Mechanical Properties of Longitudinal Basalt/Woven-Glass-Fiber-reinforced Unsaturated Polyester-Resin Hybrid Composites

This work represents a study to investigate the mechanical properties of longitudinal basalt/woven-glass-fiber-reinforced unsaturated polyester-resin hybrid composites. The hybridization of basalt and glass fiber enhanced the mechanical properties of hybrid composites. The unsaturated polyester resin (UP), basalt (B) and glass fibers (GF) were fabricated using the hand lay-up method in six formulations (UP, GF, B7.5/G22.5, B15/G15, B22.5/G7.5 and B) to produce the composites, respectively. This study showed that the addition of basalt to glass-fiber-reinforced unsaturated polyester resin increased its density, tensile and flexural properties. The tensile strength of the B22.5/G7.5 hybrid composites increased by 213.92 MPa compared to neat UP, which was 8.14 MPa. Scanning electron microscopy analysis was used to observe the fracture mode and fiber pullout of the hybrid composites.


Introduction
A composite material is a nonuniform solid produced by combining two or more materials that are mechanically bonded together. Each material in a composite retains its properties, and when combined, their combined properties improves their properties as individual solids [1][2][3][4][5]. In general, composites are composed of two phases, the matrix and the reinforcement. The matrix serves to bond the reinforcements, which in turn, increase the strength of the composite [4,6,7]. Today, composites composed of fiber and polymer are the most popular and are widely applied in various types of industries [8][9][10][11][12]. They have the potential to substitute for conventional metals in structural applications like aerospace, automobile and in wind-turbine-blade manufacturing [12][13][14]. The most well-known, fiber-reinforced polyester composites in which continuous fibers material embedded in a polyester matrix are combination of natural-fiber-reinforced polyester (NFRP), glass-fiber-reinforced polyester (GFRP) and carbon-fiber-reinforced polyester (CFRP) [15][16][17][18][19].

Materials
The materials used during this study were unsaturated polyester resin (UP), methyl ethyl ketone peroxide (MEKP) as the curing catalyst, woven glass fiber (GF) and roving basalt fiber (B). The woven glass fiber was supplied by Innovative Pultrusion Sdn. Bhd. (Negeri Sembilan, Malaysia) and the roving basalt fiber was supplied by Basaltex NV (Wevelgem, Belgium). The woven glass fiber was cut into 300 mm × 300 mm pieces for each layer. The basalt fiber was cut into 300-mm-long pieces for each fiber and was randomly distributed in each layer during the fabrication.

Fabrication of B/GF/UP Hybrid Composites
The fabrication of the composites was by hand lay-up technique in a steel mold with dimension (l × w × t) 300 mm × 300 mm × 5 mm, then were compressed using compression molding (40 tons). The fibers and the unsaturated polyester resin were fabricated into composites as sandwich-structured composite. All composites in this study consists of 30 wt % fiber and 70 wt % unsaturated polyester matrix, as shown in Table 1. For the hybrid composites, three different weight percentages (wt %) of glass-basalt fiber were fabricated to investigate the effect of various fiber compositions to the mechanical (tensile and flexural) properties of the hybrid composites.

Density
A densimeter (Mettler-Toledo (M) Sdn. Bhd, Selangor, Malaysia) was used in the determination of the density of acquired B/G/UP hybrid composites. The samples were dried for 7 days in desiccators with P 2 O 5 as the drying agent. Afterward, the computation of the initial dry matter of each hybrid composites was accomplished. The hybrid composites samples were weighed (m) before immersing hybrid composites into the liquid of volume (V) and the density denoted as (ρ), was calculated from Equation (1). Each test was carried out 6 times.

Tensile Test
A tensile test was performed to measure the force required to stretched and elongated the composite until it reached the break point. Tensile test was performed at specimen temperature of 23 • C and relative humidity of 50%, according to the standard ASTM D3039 using INSTRON 3365 (INSTRON, University Ave, Norwood, MA, US) test machine. Each sample dimension (l × w × t) was 120 mm × 20 mm × 5 mm. The gauge length was 60 mm and the strain rate was set at 5 mm/min.

Flexural Test
A flexural test was performed according to standard ASTM D790 [48] that employ three-point loading system applied to a simply supported beam with the strain limit of the test at 5.0%. The span to depth ratio was 16:1 and the crosshead speed was 5 mm/min. Each sample's dimensions (l × w × t) were 127 mm × 13 mm × 5 mm.

