Highly Electroactive Frozen-State Polymerized Polypyrrole Nanostructures for Flexible Supercapacitors

The polymerization of pyrrole in the frozen state with the presence of organic dyes (methyl orange (MO) and Acid Blue 25 (AB)) has proven to produce polypyrrole (PPy) nanostructures. Herein, we explore the electrochemical properties of PPy prepared under frozen-state conditions (−24 °C) with and without the presence of organic dyes. The electroactivity of PPy prepared with MO and AB significantly increased in all electrolytic media with a capacitance higher than this of the PPy prepared at room temperature. The highest capacitance (1914 F g−1) was obtained for PPy-MO in 0.2 M HCl solution. The impedance spectra of PPy showed a decrease in charge transfer resistance when the dyes were present. This indicates a conductivity increase of PPy. Improved electrochemical stability was observed for PPy, PPy-MO, and PPy-AB prepared at −24 °C, wherein a steady gain of capacitance was maintained during 5000 potential cycling. In addition, a PPy-based supercapacitor device was fabricated to demonstrate the energy storage characteristics of PPy, where it showed good capacitive behavior and stability. Overall, frozen-state polymerized PPy posed an impressive capacitive performance for flexible supercapacitors.

The gravimetric capacitances (F g −1 ), C CV and C GCD , of each PPy-based electrode were calculated from the cyclic voltammograms and charge-discharge curves using the following equations: where IdV = area of voltammogram, m = mass of the active material (1.0 × 10 −5 g), ∆V is the potential window (−0.2 V to 0.8 V), v is the scan rate (V s −1 ), and I is the applied charge-discharge current (A).
Raman spectra of PPy-FS, PPy-MO, PPy-AB, and PPy-RT on GC electrodes were obtained through the excitation lines 785, 633, and 514 nm and were recorded with a Renishaw InVia Reflex Raman microspectrometer (Wotton-under-Edge, UK).Scattered light was analyzed using a spectrograph with holographic gratings of 1200, 1800, and 2400 lines mm −1 , respectively.A research-grade Leica DM LM microscope was used to focus the laser beam on the active material, which was fixed by a specific accessory to hold the electrode while moving the stage.A Peltier-cooled CCD detector (576 × 384 pixels) registered the dispersed light.

Supercapacitor Assembly
A slurry mixture was prepared consisting of 50 mg of PPy-MO, 550 µL of deionized water, 400 µL of isopropanol, and 50 µL of Nafion 117 solution.The obtained mixture was drop cast onto two symmetrical carbon cloths cut into 4 cm by 1 cm substrates and was dried in the oven at 60 • C for 3 h.The drop cast active material covered half of the area of the carbon cloth (2 cm by 1 cm).The two prepared symmetrical electrodes were sandwiched together, including a filter paper (grade: 388) soaked in 1 M H 2 SO 4 aqueous electrolyte as a separator.The total loaded mass density of the supercapacitor was 6.6 mg cm −2 .The assembly was then wrapped by a plastic insulator and pressed tightly, making sure that the electrolyte was trapped in the system.

Supercapacitive Characterization
Electrochemical studies of the assembled supercapacitor were performed through EC-Lab software V11.20 using Bio-Logic SAS VSP-300 potentiostat equipment.Electrochemical impedance spectroscopy was carried out within a frequency ranging from 0.1 Hz to 100,000 Hz.Cyclic voltammetry studies were performed at the scan rates 10, 20, 50, 100, and 200 mV s −1 in a potential window from −0.2 V to 0.8 V. Galvanostatic charge-discharge measurements were obtained at an applied constant current density varying from 1.5 to 4.5 A g −1 in the same potential range.The gravimetric capacitance in F g −1 of the supercapacitor was calculated using the area of the CV curve (C SCV ) and the slope of the discharge curve of the GCD (C SCD ) [48]: Polymers 2023, 15, 4140 4 of 17 where IdV is the integrated area of the CV curve, m is the mass of the active material in grams, v is the scan rate, I is the applied current, ∆t is the discharge time during the discharge process, ∆V is the working potential window, and k is the constant multiplier.In this study, the value of k was 4 since the masses of the active material on both electrodes were considered.The energy densities E S , Whkg −1 and power densities (P S, Wkg −1 were obtained from their GCD curves using the following equations: Moreover, a cycling stability test was carried out at 10,000 charge-discharge cycles at a 3 A g −1 current density.The total cell resistance was determined in two ways: (1) IR drop based on the potential drop on the discharge curves and (2) equivalent resistance (ESR) values based on the Nyquist plot of the device before and after 10,000 cycles.

