Surface Modification of FeCoNiCr Medium-Entropy Alloy (MEA) Using Octadecyltrichlorosilane and Atmospheric-Pressure Plasma Jet

Surface condition and corrosion resistance are major concerns when metallic materials are going to be utilized for applications. In this study, FeCoNiCr medium-entropy alloy (MEA) is first treated with a nitrogen atmospheric-pressure plasma jet (APPJ) and then coated with octadecyltrichlorosilane (OTS) for the surface modification. The hydrophobicity of the FeCoNiCr MEA was effectively improved by OTS-coating treatment, APPJ treatment, or the combination of both treatments (OTS-coated APPJ-treated), which increased the water contact angle from 54.49° of the bare MEA to 70.56°, 93.94°, and 88.42°, respectively. Potentiodynamic polarization and electrochemical impedance spectroscopy tests demonstrate that the APPJ-treated FeCoNiCr MEA exhibits the best anti-corrosion properties. X-ray photoelectron spectroscopy reveals that APPJ treatment at 700 °C oxidizes all the alloying elements in the FeCoNiCr MEA, which demonstrates that a short APPJ treatment of two-minute is effective in forming a metal oxide layer on the surface to improve the corrosion resistance of FeCoNiCr MEA. These results provide a convenient and rapid method for improving surface properties of FeCoNiCr MEA.


Introduction
Medium-entropy alloys (MEAs) contain multiple principal elements with high mixing entropy for stabilization in a disordered solid solution state [1][2][3][4]. In particular, FeCoNiCrMn-based materials have attracted attention for their excellent combination of properties such as good fracture resistance, high tensile strength and ductility, excellent cryogenic properties, and superplasticity. This alloy family is based on face-centered cubic (fcc) FeCoNiCr solid solution [5]. Due to the high potential for applications, various methods were introduced to further improve the properties of FeCoNiCr MEA, including elemental alloying [6,7], precipitation hardening [8,9], and processing [10,11]. To utilize MEAs into real applications, their surface properties and corrosion resistance are critical concerns.

Preparation of FeCoNiCr MEA
The equiatomic FeCoNiCr MEA was prepared by vacuum arc melting under a high-purity Ar atmosphere. High-purity (>99.9 wt %) Fe, Co, Ni, and Cr elements were used as raw materials. Before melting the FeCoNiCr ingot, a pure Ti ingot was melted two times to reduce the oxygen content in the chamber. To improve the chemical homogeneity of the material, the FeCoNiCr ingot was flipped and remelted six times. The ingot was homogenized at 1200 • C for 24 h under Ar atmosphere in a tubular furnace and then subjected to furnace cooling. The homogenized ingot was then cold-rolled to an 80% reduction in thickness. The cold-rolled plate was then annealed at 900 • C for 1 h and then cut into 2 × 2 cm samples using a diamond saw.

Pretreatment of FeCoNiCr MEA before APPJ Treatment
First, the FeCoNiCr MEA specimens were mechanically abraded using sand paper with mesh number up to P2000. Next, the specimens were sequentially ultrasonicated in deionized water, acetone, and isopropanol; each ultrasonication was performed for 15 min. After ultrasonication, the specimens were blow-dried using a N 2 gun. Figure 1a shows the APPJ setup used in this study. The voltage, frequency, and duty cycle of the APPJ were 275 V, 25 kHz, and 17.5%, respectively. The N 2 flow rate was fixed as 34 standard liters per minute (slm). Reduce the air-quenching effect from ambient air, a quartz tube with length of 4.5 cm and internal diameter of 3 cm was installed downstream of the plasma jet exit. This arrangement can Polymers 2020, 12, 788 3 of 13 increase the plasma jet length and expand the plasma influential zone. The temperature at the sample surface was monitored using a K-type thermocouple. Figure 1b shows the temperature evolution. The temperature plateaued at~700 • C. The APPJ treatment lasted for 2 min. Figure 1c shows the photograph of APPJ during processing. can increase the plasma jet length and expand the plasma influential zone. The temperature at the sample surface was monitored using a K-type thermocouple. Figure 1b shows the temperature evolution. The temperature plateaued at ~700 °C. The APPJ treatment lasted for 2 min. Figure 1c shows the photograph of APPJ during processing.

