New Eco-Friendly Phosphorus Organic Polymers as Gas Storage Media

Three phosphate esters 1–3 were successfully synthesized from the reaction of 2-, 3- and 4-hydroxybenzaldehyde with phosphoryl chloride. Reactions of 1–3 with benzidine in the presence of glacial acetic acid gave the corresponding novel phosphorus organic polymers 4–6 containing the azomethane linkage. The structures of the synthesized compounds were confirmed by Fourier transform infrared spectroscopy, nuclear magnetic resonance and elemental analysis. Interesting physiochemical properties for the polymeric materials 4–6 were observed using a combination of several techniques such as gel permeation chromatography, scanning electron microscopy, Brunauer–Emmett–Teller and nitrogen adsorption–desorption isotherm, Barrett–Joyner–Halenda and H-sorb 2600 analyzer. The mesoporous polymers 4–6 exhibit tunable porosity with Brunauer–Emmett–Teller surface area (SABET = 24.8–30 m2·g–1), pore volume (0.03–0.05 cm3·g–1) and narrow pore size distribution, in which the average pore size was 2.4–2.8 nm. Polymers 4–6 were found to have high gas storage capacity and physico-chemical stability, particularly at a high pressure. At 323 K and 50 bars, polymers 4–6 have remarkable carbon dioxide uptake (up to 82.1 cm3·g–1) and a low hydrogen uptake (up to 7.4 cm3·g–1). The adsorption capacity of gasses for polymer 5 was found to be higher than those for polymers 4 and 6.


Introduction
Carbon dioxide (CO 2 ) emission levels in the atmosphere are increasing mainly as a result of high fossil fuel consumption. Carbon dioxide is considered one of the main greenhouse gases (GHG) which causes global warming [1][2][3][4][5][6][7][8]. This has led to climate changes such as flooding and droughts due to the changes in nature's equilibrium. Recently, research has been directed to find ways to capture GHGs such as CO 2 , which can reduce the efficiency and capacity of natural gas and lead to gas piping corrosion [9,10]. Various strategies have been developed to reduce CO 2 emission, one of the most common methods for capturing CO 2 followed by underground storage is known as carbon capture and storage (CCS) [11]. Therefore, the production of new materials that are not only capable of capturing CO 2 but also act as storage for clean energy is always of interest. The most common gas mixtures that require separation and capture technology are: natural gas, which is composed of

Instrumentation
The FT-IR spectra were recorded using Shimadzu 8400 spectrophotometer (400-4000 cm -1 ) using KBr disks technique. Proton nuclear magnetic resonance ( 1 H NMR; 400 MHz) spectra were recorded on a Bruker DRX400 NMR spectrometer (Zürich, Switzerland) in DMSO-d 6 . Elemental analyses were performed using Vario EL III Elementar instrument. Scanning electron microscopy (SEM) observations were carried out using a KYKY-EM3200 microscope (Ontario, CA, USA) at an accelerating voltage of 26 kV. The molecular weight was determined by gel permeation chromatography (GPC) using a Tosoh Bioscience GmbH EcoSEC HLC-8320GPC system (Tokyo, Japan). The system was equipped with a refractive index (RI) and an ultraviolet (UV) detector (λ = 280 nm) using a Tosoh TSK gel Alpha-4000 and 2000 columns (300 mm × 7.8 mm ID, Griesheim, Germany), with a particle size of 10 µm and a pore size of 450 Å that operated at 40 • C. Dimethylformamide (DMF) containing LiBr (10 mM) was used as the solvent at a flow rate of 1 mL/min. Calibration curves were obtained using polystyrene standards (Mn 2.89-500 × 10 6 g/mol).
Nitrogen (N 2 ) adsorption-desorption isotherms were recorded at 77 K using Quantchrome analyzer. The samples were dried at 200 • C under dry nitrogen flow for 5 h before measurement. The specific surface areas were calculated following the multipoint Brunauer-Emmett-Teller (BET) method. The pore volumes were determined at a relative pressure (P/P 0 ) of 0.98. The pore size distributions were verified by a Barrett-Joyner-Halenda (BJH) method. Gas uptake at 323 K and 50 bars were performed by H-sorb 2600 high pressure volumetric adsorption analyzer (Gold APP Instrument Corporation, Beijing, China). The gas adsorption analyzer has two degassing and analyzing ports that work simultaneously. A known amount of gas was dosed into the measurement tube containing the sample. When equilibrium between the sample and adsorbed gas was attained, a comprehensive final equilibrium pressure was automatically recorded using specialist software. The quantity of gas adsorbed was calculated from the data generated. The samples were degassed at 200 • C under dynamic vacuum for 5 h prior to the adsorption tests.

