Modification of Poly(Ethylene 2,5-Furandicarboxylate) with Poly(Ethylene glycol) for Biodegradable Copolyesters with Good Mechanical Properties and Spinnability

Using 2,5-furandicarboxylic acid, ethylene glycol, and poly(ethylene glycol) as raw materials and ethylene glycol antimony as a catalyst, poly(ethylene furandicarboxylate) (PEF) and polyethylene glycol (PEG) copolymers (PEGFs) were synthesized by transesterification by changing the molecular weight of PEG (from 600 to 10,000 g/mol) and the PEG content (from 10 to 60 wt %). The thermal, hydrophilic, degradation, and spinnility characteristics of these copolymers were then investigated. Thermogravimetric analysis shows that PEGF is thermally stable at 62 °C, much lower than the temperature for PEF. The intrinsic viscosity of the obtained copolyester was between 0.67 and 0.99 dL/g, which is higher than the viscosity value of PEF. The contact angle experiment shows that the hydrophilicity of PEGFs is improved (the surface contact angle is reduced from 91.9 to 63.3°), which gives PEGFs a certain degradability, and the maximum mass loss can reach approximately 15%. Melt spinning experiments show that the PEGF polymer has poor spinnability, but the mechanical properties of the polymer monofilament are better.


Introduction
Plastics synthesized from petroleum are common in human life, and white pollution has attracted increasing attention. The non-renewability of oil and its ultimate depletion and rising prices introduce a considerable challenge to the petroleum industry relying on petroleum resources. People have begun to focus on green polymer materials, and industry and academia have also increased efforts on the research and development of polymer materials based on renewable resources [1][2][3][4][5].
At present, widely used bio-based polymer materials mainly include polylactic acid (PLA) [6], poly(hydroxy fatty acid) (PHA) [7], poly(glycolic acid) (PGA) [8], and poly(butylene glycol succinate) (PBS) [9]. They are all aliphatic polymers. Due to the lack of a rigid aromatic ring structure in the molecular structure, their mechanical properties (such as strength and modulus) and heat resistance (such as thermomechanical properties and heat distortion temperature) are significantly lower than those of petroleum-based polymers such as poly(ethylene terephthalate) (PET), poly(carbonate) (PC), and aromatic nylon (PA), which severely restricts the range of applications of aliphatic polymers. Therefore, to partially replace petroleum-based polymer materials, there is an urgent need to introduce for 3-4 h and 93% or more of methanol was distilled out. Finally, PEG was added before the vacuum was increased to 80-100 Pa and the temperature was raised to 235 °C. The polycondensation reaction lasted for 4 h. When an increasing effect occurred, the reaction ended. The target product PEGF copolyester was obtained.
Using the above method, this research varied the content of PEG (10,20,40, 60 wt %) and the number average molecular weight was 600, 2000, 6000, 10,000 g/mol to obtain a series of PEGF copolyesters.

Purification of PEF and PEGF Copolyester
The PEF and PEGF-40%-2000 copolyesters were dissolved in a mixed solution of chloroform and trifluoroacetic acid in the ratio of 9:1. Methanol was used as a settling agent to precipitate a polyester product. The separated polyester was dried in a vacuum oven at 120 °C for 48 h to obtain purified PEF and PEGF-40%-2000 copolyester.

Melt Spinning
We built a device ourselves, including screw extruder and winding machine. The ccrew extruder is to melt and extrude the polymer evenly. The winding machine continuously pulls the extruded polymer into fibers. The copolyester was spun by a micro single screw extruder and a winder. The specific experimental setup is shown in Figure 1. The single screw temperature is set as uniform and controlled at 200 °C, the winder speed was 20 m/min, and the temperature was raised to 200 °C. The PEGF-40%-2000 copolyester was added to the screw for melt spinning.

Intrinsic Viscosity
The PEGF copolyester was dried at 65 °C for 12 h using a vacuum oven and then cooled to room temperature in a desiccator. The intrinsic viscosities were tested at (25 ± 0.05) °C by an Ubbelohde viscometer (inside diameter of 0.7-0.8 mm). A total of 250 mg of PEGF samples were dissolved in a solvent mixture of phenol/tetrachloroethane (1/1, w/w). The intrinsic viscosity was obtained using Equations (1) and (2)

Intrinsic Viscosity
The PEGF copolyester was dried at 65 • C for 12 h using a vacuum oven and then cooled to room temperature in a desiccator. The intrinsic viscosities were tested at (25 ± 0.05) • C by an Ubbelohde viscometer (inside diameter of 0.7-0.8 mm). A total of 250 mg of PEGF samples were dissolved in a solvent mixture of phenol/tetrachloroethane (1/1, w/w). The intrinsic viscosity was obtained using Equations (1) and (2): Polymers 2019, 11, 2105 4 of 20 where η sp is the specific viscosity, c is the concentration (0.5 g/dL), and t 1 and t 0 are the flow times of the solution and pure solvent, respectively.

Nuclear Magnetic Resonance (NMR) Analysis
Nuclear magnetic resonance (NMR) spectra were recorded on a 600 MHz machine manufactured by Bruker Switzerland (Fällanden, Switzerland) at 25 • C. The solvent was deuterated trifluoroacetic acid (TFA). The weight of the PEGF copolyester sample was 5-10 mg.

Differential Scanning Calorimetry (DSC)
The thermal transition behavior was recorded by DSC under a N 2 flow. A 5-10 mg aliquot of copolyester was weighed and put into a bowl. The sample was first heated from −40 to 250 • C with a 10 • C/min rate and maintained at 250 • C for 5 min to erase the thermal history; then, it was cooled to −40 • C at a rate of 10 • C/min rate. Finally, the second heating run was performed with heating at 10 • C/min to 250 • C.

Thermogravimetric Analysis (TGA)
Thermal stability was investigated under a N 2 atmosphere by a TGA instruction (USA TA/Q5000IR). Approximately 3 to 5 mg of the sample was continuously monitored from 40 to 600 • C at a rate of 10 • C/min. The variation in PEGF mass with temperature was recorded.

Wide-Angle X-Ray Diffraction (WAXD)
Crystallization of PEGF copolyester was investigated by a Japanese max-2550VB+type 18kW target X-ray diffractometer. For the tests, a Cu target was used as an electrode light source, the voltage was 40 kV, the current was 150 mA, and the 2θ angle was 5 to 40 • .

Surface Contact Angle Test
The sample film was tested at 25 • C. For the tests, the amount of water dropped was 2 µL and the dropping rate was 1 µL/s. The contact angle value of the water droplets contacting the surface of the polyester film was recorded.

