Simulation Design of Novel Non-Fluorine Polymers as Electron Transport Layer for Lead-Free Perovskite Solar Cells

Significant progress has been made in the advancement of perovskite solar cells, but their commercialization remains hindered by their lead-based toxicity. Many non-toxic perovskite-based solar cells have demonstrated potential, such as Cs2AgBi0.75Sb0.25Br6, but their power conversion efficiency is inadequate. To address this issue, some researchers are focusing on emerging acceptor–donor–acceptor’–donor–acceptor (A-DA’D-A)-type non-fullerene acceptors (NFAs) for Cs2AgBi0.75Sb0.25Br6 to find effective electron transport layers for high-performance photovoltaic responses with low voltage drops. In this comparative study, four novel A-DA’D-A-type NFAs, BT-LIC, BT-BIC, BT-L4F, and BT-BO-L4F, were used as electron transport layers (ETLs) for the proposed devices, FTO/PEDOT:PSS/Cs2AgBi0.75Sb0.25Br6/ETL/Au. Comprehensive simulations were conducted to optimize the devices. The simulations showed that all optimized devices exhibit photovoltaic responses, with the BT-BIC device having the highest power conversion efficiency (13.2%) and the BT-LIC device having the lowest (6.8%). The BT-BIC as an ETL provides fewer interfacial traps and better band alignment, enabling greater open-circuit voltage for efficient photovoltaic responses.


Introduction
Hybrid perovskite materials have demonstrated excellent performance over the past several years in the field of solar devices, and as a result their power conversion efficiency increased from a few percent to 27% in a very short period of time [1][2][3].To further improve the performance of perovskite solar cells, substantial research efforts are being made to address several outstanding problems.Due to these efforts, perovskite solar cells are more advantageous than other types of solar cells in a number of aspects, including cost, weight, flexibility, portability, wide-area application, and low-temperature production [4,5].Even though perovskite solar cells have made great advances in the laboratory environment, there are still a number of barriers to their general commercialization [6,7].
It is commonly known that the lead-based toxicity, power conversion efficiency, stability, and degradation of perovskite solar cells are the most significant unsolved challenges [8,9].A highly stable double perovskite class of a Cs 2 AgBiBr 6 absorber layer has recently been reported as a viable substitute for Pb-based perovskite.As a result, Cs 2 AgBi 0.75 Sb 0.25 Br 6 is favored for this study due to its various benefits, including being lead-free, non-toxic, extremely stable, and compatible with a variety of transport layers, as reported in the literature [10][11][12].
Despite the perovskite absorber layer, the design architectures, material properties of the charge transport layer, and other design limitations also have serious impacts on the abovementioned problems.Two design architectures, (i) standard n-i-p and (ii) inverted p-i-n, are frequently used for the fabrication of perovskite solar cells, depending on the Polymers 2023, 15, 4387 2 of 21 front electron transport layer or hole transport layer facing the photons for solar cell applications.In both architectures, the perovskite absorber layer is sandwiched between the electron transport layer and the hole transport layer.Additionally, each architecture has unique benefits and drawbacks.Currently, the inverted p-i-n design is used to create the highest-performing photovoltaic devices [13][14][15].
The electron transport layer is one of the most significant functional layers in perovskite solar cells, due to its crucial role in enhancing stability, power conversion efficiency, cost, and consequently overall performance [15][16][17].There are vital electronic parameters of the electron transport layer that are fundamentally necessary for fine-tuning the effective photovoltaic response, such as the (i) energy bandgap, (ii) electron affinity (LUMO), (iii) ionization energy (HOMO), (iv) molecular packaging, (v) carrier mobilities, (vi) reorganization energy, etc.The great majority of polymer and perovskite solar cells used for photovoltaic applications include an electron transport layer composed of fullerene materials as PC 60 BM ( [6,6]-phenyl C61-butyric acid methyl ester) and/or PC 70 BM ( [6,6]-phenyl-C71-butyric acid methyl ester) [18][19][20].The fullerene-based electron transport layer, unfortunately, has several drawbacks, such as (i) poor optical absorption, especially in the near-infrared and visible range; (ii) thermal instability; (iii) photochemical instability; (iv) restricted tuneability, etc. [21,22].
Designing a non-fullerene-based (NFA) electron transport layer might potentially overcome the drawbacks of the fullerene-based electron transport layer.The stability, tuneability, and optical absorption can all be improved by easily adjusting the chemical molecular structure, highest occupied molecular orbital (HOMO), and lowest unoccupied molecular orbital (LUMO) of a non-fullerene-based electron transport layer over a reasonably wide range [23][24][25].The design of NFAs that are reported often falls into one of two categories.One choice is the acceptor-donor-acceptor (A-D-A)-type molecule, which has a simple manufacturing process and an energy level that is easily adjusted.The other, the A-DA'D-A-type molecule, on the other hand, is supported by a greater short-circuit current density (J SC ) and wider absorption, thanks to its bigger conjugated plane and enhanced intramolecular charge transfer (ICT).It is quite interesting to design organic/polymer electron transport materials, notably with the help of A-DA'D-A-type NFAs and their variants [26][27][28][29][30][31][32][33][34][35].All these design parameters can be greatly tuned for an effective electron transport layer in a perovskite solar cell by making use of various physiochemical methodologies [36][37][38][39].On the basis of these physiochemical methodologies, four novel A-DA'D-A types of NFAs as electron transport layers have recently been reported, which are the end-group derivatives of Y5 and Y6 materials and named linear as BT-LIC and bent as BT-BIC, BT-L4F, and BT-BO-L4F [40][41][42][43], as shown in Figure 1.All of these, (i) BT-LIC, (ii) BT-BIC, (iii) BT-L4F, and (iv) BT-BO-L4F, are highly novel materials for the electron transport layer, with very little and nearly negligible information available in the reported literature.
In most cases, it may be difficult to dope polymers for electron/hole transport layers (ETLs) at higher concentrations.This problem is caused by many variables, including (i) solubility and compatibility, (ii) aggregation and phase separation, (iii) doping-induced defects, and (iv) doping process restrictions.It is crucial to note that although high doping concentrations in polymer transport layers might be difficult, they are not always required.The maximum doping of the electron/hole transport layer is still reported in the literature at a value of 10 20 cm −3 .For this reason, in our simulation of the suggested solar cell, we employ a maximum doping density of up to 10 20 cm −3 for both electron and hole transport layers [44,45].
In this study, the p-i-n-type perovskite solar cells were chosen, as they demonstrate relatively higher efficiency and ease of fabrication, as discussed above [46][47][48][49][50].Similarly, PEDOT: PSS (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate)) as the hole transport layer and Cs 2 AgBi0 .75Sb 0.25 Br 6 as the perovskite layer were selected due to many advantages, such as being lead-free, highly stable, compatible with both transport layers, etc. [51,52].Figure 2 shows the design architecture of the four proposed devices The main goal of this study is to comprehensively investigate, optimize, and compare the devices as a function of the above hole transport layer to determine the different design parameters that can offer the maximum power conversion efficiency.In order to maintain simplicity, this study focuses exclusively on the analysis and comparison of the thickness and doping density of the electron transport layer (ETL).The manuscript grows excessively lengthy in other cases.However, future study endeavors may involve the utilization of optimal thickness and doping values, as well as a comprehensive analysis and explanation of the various properties related to the electron transport layer.In most cases, it may be difficult to dope polymers for electron/hole transport layers (ETLs) at higher concentrations.This problem is caused by many variables, including (i) solubility and compatibility, (ii) aggregation and phase separation, (iii) doping-induced defects, and (iv) doping process restrictions.It is crucial to note that although high doping concentrations in polymer transport layers might be difficult, they are not always required.The maximum doping of the electron/hole transport layer is still reported in the literature at a value of 10 20 cm −3 .For this reason, in our simulation of the suggested solar cell, we employ a maximum doping density of up to 10 20 cm −3 for both electron and hole transport layers [44,45].
In this study, the p-i-n-type perovskite solar cells were chosen, as they demonstrate relatively higher efficiency and ease of fabrication, as discussed above [46][47][48][49][50].Similarly, PEDOT: PSS (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate)) as the hole transport layer and Cs2AgBi0.75Sb0.25Br6as the perovskite layer were selected due to many advantages, such as being lead-free, highly stable, compatible with both transport layers, etc. [51,52].Figure 2 shows the design architecture of the four proposed devices with their energy band diagrams, namely (i) FTO/PEDOT: PSS/Cs2AgBi0.75Sb0.25Br6/BT-LIC/Au(device BT-LIC), (ii) FTO/PEDOT: PSS/Cs2AgBi0.75Sb0.25Br6/BT-BIC/Au(device BT-BIC), (iii) FTO/PEDOT: PSS/Cs2AgBi0.75Sb0.25Br6/BT-L4F/Au(device BT-L4F), and (iv) FTO/PEDOT: PSS/Cs2AgBi0.75Sb0.25Br6/BT-BO-L4F/Au(device BT-BO-L4F).The main goal of this study is to comprehensively investigate, optimize, and compare the devices as a function of the above hole transport layer to determine the different design parameters that can offer the maximum power conversion efficiency.In order to maintain simplicity, this study focuses exclusively on the analysis and comparison of the thickness and doping density of the electron transport layer (ETL).The manuscript grows excessively lengthy in other cases.However, future study endeavors may involve the utilization of optimal thickness and doping values, as well as a comprehensive analysis and explanation of the various properties related to the electron transport layer.

