Thermal , Mechanical and UV-Shielding Properties of Poly ( Methyl Methacrylate ) / Cerium Dioxide Hybrid Systems Obtained by Melt Compounding

Thick and homogeneous hybrid film systems based on poly(methyl methacrylate) (PMMA) and CeO2 nanoparticles were synthesized using the melt compounding method to improve thermal stability, mechanical and UV-shielding properties, as well as to propose them for use in the multifunctional materials industry. The effect of the inorganic phase on these properties was assessed by using two different weight percentages of synthesized CeO2 nanoparticles (0.5 and 1.0 wt %) with the sol–gel method and thermal treatment at different temperatures (120, 235, 400, 600 and 800  ̋C). Thereafter, the nanoceria powders were added to the polymer matrix by single screw extrusion. The absorption in the UV region was increased with the crystallite size of the CeO2 nanoparticles and the PMMA/CeO2 weight ratio. Due to the crystallinity of CeO2 nanoparticles, the thermal, mechanical and UV-shielding properties of the PMMA matrix were improved. The presence of CeO2 Polymers 2015, 7 1639 nanostructures exerts an influence on the mobility of PMMA chain segments, leading to a different glass transition temperature.


Introduction
In the last years, there has been an increased tendency to use thermoplastic polymers such as polycarbonate (PC), polymethylmethacrylate (PMMA) and polyethylene-tetrafluoroethylene (PTFE) in diverse industrial applications due to their low weight and high transparency [1,2].PMMA is one of the most commonly used thermoplastic polymers in the construction industry because of its excellent optical properties (it transmits light in the 360-1000 nm range almost without loss [3]), impact and shatter properties (compared to inorganic glass), and relatively high weathering resistances.In addition, PMMA polymer has very low thermal conductivity (~0.0012 cal/s cm K), which makes it a candidate to be used as a thermal-control interface material [4,5].Unfortunately, PMMA and other polymers decompose or degrade under solar UV radiation (200-400 nm) [6].The most damaging natural UV radiation is between 290 and 350 nm where the highest energy of the solar spectrum occurs [7].The usage of inorganic UV absorbers can be a good alternative for the stability of thermoplastic polymers under weather conditions.Wide band-gap oxides such as titanium dioxide (TiO 2 ) and zinc oxide (ZnO) have been added as inorganic fillers into the PMMA matrix in order to modify its optical properties in the UV region [8][9][10][11][12].As one of the most versatile semiconductors, cerium dioxide (CeO 2 ) can be used as a solar absorber.CeO 2 has shown good thermal and chemical stabilities, a high refractive index in the visible region (2.1-2.2),good transmittance in the visible spectrum and low cost due to the fact that it is one of the most abundant rare earth elements [13][14][15].It has also potential applications such as in fuel and solar cells, catalysts, oxygen sensors, polishing agents, gate oxides, optical devices and coating materials [16][17][18].Moreover, due to its broad band gap (BG) of 2.7-3.4 eV, depending on the preparation method, effective absorption in the ultraviolet range can be ensured by this material (λ < 400 nm) [7,19].The incorporation of UV-shielding-nano CeO 2 into the PMMA polymer matrix can produce functional nanocomposites, which can be a better way of making effective solar-thermal-control-interface structures for delaying polymer degradation.Different techniques have been used for the preparation of CeO 2 , including coprecipitation, microemulsion, microwave-assisted thermal decomposition, combustion synthesis, and mechanochemical, sol-gel, hydrothermal, solvothermal and electrochemical methods [20][21][22].Among them, the sol-gel method has been widely used because it allows the synthesis of ultrafine powders with well-controlled properties such as homogeneity, purity, microstructure, particle size, and morphology, at relatively low cost [7,[23][24][25][26].
Based on the above, it is clear that the development of an interface displaying superior UV-NIR shielding for degradation control without losing its mechanical properties is in high demand.Recently, the use of PMMA/CeO 2 nanocomposites in the synthesis of a core/shell structure via the electrostatic interaction and polysiloxane@CeO 2 microspheres with multifunctional properties has been reported [13,27], but until now the effects of the crystallinity and amount of CeO 2 nanoparticles on the thermal stability, mechanical and UV-NIR-shielding properties of these structures have not been reported.In this paper, the preparation and characterization of UV-protective coatings composed of sol-gel-derived CeO 2 nanoparticles and dispersed in a PMMA polymer matrix by single screw extrusion are reported.The effect of different thermal treatments (120, 235, 400, 600 and 800 ˝C), crystallite sizes and nanoceria contents (0.5 and 1.0 wt %) on the optical, thermal and mechanical properties of PMMA are studied in detail.

Materials and Synthesis of CeO 2 Nanoparticles
CeO 2 nanoparticles were synthesized using the sol-gel method starting from cerium nitrate hexahydrate (Ce(NO 3 ) 3 ¨6H 2 O, Aldrich, ě98%, St. Louis, MS, USA) as precursor and ethanol (CH 3 CH 2 OH, Aldrich 99.5%,St. Louis, MS, USA) as solvent, using the following procedure: cerium nitrate was mixed with ethanol (0.3 M) at room temperature while it was vigorously stirred by means of a magnetic stirrer for 2 h to yield a stable and transparent sol without precipitation or turbidity.The pH was fairly constant during the synthesis process (pH « 6).The CeO 2 powders were obtained by gelification of the solutions and the gels drying at 120 ˝C for 24 h to remove organic matter; afterwards, the xerogel samples were ground in an agate mortar and then thermally treated in air at 235, 400, 600 and 800 ˝C for 2 h to study the structure and particle size effects.Finally, the powders were crushed by a horizontal ball mill at 350 rpm for 10 h.As is well known, the particle size distribution depends on various factors such as synthesis method, process parameters and in this case thermal treatment.Thus, the milling process was only used to uniform the particle size in each experiment before to obtain nanocomposites.

Preparation of Hybrid Systems
Commercial grade PMMA pellets (Plexiglas V825, Altuglas International, Arkema, Philadelphia, PA, USA) were used as raw material in this study.As first step, PMMA pellets were ground in a Thomas Wiley laboratory mill (Arthur H. Thomas Co., Philadelphia, PA, USA) using a 2 mm sieve to obtain fine particles.Thereafter, the polymeric particles were dried at 80 ˝C for 1 h before being processed.PMMA/CeO 2 hybrid systems were prepared by using a laboratory single-screw extruder (D = 19 mm, L/D = 30 mm) with three heating zones.Two different amounts of CeO 2 nanostructures (0.5 and 1.0 wt %) were added to the polymer matrix.The extruder blending temperature profiles were 235 and 240 ˝C from hopper to die zone, and the screw rotating speed was 80 rpm; finally, nanocomposite films extrudates were cooled in a water bath at room temperature.For comparison during the characterizations and performance of nanocomposites, pure PMMA were ground and extruded under the same process conditions.

