Durability of an Epoxy Resin and Its Carbon Fiber- Reinforced Polymer Composite upon Immersion in Water, Acidic, and Alkaline Solutions.

The usage of polymer composites in various engineering fields has increased. However, the long-term service performance of such materials under aggressive conditions is still poorly understood, which limits the development of safe and economically effective designs. In this study, the aging of an epoxy resin and its carbon fiber-reinforced polymer (CFRP) composites upon immersion in water, acidic, and alkaline solutions was evaluated at different temperatures. The service life of the CFRP composites under various conditions could be predicted by the Arrhenius theory. The thermal and mechanical analysis results indicated that the CFRP composites were more vulnerable to HCl owing to the higher moisture absorption and diffusion of HCl into their cracks. The scanning electron microscopy results showed that the polymer matrix was damaged and degraded. Therefore, to allow long-term application, CFRP composites must be protected from acidic environments.


Introduction
Fiber-reinforced polymer (FRP) composite materials have recently attracted significant interest in many fields, such as civil engineering and aerospace, owing to their low density, spectacular mechanical strength [1], low weight, anticipated long service-life, and resistance to corrosion [2][3][4]. FRPs are most widely used in civil infrastructure applications, such as reclamation via external bonding, in outdoor environments with concrete, for renewing various types of concrete, and in steel structures [5,6]. FRP has many advantages over steel, such as its low weight, simple installation process, and high corrosion resistance [7,8]. Carbon fiber-reinforced polymers (CFRPs) are also receiving increasing interest due to their emerging role in strengthening structural elements in construction [9,10]. To improve the toughness and strength of fibers, thermosetting polymers (epoxy, polyester, phenolic, and polyimide resins) and thermoplastics (polypropylene, and poly methyl methacrylate) have been broadly considered [2,11]. The resin matrix plays a vital role in composite materials as it transfers the load between the fibers and composite laminates in FRP composites [12]. The use of epoxy adhesives for joining composite materials and debonding, and repairing civil structures is increasing [11,13]. Owing to the rapid cure time and high mechanical strength of epoxy, it is suitable for use in civil engineering applications [13], and composite materials with epoxy matrices are highly suitable for use

Preparation of Epoxy Resin Specimens
The resin specimens were prepared by thoroughly mixing the DGEBA (Diglycidylether Bisphenol-A, E51) epoxy and hardener. This mixture was then placed in a vacuum chamber to remove any air bubbles. The resin mixture was then poured into a mold for curing at room temperature (25 ± 1 °C) for 24 h and then post-cured for 2 h at 110 °C in a hot oven.

Preparation of CFRP Plates
The CFRP composite plates were prepared following the VARI molding process. The unidirectional carbon fabrics were stacked on a glass mold, and the epoxy resin with hardener was infused into the carbon fibers under a vacuum. The composite plates were then allowed to cure at room temperature (25 ± 1 °C) for 24 h and then post-cured in an oven for 2 h at 110 °C. Figure 2 presents schematic and photographic images of the VARI molding process.

Immersion Conditions
The neat epoxy and CFRP composite plates were tested for time intervals of 20, 40 and 80 days at submersion temperatures of 20, 40 and 60 °C. The details of the immersion conditions for the epoxy and CFRP composites are listed in Table 1. Distilled water was commercially purchased, while the alkaline solution was produced by dissolving sodium hydroxide (NaOH) into distilled water at a concentration of 10% by weight.

Preparation of Epoxy Resin Specimens
The resin specimens were prepared by thoroughly mixing the DGEBA (Diglycidylether Bisphenol-A, E51) epoxy and hardener. This mixture was then placed in a vacuum chamber to remove any air bubbles. The resin mixture was then poured into a mold for curing at room temperature (25 ± 1 • C) for 24 h and then post-cured for 2 h at 110 • C in a hot oven.

Preparation of CFRP Plates
The CFRP composite plates were prepared following the VARI molding process. The unidirectional carbon fabrics were stacked on a glass mold, and the epoxy resin with hardener was infused into the carbon fibers under a vacuum. The composite plates were then allowed to cure at room temperature (25 ± 1 • C) for 24 h and then post-cured in an oven for 2 h at 110 • C. Figure 2 presents schematic and photographic images of the VARI molding process. The acidic solution was produced by dissolving hydrochloric acid (HCl) in distilled water at a concentration of 5% by weight. The pH of alkaline and acidic solutions is about 13.0 and 1.0 respectively.

Dynamic Mechanical Analysis
The thermal properties of entire resin and composite materials were analyzed using dynamic mechanical analysis (DMA) with a Q800 system (TA Instruments Co Ltd., New Castle, DE, USA) in the dual cantilever beam mode. The temperature was increased from 20 °C to 250 °C at a ramp rate of 5 °C/min. The DMA measures the storage and loss moduli as functions of temperature. The glass transition temperature of the materials was determined from the tan delta peak.