OTS Coating
The OTS coating is performed using a solution process. First, 4 µl of OTS (95%, Acros Organics, Waltham, MA, USA) was injected into 10 ml of n-dodecane (99+%, Alfa Aesar, Ward Hill, MA, USA) in a beaker. FeCoNiCr MEA specimens with/without APPJ treatment were immersed in the solution with ultrasonication for 15 min. Figure 2 shows the OTS self-assembly reaction process. It is generally accepted that OTS molecules are either chemisorbed or physisorbed on the oxide surface with some molecules forming short-range cross-linked structures [15].

OTS Coating
The OTS coating is performed using a solution process. First, 4 µL of OTS (95%, Acros Organics, Waltham, MA, USA) was injected into 10 mL of n-dodecane (99+%, Alfa Aesar, Ward Hill, MA, USA) in a beaker. FeCoNiCr MEA specimens with/without APPJ treatment were immersed in the solution with ultrasonication for 15 min. Figure 2 shows the OTS self-assembly reaction process. It is generally accepted that OTS molecules are either chemisorbed or physisorbed on the oxide surface with some molecules forming short-range cross-linked structures [15].

Materials Characterization
The water contact angle was measured using a goniometer (Model 100SB, Sindatek Instruments Co., Ltd., New Taipei City, Taiwan). An electrochemical workstation (Metrohm Autolab, PGSTAT204, Ionenstrasse, Switzerland) was used to evaluate the corrosion resistance behavior of specimens in a 3.5 wt % NaCl through potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) tests. A standard three-electrode system was used for electrochemical measurements. The specimen is the working electrode, a platinum wire and Ag-AgCl is used as the counter and reference electrodes, respectively. The potentiodynamic polarization test is performed starting from a potential from −0.5 to 1 mV v.s. open circuit potential (OCP) at a scan rate of 1 mV/s. The EIS plots were acquired at OCP in a frequency range of 10 5 −10 −2 Hz by using an alternating current with the amplitude of 10 mV (rms). The surface chemical bonding status was investigated using X-ray photoelectron spectrometry (XPS, VGS Thermo Scientific K-Alpha, Waltham, MA, USA). The binding energy (BE) was calibrated with a C1s peak at 284.8 eV. The crystallinity was inspected using an X-ray diffractometer (XRD, Bruker D8 DISCOVER SSS Multi-Function High-Power X-Ray Diffractometer, Billerica, MA, USA). The surface morphology was inspected using a scanning electron microscope (SEM, JOEL JSM-7800 Prime, Tokyo, Japan). Figure 3a shows the water contact angle (59.49°) for FeCoNiCr MEA without OTS and APPJ processing. After APPJ processing, the water contact angle increased to 70.56°, as shown in Figure  3b, possibly owing to the oxidation of FeCoNiCr MEA. Figure 3c shows the water contact angle after APPJ and OTS processing. The water contact angle is 93.94°. For comparison, we also performed OTScoating on FeCoNiCr MEA without APPJ treatment; the water contact angle is 88.42°, as shown in Figure 3d. OTS coating significantly increased the water contact angle and hydrophobicity, indicating successful coating of OTS on FeCoNiCr MEA. With APPJ processing followed by OTS coating, the water contact angle is the largest, possibly owing to the formation of surface oxides that could facilitate the follow-up OTS coating. With a better quality of the OTS coating layer, the hydrophobicity of the FeCoNiCr surface is further improved.

