Immobilization of Poly(1,1-dimethysilacyclobutane) by Means of Anionic Ring-opening Polymerization on Organic Nanoparticles and Reinvestigation of Crystallization

In the present study, the synthesis of poly(1,1-dimethylsilacyclobutane) (PDMSB) by anionic ring opening polymerization (ROP) is reinvestigated, leading to narrowly distributed molar masses (polydispersities 1.04–1.15) in the range of 2.3 to 60 kg mol −1. Investigations of thermal behavior for low molar mass PDMSB revealed an untypical multiple peaks melting phenomenon, which at first glance, seems to be of the same origin as low molar mass poly(ethylene oxide)s. Small angle X-ray scattering (SAXS) and X-ray diffraction (XRD) measurements are done, proving the fast crystallization and subsequent recrystallization for investigated low molar mass samples. Synthetic attempts are expanded to the surface-initiated anionic ROP of 1,1-dimethylsilacyclobutane (DMSB) monomer from the surface of cross-linked polystyrene (PS) nanoparticles. Novel polycarbosilanes (PCS)/organic core/shell particles are obtained, which are investigated by using transmission electron microscopy (TEM) and dynamic light scattering (DLS) experiments. First insights into the crystallization behavior 285 of surface-attached PDMSB chains reveal that crystallization seems to be hindered.


Introduction
Polycarbosilanes (PCS) gained considerable attention in the last two decades, due to their interesting optoelectronic and heat-resistant applications, but most important are applications as oxygen-free ceramic precursors [1][2][3][4][5].Recently, ordered mesoporous non-oxide materials [6], silicon carbide fibers [7] and ceramic foams [8] could be obtained by the so-called polymer precursor route of PCS and metal-substituted PCS derivatives after pyrolysis [9].There are various synthetic routes for controlling the PCS structure, which is unambiguously important for pursued ceramic materials with sufficient ceramic yields.Strategies range from Kumada rearrangement of silanes [10], Grignard coupling [11][12][13] to Pt(0)-catalyzed ring opening polymerization (ROP) of cyclic carbosilanes [9,14].The latter method has the advantage that well-defined hyperbranched materials can be obtained with high ceramic yields after pyrolysis.A postmodification of more intensively investigated polymers, e.g., polyisoprene or poly(ethylene oxide) (PEO) and also unsaturated PCS via hydrosilylation is a feasible strategy to introduce pendant side groups with additional functionalities [15][16][17][18][19][20].The above mentioned synthetic strategies suffer from the disadvantages that well-defined PCS with respect to narrowly distributed high molar masses cannot be obtained, as well as it is impossible to gain block copolymer structures.Amongst all synthetic protocols, anionic polymerization-especially anionic ROP-has several advantages and enables one to synthesize various block copolymers (BC) with precise control over block compositions, a well-defined constitution and narrowly distributed molar masses.Fascinating microstructures for manifold applications are accessible via self-assembly of such polymers [21].For example, well-defined BCs consisting of polyisoprene and polymers with laterally bonded alkyl-silane groups were recently prepared by sequential anionic polymerization and have been used as membranes for gas separation applications [22].The anionic ring opening polymerization (ROP) of ring-strained cyclic silanes, carbosilanes and metal-containing carbosilanes has also been reported and lead to well-defined polymers [23][24][25][26][27][28][29][30][31][32].Out of all cyclic carbosilanes, 1,1-dimethylsilacyclobutane (DMSB) is a well-known monomer, due to its convenient chemical and also commercial availability.The anionic ROP of DMSB leads to constitutional well-defined crystallizable polymers.Furthermore, it is reported that polymerization in a polar solvent, such as tetrahydrofuran (THF), at low temperature forces results in poly(1,1-dimethylsilacyclobutane) (PDMSB) chains precipitating during the polymerization and, hence, a loss of the "living" nature of the chains occurs, hampering the possibility of BC formation [33,34].In spite of those obstacles, PDMSB-containing block copolymers with polystyrene (PS) have been synthesized by Kim et al. using a slightly modified synthetic protocol [35].Fascinating BC structures with PS have been obtained after BC self-assembly, and even after subsequent pyrolysis, highly-ordered ceramic structures could be maintained.The synthesis and microphase separation of BCs consisting of PDMSB and various ferrocene-containing polymers have also been reported [36].In the present study, we firstly synthesize and investigate PDMSB homopolymers obtained by anionic ROP, and results are compared to previously reported studies.Absolute molar masses, which are determined via multi-angle laser light scattering size exclusion chromatography (SEC-MALLS) measurements, are varied in the range of 2.3 kg mol −1 to 60 kg mol −1 , with low polydispersities for every sample (polydispersity index (PDI) values range from 1.04 to 1.15).The thermal behavior of PDMSB is reinvestigated by differential scanning calorimetry (DSC) measurements revealing two melting peaks, but only one crystallization peak for PDMSB chains with low molar masses.Prima facie, this crystallization behavior seems similar to studies with poly(ethylene oxide)s [37].Small angle X-ray scattering (SAXS) and X-ray diffraction (XRD) are applied to ascertain whether this untypical crystallization behavior is based on two different crystal forms of PDMSB or caused by lamellar thickening of the investigated samples.PDMSB seems to be an excellent candidate for studying the crystallization of anchored polymers influenced on a curved substrate, due to its distinct and rapid crystallization.Thus, our attempts are expanded to the surface-initiated anionic ROP on the surface of cross-linked PS nanoparticles to gain PCS/organic core/shell particles.The PCS-grafted particles are characterized by using transmission electron microscopy (TEM), while dynamic light scattering (DLS) is applied to study the hydrodynamic radii of novel core/shell particles in dispersion.Additionally, the crystallization of surface-attached PDMSB is investigated via DSC measurements and results compared with free PDMSB chains.We emphasize that the herein described physical characterization leads to a more profound understanding of PDMSB, which behaves different with respect to crystallization compared to other crystallizable polymers with low glass transition temperatures, such as poly(ethylene oxide) (PEO).The synthetic protocol for surface-initiated anionic ROP of DMSB leads to novel well-defined PCS/organic core/shell structures, which are promising candidates to gain materials for SiC-based ceramic particles or hollow spheres after pyrolysis.Such SiC materials find important applications for electric devices, such as sensors or in catalysis [38][39][40].