Tensile Test
The tensile properties of the epoxy resin and CFRP plates were tested using a universal mechanical testing machine (Jinan Shijin Group Co., Ltd, Jinan, China). Dog bone-shaped epoxy resin samples were used in the test. The mechanical properties of the epoxy resins were investigated according to ASTM D 638D at a loading rate of 1 mm/min. The mechanical properties of the CFRP plates were tested based on ASTM D 3039/D 3039M (Standard Test Methods for Tensile Properties of Polymer Matrix Composite Materials). The CFRP composite plates cut using a cutting machine and tested at a loading rate of 5 mm/min per ASTM D 3039. Five samples of both the neat epoxy and CFRP composite plates subjected to each condition were tested, and the average results are reported.

Scanning Electron Microscopy
The morphologies of the aged and unaged neat epoxy and CFRP composites samples were analyzed. A Vega3 scanning electron microscope (Tescan, Brno, Czech Republic) was used to examine the morphology of the fracture surface of the materials. The samples were prepared by

Immersion Conditions
The neat epoxy and CFRP composite plates were tested for time intervals of 20, 40 and 80 days at submersion temperatures of 20, 40 and 60 • C. The details of the immersion conditions for the epoxy and CFRP composites are listed in Table 1. Distilled water was commercially purchased, while the alkaline solution was produced by dissolving sodium hydroxide (NaOH) into distilled water at a concentration of 10% by weight. The acidic solution was produced by dissolving hydrochloric acid (HCl) in distilled water at a concentration of 5% by weight. The pH of alkaline and acidic solutions is about 13.0 and 1.0 respectively.

Dynamic Mechanical Analysis
The thermal properties of entire resin and composite materials were analyzed using dynamic mechanical analysis (DMA) with a Q800 system (TA Instruments Co Ltd., New Castle, DE, USA) in the dual cantilever beam mode. The temperature was increased from 20 • C to 250 • C at a ramp rate of 5 • C/min. The DMA measures the storage and loss moduli as functions of temperature. The glass transition temperature of the materials was determined from the tan delta peak.

Tensile Test
The tensile properties of the epoxy resin and CFRP plates were tested using a universal mechanical testing machine (Jinan Shijin Group Co., Ltd., Jinan, China). Dog bone-shaped epoxy resin samples were used in the test. The mechanical properties of the epoxy resins were investigated according to ASTM D 638D at a loading rate of 1 mm/min. The mechanical properties of the CFRP plates were tested based on ASTM D 3039/D 3039M (Standard Test Methods for Tensile Properties of Polymer Matrix Composite Materials). The CFRP composite plates cut using a cutting machine and tested at a loading rate of 5 mm/min per ASTM D 3039. Five samples of both the neat epoxy and CFRP composite plates subjected to each condition were tested, and the average results are reported.

Scanning Electron Microscopy
The morphologies of the aged and unaged neat epoxy and CFRP composites samples were analyzed. A Vega3 scanning electron microscope (Tescan, Brno, Czech Republic) was used to examine the morphology of the fracture surface of the materials. The samples were prepared by mounting a section from the tensile-fractured samples on an aluminum plate and coated with a layer of gold as a conducting material using an E5200 auto sputter coater (Cambridge, UK) before testing.

Dynamic Mechanical Analysis
The aged and unaged epoxy resin and CFRP composites were thermally analyzed by conducting a DMA test, and the results indicate that the neat resin and CFRP composite behaved differently under each aging condition. The glass transition temperature of the neat resin decreased greatly (Figure 3), while that of the composite materials only slightly decreased ( Figure 4). The decrease in the glass transition temperature of a polymer material mainly depends on the degree of crosslinking; a high degree of crosslinking would decrease the chain mobility, and a high glass transition temperature indicates that a material is thoroughly cured. The glass transition temperatures (T g ) of the epoxy resin and CFRP composites under different immersion conditions were evaluated using the relaxation peaks of the tan delta vs. temperature curves, which are summarized in Table 2. Table 2. Glass transition temperature (T g ± 1 • C) of epoxy resin and CFRP composites in different immersion conditions.

