Gradation Design of Epoxy–Asphalt Mixtures for Steel Bridge Deck Pavements Optimized for Skid Resistance in Hot and Humid Climates
Abstract
1. Introduction
2. Materials and Methods
2.1. Raw Materials
2.1.1. Binder Composition and Basic Performance Properties
- (1)
- Basic properties of base asphalt:
- (2)
- Basic properties of epoxy resin and curing agent:
2.1.2. Basic Properties and Mechanical Volume Parameters of Aggregates
2.2. Experimental Methods
2.2.1. Specimen Preparation
- (1)
- Preparation of Marshall specimens:
- (2)
- Preparation of slab specimens:
2.2.2. Testing Methods
- (1)
- Density measurement of compacted asphalt mixtures:
- (2)
- Marshall stability and flow test:
- (3)
- Friction coefficient measurement:
- (4)
- Macrotexture depth measurement:
3. Results and Discussion
3.1. Design of the Orthogonal Experimental Scheme
3.2. Determination of the Optimum Asphalt–Aggregate Ratio
3.3. Influence of Gradation on Macrotexture Depth Based on Orthogonal Experiments
3.3.1. Range Analysis Results and Discussion on Macrotexture Depth
3.3.2. Analysis of Variance and Significance Testing for Macrotexture Depth
3.4. Influence of Gradation on Dry Friction Coefficient Based on Orthogonal Experiments
3.4.1. Range Analysis Results and Discussion on Dry Friction Coefficient
3.4.2. Analysis of Variance and Significance Testing for Dry Friction Coefficient
3.4.3. Integrated Analysis of Dry Friction Coefficient and Gradation Optimization Direction
3.5. Influence of Gradation on Water-Film Friction Coefficient Based on Orthogonal Experiments
3.5.1. Range Analysis Results and Discussion on Water-Film Friction Coefficient
3.5.2. Analysis of Variance and Significance Testing for Water-Film Friction Coefficient
3.5.3. Integrated Analysis of Water-Film Friction Coefficient and Gradation Optimization Direction
3.6. Integrated Analysis of Three Performance Indicators and Final Gradation Optimization Recommendations
3.7. International Friction Index (IFI)
3.7.1. IFI Calculation Model and Method
3.7.2. IFI Result Analysis
4. Conclusions
- Macrotexture depth is primarily governed by the coarse aggregate skeleton structure, with the 4.75 mm sieve passing rate acting as the dominant controlling factor and the 0.3 mm sieve passing rate playing an important regulating role. When the 4.75 mm passing rate is approximately 70% and the 0.3 mm passing rate is around 26.5%, a stable interlocking skeleton of coarse aggregates can be formed, which is favorable for the development of pavement macrotexture.
- The dry and water-film friction coefficients exhibit consistent response patterns to gradation structure and are mainly controlled by the 2.36 mm and 0.6 mm sieve passing rates. Among these, 2.36 mm has a significant effect on the dry friction coefficient at the critical significance level. The 2.36 mm passing rate determines the morphology of the surface skeleton and the degree of aggregate angularity exposure, while the 0.6 mm passing rate regulates the skeleton void structure and plays a key role in friction performance under both dry and wet conditions.
- Based on the integrated analysis of the three skid resistance indicators, a coordinated control scheme for key sieves in skid-resistance-oriented epoxy–asphalt mixtures is proposed. When the 2.36 mm passing rate is controlled within 58–61% and the 0.6 mm passing rate is maintained at approximately 34%, in combination with a 4.75 mm passing rate of about 70% and a 0.3 mm passing rate of about 26.5%, the mixture can achieve superior comprehensive skid resistance.
- IFI evaluation results demonstrate that synergistic matching between macrotexture depth and friction performance is decisive for comprehensive skid resistance, and extreme values of a single skid resistance indicator cannot fully represent the overall skid resistance level of the mixture. The graded aggregate exhibits more stable overall skid resistance through the synergistic interaction between a stable macro-scale framework and interconnected micro-scale voids formed by key fine aggregate sieve apertures such as 0.6 mm and 0.3 mm.
