Synthesis of a Low-Cost Thiophene-Indoloquinoxaline Polymer Donor and Its Application to Polymer Solar Cells

A simple wide-bandgap conjugated polymer based on indoloquinoxaline unit (PIQ) has been newly designed and synthesized via cheap and commercially available starting materials. The basic physicochemical properties of the PIQ have been investigated. PIQ possesses a broad and strong absorption band in the wavelength range of 400~660 nm with a bandgap of 1.80 eV and lower-lying highest occupied molecular orbital energy level of −5.58 eV. Polymer solar cells based on PIQ and popular acceptor Y6 blend display a preliminarily optimized power conversion efficiency of 6.4%. The results demonstrate indoloquinoxaline is a promising building unit for designing polymer donor materials for polymer solar cells.


Introduction
Polymer solar cells (PSCs) are attractive as a promising new energy device for solarto-electric conversion [1]. In a typical device, the active-layer blending film consists of a donor material and an acceptor material [2,3]. One of the most successful blends in recent years contains a p-type polymer as the donor and an n-type non-fullerene molecule as the acceptor [4]. Thanks to rational molecular design and device optimization [5], the power conversion efficiencies (PCEs) of PSCs have consistently improved [6]. However, one issue that must be critically considered is the cost of the active-layer materials [7,8]. Because of the complicated molecular structures, tedious multi-step organic synthesis, and laborious purifications, the costs of the efficient active-layer materials reported so far were too high to meet commercial application of PSCs [9]. Therefore, developing low-cost and efficient active-layer materials is one of the key challenges for the application of PSCs [10,11].
Recently, a low-cost and high-performance polymer donor, PTQ10 [12], has been demonstrated as a promising polymer donor for commercial application of PSCs. Compared to the classical benzo [1,2-b:4,5-b ] dithiophene (BDT)-based polymers [13][14][15] (see Figure 1a) synthesized via multi-step synthesis, PTQ10 has a very simple molecular structure (see Figure 1b), and it can be synthesized via simple two-step reactions with cheap raw materials. Lowcost and efficient polymer donors have gained relative less attention in recent years, and only a few polymers with these features have been developed until now [9]. We had reviewed and summarized the representative low-cost and efficient polymer donors (see Table S1 and Figure S7). It was shown that these types of polymers are promising donor materials for high-performance PSCs [16][17][18][19][20][21][22]. Therefore, we expected to develop new low-cost and efficient polymer donors. Indolo [2,3-b] quinoxaline (IQ) is a unique planar built-in donor unit that can be considered as the fusion of electron-deficient quin rich indole. Some IQ small molecular derivatives have been applie functional anti-Alzheimer agents [23], photosensitizers [24][25][26], hol rials [27] and non-fullerene acceptors [28]. In this work, we design meric p-type semiconductor material (PIQ) for polymer solar cells. strategy is shown in Figure. 1c. This polymer contains simple thio substituted IQ units with two-dimensional (2D) conjugated backbo structure is favorable for intermolecular carrier transporting [29-3 the IQ unit is to improve molecular planarity via S···F non-covalen ther enhance carrier transporting [32][33][34][35]. The alkyl side chain on t good solubility.

Synthesis of the Polymer PIQ
,5-bis(trimethylstannyl)thiophene (0.2 mmol, 0.0828 g), and toluene (6 mL) were added to a oven-dried Schlenk tube (100 mL) under argon atmosphere. The mixture was degassed with argon for 30 min. Next, Pd 2 (dba) 3 (0.004 mmol, 0.0037 g) and P(o-tolyl) 3 (0.016 mmol, 0.009 g) were added. After being degassed with argon for another 10 min, the tube was sealed. The tube was placed in a 110 • C oil bath. After 48 h, it was cooled down to room temperature. The reaction mixture was poured into stirring methanol to precipitate the crude product. The precipitate was collected by filtration and was further purified by sequential Soxhlet extractions with methanol and petroleum ether. The residue after Soxhlet extractions was then extracted with chloroform. The chloroform solution was re-precipitated with methanol. The resulting solid was collected and then dried to obtain the title polymer (0.0989 g, 80.3%) as a purple-black solid.