Samples Immersion Time (Days)
Water HCl NaOH As indicated by the DMA results, the intensity of the tan delta peaks of the aged samples decreased due to aging. The reduction of the tan delta curves in Figure 3 was greater under elevated temperatures than lower temperatures. Additionally, when the samples were aged for 80 days, the heights of the tan delta peaks were greatly reduced under soaking temperatures. After the DMA test, double peaks with a significant decrease in the glass transition temperature were observed in the tan delta vs. temperature plot for the samples immersed in the HCl solution. This might be due to the participation of the protons in the HCl in chemical reactions between water molecules via hydrogen bonding and within the hydrophilic groups of the epoxy, which resulted in the generation of a less-plasticized region dispersed across the surface of the polymer. According to previous studies, the irreversible degradation of aged materials is due to moisture or water uptake, which occurs due to plasticization [23] and results in a decrease in the glass transition temperature [24].
participation of the protons in the HCl in chemical reactions between water molecules via hydrogen bonding and within the hydrophilic groups of the epoxy, which resulted in the generation of a lessplasticized region dispersed across the surface of the polymer. According to previous studies, the irreversible degradation of aged materials is due to moisture or water uptake, which occurs due to plasticization [23] and results in a decrease in the glass transition temperature [24].    Figure 3a presents the tan delta curves of the neat epoxy against temperature upon immersion in water under various aging conditions. After 20 days, the glass transition temperature of the samples aged at 20 and 40 °C decreased by approximately 9%. However, at 60 °C, the glass transition temperature only decreased by 7%. This could be due to the post-curing reactions or the plasticization at elevated temperatures. The glass transition temperature of the samples aged for 40 days at 20 °C and 40 °C decreased by almost 7%, and that of the samples aged at 60 °C decreased by approximately 10%. At elevated temperatures, the great reduction in Tg was followed by material or polymer degradation due to the negative effects of plasticization. After 80 days of aging at 20, 40 and 60 °C, the glass transition temperatures of the neat epoxy samples decreased by approximately 8%, 6.8%, and 3.4%, respectively. This indicates that, after the initial aging periods, the rate of the reduction in Tg decreased. This is because the Tg of the materials typically decreased in the initial stage, and the reduction rate was reduced thereafter as the materials slowly became saturated with water or moisture [15]. Furthermore, as the aging continued, the post-curing reactions occurred and, when water absorption increased, the impact of plasticization was negligible [5].
The tan delta curves of the samples immersed in HCl are plotted against temperature under  Figure 3a presents the tan delta curves of the neat epoxy against temperature upon immersion in water under various aging conditions. After 20 days, the glass transition temperature of the samples aged at 20 and 40 • C decreased by approximately 9%. However, at 60 • C, the glass transition temperature only decreased by 7%. This could be due to the post-curing reactions or the plasticization at elevated temperatures. The glass transition temperature of the samples aged for 40 days at 20 • C and 40 • C decreased by almost 7%, and that of the samples aged at 60 • C decreased by approximately 10%. At elevated temperatures, the great reduction in T g was followed by material or polymer degradation due to the negative effects of plasticization. After 80 days of aging at 20, 40 and 60 • C, the glass transition temperatures of the neat epoxy samples decreased by approximately 8%, 6.8%, and 3.4%, respectively. This indicates that, after the initial aging periods, the rate of the reduction in T g decreased. This is because the T g of the materials typically decreased in the initial stage, and the reduction rate was reduced thereafter as the materials slowly became saturated with water or moisture [15]. Furthermore, as the aging continued, the post-curing reactions occurred and, when water absorption increased, the impact of plasticization was negligible [5].
Additionally, the damping properties are vital when considering the tan delta peak of a material. After immersion in water for 20 days, the height of the tan delta curve in Figure 4a increased as the temperature increased. The Tg increased by approximately 4.7% and 2.28% at 20 °C and 40 °C, and at 60 °C, it was similar to that of the control samples. Upon immersion in HCl solution at 20 °C, 60 °C, and 40 °C, the height of the tan delta peak in Figure 4b increased. The glass transition temperature increased by approximately 2% at 40 °C. As shown in Figure 4c, the height of the tan delta peak for the samples immersed in the NaOH solution increased, similar to the HCl solution. The molecularlevel penetration of NaOH molecules can restrict the segmental interactions, thereby improving Tg and decreasing the height of the tan delta peak [28]. Tg increased by approximately 6.43%, 4.88%, and 3.6% at 20, 40 and 60 °C, respectively, which was due to the effects of the post-curing and crosslinking reactions [5,[29][30][31].   As shown in Figure 4a, when the samples were submerged in water for 40 days, the height of the tan delta curve of the composite specimens increased as the temperature increased, and the glass transition temperature decreased by approximately 2%. Figure 4b shows that the height of the tan delta peak of the samples immersed in the HCl solution at 60 °C was similar to that of the control samples. Moreover, the Tg of the samples immersed in HCl and NaOH at 20 °C and 40 °C was close to that of the control samples and decreased by approximately 2% at 60 °C, as shown in Figure 4c. Owing to the plasticization effect, Tg decreased at higher temperatures. However, the decrease in Tg observed here was only approximately 2%; therefore, the degradation of the resin matrix could be considered as negligible. The tan delta curves of the samples immersed in HCl are plotted against temperature under various aging conditions in Figure 3b. The most important finding is that secondary or double peaks occurred under all aging conditions. As mentioned above, the pseudo-crosslinking effect occurred. During the initial stage, the glass transition temperatures reduced by approximately 11% at 20 • C and 13% at 40 and 60 • C. As the aging time increased, the T g decreased. After 40 days, the T g decreased by 13% at 20 • C, and decreased by almost 15% at 40 and 60 • C. Similar to the results obtained for water, the glass transition temperature reduction rate was lowest after 80 days of immersion in HCl. The results indicated that the thermal properties of the samples were reduced by immersion in an acidic solution and at elevated soaking temperatures, indicating that both the immersion temperature and solution affected the materials and the occurrence of plasticization, molecular crosslink formation, and post-curing reactions [25,26].
The tan delta curves of the samples immersed in the NaOH solution are plotted against temperature under different aging conditions in Figure 3c. After immersion for 20 days, the glass transition temperatures decreased by 7% under all soaking temperatures. At 60 • C, the T g decreased by 13% after 40 days of aging due to the effect of plasticization or the deterioration of materials at higher temperatures. After 80 days of soaking, the T g of the samples slowly stabilized, similar to the water and HCl solutions. The T g reduction rate under all aging conditions in the NaOH solution appeared to be close to those in water. The overall thermal analysis results indicate that the aged resin samples were mainly degraded in acidic environments.