Scanning Electron Microscopy (SEM)
The post tensile testing of B/G/UP hybrid composites was observed using an EM-30AX scanning electron microscope (SEM; COXEM, Daejon, Korea) with an acceleration voltage of 20 kV. All six formulations of B/G/UP hybrid composites were coated with a thin layer of gold prior to morphology analysis.

Statistical Analysis
SPSS software was used to perform the analysis of variance (ANOVA) on the obtained experimental results. Tukey's test was employed to conduct means comparisons at a 0.05 level of significance (p ≤ 0.05).

Density
The density of UP, GF, B, B7.5/G22.5, B15/G15 and B22.5/G7.5 hybrid composites are shown in Figure 1. The B composites had higher density than B22.5/G7.5 hybrid composites, which were 1.54 g/cm 3 and 1.51 g/cm 3 , respectively. As the basalt content increased from 7.5 to 22.5 wt %, the density also increased. The density of B22.5/G7.5 hybrid composites was B7.5, compared to B15/G15 and B7.5/G22.5. Nevertheless, the B composite had a higher density than the G and UP composites. Referring to Nurazzi et al. [49], the experimental density of composites decreased as the sugar palm fiber loading increase [49]. This may have been due to the lower density of sugar palm fibers (1.053 g/cm 3 ) compared to the polyester resin (1.212 g/cm 3 ). However, in this study, the main reason of the high density of B composite is the density of basalt fiber [50] that is higher than both glass fiber and unsaturated polyester [51].

Flexural Test
A flexural test was performed according to standard ASTM D790 [48] that employ three-point loading system applied to a simply supported beam with the strain limit of the test at 5.0%. The span to depth ratio was 16:1 and the crosshead speed was 5 mm/min. Each sample's dimensions (l × w × t) were 127 mm × 13 mm × 5 mm.

Scanning Electron Microscopy (SEM)
The post tensile testing of B/G/UP hybrid composites was observed using an EM-30AX scanning electron microscope (SEM; COXEM, Daejon, Korea) with an acceleration voltage of 20 kV. All six formulations of B/G/UP hybrid composites were coated with a thin layer of gold prior to morphology analysis.

Statistical analysis
SPSS software was used to perform the analysis of variance (ANOVA) on the obtained experimental results. Tukey's test was employed to conduct means comparisons at a 0.05 level of significance (p ≤ 0.05).

Density
The density of UP, GF, B, B7.5/G22.5, B15/G15 and B22.5/G7.5 hybrid composites are shown in Figure 1. The B composites had higher density than B22.5/G7.5 hybrid composites, which were 1.54 g/cm 3 and 1.51 g/cm 3 , respectively. As the basalt content increased from 7.5 to 22.5 wt %, the density also increased. The density of B22.5/G7.5 hybrid composites was B7.5, compared to B15/G15 and B7.5/G22.5. Nevertheless, the B composite had a higher density than the G and UP composites. Referring to Nurazzi et al. [49], the experimental density of composites decreased as the sugar palm fiber loading increase [49]. This may have been due to the lower density of sugar palm fibers (1.053 g/cm 3 ) compared to the polyester resin (1.212 g/cm 3 ). However, in this study, the main reason of the high density of B composite is the density of basalt fiber [50] that is higher than both glass fiber and unsaturated polyester [51].