Characterization and Measurements
The IR spectra of the CeO 2 nanoparticles and PMMA/CeO 2 hybrid systems were obtained within wavenumbers ranging from 4000 to 450 cm ´1 using a Spectrum One Perkin-Elmer spectrometer (Perkin-Elmer Life and Analytical Sciences, Bridgeport, CT, USA).Transmission IR experiments were carried out under environmental conditions with 10 scans at a resolution of 4 cm ´1.To determinate the interaction between the organic and inorganic phases, 1 H NMR and 13 C NMR spectra were carried out using a Bruker Ascend 750 (750 MHz) NMR spectrometer for liquids (Bruker Instruments, Inc., Billerica, MA, USA) at room temperature with deuterated chloroform (CDCl 3 , 1 H: δ = 7.26 ppm, Polymers 2015, 7 1641 13 C: δ = 77.0ppm, Sigma-Aldrich, 99.96%,St. Louis, MS, USA) as solvent and tetramethylsilane (TMS, δ = 0.00 ppm, Sigma-Aldrich, NMR grade, ě99.9%,St. Louis, MS, USA) as the internal reference.Crystalline phase identification of the CeO 2 powders and nanocomposites was performed using a D8 Advance Bruker X-ray diffractometer (Bruker AXS GmbH, Berlin, Germany) with Cu-Kα monochromatic radiation (Bruker AXS GmbH, Berlin, Germany).The XRD patterns were collected in the 2θ range from 10 to 90 ˝at room temperature.CeO 2 nanoparticles were examined by TEM using a JEOL-2000 FX-II microscope (JEOL Ltd., Akishima, Japan) coupled with an energy dispersive X-ray spectrometer (EDS, JEOL Ltd., Akishima, Japan) operating at 200 kV.Particle size distributions (PSD) were determined with a Malvern Zetasizer Nano ZSP (model ZEN5600, Malvern Instruments Ltd., Malvern Worcs, UK) by the dynamic light scattering (DLS) technique.A 12-mm round-aperture-glass cell (PCS8501, Malvern Instruments Ltd., Malvern Worcs, UK) was used for the DLS measurements.One milliliter of methanol dispersion sonicated for 5 min was added to the cell.The suitable refractive index was chosen for the CeO 2 samples and dispersant: 2.2 and 1.33, respectively.The distribution of nanoparticles within the polymer was observed by confocal laser scanning microscopy (CLSM) using a Carl ZEISS microscope (Carl Zeiss, Jena, Germany), LSM 700 model and high resolution scanning electron microscope (HRSEM) using a JEOL JSM-6701-F microscope (JEOL Ltd., Akishima, Japan).The fluorescence intensity measurements were performed using the built-in software ZEN of the LSM 710.The intensity peaks, characteristic of a fluorescence emission signal, were 461 nm for PMMA and 539 nm for the CeO 2 nanoparticles.The optical properties of the CeO 2 nanoparticles were analyzed by diffuse reflectance UV-vis spectroscopy using a Cary 5000 spectrophotometer (Agilent Technologies Inc., Santa Clara, CA, USA) with an Internal Diffuse Reflectance accessory (DR) consisting of a 110-mm-diameter-integrating sphere.Data were collected at a 600 nm/min scan rate with a data interval of 1.0 nm and signal-averaging time of 0.1 s in the 700-200 nm range.The optical transmission of the PMMA/CeO 2 hybrid systems was measured in the 200-1100 nm wavelength range using the same spectrometer.The thickness of the analyzed samples was about 0.5 mm.TGA studies were carried out using a Simultaneous Thermal Analyser Labsys Evo 1600 (SETARAM Instrumentation, Caluire, France).Samples were placed in aluminum crucibles.An empty aluminum crucible was used as reference.The heating ramp applied to the samples was from 25 to 450 ˝C at a constant heating rate of 5 ˝C/min under argon atmosphere.The nanoindentation data were analyzed with the CSM Instruments Nanoindentation Tester (TTX-NHT) with a Berkovich triangular diamond pyramid indenter (CSM Instruments SA, Peseux, Switzerland).Five indents were made in each sample.A loading rate of 15 mN/min was maintained until reaching a maximum load of 5 mN.The load was held at maximum value for 10 s.The hardness (H IT ), Vickers hardness (HV IT ), elastic modulus (E IT ) and creep (C IT ) were estimated from the initial gradient of the unloading curves using the Oliver and Pharr method [28].

FT-IR Analysis
The FT-IR spectra of CeO 2 nanoparticles thermally treated at different temperatures (400, 600 and 800 ˝C) are shown in Figure 1a.As a reference, FT-IR results for CeO 2 particles dried at 120 ˝C and thermally-treated at 235 ˝C were included in the figure.The spectrum of the CeO 2 xerogel (120 ˝C) shows a broad absorption band located in the region from 3600 to 3000 cm ´1 approximately, which corresponds to the -OH stretching vibration (water or ethanol), while the bands around 1632 and 1503 cm ´1 are associated with the H 2 O bending vibration [29], confirming the presence of residual physisorbed water.Moreover, the narrow and sharp band near 1384 cm ´1 is attributed to the presence of NO 3 ´groups [30].As it is evident, the absorption bands mentioned above decrease gradually until disappear with the increasing of treatment temperature.It is also seen that all the CeO 2 powders treated at different temperatures show a band in the 750-400 cm ´1 region, which is assigned to the Ce-O stretching vibration [31,32].Figure 1b shows the FT-IR spectra of the pure PMMA and PMMA/CeO 2 hybrid systems.For pure PMMA, the bands around 2996, 2952 (asymmetric) and 2844 cm ´1 (symmetric) are assigned to C-H stretching vibrations.The bending vibration bands of the methyl (-CH 3 ) group appeared at 1484 and 1436 cm ´1 in the FTIR spectra, whereas the deformation mode of the methylene (-CH 2 -) group appeared at 1387 cm ´1.In addition, the sharp and intense bands at 1728 and 753 cm ´1 are attributed to the stretching and out-of-plane-bending vibrations of the carbonyl (C=O) group, respectively [33].The PMMA/CeO 2 hybrid systems show absorption bands that matched well with pure PMMA, indicating a weak interaction between PMMA and CeO 2 nanoparticles.Furthermore, bands corresponding to the vibration absorption of CeO 2 nanoparticles are not observed owing to the incorporation of a low percentage of nanoparticles.It is worth to notice that to avoid altering the full transparency low percentages of CeO 2 were introduced (0.5 and 1.0 wt %).
Polymers 2015, 7 5 shows a broad absorption band located in the region from 3600 to 3000 cm −1 approximately, which corresponds to the -OH stretching vibration (water or ethanol), while the bands around 1632 and 1503 cm −1 are associated with the H2O bending vibration [29], confirming the presence of residual physisorbed water.Moreover, the narrow and sharp band near 1384 cm −1 is attributed to the presence of NO3 − groups [30].As it is evident, the absorption bands mentioned above decrease gradually until disappear with the increasing of treatment temperature.It is also seen that all the CeO2 powders treated at different temperatures show a band in the 750-400 cm −1 region, which is assigned to the Ce-O stretching vibration [31,32].Figure 1b shows the FT-IR spectra of the pure PMMA and PMMA/CeO2 hybrid systems.For pure PMMA, the bands around 2996, 2952 (asymmetric) and 2844 cm −1 (symmetric) are assigned to C-H stretching vibrations.The bending vibration bands of the methyl (-CH3) group appeared at 1484 and 1436 cm −1 in the FTIR spectra, whereas the deformation mode of the methylene (-CH2-) group appeared at 1387 cm −1 .In addition, the sharp and intense bands at 1728 and 753 cm −1 are attributed to the stretching and out-of-plane-bending vibrations of the carbonyl (C=O) group, respectively [33].The PMMA/CeO2 hybrid systems show absorption bands that matched well with pure PMMA, indicating a weak interaction between PMMA and CeO2 nanoparticles.Furthermore, bands corresponding to the vibration absorption of CeO2 nanoparticles are not observed owing to the incorporation of a low percentage of nanoparticles.It is worth to notice that to avoid altering the full transparency low percentages of CeO2 were introduced (0.5 and 1.0 wt %).