Device Models for Simulation
The software for modeling solar cells typically solves a set of coupled differential equations for semiconductor devices using conventional mathematical techniques.The general photovoltaic responses of solar cells, such as short-circuit current, open-circuit voltage, fill factor, and power conversion efficiency, are identified using the solutions of these equations [53][54][55][56][57]. Detailed information about these models can be found in our previously published results [7].
The SCAPS 1D (version 3.3.10)software employs a drift-diffusion model for the purpose of computing the energy levels within the band diagram of a photovoltaic cell.These equations incorporate various parameters, including carrier production, recombination, and transport processes.The SCAPS 1D software is capable of solving Poisson's equation,

Device Models for Simulation
The software for modeling solar cells typically solves a set of coupled differential equations for semiconductor devices using conventional mathematical techniques.The general photovoltaic responses of solar cells, such as short-circuit current, open-circuit voltage, fill factor, and power conversion efficiency, are identified using the solutions of these equations [53][54][55][56][57]. Detailed information about these models can be found in our previously published results [7].
The SCAPS 1D (version 3.3.10)software employs a drift-diffusion model for the purpose of computing the energy levels within the band diagram of a photovoltaic cell.These equations incorporate various parameters, including carrier production, recombination, and transport processes.The SCAPS 1D software is capable of solving Poisson's equation, which establishes a relationship between the electric field and the charge distribution present in a solar cell.The aforementioned equation incorporates the impact of the electrostatic potential on the energy levels depicted in the band diagram.SCAPS 1D utilizes the derived electric field and charge distribution to ascertain the band offsets and energy levels at different locations within the band diagram of the solar cell.

Simulation Software
A solar cell's photovoltaic response may be estimated using the mathematical equations mentioned above, which are the foundation of any photovoltaic modeling software.In theory, simulation software is a tool that allows users to foretell the output response of solar devices without performing actual testing in a variety of settings.Simulation software can reasonably predict the experimental results of a solar cell [57][58][59][60].The conditions must be met by modeling software to accurately forecast the output of photovoltaic responses accurately.Numerous researchers assert that SCAPS 1D is extremely trustworthy software that satisfies many of the criteria listed in the references [61][62][63][64] and may be used to simulate a wide range of photovoltaic processes.

Simulation Steps
In general, the SCAPS 1D simulation steps are a list of feasible actions that must be executed.The following is a list of the simulation processes that are necessary to apply to the suggested devices in order to obtain the highest power conversion efficiency.
Step 1 Start of simulation: Define the environment, geometry, and physical parameters of all the device's layers according to Table 1.
Step 3 Estimation of ranges for different parameters: Propose the range of thickness and doping density for each layer of (i) device BT-LIC, (ii) device BT-BIC, (iii) device BT-L4F, and (iv) device BT-BO-L4F from the literature.
Step 4 Thickness optimization of HTL: Determine the optimal thickness of PEDOT: PSS for each device as a hole transport layer through a series of simulations, which gives the maximum power conversion efficiency and quantum efficiency (QE).After that, update with the optimal thickness of PEDOT: PSS for further simulations.
Step 5 Determination of PV parameters as a function of HTL thickness: Determine the photovoltaic parameters such as open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency of each device as a function of PEDOT: PSS thickness.
Step 6 Thickness optimization of perovskite absorber layer: Determine the optimal thickness of the perovskite absorber layer (Cs 2 AgBi 0.75 Sb 0.25 Br 6 ) for each device as an absorber layer through a series of simulations, which gives the maximum power conversion efficiency and quantum efficiency.Then, update with the optimal thickness of the absorber for further simulations.
Step 7 Determination of PV parameters as a function of perovskite thickness: Determine the photovoltaic parameters such as open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency of each device as a function of absorber thickness.Electron Thermal Velocity (V e , cm/s)

Simulation Material Parameters
For the optimization of each layer of a perovskite solar cell, the proper selection of material parameters for each layer is essential.As the electron transport materials (i) BT-LIC, (ii) BT-BIC, (iii) BT-L4F, and (iv) BT-BO-L4F are novel, an extensive amount of related literature was reviewed to extract the simulation parameters, while for PEDOT:PSS and Cs 2 AgBi 0.75 Sb 0.25 Br 6 materials, the parameters were selected from highly reliable references, as listed in Table 1.
Both the proposed perovskite absorber and the polymer-based transport layer offer an inherently high density of defects.In most cases, these electronic defects are grown during the crystal growth or fabrication process due to uncontrolled impurities, inconsistencies in polymerization or crystal growth, thin-film deposition processes, and other environmental parameters [74][75][76][77].Therefore, a defect density of 10 14 cm 2 is introduced into the bulk region of the absorber, hole transport layer, and electron transport layer, as indicated in Table 1.