Tensile Properties
The presence of basalt fiber in the hybrid composite with glass fiber would enhance the tensile properties because basalt fiber has higher strain, strength and modulus than glass fiber [52]. The highest tensile strength was observed for B22.5/G7.5, which was 269.85 ± 23.35 MPa, followed by B, B15/G15, B7.5/G22.5, G and UP, which were 213.92 ± 5.31, 168.89 ± 11.62, 147.69 ± 15.27, 126.33 ± 16.43 and 8.14 ± 1.23 MPa, respectively. Therefore, the increment of basalt fiber (wt %) enhances the tensile properties. Similar results were also found in the previous works that the replacement of glass mat to basalt fiber resulted in enhanced mechanical property of GFRP [53]. However, according to Amuthakkannan et al. [54], a similar result was also found. The glass-basalt hybrid composite with 8B/4G had better tensile properties compared to BFRP, which indicated that the presence of glass fiber (even below the percentage of basalt fiber) would improve the tensile properties of the composite.
For the composite consisting only one type of fiber, sample B achieved higher strength compared to sample G. The average tensile strength of composite B was 213.92 MPa and sample G was 126.33 MPa. Therefore, based on the results, BFRP had higher tensile strength compared to GFRP. Figure 2 shows the trend of the tensile strength results. It can be seen that the basalt fiber added to hybrid composite was able to increase the tensile strength of the sample B7.5/G22.5 and B15/G15 compared to sample G. However, the tensile strength of the two composites were still lower compared to sample B that consisted of 30 wt % basalt fiber and 70 wt % unsaturated polyester resin. The best fiber percentage composition of glass-basalt fiber in hybrid composite was 75% basalt fiber and 25% glass fiber (sample B22.5/G7.5). Since the tensile strength of sample B22.5/G7.5 was the highest, it proved that in the percentage of glass/basalt fiber composition at 25%/75%, the hybrid composite was able to increase the maximum load at tensile test compared to GFRP and BFRP. In addition, the improvement of tensile strength of the composites can be attributed to the fact that an effective layering design of balance (B22.5/G7.5) was formed between the outer layer of the skin of the composite glass fiber mat and long and continuous of basalt fiber acted as a core and tendon for the composite structure. An effective layering and structural design of the composites resisted sudden and fast crack growth because microcrack propagation towards the core of the composites was stopped by the individual glass fiber mat at the outer surface. Moreover, an optimized matrix acted as a binder of the fibers, transferring the load to the fibers and providing rigidity and shape to the structure. This contributed to the improvement of mechanical properties of the composites [55]. The presence of basalt fiber in the hybrid composite with glass fiber would enhance the tensile properties because basalt fiber has higher strain, strength and modulus than glass fiber [52]. The highest tensile strength was observed for B22.5/G7.5, which was 269.85 ± 23.35 MPa, followed by B, B15/G15, B7.5/G22.5, G and UP, which were 213.92 ± 5.31, 168.89 ± 11.62, 147.69 ± 15.27, 126.33 ± 16.43 and 8.14 ± 1.23 MPa, respectively. Therefore, the increment of basalt fiber (wt %) enhances the tensile properties. Similar results were also found in the previous works that the replacement of glass mat to basalt fiber resulted in enhanced mechanical property of GFRP [53]. However, according to Amuthakkannan et al. [54], a similar result was also found. The glass-basalt hybrid composite with 8B/4G had better tensile properties compared to BFRP, which indicated that the presence of glass fiber (even below the percentage of basalt fiber) would improve the tensile properties of the composite.
For the composite consisting only one type of fiber, sample B achieved higher strength compared to sample G. The average tensile strength of composite B was 213.92 MPa and sample G was 126.33 MPa. Therefore, based on the results, BFRP had higher tensile strength compared to GFRP. Figure 2 shows the trend of the tensile strength results. It can be seen that the basalt fiber added to hybrid composite was able to increase the tensile strength of the sample B7.5/G22.5 and B15/G15 compared to sample G. However, the tensile strength of the two composites were still lower compared to sample B that consisted of 30 wt % basalt fiber and 70 wt % unsaturated polyester resin. The best fiber percentage composition of glass-basalt fiber in hybrid composite was 75% basalt fiber and 25% glass fiber (sample B22.5/G7.5). Since the tensile strength of sample B22.5/G7.5 was the highest, it proved that in the percentage of glass/basalt fiber composition at 25%/75%, the hybrid composite was able to increase the maximum load at tensile test compared to GFRP and BFRP. In addition, the improvement of tensile strength of the composites can be attributed to the fact that an effective layering design of balance (B22.5/G7.5) was formed between the outer layer of the skin of the composite glass fiber mat and long and continuous of basalt fiber acted as a core and tendon for the composite structure. An effective layering and structural design of the composites resisted sudden and fast crack growth because microcrack propagation towards the core of the composites was stopped by the individual glass fiber mat at the outer surface. Moreover, an optimized matrix acted as a binder of the fibers, transferring the load to the fibers and providing rigidity and shape to the structure. This contributed to the improvement of mechanical properties of the composites [55].  