NMR Studies
Figure 2a shows the 1 H NMR spectra of pure PMMA and PMMA/CeO2 (0.5 and 1.0 wt %, 800 °C) hybrid systems.The peak at 3.60 ppm is related to the methoxy protons, and peaks at the 2.2-1.5 ppm range correspond to the methylene protons of PMMA.The α-methyl protons show peaks at 1.22, 1.01 and 0.83 ppm, which are attributed to the presence of triads of several tacticities: isotactic (mm), heterotactic (mr) and syndiotactic (rr).On the other hand, it can be observed that the addition of a small amount of CeO2 nanoparticles (0.5 and 1.0 wt %) to PMMA resulted in a low-field chemical shift of the peak at 1.59 ppm (-CH2-protons).This small chemical shift suggests the existence of electrostatic interactions

NMR Studies
Figure 2a shows the 1 H NMR spectra of pure PMMA and PMMA/CeO 2 (0.5 and 1.0 wt %, 800 ˝C) hybrid systems.The peak at 3.60 ppm is related to the methoxy protons, and peaks at the 2.2-1.5 ppm range correspond to the methylene protons of PMMA.The α-methyl protons show peaks at 1.22, 1.01 and 0.83 ppm, which are attributed to the presence of triads of several tacticities: isotactic (mm), heterotactic (mr) and syndiotactic (rr).On the other hand, it can be observed that the addition of a small amount of Polymers 2015, 7 1643 CeO 2 nanoparticles (0.5 and 1.0 wt %) to PMMA resulted in a low-field chemical shift of the peak at 1.59 ppm (-CH 2 -protons).This small chemical shift suggests the existence of electrostatic interactions in the interfacial region between PMMA and CeO 2 nanoparticles, which is proposed in Figure 3. 13 C NMR spectra of PMMA and the hybrid systems with 0.5 and 1.0 wt % of CeO 2 thermally treated at 800 ˝C are reported in Figure 2b.The resonance peaks between 22 and 16 ppm are assigned to the methyl group; peaks between 46 and 44 ppm are related to the backbone quaternary carbon; the peak at 51.86 ppm is due to the methoxy group; the peak at 54.47 ppm is associated with the backbone methylene group; and the peaks between 179 and 176 ppm are correlated to the PMMA carbonyl carbon.No modification in the chemical shift is observed with the addition of CeO 2 nanoparticles, indicating that no primary chemical bond occurred with the polymer.
Polymers 2015, 7 6 in the interfacial region between PMMA and CeO2 nanoparticles, which is proposed in Figure 3. 13 C NMR spectra of PMMA and the hybrid systems with 0.5 and 1.0 wt % of CeO2 thermally treated at 800 °C are reported in Figure 2b.The resonance peaks between 22 and 16 ppm are assigned to the methyl group; peaks between 46 and 44 ppm are related to the backbone quaternary carbon; the peak at 51.86 ppm is due to the methoxy group; the peak at 54.47 ppm is associated with the backbone methylene group; and the peaks between 179 and 176 ppm are correlated to the PMMA carbonyl carbon.No modification in the chemical shift is observed with the addition of CeO2 nanoparticles, indicating that no primary chemical bond occurred with the polymer.Polymers 2015, 7 6 in the interfacial region between PMMA and CeO2 nanoparticles, which is proposed in Figure 3. 13 C NMR spectra of PMMA and the hybrid systems with 0.5 and 1.0 wt % of CeO2 thermally treated at 800 °C are reported in Figure 2b.The resonance peaks between 22 and 16 ppm are assigned to the methyl group; peaks between 46 and 44 ppm are related to the backbone quaternary carbon; the peak at 51.86 ppm is due to the methoxy group; the peak at 54.47 ppm is associated with the backbone methylene group; and the peaks between 179 and 176 ppm are correlated to the PMMA carbonyl carbon.No modification in the chemical shift is observed with the addition of CeO2 nanoparticles, indicating that no primary chemical bond occurred with the polymer.Polymers 2015, 7 1644

Structural and Morphological Characterization
Figure 4a shows XRD patterns of the CeO 2 nanoparticles thermally treated at different temperatures.It can be observed that the CeO 2 powders treated at 120 ˝C exhibited low intensity broad peaks about 2θ = 28.5, 33.0, 47.5 and 56.3 ˝, which were assigned to the (111), ( 200), ( 220) and (311) planes, respectively, and correspond to the cubic fluorite crystal structure (ICDD 81-0792).It is clear that these reflection peaks become sharper and narrower with the increasing temperature up to 800 ˝C, indicating an increase in the average crystallite size and crystallinity of nanoceria powders.The peaks at 59.0 ˝(222), 69.3 ˝(400), 76.6 ˝(331), 79.0 ˝(420) and 88.4 ˝(422) also confirms the presence of the cubic phase.