Instrumentation
Standard SEC was performed with THF as the mobile phase (flow rate 1 mL min -1 ) on a SDV column set from PSS (SDV 1000, SDV 100000, SDV 1000000) at 30 °C.Calibration was carried out using PS standards (from Polymer Standard Service, Mainz).For the SEC-MALLS experiments, a system composed of a Waters 515 pump (Waters, Milford, CT), a TSP AS100 autosampler, a Waters column oven, a Waters 486 UV detector operating at 254 nm, a Waters 410 RI-detector and a DAWN DSP light scattering detector (Wyatt Technology, Santa Barbara, CA) was used.For data acquisition and evaluation of the light-scattering experiments, Astra version 4.73 (Wyatt Technology, Santa Barbara, CA) was used.The light-scattering instrument was calibrated using pure toluene, assuming a Rayleigh ratio of 9.78 × 10 −6 cm −1 at 690 nm.An injection volume of 118 μL, a sample concentration of 1-2 g L −1 , a column temperature of 35 °C and a THF flow rate of 1 mL min -1 have been applied.SEC analysis was performed on a high resolution column set from PSS (SDV 5 μm 106 Å, SDV 5 μm 105 Å, SDV 5 μm 1000 Å).Subsequent slow addition of monomer for the PS latex synthesis was carried out by using a precision piston pump (mikro Prominent).TEM experiments were carried out with a Zeiss EM 10 electron microscope operating at 80 kV.All shown images were recorded with a slow-scan charge-coupled device (CCD) camera obtained from TRS (Tröndle) in bright field mode.Camera control was computer aided using the ImageSP software from TRS. Centrifugation was performed with an Avanti J-30I from Beckman Coulter for half an hour with a speed of 17,000 rpm.Dynamic light scattering (DLS) experiments were performed with a setup based on a He-Ne laser with a wavelength of λ = 632.8nm and a goniometer allowing one to measure at scattering angles 2θ from 30° to 160°.Polarization of the primary beam was defined by a Glan-Thomson prism.The scattered beam polarization was again analyzed for its polarization, and all experiments were performed in vertical-vertical geometry.Scattered intensity was detected with an optical fiber coupled to two phototubes.In this way, background could be minimized using the cross-correlated signal from both tubes.The correlation function of intensity was calculated with an ALV 5000 autocorrelator.The sample was filled in a cylindrical cuvette (Hellma) and immersed in a temperature controlled index matching bath.DLS measurements were carried out at 25 °C in THF.The concentrations of the nanoparticle dispersions were approximately 0.01 w% after ultrasonic treatment (3 h for the polymer-grafted particles and 6 h for bare PS particles).After that sonication time, the experimentally obtained value of the hydrodynamic radius, R h , was constant.The scattering intensity was measured in a range of scattering angles, , from 50° to 130°.The autocorrelation function of intensity, g 2 (t, q), was thus obtained.SAXS measurements were carried using a custom made system.The scattered intensity was measured as a function of scattering vector q = 4π/λsinθ, where λ is the X-ray wavelength and 2θ the scattering angle.The experimental setup used monochromatized Cu K α radiation with λ = 1.54 Å, a pinhole collimation and a two-dimensional position sensitive detector by Molecular Metrology.The accessed q-range is from 0.008 Å −1 to 0.25 Å −1 .The two-dimensional scattering image from the detector was calibrated using Ag-behenate and radially averaged to calculate the intensity I(q).Samples were measured in borosilicate capillaries with a 1.5 mm diameter, and temperature was controlled with an accuracy of ΔT = 0.2 K. XRD was conducted using a Siemens D500 diffractometer in the reflection mode using an incident X-ray wavelength of 1.54 Å with a scan rate of 0.04° min −1 .The diffractometer was equipped with a hot stage to control the temperature of the sample with an accuracy of ΔT = 1 K.The resulting plots of X-ray intensity versus 2θ were analyzed using the profile fitting program.DSC measurements were done on a computer aided TA Instruments DSC Q1000.The sample mass was in the range of 2-4 mg for PDMSB homopolymer, while for PDMSB-grafted PS particles, the mass used was in the range of 12 to 15 mg.Dried N 2 gas was purged with a constant flow rate during the measurement.The temperature reading and caloric measurements were calibrated using indium and blue sapphire as the standard.