Degradability Test
Degradation experiments were performed in a phosphate buffered solution (pH = 7.2) at 37 • C. The PEF and PEGF copolyester samples were prepared as films with the dimension of 1 cm × 3 cm × (0.1-0.3) mm. The samples were dried in a vacuum oven at 50 • C for 48 h. The dried samples were weighed separately and the mass was m 0 . The samples were placed in a phosphate buffer solution and a sample was taken every 10 days. Then, the quality and structure of the sample were characterized.

Monofilament Strength
The PEF and PEGF-40%-2000 copolyester monofilaments were tested for strength using a monofilament strength instrument (WDW3020, Chongqing, China). Each sample was repeatedly measured 10 times, and the results were averaged.

Synthesis and Characterization of PEGF Copolyester
In this study, bio-based 2,5-DMFD, PEG and EG were used as reaction materials and the polymerization scheme is shown in Figure 2. The reaction used different molecular weights of different PEGs (number average molecular weights of 600, 2000, 6000, 10,000 g/mol) and different PEG contents (10,20,40, 60 wt % relative to DMFD) of PEGF copolyester. The esterification rate during polymerization is shown in Table 2.
Polymers 2019, 11, x FOR PEER REVIEW 5 of 21 In this study, bio-based 2,5-DMFD, PEG and EG were used as reaction materials and the polymerization scheme is shown in Figure 2. The reaction used different molecular weights of different PEGs (number average molecular weights of 600, 2000, 6000, 10,000 g/mol) and different PEG contents (10,20,40, 60 wt % relative to DMFD) of PEGF copolyester. The esterification rate during polymerization is shown in Table 2.  From the data in Table 1, when the esterification temperature is 190 °C, the esterification rate of each sample is above 90%. The intrinsic viscosity of PEGFs is shown in Table 1. The intrinsic viscosity of PEGF copolyester is between 0.62-0.99 dL/g, which is higher than the intrinsic viscosity of PEF (0.61 dL/g). When the content or molecular weight of PEG is increased, the intrinsic viscosity of PEGFs is increased, mainly because of the existence of flexible long-chain PEG, which increases the chain length and flexibility of PEGFs. These changes make part of the copolyester molecular chain tangle in the capillary, resulting in prolonged residence time of the solution in the capillary and indicating that the introduction of flexible PEG achieves a thickening effect on PEF.
The 1 H NMR spectra of PEGFs are presented. The structure of PEGFs with different PEG contents when the number average molecular weight of PEG is 2000 g/mol is shown in Figure 3. The structure of PEGFs with different molecular weights when the PEG mass content is 40 wt % is shown From the data in Table 1, when the esterification temperature is 190 • C, the esterification rate of each sample is above 90%. The intrinsic viscosity of PEGFs is shown in Table 1. The intrinsic viscosity of PEGF copolyester is between 0.62-0.99 dL/g, which is higher than the intrinsic viscosity of PEF (0.61 dL/g). When the content or molecular weight of PEG is increased, the intrinsic viscosity of PEGFs is increased, mainly because of the existence of flexible long-chain PEG, which increases the chain length and flexibility of PEGFs. These changes make part of the copolyester molecular chain tangle in the capillary, resulting in prolonged residence time of the solution in the capillary and indicating that the introduction of flexible PEG achieves a thickening effect on PEF. The 1 H NMR spectra of PEGFs are presented. The structure of PEGFs with different PEG contents when the number average molecular weight of PEG is 2000 g/mol is shown in Figure 3. The structure of PEGFs with different molecular weights when the PEG mass content is 40 wt % is shown in Figure 4. As seen in the figure, each copolyester contains a total of four different types of H atoms with different chemical environments, where δ a = 7.32 ppm corresponds to the H atom on the furan ring, δ b = 4.73 ppm corresponds to the H atom of the methylene group in the hard segment of the polyester, δ c = 3.84 ppm corresponds to the H atom of the methylene group on the segment of PEG, and δ d = 3.81 ppm corresponds to the H atom in the terminal hydroxyl group of each copolyester. Due to the different positions of -CH 2 -in the copolyester segment, the inductive effects of the surrounding atoms are different. The chemical shift of -CH 2 -at the chain end will shift. Therefore, there are small proton peaks near the peaks of b and c, where b2 is the proton peak of -CH 2 -in the PEF chain end, and c2 is the proton peak of -CH 2 -in the PEG segment. According to the NMR results, when the molecular weight of PEG is 2000 g/mol, the PEG content increases, and the area of the c peak gradually increases. The above information indicates that the copolyester obtained by the polymerization is the target product.
