Synthesis of Iron(II) Clathrochelate-Based Poly(vinylene sulfide) with Tetraphenylbenzene Bridging Units and Their Selective Oxidation into Their Corresponding Poly(vinylene sulfone) Copolymers: Promising Materials for Iodine Capture

The development of a simple and efficient synthetic methodology to engineer functional polymer materials for gas adsorption is necessary due to its relevance for various applications. Herein, we report the synthesis of metalorganic poly(vinylene sulfide) copolymers CTP1-3 with iron(II) clathrochelate of various side groups connected by tetraphenylbenzene units. CTP1-3 were subsequently oxidized into their respective poly(vinylene sulfone) copolymers CTP4-6 under green reaction conditions. The target copolymers CTP1-6 were characterized using various instrumental analysis techniques. Examination of the iodine adsorption properties of the copolymers revealed high iodine uptake properties, reaching 2360 mg g−1 for CTP2, and whose reusability tests proved its efficient regeneration, thus proving the importance of iron(II) clathrochelate polymers in iodine capture.


Introduction
The global demand for energy is drastically increasing due to the surge in world population and economic development. Energy consumed in 2021 has achieved a historical world record [1] and it is estimated that by 2040 the worldwide demand for primary energy will exceed 800 quadrillion British thermal units [2]. Since the industrial revolution, fossil fuels have always been employed as the chief energy source, accounting for~82% of the total energy consumed in 2021 [1]. This major reliance on fossil fuel combustion to produce energy entails serious impacts on the environment caused by the emission of various harmful gases into the atmosphere, namely, carbon dioxide, which contributes to global warming, and nitrogen and sulfur oxides (i.e., NOx and SOx), which produce acid rain and release particulate matter (PM) that leads to smog formation, thus, bringing about serious environmental and health complications [3][4][5][6]. These risks have consequently led to global initiatives and extensively funded research programs to find alternative energy sources with properties that overcome the hurdles encountered with fossil fuels: namely, renewability, efficiency, and zero-or low-greenhouse gases emission. Interestingly, renewable energy resources continue to grow strongly every year, showing a~17% increase in 2021, and thus accounting for~13% of the total power generation during that year [1].
Nuclear power is amongst the most important sources to produce large-scale renewable energy in the world [7]. Ideally, nuclear energy is rather safe, economically competitive,

Characterization Techniques
Thin layer chromatography (TLC) was performed on aluminum sheets coated with silica gel 60 F254 and revealed using a UV lamp. NMR ( 1 H: 600 MHz, 13 C: 150 MHz) spectra were recorded using a Bruker BioSpin GmbH 600 MHz spectrometer using DMSO-d 6 , CDCl 3 , and CD 2 Cl 2 as a solvent with the chemical shifts (δ) given in ppm and referenced to tetramethylsilane (TMS). Electron impact high-resolution mass spectra (EI-HRMS) were recorded on a Thermo Scientific DFS system with a standard PFK (perfluorokerosene) as a lock mass. The analyzed data were converted to accurate mass employing the Xcalibur accurate mass calculation software. UV-Vis spectra were recorded using a Shimadzu UV1800 spectrophotometer. FTIR spectra were recorded on an FT/IR-6300 type A instrument using a KBr matrix. Thermogravimetric analysis (TGA) was recorded on a Shimadzu TGA-60H (Kyoto, Japan) analyzer and used to measure the thermal stability of composites. TGA was carried out from room temperature to 800 • C. The heating rate was kept at 10 • C/min under inert atmosphere using pure nitrogen. X-ray photoelectron spectroscopy (XPS) data were recorded with a Thermo ESCALAB 250 Xi using a monochromatic Al K-radiation source (1486.6 eV) with a spot size of 850 µm. Spectra acquisition and processing were carried out using the software Thermo Advantage Version 4.87. The base pressure in the XPS analysis chamber was in the range 10 −10 to 10 −9 torr. The analyzer was operated with pass energy of 20 eV, dwell time of 50 min, and with a step size of 0.1 eV. Agilent Gel Permeation Chromatography (GPC/SEC) equipped with two columns (PL mixed-C) and calibrated against twelve monodisperse polystyrene (PS) standards, using THF as eluent at a flow rate of 1.0 mL min −1 , was employed to determine the relative weight-average (Mw) and number-average (Mn) molecular weights, and polydispersity index (Ð = M w /M n ) of all the reported polymers.