There is a correlation between tensile modulus and the tensile strength of the sample composites. A higher tensile modulus indicated higher elasticity of a material. From the results obtained, sample B22.5/7.5 achieved the highest tensile at average of 7106.32 MPa, followed by sample B at average of 6620.11 MPa, sample B15/G15 at average of 6503.5 MPa, sample B7.5/G22.5 and the lowest tensile modulus obtained by sample G at average of 3802.17 MPa. Figure 3 shows the trend of tensile modulus average values for each sample. It can be seen for the hybrid composites, the higher the weight percentage of basalt fiber, the higher the tensile modulus. However, from the results obtained in this study, sample B that consisted the highest weight percentage of basalt fiber possessed lower tensile modulus compared to sample B22.5/G7.5. A balance ratio between the basalt fiber and glass fiber is needed in providing the stiffness and toughness to the composite structure. This is because, the glass fiber's outer layer performed as a skin to protect fast micro or macro cracking initiation that supported by the core of the composites which contributed by basalt fiber. There is a correlation between tensile modulus and the tensile strength of the sample composites. A higher tensile modulus indicated higher elasticity of a material. From the results obtained, sample B22.5/7.5 achieved the highest tensile at average of 7106.32 MPa, followed by sample B at average of 6620.11 MPa, sample B15/G15 at average of 6503.5 MPa, sample B7.5/G22.5 and the lowest tensile modulus obtained by sample G at average of 3802.17 MPa. Figure 3 shows the trend of tensile modulus average values for each sample. It can be seen for the hybrid composites, the higher the weight percentage of basalt fiber, the higher the tensile modulus. However, from the results obtained in this study, sample B that consisted the highest weight percentage of basalt fiber possessed lower tensile modulus compared to sample B22.5/G7.5. A balance ratio between the basalt fiber and glass fiber is needed in providing the stiffness and toughness to the composite structure. This is because, the glass fiber's outer layer performed as a skin to protect fast micro or macro cracking initiation that supported by the core of the composites which contributed by basalt fiber.  Figure 4 shows the percentage elongation at break of the samples. Elongation at break is the ration between changed length after breakage and initial length of the material. Composite sample G that consisted of 30 wt % glass fiber showed the highest elongation and sample B that consisted of 30 wt % basalt fiber showed the lowest elongation at break. From the trend, it can be observed that the higher the basalt fiber contained in the composite, the lower the elongation at break. This is due to the improvement of rigidity of the composite after the improvement in the silica oxide (SiO2) and aluminum oxide (Al2O3) that had little contribution to the elongation but increased the modulus properties of the basalt fiber composite. Thus, basalt/glass fiber compared with glass fiber composite had a higher strain to failure characteristic compared to the low strain of extensibility of basalt fiber composite. The observed decrement in flexibility through decreasing elongation at break of the composites was likely related to the high stiffness of the composites with an increasing tensile modulus.  Figure 4 shows the percentage elongation at break of the samples. Elongation at break is the ration between changed length after breakage and initial length of the material. Composite sample G that consisted of 30 wt % glass fiber showed the highest elongation and sample B that consisted of 30 wt % basalt fiber showed the lowest elongation at break. From the trend, it can be observed that the higher the basalt fiber contained in the composite, the lower the elongation at break. This is due to the improvement of rigidity of the composite after the improvement in the silica oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) that had little contribution to the elongation but increased the modulus properties of the basalt fiber composite. Thus, basalt/glass fiber compared with glass fiber composite had a higher strain to failure characteristic compared to the low strain of extensibility of basalt fiber composite. The observed decrement in flexibility through decreasing elongation at break of the composites was likely related to the high stiffness of the composites with an increasing tensile modulus. Table 2 presents the results of tensile properties of the samples. The results shown that composite B22.5/G7.5 achieved the highest tensile strength and the highest tensile modulus at average of 269.85 and 7106.32 Mpa. The lowest tensile strength and tensile modulus were achieved by sample G that consisted of 30 wt % of glass fiber and 70 wt % of unsaturated polyester resin. For the elongation at break, sample B had the lowest average value at 1.51% and sample G had the highest value at 6.17%.  Overall, based on the obtained results for hybrid composites, the higher the weight percentage of basalt fiber contained in the hybrid composite, the higher the strength of the tensile properties. However, BFRP had lower strength of tensile properties compared to B22.5/G7.5. Thus, the presence of glass fiber in glass-basalt reinforced hybrid composite with ratio fiber percentage of 25% glass fiber and 75% basalt fiber, will improve the overall tensile properties.