Polymers 2019, 11, x FOR PEER REVIEW 6 of 21 in Figure 4. As seen in the figure, each copolyester contains a total of four different types of H atoms with different chemical environments, where δa = 7.32 ppm corresponds to the H atom on the furan ring, δb = 4.73 ppm corresponds to the H atom of the methylene group in the hard segment of the polyester, δc = 3.84 ppm corresponds to the H atom of the methylene group on the segment of PEG, and δd = 3.81 ppm corresponds to the H atom in the terminal hydroxyl group of each copolyester. Due to the different positions of -CH2in the copolyester segment, the inductive effects of the surrounding atoms are different. The chemical shift of -CH2-at the chain end will shift. Therefore, there are small proton peaks near the peaks of b and c, where b2 is the proton peak of -CH2-in the PEF chain end, and c2 is the proton peak of -CH2-in the PEG segment. According to the NMR results, when the molecular weight of PEG is 2000 g/mol, the PEG content increases, and the area of the c peak gradually increases. The above information indicates that the copolyester obtained by the polymerization is the target product.    in Figure 4. As seen in the figure, each copolyester contains a total of four different types of H atoms with different chemical environments, where δa = 7.32 ppm corresponds to the H atom on the furan ring, δb = 4.73 ppm corresponds to the H atom of the methylene group in the hard segment of the polyester, δc = 3.84 ppm corresponds to the H atom of the methylene group on the segment of PEG, and δd = 3.81 ppm corresponds to the H atom in the terminal hydroxyl group of each copolyester. Due to the different positions of -CH2in the copolyester segment, the inductive effects of the surrounding atoms are different. The chemical shift of -CH2at the chain end will shift. Therefore, there are small proton peaks near the peaks of b and c, where b2 is the proton peak of -CH2in the PEF chain end, and c2 is the proton peak of -CH2-in the PEG segment. According to the NMR results, when the molecular weight of PEG is 2000 g/mol, the PEG content increases, and the area of the c peak gradually increases. The above information indicates that the copolyester obtained by the polymerization is the target product.    The content of PEG in the copolyester was calculated according to Equations (3) and (4), and the results are shown in Table 1. According to the results of the calculation, the actual added PEG content is consistent with the nuclear magnetic calculation results, indicating that the actually added PEG is fully involved in the reaction. The chemical structure of the PEGFs was confirmed by FTIR. The infrared spectrum of the copolyester of different content of PEG when the number average molecular weight of PEG is 2000 g/mol is shown in Figure 5; the infrared spectrum of the copolyester of different PEG molecular weights when the content of PEG is 40 wt % is shown in Figure 6. The peaks at 2885 and 1115 cm −1 are attributed to the -CH 2 -and C-O-C vibration modes of PEG, respectively. In the copolyester, not only the characteristic peak of PEG, but also the characteristic peak of PEF appeared. The peak at 1720 cm −1 is attributed to the C=O stretching vibration. The stretching vibration peaks of C-O-C appear at 1260 cm −1 . The stretching vibration peak of -CH 2 -is observed at 2962 cm −1 . The C-H and C=C stretching vibration peaks on the furan are observed at 3120 and 1580 cm −1 , respectively, and the bending vibration peaks of the furan ring appeared at 960, 828, and 760 cm −1 . According to the 1 H NMR and FTIR results, the positions of the characteristic peaks of the synthesized products are consistent with the positions of the characteristic peaks of each group in PEF and PEG. After the addition of PEG, the C-O-C peak of the product at 1115 cm −1 appeared to move to the low wavelength region. When the number of average molecular weight of PEG was 2000 g/mol, the peak width at that point increased with the increasing PEG content. When the molecular weight of PEG gradually increases, the peak widths change a little, indicating that when the molecular weight of PEG is 2000 g/mol, the obtained product is a PEGF copolyester. When the molecular weight of PEG is higher than 2000 g/mol, the resulting product may be a blend of PEGF copolyester and PEG, which remains to be further characterized. results are shown in Table 1. According to the results of the calculation, the actual added PEG content is consistent with the nuclear magnetic calculation results, indicating that the actually added PEG is fully involved in the reaction.
The chemical structure of the PEGFs was confirmed by FTIR. The infrared spectrum of the copolyester of different content of PEG when the number average molecular weight of PEG is 2000 g/mol is shown in Figure 5; the infrared spectrum of the copolyester of different PEG molecular weights when the content of PEG is 40 wt % is shown in Figure 6. The peaks at 2885 and 1115 cm −1 are attributed to the -CH2-and C-O-C vibration modes of PEG, respectively. In the copolyester, not only the characteristic peak of PEG, but also the characteristic peak of PEF appeared. The peak at 1720 cm −1 is attributed to the C=O stretching vibration. The stretching vibration peaks of C-O-C appear at 1260 cm −1 . The stretching vibration peak of -CH2-is observed at 2962 cm −1 . The C-H and C=C stretching vibration peaks on the furan are observed at 3120 and 1580 cm −1 , respectively, and the bending vibration peaks of the furan ring appeared at 960, 828, and 760 cm −1 . According to the 1 H NMR and FTIR results, the positions of the characteristic peaks of the synthesized products are consistent with the positions of the characteristic peaks of each group in PEF and PEG. After the addition of PEG, the C-O-C peak of the product at 1115 cm −1 appeared to move to the low wavelength region. When the number of average molecular weight of PEG was 2000 g/mol, the peak width at that point increased with the increasing PEG content. When the molecular weight of PEG gradually increases, the peak widths change a little, indicating that when the molecular weight of PEG is 2000 g/mol, the obtained product is a PEGF copolyester. When the molecular weight of PEG is higher than 2000 g/mol, the resulting product may be a blend of PEGF copolyester and PEG, which remains to be further characterized.