Iodine Adsorption Studies of CTP1-6
A 25 mg sample of a given copolymer (CTP1-6) and iodine flakes were placed in two connected and closed pre-weighed bottles. The vessel was degassed and maintained at 80 • C. The iodine uptake was measured at different time intervals and the amount of iodine adsorbed was calculated using the following equation [50]: where M 2 and M 1 are the masses of the given copolymer after and before iodine uptake, respectively.

Adsorption Equilibrium and Kinetics
The adsorption kinetics were explored using the pseudo-first-order and pseudosecond-order models, expressed respectively in Equations (2) and (3) below [50]: t/Q t = t/Q e + 1/K 2 Q e 2 (3) where Q t (mg g −1 ) and Q e (mg g −1 ) denote the amounts of iodine adsorbed per gram adsorbent at time t and at equilibrium, respectively. K 1 and K 2 (mg g −1 h −1 ) represent the rate constants of the pseudo-first-order model and pseudo-second-order model, respectively.

Synthesis of TBM
The diethynyl tetraphenylbenzene derivative 3 was synthesized following a reported procedure [48,51,52] and its structure was confirmed by 1 H-and 13 C-nuclear magnetic resonance (NMR), high-resolution mass spectrometry (EI-HRMS), FTIR spectroscopy and single-crystal XRD (synthetic procedures (i) and (ii), in addition to Figures S1, S5, S10 and S12 in Supplementary Materials).
The adsorption kinetics were explored using the pseudo-first-order and pseudo-second-order models, expressed respectively in Equations (2) and (3) below [50]: (2) t/Qt = t/Qe + 1/K2Qe 2 (3) where Qt (mg g −1 ) and Qe (mg g −1 ) denote the amounts of iodine adsorbed per gram adsorbent at time t and at equilibrium, respectively. K 1 and K 2 (mg g −1 h −1 ) represent the rate constants of the pseudo-first-order model and pseudo-second-order model, respectively.
Scheme 2. Synthesis of copolymers CTP1-3. Table 1 summarizes the attempts carried out to optimize the copolymerization reaction conditions. Synthesis of CTP1 was first tried by reacting a 0.05 M concentration of TBM and three equivalents of BD in presence of one equivalent of FeCl2 in refluxing chloroform for one day, which afforded the desired copolymer in 67% yield and whose GPC analysis revealed the formation of short chains weight-average molecular weight Mw ≈ 10 KDa (Table 1, entry 1). Additionally, doubling the reaction time led to a lower yield (~30%) and resulted in the formation of polymers with Mw ≈ 40 KDa but which suffer from a large Scheme 1. Synthesis of comonomer TBM.
The adsorption kinetics were explored using the pseudo-first-order and pseudo-second-order models, expressed respectively in Equations (2) and (3) below [50]: (2) t/Qt = t/Qe + 1/K2Qe 2 where Qt (mg g −1 ) and Qe (mg g −1 ) denote the amounts of iodine adsorbed per gram adsorbent at time t and at equilibrium, respectively. K 1 and K 2 (mg g −1 h −1 ) represent the rate constants of the pseudo-first-order model and pseudo-second-order model, respectively.
Scheme 2. Synthesis of copolymers CTP1-3. Table 1 summarizes the attempts carried out to optimize the copolymerization reaction conditions. Synthesis of CTP1 was first tried by reacting a 0.05 M concentration of TBM and three equivalents of BD in presence of one equivalent of FeCl2 in refluxing chloroform for one day, which afforded the desired copolymer in 67% yield and whose GPC analysis revealed the formation of short chains weight-average molecular weight Mw ≈ 10 KDa (Table 1, entry 1). Additionally, doubling the reaction time led to a lower yield (~30%) and resulted in the formation of polymers with Mw ≈ 40 KDa but which suffer from a large Scheme 2. Synthesis of copolymers CTP1-3. Table 1 summarizes the attempts carried out to optimize the copolymerization reaction conditions. Synthesis of CTP1 was first tried by reacting a 0.05 M concentration of TBM and three equivalents of BD in presence of one equivalent of FeCl 2 in refluxing chloroform for one day, which afforded the desired copolymer in 67% yield and whose GPC analysis revealed the formation of short chains weight-average molecular weight M w ≈ 10 KDa (Table 1, entry 1). Additionally, doubling the reaction time led to a lower yield (~30%) and resulted in the formation of polymers with M w ≈ 40 KDa but which suffer from a large polydispersity Ð = 4.6 (Table 1, entry 2). Therefore, to improve the solubility of all the species during the reaction, the concentration of the comonomers was further diluted by doubling the amount of solvent in the medium, thus, reaching a molar concentration of 0.025 M for TBM, and the reaction time was also increased to three days instead of one, which afforded a slight improvement in the reaction yield to 45% of the isolated copolymer CTP1 revealing a molar mass M w ≈ 10 KDa with a polydispersity Ð = 2.8 (Table 1, entry 3). Further dilution of the comonomers by a factor of 2.5 (i.e., 0.01 M of TBM) resulted only in a slight improvement in both the reaction yield (52%) and molar mass (Table 1,

entry 4).