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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| Testing Items | Unit | Technical Requirement | Measured Value | Experiment Methods |
|---|---|---|---|---|
| Penetration (25 °C, 5 s, 100 g) | 0.1 mm | 60~80 | 62 | T0604-2011 |
| Softening point (TR&B) | °C | ≥47 | 48.0 | T0606-2011 |
| Ductility (10 °C, 5 cm/min) | cm | ≥20 | 35 | T0605-2011 |
| Ductility (15 °C, 5 cm/min) | cm | ≥100 | >100 | T0605-2011 |
| Flash point | °C | ≥260 | 336 | T0611-2011 |
| Density (15 °C) | g/cm3 | ≥1.000 | 1.028 | T0603-2011 |
| Residue after the Rolling Thin Film Oven Test (RTFOT) (163 °C, 85 min) | ||||
| Mass change | % | 8.367 | 8 | T0610-2011 |
| Residual ductility (10 °C, 5 cm/min) | cm | 9.41 | 9 | T0605-2011 |
| Residual penetration ratio (25 °C) | % | 10.45 | 10 | T0604-2011 |
| Testing Items | Unit | Technical Requirement | Test Results | Experiment Methods |
|---|---|---|---|---|
| Viscosity (23 °C) | / | 1000~5000 | 2215 | GB/T12007.4-1989 [35] |
| Specific gravity (23 °C) | g/cm3 | 1.00~1.20 | 1.138 | T0603-1993 |
| Epoxy equivalent | / | 190~220 | 200 | GB/T4612-1984 [36] |
| Flash point | °C | >220 | 235 | T0611-1993 |
| Appearance | / | Pale yellow transparent liquid | Pale yellow transparent liquid | Visual inspection |
| Testing Items | Unit | Technical Requirement | Test Results | Experiment Methods |
|---|---|---|---|---|
| Amine value | mg, KOH/g | 150~200 | 160 | T0606-2000 |
| Viscosity (23 °C) | / | 100~800 | 191 | GB/T12007.4-1989 |
| Specific gravity (23 °C) | g/cm3 | 0.80~1.00 | 0.848 | T0603-1993 |
| Flash point | °C | >145 | 169 | T0611-1993 |
| Appearance | / | Light yellowish-brown liquid | Light yellowish-brown liquid | Visual inspection |
| Testing Items | Technical Requirement | Test Results | Experiment Methods |
|---|---|---|---|
| Los Angeles abrasion rate, % | ≤16 | 11.2 | JTG E42-2005(T 0317-2005) |
| Polish value, PSV | ≥44 | 50 | JTG E42-2005 (T0321-2005) |
| Needle and flake content, % | ≤5 | 3.8 | JTGE42-2005 (T0312-2005) |
| Crush value, % | ≤12 | 9.1 | JTG E42-2005 (T0316-2005) |
| Adhesion to asphalt, Grade | ≥4 | 5 | JTJ E20-2011 (T0616-1993) |
| Water absorption rate, % | ≤1.5 | 0.61 | JTG E42-2005 (T0308-2005) |
| Apparent density, g·cm−3 | ≥2.70 | 2.946 | JTG E42-2005 (T0308-2005) |
| Sturdiness, % | ≤5 | 1 | JTG E42-2005 (T0314-2000) |
| Soft rock content, % | ≤1 | 0.1 | JTG E42-2005 (T0320-2000) |
| Particle content <0.075, % | ≤0.8 | 0.1 | JTG E42-2005 (T0303-2005) |
| Testing Items | Unit | Technical Requirement | Test Results | Experiment Methods |
|---|---|---|---|---|
| Apparent relative density | g·cm−3 | ≥2.70 | 2.926 | JTG E42-2005 T0328 |
| Sturdiness | % | ≤12 | 2 | JTG E42-2005 T0340 |