Thickness Optimization of the Hole Transport Layer
Generally, for any type of solar cell, the thickness of the hole transport layer (HTL) plays a crucial role in improving the overall performance of the solar cell.The effectiveness of the charge transfer process between the perovskite absorber layer and the electrode can be considerably impacted by the thickness of the hole transport layer.To obtain the highest possible efficiency in solar cells, it is essential to optimize the thickness of the hole transport layer.
Therefore, determining the optimized thickness of the hole transport layer is a design challenge for perovskite solar cells.In order to determine the optimal thickness of the hole transport layer, each of the four devices was simulated as a function of hole transport layer thickness, and a very similar photovoltaic response was observed.For simplicity, randomly elected device D (BT-LIC) responses are shown in Figure 3.The photo current-voltage response may be used to estimate the thickness of the hole transport layer for perovskite solar cells with the maximum feasible efficiency.Therefore, the photovoltaic responses of device D are depicted in Figure 3 as functions of the thickness of the hole transport layer, which ranges from 10 nm to 90 nm.Based on Figure 3, it can be seen that device D exhibits respectable photovoltaic behavior.However, when the thickness increases, the photovoltaic responsiveness suffers, as the parameters are severely degraded.
Polymers 2023, 15, x FOR PEER REVIEW 7 of 23 voltage response may be used to estimate the thickness of the hole transport layer for perovskite solar cells with the maximum feasible efficiency.Therefore, the photovoltaic responses of device D are depicted in Figure 3 as functions of the thickness of the hole transport layer, which ranges from 10 nm to 90 nm.Based on Figure 3, it can be seen that device D exhibits respectable photovoltaic behavior.However, when the thickness increases, the photovoltaic responsiveness suffers, as the parameters are severely degraded.The photovoltaic parameters were calculated, and the results are shown in Figure 4 as a function of PEDOT: PSS thickness.Therefore, the photovoltaic parameters, such as (i) open-circuit voltage, short-circuit current (Figure 4a), (ii) fill factor, and (iv) power conversion efficiency (Figure 4b), follow more or less very similar trends, where all these pa- The photovoltaic parameters were calculated, and the results are shown in Figure 4 as a function of PEDOT: PSS thickness.Therefore, the photovoltaic parameters, such as (i) open-circuit voltage, short-circuit current (Figure 4a), (ii) fill factor, and (iv) power conversion efficiency (Figure 4b), follow more or less very similar trends, where all these parameters are severely degraded.According to a previous report, PEDOT: PSS, like many other organic/polymer semiconductors, inherently has a large number of traps that serve as recombination centers.The density of traps exponentially rises as PEDOT:PSS thickness increases, and photovoltaic characteristics rapidly deteriorate [78][79][80].As power conversion efficiency is a decisive parameter and it is maximum at 10 nm for each device (here only device D is shown), it can be justified that 10 nm is the optimum thickness of the hole transport layer for each device.This is because the optimal PEDOT:PSS doping density for each proposed device is obtained at 10 20 cm −3 through simulation, which is quite comparable to our previous results [7,61,62,[68][69][70].For a perovskite-type solar cell, the optimal thickness of the hole transport layer can also be estimated using external quantum efficiency (EQE).The external quantum efficiency depends on the wavelength of the incident light and is often stated in terms of percentage.Figure 5 shows the external quantum efficiency of device D (BT-BO-L4F) as a function of the thickness of PEDOT: PSS.It also confirms that as thickness increases, the area under the QE curve also decreases.It clearly demonstrates that the total charges col-  For a perovskite-type solar cell, the optimal th also be estimated using external quantum efficien ciency depends on the wavelength of the inciden percentage.Figure 5   For a perovskite-type solar cell, the optimal thickness of also be estimated using external quantum efficiency (EQE).ciency depends on the wavelength of the incident light and percentage.Figure 5   For a perovskite-type solar cell, the optimal thickness of the hole transport layer can also be estimated using external quantum efficiency (EQE).The external quantum efficiency depends on the wavelength of the incident light and is often stated in terms of percentage.Figure 5 shows the external quantum efficiency of device D (BT-BO-L4F) as a function of the thickness of PEDOT: PSS.It also confirms that as thickness increases, the area under the QE curve also decreases.It clearly demonstrates that the total charges col-  For a perovskite-type solar cell, the optimal thickness of the hole transport layer can also be estimated using external quantum efficiency (EQE).The external quantum efficiency depends on the wavelength of the incident light and is often stated in terms of percentage.Figure 5 shows the external quantum efficiency of device D (BT-BO-L4F) as a function of the thickness of PEDOT: PSS.It also confirms that as thickness increases, the area under the QE curve also decreases.It clearly demonstrates that the total charges col- For a perovskite-type solar cell, the optimal thickness of the hole transport layer can also be estimated using external quantum efficiency (EQE).The external quantum efficiency depends on the wavelength of the incident light and is often stated in terms of percentage.Figure 5 shows the external quantum efficiency of device D (BT-BO-L4F) as a function of the thickness of PEDOT: PSS.It also confirms that as thickness increases, the area under the QE curve also decreases.It clearly demonstrates that the total charges collected at the respective electrodes also decrease, and hence it can be inferred that more and more recombination will take place at the higher thickness of PEDOT:PSS.Both power conversion efficiency and external quantum efficiency are decisive factors in the selection of the thickness of PEDOT:PSS for efficient photovoltaic response, and maximum power conversion efficiency and quantum efficiency is observed at 10 nm of PEDOT:PSS, so it can be justified that 10 nm is the most optimum thickness of PEDOT:PSS for the proposed devices.