It is worthwhile to mention that oligomers and starting materials were detected in all the previous copolymerization reactions. Therefore, the reaction time was increased to five days to ensure complete reaction where pure CTP1 was obtained in 91% yield and a weight-average molecular weight M w ≈ 9.5 KDa with Ð ≈ 1.8 from the reaction of a 0.025 M concentration of TBM, three equivalents of BD, and one equivalent of FeCl 2 in refluxing chloroform ( Figure 1 and Table 1, entry 5). Similar reaction conditions were utilized in the copolymerization of TBM in the presence of an equimolar amount of FeCl 2 with three equivalents of either CD or PD, which afforded CTP2 and CTP3 in 93% and 90% yields, respectively, as highly insoluble copolymers. sulted only in a slight improvement in both the reaction yield (52%) and molar mass (Table 1, entry 4). It is worthwhile to mention that oligomers and starting materials were detected in all the previous copolymerization reactions. Therefore, the reaction time was increased to five days to ensure complete reaction where pure CTP1 was obtained in 91% yield and a weight-average molecular weight Mw ≈ 9.5 KDa with Ð ≈ 1.8 from the reaction of a 0.025 M concentration of TBM, three equivalents of BD, and one equivalent of FeCl2 in refluxing chloroform ( Figure 1 and Table 1, entry 5). Similar reaction conditions were utilized in the copolymerization of TBM in the presence of an equimolar amount of FeCl2 with three equivalents of either CD or PD, which afforded CTP2 and CTP3 in 93% and 90% yields, respectively, as highly insoluble copolymers. The structure and high purity of CTP1 were confirmed by GPC analyses and 1 H-and 13 C-NMR spectroscopy (Figures 1 and 2, and Figures S3 and S7 in Supplementary Materials). In addition, target copolymers CTP1-3 were characterized by FTIR, XPS, and TGA (Figures 3, 4, and 7, and Figures S13, S14, S18, and S19 in Supplementary Materials).  The structure and high purity of CTP1 were confirmed by GPC analyses and 1 Hand 13 C-NMR spectroscopy (Figures 1 and 2, and Figures S3 and S7 in Supplementary Materials). In addition, target copolymers CTP1-3 were characterized by FTIR, XPS, and TGA (Figures 3, 4 and 7 and Figures S13, S14, S18 and S19 in Supplementary Materials). Figure 2 depicts the 1 H-and 13 C-NMR spectra of copolymer CTP1 confirming its structure as proven by the presence of all the desired peaks. The aromatic protons and carbons of CTP1 were detected in the ranges 6.8-7.7 and 125.6-141.0 ppm, respectively. It is noteworthy that all the characteristic proton peaks of the butyl group were depicted at 0.9, 1.3, 1.5, and 2.8 ppm, whereas those carbon peaks of the latter group were identified at 14.2, 23.1, 27.6, and 29.7 ppm (peaks labeled a-d in Figure 2). Furthermore, the distinctive C=N carbon in the clathrochelate moiety of CTP1 was detected at 157.7 ppm, which supports the formation of the desired product (peak labeled e in Figure 2). 0.9, 1.3, 1.5, and 2.8 ppm, whereas those carbon peaks of the latter group were identified at 14.2, 23.1, 27.6, and 29.7 ppm (peaks labeled a-d in Figure 2). Furthermore, the distinctive C=N carbon in the clathrochelate moiety of CTP1 was detected at 157.7 ppm, which supports the formation of the desired product (peak labeled e in Figure 2).  Figure 3 portrays the comparative FTIR absorption spectra for both comonomer TBM and target copolymer CTP1. The characteristic stretching vibrations of the hydroxyl groups (O-H) were detected at ~3212 cm −1 for TBM, which disappear in the spectrum of copolymer CTP1. It is noteworthy that the absorption bands identified at ~2957 cm −1 and ~1460 cm −1 correspond to the distinctive aliphatic C-H stretching and bending vibrations, respectively, and which clearly indicate the presence of the butyl group in CTP1. In addition, the fingerprint stretching vibrations [55] were confirmed for each of the conjugated C=C (~1604 cm −1 ), B-O (1399 cm −1 ), B-C aromatic (1182 cm −1 ), and C-H (824 cm −1 ) and alkene C=C (694 cm −1 ) bending vibration peaks, which further supports the formation of target copolymer CTP1. Similarly, FTIR absorption spectra of target copolymers CTP2-3 reveal their distinctive stretching and bending vibration peaks that corroborate their successful formation (Figures S13 and S14 in Supplementary Materials).    