Synthesis of Phosphate Esters 1-3
To a stirred mixture of phosphoryl chloride (1.53 g, 10 mmol) and triethylamine (3.04 g, 30 mmol) in dry tetrahydrofuran (THF; 15 mL), in a dried three-necked round bottom flask (200 mL) fitted with a thermometer probe and mechanical stirrer, a solution of the appropriate hydroxybenzaldehyde (3.66 g, 30 mmol) in dry THF (15 mL) was added dropwise through a dropping funnel over a period of 20 min at 0 • C. The mixture was stirred at 40-45 • C for 5 h and then left to cool down to room temperature. The filtrate was collected by filtration and the solid, triethylamine hydrochloride, was washed with THF (3 × 25 mL). The combined THF was removed under reduced pressure to give the phosphate esters 1-3 as brownish oils in 71-77% yields.

Synthesis of Polymeric Schiff Bases 4-6
A mixture of phosphate esters 1-3 (8.21 g, 20 mmol) and benzidine (5.53 g, 30 mmol) in chloroform (25 mL) containing glacial acetic acid (0.5 mL) was stirred under reflux for 6 h. The mixture was left to cool to room temperature and the solid obtained was filtered, washed with chloroform (3 × 10 mL) and dried to give polymeric materials 4-6 as orange powders in 80-86% yields.

FT-IR Spectroscopy of Phosphate Esters 1-3
The FT-IR spectra of phosphate esters 1-3 show no hydroxyl groups absorption. The spectra show the presence of carbonyl groups (1681-1693 cm -1 ) and the P-O-C groups (1161-1188 cm -1 ) which is a clear indication that the esterification has taken place. The most common IR absorption bands for phosphate esters 1-3 are represented in Table 1 along with their elemental analyses.

1 H NMR Spectroscopy of Phosphate Esters 1-3
The structures of phosphate esters 1-3 were also confirmed by the 1 H NMR spectral data ( Table 2). They show singlet signals that resonate at 9.79-10.30 ppm region corresponding to the aldehyde proton. They also show the expected types of aromatic protons.

FT-IR Spectroscopy of Phosphate Polymers 4-6
The FT-IR spectra of 4-6 show the absence of the carbonyl groups which is a clear indication that the polymerization process of the phosphate esters 1-3 has taken place. The FT-IR spectra of 4-6 show the presence of absorption bands that appear at 1616-1635 cm -1 and can be attributed to the azomethane bands (C=N). Some of the most common and intense absorption bands in the FT-IR spectra for 4-6 are shown in Table 3.

FT-IR Spectroscopy of Phosphate Polymers 4-6
The FT-IR spectra of 4-6 show the absence of the carbonyl groups which is a clear indication that the polymerization process of the phosphate esters 1-3 has taken place. The FT-IR spectra of 4-6 show the presence of absorption bands that appear at 1616-1635 cm -1 and can be attributed to the azomethane bands (C=N). Some of the most common and intense absorption bands in the FT-IR spectra for 4-6 are shown in Table 3. Gel Permeation Chromatography is a good technique to evaluate the molecular weight distribution (MWD) of resins which plays a major role in characterizing the resins performance capacities such as cure speed, viscosity, green strength development, substrates penetration and adhesion [51]. Higher molecular oligomers usually have smaller pores in packing column and can be eluted faster with a small retention time. On the other hand, smaller molecular weight oligomers remain in the pores and eluted slowly with a longer retention time [52]. The GPC chromatograms of polymers 4-6 are represented in Figure 1. The number average molecular weight (Mn), weight average molecular weight (Mw) and polydispersity index (Dp) were calculated using Equations (1)-(3) [53] and represented in Table 4.
where ni is the number of molecules, Mi is the molecular weight, Ai is the area of slice i in which total area is A and hi is the peak height at each interval of molecular weight.

Scanning Electron Microscopy (SEM) of Phosphate Polymers 4-6
The morphologies, sizes of particles and porosity of phosphate polymers 4-6 were observed by SEM analysis. Higher magnification SEM images revealed the irregular morphology of 4-6 ( Figure 2) with a grain size that ranged from ten to hundreds of nanometers. The polymers were amorphous and mostly micro-sized particles in which their dimensions ranged 40.0-164.8, 28.4-805.9 and 29.8-598 nm for 4, 5 and 6, respectively. The SEM images demonstrate that the polymers consist of agglomerated particles arranged side by side which formed a topographical microporous structures, each particle gathered to form a clusters due to the high surface energy. The SEM images of polymers 4-6 exhibit a porous structure due to the azomethane C=N linked network (Figure 2).