Structural and Morphological Characterization
Figure 4a shows XRD patterns of the CeO2 nanoparticles thermally treated at different temperatures.It can be observed that the CeO2 powders treated at 120 °C exhibited low intensity broad peaks about 2θ = 28.5, 33.0, 47.5 and 56.3°, which were assigned to the (111), ( 200), ( 220) and (311) planes, respectively, and correspond to the cubic fluorite crystal structure (ICDD 81-0792).It is clear that these reflection peaks become sharper and narrower with the increasing temperature up to 800 °C, indicating an increase in the average crystallite size and crystallinity of nanoceria powders.The peaks at 59.0° (222), 69.3° (400), 76.6° (331), 79.0° (420) and 88.4° (422) also confirms the presence of the cubic phase.The crystallite size (t) of CeO2 was estimated from XRD patterns by applying the full-width at half-maximum (β) of the characteristic (111) peak in the Scherrer Equation [34]: where λ is the incident X-ray wavelength (1.54056 Å) and θβ is the diffraction angle for the (111) plane.
The average CeO2 crystallite diameters determined with the Scherrer Equation were about 5.5 ± 0.1, 8.6 ± 0.2, 8.8 ± 0.1, 29.3 ± 0.7 and 47.5 ± 1.1 nm for CeO2 powders at 120, 235, 400, 600 and 800 °C, respectively.The crystallite size increased along with the increasing-thermal-treatment temperature due to a typical diffusion effect.Figure 4b shows the XRD patterns of the PMMA/CeO2 hybrid systems.The diffraction pattern of pure PMMA shows a broad diffraction peak at 2θ = 14.5° with other two lower intensity signals centered at 2θ = 30.7 and 42.1°, as a result of the diffuse scattering of amorphous PMMA [35].The shape of the first main signal indicates the ordered packing of the polymer chains.The intensity and shape of the second signal are attributed to the effect inside the main chains [36].
The diffraction patterns of all PMMA/CeO2 hybrid systems show the first two signals observed in the pure PMMA, indicating that neither the presence of the nanoparticles nor the preparation process changes the orientation of the PMMA chains.The PMMA systems with CeO2 thermally treated at 600 °C (1.0 wt %)  The crystallite size (t) of CeO 2 was estimated from XRD patterns by applying the full-width at half-maximum (β) of the characteristic (111) peak in the Scherrer Equation [34]: where λ is the incident X-ray wavelength (1.54056 Å) and θ β is the diffraction angle for the (111) plane.The average CeO 2 crystallite diameters determined with the Scherrer Equation were about 5.5 ˘0.1, 8.6 ˘0.2, 8.8 ˘0.1, 29.3 ˘0.7 and 47.5 ˘1.1 nm for CeO 2 powders at 120, 235, 400, 600 and 800 ˝C, respectively.The crystallite size increased along with the increasing-thermal-treatment temperature due to a typical diffusion effect.Figure 4b shows the XRD patterns of the PMMA/CeO 2 hybrid systems.The diffraction pattern of pure PMMA shows a broad diffraction peak at 2θ = 14.5 ˝with other two lower intensity signals centered at 2θ = 30.7 and 42.1 ˝, as a result of the diffuse scattering of amorphous PMMA [35].The shape of the first main signal indicates the ordered packing of the polymer chains.The intensity and shape of the second signal are attributed to the effect inside the main chains [36].
The diffraction patterns of all PMMA/CeO 2 hybrid systems show the first two signals observed in the pure PMMA, indicating that neither the presence of the nanoparticles nor the preparation process changes the orientation of the PMMA chains.The PMMA systems with CeO 2 thermally treated at 600 ˝C (1.0 wt %) and 800 ˝C (0.5 and 1.0 wt %) display a strong tendency toward an amorphous structure with low-intensity peaks at 2θ = 28.5, 33.0, 47.5 and 56.3 ˝, which corresponds to the fcc structure of CeO 2 .
Polymers 2015, 7 1645 The lattice parameter was calculated from XRD patterns and the results confirmed that except for 120 ˝C, where a value of 5.4448 Å was obtained, a quite small change in the lattice parameter was observed with the thermal treatment: 5.4192 Å (235 ˝C), 5.4187 Å (400 ˝C), 5.4107 Å (600 ˝C) and 5.4127 Å (800 ˝C).It was determined that the lattice parameter showed a trend of expansion with the annealing temperature but the changing extent is moderately limited.The lattice distortion rate (∆a/a) was estimated to be between 0.60% and 0.013%.The highest distortion was obtained at 120 ˝C and is undoubtedly due to this temperature that some organic compounds or water or both can be still partially bonded with cerium powders.The formation of nanoceria powders by sol-gel contains complicated reactions; in the first instance, they began to nucleate into Ce(OH) 3 form, so the supplied energy during the sol-gel process and subsequent heat treatment must be enough for the complete conversion to Ce(OH) 4 nuclei and thereafter into CeO 2 nuclei via dehydration and subsequent growth of highly crystallized nanoceria.
TEM images of CeO 2 in bright field mode with their corresponding selected area electron diffraction pattern (SAEDP) are shown in Figure 5.The CeO 2 nanopowders exhibit a heterogeneous size and non-uniform shape with a high agglomeration degree.Indeed, a higher treatment temperature seems to increase the particle size.The images show that the CeO 2 powders thermally treated at 120 ˝C are constituted of aggregates with sizes between 0.1 and 0.2 µm and composed by crystals of about 1-5 nm in diameter.CeO 2 thermally treated at 235 ˝C shows aggregates between 0.2 and 0.3 µm with irregular smaller crystals of about 4-12 nm, while CeO 2 thermally treated at 400 ˝C consists of aggregates formed of nanocrystals with an average size of 5-13 nm.When the heat treatment of CeO 2 is increased to 600 ˝C, the resulting samples are 0.45-0.35µm aggregates with semispherical nanocrystal sizes around 4-22 nm.Likewise, CeO 2 thermally treated at 800 ˝C shows aggregates between 0.52-0.75µm constituted by nanocrystals of about 20-80 nm.The SAEDPs of CeO 2 thermally treated at different temperatures (120, 235, 400, 600 and 800 ˝C) show concentric rings, which also indicate the polycrystalline nature of the powder and that the crystallite size is on the nanoscale.The SAEDPs were indexed according to the ICDD card of face-centered cubic phase of CeO 2 .The mean crystal size values and the diffraction rings of SAED obtained in TEM images for CeO 2 matched well with XRD results.
From measurements of dynamic light scattering, different particle diameter moments (number-average diameter D n ; weight-average diameter D w and z-average diameter D z ) were calculated using Equations (2-4), and the polydispersity index (PDI) was determined using Equation ( 5): where n i is the number of CeO 2 nanoparticles with diameter D i .The particle size distributions (PSDs) for the samples are shown in Figure 6, whereas the obtained average particle size and calculated polydispersity index (PDI) are shown in Table 1.From these data, the CeO2 particle size was increased as the temperature varied from 120 to 400 °C.After this temperature, a decrease in the particle size was observed (600 and 800 °C).It is noteworthy to mention that the particle size distribution can be influenced by sonification and dispersant agent [37].Furthermore, the CeO2 powders have different particle sizes and therefore they can be considered as polydispersed systems (PDI > 1).In general, these results confirm the presence of agglomerated nanoparticles due to Van der Waals forces and their high surface energy.The particle size distributions (PSDs) for the samples are shown in Figure 6, whereas the obtained average particle size and calculated polydispersity index (PDI) are shown in Table 1.From these data, the CeO 2 particle size was increased as the temperature varied from 120 to 400 ˝C.After this temperature, a decrease in the particle size was observed (600 and 800 ˝C).It is noteworthy to mention that the particle size distribution can be influenced by sonification and dispersant agent [37].Furthermore, the CeO 2 powders have different particle sizes and therefore they can be considered as polydispersed systems (PDI > 1).In general, these results confirm the presence of agglomerated nanoparticles due to Van der Waals forces and their high surface energy.