Materials
All solvents and reagents were purchased from Alfa Aesar, Sigma Aldrich, Fisher Scientific and ABCR and used as received, unless otherwise stated.Tetrahydro-furan (THF), toluene and n-hexane were distilled from sodium/benzophenone under reduced pressure (cryo-transfer) prior to the addition of 1,1-diphenylethylene and n-butyllithium (n-BuLi), followed by a second cryo-transfer.1,1-dimethysilacyclobutane (DMSB) was dried over CaH 2 and distilled, followed by the addition of 1,1-diphenylethylenelithium (DPHLi), until the red color remained.DMSB was freshly distilled from that solution prior to the anionic ROP.All syntheses were carried out under an atmosphere of nitrogen or argon using the Schlenk technique or a glovebox equipped with a Coldwell apparatus.

Anionic Polymerization of 1,1-Dimethylsilacyclobutane (DMSB)
Exemplary synthesis for PDMSB with a molar mass of Approx.30 kg mol −1 : In a glovebox, 470 mg DMSB (4.69 mmol) is dissolved in 20 mL of neat THF in an ampoule equipped with a stirring bar.The solution is cooled to −60 °C by using the Coldwell apparatus, and the polymerization is initiated by adding 7 µL n-BuLi (1.6 M, 11.2 µmol).After 1 h, the reaction is terminated with methanol and the solution poured into a 10-fold excess of methanol.The polymer precipitates as a colorless solid, is filtered and dried in vacuo (yield: 454 mg, 97%).Molar mass is determined by using SEC-MALLS (M n = 31,500, M w = 32,600, PDI = 1.04).

Synthesis of Cross-Linked PS Particles
In a 500 mL three-necked flask equipped with magnetic stirring bar, 105 mL degassed water, 6.30 g styrene, 0.70 g divinylbenzene and 0.1 g sodium dodecylsulfate are added.The mixture is stirred and heated to 75 °C.A solution of 0.175 g sodium peroxodisulfate and 0.035 g sodium dithionite in 5 mL water are added to initiate the batch polymerization.After 30 min, an emulsion of 37.8 g styrene, 4.2 g divinylbenzene, 0.35 g sodium dodecylsulfate and 0.42 g Triton X405 in 86 mL degassed water is added continuously with a precision piston pump (flow rate of 1 mL min −1 ).After the addition, stirring is continued for 1 h at 75 °C with a stirring rate of 300 rpm.The resulting PS latex was characterized by using TEM, revealing a particle diameter of approximately 230 nm.