Materials Characterization
The water contact angle was measured using a goniometer (Model 100SB, Sindatek Instruments Co., Ltd., New Taipei City, Taiwan). An electrochemical workstation (Metrohm Autolab, PGSTAT204, Ionenstrasse, Switzerland) was used to evaluate the corrosion resistance behavior of specimens in a 3.5 wt % NaCl through potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) tests. A standard three-electrode system was used for electrochemical measurements. The specimen is the working electrode, a platinum wire and Ag-AgCl is used as the counter and reference electrodes, respectively. The potentiodynamic polarization test is performed starting from a potential from −0.5 to 1 mV v.s. open circuit potential (OCP) at a scan rate of 1 mV/s. The EIS plots were acquired at OCP in a frequency range of 10 5 -10 −2 Hz by using an alternating current with the amplitude of 10 mV (rms). The surface chemical bonding status was investigated using X-ray photoelectron spectrometry (XPS, VGS Thermo Scientific K-Alpha, Waltham, MA, USA). The binding energy (BE) was calibrated with a C1s peak at 284.8 eV. The crystallinity was inspected using an X-ray diffractometer (XRD, Bruker D8 DISCOVER SSS Multi-Function High-Power X-Ray Diffractometer, Billerica, MA, USA). The surface morphology was inspected using a scanning electron microscope (SEM, JOEL JSM-7800 Prime, Tokyo, Japan). Figure 3a shows the water contact angle (59.49 • ) for FeCoNiCr MEA without OTS and APPJ processing. After APPJ processing, the water contact angle increased to 70.56 • , as shown in Figure 3b, possibly owing to the oxidation of FeCoNiCr MEA. Figure 3c shows the water contact angle after APPJ and OTS processing. The water contact angle is 93.94 • . For comparison, we also performed OTS-coating on FeCoNiCr MEA without APPJ treatment; the water contact angle is 88.42 • , as shown in Figure 3d. OTS coating significantly increased the water contact angle and hydrophobicity, indicating successful coating of OTS on FeCoNiCr MEA. With APPJ processing followed by OTS coating, the water contact angle is the largest, possibly owing to the formation of surface oxides that could facilitate the follow-up OTS coating. With a better quality of the OTS coating layer, the hydrophobicity of the FeCoNiCr surface is further improved.