Dispersion Analysis
Dispersion is the key factor that determines quality and properties of hybrid compounds [38].During the dispersion process two kinds of interaction can occur: (i) polymer filler interaction, adhesion of the polymer to the surface of the particles; and (ii) filler-filler interaction, where the particles interact to form aggregates. Figure 7 shows the 3D images revealing the CeO 2 nanoparticles' location within the PMMA.In these images, it can be observed that in all the PMMA/CeO 2 hybrid systems the nanoparticles tend to form agglomerates of different sizes and semispherical morphologies.According to Yang et al., the nanoparticles tend to form aggregates to reduce the surface energy due to their high surface energy and small size [39].It can also be observed that the CeO 2 nanoparticles thermally treated at 120, 235 and 400 ˝C show a uniform distribution within the PMMA matrix.In the PMMA/CeO 2 hybrid systems with nanoparticles thermally treated at 600 and 800 ˝C, a small quantity of nanoparticles can be seen because the fluorescence intensity decreases with the increasing crystal size.However, these last systems also show a uniform dispersion, which is a relevant aspect for increasing the thermal stability of the PMMA/CeO 2 hybrid systems.

Dispersion Analysis
Dispersion is the key factor that determines quality and properties of hybrid compounds [38].During the dispersion process two kinds of interaction can occur: (i) polymer filler interaction, adhesion of the polymer to the surface of the particles; and (ii) filler-filler interaction, where the particles interact to form aggregates. Figure 7 shows the 3D images revealing the CeO2 nanoparticles' location within the PMMA.In these images, it can be observed that in all the PMMA/CeO2 hybrid systems the nanoparticles tend to form agglomerates of different sizes and semispherical morphologies.According to Yang et al., the nanoparticles tend to form aggregates to reduce the surface energy due to their high surface energy and small size [39].It can also be observed that the CeO2 nanoparticles thermally treated at 120, 235 and 400 °C show a uniform distribution within the PMMA matrix.In the PMMA/CeO2 hybrid systems with nanoparticles thermally treated at 600 and 800 °C, a small quantity of nanoparticles can be seen because the fluorescence intensity decreases with the increasing crystal size.However, these last systems also show a uniform dispersion, which is a relevant aspect for increasing the thermal stability of the PMMA/CeO2 hybrid systems.8a-c).The samples were analyzed at different magnifications using both secondary electrons (SE) and backscattered electrons (BSE).The present morphology confirms that even with the tendency to form some aggregates with a very variable size, the shear stress during melt mixing separate the CeO 2 nanoparticles to obtain a good dispersion with an interaction type (i) throughout hydrodynamic forces; in such a case, the effectiveness is also distributed in the entire sample.SEM micrographs reveal that PMMA incorporates semispherical CeO 2 domains, which are an ideal physical form to improve polymer properties.
Polymers 2015, 7 12 800 °C (Figure 8a-c).The samples were analyzed at different magnifications using both secondary electrons (SE) and backscattered electrons (BSE).The present morphology confirms that even with the tendency to form some aggregates with a very variable size, the shear stress during melt mixing separate the CeO2 nanoparticles to obtain a good dispersion with an interaction type (i) throughout hydrodynamic forces; in such a case, the effectiveness is also distributed in the entire sample.SEM micrographs reveal that PMMA incorporates semispherical CeO2 domains, which are an ideal physical form to improve polymer properties.

Optical Properties
The Kulbeka-Munk Equation was used to obtain the accurate band gap energy of CeO2 nanoparticles (Eg).The reflectance data were converted to the absorption coefficient F(R∞) values using the following equation: where R∞ is the diffused reflectance at a given wavelength of an infinitely thick sample and where h is Planck's constant (6.626 × 10 −34 J s), C is the light speed (3.0 × 10 8 ms −1 ) and λ is the wavelength (nm) [40].The relationship between (F(R∞)hv) 2 and the photon energy of CeO2 nanoparticles thermally treated at different temperatures are shown in Figure 9.The indirect band gap energy (Eg) was obtained from the intersection of the extrapolated linear portion.The Eg values of the CeO2 powders thermally treated at 120, 235, 400, 600 and 800 °C were 3.40 ± 0.01, 3.34 ± 0.02, 3.33 ± 0.03, 3.40 ± 0.02 and 3.44 ± 0.01, respectively.It reveals that the Eg decreases with increasing the treatment temperature up to 400 °C and then a slight increase is observed with the powders treated at 600 and 800 °C .In addition, in the inset, (F(R∞)hv) 2 vs λ curves, it was found that all the CeO2 powders show a strong absorption band at 210-350 nm in the UV range originated from the charge-transfer between the O 2p and Ce 4f states in O 2− and Ce 4+ [41].UV shielding materials are generally expected to absorb UV light at less than 400 nm wavelengths, as obtained for the CeO2 nanoparticles thermally treated at different temperatures.
Transmission spectra in the UV-Vis region for pure PMMA and PMMA samples with 0.5 and 1.0 wt % CeO2 at different thermal-treatment temperatures are shown in Figure 10.It can be seen that the UV-Vis