| Sand equivalent | % | ≥70 | 88 | JTG E42-2005 T0334 |
| Methylene blue value | g/kg | ≤2.5 | 0.8 | JTG E42-2005 T0349 |
| Angularity (flow time) | s | ≥30 | 30.3 | JTG E42-2005 T0345 |
| Testing Items | Technical Requirement | Test Results | Experiment Methods |
|---|---|---|---|
| Apparent density, g·cm−3 | ≥2.50 | 2.764 | JTG E42-2005 T0352 |
| Appearance | No clumping | No clumping | —— |
| Moisture content, % | ≤1 | 0.2 | JTG 051-1993 T0103 |
| Hydrophilicity coefficient | ≤1 | 0.81 | JTG E42-2005 T0353 |
| Plasticity Index, % | ≤4 | 3.8 | JTG E42-2005 T0355 |
| Stability | No deteriorating | No change | JTG E42-2005 T0355 |
| Number | Sieve Aperture Size/mm (Passing Rates/%) | |||||||
|---|---|---|---|---|---|---|---|---|
| 9.5 | 4.75 | 2.36 | 1.18 | 0.6 | 0.3 | 0.15 | 0.075 | |
| EA-10-1 | 100 | 70 | 52 | 42 | 30 | 23.5 | 15.5 | 8.5 |
| EA-10-2 | 100 | 70 | 55 | 47 | 34 | 29.5 | 21.5 | 8.5 |
| EA-10-3 | 100 | 70 | 58 | 42 | 38 | 29.5 | 18.5 | 10.5 |
| EA-10-4 | 100 | 70 | 61 | 52 | 30 | 26.5 | 21.5 | 10.5 |
| EA-10-5 | 100 | 70 | 64 | 47 | 38 | 26.5 | 15.5 | 12.5 |
| EA-10-6 | 100 | 70 | 67 | 52 | 34 | 23.5 | 18.5 | 12.5 |
| EA-10-7 | 100 | 75 | 67 | 42 | 38 | 26.5 | 21.5 | 8.5 |
| EA-10-8 | 100 | 75 | 64 | 52 | 30 | 29.5 | 18.5 | 8.5 |
| EA-10-9 | 100 | 75 | 52 | 47 | 34 | 26.5 | 18.5 | 10.5 |
| EA-10-10 | 100 | 75 | 55 | 52 | 38 | 23.5 | 15.5 | 10.5 |
| EA-10-11 | 100 | 75 | 61 | 42 | 34 | 29.5 | 15.5 | 12.5 |
| EA-10-12 | 100 | 75 | 58 | 47 | 30 | 23.5 | 21.5 | 12.5 |
| EA-10-13 | 100 | 80 | 61 | 47 | 38 | 23.5 | 18.5 | 8.5 |
| EA-10-14 | 100 | 80 | 58 | 52 | 34 | 26.5 | 15.5 | 8.5 |
| EA-10-15 | 100 | 80 | 64 | 42 | 34 | 23.5 | 21.5 | 10.5 |
| EA-10-16 | 100 | 80 | 67 | 47 | 30 | 29.5 | 15.5 | 10.5 |
| EA-10-17 | 100 | 80 | 55 | 42 | 30 | 26.5 | 18.5 | 12.5 |
| EA-10-18 | 100 | 80 | 52 | 52 | 38 | 29.5 | 21.5 | 12.5 |
| EA-10-19 | 100 | 75 | 61 | 47 | 34 | 26.5 | 18.5 | 10.5 |
| EA-10-20 | 100 | 80 | 67 | 52 | 38 | 29.5 | 21.5 | 12.5 |
| Gradation Number | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
| Texture Depth (mm) | 0.73 | 0.72 | 0.70 | 0.76 | 0.75 | 0.69 | 0.71 | 0.69 | 0.70 | 0.68 |
| Gradation Number | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
| Texture Depth (mm) | 0.66 | 0.69 | 0.70 | 0.69 | 0.69 | 0.67 | 0.68 | 0.69 | 0.71 | 0.67 |
| Indicator | Factor A | Factor B | Factor C | Factor D | Factor E | Factor F | Factor G |
|---|---|---|---|---|---|---|---|
| K1 | 4.35 | 2.12 | 4.17 | 4.22 | 4.18 | 4.18 | 4.24 |
| K2 | 4.84 | 2.08 | 4.94 | 4.86 | 5.00 | 4.87 | 4.91 |
| K3 | 4.79 | 2.08 | 4.87 | 4.90 | 4.80 | 4.93 | 4.83 |
| K4 | 2.83 | ||||||
| K5 | 2.13 | ||||||
| K6 | 2.74 | ||||||
| k1 | 0.725 | 0.707 | 0.695 | 0.703 | 0.697 | 0.697 | 0.707 |
| k2 | 0.691 | 0.693 | 0.706 | 0.694 | 0.714 | 0.696 | 0.701 |