Materials Characterization
The water contact angle was measured using a goniometer (Model 100SB, Sindatek Instruments Co., Ltd., New Taipei City, Taiwan). An electrochemical workstation (Metrohm Autolab, PGSTAT204, Ionenstrasse, Switzerland) was used to evaluate the corrosion resistance behavior of specimens in a 3.5 wt % NaCl through potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) tests. A standard three-electrode system was used for electrochemical measurements. The specimen is the working electrode, a platinum wire and Ag-AgCl is used as the counter and reference electrodes, respectively. The potentiodynamic polarization test is performed starting from a potential from −0.5 to 1 mV v.s. open circuit potential (OCP) at a scan rate of 1 mV/s. The EIS plots were acquired at OCP in a frequency range of 10 5 −10 −2 Hz by using an alternating current with the amplitude of 10 mV (rms). The surface chemical bonding status was investigated using X-ray photoelectron spectrometry (XPS, VGS Thermo Scientific K-Alpha, Waltham, MA, USA). The binding energy (BE) was calibrated with a C1s peak at 284.8 eV. The crystallinity was inspected using an X-ray diffractometer (XRD, Bruker D8 DISCOVER SSS Multi-Function High-Power X-Ray Diffractometer, Billerica, MA, USA). The surface morphology was inspected using a scanning electron microscope (SEM, JOEL JSM-7800 Prime, Tokyo, Japan). Figure 3a shows the water contact angle (59.49°) for FeCoNiCr MEA without OTS and APPJ processing. After APPJ processing, the water contact angle increased to 70.56°, as shown in Figure  3b, possibly owing to the oxidation of FeCoNiCr MEA. Figure 3c shows the water contact angle after APPJ and OTS processing. The water contact angle is 93.94°. For comparison, we also performed OTScoating on FeCoNiCr MEA without APPJ treatment; the water contact angle is 88.42°, as shown in Figure 3d. OTS coating significantly increased the water contact angle and hydrophobicity, indicating successful coating of OTS on FeCoNiCr MEA. With APPJ processing followed by OTS coating, the water contact angle is the largest, possibly owing to the formation of surface oxides that could facilitate the follow-up OTS coating. With a better quality of the OTS coating layer, the hydrophobicity of the FeCoNiCr surface is further improved.   Table 1 lists the corresponding corrosion potential (Ecorr), corrosion current density (Icorr), pitting potential (Epit), and passive region (Epit-Ecorr) values determined with methods described in [45,46]. As shown from the table, APPJ treatment can increase pitting potential and passive region range of FeCoNiCr MEA. In addition, APPJ treatment also reduces the current density in the passive region. This enhancement in anticorrosion properties can be attributed to the formation of metal oxides on the surface of FeCoNiCr MEA. However, the lower pitting potential and narrower passive region were observed in OTScoated APPJ-treated FeCoNiCr MEA sample. It is plausible that the ultrasonication during OTS coating may produce defects on part of the loosely grown oxides during APPJ treatment. Nevertheless, APPJ treatment increases Ecorr from −0.045 V to 0.006 V. OTS coating does not drastically affect the corrosion potential and the current density in the passivation area compared with the bare and APPJ-treated MEAs. The OTS coating treatment after APPJ treatment improves the Ecorr further to 0.022 V, however, the passive region drops to a level worse than the one without any treatment. Following the analyses, although the OTS coating increases the water contact angle, as shown in Figure 3, it seems not to be a suitable protective layer to prevent corrosion. In the end, the APPJ-treated MEA shows the best anti-corrosion performance based on the indicators of the pitting potential and the width of the passive region range. Figure S1 shows the XRD results, and Table S1 summarized corresponding crystallinity information obtained from XRD results in Figure S1. After the APPJ treatment, the grain size slightly increased because of the thermal effect. The relation between crystal size and corrosion may vary among different materials. In one particular case, the previous report indicates that grain size of 304L austenitic stainless steel has no effect on pitting potential [45].  FeCoNiCr, FeCoNiCr_OTS, FeCoNiCr_APPJ, and FeCoNiCr_APPJ_OTS represent bare, OTS-coated, APPJ-treated, and OTS-coated APPJ-treated FeCoNiCr MEAs, respectively. Table 1 lists the corresponding corrosion potential (Ecorr), corrosion current density (Icorr), pitting potential (Epit), and passive region (Epit-Ecorr) values determined with methods described in [45,46]. As shown from the table, APPJ treatment can increase pitting potential and passive region range of FeCoNiCr MEA. In addition, APPJ treatment also reduces the current density in the passive region. This enhancement in anti-corrosion properties can be attributed to the formation of metal oxides on the surface of FeCoNiCr MEA. However, the lower pitting potential and narrower passive region were observed in OTS-coated APPJ-treated FeCoNiCr MEA sample. It is plausible that the ultrasonication during OTS coating may produce defects on part of the loosely grown oxides during APPJ treatment. Nevertheless, APPJ treatment increases Ecorr from −0.045 V to 0.006 V. OTS coating does not drastically affect the corrosion potential and the current density in the passivation area compared with the bare and APPJ-treated MEAs. The OTS coating treatment after APPJ treatment improves the Ecorr further to 0.022 V, however, the passive region drops to a level worse than the one without any treatment. Following the analyses, although the OTS coating increases the water contact angle, as shown in Figure 3, it seems not to be a suitable protective layer to prevent corrosion. In the end, the APPJ-treated MEA shows the best anti-corrosion performance based on the indicators of the pitting potential and the width of the passive region range. Figure S1 shows the XRD results, and Table S1 summarized corresponding crystallinity information obtained from XRD results in Figure S1. After the APPJ treatment, the grain size slightly increased because of the thermal effect. The relation between crystal size and corrosion may vary among different materials. In one particular case, the previous report indicates that grain size of 304L austenitic stainless steel has no effect on pitting potential [45].