PPy-Based Electrodes in Different Aqueous Electrolytes
Cyclic voltammograms of PPy-FS, PPy-MO, PPy-AB, and PPy-RT on GC electrodes were studied in different aqueous solutions (0.2 M HCl, 1 M H 2 SO 4 , 2 M KCl, and 6 M KOH) in a three-electrode system.In Figures S2-S5, the CV curves were obtained at scan rates: 10, 20, 50, 100, and 200 mV s −1 from −0.2 V to 0.8 V potential range.As seen in the CVs, the current density peak for each PPy-based electrode increased at an increasing scan rate.This behavior was observed in all aqueous electrolytes displaying the electroactive property of the electrodes.In particular, the obtained CVs in 0.2 M HCl, 1 M H 2 SO 4 , and 2 M KCl showed a consistent quasi-rectangular curve with symmetry in shape along the anodic and cathodic sweeps in all scan rates.These are indications that the overall capacitive behavior of the electrodes is ascribed to the contribution of both electric double-layer capacitance (EDLC) and pseudocapacitance (faradaic contribution).The current density peaks were relatively greater in acidic than in alkaline conditions, suggesting that the electroactivity of the PPy-based electrodes increased in the following order of electrolytes: HCl > H 2 SO 4 > KCl > KOH (as shown in Figures S2-S5).The electrochemical response in acidic electrolytes rapidly increased the current density for every scan rate increase, indicating a good capacitive performance.In the KOH solution, the voltammograms were not uniform in shape at an increasing scan rate.This can be attributed to the deprotonation of PPy in the alkaline solution, which resulted in lower conductivity and instability [46,47].Moreover, it was observed, in the KOH solution, that the electroactivity of PPy-based electrodes was at poor rate capacity due to its low current peaks.Thus, the capacitive performance in the acidic medium was better than in neutral and basic electrolytes.
The gravimetric capacitance of PPy-based electrodes was dependent on the area under the CV curve.Therefore, the larger the area of the voltammogram, the higher the calculated capacitance.Herein, the gravimetric capacitance of the PPy-based electrodes was calculated using Equation (1) and is shown in Figure 1 and Table S1.The capacitance decreased with the increasing scan rate since the diffusion time of charges/ions to the active material is faster at higher scan rates.The highest calculated capacitance was estimated at 10 mV s −1 in all electrolytic solutions.The determined capacitance in the HCl solution was the highest, followed by the capacitance values obtained in the H 2 SO 4 , KCl, and KOH solutions.Although both HCl and H 2 SO 4 are acidic electrolytes, their current response differs as their ionic size differs.Cl − ions are faster and easier to move across the diffusion path compared to SO 4 2− ions; hence, capacitance was higher in the HCl solution.
Polymers 2023, 15, 4140 5 of 17 10 mV s −1 in all electrolytic solutions.The determined capacitance in the HCl solution was the highest, followed by the capacitance values obtained in the H2SO4, KCl, and KOH solutions.Although both HCl and H2SO4 are acidic electrolytes, their current response differs as their ionic size differs.Cl − ions are faster and easier to move across the diffusion path compared to SO4 The GCD curves in Figures S6-S9 of PPy-based electrodes in all electrolytes exhibited a non-symmetric charge-discharge process for every applied current density.This was ascribed to the pseudocapacitive nature of PPy, which was cohesive with the CV results.The gravimetric capacitance of PPy-based electrodes was also calculated based on the discharge process at varying current densities using Equation (2).The capacitance values estimated from GCD curves are presented in Figure 2 and Table S2.The gravimetric capacitance values from the discharge curves exhibited a similar trend, wherein higher capacitance values were computed in acidic electrolytes.The CV and GCD curves proved the excellent electroactivity of PPy-based electrodes in acidic electrolytes.Hence, the electrochemical behavior of PPy-based electrodes in the acidic medium was better than in basic solutions owing to the high conductivity and fast charge transfer behavior of PPy.The GCD curves in Figures S6-S9 of PPy-based electrodes in all electrolytes exhibited a non-symmetric charge-discharge process for every applied current density.This was ascribed to the pseudocapacitive nature of PPy, which was cohesive with the CV results.The gravimetric capacitance of PPy-based electrodes was also calculated based on the discharge process at varying current densities using Equation (2).The capacitance values estimated from GCD curves are presented in Figure 2 and Table S2.The gravimetric capacitance values from the discharge curves exhibited a similar trend, wherein higher capacitance values were computed in acidic electrolytes.The CV and GCD curves proved the excellent electroactivity of PPy-based electrodes in acidic electrolytes.Hence, the electrochemical behavior of PPy-based electrodes in the acidic medium was better than in basic solutions owing to the high conductivity and fast charge transfer behavior of PPy.