Optical Properties
The Kulbeka-Munk Equation was used to obtain the accurate band gap energy of CeO 2 nanoparticles (E g ).The reflectance data were converted to the absorption coefficient 8 ) values using the following equation: where R 8 is the diffused reflectance at a given wavelength of an infinitely thick sample and where h is Planck's constant (6.626 ˆ10 ´34 J s), C is the light speed (3.0 ˆ10 8 ms ´1) and λ is the wavelength (nm) [40].The relationship between (F(R 8 )hv) 2 and the photon energy of CeO 2 nanoparticles thermally treated at different temperatures are shown in Figure 9.The indirect band gap energy (E g ) was obtained from the intersection of the extrapolated linear portion.The E g values of the CeO 2 powders thermally treated at 120, 235, 400, 600 and 800 ˝C were 3.40 ˘0.01, 3.34 ˘0.02, 3.33 ˘0.03, 3.40 ˘0.02 and 3.44 ˘0.01, respectively.It reveals that the E g decreases with increasing the treatment temperature up to 400 ˝C and then a slight increase is observed with the powders treated at 600 and 800 ˝C.In addition, in the inset, (F(R 8 )hv) 2 vs λ curves, it was found that all the CeO 2 powders show a strong absorption band at 210-350 nm in the UV range originated from the charge-transfer between the O 2p and Ce 4f states in O 2´a nd Ce 4+ [41].UV shielding materials are generally expected to absorb UV light at less than 400 nm wavelengths, as obtained for the CeO 2 nanoparticles thermally treated at different temperatures.
Transmission spectra in the UV-Vis region for pure PMMA and PMMA samples with 0.5 and 1.0 wt % CeO 2 at different thermal-treatment temperatures are shown in Figure 10.It can be seen that the UV-Vis absorption of the PMMA/CeO 2 nanocomposites increased with the CeO 2 nanoparticle content in the nanocomposite.The PMMA/CeO 2 hybrid system with nanoparticles thermally treated at 120 and 235 ˝C shows similar behavior with a transmittance decrease of about 22 and 40 percent (0.5 and 1.0 wt %) in comparison with pure PMMA.This strong decrease is primarily attributed to the organic matter present in CeO 2 as it was observed by FTIR, as a result of the low thermal-treatment temperatures.On the other hand, the PMMA/CeO 2 hybrid systems with 0.5 and 1.0 wt % CeO 2 thermally treated at 400 ˝C display a transmittance reduction of approximately 7-15 percent in comparison with pure PMMA, which are the most transparent systems.It can be noticed that of all the hybrid systems, nanocomposites with 0.5 wt % of CeO 2 at 400 ˝C showed the highest percentage of transmittance, whereas the PMMA with 1.0 wt % of CeO 2 treated at high temperatures (600 and 800 ˝C) showed lower values in comparison with systems formed by CeO 2 at 400 ˝C.The aforesaid is related to the formations of small crystalline domains embedded in the amorphous PMMA as well as crystal size growth with sintered temperature.Figure 11 shows photographs of these films, where it is evident that even the presence of a small percentage of CeO 2 leads opacity or turbidity due to the fact that the agglomerated CeO 2 nanoparticles act as a strong scattering center.This point also suggests that the UV shielding properties of the hybrid films are mainly due to the scattering of these agglomerates in the film.As it was mentioned, the particles agglomeration enhanced with the thermal treatment and crystallite size; however, the aggregates are homogeneously distributed within the polymeric matrix.
Polymers 2015, 7 13 nanocomposite.The PMMA/CeO2 hybrid system with nanoparticles thermally treated at 120 and 235 °C shows similar behavior with a transmittance decrease of about 22 and 40 percent (0.5 and 1.0 wt %) in comparison with pure PMMA.This strong decrease is primarily attributed to the organic matter present in CeO2 as it was observed by FTIR, as a result of the low thermal-treatment temperatures.On the other hand, the PMMA/CeO2 hybrid systems with 0.5 and 1.0 wt % CeO2 thermally treated at 400 °C display a transmittance reduction of approximately 7-15 percent in comparison with pure PMMA, which are the most transparent systems.It can be noticed that of all the hybrid systems, nanocomposites with 0.5 wt % of CeO2 at 400 °C showed the highest percentage of transmittance, whereas the PMMA with 1.0 wt % of CeO2 treated at high temperatures (600 and 800 °C) showed lower values in comparison with systems formed by CeO2 at 400 °C.The aforesaid is related to the formations of small crystalline domains embedded in the amorphous PMMA as well as crystal size growth with sintered temperature.Figure 11 shows photographs of these films, where it is evident that even the presence of a small percentage of CeO2 leads opacity or turbidity due to the fact that the agglomerated CeO2 nanoparticles act as a strong scattering center.This point also suggests that the UV shielding properties of the hybrid films are mainly due to the scattering of these agglomerates in the film.As it was mentioned, the particles agglomeration enhanced with the thermal treatment and crystallite size; however, the aggregates are homogeneously distributed within the polymeric matrix.Likewise, spectra of pure PMMA and PMMA/CeO2 nanocomposites show an absorption band at about 272 nm, which is attributed to the n-π* transition of the C=O group in the PMMA [42].This band is attenuated with the incorporation of CeO2 treated at different temperatures causing a significant decrease in transmittance in the 250-360 nm range, which can be associated with the band-gap absorption of CeO2.In general, the synthetic polymers are susceptible to degradation by UV and visible light; specifically, the photodegradation of PMMA took place by irradiation between 260 and 300 nm [43].The transmitting efficiency of the PMMA/CeO2 hybrid systems in the UV band up to 350 nm is approximately zero, demonstrating that such hybrid systems are a good option for exterior applications.Likewise, spectra of pure PMMA and PMMA/CeO 2 nanocomposites show an absorption band at about 272 nm, which is attributed to the n-π* transition of the C=O group in the PMMA [42].This band is attenuated with the incorporation of CeO 2 treated at different temperatures causing a significant decrease in transmittance in the 250-360 nm range, which can be associated with the band-gap absorption of CeO 2 .In general, the synthetic polymers are susceptible to degradation by UV and visible light; specifically, the photodegradation of PMMA took place by irradiation between 260 and 300 nm [43].The transmitting efficiency of the PMMA/CeO 2 hybrid systems in the UV band up to 350 nm is approximately zero, demonstrating that such hybrid systems are a good option for exterior applications.
Likewise, spectra of pure PMMA and PMMA/CeO2 nanocomposites show an absorption band at about 272 nm, which is attributed to the n-π* transition of the C=O group in the PMMA [42].This band is attenuated with the incorporation of CeO2 treated at different temperatures causing a significant decrease in transmittance in the 250-360 nm range, which can be associated with the band-gap absorption of CeO2.In general, the synthetic polymers are susceptible to degradation by UV and visible light; specifically, the photodegradation of PMMA took place by irradiation between 260 and 300 nm [43].The transmitting efficiency of the PMMA/CeO2 hybrid systems in the UV band up to 350 nm is approximately zero, demonstrating that such hybrid systems are a good option for exterior applications.