Figure 3 portrays the comparative FTIR absorption spectra for both comonomer TBM and target copolymer CTP1. The characteristic stretching vibrations of the hydroxyl groups (O-H) were detected at~3212 cm −1 for TBM, which disappear in the spectrum of copolymer CTP1. It is noteworthy that the absorption bands identified at~2957 cm −1 and~1460 cm −1 correspond to the distinctive aliphatic C-H stretching and bending vibrations, respectively, and which clearly indicate the presence of the butyl group in CTP1. In addition, the fingerprint stretching vibrations [55] were confirmed for each of the conjugated C=C (~1604 cm −1 ), B-O (1399 cm −1 ), B-C aromatic (1182 cm −1 ), and C-H (824 cm −1 ) and alkene C=C (694 cm −1 ) bending vibration peaks, which further supports the formation of target copolymer CTP1. Similarly, FTIR absorption spectra of target copolymers CTP2-3 reveal their distinctive stretching and bending vibration peaks that corroborate their successful formation (Figures S13 and S14 in Supplementary Materials). X-ray photoelectron spectroscopy (XPS) survey-scan spectra of CTP1-3 confirm the presence of all its constituting elements such as C1s, O1s, N1s, S2p, B1s, and Fe2p binding energies in the ranges ~284.6-285.4, 532.5-532.6, 400.7-400. 8, 163.4-163.8, 191.1-191.2, and 709.3-722.2 eV, respectively ( Figure 4, and Figures S18 and S19 in Supplementary Materials).

Synthesis of Poly(vinylene sulfone) Derivatives CTP4-6
Selective oxidation of poly(vinylene sulfide) copolymers CTP1-3 into their corresponding poly(vinylene sulfone) derivatives CTP4-6 was carried out using hydrogen peroxide in acetic acid (Scheme 3). Selective oxidation of poly(vinylene sulfide) copolymers CTP1-3 into their corresponding poly(vinylene sulfone) derivatives CTP4-6 was carried out using hydrogen peroxide in acetic acid (Scheme 3). Nevertheless, control studies of the reaction temperature and time were carried out to optimize the selective oxidation conditions. Thus, a thorough analysis of the reaction mixture was monitored by FTIR, which is the best analytical technique to identify sulfone peaks. Surprisingly, only the starting materials were isolated when the reaction was carried out using the conventional conditions of 30 °C for 60 min and the same result was Nevertheless, control studies of the reaction temperature and time were carried out to optimize the selective oxidation conditions. Thus, a thorough analysis of the reaction mixture was monitored by FTIR, which is the best analytical technique to identify sulfone peaks. Surprisingly, only the starting materials were isolated when the reaction was carried out using the conventional conditions of 30 • C for 60 min and the same result was encountered when the temperature was raised to 50 • C ( Figure 5 and Table 2 entry 1 and 2). On the other hand, decomposition products of copolymer CTP1 were detected upon increasing the reaction temperature of the medium to 100 • C (Table 2, entry 3). Interestingly, the desired target copolymer CTP4 was obtained when the temperature of the reaction medium was maintained at 90 • C for only 10 min of reaction time ( Figure 5, and Table 2 entry 4). The poly(vinylene sulfone) copolymer derivatives CTP2-3 were oxidized into their respective poly(vinylene sulfone) moieties CTP5-6 at 90 • C but for a longer reaction time of 60 min ( Figure 5 and Table 2 entry 5 and 6) and which could be possibly explained by the insolubility of synthons CTP2-3. The target copolymers CTP4-6 were isolated by simple filtration from the reaction medium in high yields (93-98%). FTIR absorption spectra of CTP4-6 depict the characteristic asymmetric and symmetric stretching vibrations peaks of sulfone (O=S=O) in the ranges~1309-1316 cm −1 and~1130-1146 cm −1 , respectively ( Figure 5, and Figures S15 and S17 in Supplementary Materials). It should be also noted that none of the poly(vinylene sulfone) derivatives CTP4-6 showed any FTIR absorption peak that can be attributed to the sulfoxide group, usually observed at~1030 cm −1 [53].