Surface-Initiated Anionic Ring Opening Polymerization of DMSB
PDMSB@PS 1: In an ampoule equipped with a stirring bar, 300 mg of dried cross-linked PS particles are dispersed with 7.5 mL dry toluene by stirring vigorously for 24 h inside a glovebox.45 µL sec-BuLi (c = 1.3 M, 35 µmol) are added, and the dispersion turns slightly orange.After stirring the dispersion for 1 h at room temperature, it is transferred into an ampoule with cooled THF (−60 °C).After stirring the dispersion for 30 min cooled inside the Coldwell apparatus at −60 °C, 280 mg precooled DMSB (−15 °C) are added.The solution is stirred for 2.5 h at −60 °C.The reaction is terminated with methanol and the particle dispersion centrifuged for 30 min at 15,000 rpm.To get rid of impurities and freely formed PDMSB chains, the particles are dispersed in toluene and again centrifuged.This step is repeated at least five times, followed by drying of the functionalized particles in vacuo.
PDMSB@PS 2: In an ampoule equipped with a stirring bar, 280 mg of dried cross-linked PS particles are dispersed with 7.5 mL dry toluene by stirring vigorously for 24 h inside a glovebox.20 µL sec-BuLi (c = 1.3 M, 15 µmol) are added, and the dispersion turns slightly orange.After stirring the dispersion for 1 h at room temperature, it is transferred into an ampoule with cooled THF (−60 °C).After stirring the dispersion for 30 min at −60 °C inside the Coldwell apparatus, 280 mg precooled DMSB (−15 °C) are added.The solution is stirred for 2.5 h at −60 °C.The reaction is terminated with methanol and the particle dispersion centrifuged for 30 min at 15,000 rpm.To get rid of impurities and freely formed PDMSB chains, the particles are dispersed in toluene and again centrifuged.This step is repeated at least five times, followed by drying of the functionalized particles in vacuo.

PDMSB Synthesis
Although anionic ROP of DMSB monomer in THF at low temperatures (−48 °C to −60 °C) (Figure 1) leads to a turbidity after approximately 10 to 15 min after addition of n-BuLi as initiator independently of the intended molar mass, high molar masses up to 60 kg mol −1 could be obtained with low polydispersity values (PDI < 1.15).The results are summarized in Table 1.    and PDI obtained by SEC-MALLS measurements; the refractive index increment dn/dc could be determinated to 0.0966 (THF, 30°C).THF: tetrahydrofuran; PDI: polydispersity index.
From Table 1, it becomes clear that molar masses obtained via conventional SEC with PS standards were slightly lower compared to the absolute molar mass values obtained by using SEC-MALLS.An exemplary monomodal, narrowly distributed SEC-MALLS trace for PDMSB with an average molar mass of approximately 32 kg mol −1 is given in Figure 2. The anionic ROP of DMSB is quite fast, and living chain ends can be thought to be very reactive.However, after a longer reaction time (>1 h) under applied conditions, PDMSB samples showed a significant shoulder in SEC traces shifted to higher molar masses, which can be assumed to be caused by an undesired coupling process of living chain ends with the silane moieties.

DSC Measurements of PDMSB Homopolymers
For a study of the melting and crystallization behavior of PDMSB homopolymers, samples were heated with a rate of 10 K min −1 to 353 K, and the temperature was kept constant for 10 min to delete thermal history.Then, the sample was cooled to 253 K with a rate of 10 K min −1 to obtain the DSC exotherms, followed by heating again to obtain the DSC endotherms.In Figure 3, the DSC curve of PDMSB with an average molar mass of 5.6 kg mol −1 is exemplarily given.From Figure 3, it becomes clear that only one crystallization peak in the vicinity of 283 K during the cooling process was apparent.However, subsequent heating showed that there are unambiguously two melting peaks at 295 K and another at 303 K. Similar multiple melting peak phenomena have been reported in studies with low molar mass PEO homopolymers.In those investigations with PEO, the untypical thermal behavior is known as the integral folding (IF) and nonintegral folding (NIF) structure.Kovacs et al. pioneered this issue and studied the relationship between linear growth rate, single crystal morphology and the IF structure [41][42][43][44][45]. Cheng et al. demonstrated the existence of the NIF structure using time resolved small-angle X-ray scattering (SAXS) [46][47][48][49][50][51][52][53][54][55][56].At first glance, it seems that a similar mechanism might play a role for low molar mass PDMSB homopolymers, but further investigations are necessary, as described in the following section.