Thermal Properties of PEGF Copolyesters
The thermal stability of the PEGFs was characterized by TGA. The results are shown in Figures 7 and 8. From Table 2, the thermal decomposition temperature of each copolyester is approximately 350 °C, the temperature at the fastest thermal decomposition rate is approximately 395 °C, and the remaining copolyester approximately 9% after the temperature is raised to 600 °C. Compared with that of PEF, the thermal stability of PEGFs is slightly decreased, but it is still much higher than the spinning temperature of conventional polyesters. Therefore, the addition of PEG does not affect its practical application in terms of thermal stability.

Thermal Properties of PEGF Copolyesters
The thermal stability of the PEGFs was characterized by TGA. The results are shown in Figures 7 and 8. From Table 2, the thermal decomposition temperature of each copolyester is approximately 350 • C, the temperature at the fastest thermal decomposition rate is approximately 395 • C, and the remaining copolyester approximately 9% after the temperature is raised to 600 • C. Compared with that of PEF, the thermal stability of PEGFs is slightly decreased, but it is still much higher than the spinning temperature of conventional polyesters. Therefore, the addition of PEG does not affect its practical application in terms of thermal stability.

Thermal Properties of PEGF Copolyesters
The thermal stability of the PEGFs was characterized by TGA. The results are shown in Figures 7 and 8. From Table 2, the thermal decomposition temperature of each copolyester is approximately 350 °C, the temperature at the fastest thermal decomposition rate is approximately 395 °C, and the remaining copolyester approximately 9% after the temperature is raised to 600 °C. Compared with that of PEF, the thermal stability of PEGFs is slightly decreased, but it is still much higher than the spinning temperature of conventional polyesters. Therefore, the addition of PEG does not affect its practical application in terms of thermal stability.  The crystallization behavior and melting performance of PEGFs were investigated by DSC. The crystallization and melting curves of PEGFs with different PEG contents (PEG Mn = 2000 g/mol) are shown in Figure 9a,b. Compared with PEF, when the PEG content increases gradually, the melting peak area of PEGFs increases gradually. When the PEG content reaches 40 and 60 wt %, the copolyester exhibits an obvious crystallization peak during cooling, indicating that the increased PEG content can promote the crystallization of PEGFs and increase the crystallization rate. This is mainly because the copolyester uses a part of the shorter PEF segment as the crystal nucleus during the cooling process; thus the PEG segment with strong kinetic ability will be rapidly arranged on the crystal nucleus formed by the PEF, the crystal will gradually grow and the crystallization rate will be increased. As seen from Figure 9b, when the PEG content increases, the melting point of PEGFs gradually decreases. When the PEG content is 10 and 20 wt %, the crystallization peak appears before the melting of the PEGFs, indicating that when the PEG content in PEGFs is low, the crystallization rate of PEGFs is limited. In the cooling process, the PEGFs are not completely crystallized. During the heating process, when the temperature reaches the crystallization temperature again, the secondary crystals of PEGFs will appear, and imperfect crystallization peaks appear. When the PEG content is 40 and 60 wt %, the imperfect crystallization peak does not appear before the melting of the PEGFs, indicating that the crystallization rate of the PEGFs is faster with the increased PEG content, and that the crystallization is more perfect during the cooling process than before.   Table 2. Thermodynamic parameters of PEGF copolyester. Tg (Glass transition temperature); Tc (Crystallization temperature); ∆Hc (Crystallization enthalpy change); ∆Hm (Melting enthalpy change); Tm (Melting temperature); T d , 5% ( Temperature at 5% mass loss); T d , max ( • C)(Temperature when decomposition rate is maximum); R600 (Residual amount). Figure 10 a shows the cooling crystallization curves of PEGFs with PEG of different molecular weights (mass content: 40%). Compared with PEF, the addition of PEG promotes crystallization of the copolyester and increases its crystallization rate. When the molecular weight of PEG is 2000 g/mol, there is only one obvious crystallization peak during the cooling process of PEGFs. When the PEG molecular weight is 6000 and 10,000 g/mol, two crystallization peaks of PEGFs are observed during cooling, which is because the molecular weight of PEG of 2000 g/mol is equivalent to the molecular weight of PEF, so the two segments are well compatible. When the PEG molecular weight is 6000 and 10,000 g/mol, the PEG segment is long, and it is difficult for some PEG to begin the polycondensation reaction with PEF esterification during the polycondensation stage, resulting in some PEG coexisting with the copolyester in the form of a blend. During the cooling process, PEG present in a blended form is likely to undergo phase separation, so two crystallization peaks appear. Figure 10b shows the melting curve of PEGFs with PEG of different molecular weights (mass content: 40%). When the molecular weight of PEG increases gradually, the melting point of PEGFs increases first and then decreases, but always exceeds the melting point of PEF, indicating that the introduction of PEG segments destroys the regularity of PEF segments and decreases the melting point of PEGFs. When the molecular weight of PEG reaches 10,000 g/mol, substantial phase separation occurs in the PEGFs, which leads to a decrease in the melting point of the PEGFs. Figure 10 (a) shows the cooling crystallization curves of PEGFs with PEG of different molecular weights (mass content: 40%). Compared with PEF, the addition of PEG promotes crystallization of the copolyester and increases its crystallization rate. When the molecular weight of PEG is 2000 g/mol, there is only one obvious crystallization peak during the cooling process of PEGFs. When the PEG molecular weight is 6000 and 10,000 g/mol, two crystallization peaks of PEGFs are observed during cooling, which is because the molecular weight of PEG of 2000 g/mol is equivalent to the molecular weight of PEF, so the two segments are well compatible. When the PEG molecular weight is 6000 and 10,000 g/mol, the PEG segment is long, and it is difficult for some PEG to begin the polycondensation reaction with PEF esterification during the polycondensation stage, resulting in some PEG coexisting with the copolyester in the form of a blend. During the cooling process, PEG present in a blended form is likely to undergo phase separation, so two crystallization peaks appear. Figure 10 (b) shows the melting curve of PEGFs with PEG of different molecular weights (mass content: 40%). When the molecular weight of PEG increases gradually, the melting point of PEGFs increases first and then decreases, but always exceeds the melting point of PEF, indicating that the introduction of PEG segments destroys the regularity of PEF segments and decreases the melting point of PEGFs. When the molecular weight of PEG reaches 10,000 g/mol, substantial phase separation occurs in the PEGFs, which leads to a decrease in the melting point of the PEGFs.    Figure 10 (a) shows the cooling crystallization curves of PEGFs with PEG of different molecular weights (mass content: 40%). Compared with PEF, the addition of PEG promotes crystallization of the copolyester and increases its crystallization rate. When the molecular weight of PEG is 2000 g/mol, there is only one obvious crystallization peak during the cooling process of PEGFs. When the PEG molecular weight is 6000 and 10,000 g/mol, two crystallization peaks of PEGFs are observed during cooling, which is because the molecular weight of PEG of 2000 g/mol is equivalent to the molecular weight of PEF, so the two segments are well compatible. When the PEG molecular weight is 6000 and 10,000 g/mol, the PEG segment is long, and it is difficult for some PEG to begin the polycondensation reaction with PEF esterification during the polycondensation stage, resulting in some PEG coexisting with the copolyester in the form of a blend. During the cooling process, PEG present in a blended form is likely to undergo phase separation, so two crystallization peaks appear. Figure 10 (b) shows the melting curve of PEGFs with PEG of different molecular weights (mass content: 40%). When the molecular weight of PEG increases gradually, the melting point of PEGFs increases first and then decreases, but always exceeds the melting point of PEF, indicating that the introduction of PEG segments destroys the regularity of PEF segments and decreases the melting point of PEGFs. When the molecular weight of PEG reaches 10,000 g/mol, substantial phase separation occurs in the PEGFs, which leads to a decrease in the melting point of the PEGFs.