DMA of Aged CFRP Composites
The DMA of composite materials can indicate small-scale movements of the polymer-resin matrix over a wide range of temperatures. The DMA results indicate that the Tg of composites first increased, and was then similar to that of the control samples, remaining stable under all submersion conditions. Figure 4 plots the tan delta curves of the CFRP composites against temperature under different aging conditions. After 20 days of immersion in all solutions, the glass transition temperature increased, particularly in NaOH, where it increased by 6.5%. The increase in the glass transition was largely due to increases in the crosslinking density of the materials [24,27]. Additionally, the damping properties are vital when considering the tan delta peak of a material. After immersion in water for 20 days, the height of the tan delta curve in Figure 4a increased as the temperature increased. The T g increased by approximately 4.7% and 2.28% at 20 • C and 40 • C, and at 60 • C, it was similar to that of the control samples. Upon immersion in HCl solution at 20 • C, 60 • C, and 40 • C, the height of the tan delta peak in Figure 4b increased. The glass transition temperature increased by approximately 2% at 40 • C. As shown in Figure 4c, the height of the tan delta peak for the samples immersed in the NaOH solution increased, similar to the HCl solution. The molecular-level penetration of NaOH molecules can restrict the segmental interactions, thereby improving T g and decreasing the height of the tan delta peak [28]. T g increased by approximately 6.43%, 4.88%, and 3.6% at 20, 40 and 60 • C, respectively, which was due to the effects of the post-curing and crosslinking reactions [5,[29][30][31].
As shown in Figure 4a, when the samples were submerged in water for 40 days, the height of the tan delta curve of the composite specimens increased as the temperature increased, and the glass transition temperature decreased by approximately 2%. Figure 4b shows that the height of the tan delta peak of the samples immersed in the HCl solution at 60 • C was similar to that of the control samples. Moreover, the T g of the samples immersed in HCl and NaOH at 20 • C and 40 • C was close to that of the control samples and decreased by approximately 2% at 60 • C, as shown in Figure 4c. Owing to the plasticization effect, T g decreased at higher temperatures. However, the decrease in T g observed here was only approximately 2%; therefore, the degradation of the resin matrix could be considered as negligible.
As shown in Figure 4, after 80 days of soaking in all solutions at all temperatures, the heights of the tan delta peaks increased and were almost similar, and the T g values decreased by approximately 2%. This may have been due to the plasticization effect when the materials were submerged in solutions for an extended period of time and was negligible. Additionally, the heights of the tan delta peaks for the composites immersed at higher temperatures decreased, which may have been due to the slow curing rate at higher temperatures over time. Therefore, the improvement in the overall crosslink density decreased the segmental molecular chain mobility of the polymer matrix, resulting in low Polymers 2020, 12, 614 9 of 23 energy loss. Acidic media are also highly corrosive environments, and the composites subjected to the acidic solution were dehydrated due to the diffusion of the solution into the polymer matrix and the carbon fiber surface. This penetration is either activated by the presence of micro-cracks on the surface of the composite or manufacturing defects.

Tensile Properties
The effects of moisture on the tensile properties of the neat epoxy resin and its CFRP plates upon immersion in water, acidic, and alkaline solutions for 80 days were tested to determine the mechanical properties of the composites as they play a vital role in their use in engineering applications. The strength of composite materials affects their service life, and the tensile strength and modulus should be determined to improve the service life and the design of materials used in civil engineering. The degradation of the materials affected the mechanical properties of both the aged neat resin and composites. The influence of moisture and temperature on the tensile properties of the materials aged with a long immersion time may have been due to the deterioration process [32]. Zhang et al. [33] found that moisture may either increase or decrease the tensile strength of composite materials. In our study, the tensile strength of both the resin and composites decreased, while the modulus did not significantly change. Table 3 presents the reduction (%) in tensile strength, and Table 4 presents the reduction (%) in the tensile modulus of the epoxy resin and CFRP composites under various immersion conditions. Table 3.
Tensile strength reduction (%) of the epoxy and CFRP composites at different immersion conditions.