Pure Gas Adsorption of Phosphate Polymers 4-6
The N 2 adsorption-desorption measurements were studied at 77 K to investigate the pore textural properties of polymers 4-6. The adsorption desorption isotherms of N 2 and pore size distribution curves for polymers 4-6 are shown in Figures 3-5.
The synthesized polymer networks 4-6 show Type-III nitrogen sorption isotherms, which has no identifiable monolayer formation. The adsorbent-adsorbate interactions also appear to be relatively weak and the adsorbed molecules are clustered around the most favorable sites on the surface [54] indicating that the polymers have mesoporous structures. The apparent surface area of 4-6, calculated from the Brunauer-Emmett-Teller (S BET ), were 27.514, 30.021 and 24.840 m 2 ·g -1 , respectively. Polymers 4-6 have pore volumes 0.036, 0.052 and 0.040 cm 3 ·g -1 , respectively ( Table 5).
The sorption of each polymer was studied at 323 K under 50 bars. The CO 2 and H 2 sorption isotherms of polymers 4-6 are shown in Figures 6-8 and the data were recorded in Table 6. There is no apparent adsorption-desorption hysteresis, indicating that CO 2 and H 2 can be reversibly adsorbed in the pores under the chosen temperature and pressure. Polymers 4-6 show a high CO 2 uptake. The CO 2 adsorption quantity was 10.2, 82.1 and 63.4 cm 3 ·g -1 for 4, 5 and 6, respectively (Table 5). Polymer 5 exhibits the highest BET surface area, total pore volume, H 2 storage and CO 2 uptake among tested polymers. Under the same condition, the polymers show low adsorption for H 2 as 4.0, 7.4 and 5.5 cm 3 ·g -1 , respectively. Such behavior is due to the unfavorable interactions between hydrogen and the polymers. The synthesized polymer networks 4-6 show Type-III nitrogen sorption isotherms, which has no identifiable monolayer formation. The adsorbent-adsorbate interactions also appear to be relatively weak and the adsorbed molecules are clustered around the most favorable sites on the surface [54] indicating that the polymers have mesoporous structures. The apparent surface area of 4-6, calculated from the Brunauer-Emmett-Teller (SBET), were 27.514, 30.021 and 24.840 m 2 ·g -1 , respectively. Polymers 4-6 have pore volumes 0.036, 0.052 and 0.040 cm 3 ·g -1 , respectively ( Table 5).
The sorption of each polymer was studied at 323 K under 50 bars. The CO2 and H2 sorption isotherms of polymers 4-6 are shown in Figures 6-8 and the data were recorded in Table 6. There is no apparent adsorption-desorption hysteresis, indicating that CO2 and H2 can be reversibly adsorbed in the pores under the chosen temperature and pressure. Polymers 4-6 show a high CO2 uptake. The CO2 adsorption quantity was 10.2, 82.1 and 63.4 cm 3 ·g -1 for 4, 5 and 6, respectively (Table 5). Polymer 5 exhibits the highest BET surface area, total pore volume, H2 storage and CO2 uptake among tested polymers. Under the same condition, the polymers show low adsorption for H2 as 4.0, 7.4 and 5.5 cm 3 ·g -1 , respectively. Such behavior is due to the unfavorable interactions between hydrogen and the polymers.   The synthesized polymer networks 4-6 show Type-III nitrogen sorption isotherms, which has no identifiable monolayer formation. The adsorbent-adsorbate interactions also appear to be relatively weak and the adsorbed molecules are clustered around the most favorable sites on the surface [54] indicating that the polymers have mesoporous structures. The apparent surface area of 4-6, calculated from the Brunauer-Emmett-Teller (SBET), were 27.514, 30.021 and 24.840 m 2 ·g -1 , respectively. Polymers 4-6 have pore volumes 0.036, 0.052 and 0.040 cm 3 ·g -1 , respectively ( Table 5).
The sorption of each polymer was studied at 323 K under 50 bars. The CO2 and H2 sorption isotherms of polymers 4-6 are shown in Figures 6-8 and the data were recorded in Table 6. There is no apparent adsorption-desorption hysteresis, indicating that CO2 and H2 can be reversibly adsorbed in the pores under the chosen temperature and pressure. Polymers 4-6 show a high CO2 uptake. The CO2 adsorption quantity was 10.2, 82.1 and 63.4 cm 3 ·g -1 for 4, 5 and 6, respectively (Table 5). Polymer 5 exhibits the highest BET surface area, total pore volume, H2 storage and CO2 uptake among tested polymers. Under the same condition, the polymers show low adsorption for H2 as 4.0, 7.4 and 5.5 cm 3 ·g -1 , respectively. Such behavior is due to the unfavorable interactions between hydrogen and the polymers.             . Adsorption-desorption isotherms of N2 and pore size distribution curve for 5. Figure 5. Adsorption-desorption isotherms of N2 and pore size distribution curve for 6. Figure 5. Adsorption-desorption isotherms of N 2 and pore size distribution curve for 6. Table 5. Surface area and porosity parameters of 4-6 obtained by the N 2 adsorption.