Hydrophilicity of PEGF Copolyester
When PEF is applied to the fiber field, there are still problems such as poor hydrophilicity of the polyester. To improve the hydrophilicity of PEF, this research introduced a flexible PEG segment into the PEF segment to increase the amorphous area in the PEGF so that water molecules can easily penetrate into the structure of the PEGFs. The molecular weight and content of PEG all affect the hydrophilicity of PEGFs. In this research, the hydrophilicity of PEGFs with different PEG molecular weights (600, 2000, 6000, 10,000 g/mol) and different contents (10, 20, 40, 60 wt %) was characterized. The results are shown in Figures 11 and 12. polyester. To improve the hydrophilicity of PEF, this research introduced a flexible PEG segment into the PEF segment to increase the amorphous area in the PEGF so that water molecules can easily penetrate into the structure of the PEGFs. The molecular weight and content of PEG all affect the hydrophilicity of PEGFs. In this research, the hydrophilicity of PEGFs with different PEG molecular weights (600, 2000, 6000, 10,000 g/mol) and different contents (10,20,40, 60 wt %) was characterized. The results are shown in Figures 11 and 12.   Figure 11 shows the change in contact angle on the surface of PEGFs with different PEG contents (PEG Mn = 2000 g/mol). As seen from Figure 11, when the molecular weight of PEG is the same, the surface contact angle of the PEGFs decreases from 80.1 to 63.3° with increasing the PEG content, but both are lower than the surface contact angle of the PEF polyester. This is mainly because after the introduction of PEG, the PEGFs form a block structure in which the hydrophilic and hydrophobic groups coexist, and the partial molecular chain of the PEG loosely arranges, so that surface water molecules can easily enter the surface of the PEGFs and increase the hydrophilicity of the PEGFs. Figure 12 shows the change of contact angle on the surface of PEGFs with different PEG molecular weights (mass content: 40%). When the molecular weight of PEG increases, the surface contact angle of PEGFs decreases from 84.2 to 37.6°. Compared with the PEG content, the molecular weight of PEG has a greater influence on the hydrophilicity of PEGFs. The reason for this phenomenon is that when the molecular weight of PEG is 2000 g/mol, the length of the PEG segment is equivalent to the length of the segment of the PEF. In the polycondensation stage, the PEF is easily the PEF segment to increase the amorphous area in the PEGF so that water molecules can easily penetrate into the structure of the PEGFs. The molecular weight and content of PEG all affect the hydrophilicity of PEGFs. In this research, the hydrophilicity of PEGFs with different PEG molecular weights (600, 2000, 6000, 10,000 g/mol) and different contents (10, 20, 40, 60 wt %) was characterized. The results are shown in Figures 11 and 12.   Figure 11 shows the change in contact angle on the surface of PEGFs with different PEG contents (PEG Mn = 2000 g/mol). As seen from Figure 11, when the molecular weight of PEG is the same, the surface contact angle of the PEGFs decreases from 80.1 to 63.3° with increasing the PEG content, but both are lower than the surface contact angle of the PEF polyester. This is mainly because after the introduction of PEG, the PEGFs form a block structure in which the hydrophilic and hydrophobic groups coexist, and the partial molecular chain of the PEG loosely arranges, so that surface water molecules can easily enter the surface of the PEGFs and increase the hydrophilicity of the PEGFs. Figure 12 shows the change of contact angle on the surface of PEGFs with different PEG molecular weights (mass content: 40%). When the molecular weight of PEG increases, the surface contact angle of PEGFs decreases from 84.2 to 37.6°. Compared with the PEG content, the molecular weight of PEG has a greater influence on the hydrophilicity of PEGFs. The reason for this phenomenon is that when the molecular weight of PEG is 2000 g/mol, the length of the PEG segment is equivalent to the length of the segment of the PEF. In the polycondensation stage, the PEF is easily  Figure 11 shows the change in contact angle on the surface of PEGFs with different PEG contents (PEG Mn = 2000 g/mol). As seen from Figure 11, when the molecular weight of PEG is the same, the surface contact angle of the PEGFs decreases from 80.1 to 63.3 • with increasing the PEG content, but both are lower than the surface contact angle of the PEF polyester. This is mainly because after the introduction of PEG, the PEGFs form a block structure in which the hydrophilic and hydrophobic groups coexist, and the partial molecular chain of the PEG loosely arranges, so that surface water molecules can easily enter the surface of the PEGFs and increase the hydrophilicity of the PEGFs. Figure 12 shows the change of contact angle on the surface of PEGFs with different PEG molecular weights (mass content: 40%). When the molecular weight of PEG increases, the surface contact angle of PEGFs decreases from 84.2 to 37.6 • . Compared with the PEG content, the molecular weight of PEG has a greater influence on the hydrophilicity of PEGFs. The reason for this phenomenon is that when the molecular weight of PEG is 2000 g/mol, the length of the PEG segment is equivalent to the length of the segment of the PEF. In the polycondensation stage, the PEF is easily polycondensed with PEG to form a PEF-PEG copolyester. The hydrophilicity of PEGFs increases only because the PEG segment is loosely arranged, and there is a weak microphase separation between the soft and hard segments, which has less influence on the hydrophilicity of the copolyester. When the molecular weight of PEG reaches 10,000 g/mol, the molecular weight of PEF differs greatly from the molecular weight of PEG. During the polycondensation process, part of the PEF can react with PEG to form PEGFs, but some PEG still exists in the form of polymer blends. When the PEG segment increases, the molecular chain of the copolyester is loosely arranged, and there is a relatively substantial phase separation in the form of a blend of PEG and PEPFs, which greatly improves the hydrophilicity of the PEGFs.