Scheme 3. Synthesis of the poly(vinylene sulfone) copolymers CTP4-6.
Nevertheless, control studies of the reaction temperature and time were carried out to optimize the selective oxidation conditions. Thus, a thorough analysis of the reaction mixture was monitored by FTIR, which is the best analytical technique to identify sulfone peaks. Surprisingly, only the starting materials were isolated when the reaction was carried out using the conventional conditions of 30 °C for 60 min and the same result was encountered when the temperature was raised to 50 °C ( Figure 5 and Table 2 entry 1 and 2). On the other hand, decomposition products of copolymer CTP1 were detected upon increasing the reaction temperature of the medium to 100 °C (Table 2, entry 3). Interestingly, the desired target copolymer CTP4 was obtained when the temperature of the reaction medium was maintained at 90 °C for only 10 min of reaction time ( Figure 5, and Table  2 entry 4). The poly(vinylene sulfone) copolymer derivatives CTP2-3 were oxidized into their respective poly(vinylene sulfone) moieties CTP5-6 at 90 °C but for a longer reaction time of 60 min ( Figure 5 and Table 2 entry 5 and 6) and which could be possibly explained by the insolubility of synthons CTP2-3. The target copolymers CTP4-6 were isolated by simple filtration from the reaction medium in high yields (93-98%). FTIR absorption spectra of CTP4-6 depict the characteristic asymmetric and symmetric stretching vibrations peaks of sulfone (O=S=O) in the ranges ~1309-1316 cm −1 and ~1130-1146 cm −1 , respectively ( Figure 5, and Figures S15 and S17 in Supplementary Materials). It should be also noted that none of the poly(vinylene sulfone) derivatives CTP4-6 showed any FTIR absorption peak that can be attributed to the sulfoxide group, usually observed at ~1030 cm −1 [53].    The solubility of poly(vinylene sulfone) copolymer CTP4 permitted its structure elucidation by 1 H-and 13 C-NMR spectroscopy and its molar mass determination using GPC analysis ( Figures S4, S8 and S9 in Supplementary Materials). Additionally, target copolymers CTP4-6 were all characterized by XPS and FTIR spectroscopy, which are the most suitable analytical techniques used to confirm the formation of sulfone groups. Additionally, the thermal properties of the poly(vinylene sulfone) copolymers were determined using TGA analysis (Figures 6 and 7 and Figures S15-S17, S20 and S21 in Supplementary Materials).  Figure 7 illustrates the thermogravimetric analysis (TGA) of poly(vinylene sulfide) copolymers CTP1-3 depicting their 10% weight-loss temperatures in the range 250-321 °C, which corroborates the relatively high thermal stability of the target copolymers CTP1-3. Oxidation of the latter compounds into their respective poly(vinylene sulfone) moieties shows an increased thermal stability for CTP4,5 by ~30 °C, therefore, reaching 10% weight-loss temperatures of 283 and 327 °C, respectively, whereas the poly(vinylene sulfone)-bearing phenyl side groups CTP6 portrays a 10% weight-loss temperature of 279 °C, which is lower by 40 °C than its synthon CTP3 (Figure 7).  Figure 7 illustrates the thermogravimetric analysis (TGA) of poly(vinylene sulfide) copolymers CTP1-3 depicting their 10% weight-loss temperatures in the range 250-321 °C, which corroborates the relatively high thermal stability of the target copolymers CTP1-3. Oxidation of the latter compounds into their respective poly(vinylene sulfone) moieties shows an increased thermal stability for CTP4,5 by ~30 °C, therefore, reaching 10% weight-loss temperatures of 283 and 327 °C, respectively, whereas the poly(vinylene sulfone)-bearing phenyl side groups CTP6 portrays a 10% weight-loss temperature of 279 °C, which is lower by 40 °C than its synthon CTP3 (Figure 7).  