The Frozen-State Polymerized PPy with Dyes and Its Capacitive Performance
Dye-incorporated PPy prepared in the frozen state displayed the formation of homogenous PPy nanostructures (check Figure S1), which greatly influenced the improvement of PPy's electrical conductivity.In this study, an in-depth investigation of the electrochemical properties of frozen-state polymerized PPy in the presence of organic dyes (MO and AB) was carried out.The calculated capacitance values of PPy-FS, PPy-RT, PPy-MO, and PPy-AB are presented in Tables S1 and S2 of the Supporting Information File.
In HCl solution, PPy-MO was observed to have the highest capacitance (1914 F g −1 ), followed by PPy-AB (1186 F g −1 ), PPy-FS (193 F g −1 ), and PPy-RT (20 F g −1 ) at 10 mV s −1 .Also, a similar course of electrochemical response was noticed based on PPy's computed capacitance from GCD curves at 5 A g −1 : PPy-MO (537 F g −1 ); PPy-AB (217 F g −1 ); PPy-FS (145 F g −1 ); and PPy-RT (9.1 F g −1 ).This large improvement in the capacitance of PPy was due to its morphological change caused by MO and AB.The presence of MO and AB modified the PPy morphology from globules to uniform nanostructures, as presented in Figure 1.This alteration of PPy's structural arrangement had a significant effect on PPy's capacitance.The interconnected structure and more uniform porosity in PPy-MO and PPy-AB promoted higher chances for the charges/ions to access the electrode surface at a shorter diffusion time.This was clearly evident on the higher current density peaks achieved by PPy-MO and PPy-AB compared to PPy-FS and PPy-RT.Moreover, PPy-MO and PPy-AB contain more electrochemically active sites, enabling full access for charges/ions to move from the electrolyte to the electrode, thereby resulting in a longer discharging process and higher gravimetric capacitance.By comparing the gaps in the capacitance values of PPy-MO and PPy-AB, this can be attributed to their differences in morphology, as PPy-MO contains nanotubular structures while PPy-AB has a nanofibrillar structural arrangement.