Scanning Electron Microscopy
Figure 5a-f shows the morphology of basalt/glass-fiber-reinforced unsaturated polyester hybrid composites. For UP resin, there were microcracks appeared in the surface, as shown in Figure 5a. It was observed that more presence of fiber pull-out with increasing addition of basalt fiber even though initially, the UP surface was smooth than UP composites. The SEM morphology showed clear appearance of more fiber breakage and fewer voids as in Figure 5c-e. This was due to the debonding of the UP matrix when the samples were mechanically fractured, as in Figure 5e. This can be correlated in the tensile properties of B22.5/G7.5 that was improved than other composites. It was  Overall, based on the obtained results for hybrid composites, the higher the weight percentage of basalt fiber contained in the hybrid composite, the higher the strength of the tensile properties. However, BFRP had lower strength of tensile properties compared to B22.5/G7.5. Thus, the presence of glass fiber in glass-basalt reinforced hybrid composite with ratio fiber percentage of 25% glass fiber and 75% basalt fiber, will improve the overall tensile properties.

Scanning Electron Microscopy
Figure 5a-f shows the morphology of basalt/glass-fiber-reinforced unsaturated polyester hybrid composites. For UP resin, there were microcracks appeared in the surface, as shown in Figure 5a. It was observed that more presence of fiber pull-out with increasing addition of basalt fiber even though initially, the UP surface was smooth than UP composites. The SEM morphology showed clear appearance of more fiber breakage and fewer voids as in Figure 5c-e. This was due to the debonding of the UP matrix when the samples were mechanically fractured, as in Figure 5e. This can be correlated in the tensile properties of B22.5/G7.5 that was improved than other composites. It was found that the B22.5/G7.5 hybrid composites in Figure 5e showed less matrix cracking and fiber debonding, which may be contributed to higher stress absorption resulting in higher tensile and flexural properties (Tables 2 and 3). When the hybrid composites were in tension, the basalt fibers were able to resist the high tension, as well as to absorb a significant amount of tensile stress through the delamination of the glass fiber at the outer surface, fiber breakage and fiber pull-out of the glass fiber and induction of micro-to macro-cracking of the UP matrix [56][57][58].
Polymers 2020, 12, x 8 of 14 found that the B22.5/G7.5 hybrid composites in Figure 5e showed less matrix cracking and fiber debonding, which may be contributed to higher stress absorption resulting in higher tensile and flexural properties (Table 2 and Table 3). When the hybrid composites were in tension, the basalt fibers were able to resist the high tension, as well as to absorb a significant amount of tensile stress through the delamination of the glass fiber at the outer surface, fiber breakage and fiber pull-out of the glass fiber and induction of micro-to macro-cracking of the UP matrix [56][57][58].

Flexural Properties
According to previous study by Fiore et al. [53], the increase of basalt layer will improve the stiffness of the hybrid structures compared to the GFRP. Furthermore, during three-point bending test, the stress increment changed from the central zone to the external sides of the beam. The middle zone of the beam was in neutral axis since the top and bottom layer were subjected to the maximum stress. Therefore, since basalt fiber has better properties than glass fiber, the presence of basalt fiber in the hybrid composite enhance the flexural properties compared to GF composites. From the results obtained for GF and B composites, it was shown that basalt fiber reinforced polymer composite had higher flexural strength and Young's modulus compared to sample G. The flexural strength of B composites was higher by 380% to the flexural strength of GF composites. Furthermore, young's modulus of B composites was also higher by 250% compared to Young's modulus of GF composites. Figure 6 shown the trend of the flexural strength results. Figure 7 displays the trend of Young's modulus results. For the hybrid composite, from the trend, the higher the basalt fiber contained in the composite, the higher the flexural strength and Young's modulus. However, sample B22.5/G7.5 had a higher tensile strength and Young's modulus compared to sample B, even though sample B contained higher weight percentage of basalt fiber.