Device Fabrication and Characterization
The OPV device structure was set to ITO/PEDOT:PSS/PIQ:Y6/PDINN/Ag. The ITO glass substrates were ultrasonicated in deionized water with various reagents (acetone and 1,2-propanol), and dried in ambient atmosphere for 15 h. The dried glass substrates were treated with UV ozone for 20 min, and the PEDOT:PSS layers were spin-coated onto substrates at 7000 rpm for 60 s. The PEDOT:PSS layers had a thickness of 30 nm. Next, the film underwent an annealing process in the air at 150 • C for 15 min. The substrates were transferred into an Ar-filled glove box to spin-coat the active layers. The active layer materials PIQ and Y6 were dissolved in chloroform with a 1:1 weight ratio at a total concentration of 16.8 mg/mL. The solution of the PIQ and Y6 was subsequently spin-coated onto the hole transport layer (PEDOT: PSS), and the spin speed was 2000 rpm for 50s, to form ca. 80 nm uniform active layers. After that, the active layer needed to anneal for 12 min at 100 • C in the vacuum glove box. Finally, a thin PDINN layer (ca. 1 nm) and Ag (ca. 120 nm) were evaporated in a high vacuum chamber (ca. 4 × 10 −6 torr). After this step, the device can be used for corresponding characterizations. Under AM1.5 solar illumination, J-V curves were measured by PV Test Solutions solar simulator. The external quantum efficiency (EQE) of the solar cells was tested using Zolix SolarCellScan 100.

Results and Discussion
PIQ can be synthesized with low cost via a three-step reaction from cheap raw materials. Two synthetic routes were explored to obtain monomer 3 with indoline-2,3-dione as the cheap raw material. N-alkylation reaction between 1-(2-octyldodecyl)indoline-2,3-dione and 9-(iodomethyl)nonadecane was used to synthesize compound 1 in a high yield of 97.4%. The acetic acid-catalyzed condensation reaction between compound 1 and 3,6-dibromo-4,5-difluorobenzene-1,2-diamine was conducted to synthesize monomer 3 Polymers 2022, 14, 1554 5 of 10 in a low yield of 28.9%. Thus, monomer 3 was obtained with a low overall yield of 28% through this synthetic route. An improved route is to conduct the acetic acid-catalyzed condensation reaction followed by the N-alkylation reaction, as monomer 3 could be obtained with a reasonable overall yield of 46%. The Stille cross-coupling polycondensation of 2,5-bis(trimethylstannyl) thiophene and monomer 3 was performed to gain the target polymer PIQ as a purple-black solid (80.3% yield). The number average molecular weight and polydispersity index for PIQ were 7.1 kDa and 1.98, respectively, and PIQ had good solubility in common organic solvents. We performed synthesis cost calculations of the polymer PIQ using the model developed by Li et al. [36], which can be used as a rough indication of synthetic complexity. The results were displayed in Supporting Information (see Table S2). The cost of PIQ synthesized via route 1 is approximately 414.3 ¥/g, whereas the cost of PIQ synthesized via route 2 is approximately 241.1 ¥/g. The latter is significantly lower than the former, indicating that route 2 is the preferable route. As shown in Table S3, the synthesis cost of PIQ is compared to those of some famous polymer donors (e.g., PTQ10, PBDB-T, and PM6) [37][38][39].

Optical Properties
To study the optical properties of polymer PIQ, the UV-vis absorption spectra of monomer 3 and PIQ were tested. The photograph and absorption spectra of monomer 3 and polymer PIQ in dilute chlorobenzene solutions are shown in Figure 2a. PIQ solution exhibited absorption edge at 663 nm, which red-shifted over 188 nm relative to the monomer 3 solution. Introduction of the electron-donating thiophene to conjugated backbone can significantly enhance electronic delocalization along the chain axis via intramolecular charge transfer [40][41][42]. The monomer 3 solution has a strong absorption at 400-470 nm with a maximum absorption coefficient (ε) of 1.25×10 5 M −1 cm −1 , whereas the polymer PIQ solution has a much larger range of absorption, showing strong absorption in the 400-660 nm range with a slightly higher maximum absorption coefficient of 1.37 × 10 5 M −1 cm −1 (Figure 2b). The absorption spectra of PIQ as a thin film is also displayed in Figure 2a. Compared to that of its solution, a distinct red shift by 22 nm was observed due to stronger aggregation in a solid state. The bandgap of PIQ as a thin film was estimated to be 1.80 eV, which could be comparable to that of PTQ10 and matched well with the typical low-bandgap acceptor of Y6 (see Figure S9 for its molecular structure) to show a complementary absorption [12,43]. The optical properties of PIQ are summarized in Table 1.