Thickness Optimization of the Absorber Layer
To increase the photo conversion efficiency of perovskite solar cells, the thickness of the absorber layer of Cs2AgBi0.75Sb0.25Br6must be optimized.The ideal thickness of the perovskite absorber layer depends on a number of parameters, including the composition of the perovskite material, the design of the photovoltaic device, and the thin-film deposition process.Thick perovskite absorber layers can boost photon absorption, and on the other hand, thin perovskite absorber layers can decrease recombination losses and lead to improved power conversion efficiency [81,82].In the literature, both experimental methods and device simulation modeling can be used to determine the optimal thickness of the perovskite absorber layer.
As discussed above, the optimization of perovskite layer thickness is a critical parameter in determining the performance of a solar cell.In order to achieve a suitable balance between light absorption and charge carrier extraction, it is often necessary to optimize the thickness of the active layer.Increased thickness of the active layer facilitates enhanced light absorption due to the greater availability of material for photon interaction.However, a thick active layer increases the carrier recombination.In thicker active layers, the distance that charge carriers need to travel to reach the electrodes increases.Conversely, when the active layer is very thin, it may lead to inadequate light absorption, thus leading to less production of photocurrent.Similarly, a thin active layer may also limit the ability to extract charge carriers efficiently, leading to poor charge collection and reduced overall performance.
Here, the optimal thickness of the perovskite absorber Cs2AgBi0.75Sb0.25Br6layer was estimated using simulation techniques.In order to start the simulation, the absorber layer was initialized with random values extracted from Table 1.The photovoltaic response of device D is depicted in Figure 6 as a function of absorber layer thickness from 10 nm to 100 nm.According to the device's photovoltaic response, unlike the thickness of the hole transport layer, the photovoltaic response is degraded at lower absorber layer thicknesses, increases up to when the absorber layer reaches its maximum photovoltaic response, and then again gradually decreases; the above-discussed responses are more clearly observed in Figure 7.

Thickness Optimization of the Absorber Layer
To increase the photo conversion efficiency of perovskite solar cells, the thickness of the absorber layer of Cs 2 AgBi 0.75 Sb 0.25 Br 6 must be optimized.The ideal thickness of the perovskite absorber layer depends on a number of parameters, including the composition of the perovskite material, the design of the photovoltaic device, and the thin-film deposition process.Thick perovskite absorber layers can boost photon absorption, and on the other hand, thin perovskite absorber layers can decrease recombination losses and lead to improved power conversion efficiency [81,82].In the literature, both experimental methods and device simulation modeling can be used to determine the optimal thickness of the perovskite absorber layer.
As discussed above, the optimization of perovskite layer thickness is a critical parameter in determining the performance of a solar cell.In order to achieve a suitable balance between light absorption and charge carrier extraction, it is often necessary to optimize the thickness of the active layer.Increased thickness of the active layer facilitates enhanced light absorption due to the greater availability of material for photon interaction.However, a thick active layer increases the carrier recombination.In thicker active layers, the distance that charge carriers need to travel to reach the electrodes increases.Conversely, when the active layer is very thin, it may lead to inadequate light absorption, thus leading to less production of photocurrent.Similarly, a thin active layer may also limit the ability to extract charge carriers efficiently, leading to poor charge collection and reduced overall performance.
Here, the optimal thickness of the perovskite absorber Cs 2 AgBi 0.75 Sb 0.25 Br 6 layer was estimated using simulation techniques.In order to start the simulation, the absorber layer was initialized with random values extracted from Table 1.The photovoltaic response of device D is depicted in Figure 6 as a function of absorber layer thickness from 10 nm to 100 nm.According to the device's photovoltaic response, unlike the thickness of the hole transport layer, the photovoltaic response is degraded at lower absorber layer thicknesses, increases up to when the absorber layer reaches its maximum photovoltaic response, and then again gradually decreases; the above-discussed responses are more clearly observed in Figure 7.While the short-circuit current and power conversion efficiency behavior are different for a device as a function of absorber layer thickness, both of these photovoltaic parameters increase gradually, and the power conversion efficiency in particular reaches its maximum at 70 nm thickness of the absorber layer before beginning to slowly decline.
Figure 8 illustrates the quantum efficiency response of the proposed perovskite solar cell for devices where the thickness of the absorber layer (Cs 2 AgBi 0.75 Sb 0.25 Br 6 ) is varied from 10 nm to 100 nm and the thickness of the PEDOT:PSS is optimized at 10 nm.It is not clearly observed from the figure which thickness of the absorber layer gives the maximum area under the quantum efficiency curve.However, with the help of software calculations, it is found that at the thickness of 70 nm of the absorber layer, the device gives the maximum quantum efficiency, which further supports the finding that 70 nm is the optimum thickness of the absorber layer.where the open-circuit voltage and fill factor climb suddenly, peak, and then rapidly deteriorate.While the short-circuit current and power conversion efficiency behavior are different for a device as a function of absorber layer thickness, both of these photovoltaic parameters increase gradually, and the power conversion efficiency in particular reaches its maximum at 70 nm thickness of the absorber layer before beginning to slowly decline.
Figure 8 illustrates the quantum efficiency response of the proposed perovskite solar cell for devices where the thickness of the absorber layer (Cs2AgBi0.75Sb0.25Br6) is varied from 10 nm to 100 nm and the thickness of the PEDOT:PSS is optimized at 10 nm.It is not clearly observed from the figure which thickness of the absorber layer gives the maximum area under the quantum efficiency curve.However, with the help of software calculations, it is found that at the thickness of 70 nm of the absorber layer, the device gives the maximum quantum efficiency, which further supports the finding that 70 nm is the optimum thickness of the absorber layer.In a Cs2AgBi0.75Sb0.25Br6-basedsolar cell, the redshift of the band edge impacts its quantum efficiency, which is influenced by the thickness of the Cs2AgBi0.75Sb0.25Br6absorber layer, as shown Figure 8. Increasing the absorber layer thickness causes the band boundary to shift towards longer wavelengths, resulting from changes in the electrical structure and optical properties of the perovskite absorber layer.The relationship between electronic structure, optical properties, and thickness can be summarized as follows: 1. Thicker absorber layers enhance absorption efficacy by capturing more photons, increasing the likelihood of photon absorption and charge carrier generation.2. The thickness of the absorber layer affects charge carrier extraction.Excessive thickness can lead to increased recombination or trapping of charge carriers, reducing the quantum efficiency.In a Cs 2 AgBi 0.75 Sb 0.25 Br 6 -based solar cell, the redshift of the band edge impacts its quantum efficiency, which is influenced by the thickness of the Cs 2 AgBi 0.75 Sb 0.25 Br 6 absorber layer, as shown Figure 8. Increasing the absorber layer thickness causes the band boundary to shift towards longer wavelengths, resulting from changes in the electrical structure and optical properties of the perovskite absorber layer.The relationship between electronic structure, optical properties, and thickness can be summarized as follows: 1.
Thicker absorber layers enhance absorption efficacy by capturing more photons, increasing the likelihood of photon absorption and charge carrier generation.

2.
The thickness of the absorber layer affects charge carrier extraction.Excessive thickness can lead to increased recombination or trapping of charge carriers, reducing the quantum efficiency.