Samples Immersion Time (Days)
Water HCl NaOH

Tensile Properties of Aged Epoxy Resins
The tensile test results showed that the mechanical properties of the neat epoxy resin decreased during aging. Figure 5 shows the tensile strength and moduli of the aged and unaged epoxy resins under various conditions. The initial tensile strength of the epoxy resin was 61.  days, respectively. The decreases in tensile strength were due to the deterioration of the material and the formation of cracks due to the acid [34] or moisture uptake. Figure 5c shows that the tensile strength of the resin immersed in NaOH changed under all soaking conditions. The strength of the resin immersed at 20 and 40 • C decreased to 61.69 MPa and 59.35 MPa after 20 days of immersion, respectively. After immersion at 20 and 40 • C, for 40 days, the strength of the resin decreased to 60.29 and 52.12 MPa, respectively. Moreover, after aging for 80 days, the tensile strength decreased to approximately 57.57 and 45.21 MPa, respectively. After soaking at 60 • C for 20, 40 and 80 days, the strength decreased to 57.83, 44.25, and 36.33 MPa, respectively, which are decreases of 6.6%, 28.5%, and 41.3% from the initial value. Bin et al. [35] reported that, at higher immersion temperatures, the decrease in tensile strength was due to the plasticization effect. The tensile modulus values of the epoxy resin samples soaked in water for 80 days at 20, 40 and 60 • C decreased by approximately 7.34%, 10.97%, and 13.3%, while those of the samples soaked in the HCl solution decreased by 11.74%, 14.07%, and 16.14%, respectively. The tensile moduli of the samples immersed in the NaOH solution decreased by 8.9%, 10.45%, and 12.52% after 80 days of soaking at 20, 40 and 60 • C, respectively. Table 2 shows that the degradation of the tensile modulus of the neat epoxy was lower than that of the tensile strength.

Tensile Properties of Aged CFRP Composites
The results of this study indicated that the addition of carbon fibers had little impact on the moisture absorption or degradation of the composites. The epoxy matrix caused stress to the interface; subsequently, debonding and cracking occurred at the fiber-matrix interphase. The unaged and aged composites exposed to various environments were mechanically tested, and the results are presented in Figure 6. respectively, which are decreases of 6.6%, 28.5%, and 41.3% from the initial value. Bin et al. [35] reported that, at higher immersion temperatures, the decrease in tensile strength was due to the plasticization effect. The tensile modulus values of the epoxy resin samples soaked in water for 80 days at 20, 40 and 60 °C decreased by approximately 7.34%, 10.97%, and 13.3%, while those of the samples soaked in the HCl solution decreased by 11.74%, 14.07%, and 16.14%, respectively. The tensile moduli of the samples immersed in the NaOH solution decreased by 8.9%, 10.45%, and 12.52% after 80 days of soaking at 20, 40 and 60 °C, respectively. Table 2 shows that the degradation of the tensile modulus of the neat epoxy was lower than that of the tensile strength.