Degradability of PEGF Copolyester
Hydrolytic degradation of PEGFs was performed in a phosphate buffer solution (pH = 7.2) at 37 • C. Samples were taken every 10 days and dried in a vacuum oven at 50 • C for 48 h, and the mass of the sample was measured. Figure 13 shows the variation of the quality of PEF and its copolyester film with the degradation time. As seen from Figure 13, the quality change of PEF is not obvious during treatment in the phosphate buffer solution at pH = 7.2, and the mass loss is only approximately 0.5%, which fully indicates that under neutral conditions, PEF is not a degradable polymer. When PEG was introduced into PEF, the quality of PEGFs decreased with the prolongation of degradation time, which indicates that the introduction of PEG endowed the PEGFs with certain degradability, and the content and molecular weight of PEG had a great influence on the mass loss of PEGFs.
Hydrolytic degradation of PEGFs was performed in a phosphate buffer solution (pH = 7.2) at 37 °C. Samples were taken every 10 days and dried in a vacuum oven at 50 °C for 48 h, and the mass of the sample was measured. Figure 13 shows the variation of the quality of PEF and its copolyester film with the degradation time. As seen from Figure 13, the quality change of PEF is not obvious during treatment in the phosphate buffer solution at pH = 7.2, and the mass loss is only approximately 0.5%, which fully indicates that under neutral conditions, PEF is not a degradable polymer. When PEG was introduced into PEF, the quality of PEGFs decreased with the prolongation of degradation time, which indicates that the introduction of PEG endowed the PEGFs with certain degradability, and the content and molecular weight of PEG had a great influence on the mass loss of PEGFs.
As seen from Figure 13(a), when the molecular weight of PEG is 2000 g/mol, the weight loss rate of the PEGFs increases with increasing PEG content. When the PEG content is 60 wt %, the mass loss of the PEGFs is the highest, reaching about 15%. From the degradation results, the change in the degradability of PEGFs is consistent with the change in hydrophilicity of PEGFs. This is mainly because the introduction of PEG improves the hydrophilicity of PEGFs, and water molecules easily enter the interior of the molecule. The ester bond in the molecular chain is attacked by water molecules, a hydrolysis reaction occurs, and the molecular chain is broken. As seen from Figure 13(b), when the PEG content reaches 40 wt %, the PEGFs experience an obvious mass loss. With the increase in the molecular weight of PEG, the mass loss of PEGFs is more obvious and the degradation is more substantial. When the molecular weight of PEG is 10,000 g/mol, the mass loss of PEGFs is the highest, at 15.3%. When the molecular weight of PEG is 600 and 2000 g/mol, the change in quality of the two is basically the same as the degradation time increases. When the molecular weight of PEG is 6000 and 10,000 g/mol, the change in quality of both are the same. This is mainly because when the molecular weight of PEG is low, the length of the segment is equivalent to that of PEF. The compatibility between soft and hard segments is better, the attack probability of water molecules on ester bonds is not large, and the mass loss is relatively small. When the molecular weight of PEG reaches 6000 and 10,000 g/mol, the molecular chain lengths between the As seen from Figure 13a, when the molecular weight of PEG is 2000 g/mol, the weight loss rate of the PEGFs increases with increasing PEG content. When the PEG content is 60 wt %, the mass loss of the PEGFs is the highest, reaching about 15%. From the degradation results, the change in the degradability of PEGFs is consistent with the change in hydrophilicity of PEGFs. This is mainly because the introduction of PEG improves the hydrophilicity of PEGFs, and water molecules easily enter the interior of the molecule. The ester bond in the molecular chain is attacked by water molecules, a hydrolysis reaction occurs, and the molecular chain is broken.
As seen from Figure 13b, when the PEG content reaches 40 wt %, the PEGFs experience an obvious mass loss. With the increase in the molecular weight of PEG, the mass loss of PEGFs is more obvious and the degradation is more substantial. When the molecular weight of PEG is 10,000 g/mol, the mass loss of PEGFs is the highest, at 15.3%. When the molecular weight of PEG is 600 and 2000 g/mol, the change in quality of the two is basically the same as the degradation time increases. When the molecular weight of PEG is 6000 and 10,000 g/mol, the change in quality of both are the same. This is mainly because when the molecular weight of PEG is low, the length of the segment is equivalent to that of PEF. The compatibility between soft and hard segments is better, the attack probability of water molecules on ester bonds is not large, and the mass loss is relatively small. When the molecular weight of PEG reaches 6000 and 10,000 g/mol, the molecular chain lengths between the soft and hard segments are significantly different. These two are prone to serious phase separation, which increases the probability of attack by water molecules on ester bonds, and the quality loss is more substantial. Table 3 shows the change in intrinsic viscosity after 100 days of degradation of PEGFs. From the table, after 100 days of degradation treatment, the intrinsic viscosity of PEF changes very little, only 0.1 dL/g, while the intrinsic viscosity of PEGF copolyester changes greatly. When the molecular weight of PEG is 2000 g/mol, the intrinsic viscosity of PEGFs increases with increasing PEG content. When the PEG content reaches 60 wt %, the intrinsic viscosity decreases by 0.66 dL/g. The conversion of PEGFs from high-molecular-weight polymers to low-molecular-weight polymers leads to the degradation of PEGFs. When the PEG content is 40 wt %, as the molecular weight of PEG increases, the intrinsic viscosity of PEGFs also decreases. When the molecular weight of PEG is 10,000 g/mol, the intrinsic viscosity of the PEGFs decreases by at most 0.45 dL/g. From the trend of intrinsic viscosity change, the introduction of PEG endows PEGFs with certain degradability, and its change trend is consistent with the trend of the change in quality of PEGFs. Note: η 1 is the intrinsic viscosity of the sample for 0 days of degradation; η 2 is the intrinsic viscosity of the sample for 100 days of degradation; η = η 1 − η 2 . Figure 14 shows the change in the pH value of the degradation solution after 100 days of degradation of PEGFs. With the prolongation of degradation time, the pH value of PEF and its copolyester degradation solution shows a decreasing trend, and the degradation solution gradually changes from neutral to weakly acidic, which indicates that the degradation mechanism of PEEFs is acidic hydrolysis. The mechanism is shown in Figure 15. As seen from Figure 14a, when the molecular weight of the PEG is 2000 g/mol and the PEG content is increased, the pH of the PEGF degradation solution is gradually increased. As seen from Figure 14b, with the increase of the PEG molecular weight, the pH value of the PEGF degradation solution is the same, which indicates that the content of PEG has a major influence on the pH value of the PEGF degradation solution.
weight of PEG is 2000 g/mol, the intrinsic viscosity of PEGFs increases with increasing PEG content. When the PEG content reaches 60 wt %, the intrinsic viscosity decreases by 0.66 dL/g. The conversion of PEGFs from high-molecular-weight polymers to low-molecular-weight polymers leads to the degradation of PEGFs. When the PEG content is 40 wt %, as the molecular weight of PEG increases, the intrinsic viscosity of PEGFs also decreases. When the molecular weight of PEG is 10,000 g/mol, the intrinsic viscosity of the PEGFs decreases by at most 0.45 dL/g. From the trend of intrinsic viscosity change, the introduction of PEG endows PEGFs with certain degradability, and its change trend is consistent with the trend of the change in quality of PEGFs.  Figure 14 shows the change in the pH value of the degradation solution after 100 days of degradation of PEGFs. With the prolongation of degradation time, the pH value of PEF and its copolyester degradation solution shows a decreasing trend, and the degradation solution gradually changes from neutral to weakly acidic, which indicates that the degradation mechanism of PEEFs is acidic hydrolysis. The mechanism is shown in Figure 15. As seen from Figure 14(a), when the molecular weight of the PEG is 2000 g/mol and the PEG content is increased, the pH of the PEGF degradation solution is gradually increased. As seen from Figure 14(b), with the increase of the PEG molecular weight, the pH value of the PEGF degradation solution is the same, which indicates that the content of PEG has a major influence on the pH value of the PEGF degradation solution. To further explain the degradation mechanism of PEGFs and the change in structure of PEGFs during hydrolysis, in this research, the most degraded samples (PEGF-60%-2000 and PEGF-40%-10000) were selected for the analysis of the surface topography of polyester film, nuclear magnetic resonance, and PEGF degradation experiments. Samples were selected after 0, 40, 70, and 100 days of PEGF degradation.