3.
Thicker absorber layers may experience more light scattering or reflection at interfaces, resulting in a loss of absorbed photons and potentially impacting the quantum efficiency.

4.
Thin absorber layers may exhibit limited charge transport and higher recombination rates, while excessively thick layers can impede charge extraction due to longer carrier transit times, both affecting the overall efficiency.
Therefore, to optimize the perovskite absorber, it is crucial to find the right thickness of the Cs 2 AgBi 0.75 Sb 0.25 Br 6 absorber layer that balances effective charge carrier extraction with efficient photon absorption.Thus, it can be assumed that 70 nm is the optimal thickness of the perovskite absorber layer that provides a balance between the above-stated variables.

Thickness Optimization of Electron Transport Layer
Another critical design factor for producing highly efficient perovskite solar cells is the thickness optimization of the electron transport layer.Thickness optimization, particularly for polymer-based electron layers, is very important because it affects several physical, material, and photovoltaic parameters.
(a) Device architecture: The optimal electron transport layer thickness may vary according to the specific device architecture, such as whether the solar cell has a planar or mesoporous structure.(b) Material characteristics: The ideal thickness for effective charge transfer and extraction can be influenced by the electron transport layer's material characteristics, such as (i) electron transport, (ii) series resistance, (iii) shunt resistance, (iv) carrier lifetime, (v) electron mobility, (vi) electron density, (vii) recombination losses, (viii) charge extraction efficiency, (ix) optical absorption, and (x) interface energy level alignment, among others.(c) Thin-film deposition method: There are several thin-film deposition methods that may be used to manage the electron transport layer's thickness, and each has advantages and limitations of its own.Spin coating, for instance, is a very cheap and simple method.(d) Post-deposition method: By modifying the thickness of the electron transport layer using post-deposition techniques like solvent or annealing, the morphology and interface properties of the electron transport layer may be altered.(e) Photovoltaic performance matrices: Depending on the device's individual performance metrics, such as power conversion efficiency, short-circuit current, and fill factor, the ideal electron transport layer thickness may vary.These metrics may all be influenced by the electron transport layer's thickness.(f) Trade-offs: When determining the ideal electron transport layer thickness, it is frequently necessary to compromise between several device characteristics, such as reducing leakage currents while increasing charge transfer efficiency.(g) Interaction with other layers: The electron transport layer's thickness can have an impact on how the electrode, absorber layer, and hole transport layer interact with other layers in the device.(h) Energy level alignment: The energy level alignment between the ETL and the perovskite layer exhibits some differences.Such differences can lead to a modification of the energy levels inside the valence band (VB) and conduction band (CB) at the interface separating the electron transport layer (ETL) and the perovskite material.The determination of the energy level offset plays a crucial role in driving the process of charge transfer and has a significant impact on the efficiency of charge extraction and hence the efficiency of solar cells.This might make the optimization procedure more challenging.
Overall, the complicated interactions between these variables make optimizing the electron transport layer thickness a difficult iterative process that frequently calls for simulation methods.
The photovoltaic parameters (i) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (iv) power conversion efficiency are shown in Figure 9 as functions of the thickness of the electron transport layer for the devices (a) A (BT-LIC), (b) B (BT-BIC), (c) C (BT-L4F), and (d) D (BT-BO-L4F).Figure 9 demonstrates that although the open-circuit voltage varies for each device, it does not change relatively as the thickness of the electron transport layer increases.This is because the open-circuit voltage is generally determined by the energy bandgap offset, and its value is generally unaffected by the thickness of the electron transport layer [83,84], as observed in Figure 9.In addition, Figure 9 shows the relative short-circuit responses for the devices as functions of the thickness of the electron transport layer.The figure demonstrates that all devices behave in a consistent manner, with the short-circuit current reducing as the thickness of the electron layer grows.Device A's behavior stands out, whereas other devices' rates of decrease are very insignificant.Similarly, when the thickness of the electron transport layer increases, the fill-factor behavior of all devices likewise deteriorates.This could be because the devices experience increasing series resistance and recombination losses as the thickness of the electron layer rises.The power conversion efficiency responses, which are the resultant behavior of open-circuit voltage, short-circuit current, and fill-factor responses, also behave in a very similar way, while the power conversion efficiency deteriorates as a function of electron transport layer thickness.The figure clearly demonstrates that device BT-LIC is sharply degraded, while device BT-BIC shows a relatively excellent power conversion efficiency response as a function of electron transport layer thickness.Power conversion efficiency is the most important parameter, and all devices show maximum power conversion efficiency at 25 nm.Thus, it can be inferred that 25 nm is the most optimal thickness of the corresponding electron transport layer for each device.
Overall, the complicated interactions between these variables make optimizing the electron transport layer thickness a difficult iterative process that frequently calls for simulation methods.
The photovoltaic parameters (i) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (iv) power conversion efficiency are shown in Figure 9 as functions of the thickness of the electron transport layer for the devices (a) A (BT-LIC), (b) B (BT-BIC), (c) C (BT-L4F), and (d) D (BT-BO-L4F).Figure 9 demonstrates that although the open-circuit voltage varies for each device, it does not change relatively as the thickness of the electron transport layer increases.This is because the open-circuit voltage is generally determined by the energy bandgap offset, and its value is generally unaffected by the thickness of the electron transport layer [83,84], as observed in Figure 9.In addition, Figure 9 shows the relative short-circuit responses for the devices as functions of the thickness of the electron transport layer.The figure demonstrates that all devices behave in a consistent manner, with the short-circuit current reducing as the thickness of the electron layer grows.Device A's behavior stands out, whereas other devices' rates of decrease are very insignificant.Similarly, when the thickness of the electron transport layer increases, the fill-factor behavior of all devices likewise deteriorates.This could be because the devices experience increasing series resistance and recombination losses as the thickness of the electron layer rises.The power conversion efficiency responses, which are the resultant behavior of open-circuit voltage, short-circuit current, and fill-factor responses, also behave in a very similar way, while the power conversion efficiency deteriorates as a function of electron transport layer thickness.The figure clearly demonstrates that device BT-LIC is sharply degraded, while device BT-BIC shows a relatively excellent power conversion efficiency response as a function of electron transport layer thickness.Power conversion efficiency is the most important parameter, and all devices show maximum power conversion efficiency at 25 nm.Thus, it can be inferred that 25 nm is the most optimal thickness of the corresponding electron transport layer for each device.