XRD and SAXS Measurements of PDMSB Homopolymers
In Figure 4, the X-ray diffraction (XRD) pattern of the PDMSB sample with an average molar mass of 5.6 kg mol −1 is shown, which has been isothermally crystallized at 283 K after annealing at 353 K for 10 min.The scattering pattern consists of a series of narrow Bragg peaks.Obviously, the sample is partially crystalline.The peak positions are the same as those reported previously by Kawahara et al. [34].Only the relative intensity of the peaks is different.This can be caused by a different orientation of crystallites in the samples as a consequence of the sample preparation procedure.We now turn to the crystalline/amorphous mesostructure of the sample.Figure 5 shows the Lorentz-corrected SAXS profile for the melt-crystallized sample at 283 K for 120 min.The results show one long range order peak, which relates to a long period of 10.7 nm.This differs from observations in the isothermal crystallization behavior of PEO homopolymers [48].For PEO, it has been found that at first, a scattering peak was observed during isothermal crystallization, followed by a decrease of the scattering peak, and the appearance of two other scattering peaks developed gradually.Isothermal thickening and/or thinning processes lead to the formation of the final IF chain crystals for low molecular weight PEO, which can be used to explain the multiple melting peaks phenomenon.However, for PDMSB, this is not the case, as only one scattering peak is observed after crystallization.To sum up, for all results derived by DSC, XRD and SAXS measurements for low molar mass PDMSB homopolymers, we assume that the first melting peak corresponds to crystal lamellae formed during isothermal crystallization, while the second one is caused by recrystallization during the heating process.DSC measurements show that when isothermal crystallization temperature, T c , is low enough, there will be two melting peaks, but only one melting peak when T c is high.Recent DSC curves of isothermal crystallized PDMSB samples also show that there is only one peak without any shoulders.This interesting crystallization behavior for low molar mass PDMSB will be explicitly discussed in a prospective work.
Investigations regarding the crystallization of PDMSB homopolymers with higher molar masses show a fast and distinct crystallization, which shows PDMSB to be an excellent candidate for studying the influence of the crystallization of anchored polymers on a curved substrate, as described in the following sections.

Surface-Initiated Anionic Polymerization of DMSB on Cross-Linked PS Nanoparticles
As a solid model substrate for the intended surface-initiated anionic polymerization of DMSB and to study the crystallization behavior of surface-attached PDMSB chains, PS nanoparticles were used, which were cross-linked with 10 wt% divinylbenzene.Those particles were used because of their simple synthesis via seeded emulsion polymerization, similar to a previously described procedure, leading to almost monodisperse particles [57].For further purification, the particles were dried by three-fold azeotropic distillation with dry toluene under high vacuum conditions.To ensure the absence of protic impurities, which would immediately cause a termination of the anionic polymerization, the particle dispersion in toluene was additionally titrated, as described in the following.Therefore, sec-BuLi was slowly added with a µL-syringe, until a slightly yellowish color appeared, which remained for at least 15 min, due to the nucleophilic addition at the accessible vinyl groups in the swollen particles' shell.In the next step, the calculated amount of initiator for the intended molar masses of PDMSB was added, followed by DMSB monomer addition (Figure 6).The polymerization was terminated with degassed methanol, and surface-grafted particles were purified by repeated centrifugation and redispersing in neat THF for at least five times.

TEM Investigations
Purified PDMSB-grafted PS particles were dispersed in neat THF and drop-casted on a carbon-coated copper grid for intended TEM investigations.The images shown in Figure 7 compared to the images of bare PS particles reveal that anionic surface-grafting was successful, due to the film formation during the sample preparation process caused by the particles' shell, which consisted of linear PDMSB chains.Gray scale analysis of PDMSB@PS-2 TEM images reveal a particle-particle distance of approx.102 nm, which corresponds to a shell thickness for each particle of 51 nm in the solid state.To prove the successful grafting-from approach for DMSB on the surface of PS particles additionally to TEM studies, DLS measurements were done to obtain changes of the hydrodynamic radii and diffusion coefficients of the grafted particles.In all cases, the correlation functions, g 2 , were found to be very close to exponential, and no indication of polydispersity was found.The correlation time, τ, is related to the translational diffusion coefficient, D, by D = 1/(τq 2 ), and the expected linear variation of <τ> −1 with q 2 was very nicely fulfilled by our data.Figure 8 shows, therefore, the scattering vector (q 2 ) dependence of the reciprocal average relaxation time <τ> −1 for bare and grafted PS nanoparticles in THF.Applying the Stokes-Einstein relation allowed to calculate hydrodynamic radii, R h = k B T/6πηD, with k B , T and η as the Boltzmann constant, the absolute temperature and the solvent viscosity, respectively.From results in Figure 8, it can be concluded that the slope decreases after PDMSB-grafting of the PS nanoparticles and, hence, indicating an increase in hydrodynamic radii.Obtained R h increases from 148 nm for bare PS nanoparticles to 209 nm for sample PDMSB@PS-1 and to 175 nm for sample PDMSB@PS-2, which corresponds to a shell thickness of 61 nm for the first and 27 nm for the second sample, respectively, evidencing a successful particle grafting with PDMSB.(ms) Bare PS Particle PDMSB@PS-1 PDMSB@PS-2