As shown in Figure 16, the area was integrated to calculate the content of PEG in PEGFs. The results are shown in Table 4. As seen from Table 4, when the degradation time increases, the PEG content in PEGFs decreases gradually. Peaks a and b are integrated. The ratio of peak area do not change with the prolongation of degradation time, which indicates that during the degradation of PEGFs, the ester bond linking the PEG moiety is mainly hydrolyzed and broken, and the PEGFs are partially is degraded. To further explain the degradation mechanism of PEGFs and the change in structure of PEGFs during hydrolysis, in this research, the most degraded samples (PEGF-60%-2000 and PEGF-40%-10000) were selected for the analysis of the surface topography of polyester film, nuclear magnetic resonance, and PEGF degradation experiments. Samples were selected after 0, 40, 70, and 100 days of PEGF degradation.
As shown in Figure 16, the area was integrated to calculate the content of PEG in PEGFs. The results are shown in Table 4. As seen from Table 4, when the degradation time increases, the PEG content in PEGFs decreases gradually. Peaks a and b are integrated. The ratio of peak area do not change with the prolongation of degradation time, which indicates that during the degradation of PEGFs, the ester bond linking the PEG moiety is mainly hydrolyzed and broken, and the PEGFs are partially is degraded.    The degradation solution of the PEGF-60%-2000 copolyester was subjected to rotary evaporation at 70 • C to obtain a white flocculent material, which was subjected to nuclear magnetic resonance characterization. As seen from Figure 17, there are three proton peaks in the nuclear magnetic resonance curve, where δ = 4.79 ppm is the proton peak of deuterated water, and δ = 7.36 ppm is the proton peak in phosphate. By inspection, δ = 3.72 ppm is the proton peak of -CH 2 -in the PEG segment, which indicates that in the degradation of PEGFs, mainly occurs by PEG partial chain scission.  The degradation solution of the PEGF-60%-2000 copolyester was subjected to rotary evaporation at 70 °C to obtain a white flocculent material, which was subjected to nuclear magnetic resonance characterization. As seen from Figure 17, there are three proton peaks in the nuclear magnetic resonance curve, where δ = 4.79 ppm is the proton peak of deuterated water, and δ = 7.36 ppm is the proton peak in phosphate. By inspection, δ = 3.72 ppm is the proton peak of -CH2-in the PEG segment, which indicates that in the degradation of PEGFs, mainly occurs by PEG partial chain scission. As seen in Table 4, at the beginning of degradation, the content of PEG changes slightly, but its mass loss is substantial. In the later stage of degradation, the content of PEG changes greatly, but its mass loss is small. In the beginning of degradation, although the copolyester has a certain hydrophilicity, the internal structure of the PEGFs is still very regular, and it is difficult for water molecules to interact with each ester bond. Some PEG-linked short-chain PEFs enter the degradation solution together, making the weight loss of the PEGFs more obvious. In the late stage of degradation, the molecular weight of PEGFs is low, and there are many pores inside the molecule. The ester bond linked to PEG is easily attacked by water molecules, which causes the ester bond at both ends of the PEG to break, allowing the PEG molecule to enter the degradation liquid, and the remaining short chain PEF is still present in the PEGFs. The mechanical properties of the PEGFs gradually deteriorate, showing the fragile nature of the material. The result is shown in Figure 19. Figure 18 shows the nuclear magnetic resonance curve of the PEGF-40%-10000 degradation sample after treatment for different numbers of days. Table 5 shows changes in the PEG content. The PEG content in the PEGFs gradually decreases when the degradation time increases, but when the degradation time increases, the changes in the PEG content in each stage are almost the same. In the late stage of degradation, the change is slightly reduced. This phenomenon is completely different from that observed for the PEGF-60%-2000 copolyester. The reason for this phenomenon is that when the molecular weight of PEG reaches 10,000 g/mol, the segment of PEG is longer, and the PEF esterification chain length is much different from that of PEG. Thus, part of the PEG segment forms an ester with PEF, and part of the PEG segment forms a blend with PEGFs. With the prolongation of degradation time, the PEG segment in the form of blend is gradually degraded and dissolved in the degradation solution, and the PEG in the form of copolyester is gradually hydrolyzed and undergoes chain breakage during degradation. The mechanical properties of PEGFs were analyzed. When the degradation time is prolonged, the PEGF-40%-10000 copolyester is gradually transformed from a PEMF film with good toughness into a fragile film. Figure 18 shows the nuclear magnetic resonance curve of the PEGF-40%-10000 degradation sample after treatment for different numbers of days. Table 5 shows changes in the PEG content. The PEG content in the PEGFs gradually decreases when the degradation time increases, but when the degradation time increases, the changes in the PEG content in each stage are almost the same. In the late stage of degradation, the change is slightly reduced. This phenomenon is completely different from that observed for the PEGF-60%-2000 copolyester. The reason for this phenomenon is that when the molecular weight of PEG reaches 10,000 g/mol, the segment of PEG is longer, and the PEF esterification chain length is much different from that of PEG. Thus, part of the PEG segment forms an ester with PEF, and part of the PEG segment forms a blend with PEGFs. With the prolongation of degradation time, the PEG segment in the form of blend is gradually degraded and dissolved in the degradation solution, and the PEG in the form of copolyester is gradually hydrolyzed and undergoes chain breakage during degradation. The mechanical properties of PEGFs were analyzed. When the degradation time is prolonged, the PEGF-40%-10000 copolyester is gradually transformed from a PEMF film with good toughness into a fragile film.   Figure 18. NMR of PEGF-40%-10000 degradation samples. The surface morphology of PEGFs was analyzed by SEM. Figure 19 shows SEM images of the PEF, PEGF-60%-2000, and PEGF-40%-10000 degradation films. With the prolongation of degradation time, there is almost no change in the surface of PEF, indicating that PEF cannot be degraded in a neutral buffer solution. For the PEGF-60%-2000 copolyester, during the pressing film formation, when the surface of the polyester film is naturally cooled from 240 • C to room temperature, the PEG segment rapidly crystallizes. When the degradation time is prolonged, the PEG segment on the surface of the polyester film is gradually reduced, and at the same time the surface has irregularities and a certain depth of pores. For the PEGF-40%-10000 copolyester, when the degradation continues for to 40 days, many pores appear on the surface of the PEGFs. As the degradation time is prolonged, the pores became larger and deeper, which indicates that the degradation of the PEGFs is more substantial. segment rapidly crystallizes. When the degradation time is prolonged, the PEG segment on the surface of the polyester film is gradually reduced, and at the same time the surface has irregularities and a certain depth of pores. For the PEGF-40%-10000 copolyester, when the degradation continues for to 40 days, many pores appear on the surface of the PEGFs. As the degradation time is prolonged, the pores became larger and deeper, which indicates that the degradation of the PEGFs is more substantial. Figure 19. SEM images of PEF and its copolyester degradation samples.