XPS survey-scan spectra of CTP4-6 ( Figure 6, and Figures S20 and S21 in Supplementary Materials) reveal the presence of all the constituting elements: namely, carbon, oxygen, nitrogen, sulfur, boron, and iron. Figure 6 portrays the XPS spectrum of CTP5 where the C1s peak is fitted into two main binding energy values at~284.66 eV and 285.38 eV with the former assigned to the aromatic carbon groups (C=C) whereas the latter designated to the imine carbons (C=N). Similarly, the binding energy for oxygen exhibits two fingerprint peaks, one observed at~531.58 eV, which corresponds to the sulfonic oxygen [56], and the second detected at 532.6 eV, which is assigned to the oxygen bonded to boron and nitrogen [40]. On the other hand, the N1s spectrum detected at 400.66 eV is correlated to the nitrogen (C-N). It is worthwhile to mention that the S2p binding energy in copolymer CTP2 detected at~163.8 eV [57] was shifted to 167.79 eV [56], therefore, strongly confirming the conversion of the sulfide group in CTP2 into the sulfone in copolymer CTP5. B1s core-level spectrum was detected at 191.05 eV, which clearly divulges the presence of boron oxide (B-O). Figure 6 also reveals the XPS peak for Fe2p with binding energy values 709.37 eV and 721.98 eV, which are attributed to Fe(II)-N bonding order [58]. Similarly, target copolymers CTP4,6 portray conclusive XPS binding energy values that undoubtedly corroborate their formation ( Figures S21 and S22 in Supplementary Materials). Figure 7 illustrates the thermogravimetric analysis (TGA) of poly(vinylene sulfide) copolymers CTP1-3 depicting their 10% weight-loss temperatures in the range 250-321 • C, which corroborates the relatively high thermal stability of the target copolymers CTP1-3. Oxidation of the latter compounds into their respective poly(vinylene sulfone) moieties shows an increased thermal stability for CTP4,5 by~30 • C, therefore, reaching 10% weightloss temperatures of 283 and 327 • C, respectively, whereas the poly(vinylene sulfone)bearing phenyl side groups CTP6 portrays a 10% weight-loss temperature of 279 • C, which is lower by 40 • C than its synthon CTP3 (Figure 7).

Gravimetric Iodine Capture Studies
Copolymers CTP1-3 were tested as adsorbents of iodine vapor and their uptake capacity was evaluated using gravimetric analysis. A sample of a given copolymer and iodine flakes were placed in two connected closed pre-weighed vials and the container was degassed and maintained at 80 • C in an oven during the process. The mass of the copolymer was recorded at different time intervals until there was no further change ( Figure 8). The results reveal that the iodine uptake gradually increased during the first~24 h and reached a plateau thereafter. The target copolymers CTP1,3 revealed iodine uptake values 1240 and 1510 mg g −1 , respectively, after 24 h of exposure to I 2 vapors (Table 3, entry 1 and 3). Interestingly,~960 mg g −1 of iodine vapor was adsorbed by CTP2 after seven hours, reaching a maximum iodine uptake of~2360 mg g −1 after 48 h of exposure to gaseous I 2 ( Figure 8 and Table 3, entry 2). This result is considered promising when compared to some iodine adsorbents reported in the literature: namely, nitrogen-rich thorium-organic nanotube materials (955 mg g −1 ) [59], copper-loaded zeolites (450 mg g −1 ) [13], zeolitic imidazolate (ZIF-8) metalorganic frameworks MOFs (877 mg g −1 ) [60], porous carbon materials (955 mg g −1 ) [61], polyhedral silsesquioxane materials (363 mg g −1 ) [25], nitrogenrich covalent organic framework (COFs, 980 mg g −1 ) [62], and copper-and zinc-based metal organic frameworks (Cu 2 O/Zn-MOF-NH 2 , 567 mg g −1 ) [63]. Although the iodine adsorption tests of poly(vinylene sulfone) copolymers CTP4-6 reveal relatively high uptakes reaching up to 1380 mg g −1 , they suffer from needing a long exposure time to iodine vapors reaching up to 72 h, therefore displaying a lower performance when compared to CTP1-3 (Table 3 entry 5 and Figure S24 in Supplementary Materials). These findings corroborate the literature about the impeding effect that sulfones and sulfoxides generally have on iodine adsorption capacity [8].
The iodine adsorption kinetics of copolymers CTP1-3 were analyzed using pseudofirst-order and pseudo-second-order models (Figure 9, and Figures S22 and S23 in Supplementary Materials) [50]. The results show that the adsorption of CTP1 and CTP3 fit the pseudo-second-order kinetic model with linear correlation coefficient (R 2 ) values of 0.997 and 0.981 ( Figure 9, and Figure S22 in Supplementary Materials), respectively. On the other hand, CTP2 portrays a better correlation with the pseudo-first-order kinetic model with a linear correlation coefficient (R 2 ) of 0.998 ( Figure S23 in Supplementary Materials) [7,64].