Results and Discussion
Polymers 2020, 12, 788 6 of 13 summarized corresponding crystallinity information obtained from XRD results in Figure S1. After the APPJ treatment, the grain size slightly increased because of the thermal effect. The relation between crystal size and corrosion may vary among different materials. In one particular case, the previous report indicates that grain size of 304L austenitic stainless steel has no effect on pitting potential [45].  From potentiodynamic polarization curves, APPJ treated-MEA shows better corrosion-resistant properties. For clarity, hereafter we compare data with bare MEA and APPJ-treated MEA. Figure 5 shows the results of the EIS plots of bare and APPJ-treated MEAs. Figure 5a As can be seen in Figure 5a,b, the impedance value at low frequency (|Z|0.01Hz) of APPJ-treated MEA (112995Ω) was higher than that of bare MEA (50704Ω) at the beginning of the EIS measurement. Although a slight decrease of |Z|0.01Hz for APPJ-treated FeCoNiCr MEA was observed as the immersion time increased, as shown in Figure 5d, APPJ-treated FeCoNiCr MEA still exhibited a higher |Z|0.01Hz value compared with that obtained from bare FeCoNiCr MEA, suggesting that APPJ treatment can enhance the anti-corrosion properties of FeCoNiCr MEA. In addition, Figures S2-S5 show the details of EIS plots for each specimen. Figure 6 shows the XPS survey scan spectra of FeCoNiCr and APPJ-treated FeCoNiCr MEAs. Table 2 lists the atomic contents analyzed from Figure 6. Carbon content decreased [43] and oxygen content increased after APPJ processing, indicating the removal of organic contaminants and oxidation of FeCoNiCr MEA.
Polymers 2020, 12, 788 7 of 13 MEA (112995Ω) was higher than that of bare MEA (50704Ω) at the beginning of the EIS measurement. Although a slight decrease of |Z|0.01Hz for APPJ-treated FeCoNiCr MEA was observed as the immersion time increased, as shown in Figure 5d, APPJ-treated FeCoNiCr MEA still exhibited a higher |Z|0.01Hz value compared with that obtained from bare FeCoNiCr MEA, suggesting that APPJ treatment can enhance the anti-corrosion properties of FeCoNiCr MEA. In addition, Figures S2,  S3, S4 and S5 show the details of EIS plots for each specimen.  Figure 6 shows the XPS survey scan spectra of FeCoNiCr and APPJ-treated FeCoNiCr MEAs. Table 2 lists the atomic contents analyzed from Figure 6. Carbon content decreased [43] and oxygen content increased after APPJ processing, indicating the removal of organic contaminants and oxidation of FeCoNiCr MEA.   Figure 7 shows the XPS O1s spectra of FeCoNiCr and APPJ-treated FeCoNiCr MEAs. Deconvoluted peaks represent O2+ (530 eV), OH (531.6 eV), and H2O (532.8 eV) [4]. Table 3 lists the areal atomic ratio of these contents. After APPJ treatment, the overall peak intensity significantly increased, suggesting the occurrence of oxidation. Figure 8 shows the XPS Fe2p spectra that can be   Figure 7 shows the XPS O1s spectra of FeCoNiCr and APPJ-treated FeCoNiCr MEAs. Deconvoluted peaks represent O 2+ (530 eV), OH (531.6 eV), and H 2 O (532.8 eV) [4]. Table 3 lists the areal atomic ratio of these contents. After APPJ treatment, the overall peak intensity significantly increased, suggesting the occurrence of oxidation. Figure 8 shows the XPS Fe2p spectra that can be deconvoluted into four components, metallic Fe (706.6 eV), Fe ox 2+ (708.2 eV), Fe ox 3+ (709.8 eV), and Fe hy 3+ (711.6 eV) [4,46]. Table 4 lists the ratio of these four components. Metallic Fe (Fe 0 ) content significantly decreased from 15.10% to 0% and Fe 2+ decreased from 3.4% to 0%, whereas Fe 3+ increased from 19.06% to 49.23%; this strongly suggests the oxidation of the Fe component by APPJ treatment. Fe is oxidized into Fe 3+ state after APPJ processing. Figure 9 shows the XPS Co2p spectra and Table 5 lists the ratio of deconvoluted components, metallic Co (777.5 eV), Co 3 O 4 (779.8 eV), CoO (780.3 eV), Co(OH) 2 (781.2 eV), Co 2 O 3 (780.4 eV), and Co 2 N 3 (778.1 eV) [4,47,48]. No metallic Co was detected even without APPJ treatment, implying high oxidization proportion of Co on the surface. After APPJ treatment, alteration of cobalt oxide status was noted. The whole surface was in the oxidized state for Co. No Co nitridation was noted with nitrogen APPJ treatment. Figure 10 shows  [4,49]. Table 6 lists the component ratio. After APPJ processing, all Ni components including large portions of metallic Ni and NiO and a small amount of Ni(OH) 2 were oxidized into Ni 2 O 3 . Before APPJ treatment, the surface of FeCoNiCr MEA contained 16.59% metallic Ni and 44.36% NiO. All these components were completely oxidized into Ni 2 O 3 . Figure 11 shows the XPS Cr2p spectra that can be deconvoluted into metallic Cr (574 eV), Cr 2 O 3 (576.3 eV), and Cr(OH) 3 (577.1 eV) [4,50,51]. Table 7 lists the ratio of each component. Before APPJ treatment, 13.22% metallic Cr was seen on the surface. After APPJ treatment, the metallic Cr content reduced to 0% and the Cr(OH) 3 component increased. This also indicates oxidation of Cr by APPJ processing. Overall, all metal components in FeCoNiCr MEA were oxidized by nitrogen APPJ treatment because of the involvement of oxygen from ambient air in APPJ processing. The APPJ temperature was set as 700 • C; in this high-temperature environment, MEA oxidation occurred easily. The oxidations of all the metallic components in the FeCoNiCr MEA formed effective surface oxide layer which contributed to the better follow-up OTS treatment and the better corrosion resistance. Experimental results demonstrate that APPJ treatment is a convenient and economic method to improve the anti-corrosion properties of FeCoNiCr MEA. Furthermore, Figure S6 shows the SEM images of specimens of bare, APPJ-treated, OTS-coated APPJ-treated and OTS-coated MEAs. No apparent morphology difference is noted.
Polymers 2020, 12, x FOR PEER REVIEW 8 of 13 treatment because of the involvement of oxygen from ambient air in APPJ processing. The APPJ temperature was set as 700 °C; in this high-temperature environment, MEA oxidation occurred easily. The oxidations of all the metallic components in the FeCoNiCr MEA formed effective surface oxide layer which contributed to the better follow-up OTS treatment and the better corrosion resistance. Experimental results demonstrate that APPJ treatment is a convenient and economic method to improve the anti-corrosion properties of FeCoNiCr MEA. Furthermore, Figure S6 shows the SEM images of specimens of bare, APPJ-treated, OTS-coated APPJ-treated and OTS-coated MEAs. No apparent morphology difference is noted.    (a) (b) Figure 7. XPS O1s spectra of (a) FeCoNiCr and (b) APPJ-treated FeCoNiCr MEAs.     (a) (b) Figure 9. XPS Co2p spectra of (a) FeCoNiCr and (b) APPJ-treated FeCoNiCr MEAs.       Table 6. XPS Ni2p deconvoluted peak areal ratios from XPS spectra shown in Figure 10. (a) (b) Figure 11. XPS Cr2p spectra of (a) FeCoNiCr and (b) APPJ-treated FeCoNiCr MEAs. Table 7. XPS Cr2p deconvoluted peak areal ratios from XPS spectra shown in Figure 11.