EER REVIEW 5 of 10
(see Table S2). The cost of PIQ synthesized via route 1 is approximately 414.3 ¥/g, whereas the cost of PIQ synthesized via route 2 is approximately 241.1 ¥/g. The latter is significantly lower than the former, indicating that route 2 is the preferable route. As shown in Table S3, the synthesis cost of PIQ is compared to those of some famous polymer donors (e.g., PTQ10, PBDB-T, and PM6) [37][38][39].

Optical Properties
To study the optical properties of polymer PIQ, the UV-vis absorption spectra of monomer 3 and PIQ were tested. The photograph and absorption spectra of monomer 3 and polymer PIQ in dilute chlorobenzene solutions are shown in Figure 2a. PIQ solution exhibited absorption edge at 663 nm, which red-shifted over 188 nm relative to the monomer 3 solution. Introduction of the electron-donating thiophene to conjugated backbone can significantly enhance electronic delocalization along the chain axis via intramolecular charge transfer [40][41][42]. The monomer 3 solution has a strong absorption at 400-470 nm with a maximum absorption coefficient (ε) of 1.25×10 5 M −1 cm −1 , whereas the polymer PIQ solution has a much larger range of absorption, showing strong absorption in the 400-660 nm range with a slightly higher maximum absorption coefficient of 1.37 × 10 5 M −1 cm −1 (Figure 2b). The absorption spectra of PIQ as a thin film is also displayed in Figure 2a. Compared to that of its solution, a distinct red shift by 22 nm was observed due to stronger aggregation in a solid state. The bandgap of PIQ as a thin film was estimated to be 1.80 eV, which could be comparable to that of PTQ10 and matched well with the typical lowbandgap acceptor of Y6 (see Figure S9 for its molecular structure) to show a complementary absorption [12,43]. The optical properties of PIQ are summarized in Table 1.

Electrochemical Properties
The electronic energy levels of PIQ were measured by electrochemical cyclic voltammetry ( Figure 3). The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular (LUMO) levels of PIQ were estimated to be −5.58/−3.51 eV from the first onset oxidation and onset reduction potentials, respectively. The electrochemical properties of PIQ are also summarized in Table 1. The value of the electrochemical band gap for PIQ thin film was found to be 2.07 eV, which was larger than that of its optical band gap (1.8 eV). This may be due to the exciton binding energy for conjugated polymers [44].
Polymers 2022, 14, x FOR PEER REVIEW thin film was found to be 2.07 eV, which was larger than that of its optical band ga eV). This may be due to the exciton binding energy for conjugated polymers [44].

Thermal Properties and X-ray Diffraction Characterization
The thermal stability of the PIQ polymer was tested by thermogravimetric an by taking approximately 6 mg of sample and placing it in an alumina ceramic cr under nitrogen protection at a temperature increase rate of 20 °C/min up to 600 °C mass change of the sample at different temperatures was observed by heating. O polymer semiconductor materials can be considered to have good thermal stability the temperature of 5% thermal weight loss is above 300 °C, which fully meets the re ments of optoelectronic device construction and testing. The temperature of 5% th weight loss of PIQ was 464 °C (see Figure S6), indicating that PIQ has good therm bility.
To investigate the crystallinity of PIQ film, the X-ray diffraction (XRD) measur was performed on a drop-cast film of PIQ ( Figure S6). The sample showed distin peak at 5.17°, corresponding to a lamellar distance of 17.08 Å.

Photovoltaic Properties and Photoluminescence Characterization
To study the photovoltaic properties of PIQ, we fabricated BHJ polymer sola with a device structure of ITO/PEDOT:PSS/PIQ:Y6/PDINN/Ag (Figure 4c). The sponding energy level diagram of the related materials is shown in Figure 4d. The mer PIQ and Y6 were dissolved in chloroform. Devices with a donor/acceptor (D/A

Thermal Properties and X-ray Diffraction Characterization
The thermal stability of the PIQ polymer was tested by thermogravimetric analysis by taking approximately 6 mg of sample and placing it in an alumina ceramic crucible under nitrogen protection at a temperature increase rate of 20 • C/min up to 600 • C. The mass change of the sample at different temperatures was observed by heating. Organic polymer semiconductor materials can be considered to have good thermal stability when the temperature of 5% thermal weight loss is above 300 • C, which fully meets the requirements of optoelectronic device construction and testing. The temperature of 5% thermal weight loss of PIQ was 464 • C (see Figure S6), indicating that PIQ has good thermal stability.
To investigate the crystallinity of PIQ film, the X-ray diffraction (XRD) measurement was performed on a drop-cast film of PIQ ( Figure S6). The sample showed distinct 100 peak at 5.17 • , corresponding to a lamellar distance of 17.08 Å.