DSC Investigations of PDMSB-Grafted PS Particles
To gain first insights into the crystallization behavior of PDMSB chains attached on a curved substrate, the grafted particles were investigated by using DSC in a similar manner as the PDMSB homopolymers.PDMSB-grafted PS particles were heated to 473 K, and the temperature was held for 10 min to remove the thermal history.The sample was measured with a cooling rate of 30 K min −1 down to 253 K, followed by heating again to 473 K with a rate of 30 K min −1 .The results are given in Figure 9 for sample PS@PDMSB-1, the sample with a higher content of PDMSB attached on the surface of the particles, and in Figure 10, the DSC results are given for sample PS@PDMSB-2.Both DSC diagrams in Figures 9 and 10 show the glass transition caused by the cross-linked PS nanoparticles.The transition temperature was estimated to be 398 K, which is higher than the glass transition of PS homopolymers (380 K) due to the crosslinking of PS with DVB [58].Also, during the cooling process, no crystallization peak could be observed, as is the case for PDMSB homopolymers, independently of obtained molar masses.This can be explained by either too few PDMSB chains attached at the surface of PS nanoparticles or a tremendous influence of the curved substrate both hampering the crystallization.In the subsequent heating process, a weak melting peak was observed at about 301 K, which is very close to the melting peak of PDMSB homopolymers (303 K).In contrast to PDMSB homopolymer investigations, only one melting peak was observed.This is because the diffusion of PDMSB chains attached to the surface is remarkably hindered, and the chains can only crystallize locally at the surface of PS nanoparticles.Hence, the recrystallization process is inhibited.Figure 10 is the DSC diagram of PS@PDMSB-2.From DLS results in the previous section, R h for PS@PDMSB-2 could be determinated to 175 nm, which was much smaller than the value of PS@PDMSB-2 (209 nm).This means that there is even less crystallizable material at the surface.And indeed, DSC results show that after sample treatment, to obtain the same thermal history, there is no melting peak during the heating process for PS@PDMSB-2.

Conclusions
In conclusion, a synthetic protocol leading to crystallizable poly(1,1-dimethylsilacyclobutane) (PDMSB) homopolymers with molar masses ranging from 2.3 kg mol −1 to 60 mol −1 with low polydispersities for every sample (PDI between 1.04 and 1.15) was reported.Absolute molar masses of investigated polycarbosilanes (PCS) were determinated by using SEC-MALLS and were directly compared to SEC measurements, with PS standards revealing a slightly lower molar mass for investigated samples in the latter case.Low molar mass PDMSB homopolymers were found to be rapidly crystallizing.They showed an interesting crystallization phenomenon, which at first glance, was similar to the untypical crystallization of low molar mass poly(ethylene oxide)s.However, SAXS,

Table 1 .
Size exclusion chromatography (SEC) with polystyrene (PS) standards vs. multi-angle laser light scattering size exclusion chromatography (SEC-MALLS) results of investigated PDMSB homopolymers.

Figure 2 .
Figure 2. Exemplary SEC-MALLS trace (a) and molar mass distribution (b) of PDMSB obtained by SEC-MALLS measurement synthesized via anionic ROP in THF at −60 °C.

Figure 4 .
Figure 4. X-ray diffraction pattern of PDMSB with an average molar mass of 5.6 kg mol −1 isothermally crystallized at 283 K after annealing at 353 K for 10 min.

Figure 5 .
Figure5.Lorentz-corrected small-angle X-ray scattering (SAXS) profile evaluated for the melt-crystallized sample at 283 K for 120 min.q m * denotes the scattering vector corresponding to the reciprocal of the long period.

Figure 6 .
Figure 6.Surface-initiated anionic ROP of DMSB on the surface of PS nanoparticles.

Figure 7 .Figure 7 .
Figure 7. TEM images of bare cross-linked PS particles (a) and surface-modified PDMSB particles with high content (b) and low content of PDMSB (c).