Summary
We use a nitrogen APPJ and OTS coating for the surface modification of FeCoNiCr MEA. A short nitrogen APPJ treatment for 2 min at 700 °C oxidized FeCoNiCr MEA. The metal oxide layer resulted from the APPJ treatment not only increases the passivation region and pitting potential but also decreases the current density of the passivation area. An OTS coating improves the hydrophobicity but narrows down the passivation region. Nevertheless, an OTS coating does not drastically influence the corrosion potential, the corrosion rate, and the current density in the passivation area. OTS-coated APPJ-treated FeCoNiCr MEA shows the highest hydrophobicity with water contact angle of 93.94°, however, APPJ-treated FeCoNiCr MEA shows the best anti-corrosion property. The APPJ and OTS coating methods introduced in this study provide convenient and economic surface modifications to improve the corrosion resistance and surface hydrophobicity of FeCoNiCr MEA.
Supplementary Materials: The following are available online at www.mdpi.com/xxx/s1, Figure S1: Low-angle  Table 7. XPS Cr2p deconvoluted peak areal ratios from XPS spectra shown in Figure 11.

Summary
We use a nitrogen APPJ and OTS coating for the surface modification of FeCoNiCr MEA. A short nitrogen APPJ treatment for 2 min at 700 • C oxidized FeCoNiCr MEA. The metal oxide layer resulted from the APPJ treatment not only increases the passivation region and pitting potential but also decreases the current density of the passivation area. An OTS coating improves the hydrophobicity but narrows down the passivation region. Nevertheless, an OTS coating does not drastically influence the corrosion potential, the corrosion rate, and the current density in the passivation area. OTS-coated APPJ-treated FeCoNiCr MEA shows the highest hydrophobicity with water contact angle of 93.94 • , however, APPJ-treated FeCoNiCr MEA shows the best anti-corrosion property. The APPJ and OTS coating methods introduced in this study provide convenient and economic surface modifications to improve the corrosion resistance and surface hydrophobicity of FeCoNiCr MEA.