The Frozen-State Polymerized PPy with Dyes and Its Capacitive Performance
Dye-incorporated PPy prepared in the frozen state displayed the formation of homogenous PPy nanostructures (check Figure S1), which greatly influenced the improvement of PPy's electrical conductivity.In this study, an in-depth investigation of the electrochemical properties of frozen-state polymerized PPy in the presence of organic dyes (MO and AB) was carried out.The calculated capacitance values of PPy-FS, PPy-RT, PPy-MO, and PPy-AB are presented in Tables S1 and S2 of the Supporting Information File.
In HCl solution, PPy-MO was observed to have the highest capacitance (1914 F g −1 ), followed by PPy-AB (1186 F g −1 ), PPy-FS (193 F g −1 ), and PPy-RT (20 F g −1 ) at 10 mV s −1 .Also, a similar course of electrochemical response was noticed based on PPy's computed capacitance from GCD curves at 5 A g −1 : PPy-MO (537 F g −1 ); PPy-AB (217 F g −1 ); PPy-FS (145 F g −1 ); and PPy-RT (9.1 F g −1 ).This large improvement in the capacitance of PPy was The capacitance of CV curves of PPy-MO at 10 mV s −1 (169 F g −1 ) and PPy-AB (161 F g −1 ) in H 2 SO 4 solution had a similar trend when compared to pristine PPy prepared in the frozen state (102 F g −1 ) and at room temperature (9.3 F g −1 ).Likewise, the calculated PPy-MO capacitance (136 F g −1 ) at 5 A g −1 from GCD curves showed to be the highest.PPy-AB is next, having a capacitance of 76 F g −1 , followed by PPy-FS (33 F g −1 ) and PPy-RT (1.2 F g −1 ) measured at 5 A g −1 .This large increase in capacitance indicates the improved electrochemical behavior of PPy in the H 2 SO 4 electrolyte.It was noted from previous works that using H 2 SO 4 as an electrolyte for supercapacitors has led to higher capacitance with smaller equivalent series resistance (ESR) values because of its good ionic conductivity [49][50][51].Hence, this study opted to test the electrochemical properties of PPy with and without the presence of dyes in H 2 SO 4 solution for supercapacitor evaluation.
PPy-MO and PPy-AB were also experimented with a 2 M KCl solution.A large gap in the calculated capacitance from CV curves at 10 mV s −1 of PPy-MO (136 F g −1 ) and PPy-AB (72 F g −1 ) to the capacitance of PPy-FS (47 F g −1 ) and PPy-RT (6.8 F g −1 ) was observed.Similar behavior from charge-discharge curves at 5 A g −1 were seen for the computed capacitance of PPy-MO (134 F g −1 ), PPy-AB (63 F g −1 ), PPy-FS (16 F g −1 ), and PPy-RT (1.2 F g −1 ).As expected, even in a neutral solution, the capacitive behavior of PPy-MO and PPy-AB was excellent.This certainly proves that modifying the processability of preparing PPy has a positive outcome in enhancing its electrochemical properties.
Furthermore, the electrochemical performance of PPy-MO and PPy-AB in KOH solution was tested.In this electrolyte, PPy-MO and PPy-AB have relatively high peak currents compared to PPy-FS and PPy-RT based on their CV curves.The capacitance values of PPy-MO vary between 15 F g −1 and 92 F g −1 and between 14 F g −1 and 98 F g −1 for PPy-AB measured from 10 mV s −1 to 200 mV s −1 .This implies that, in alkaline conditions, PPy-MO and PPy-AB have good electroactivity.In spite of their good current response, the CVs are not stable or symmetric with the increase in scan rate.This can be attributed to the loss of conductivity of PPy in basic electrolytes.For this reason, charge-discharge measurements in KOH electrolytes were omitted.
EIS studies of PPy-FS, PPy-MO, and PPy-AB in various electrolytes were evaluated as well.In Figure 3, the Nyquist plots of PPy-based electrodes showed different spectral representations in different electrolytes.Semicircles were present in the high frequency region, indicating the charge transfer process taking place between the working electrode and the electrolyte [52].Straight lines of varying slopes were seen in the low frequency region, referring to the diffusion of charges/ions in the electrodes [52,53].Here, PPy-MO had the least charge transfer resistance, R ct (see Table S3), in all electrolytes, indicating its good conductivity, and then, it was succeeded by PPy-AB and PPy-FS.In the lower frequency region, the increase in the slope of the line refers to the increase of capacitive behavior of PPy.The Nyquist plots showed that the capacitance increased in the following order: PPy-MO > PPy-AB > PPy-FS, according to the increase of their slopes.Thus, we verified that the frozen-state polymerized PPy with the presence of dyes enhanced the overall electrochemical properties of PPy.Moreover, the collected data from Nyquist plots were fitted to obtain the equivalent electrochemical circuit (EEC) presented in Figure S10 and Table S4.The fit corresponds to the electrochemical processes occurring on the PPy-based electrode at this potential.Based on the acquired EEC, R 1 represents the total resistance of the electrode, which includes the bulk electrolyte and electrode resistances [54].R 2 represents R ct , which corresponds to the charge transfer resistance at a lower frequency.R 2 indicates the resistance involved during the diffusion of charges/ions between the polymer and electrolyte interface that usually occurs in the lower frequency region [54,55].The presence of constant phase elements, CPE 1 and CPE 2, in EEC reflects the non-ideal capacitive behavior of the PPy-based electrode [56].Its underlying physical basis can be attributed to the double-layer capacitive behavior of charges on an inhomogeneous electrode surface [56][57][58].The inhomogeneity on the electrode surface may be caused by the microscopic surface roughness, porosity, nature of the electrode, and the dynamic disorder associated with diffusion [57,58].The W in EEC refers to Warburg element, indicating the diffusion impedance of charges caused by the faradaic processes involved on the PPy-based electrode [54,58].
The capacitance retention of electrodes was measured through cyclic voltammetry in a three-electrode system (see Figure 4).In 5000 potential cycling, steady gain of capacitance was observed for all frozen-state polymerized PPy with and without the dyes added.PPy-FS (101%), PPy-MO (104%), and PPy-AB (106%) displayed outstanding stability that is very valuable for supercapacitor use.
Polymers 2023, 15, 4140 8 of 17 attributed to the double-layer capacitive behavior of charges on an inhomogeneous electrode surface [56][57][58].The inhomogeneity on the electrode surface may be caused by the microscopic surface roughness, porosity, nature of the electrode, and the dynamic disorder associated with diffusion [57,58].The W in EEC refers to Warburg element, indicating the diffusion impedance of charges caused by the faradaic processes involved on the PPybased electrode [54,58].The capacitance retention of electrodes was measured through cyclic voltammetry in a three-electrode system (see Figure 4).In 5000 potential cycling, steady gain of capacitance was observed for all frozen-state polymerized PPy with and without the dyes added.PPy-FS (101%), PPy-MO (104%), and PPy-AB (106%) displayed outstanding stability that is very valuable for supercapacitor use.