Polymers
S BET (m 2 ·g -1 ) a V total (cm 3     a The data were collected at 323 K and 50 bar; b The data were collected by volumetric H2 sorption method; c The data were collected by volumetric CO2 sorption method.         Three monomers with different geometrical configurations were selected as the building block to produce polymers 4-6, which have tetrahedral shape with sp 3 -hybridized phosphorus core. Linking the monomers with different geometries may tune the porosity and functionality of the synthesized polymeric materials [55]. Tetrahedral monomers are of interest since the porous polymers can be designed to possess high specific surface area that lack the flexibility to pack efficiently and leads to the facile formation of free volumes to promote the porosity [22,34,[55][56][57][58][59][60][61]. Three-dimensional polymers possess stronger sorption ability for CO2 compared to H2. The heteroatoms (oxygen, sulfur or nitrogen) in POPs were reported to play an important role in the efficient capture of polar gases and adsorption selectivity of CO2 over N2 or CH4 [62][63][64][65]. The CO2 uptake for the most common MOF materials is up to 18 wt % at different temperature and pressure [37,66]. However, the health and environmental impacts of such materials are questionable [67].
The efficiency of the synthesized polymers was found to follow the order 5 > 6 > 4. The difference in gas capture efficiency could be explained by the structure geometry of the building units for 4-6. The kinked geometry of 5 (meta-phosphate) and 6 (ortho-phosphate) could lead to a distorted networks compared to polymer 4 (para-phosphate) that has a relatively less distorted structure. The synthesized polymers are suitable for CO2 capture as a result of the high number of Lewis base sites. In addition, the interaction between polarized groups and gas molecules increases the CO2 uptake of 14 wt % at 50 bars. Moreover, the van der Waals interaction between the skeleton and weak nonpolar CO2 might be stronger compared to those between the skeleton and strong nonpolar H2.

Conclusions
Three novel 3D polymeric Schiff bases containing phosphate group were successfully synthesized in high yields. The chemical structures of the synthesized polymers were confirmed by FTIR, SEM, GPC, BET, BJH and H-sorb2600 analyzer. The analysis of N2 sorption isotherms reveal that the three polymers have type III isotherm and quite narrow pore size distribution. The pronounced affinity towards CO2 gas uptake was found to be high compared to that of H2 uptake at 323 K and 50 bars. The outstanding storage of CO2 gas endows these polymers a promising potential as efficient adsorbents in clean energy applications. Three monomers with different geometrical configurations were selected as the building block to produce polymers 4-6, which have tetrahedral shape with sp 3 -hybridized phosphorus core. Linking the monomers with different geometries may tune the porosity and functionality of the synthesized polymeric materials [55]. Tetrahedral monomers are of interest since the porous polymers can be designed to possess high specific surface area that lack the flexibility to pack efficiently and leads to the facile formation of free volumes to promote the porosity [22,34,[55][56][57][58][59][60][61]. Three-dimensional polymers possess stronger sorption ability for CO 2 compared to H 2 . The heteroatoms (oxygen, sulfur or nitrogen) in POPs were reported to play an important role in the efficient capture of polar gases and adsorption selectivity of CO 2 over N 2 or CH 4 [62][63][64][65]. The CO 2 uptake for the most common MOF materials is up to 18 wt % at different temperature and pressure [37,66]. However, the health and environmental impacts of such materials are questionable [67].
The efficiency of the synthesized polymers was found to follow the order 5 > 6 > 4. The difference in gas capture efficiency could be explained by the structure geometry of the building units for 4-6. The kinked geometry of 5 (meta-phosphate) and 6 (ortho-phosphate) could lead to a distorted networks compared to polymer 4 (para-phosphate) that has a relatively less distorted structure. The synthesized polymers are suitable for CO 2 capture as a result of the high number of Lewis base sites. In addition, the interaction between polarized groups and gas molecules increases the CO 2 uptake of 14 wt % at 50 bars. Moreover, the van der Waals interaction between the skeleton and weak nonpolar CO 2 might be stronger compared to those between the skeleton and strong nonpolar H 2 .

Conclusions
Three novel 3D polymeric Schiff bases containing phosphate group were successfully synthesized in high yields. The chemical structures of the synthesized polymers were confirmed by FTIR, SEM, GPC, BET, BJH and H-sorb2600 analyzer. The analysis of N 2 sorption isotherms reveal that the three polymers have type III isotherm and quite narrow pore size distribution. The pronounced affinity towards CO 2 gas uptake was found to be high compared to that of H 2 uptake at 323 K and 50 bars. The outstanding storage of CO 2 gas endows these polymers a promising potential as efficient adsorbents in clean energy applications.

Conflicts of Interest:
The authors declare no conflict of interest.