idazolate (ZIF-8) metalorganic frameworks MOFs (877 mg g −1 ) [60], porous carbon materials (955 mg g −1 ) [61], polyhedral silsesquioxane materials (363 mg g −1 ) [25], nitrogen-rich covalent organic framework (COFs, 980 mg g −1 ) [62], and copper-and zinc-based metal organic frameworks (Cu2O/Zn-MOF-NH2, 567 mg g −1 ) [63]. Although the iodine adsorption tests of poly(vinylene sulfone) copolymers CTP4-6 reveal relatively high uptakes reaching up to 1380 mg g −1 , they suffer from needing a long exposure time to iodine vapors reaching up to 72 h, therefore displaying a lower performance when compared to CTP1-3 (Table 3 entry 5 and Figure S24 in Supplementary Materials). These findings corroborate the literature about the impeding effect that sulfones and sulfoxides generally have on iodine adsorption capacity [8].    The iodine adsorption kinetics of copolymers CTP1-3 were analyzed using pseudofirst-order and pseudo-second-order models (  To better understand the mechanism of iodine capture by poly(vinylene sulfide) copolymers CTP1-3, a model sample of iodine-loaded copolymer (CTP3@I2) was investigated using FTIR spectroscopy. Figure 10 depicts the comparative FTIR spectra of copolymer CTP3 before and after iodine capture (CTP3@I2), clearly revealing the characteristic peaks shifts because of iodine absorption: mainly, the bands of aromatic C=C stretching, Ar-CH bending, and alkene C=C stretching vibrations. These conspicuous changes in the FTIR spectrum of CTP3@I2 strongly suggest the interaction between the abundant π-electrons of CTP3 and iodine species [29,50]. In addition, the presence of heteroatoms in the clathrochelate copolymer backbone, such as oxygen, nitrogen, and sulfur, can also plays a pivotal role in iodine capture by acting as binding sites for iodine molecules [65]. The minor change in the peaks also suggests weak interactions between the copolymer and iodine, thus suggesting a physisorption of the latter onto the surface of the copolymer. To better understand the mechanism of iodine capture by poly(vinylene sulfide) copolymers CTP1-3, a model sample of iodine-loaded copolymer (CTP3@I 2 ) was investigated using FTIR spectroscopy. Figure 10 depicts the comparative FTIR spectra of copolymer CTP3 before and after iodine capture (CTP3@I 2 ), clearly revealing the characteristic peaks shifts because of iodine absorption: mainly, the bands of aromatic C=C stretching, Ar-CH bending, and alkene C=C stretching vibrations. These conspicuous changes in the FTIR spectrum of CTP3@I 2 strongly suggest the interaction between the abundant π-electrons of CTP3 and iodine species [29,50]. In addition, the presence of heteroatoms in the clathrochelate copolymer backbone, such as oxygen, nitrogen, and sulfur, can also plays a pivotal role in iodine capture by acting as binding sites for iodine molecules [65]. The minor change in the peaks also suggests weak interactions between the copolymer and iodine, thus suggesting a physisorption of the latter onto the surface of the copolymer.
To better understand the mechanism of iodine capture by poly(vinylene sulfide) copolymers CTP1-3, a model sample of iodine-loaded copolymer (CTP3@I2) was investigated using FTIR spectroscopy. Figure 10 depicts the comparative FTIR spectra of copolymer CTP3 before and after iodine capture (CTP3@I2), clearly revealing the characteristic peaks shifts because of iodine absorption: mainly, the bands of aromatic C=C stretching, Ar-CH bending, and alkene C=C stretching vibrations. These conspicuous changes in the FTIR spectrum of CTP3@I2 strongly suggest the interaction between the abundant π-electrons of CTP3 and iodine species [29,50]. In addition, the presence of heteroatoms in the clathrochelate copolymer backbone, such as oxygen, nitrogen, and sulfur, can also plays a pivotal role in iodine capture by acting as binding sites for iodine molecules [65]. The minor change in the peaks also suggests weak interactions between the copolymer and iodine, thus suggesting a physisorption of the latter onto the surface of the copolymer. The complete desorption efficiency of the iodine-loaded copolymers (CTP1-3@I 2 ) was recorded at different time intervals when adsorbed iodine by CTP1-3 was released by simple heating of the copolymers in air at 120 • C (Figure 8). Iodine desorption was further investigated by immersing an iodine-loaded copolymer sample CTP2@I 2 in ethanol and recording the UV-Vis absorbance spectra at different time intervals (Figure 11). A noticeable increase in the intensity of the absorbance maxima that correspond to iodine was observed with time, which confirms the adsorbate release from CTP2 under ambient conditions. The amount of iodine released increased gradually and reached equilibrium after 30 min, and the color of the solution changed from