Spectroscopy Study
The molecular structures of PPy-RT, PPy-FS, PPy-MO, and PPy-AB before and after cycling stability tests were assessed by Raman spectroscopy.In Figure 5, the spectral features of PPy can be clearly distinguished and are in accordance with the previous reports [46,59].The Raman spectrum of PPy-FS exhibited an increase in the intensity of the band at 1079 cm −1 (C-H deformation in bipolaron) and a decrease in the intensity of the band at 1058 cm −1 (C-H deformation in polaron) as compared to the spectrum of PPy-RT.This corresponds to the increased protonated state of PPy-FS [60].After cycling stability tests, a significant change in the intensities of the two peaks 1380 cm −1 and 1322 cm −1 , which are attributed to the inter-ring stretching C-C vibration mode of PPy in bipolaron and polaron

Spectroscopy Study
The molecular structures of PPy-RT, PPy-FS, PPy-MO, and PPy-AB before and after cycling stability tests were assessed by Raman spectroscopy.In Figure 5, the spectral features of PPy can be clearly distinguished and are in accordance with the previous reports [46,59].The Raman spectrum of PPy-FS exhibited an increase in the intensity of the Polymers 2023, 15, 4140 9 of 17 band at 1079 cm −1 (C-H deformation in bipolaron) and a decrease in the intensity of the band at 1058 cm −1 (C-H deformation in polaron) as compared to the spectrum of PPy-RT.This corresponds to the increased protonated state of PPy-FS [60].After cycling stability tests, a significant change in the intensities of the two peaks 1380 cm −1 and 1322 cm −1 , which are attributed to the inter-ring stretching C-C vibration mode of PPy in bipolaron and polaron structures, respectively, was noticed in the spectrum of PPy-FS.This is probably because of the irreversible oxidation state of PPy-FS during electrochemical cycling.The Raman spectra of PPy-AB before and after the cycling stability test are given in Figure 6.The green solid lines refer to AB peaks and the black ones to PPy-FS characteristic peaks.Typical bands of AB dye molecule at 1407 cm −1 , 1364 cm −1 , 1325 cm −1 , and 1267 cm −1 are related to C=C and C-N stretching vibrations.Other peaks refer to the deformation vibrations of AB molecules located at 1158 cm −1 , 1037 cm −1 , 924 cm −1 , and 510 cm −1 [45].In addition, the small shoulder appearing at 1596 cm −1 in the PPy-AB spectrum belongs to C=C stretching in the bipolaron structure, which indicates a higher protonation state of PPy in the presence of the dye.The Raman spectra of PPy-AB before and after the cycling stability test are given in Figure 6.The green solid lines refer to AB peaks and the black ones to PPy-FS characteristic peaks.Typical bands of AB dye molecule at 1407 cm −1 , 1364 cm −1 , 1325 cm −1 , and 1267 cm −1 are related to C=C and C-N stretching vibrations.Other peaks refer to the deformation vibrations of AB molecules located at 1158 cm −1 , 1037 cm −1 , 924 cm −1 , and 510 cm −1 [45].In addition, the small shoulder appearing at 1596 cm −1 in the PPy-AB spectrum belongs to C=C stretching in the bipolaron structure, which indicates a higher protonation state of PPy in the presence of the dye.The Raman spectra of PPy-AB before and after the cycling stability test are given in Figure 6.The green solid lines refer to AB peaks and the black ones to PPy-FS characteristic peaks.Typical bands of AB dye molecule at 1407 cm −1 , 1364 cm −1 , 1325 cm −1 , and 1267 cm −1 are related to C=C and C-N stretching vibrations.Other peaks refer to the deformation vibrations of AB molecules located at 1158 cm −1 , 1037 cm −1 , 924 cm −1 , and 510 cm −1 [45].In addition, the small shoulder appearing at 1596 cm −1 in the PPy-AB spectrum belongs to C=C stretching in the bipolaron structure, which indicates a higher protonation state of PPy in the presence of the dye.For PPy-MO, the orange solid lines refer to MO distinctive spectral peaks, and the black ones refer to the spectral features of PPy-FS.Raman spectra of PPy-MO were measured using a 514 nm excitation line since it is in resonance with the energetic transitions in MO.The following are the detected vibrational features of MO: 1621 cm −1 (N-H inplane deformation), 1495 cm −1 (N-ring stretching), 1265 cm −1 (C-N stretching, N-H stretching), 1174 cm -1 (N-N bending), 1114 cm −1 (S-O stretching), 1142 cm −1 (C-S stretching), 1364 cm −1 (S-ring and C-C stretching), 1384 cm −1 (C-SO2-O) stretching), and 1402 cm −1 (N=N stretching) [42].
After long potential cycling, there were no Raman shifts in the spectral bands of PPy-MO and PPy-AB.Therefore, the stability of the molecular structure of PPy was improved in the presence of MO and AB.