| k3 | 0.684 | 0.693 | 0.696 | 0.700 | 0.686 | 0.704 | 0.690 |
| k4 | 0.708 | ||||||
| k5 | 0.710 | ||||||
| k6 | 0.685 | ||||||
| Range | 0.041 | 0.025 | 0.011 | 0.009 | 0.029 | 0.009 | 0.017 |
| Sources of Variance | Sum of Squares | Degrees of Freedom | Mean Square | F-Value | Significance |
|---|---|---|---|---|---|
| A | 0.006 | 2 | 0.003 | 111.575 | 0.009 |
| B | 0.001 | 5 | 0.000 | 10.195 | 0.092 |
| C | 0.000 | 2 | 0.000 | 7.163 | 0.123 |
| D | 0.001 | 2 | 0.000 | 11.382 | 0.081 |
| E | 0.003 | 2 | 0.001 | 50.209 | 0.020 |
| F | 0.001 | 2 | 0.000 | 17.801 | 0.053 |
| G | 0.001 | 2 | 0.000 | 11.165 | 0.082 |
| Error | 5.143 × 10−5 | 2 | 2.571 × 10−5 |
| Gradation Number | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
| Dry Friction Coefficient | 80 | 69 | 69 | 79.5 | 65 | 69.5 | 65 | 70.5 | 72.5 | 69.5 |
| Gradation Number | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
| Dry Friction Coefficient | 67.5 | 85 | 70 | 81.5 | 65 | 70.5 | 79 | 68.5 | 70.5 | 66 |
| Indicator | Factor A | Factor B | Factor C | Factor D | Factor E | Factor F | Factor G |
|---|---|---|---|---|---|---|---|
| K1 | 432.0 | 221.0 | 425.5 | 464.5 | 439.0 | 434.0 | 436.0 |
| K2 | 500.5 | 217.5 | 502.5 | 495.5 | 513.0 | 501.0 | 496.5 |
| K3 | 500.5 | 235.5 | 505.0 | 473.0 | 481.0 | 498.0 | 500.5 |
| K4 | 287.5 | ||||||
| K5 | 200.5 | ||||||
| K6 | 271.0 | ||||||
| k1 | 72.0 | 73.7 | 70.9 | 77.4 | 73.2 | 72.3 | 72.7 |
| k2 | 71.5 | 72.5 | 71.8 | 70.8 | 73.3 | 71.6 | 70.9 |
| k3 | 71.5 | 78.5 | 72.1 | 67.6 | 68.7 | 71.1 | 71.5 |
| k4 | 71.9 | ||||||
| k5 | 66.8 | ||||||
| k6 | 67.8 | ||||||
| Range | 0.5 | 11.7 | 1.2 | 9.9 | 4.6 | 1.2 | 1.7 |
| Sources of Variance | Sum of Squares | Degrees of Freedom | Mean Square | F-Value | Significance |
|---|---|---|---|---|---|
| A | 3.324 | 2 | 1.662 | 0.824 | 0.548 |
| B | 253.116 | 5 | 50.623 | 25.102 | 0.039 |
| C | 19.521 | 2 | 9.761 | 4.840 | 0.171 |
| D | 287.608 | 2 | 143.804 | 71.308 | 0.014 |
| E | 71.260 | 2 | 35.630 | 17.668 | 0.054 |
| F | 1.315 | 2 | 0.657 | 0.326 | 0.754 |
| G | 11.964 | 2 | 5.982 | 2.966 | 0.252 |
| Error | 4.033 | 2 | 2.017 |
| Gradation Number | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
| Water-Film Friction Coefficient | 75.5 | 62 | 65.5 | 76 | 59 | 63 | 59.5 | 68 | 68.5 | 64 |
| Gradation Number | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
| Water-Film Friction Coefficient | 65.5 | 81.5 | 64.5 | 76 | 59.5 | 65 | 73 | 64.5 | 67 | 60.5 |
| Indicator | Factor A | Factor B | Factor C | Factor D | Factor E | Factor F | Factor G |
|---|---|---|---|---|---|---|---|
| K1 | 401.0 | 208.5 | 398.5 | 439.0 | 408.0 | 405.0 | 405.5 |
| K2 | 474.0 | 199.0 | 467.5 | 461.5 | 479.0 | 469.5 | 465.5 |
| K3 | 463.0 | 223.0 | 472.0 | 437.5 | 451.0 | 463.5 | 467.0 |