Flexural Properties
According to previous study by Fiore et al. [53], the increase of basalt layer will improve the stiffness of the hybrid structures compared to the GFRP. Furthermore, during three-point bending test, the stress increment changed from the central zone to the external sides of the beam. The middle zone of the beam was in neutral axis since the top and bottom layer were subjected to the maximum stress. Therefore, since basalt fiber has better properties than glass fiber, the presence of basalt fiber in the hybrid composite enhance the flexural properties compared to GF composites. From the results obtained for GF and B composites, it was shown that basalt fiber reinforced polymer composite had higher flexural strength and Young's modulus compared to sample G. The flexural strength of B composites was higher by 380% to the flexural strength of GF composites. Furthermore, young's modulus of B composites was also higher by 250% compared to Young's modulus of GF composites. Figure 6 shown the trend of the flexural strength results. Figure 7 displays the trend of Young's modulus results. For the hybrid composite, from the trend, the higher the basalt fiber contained in the composite, the higher the flexural strength and Young's modulus. However, sample B22.5/G7.5 had a higher tensile strength and Young's modulus compared to sample B, even though sample B contained higher weight percentage of basalt fiber.  As depicted in Figure 6 and 7, the flexural strength and modulus of the hybrid composites have similar trends as the tensile properties. The flexural properties increased with the increase of basalt fiber. In flexural test, failures mainly occurred due to bending and shearing [59]. The increased flexural strength of the hybrid composites with the loading of basalt fiber was mainly due to the increased resistance to shearing of the composites. The rigid basalt fiber was effectively acted as a core for the composites and a further increase of basalt fiber content in the hybrid composites resulted in the composite having sufficient modulus [60]. This was due to the fibers which were present in a sufficient amount, providing an effective stress transfer between the matrix and fiber and also due to the inherent properties of basalt fiber in the middle. This suggested that the flexural properties of the composites were more dependent on the amount of basalt fiber rather than glass fiber, which may be due to the high modulus of the basalt fiber compared to glass fiber that contributed by their unique chemical compositions [61]. Table 3 shows the results of flexural properties of the composite samples. Overall, the sample B22.5/G7.5 had the average of flexural strength and Young's modulus which were at 946.46 and 44,890.05 MPa, respectively. The lowest results for average flexural strength and Young's modulus achieved by sample G were 215.72 and 14,546.90 MPa, respectively. Overall, based on the obtained results for hybrid composites, the higher the weight percentage of basalt fiber contained in the hybrid composite, the higher the flexural strength. However, BFRP had lower strength in flexural properties compared to B22.5/G7.5. Thus, the presence of glass fiber in glass-basalt reinforced hybrid composite with ratio fiber percentage 25% glass fiber and 75% basalt fiber, improved the overall its flexural properties.

Conclusions
The mechanical properties of long basalt/woven-glass-fiber-reinforced unsaturated polyesterresin hybrid composites was investigated. The density of B composites with the addition of basalt fiber was slightly better at 1.8%, than B22.5/G7.5 hybrid composites. The tensile and flexural properties increased with the proportion of basalt fibers, the tensile strength was increased at 69% for B composites in relations to G composites, then further increased by 26% in relations to B22.5/G7.5 As depicted in Figures 6 and 7, the flexural strength and modulus of the hybrid composites have similar trends as the tensile properties. The flexural properties increased with the increase of basalt fiber. In flexural test, failures mainly occurred due to bending and shearing [59]. The increased flexural strength of the hybrid composites with the loading of basalt fiber was mainly due to the increased resistance to shearing of the composites. The rigid basalt fiber was effectively acted as a core for the composites and a further increase of basalt fiber content in the hybrid composites resulted in the composite having sufficient modulus [60]. This was due to the fibers which were present in a sufficient amount, providing an effective stress transfer between the matrix and fiber and also due to the inherent properties of basalt fiber in the middle. This suggested that the flexural properties of the composites were more dependent on the amount of basalt fiber rather than glass fiber, which may be due to the high modulus of the basalt fiber compared to glass fiber that contributed by their unique chemical compositions [61]. Table 3 shows the results of flexural properties of the composite samples. Overall, the sample B22.5/G7.5 had the average of flexural strength and Young's modulus which were at 946.46 and 44,890.05 MPa, respectively. The lowest results for average flexural strength and Young's modulus achieved by sample G were 215.72 and 14,546.90 MPa, respectively. Overall, based on the obtained results for hybrid composites, the higher the weight percentage of basalt fiber contained in the hybrid composite, the higher the flexural strength. However, BFRP had lower strength in flexural properties compared to B22.5/G7.5. Thus, the presence of glass fiber in glass-basalt reinforced hybrid composite with ratio fiber percentage 25% glass fiber and 75% basalt fiber, improved the overall its flexural properties.

Conclusions
The mechanical properties of long basalt/woven-glass-fiber-reinforced unsaturated polyester-resin hybrid composites was investigated. The density of B composites with the addition of basalt fiber was slightly better at 1.8%, than B22.5/G7.5 hybrid composites. The tensile and flexural properties increased with the proportion of basalt fibers, the tensile strength was increased at 69% for B composites in relations to G composites, then further increased by 26% in relations to B22.5/G7.5 hybrid composites. The flexural strength was increased by 15% for B22.5/G7.5 hybrid composites than B composites.