Supercapacitor Assembly
A flexible supercapacitor device was constructed using the as-prepared PPy-MO as the active material for the two-electrode cell.PPy-MO was chosen since it has the best electrochemical performance among the rest of the PPy-based materials studied here.The assembled flexible supercapacitor was examined in two positions, (1) in normal and (2) folded orientations (see Figure 7), in order to test the supercapacitive behavior of the device when its orientation varied.Different electrochemical methods (CV, GCD, EIS, and stability measurements) were conducted to study the prototype.For PPy-MO, the orange solid lines refer to MO distinctive spectral peaks, and the black ones refer to the spectral features of PPy-FS.Raman spectra of PPy-MO were measured using a 514 nm excitation line since it is in resonance with the energetic transitions in MO.The following are the detected vibrational features of MO: 1621 cm −1 (N-H in-plane deformation), 1495 cm −1 (N-ring stretching), 1265 cm −1 (C-N stretching, N-H stretching), 1174 cm −1 (N-N bending), 1114 cm −1 (S-O stretching), 1142 cm −1 (C-S stretching), 1364 cm −1 (S-ring and C-C stretching), 1384 cm −1 (C-SO 2 -O) stretching), and 1402 cm −1 (N=N stretching) [42].
After long potential cycling, there were no Raman shifts in the spectral bands of PPy-MO and PPy-AB.Therefore, the stability of the molecular structure of PPy was improved in the presence of MO and AB.

Supercapacitor Assembly
A flexible supercapacitor device was constructed using the as-prepared PPy-MO as the active material for the two-electrode cell.PPy-MO was chosen since it has the best electrochemical performance among the rest of the PPy-based materials studied here.The assembled flexible supercapacitor was examined in two positions, (1) in normal and (2) folded orientations (see Figure 7), in order to test the supercapacitive behavior of the device when its orientation varied.Different electrochemical methods (CV, GCD, EIS, and stability measurements) were conducted to study the prototype.For PPy-MO, the orange solid lines refer to MO distinctive spectral peaks, and the black ones refer to the spectral features of PPy-FS.Raman spectra of PPy-MO were measured using a 514 nm excitation line since it is in resonance with the energetic transitions in MO.The following are the detected vibrational features of MO: 1621 cm −1 (N-H inplane deformation), 1495 cm −1 (N-ring stretching), 1265 cm −1 (C-N stretching, N-H stretching), 1174 cm -1 (N-N bending), 1114 cm −1 (S-O stretching), 1142 cm −1 (C-S stretching), 1364 cm −1 (S-ring and C-C stretching), 1384 cm −1 (C-SO2-O) stretching), and 1402 cm −1 (N=N stretching) [42].
After long potential cycling, there were no Raman shifts in the spectral bands of PPy-MO and PPy-AB.Therefore, the stability of the molecular structure of PPy was improved in the presence of MO and AB.