Doping Density Optimization of the Electron Transport Layer
The electron transport layer's doping density can have a big influence on the electrical conductivity of solar cells, charge carrier mobility, and overall power conversion efficiency.Usually, organic or polymeric compounds with strong electron-withdrawing groups and significant electron affinities are used as dopants to dope polymer-based electron transport layers [85,86].High doping of the electron transport layer (ETL) can improve the power conversion efficiency of a perovskite solar cell by lowering the series resistance Polymers 2023, 15, 4387 13 of 21 and electrode-transport layer interface losses, but on the other hand, excessive doping can increase charge carrier recombination and degrade the device's overall efficiency.Therefore, doping optimization of the electron transport layer is crucial for the efficient design of the proposed perovskite solar cells.
Therefore, the photovoltaic parameters (a) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (d) power conversion efficiency were estimated through simulation, and the results are shown in Figure 10 as functions of the doping density of the electron transport layer for the devices (a) A (BT-LIC), (b) B (BT-BIC), (c) C (BT-L4F), and (d) D (BT-BO-L4F).The figure shows that all the photovoltaic parameters, open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency, are improving as the doping density is increased in the corresponding electron transport layer.The thickness of the electron transport layer is already optimized, and it can be assumed that the electron transport layer offers very little recombination losses; therefore, the reduction in resistivity as a function of increasing doping density is the dominating factor for each device.As power conversion efficiency is a decisive parameter and it is maximum at 10 20 cm −3 for each device, it can be justified that 10 20 cm −3 is the optimum doping of the electron transport layer for each device.
The electron transport layer's doping density can have a big influence on the electrical conductivity of solar cells, charge carrier mobility, and overall power conversion efficiency.Usually, organic or polymeric compounds with strong electron-withdrawing groups and significant electron affinities are used as dopants to dope polymer-based electron transport layers [85,86].High doping of the electron transport layer (ETL) can improve the power conversion efficiency of a perovskite solar cell by lowering the series resistance and electrode-transport layer interface losses, but on the other hand, excessive doping can increase charge carrier recombination and degrade the device's overall efficiency.Therefore, doping optimization of the electron transport layer is crucial for the efficient design of the proposed perovskite solar cells.
Therefore, the photovoltaic parameters (a) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (d) power conversion efficiency were estimated through simulation, and the results are shown in Figure 10 as functions of the doping density of the electron transport layer for the devices (a) A (BT-LIC), (b) B (BT-BIC), (c) C (BT-L4F), and (d) D (BT-BO-L4F).The figure shows that all the photovoltaic parameters, open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency, are improving as the doping density is increased in the corresponding electron transport layer.The thickness of the electron transport layer is already optimized, and it can be assumed that the electron transport layer offers very little recombination losses; therefore, the reduction in resistivity as a function of increasing doping density is the dominating factor for each device.As power conversion efficiency is a decisive parameter and it is maximum at 10 20 cm −3 for each device, it can be justified that 10 20 cm −3 is the optimum doping of the electron transport layer for each device.

Photo Current-Voltage Response of the Optimized Devices
The influence of the electron transport layer on the overall performance of perovskite solar cells may be further investigated by using the photo current-voltage responses of the optimized perovskite solar cells.In Figure 11, the typical photo current-voltage responses of the perovskite solar cells are observed.The figure offers important information about its photovoltaic performance parameters such as open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency.Table 2 displays all these photovoltaic parameters as estimated from Figure 11 for each device.The figure and Table 2 clearly reveal that all devices perform differently, while device B (BT-BIC) has the best photovoltaic response (power conversion efficiency ~13.2%), and device A (BT-LIC) has the worst photovoltaic response (power conversion efficiency ~6.8%).It is also observed that the improvements in open-circuit voltage as well as fill factor are relatively higher for device B. This clearly demonstrates that the photovoltaic device B fabricated with BT-BIC as an electron transport layer may manage the optimum build-in potential and excellent interface quality, which in turn improve the overall charge collection and charge transport and suppress recombination losses [87][88][89] compared to the other electron transport layers for devices A, C, and D. solar cells may be further investigated by using the photo current-voltage responses of the optimized perovskite solar cells.In Figure 11, the typical photo current-voltage responses of the perovskite solar cells are observed.The figure offers important information about its photovoltaic performance parameters such as open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency.Table 2 displays all these photovoltaic parameters as estimated from Figure 11 for each device.The figure and Table 2 clearly reveal that all devices perform differently, while device B (BT-BIC) has the best photovoltaic response (power conversion efficiency ~13.2%), and device A (BT-LIC) has the worst photovoltaic response (power conversion efficiency ~6.8%).It is also observed that the improvements in open-circuit voltage as well as fill factor are relatively higher for device B. This clearly demonstrates that the photovoltaic device B fabricated with BT-BIC as an electron transport layer may manage the optimum build-in potential and excellent interface quality, which in turn improve the overall charge collection and charge transport and suppress recombination losses [87][88][89] compared to the other electron transport layers for devices A, C, and D.    The external quantum efficiency responses of the fully optimized devices may be used to further examine the impact of the electron transport layer on the overall performance of perovskite solar cells.The external quantum efficiency can be defined as the fraction of the total number of collected charge carriers at the electrodes to the total number of incident photons [90].Mathematically, external quantum efficiency (QE) can be defined as a function of either energy E or wavelength (λ), and therefore the relation between quantum efficiency and short-circuit current (Jsc) can be expressed as Polymers 2023, 15,4387 where ϕ(λ) is the incident flux of photons per unit wavelength.Figure 12 shows the external quantum efficiency responses of (i) device BT-LIC, (ii) device BT-BIC, (iii) device BT-L4F, and (iv) device BT-BO-L4F as a function of incident photon wavelengths from 300 to 900 nm: more or less very similar responses are observed for all devices.It can be seen in the figure that for all devices, the quantum efficiency rises from photon wavelengths greater than 300 nm, while the highest QE is achieved in the 480-485 nm range of photon wavelengths for all devices; then, the QE of devices gradually decreased, and the relative magnified quantum efficiency responses for all devices are shown in the inset of Figure 12.This clearly reveals that the device, which uses BT-BIC as its electron transport layer, exhibits relatively improved quantum efficiency, and it also confirms the earlier simulation results that were already discussed.
fraction of the total number of collected charge carriers at the electrodes to the total number of incident photons [90].Mathematically, external quantum efficiency (QE) can be defined as a function of either energy € or wavelength (λ), and therefore the relation between quantum efficiency and short-circuit current (Jsc) can be expressed as where φ(λ) is the incident flux of photons per unit wavelength.Figure 12 shows the external quantum efficiency responses of (i) device BT-LIC, (ii) device BT-BIC, (iii) device BT-L4F, and (iv) device BT-BO-L4F as a function of incident photon wavelengths from 300 to 900 nm: more or less very similar responses are observed for all devices.It can be seen in the figure that for all devices, the quantum efficiency rises from photon wavelengths greater than 300 nm, while the highest QE is achieved in the 480-485 nm range of photon wavelengths for all devices; then, the QE of devices gradually decreased, and the relative magnified quantum efficiency responses for all devices are shown in the inset of Figure 12.This clearly reveals that the device, which uses BT-BIC as its electron transport layer, exhibits relatively improved quantum efficiency, and it also confirms the earlier simulation results that were already discussed.In addition, Figure 12 shows that the quantum efficiency of the BT-BIC device reaches its optimum value, even though the short-circuit current does not.As shown in Figure 11, the device BT-L4F displays the maximum short-circuit current.While there is a correlation between short-circuit current and quantum efficiency, it is essential to recognize that recombination losses can lead to such discrepancies.Quantum efficiency refers to the In addition, Figure 12 shows that the quantum efficiency of the BT-BIC device reaches optimum value, even though the short-circuit current does not.As shown in Figure 11, the device BT-L4F displays the maximum short-circuit current.While there is a correlation between short-circuit current and quantum efficiency, it is essential to recognize that recombination losses can lead to such discrepancies.Quantum efficiency refers to the measurement of the effectiveness of photon absorption and subsequent transformation into charge carriers.In contrast, the short-circuit current density includes other variables, such as recombination losses, resistive losses, and other internal variables.Consequently, the presence of these losses may cause a slight decrease in the short-circuit current relative to the theoretical quantum efficiency.Given the comparative nature of this study, it can be argued that while the BT-LIC device has a slightly lower short-circuit current than the BT-L4F device, it has superior electrical and optical properties.Figure 11 depicts the enhanced photovoltaic response as evidence.
Based on the data presented in Table 3, it is evident that a majority of the efficient NFA electron transport layers have been reported in association with the leading MAPbI 3 -based perovskite solar cells, which are toxic in nature due to the presence of Pb.The power conversion efficiency of other lead-free perovskites (having very close energy bandgaps compared to Cs 2 AgBi 0.75 Sb 0.25 Br 6 ) with an NFA electron transport layer is not up to the mark, as evident in Table 3. Comparing electron transport layer materials, such as BT-LIC, BT-BIC, BT-L4F, and BT-BO-L4F, for perovskite Cs 2 AgBi 0.75 Sb 0.25 Br 6 -based solar cells with previously reported NFA-based lead-free perovskite solar cells, as shown in Table 3, poses significant improvements.Such improvements may be due to their distinctive electronic characteristics and customized energy levels, which enable effective charge extraction and transportation throughout the device.The electron transport layers (ETLs), namely BT-LIC, BT-BIC, BT-L4F, and BT-BO-L4F, are likely comprised of organic or mixed materials.These materials seek to facilitate charge transport within the electron transport layer for Cs 2 AgBi 0.75 Sb 0.25 Br 6 -based leadfree perovskite materials, which are still not so efficient.This is because the mobility of the abovementioned ETL, which falls within the range of 10 −4 cm 2 /V.sec, is lower when compared to the mobility of C60-based thin films, which is measured at 0.5 ± 0.2 cm 2 /V.sec.The limited mobility exhibited by these non-fullerene acceptors (NFAs) has the potential to lower the efficiency of electron collection, increase recombination rates, and contribute to increased series resistance.Consequently, all these factors collectively contribute to the deterioration of the photovoltaic responses of the proposed devices.
The use of innovative electron transport layers, including BT-LIC, BT-BIC, BT-L4F, and BT-BO-L4F, in perovskite solar cells has resulted in a notable improvement in power conversion efficiency when compared to other lead-free solar cell technologies based on non-fullerene acceptors (NFAs).The use of the novel BT-BIC in ETL materials and design facilitates increased photon absorption and charge carrier mobility, hence leading to improved power conversion efficiency.Based on our limited information, no experimental or even modeling findings have been published for the use of the innovative above-listed electron layers with Cs 2 AgBi 0.75 Sb 0.25 Br 6 -based perovskite in the context of solar cell applications.In general, the research exhibits significant promise in terms of developing the domain of solar energy harvesting.