colorless to yellow (Figure 11), which further confirms the iodine release in ethanol. These experimental observations strongly suggest that CTP2 can be employed as a sorbent material for efficient iodine vapor uptake. The complete desorption efficiency of the iodine-loaded copolymers (CTP1-3@I2) was recorded at different time intervals when adsorbed iodine by CTP1-3 was released by simple heating of the copolymers in air at 120 °C ( Figure 8). Iodine desorption was further investigated by immersing an iodine-loaded copolymer sample CTP2@I2 in ethanol and recording the UV-Vis absorbance spectra at different time intervals (Figure 11). A noticeable increase in the intensity of the absorbance maxima that correspond to iodine was observed with time, which confirms the adsorbate release from CTP2 under ambient conditions. The amount of iodine released increased gradually and reached equilibrium after 30 min, and the color of the solution changed from colorless to yellow (Figure 11), which further confirms the iodine release in ethanol. These experimental observations strongly suggest that CTP2 can be employed as a sorbent material for efficient iodine vapor uptake. The reusability of copolymers CTP1-3 was also investigated using the copolymer CTP2, which revealed the highest iodine uptake as a model adsorbent where a sample of CTP2 fully loaded with iodine vapors (CTP2@I2) was heated at 120 °C for 24 h, to ensure the complete release of the adsorbate from the copolymer backbone. The reactivated CTP2 was then exposed to iodine vapors and its uptake efficiency was recorded gravimetrically using the procedure described above. The regeneration test was repeated for four successive adsorption-desorption cycles, disclosing a minor change in the iodine adsorption efficiency for the regenerated copolymer CTP2 with a slight 11% decrease throughout the whole set of reusability experiments (Figure 12). The reusability of copolymers CTP1-3 was also investigated using the copolymer CTP2, which revealed the highest iodine uptake as a model adsorbent where a sample of CTP2 fully loaded with iodine vapors (CTP2@I 2 ) was heated at 120 • C for 24 h, to ensure the complete release of the adsorbate from the copolymer backbone. The reactivated CTP2 was then exposed to iodine vapors and its uptake efficiency was recorded gravimetrically using the procedure described above. The regeneration test was repeated for four successive adsorption-desorption cycles, disclosing a minor change in the iodine adsorption efficiency for the regenerated copolymer CTP2 with a slight 11% decrease throughout the whole set of reusability experiments ( Figure 12).
solutions showing the color change upon immersion in ethanol.
The reusability of copolymers CTP1-3 was also investigated using the copolymer CTP2, which revealed the highest iodine uptake as a model adsorbent where a sample of CTP2 fully loaded with iodine vapors (CTP2@I2) was heated at 120 °C for 24 h, to ensure the complete release of the adsorbate from the copolymer backbone. The reactivated CTP2 was then exposed to iodine vapors and its uptake efficiency was recorded gravimetrically using the procedure described above. The regeneration test was repeated for four successive adsorption-desorption cycles, disclosing a minor change in the iodine adsorption efficiency for the regenerated copolymer CTP2 with a slight 11% decrease throughout the whole set of reusability experiments ( Figure 12).

Conclusions
In summary, new metalorganic poly(vinylene sulfide) copolymers CTP1-3 bearing iron(II) clathrochelate unit and connected by tetraphenyl benzene vinylene sulfide groups were made in high yields via a simple one-pot reaction. Subsequently, the poly(vinylene-sulfide) copolymers CTP1-3 were selectively oxidized into their corresponding poly(vinylene-sulfone) copolymers CTP4-6. Iodine adsorption tests revealed uptake properties of CTP1-3 in the range 1240-2360 mg g −1 . Kinetic studies of iodine adsorption by copolymers CTP1-3 reveal that the CTP1,3 fit the pseudo-secondary kinetic model whereas CTP2, which discloses the highest iodine uptake, is in good agreement with the pseudo-first-order kinetic model. In addition, reusability tests of CTP2 divulged promising results with virtually no change in its iodine adsorption efficacy even after four adsorption-desorption cycles. The versatile synthesis of the metalorganic copolymers CTP1-6 reported herein and their excellent iodine uptake properties clearly emphasize the potential use of iron(II) clathrochelate as a modular building block for designing novel materials for applications in environmental remediation, particularly the capture of radioactive elements.

Data Availability Statement:
The raw/processed data required to reproduce these findings can be shared upon demand.