Thermal Studies
Different studies have been performed on the different steps involved in the thermal degradation of PMMA.According to Kashiwagi et al. [44], the bond dissociation energy of H-H linkages is estimated to be less than that of the C-C backbone bond due to the large steric hindrance and inductive effect of vicinal ester groups.The first degradation step (155-220 °C) is initiated by scissions of head-to-head linkages (H-H).Likewise, PMMA chains having unsaturated end group are less thermally stable than those with saturated end groups.Therefore, the second step (230-300 °C) is initiated by scissions at unsaturated ends involving a hemolytic scission β to the vinyl group and the last step (>300 °C) is initiated by random scission within the main polymer chain.Typical TGA and derivative thermogravimetry (DTG) results on PMMA and PMMA/CeO2 hybrid materials degraded under argon atmosphere are shown in Figure 12.In Figure 12a, it can be observed that the pure PMMA shows appreciable weight loss at around 240 °C, while the PMMA/CeO2 nanocomposites show detectable weight loss at 320 °C.It is also evident that the stability of the nanocomposites is enhanced with the thermal treatment applied to CeO2 nanopowders.Particularly, PMMA/CeO2 hybrid systems with 0.5-1.0wt % CeO2 thermally treated at 120 °C began to show a weight loss below 250 °C.Underneath to 200 °C the weight loss is commonly referred to removal of water and organic components from the structure, whereas between 200 and 300 °C corresponds to nitrates decomposition and carbonization of organic parts of the precursor [45].Furthermore, a single broad loss, extending from 320 to about 450 °C, is observed for all nanocomposites.From Figure 12a, data were taken for the onset temperature at which 10% (T0.1) and 50% (T0.5)degradation occurs and the corresponding temperature difference (ΔT) between the onset temperatures of hybrid systems and PMMA (Table 2).Evidently, the onset degradation temperatures of PMMA/CeO2 hybrid systems shift to higher temperatures in comparison with that of pure PMMA, independently of the CeO2 thermal-treatment temperature and content, indicating that the CeO2 nanocrystals can significantly improve the thermal stability of the polymer.As seen in Figure 12b, it is confirmed that the temperature at maximum degradation rate increases largely from 273 °C for pure PMMA to 365 °C for all the PMMA/CeO2 nanocomposites.Although the CeO2 nanoparticles are agglomerated within the PMMA, their homogeneous presence play an important role enhancing the thermal stability of PMMA as a result of the mobility restriction of polymer chains near their interfaces due to the steric hindrance, hindering the out-diffusion of the volatile decomposition products [46,47].

Thermal Studies
Different studies have been performed on the different steps involved in the thermal degradation of PMMA.According to Kashiwagi et al. [44], the bond dissociation energy of H-H linkages is estimated to be less than that of the C-C backbone bond due to the large steric hindrance and inductive effect of vicinal ester groups.The first degradation step (155-220 ˝C) is initiated by scissions of head-to-head linkages (H-H).Likewise, PMMA chains having unsaturated end group are less thermally stable than those with saturated end groups.Therefore, the second step (230-300 ˝C) is initiated by scissions at unsaturated ends involving a hemolytic scission β to the vinyl group and the last step (>300 ˝C) is initiated by random scission within the main polymer chain.Typical TGA and derivative thermogravimetry (DTG) results on PMMA and PMMA/CeO 2 hybrid materials degraded under argon atmosphere are shown in Figure 12.
In Figure 12a, it can be observed that the pure PMMA shows appreciable weight loss at around 240 ˝C, while the PMMA/CeO 2 nanocomposites show detectable weight loss at 320 ˝C.It is also evident that the stability of the nanocomposites is enhanced with the thermal treatment applied to CeO 2 nanopowders.Particularly, PMMA/CeO 2 hybrid systems with 0.5-1.0wt % CeO 2 thermally treated at 120 ˝C began to show a weight loss below 250 ˝C.Underneath to 200 ˝C the weight loss is commonly referred to removal of water and organic components from the structure, whereas between 200 and 300 ˝C corresponds to nitrates decomposition and carbonization of organic parts of the precursor [45].Furthermore, a single broad loss, extending from 320 to about 450 ˝C, is observed for all nanocomposites.From Figure 12a, data were taken for the onset temperature at which 10% (T 0.1 ) and 50% (T 0.5 ) degradation occurs and the corresponding temperature difference (∆T) between the onset temperatures of hybrid systems and PMMA (Table 2).Evidently, the onset degradation temperatures of PMMA/CeO 2 hybrid systems shift to higher temperatures in comparison with that of pure PMMA, independently of the CeO 2 thermal-treatment temperature and content, indicating that the CeO 2 nanocrystals can significantly improve the thermal stability of the polymer.As seen in Figure 12b, it is confirmed that the temperature at maximum degradation rate increases largely from 273 ˝C for pure PMMA to 365 ˝C for all the PMMA/CeO 2 nanocomposites.Although the CeO 2 nanoparticles are agglomerated within the PMMA, their homogeneous presence play an important role enhancing the thermal stability of PMMA as a result of the mobility restriction of polymer chains near their interfaces due to the steric hindrance, hindering the out-diffusion of the volatile decomposition products [46,47].The glass transition temperature is generally taken as the inflection point of the specific heat increment at the glass-rubber transition in DSC experiments.Figure 13 shows the effect of CeO2 nanoparticles on the Tg of the PMMA/CeO2 hybrid systems measured by DSC.It can be seen that the incorporation of low contents of CeO2 nanocrystals (0.5 and 1.0 wt %) thermally treated at different temperatures slightly increased the glass transition temperature up to ~125 °C in comparison with pure PMMA ~121 °C.In agreement with previous reports with other composites [33,48], the trend of the glass transition shifting to a slightly higher temperature is attributed to the electrostatic interactions between the PMMA matrix side chain and CeO2, which hinder the rotation of polymeric chains, leading to increased Tg.The glass transition temperature is generally taken as the inflection point of the specific heat increment at the glass-rubber transition in DSC experiments.Figure 13 shows the effect of CeO 2 nanoparticles on the T g of the PMMA/CeO 2 hybrid systems measured by DSC.It can be seen that the incorporation of low contents of CeO 2 nanocrystals (0.5 and 1.0 wt %) thermally treated at different temperatures slightly increased the glass transition temperature up to ~125 ˝C in comparison with pure PMMA ~121 ˝C.In agreement with previous reports with other composites [33,48], the trend of the glass transition shifting to a slightly higher temperature is attributed to the electrostatic interactions between the PMMA matrix side chain and CeO 2 , which hinder the rotation of polymeric chains, leading to increased T g .