Tensile Properties of Aged CFRP Composites
The results of this study indicated that the addition of carbon fibers had little impact on the moisture absorption or degradation of the composites. The epoxy matrix caused stress to the interface; subsequently, debonding and cracking occurred at the fiber-matrix interphase. The unaged and aged composites exposed to various environments were mechanically tested, and the results are presented in Figure 6. During the initial stage (20 days) of aging, the tensile strength and modulus of the composites decreased slightly, and after 40 and 80 days, degradation mainly increased in the HCl solution, which could be attributed to the corrosion of the polymer matrix and the cracks that may have been formed by the residual thermal stress during fabrication, which allowed the HCl to reach the fibers [36]. The tensile tests indicate that, during hygrothermal aging, the immersion solution greatly affects the mechanical properties as all composites behaved differently in water, NaOH, and HCl. The degradation details of tensile strength and modulus of CFRP materials is shown in Tables 3 and 4. From the table we can clearly understand that in HCl solution, especially at 60 °C the mechanical properties decreased. Sindhu et al. [28] found that the tensile strength and Young's modulus of natural and glass fibers increased upon long-term immersion in a HCl solution, but decreased upon immersion in NaOH. According to Somjai et al. [26], immersion in an acidic solution at 60 °C and room temperature affected the surface of the material, and the mechanical properties were damaged by water and alkaline solutions. However, Amaro et al. [37] found that immersion in an alkaline solution resulted in a greater decrease in the mechanical properties of a material than immersion in an acidic solution. The mechanical properties can be influenced by the fracture mechanism [38]. The degradation of the polymer matrix of the composite samples in the HCl solution is presented in the SEM image in Figure 7, which shows the damage, cracks, and deterioration that occurred in the matrix. The initial tensile strength of the composite was 1276.1 MPa. Upon immersion in water, HCl, and NaOH solutions for 80 days at 60 °C, the tensile strength decreased by approximately 20.06%, 24.77%, and 23.98%, respectively. The exposure of the composite materials to moisture caused the During the initial stage (20 days) of aging, the tensile strength and modulus of the composites decreased slightly, and after 40 and 80 days, degradation mainly increased in the HCl solution, which could be attributed to the corrosion of the polymer matrix and the cracks that may have been formed by the residual thermal stress during fabrication, which allowed the HCl to reach the fibers [36]. The tensile tests indicate that, during hygrothermal aging, the immersion solution greatly affects the mechanical properties as all composites behaved differently in water, NaOH, and HCl. The degradation details of tensile strength and modulus of CFRP materials is shown in Tables 3 and 4. From the table we can clearly understand that in HCl solution, especially at 60 • C the mechanical properties decreased. Sindhu et al. [28] found that the tensile strength and Young's modulus of natural and glass fibers increased upon long-term immersion in a HCl solution, but decreased upon immersion in NaOH. According to Somjai et al. [26], immersion in an acidic solution at 60 • C and room temperature affected the surface of the material, and the mechanical properties were damaged by water and alkaline solutions. However, Amaro et al. [37] found that immersion in an alkaline solution resulted in a greater decrease in the mechanical properties of a material than immersion in an acidic solution. The mechanical properties can be influenced by the fracture mechanism [38]. The degradation of the polymer matrix of the composite samples in the HCl solution is presented in the SEM image in Figure 7, which shows the damage, cracks, and deterioration that occurred in the matrix. During the initial stage (20 days) of aging, the tensile strength and modulus of the composites decreased slightly, and after 40 and 80 days, degradation mainly increased in the HCl solution, which could be attributed to the corrosion of the polymer matrix and the cracks that may have been formed by the residual thermal stress during fabrication, which allowed the HCl to reach the fibers [36]. The tensile tests indicate that, during hygrothermal aging, the immersion solution greatly affects the mechanical properties as all composites behaved differently in water, NaOH, and HCl. The degradation details of tensile strength and modulus of CFRP materials is shown in Tables 3 and 4. From the table we can clearly understand that in HCl solution, especially at 60 °C the mechanical properties decreased. Sindhu et al. [28] found that the tensile strength and Young's modulus of natural and glass fibers increased upon long-term immersion in a HCl solution, but decreased upon immersion in NaOH. According to Somjai et al. [26], immersion in an acidic solution at 60 °C and room temperature affected the surface of the material, and the mechanical properties were damaged by water and alkaline solutions. However, Amaro et al. [37] found that immersion in an alkaline solution resulted in a greater decrease in the mechanical properties of a material than immersion in an acidic solution. The mechanical properties can be influenced by the fracture mechanism [38]. The degradation of the polymer matrix of the composite samples in the HCl solution is presented in the SEM image in Figure 7, which shows the damage, cracks, and deterioration that occurred in the matrix.  The initial tensile strength of the composite was 1276.1 MPa. Upon immersion in water, HCl, and NaOH solutions for 80 days at 60 • C, the tensile strength decreased by approximately 20.06%, 24.77%, and 23.98%, respectively. The exposure of the composite materials to moisture caused the decrease in the mechanical properties [29]. The material toughness indicated that the changed in the mechanical properties during treatment was caused by volatile matter, such as water molecules, and that it reduced the plasticity or oxidation of the molecules in the materials [39,40]. The changes were attributed to the cross-linking effect upon exposure to higher temperatures. The tensile modulus of the composites also decreased upon immersion at 60 • C by approximately 10%, 8%, and 7% in HCl, water, and NaOH solutions, respectively. As the aging temperature and duration increased, mechanical degradation increased [23,41].
From the thermal and mechanical analysis, we perceived that the rate of degradation is accelerated with increase in temperature. In addition, the main correlation observed during the DMA and tensile test is that the decrease in properties is observed higher in acidic environments. From the thermal analysis of CFRP samples it is observed that during initial stages, the T g increased in all immersion conditions, this can be attributed to the increase in crosslink density of the material. On co-relating the cross-linking effect to the tensile properties of CFRP samples the overall the rate of degradation is also observed at a lower rate during the initial stages. The degradation in tensile strength and DMA may ascribed due to the plasticization effect of the materials.

Service Life Prediction of the CFRP Composite in the Three Solutions
The service life of composite materials must be understood when considering civil engineering applications. Our experimental results indicated the degradation of the aged materials. Therefore, we predicted the service life of the composites in water, acidic, and alkaline solutions using the Arrhenius theory.

Arrhenius Relationship
According to the Arrhenius relationship, the rate of degradation can be expressed [42][43][44] as Equation (1): where k is the degradation rate, i.e., 1/time, A is the material constant, E a is the activation energy, R is the universal gas constant, and T is the temperature (Kelvin). The Arrhenius relationship assumes that, during aging, the sole leading degradation mechanism does not change over time and with changes in temperature. However, the rate of degradation increased as the temperature increased. Equation (1) can be transformed into Equations (2) and (3): Equation (2) represents the rate of degradation, where k is the inverse of the time required for a material property to reach a given value. Equation (3) is the logarithm of the time required for a material property to reach a given value, and is a linear function of 1/T with a slope value of E a /RT.