Supercapacitor Assembly
A flexible supercapacitor device was constructed using the as-prepared PPy-MO as the active material for the two-electrode cell.PPy-MO was chosen since it has the best electrochemical performance among the rest of the PPy-based materials studied here.The assembled flexible supercapacitor was examined in two positions, (1) in normal and (2) folded orientations (see Figure 7), in order to test the supercapacitive behavior of the device when its orientation varied.Different electrochemical methods (CV, GCD, EIS, and stability measurements) were conducted to study the prototype.) in normal and folded positions.The voltammograms showed a high current response to the quasi-rectangular shape similar to the CVs of PPy-MO obtained in a three-electrode system.The increase of the current with respect to scan rate evidently confirmed the outstanding electrochemical activity of the PPy-MO-based supercapacitor.The CV curve in the folded position was on a par with the normal one, indicating the good stability of the constructed device.At scan rates above 50 mV s −1 , the charge transfer process became faster, which limited the diffusion of charges/ions following the deviation of CVs from the quasi-rectangular shape.Galvanostatic chargedischarge measurements were performed at an applied current density that varied from 1.5 A g −1 to 4.5 A g −1 , as shown in Figure 8C,D.The GCD curves of the device in both orientations illustrate a non-symmetric triangular form akin to the GCD curves observed in the three-electrode system.Figure 8A,B shows the CV curves of the supercapacitor device at different scan rates (10, 20 50, 100, and 200 mV s −1 ) in normal and folded positions.The voltammograms showed a high current response to the quasi-rectangular shape similar to the CVs of PPy-MO obtained in a three-electrode system.The increase of the current with respect to scan rate evidently confirmed the outstanding electrochemical activity of the PPy-MO-based supercapacitor.The CV curve in the folded position was on a par with the normal one, indicating the good stability of the constructed device.At scan rates above 50 mV s −1 , the charge transfer process became faster, which limited the diffusion of charges/ions following the deviation of CVs from the quasi-rectangular shape.Galvanostatic charge-discharge measurements were performed at an applied current density that varied from 1.5 A g −1 to 4.5 A g −1 , as shown in Figure 8C,D.The GCD curves of the device in both orientations illustrate a non-symmetric triangular form akin to the GCD curves observed in the three-electrode system.The capacitance of the device was determined using Equations ( 3) and (4), respectively.As shown in Table 1, the decrease in capacitance with respect to the increase in scan rate was caused by the high current response demonstrated by the PPy-MO-based supercapacitor.The highest computed capacitance was at 10 mV s −1 , equivalent to 122 F g −1 in the normal position, and it slightly decreased to 105 F g −1 when folded.Likewise, as the applied current density increased, the capacitance decreased as well because of the fast chargedischarge performance of the device.At the applied current density of 1.5 A g −1 , the capacitance was 116 F g −1 (in normal position), and the capacitance lowered to 107 A g −1 in the folded state.The capacitance difference in both orientations was certainly observed since the charge transfer process changed as the device shifted positions.Yet, there was no significant disparity between the capacitive behavior of the folded and unfolded device, as the capacitance values remained in the same order of magnitude.This proves that the PPy-MO-based supercapacitor has good charge storage characteristics with good flexibility.The energy density, power density, and Ragone plot of the PPy-MO-based supercapacitor are provided in Figure 9A and Table 1.The energy density and power density of the device in normal form were 16 Wh kg −1 and 3026 W kg −1 at 1.5 A g −1 , respectively.The energy density lowered to 15 Wh kg −1 when the device was folded at 1.5 A g −1 .Also, the power density reached up to 9077 W kg −1 at 4.5 A g −1 .The measured energy and power densities of the PPy-MO-based supercapacitor were higher than or comparable to the recently reported PPy-based symmetric supercapacitors [60][61][62][63][64][65][66][67][68][69][70], as illustrated in Figure 9B.The capacitance retention of the device was estimated for 10,000 charge-discharge cycles.Figure 9C shows the capacitance retention of the PPy-MO-based device in normal and folded position.After 10,000 cycles, the capacitance of the normally positioned device was retained at 89%, and only a small increase in IR drop was noticed as shown in Figure 9D.When folded, the capacitance retention was down to 56%, with a larger increase in IR drop after long cycling.In addition, the capacitance declined faster beyond 5000 cycles for both positions as a result of the drying of the electrolyte during the entire measurement period.The comparison of the capacitance retention and ESR values of the PPy-MO-based supercapacitor to other PPy-based supercapacitors was presented in Table S5.The assembled PPy-MO-based device showed good and comparable stability and ESR values, contrary to other PPy-based materials.
Moreover, ESR values of the device were also determined before and after its cycling stability experiment (see Figure 9E,F).The ESR value of the device in the normal position was initially low (1.63 Ω), and after 10,000 cycles, its ESR slightly increased to 1.84 Ω.When folded, its ESR was at 1.69 Ω then increased marginally to 1.83 Ω after long cycling.These observations were consistent with the IR drop increase after cycling stability.In addition, the small ESR difference between before and after cycling stability revealed the good electrical and ionic conductivity of the supercapacitor, regardless of the magnitude of its capacitance.Nonetheless, the stability and energy storage properties of PPy-MO can be considered competent for improvising an efficient flexible supercapacitor.Moreover, ESR values of the device were also determined before and after its cycling stability experiment (see Figure 9E,F).The ESR value of the device in the normal position was initially low (1.63 Ω), and after 10,000 cycles, its ESR slightly increased to 1.84 Ω.When folded, its ESR was at 1.69 Ω then increased marginally to 1.83 Ω after long cycling.These observations were consistent with the IRdrop increase after cycling stability.In addition, the small ESR difference between before and after cycling stability revealed the good electrical  [61], PPy/GO/MnOx [62], PPyMO-2h [63], PPy@a-NCFs [64], PPy/MnOx/Na-CMC [65], PPy hydrogel [66], GO-PPy-Ag [67], HHAc/PPy [68], TP2(PPy hydrogel) [69], PVA-GO-PPy [70]).