Hardness Tests
Figure 14 shows typical load-displacement curves obtained in the nanoindentation tests for pure PMMA and PMMA/CeO2 hybrid systems.It is clear that the addition of CeO2 nanoparticles within PMMA increases the mechanical properties with decreasing penetration depths.For example, for pure PMMA, the maximum indentation depth at maximum load (5 mN) was 1049 nm, whereas with 0.5 and 1.0 wt % CeO2 thermally treated at 800 °C, the maximum depth was about 874 and 832 nm, respectively.
The hardness (HIT), Vickers hardness (HVIT), elastic modulus (EIT) and creep (CIT) results for pure polymer and PMMA/CeO2 hybrid systems are presented in Table 3.As expected, the HIT and HVIT values were increased with nanoceria powders content from 0.5 to 1.0 wt % as well as with thermal treatment temperature, due to average crystal size and crystallinity of CeO2 nanoparticles.Elastic modulus in the best case (treated samples at 235 and 400 °C) enhanced up to 24%, although no clear trend was observed.In general, a decrease in creep displacement has been observed in PMMA/CeO2 hybrid systems with increasing CeO2 content, showing that the incorporation of rigid CeO2 nanocrystals improves the creep resistance.Finally, the time-dependent deformation of the composites under the applied load was in the range of 2.46%-7.48%.In a previous study, similar HIT and EIT increments were observed in PMMA nanocomposites with ZrO2 nanoparticles prepared by melt blending and ZnO nanoparticles synthesized by spin coating [49,50].This mechanical enhancement is a result of a homogenous dispersion of aggregates combined with an increase in crystallinity of the nanoparticles.Thus, the overall hardness results of as-prepared samples indicate that the PMMA/CeO2 hybrid systems provide greater stiffness than pure PMMA and therefore are less ductile.

Hardness Tests
Figure 14 shows typical load-displacement curves obtained in the nanoindentation tests for pure PMMA and PMMA/CeO 2 hybrid systems.It is clear that the addition of CeO 2 nanoparticles within PMMA increases the mechanical properties with decreasing penetration depths.For example, for pure PMMA, the maximum indentation depth at maximum load (5 mN) was 1049 nm, whereas with 0.5 and 1.0 wt % CeO 2 thermally treated at 800 ˝C, the maximum depth was about 874 and 832 nm, respectively.
The hardness (H IT ), Vickers hardness (HV IT ), elastic modulus (E IT ) and creep (C IT ) results for pure polymer and PMMA/CeO 2 hybrid systems are presented in Table 3.As expected, the H IT and HV IT values were increased with nanoceria powders content from 0.5 to 1.0 wt % as well as with thermal treatment temperature, due to average crystal size and crystallinity of CeO 2 nanoparticles.Elastic modulus in the best case (treated samples at 235 and 400 ˝C) enhanced up to 24%, although no clear trend was observed.In general, a decrease in creep displacement has been observed in PMMA/CeO 2 hybrid systems with increasing CeO 2 content, showing that the incorporation of rigid CeO 2 nanocrystals improves the creep resistance.Finally, the time-dependent deformation of the composites under the applied load was in the range of 2.46%-7.48%.In a previous study, similar H IT and E IT increments were observed in PMMA nanocomposites with ZrO 2 nanoparticles prepared by melt blending and ZnO nanoparticles synthesized by spin coating [49,50].This mechanical enhancement is a result of a homogenous dispersion of aggregates combined with an increase in crystallinity of the nanoparticles.Thus, the overall hardness results of as-prepared samples indicate that the PMMA/CeO 2 hybrid systems provide greater stiffness than pure PMMA and therefore are less ductile.nanoparticles varies from 10% to 19% in the 250-350 nm region, whereas it was close to zero with 1.0 wt %.Thus, only samples PMMA/CeO 2 with 0.5 wt % of nanoparticles sintered at 400 ˝C showed a balance between UV absorption, color of the material and transparency, which is a necessary condition for building applications.Nevertheless, the other systems that displayed excellent UV-shielding properties are expected to be applied in multifunctional materials industry.
The addition of nanoceria powders increases the degradation and glass transition temperatures of PMMA, independently of the thermal treatment temperature and CeO 2 content, which was the result of a homogeneous dispersion of the aggregates and the restriction of mobility of polymer chains.Nanoindentation revealed that the hardness and elastic modulus increase with raising the particle contents and thermal treatment temperature.Finally, these results demonstrate that the crystalline CeO 2 particles are useful fillers to increase the mechanical properties of PMMA.

Figure 1 .
Figure 1.FT-IR spectra of (a) CeO2 thermally treated at different temperatures and (b) pure PMMA and PMMA/CeO2 hybrid systems.

Figure 1 .
Figure 1.FT-IR spectra of (a) CeO 2 thermally treated at different temperatures and (b) pure PMMA and PMMA/CeO 2 hybrid systems.

Figure 3 .
Figure 3. Proposed interaction between the PMMA matrix and CeO2 nanoparticles.

Figure 2 .
Figure 2. NMR spectra of pure PMMA and PMMA/CeO 2 hybrid systems by (a) 1 H NMR and (b) 13 C NMR.

Figure 3 .
Figure 3. Proposed interaction between the PMMA matrix and CeO2 nanoparticles.Figure 3. Proposed interaction between the PMMA matrix and CeO 2 nanoparticles.

Figure 3 .
Figure 3. Proposed interaction between the PMMA matrix and CeO2 nanoparticles.Figure 3. Proposed interaction between the PMMA matrix and CeO 2 nanoparticles.

Figure 4 .
Figure 4. XRD patterns of (a) nanocrystalline CeO2 powders thermally treated at different temperatures and (b) pure PMMA and PMMA/CeO2 hybrid systems.

Figure 4 .
Figure 4. XRD patterns of (a) nanocrystalline CeO 2 powders thermally treated at different temperatures and (b) pure PMMA and PMMA/CeO 2 hybrid systems.

Figure 5 .
Figure 5. TEM images and SAEDPs of nanocrystalline CeO 2 powders thermally treated at different temperatures.

9 .
Kubelka-Munk modified spectra and their equivalence in hν vs λ (insert) of CeO 2 powders thermally treated at different temperatures.

Figure 11 .
Figure 11.Photographs of the pure PMMA and PMMA/CeO 2 hybrid systems.

Figure 13 .
Figure 13.DSC thermograms of the pure PMMA and PMMA/CeO 2 hybrid systems.

Table 1 .
Particle size distribution of the as-prepared CeO2 powders.

120 °C CeO2 235 °C CeO2 400 °C CeO2 600 °C CeO2 800 °C Size d, nm Mean number % Size d, nm Mean number % Size d, nm Mean number % Size d, nm Mean number % Size d, nm
Figure 6.Size distribution of CeO 2 thermally treated at different temperatures.

Table 1 .
Particle size distribution of the as-prepared CeO 2 powders.

Table 2 .
Onset and difference temperatures (°C) at 10 and 50 wt % loss of pure PMMA and PMMA/CeO2 hybrid systems.

Table 2 .
Onset and difference temperatures ( ˝C) at 10 and 50 wt % loss of pure PMMA and PMMA/CeO 2 hybrid systems.