Degradation Prediction Procedure
In this study, the tensile properties of the accelerated aged CFRP composites subjected to three different immersion media (water, acid, and alkali) at three different temperature ranges were predicted using the degradation model given in Equation (4), which defines the relationship between the tensile strength retention of the CFRP composite and the exposure time in the accelerated aging study: where Y is the tensile strength retention (%), t is the exposure/aging time, and τ is the fitted parameter. The experimental values were applied to Equation (4) and the results are plotted in Figure 8. The values of τ and the correlation coefficient R 2 for the three different test conditions are given in Table 5. where Y is the tensile strength retention (%), t is the exposure/aging time, and is the fitted parameter.
The experimental values were applied to Equation (4) and the results are plotted in Figure 8. The values of and the correlation coefficient for the three different test conditions are given in Table  5.   In the second step, by applying the regression coefficient τ, the time (t) required for the tensile strength retention to reach 60%, 70%, 80%, and 90% at temperatures of 20, 40 and 60 • C was calculated, and the obtained values were then fitted to Equation (3). The relationships between the results and ln(1/k) = ln t and 1/T are shown in Figure 9. By plotting the results of Equation (3), we acquired values that were parallel straight lines. The values of E a /RT are the slopes of the straight lines, and the correlation coefficients are given in Table 6.
Polymers 2020, 12, x FOR PEER REVIEW 15 of 23 In the second step, by applying the regression coefficient , the time (t) required for the tensile strength retention to reach 60%, 70%, 80%, and 90% at temperatures of 20, 40 and 60 °C was calculated, and the obtained values were then fitted to Equation (3). The relationships between the results and ln(1/k) = ln and 1/T are shown in Figure 9. By plotting the results of Equation (3), we acquired values that were parallel straight lines. The values of ⁄ are the slopes of the straight lines, and the correlation coefficients are given in Table 6.   In the third step, the time shift factor (TSF) to reach the same tensile strength values (represented by c) at temperatures and was determined from the previous Arrhenius plots. The time-shift factor (TSF) can be calculated as: To predict the long-term behavior of the CFRP composites in this study, we have selected five reference temperatures from cities in Canada. In Equation (6), the reference temperature is the annual mean temperature of the selected cities. The TSF of the composites at different temperatures was calculated, and the results are presented in Table 7.  In the third step, the time shift factor (TSF) to reach the same tensile strength values (represented by c) at temperatures T 0 and T 1 was determined from the previous Arrhenius plots.
The time-shift factor (TSF) can be calculated as: To predict the long-term behavior of the CFRP composites in this study, we have selected five reference temperatures from cities in Canada. In Equation (6), the reference temperature T 0 is the annual mean temperature of the selected cities. The TSF of the composites at different temperatures was calculated, and the results are presented in Table 7. The master curves of the relationship of the tensile strength retention of the CFRP composites with exposure time in the five selected cities with five different annual temperatures obtained under the different TSF values at 20, 40 and 60 • C were determined, and, based on the annual service temperatures, Figure 9 was transformed into Figure 10. The results of the fitted master curves for all immersion media are summarized in Table 8.  The master curves of the relationship of the tensile strength retention of the CFRP composites with exposure time in the five selected cities with five different annual temperatures obtained under the different TSF values at 20, 40 and 60 °C were determined, and, based on the annual service temperatures, Figure 9 was transformed into Figure 10. The results of the fitted master curves for all immersion media are summarized in Table 8.

Long-Term Tensile Strength Retention Prediction
The time in years required to reach a selected tensile strength retention value, i.e., 70%, for the CFRP composites immersed in water, acidic, and alkaline solutions under the five service temperatures selected from Canada was predicted and is presented in Table 9. Under the five selected annual service temperatures, it is expected that it will take 9.7-15.8, 4.3-6.7, and 8.3-10.2 years for the tensile strength retention of the CFRP composites to reach 70% in water, acidic, and alkaline solutions. The analysis indicated that the CFRP composites were more durable in water than acidic and alkaline solutions. Furthermore, the CFRP composites were less durable in acidic solutions and are more susceptible to degradation in acid.

Long-Term Tensile Strength Retention Prediction
The time in years required to reach a selected tensile strength retention value, i.e., 70%, for the CFRP composites immersed in water, acidic, and alkaline solutions under the five service temperatures selected from Canada was predicted and is presented in Table 9. Under the five selected annual service temperatures, it is expected that it will take 9.7-15.8, 4.3-6.7, and 8.3-10.2 years for the tensile strength retention of the CFRP composites to reach 70% in water, acidic, and alkaline solutions. The analysis indicated that the CFRP composites were more durable in water than acidic and alkaline solutions. Furthermore, the CFRP composites were less durable in acidic solutions and are more susceptible to degradation in acid.  Table 10 lists the predicted tensile strength retention values of the CFRP composites in the three media studied here under the selected five annual service temperatures. The tensile strength retention values were calculated using Equation (4) by substituting the values of τ with those given in Table 8, corresponding to the five average annual service temperatures. The prediction results indicated that the tensile strength retention values varied from 63.6-48% for the samples immersed in water for 20 years. The durability of the samples in the alkaline medium was better than that in acid and lower than that in water, and ranged from 49.8-32.7%. The CFRP composites exhibited low durability in the acidic solution, with the tensile strength retention after 15 years ranging from 44.9-29.1%. Following the experimental study and theoretical analysis based on the Arrhenius relationship, we can conclude that the CFRP composites tested in this study were more susceptible to acid degradation than degradation in alkaline solutions and water. The fitted curves of the prediction of the long-term tensile strength using the Arrhenius relationship (Table 8) had correlation coefficients of 0.97, 0.96, and 0.91 for water, acidic, and alkaline media, indicating the consistency of this analysis.