Conclusions
In this comparative study, four non-fullerene acceptors (NFAs), (i) BT-LIC, (ii) BT-BIC, (iii) BT-L4F, and (iv) BT-BO-L4F, were used as electron transport layers for novel proposed solar devices, i.e., FTO/PEDOT: PSS/Cs 2 AgBi 0.75 Sb 0.25 Br 6 /ETL/Au.All these devices were comprehensively investigated through simulation to determine the most efficient electron transport layer for the proposed devices.For this purpose, comprehensive simulations were carried out to optimize each layer with respect to film thickness and doping density, and then the photovoltaic responses of all the optimized devices were simulated as a function of the electron transport layer, and open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency were determined.It is observed that all devices show reasonable photovoltaic responses, and the device containing BT-BIC as an electron transport layer shows the highest power conversion efficiency of ~13.2% (open-circuit voltage = ~1.36V, short-circuit current = ~12.1 mA/cm 2 , and fill factor = ~80%).The BT-LIC device shows the lowest power conversion efficiency of approximately ~6.8% (open-circuit voltage = ~1.23 V, short-circuit current = ~11.2mA/cm 2 , and fill factor = ~50%).It is also observed that the improvements in open-circuit voltage and fill factor are relatively higher for device B. This clearly demonstrates that the photovoltaic device B fabricated with BT-BIC as an electron transport layer may manage high build-in potential and excellent interface quality, which in turn improve the overall charge collection and charge transport and suppress recombination losses compared to the other electron transport layers BT-LIC, BT-L4F, and BT-BO-L4F.

Figure 3 .
Figure 3.The photo current-voltage responses of the proposed perovskite solar cell for devices where absorber and ETL (device D) thickness are randomly selected (optimization will be performed in a later stage) but the thickness of PEDOT:PSS is varied from 10 nm to 90 nm.

Figure 3 .
Figure 3.The photo current-voltage responses of the proposed perovskite solar cell for devices where absorber and ETL (device D) thickness are randomly selected (optimization will be performed in a later stage) but the thickness of PEDOT:PSS is varied from 10 nm to 90 nm.

Figure 4 .
Figure 4.The photovoltaic parameters (a) open-circuit voltage ( ), short-circuit current ( ), (b) fill factor ( ), and power conversion efficiency ( ) of device D as a function of the thickness of the PEDOT:PSS as hole transport layer.