Melt Spinning on PEF and PEGF-40%-2000
When the PEG content is 40 wt % and the molecular weight is 2000 g/mol, the obtained PEGFs have relatively excellent elasticity. In this research, a single-screw extruder and a small drafting device were used to spin the PEGF-40%-2000 to obtain the monofilament of the PEGFs. For comparison, the prepared PEF was spun and treated with a monofilament. The strength of the monofilaments is measured. Figure 20 shows the PEF and PEGF-40%-2000 monofilaments. PEF shows large brittleness during spinning, so spinning is difficult to carry out. There are many broken filaments in the obtained monofilament. PEGF-40%-2000 has good elasticity during the spinning process, but the copolyester has a high viscosity and easily adheres to the mould. Thus, the fiber forming property is poor. The obtained monofilament has an uneven distribution and broken filaments.

Melt Spinning on PEF and PEGF-40%-2000
When the PEG content is 40 wt % and the molecular weight is 2000 g/mol, the obtained PEGFs have relatively excellent elasticity. In this research, a single-screw extruder and a small drafting device were used to spin the PEGF-40%-2000 to obtain the monofilament of the PEGFs. For comparison, the prepared PEF was spun and treated with a monofilament. The strength of the monofilaments is measured. Figure 20 shows the PEF and PEGF-40%-2000 monofilaments. PEF shows large brittleness during spinning, so spinning is difficult to carry out. There are many broken filaments in the obtained monofilament. PEGF-40%-2000 has good elasticity during the spinning process, but the copolyester has a high viscosity and easily adheres to the mould. Thus, the fiber forming property is poor. The obtained monofilament has an uneven distribution and broken filaments.
when the surface of the polyester film is naturally cooled from 240 °C to room temperature, the PEG segment rapidly crystallizes. When the degradation time is prolonged, the PEG segment on the surface of the polyester film is gradually reduced, and at the same time the surface has irregularities and a certain depth of pores. For the PEGF-40%-10000 copolyester, when the degradation continues for to 40 days, many pores appear on the surface of the PEGFs. As the degradation time is prolonged, the pores became larger and deeper, which indicates that the degradation of the PEGFs is more substantial. Figure 19. SEM images of PEF and its copolyester degradation samples.

Melt Spinning on PEF and PEGF-40%-2000
When the PEG content is 40 wt % and the molecular weight is 2000 g/mol, the obtained PEGFs have relatively excellent elasticity. In this research, a single-screw extruder and a small drafting device were used to spin the PEGF-40%-2000 to obtain the monofilament of the PEGFs. For comparison, the prepared PEF was spun and treated with a monofilament. The strength of the monofilaments is measured. Figure 20 shows the PEF and PEGF-40%-2000 monofilaments. PEF shows large brittleness during spinning, so spinning is difficult to carry out. There are many broken filaments in the obtained monofilament. PEGF-40%-2000 has good elasticity during the spinning process, but the copolyester has a high viscosity and easily adheres to the mould. Thus, the fiber forming property is poor. The obtained monofilament has an uneven distribution and broken filaments.  The mechanical properties of the monofilament were analyzed. The results are shown in Figure 21 and Table 6. As shown in Table 6, the PEF monofilament is difficult to draft, and its strength is low, only 1.15 cN/dtex. The monofilament shows high brittleness and poor mechanical strength. For the PEGF-40%-2000 copolyester, the monofilament can be stretched greatly at room temperature, the drafting ratio is four times, the fiber strength can reach 2.48 cN/dtex, and the elongation at break is 52.4%. Monofilaments have good elasticity and mechanical strength, but the spinnability of PEGF-40%-2000 still needs to be further improved. 21 and Table 6. As shown in Table 6, the PEF monofilament is difficult to draft, and its strength is low, only 1.15 cN/dtex. The monofilament shows high brittleness and poor mechanical strength. For the PEGF-40%-2000 copolyester, the monofilament can be stretched greatly at room temperature, the drafting ratio is four times, the fiber strength can reach 2.48 cN/dtex, and the elongation at break is 52.4%. Monofilaments have good elasticity and mechanical strength, but the spinnability of PEGF-40%-2000 still needs to be further improved.

Conclusion
In this work, PEGF copolyseters with different PEG molecular weights of 600 to 10,000 g/mol and different PEG contents were synthesized from DMFD, EG, and PEG. The effect of the PEG molecular weight and the PEG content on the structure and properties of the copolyester was analyzed. The intrinsic viscosity of the obtained copolyester was between 0.67 and 0.99 dL/g which is higher than the viscosity value of PEF. When the molecular weight of PEG is 2000 g/mol, the crystallization rate of copolyester increases with increasing PEG content. When the PEG content is 40 wt %, the crystallization rate increases most obviously, and the melting temperature and crystallization temperature decrease gradually. The hydrophilicity of PEGFs is improved (the surface contact angle is reduced from 91.9 to 63.3°), which endows PEGFs with a certain degradability, and the maximum mass loss can reach approximately 15%. When the PEG content is 40 wt %, the crystallization rate of PEGFs increases with increasing PEG molecular weight. The melting temperature and crystallization temperature first increase and then decrease, and the hydrophilicity of the PEGFs is improved (the surface contact angle is reduced from 91.9 to 37.9°), which gives the PEGFs a certain degree of degradability, and the mass loss can reach up to 15%. In this study, the fusion of PEF and PEGF-40%-2000 polyesters was analyzed for the first time. There are still many problems in the obtained fiber, such as uneven fiber distribution and the occurrence of broken wires and filaments. Therefore, further research on the polymerization conditions of PEF and its

Conclusions
In this work, PEGF copolyseters with different PEG molecular weights of 600 to 10,000 g/mol and different PEG contents were synthesized from DMFD, EG, and PEG. The effect of the PEG molecular weight and the PEG content on the structure and properties of the copolyester was analyzed. The intrinsic viscosity of the obtained copolyester was between 0.67 and 0.99 dL/g which is higher than the viscosity value of PEF. When the molecular weight of PEG is 2000 g/mol, the crystallization rate of copolyester increases with increasing PEG content. When the PEG content is 40 wt %, the crystallization rate increases most obviously, and the melting temperature and crystallization temperature decrease gradually. The hydrophilicity of PEGFs is improved (the surface contact angle is reduced from 91.9 to 63.3 • ), which endows PEGFs with a certain degradability, and the maximum mass loss can reach approximately 15%. When the PEG content is 40 wt %, the crystallization rate of PEGFs increases with increasing PEG molecular weight. The melting temperature and crystallization temperature first increase and then decrease, and the hydrophilicity of the PEGFs is improved (the surface contact angle is reduced from 91.9 to 37.9 • ), which gives the PEGFs a certain degree of degradability, and the mass loss can reach up to 15%. In this study, the fusion of PEF and PEGF-40%-2000 polyesters was analyzed for the first time. There are still many problems in the obtained fiber, such as uneven fiber distribution and the occurrence of broken wires and filaments. Therefore, further research on the polymerization conditions of PEF and its copolyester and the content and molecular weight of PEG are needed to produce bio-based fibers with certain spinnability and excellent mechanical properties.