Morphological Analysis
The morphology of the neat epoxy and composite tensile test samples was examined based on the fracture mode by scanning electron microscopy. The main degradation of the aged resin and composites upon immersion in the HCl solution is shown in Figure 11. The SEM images show the breakage of fibers and debonding of the interphase matrix and voids. The cracking [34], debonding at the interphase matrix region, and shrinkage can enhance degradation for a long aging time at elevated temperatures [45,46]. Following thermal and mechanical analysis, we observed that the properties reduced and the materials degraded. The morphological analysis results can be used to understand the main degradation phases for the neat resin and CFRP composites immersed in the HCl solution. The role that the epoxy matrix plays in epoxy/CFRP composites during hygrothermal aging can be detected from the SEM images. The carbon fibers neither absorbed or swelled in the solutions, while the epoxy matrix swelled due to the stress at the interphase, resulting in cracking and debonding [47,48]. The cracks indicated the increased degradation kinetics in high-stress situations [32]. Acid caused more damage at 60 • C than that at room temperature [26]. The deterioration of the composite material was not solely due to plasticization, although hydrolysis and the debonding of the fiber-matrix interphase resulted in the densification of microcracks at higher submergence temperatures. This indicates that the acid solution reached the surface of the fibers and attacked their structure. Figure 11c,d show the degradation of resin and the moisture ingress for the aged and unaged neat resin. The SEM images of the composite samples indicated that the resin matrix area was more affected by degradation than the fibers.
Polymers 2020, 12, x FOR PEER REVIEW 20 of 23 at the interphase matrix region, and shrinkage can enhance degradation for a long aging time at elevated temperatures [45,46]. Following thermal and mechanical analysis, we observed that the properties reduced and the materials degraded. The morphological analysis results can be used to understand the main degradation phases for the neat resin and CFRP composites immersed in the HCl solution. The role that the epoxy matrix plays in epoxy/CFRP composites during hygrothermal aging can be detected from the SEM images. The carbon fibers neither absorbed or swelled in the solutions, while the epoxy matrix swelled due to the stress at the interphase, resulting in cracking and debonding [47,48]. The cracks indicated the increased degradation kinetics in high-stress situations [32]. Acid caused more damage at 60 °C than that at room temperature [26]. The deterioration of the composite material was not solely due to plasticization, although hydrolysis and the debonding of the fiber-matrix interphase resulted in the densification of microcracks at higher submergence temperatures. This indicates that the acid solution reached the surface of the fibers and attacked their structure. Figures 11c,d show the degradation of resin and the moisture ingress for the aged and unaged neat resin. The SEM images of the composite samples indicated that the resin matrix area was more affected by degradation than the fibers.
(a) (b) (c) (d) Figure 11. SEM images of the specimens (a) unaged CFRP composite, tensile fractured surface of (b) aged CFRP composites in HCl solution at 60 °C for 80 days, (c) unaged epoxy resin and (d) aged epoxy resin in HCl solution at 60 °C for 80 days.

Conclusions
In this study, we explored the aging of neat epoxy and its CFRP composite in water, acidic, and alkaline solutions at different temperatures. The long-term service life of the CFRP composites was also predicted from the tensile strength retention values under different environmental conditions by the Arrhenius theory.
The DMA results showed that the glass transition temperature initially increased and the height of tan delta peak decreased for the CFRP composites; however, the glass transition temperature of the neat epoxy samples decreased, and a double peak was observed for the samples immersed in the

Conclusions
In this study, we explored the aging of neat epoxy and its CFRP composite in water, acidic, and alkaline solutions at different temperatures. The long-term service life of the CFRP composites was also predicted from the tensile strength retention values under different environmental conditions by the Arrhenius theory.
The DMA results showed that the glass transition temperature initially increased and the height of tan delta peak decreased for the CFRP composites; however, the glass transition temperature of the neat epoxy samples decreased, and a double peak was observed for the samples immersed in the HCl solution. The tensile tests revealed that degradation adversely affected the tensile strength, although the tensile modulus values did not significantly decrease throughout the aging study. According to the thermal and mechanical analysis, degradation occurred in a higher rate as the exposure temperature is higher. In general, from the thermal and mechanical analysis it was observed the rate of degradation is accelerated at elevated temperature and is obvious in acidic conditions.
The degradation of the composite materials can be attributed to the deterioration of the resin matrix and debonding at the fiber-resin interface. This damage was visible in the morphological analysis. The potential relation of temperature and time-dependency of the degradation rate of the composite in different solutions were predicted using the Arrhenius equation, and the service life of the CFRP composites in the HCl solutions was shorter. By correlating the experimental data and prediction results, it can be concluded that the CFRP composite materials may need to be developed further to withstand acidic media and ensure a longer service life.

Conflicts of Interest:
The authors declare no conflict of interest.