Figure 4 .
Figure 4.The photovoltaic parameters (a) open-circuit fill factor ( ), and power conversion efficiency ( ) of d PEDOT:PSS as hole transport layer.
shows the external quantum function of the thickness of PEDOT: PSS.It also c area under the QE curve also decreases.It clearly d lected at the respective electrodes also decrease, a ), short-circuit current ( Polymers 2023, 15, x FOR PEER REVIEW

Figure 4 .
Figure 4.The photovoltaic parameters (a) open-circuit voltage ( ), fill factor ( ), and power conversion efficiency ( of device D as the PEDOT:PSS as hole transport layer.
shows the external quantum efficiency of function of the thickness of PEDOT: PSS.It also confirms tha area under the QE curve also decreases.It clearly demonstrate lected at the respective electrodes also decrease, and hence i ), (b) fill factor ( Polymers 2023, 15, x FOR PEER REVIEW 8 of 23

Figure 4 .
Figure 4.The photovoltaic parameters (a) open-circuit voltage ( ), short-circuit current ( ), (b) fill factor ( ), and power conversion efficiency ( ) of device D as a function of the thickness of the PEDOT:PSS as hole transport layer.

Figure 4 .
Figure 4.The photovoltaic parameters (a) open-circuit voltage ( ), short-circuit current ( ), (b) fill factor ( ), and power conversion efficiency ( of device D as a function of the thickness of the PEDOT:PSS as hole transport layer.

)
of device D as a function of the thickness of the PEDOT:PSS as hole transport layer.

23 Figure 5 .
Figure 5.The external quantum efficiency responses of the proposed perovskite solar device D (BT-BO-L4F) as a function of incident photon wavelengths from 300 to 900 nm as a function of PE-DOT:PSS thickness from 10 to 90 nm.

Figure 5 .
Figure 5.The external quantum efficiency responses of the proposed perovskite solar device D (BT-BO-L4F) as a function of incident photon wavelengths from 300 to 900 nm as a function of PEDOT:PSS thickness from 10 to 90 nm.

Polymers 2023 , 23 Figure 6 .
Figure 6.The photo current-voltage responses of the proposed perovskite solar cell for device D while the thickness of the absorber layer (Cs2AgBi0.75Sb0.25Br6)varied from 10 nm to 100 nm.

Figure 7 .
Figure 7.The responses of photovoltaic parameters (a) open-circuit voltage and short-circuit current and (b) fill factor and power conversion efficiency of the proposed perovskite solar cell for

Figure 6 . 23 Figure 6 .
Figure 6.The photo current-voltage responses of the proposed perovskite solar cell for device D while the thickness of the absorber layer (Cs 2 AgBi 0.75 Sb 0.25 Br 6 ) varied from 10 nm to 100 nm.

Figure 7 .Figure 7 .
Figure 7.The responses of photovoltaic parameters (a) open-circuit voltage and short-circuit current and (b) fill factor and power conversion efficiency of the proposed perovskite solar cell for Figure 7.The responses of photovoltaic parameters (a) open-circuit voltage and short-circuit current and (b) fill factor and power conversion efficiency of the proposed perovskite solar cell for device D while the thickness of the absorber layer (Cs 2 AgBi 0.75 Sb 0.25 Br 6 ) is varied from 10 nm to 100 nm.

Polymers 2023 ,
15,  x FOR PEER REVIEW 11 of 23 device D while the thickness of the absorber layer (Cs2AgBi0.75Sb0.25Br6) is varied from 10 nm to 100 nm.

Figure
Figure 7a,b illustrate the photovoltaic parameters of each device as a function of absorber layer thickness, including open-circuit voltage, short-circuit current, fill factor, and power conversion efficiency.Complex photovoltaic parameter patterns are observed,where the open-circuit voltage and fill factor climb suddenly, peak, and then rapidly deteriorate.While the short-circuit current and power conversion efficiency behavior are different for a device as a function of absorber layer thickness, both of these photovoltaic parameters increase gradually, and the power conversion efficiency in particular reaches its maximum at 70 nm thickness of the absorber layer before beginning to slowly decline.Figure8illustrates the quantum efficiency response of the proposed perovskite solar cell for devices where the thickness of the absorber layer (Cs2AgBi0.75Sb0.25Br6) is varied from 10 nm to 100 nm and the thickness of the PEDOT:PSS is optimized at 10 nm.It is not clearly observed from the figure which thickness of the absorber layer gives the maximum area under the quantum efficiency curve.However, with the help of software calculations, it is found that at the thickness of 70 nm of the absorber layer, the device gives the maximum quantum efficiency, which further supports the finding that 70 nm is the optimum thickness of the absorber layer.

Figure 8 .
Figure 8.The quantum efficiency responses of the proposed perovskite solar cell for device D, where the thickness of the absorber layer (Cs2AgBi0.75Sb0.25Br6) is varied from 10 nm to 100 nm.

Figure 8 .
Figure 8.The quantum efficiency responses of the proposed perovskite solar cell for device D, where the thickness of the absorber layer (Cs 2 AgBi 0.75 Sb 0.25 Br 6 ) is varied from 10 nm to 100 nm.

Figure 9 .
Figure 9.The photovoltaic parameters (i) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (iv) power conversion efficiency of all devices, (a) BT-LIC, (b) BT-BIC, (c) BT-L4F, and (d) BT-BO-L4F, as a function of the thickness of the electron transport layer.

Figure 9 .
Figure 9.The photovoltaic parameters (i) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (iv) power conversion efficiency of all devices, (a) BT-LIC, (b) BT-BIC, (c) BT-L4F, and (d) BT-BO-L4F, as a function of the thickness of the electron transport layer.

Figure 10 .
Figure 10.The photovoltaic parameters (i) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (iv) power conversion efficiency of the proposed devices, (a) device BT-LIC, (b) device BT-BIC, (c) device BT-L4F, and (d) device BT-BO-L4F, as a function of the doping density of the electron transport layer.

Figure 10 .
Figure 10.The photovoltaic parameters (i) open-circuit voltage, (ii) short-circuit current, (iii) fill factor, and (iv) power conversion efficiency of the proposed devices, (a) device BT-LIC, (b) device BT-BIC, (c) device BT-L4F, and (d) device BT-BO-L4F, as a function of the doping density of the electron transport layer.

Figure 12 .
Figure 12.The external quantum efficiency responses of the proposed perovskite solar cells for the device (i) BT-LIC, (ii) BT-BIC, (iii) BT-L4F, and (iv) BT-BO-L4F as a function of incident photon wavelengths from 300 to 900 nm.The inset of the figure shows the magnified responses of all the devices for the incident photon wavelength range from 300 to 390 nm.

Figure 12 .
Figure 12.The external quantum efficiency responses of the proposed perovskite solar cells for the device (i) BT-LIC, (ii) BT-BIC, (iii) BT-L4F, and (iv) BT-BO-L4F as a function of incident photon wavelengths from 300 to 900 nm.The inset of the figure shows the magnified responses of all the devices for the incident photon wavelength range from 300 to 390 nm.

Table 1 .
Random simulation parameters such as thickness and doping are used for the novel nonfluorine polymer acceptor transport layer, while other simulation parameters for given materials are taken from the given references.