Conclusions
This work demonstrated the electrochemical properties of PPy prepared with and without the presence of MO and AB in frozen conditions (−24 • C) and its applicability for supercapacitors.PPy-MO presented remarkable capacitive features, including the highest gravimetric capacitance of 1914 F g −1 at 10 mV s −1 and 537 F g −1 at 5.0 A g −1 in the HCl aqueous electrolyte.The Raman spectra of frozen-state polymerized PPy-FS, PPy-MO, and PPy-AB manifested a stable molecular arrangement even after 5000 potential cycling.The

Figure 3 .
Figure 3. Impedance spectra of PPy and PPy with dyes prepared in the frozen state in 0.2 M HCl, 2 M KCl, 6 M KOH, and 1 M H2SO4.

Figure 3 .Figure 4 .
Figure 3. Impedance spectra of PPy and PPy with dyes prepared in the frozen state in 0.2 M HCl, 2 M KCl, 6 M KOH, and 1 M H 2 SO 4 .

Figure 7 .
Figure 7. Assembled flexible supercapacitor in normal and folded orientations.

Figure
Figure 8A,B shows the CV curves of the supercapacitor device at different scan rates (10, 20 50, 100, and 200 mV s −1 ) in normal and folded positions.The voltammograms showed a high current response to the quasi-rectangular shape similar to the CVs of PPy-MO obtained in a three-electrode system.The increase of the current with respect to scan

Figure 7 .
Figure 7. Assembled flexible supercapacitor in normal and folded orientations.

Figure 8 .
Figure 8. (A,B) CV curves of the PPy-MO-based supercapacitor device (in normal and folded positions) measured at 10, 20, 50, 100, and 200 mV s −1 scan rates.(C,D) GCD curves of the normal and folded PPy-MO-based supercapacitor device at varying current densities from 1.5 A g −1 to 4.5 A g −1 .

Figure 8 .
Figure 8. (A,B) CV curves of the PPy-MO-based supercapacitor device (in normal and folded positions) measured at 10, 20, 50, 100, and 200 mV s −1 scan rates.(C,D) GCD curves of the normal and folded PPy-MO-based supercapacitor device at varying current densities from 1.5 A g −1 to 4.5 A g −1 .
2−ions; hence, capacitance was higher in the HCl solution.

Table 1 .
Estimated capacitance, energy density, and power density of the PPy-MO-based supercapacitor device at varying scan rates and current densities.