Current and Future Trends in Environmental Electrochemistry for Wastewater Treatment

In recent years, the demand for high-quality water has constantly been increasing, while at the same time, the legislations regarding wastewater reuse are becoming stricter [...]

time, the required energy was calculated as 0.25 kWh/m 3 of wastewater, and the cost equal to 0.423 USD/m 3 .Interestingly, the optimal conditions were also applied to real metallurgical industry wastewater instead of synthetic solutions and resulted in 94.2% Pb removal, confirming both the industrial application and the validity of the model used.
Several published works demonstrated the efficiency of the anodic electrochemical oxidation of different pharmaceutical compounds using different electrodes such as Dimensionally Stable Anodes (DSA) electrodes such as IrO 2 , SnO 2 [2,3,8], or non-active electrodes such as Boron Doped Diamond (BDD) [9].Despite the promising results, one of the biggest problems of electrochemical oxidation is the mass transfer limitations, hence the need for larger electrode surfaces, which significantly increases the cost.Various strategies have been proposed to address this problem.For example, some researchers suggest the use of 3D electrodes or the use of particle electrodes from relatively inexpensive materials [4] that will allow pollutants to oxidize over significantly larger surfaces.
Another approach is the work of Zwane et al. [10], which proposes the combination of electrochemical oxidation with the conventional Fenton process through the in situ electrosynthesis of hydrogen peroxide in a carbon felt cathode (Electro Fenton process).Indeed, the combined process showed better results than electrochemical oxidation by completely removing the pharmaceutical tetracycline in less than 30 min under optimal conditions, while the removal of total organic carbon reached 69% in 4 h using 0.05 mM Na 2 SO 4 as the supporting electrolyte at pH 3 and 120 mA current, while Ti 4 O 7 was served as the anode.Intermediate products, as well as the toxicity of the combined process, were also investigated.Toxicity decreased for both 20 and 50 mg/L Tetracycline solution using the bacteria Vibrio Fischeri as indicators Another combination of electrochemical oxidation with the Fenton process has also been investigated by Deng et al. [11] to treat industrial-pharmaceutical wastewater.The researchers followed an interesting approach.Instead of adding Fe 2+ iron salts, they studied the magnetically decorating zero-valent iron (ZVI) on a RuO 2 -IrO 2 /Ti electrode.In this way, zero-valent iron can be a constant source of Fe 2+ during electrochemical treatment.
By applying the maximum voltage (12 V), the proposed Electro-Fenton system based on ZVI-RuO 2 -IrO 2 /Ti electrode removed 78.69% of Chemical Oxygen Demand (COD) and 76.40% of Total Organic Carbon (TOC) in 12 h of treatment of pharmaceutical wastewater with initial COD 5500 mg/L.This efficiency was significantly higher than the experiments without zero-valent iron or hydrogen peroxide.At the same time, the proposed system removed 100% of the total phosphorus (TP) in 12 h using a lower voltage (3 V).Interestingly, the BOD/COD ratio was increased from 0.21 to 0.42, indicating that the proposed process could be used as pretreatment followed by a biological method.

Future Trends
In summary, electrochemistry remains particularly attractive for treating different types of non-biodegradable wastewater [12].Some processes, such as electrocoagulation, are quite close to many industrial applications, while others are several steps away from the widespread application.Nevertheless, future research should focus on optimizing the process and reducing costs, which can be achieved either by developing new reactors or combining them with other biological or physicochemical methods.At the same time, an important issue that is expected to concern the final users is the disposal of the produced sludge, especially in light of the circular economy and minimizing the total cost.On the other hand, in processes such as electrochemical oxidation, there are various future research directions, such as the development of new materials with increased activity or the combination with other processes, where the existence of synergy can significantly increase efficiency and, therefore, the viability of the combined or hybrid process.In all electrochemical applications, their coupling with renewable energy sources or even with microbial cells is expected in the future to lead to integrated systems with a significantly reduced environmental and energy footprint.