Photovoltaic Properties and Photoluminescence Characterization
To study the photovoltaic properties of PIQ, we fabricated BHJ polymer solar cells with a device structure of ITO/PEDOT:PSS/PIQ:Y6/PDINN/Ag (Figure 4c). The corresponding energy level diagram of the related materials is shown in Figure 4d. The polymer PIQ and Y6 were dissolved in chloroform. Devices with a donor/acceptor (D/A) ratio of 1:1 were fabricated. As illustrated in Figure 4a, a power conversion efficiency (PCE) of 6.41% was achieved with the fill factor (FF) of 46.6%, combined with the J SC of 18.65 mA/cm 2 ) and V OC of 0.737 V. The J SC value of polymer solar cells can be confirmed by the external quantum efficiency (EQE) measurement, and the result is shown in Figure 4b. Thin-film photoluminescence (PL) spectra of PIQ, PIQ:Y6 blend were measured ( Figure 5). Blending PIQ with Y6 results in strong fluorescence quenching, indicating efficient photo-induced charge transfer [2,45] between PIQ and Y6 in blend.

Conclusions
In summary, a new polymer donor, PIQ, has been developed. PIQ can be easily gained via a simple three-step reaction from cheap raw materials with reasonable overall yield. PIQ has a medium bandgap of 1.80 eV, a broad and strong absorption feature in the wavelength range of 400~650 nm, and a low-lying HOMO energy level. The PSCs based on binary blend with PIQ as donor and Y6 as acceptor displayed a reasonable PCE of 6.41%. We believe that the tuning of physicochemical properties of the PIQ via optimization of conjugated backbones and side chains and its polymerization reaction may bring about further improvement in photovoltaic performance. We have developed the indoloquinoxaline-based polymer as the donor material for organic solar cells, and we also believe that indoloquinoxaline-based polymers can be promising low-cost and efficient polymer donor photovoltaic materials.
Supplementary Materials: The following supporting information can be downloaded at: www.mdpi.com/xxx/s1, Figures S1-S3: NMR spectrum; Figure S4: GPC test result of the polymer

Conclusions
In summary, a new polymer donor, PIQ, has been developed. P gained via a simple three-step reaction from cheap raw materials with r yield. PIQ has a medium bandgap of 1.80 eV, a broad and strong absorp wavelength range of 400~650 nm, and a low-lying HOMO energy level on binary blend with PIQ as donor and Y6 as acceptor displayed a re 6.41%. We believe that the tuning of physicochemical properties of the P

Conclusions
In summary, a new polymer donor, PIQ, has been developed. PIQ can be easily gained via a simple three-step reaction from cheap raw materials with reasonable overall yield. PIQ has a medium bandgap of 1.80 eV, a broad and strong absorption feature in the wavelength range of 400~650 nm, and a low-lying HOMO energy level. The PSCs based on binary blend with PIQ as donor and Y6 as acceptor displayed a reasonable PCE of 6.41%. We believe that the tuning of physicochemical properties of the PIQ via optimization of conjugated backbones and side chains and its polymerization reaction may bring about further improvement in photovoltaic performance. We have developed the indoloquinoxaline-based polymer as the donor material for organic solar cells, and we also believe that indoloquinoxaline-based polymers can be promising low-cost and efficient polymer donor photovoltaic materials.
Supplementary Materials: The following supporting information can be downloaded at: https:// www.mdpi.com/article/10.3390/polym14081554/s1, Figures S1-S3: NMR spectrum; Figure S4: GPC test result of the polymer PIQ; Figure S5: TGA curve of the polymer PIQ; Figure S6: XRD pattern of the polymer PIQ thin film; Figure S7: Chemical structures of polymer donors involved in Table S1; Figure S8: Chemical structures of PBDB-T and PBDB-T-2F; Figure S9: Chemical structures of Y6; Table S1: Survey of polymer solar cells based on some representative low-cost and efficient donor polymers materials; Table S2: Survey of calculated chemical synthesis costs for PIQ; Table S3: Comparison of the synthetic steps and synthesis costs for polymer donor materials.

Data Availability Statement:
The data presented in this study are available on request from the corresponding author.

Conflicts of Interest:
The authors declare no conflict of interest.