| K4 | 273.0 | ||||||
| K5 | 186.5 | ||||||
| K6 | 248.0 | ||||||
| k1 | 66.8 | 69.5 | 66.4 | 73.2 | 68.0 | 67.5 | 67.6 |
| k2 | 67.7 | 66.3 | 66.8 | 65.9 | 68.4 | 67.1 | 66.5 |
| k3 | 66.1 | 74.3 | 67.4 | 62.5 | 64.4 | 66.2 | 66.7 |
| k4 | 68.3 | ||||||
| k5 | 62.2 | ||||||
| k6 | 62.0 | ||||||
| Range | 1.6 | 12.3 | 1.0 | 10.7 | 4.0 | 1.3 | 1.1 |
| Sources of Variance | Sum of Squares | Degrees of Freedom | Mean Square | F-Value | Significance |
|---|---|---|---|---|---|
| A | 3.064 | 2 | 1.523 | 0.675 | 0.597 |
| B | 316.853 | 5 | 63.371 | 28.076 | 0.035 |
| C | 21.912 | 2 | 10.956 | 4.854 | 0.171 |
| D | 340.184 | 2 | 170.092 | 75.357 | 0.013 |
| E | 39.849 | 2 | 19.924 | 8.827 | 0.102 |
| F | 0.661 | 2 | 0.331 | 0.146 | 0.872 |
| G | 8.830 | 2 | 4.415 | 1.956 | 0.338 |
| Error | 4.514 | 2 | 2.257 |
| Gradation Number | MTD/mm | Water-Film Friction Coefficient | Texture Parameter Sp | Relative IFI |
|---|---|---|---|---|
| 1 | 0.73 | 75.5 | 1.54 | 0.162 |
| 2 | 0.72 | 62 | 1.53 | 0.194 |
| 3 | 0.7 | 65.5 | 1.5 | 0.408 |
| 4 | 0.76 | 76 | 1.56 | 0.112 |
| 5 | 0.75 | 59 | 1.55 | 0.136 |
| 6 | 0.69 | 63 | 1.49 | 0.54 |
| 7 | 0.71 | 59.5 | 1.51 | 0.322 |
| 8 | 0.69 | 68 | 1.49 | 0.515 |
| 9 | 0.7 | 68.5 | 1.5 | 0.446 |
| 10 | 0.68 | 64 | 1.48 | 0.646 |
| 11 | 0.66 | 65.5 | 1.46 | 1.0 |
| 12 | 0.69 | 81.5 | 1.49 | 0.57 |
| 13 | 0.7 | 64.5 | 1.5 | 0.442 |
| 14 | 0.69 | 76 | 1.49 | 0.6 |
| 15 | 0.69 | 59.5 | 1.49 | 0.45 |
| 16 | 0.67 | 65 | 1.47 | 0.826 |
| 17 | 0.68 | 73 | 1.48 | 0.506 |
| 18 | 0.69 | 64.5 | 1.49 | 0.442 |
| 19 | 0.71 | 67 | 1.51 | 0.297 |
| 20 | 0.67 | 60.5 | 1.47 | 0.677 |
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Du, P.; He, Q.; Han, Z.; Zhang, Q.; Xiong, C.; Zhang, Y. Gradation Design of Epoxy–Asphalt Mixtures for Steel Bridge Deck Pavements Optimized for Skid Resistance in Hot and Humid Climates. Polymers 2026, 18, 1088. https://doi.org/10.3390/polym18091088
Du P, He Q, Han Z, Zhang Q, Xiong C, Zhang Y. Gradation Design of Epoxy–Asphalt Mixtures for Steel Bridge Deck Pavements Optimized for Skid Resistance in Hot and Humid Climates. Polymers. 2026; 18(9):1088. https://doi.org/10.3390/polym18091088
Chicago/Turabian StyleDu, Peidong, Qinghua He, Zhenqiang Han, Qiang Zhang, Chuan Xiong, and Yujie Zhang. 2026. "Gradation Design of Epoxy–Asphalt Mixtures for Steel Bridge Deck Pavements Optimized for Skid Resistance in Hot and Humid Climates" Polymers 18, no. 9: 1088. https://doi.org/10.3390/polym18091088
APA StyleDu, P., He, Q., Han, Z., Zhang, Q., Xiong, C., & Zhang, Y. (2026). Gradation Design of Epoxy–Asphalt Mixtures for Steel Bridge Deck Pavements Optimized for Skid Resistance in Hot and Humid Climates. Polymers, 18(9), 1088. https://doi.org/10.3390/polym18091088

