also increases with an increase in scanning speed. The fitted line plot gives similar results, i.e., with the increasing laser power wear of coating decreases (Figure 11b) and increases if the scanning speed increases (Figure 11c).

Desirability Test
Laser power and scanning speed contradict each other to the optimal setting of the input process parameter. The parameters are confounded in nature and it is difficult to achieve the optimal process parameters for better outcomes. The desirability function approach was used in this case. In this method, the translation of each response is carried out on a common scale. The desirability function ranges from 0 to 1 [30]. Therefore, the response feedback 'xi' is translated into possible values of xi in the desirability function Di (xi). In this experiment, desirability is to get the maximum hardness and minimum wear of the coating. Figure 12 shows the optimum parameter conditions required to achieve the desired outcome. In the graph, the x-axis is an input parameter (laser power, scanning speed) and the y-axis shows the desirability of the output parameter (wear rate and hardness).

Desirability Test
Laser power and scanning speed contradict each other to the optimal setting of the input process parameter. The parameters are confounded in nature and it is difficult to achieve the optimal process parameters for better outcomes. The desirability function approach was used in this case. In this method, the translation of each response is carried out on a common scale. The desirability function ranges from 0 to 1 [30]. Therefore, the response feedback 'xi' is translated into possible values of xi in the desirability function Di (xi).
In this experiment, desirability is to get the maximum hardness and minimum wear of the coating. Figure 12 shows the optimum parameter conditions required to achieve the desired outcome. In the graph, the x-axis is an input parameter (laser power, scanning speed) and the y-axis shows the desirability of the output parameter (wear rate and hardness). The results show that the maximum hardness and minimum wear rate are obtained at laser power 220.71 W and scanning speed 179.28 mm/min.

Correlation Test
A correlation test was done with the help of R software between the hardness and wear rate of the coating. There is a negative correlation between those parameters [31]. Spearman correlation test was carried out. This correlation provides the relation between two parameters in the form of a numerical value. The outcome of these correlations lies between −1 to 1. In this experiment, all hardness data and wear rate data fit into the R-software. The detail report was shown in Table 8. The correlation gives different types of results with Spearman (−0.9807163). These results show that there is a strong negative correlation between hardness and wear of the coating, indicating that The results show that the maximum hardness and minimum wear rate are obtained at laser power 220.71 W and scanning speed 179.28 mm/min.

Correlation Test
A correlation test was done with the help of R software between the hardness and wear rate of the coating. There is a negative correlation between those parameters [31]. Spearman correlation test was carried out. This correlation provides the relation between two parameters in the form of a numerical value. The outcome of these correlations lies between −1 to 1. In this experiment, all hardness data and wear rate data fit into the R-software. The detail report was shown in Table 8. The correlation gives different types of results with Spearman (−0.9807163). These results show that there is a strong negative correlation between hardness and wear of the coating, indicating that as the hardness of the coating increases its wear decreases and the vice-versa.

Conclusions
In this paper, a nano-WC powder was coated on the worn-out cutter ring (substrate) using the LSC process. Laser power and scanning speed are two major process control parameters that are used for the coating. Thirteen samples were prepared on the basis of CCD at different input parameters.
The results of the study confirm the following observations: • The laser cladding was performed at different values of the process control parameters provided a layered and uneven coating on the substrate.

•
Dendritic and needle type microstructures were formed and that shows the presence of WC on the cladding. Different types of deformities are present on the coating in the form of micro-holes, cracks, globules.

•
The hardness of coating layers varied from 580 to 870 HV0.2, which is much higher than that of the substrate (400-460 HV0.2). The microhardness increased due to strong bonding among the elements.

•
Wear of the substrate is 68 × 10 −5 (loss in mass) g/min whereas the wear of the coated samples lies between 4 to 41 × 10 −5 (loss in mass) g/min at different levels of process control parameters. • ANOVA depicts the crucial role of the major input parameters (laser power, scanning speed) on the response variables (hardness and wear).

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The desirability function provides the optimal response of input parameters on the yield parameters. It shows that maximum hardness and minimum wear rate are attained at laser power (220 W) and scanning speed (179 mm/min). • A negative correlation (Spearman rho = −0.9807163) was observed between the hardness values and the wear of the coating. This depicts that with the increase in hardness of coating wear decreases.
These results show that the coating of WC on the substrate is an effective approach for eco-friendly reuse and refurbishment of worn out cutter rings for enhanced cutter life. This has direct economic benefits in deploying TBM technologies for tunneling projects.
Author Contributions: All the authors contributed equally to the conception of the idea, implementing and analyzing the experimental results, and writing the manuscript. All authors have read and agreed to the published version of the manuscript.
Funding: This research received no external funding.