Thermally Activated Paramagnets from Diamagnetic Polymers of Biphenyl-3 , 5-diyl Bis ( tert-butyl Nitroxides ) Carrying Methyl and Fluoro Groups at the 2 ’-and 5 ’-Positions

Three new biradicals—2’,5’-dimethyl-, 2’-fluoro-5’-methyl-, and 5’-fluoro-2’-methylbiphenyl-3,5-diyl bis(tert-butyl nitroxides)—were synthesized. The magnetic susceptibility measurements revealed their diamagnetism below and around room temperature. The nitroxide groups are located close to each other in an intermolecular fashion to form a weakly covalent head-to-tail (NO)2 ring. Biradical molecules are connected on both radical sites, constructing a diamagnetic chain. The dimethyl derivative underwent a structural phase transition at 83  ̋C, clarified via differential scanning calorimetry and powder X-ray diffraction, and a paramagnetic solid phase with S = 1 irreversibly appeared. The other analogues exhibited a similar irreversible upsurge of the magnetic susceptibility on heating, but the transition was characterized as the melting.

Various solid-state magnetic switches are of increasing interest for future applications to sensing, memory, display, and other devices [12].There have been few known skeletons of organic materials showing facile σ-bond cleavage accompanied by drastic changes of both chromic and magnetic properties.We have reported that the intermolecular N¨¨¨O σ-type bond is formed and cleaved in the crystals of the BPBN derivatives [6][7][8]13].The nitroxide spin centers have a strong tendency to form an intermolecular antiferromagnetic couple or a weak covalent bond.The head-to-tail dimerization of the nitroxide groups is explained in terms of a dipolar character: >N-O ‚ Ø >N `‚-O ´ [14][15][16][17][18].

Crystal Structure Analysis
As the X-ray diffraction study at 90-110 K clarifies, they crystallize in a triclinic space group 1 with Z = 2, except for β-25MeBPBN.Table 1 summarizes selected crystallographic data on α-25Me-, β-25Me-, 2F5Me-, and 5F2MeBPBN, together with related known compounds (3Me-and 25FBPBN).The present triclinic compounds are isomorphous (Figure 1a-c, top), and the intermolecular close contacts between O and N atoms are found to be identical (Figure 1a-c, bottom).Although the conformation of the tert-butyl nitroxide group is slightly different from those of 3Me-, 3F-, and 25FBPBN, the molecular arrangements are also similar among them.Every nitroxide group is located in very close proximity to each other in an intermolecular fashion, to form a centrosymmetric fourmembered (NO)2 ring from head-to-tail dimerization.The molecules are connected on both radical sites (Figure 2).As a result, they form a weakly covalent bonded chain running in the crystallographic b + c direction.The intermolecular O1
Scheme 1. Structural formula and abbreviations.

Crystal Structure Analysis
As the X-ray diffraction study at 90-110 K clarifies, they crystallize in a triclinic space group 1 with Z = 2, except for β-25MeBPBN.Table 1 summarizes selected crystallographic data on α-25Me-, β-25Me-, 2F5Me-, and 5F2MeBPBN, together with related known compounds (3Me-and 25FBPBN).The present triclinic compounds are isomorphous (Figure 1a-c, top), and the intermolecular close contacts between O and N atoms are found to be identical (Figure 1a-c, bottom).Although the conformation of the tert-butyl nitroxide group is slightly different from those of 3Me-, 3F-, and 25FBPBN, the molecular arrangements are also similar among them.Every nitroxide group is located in very close proximity to each other in an intermolecular fashion, to form a centrosymmetric fourmembered (NO)2 ring from head-to-tail dimerization.The molecules are connected on both radical sites (Figure 2).

Crystal Structure Analysis
As the X-ray diffraction study at 90-110 K clarifies, they crystallize in a triclinic space group P1 with Z = 2, except for β-25MeBPBN.Table 1 summarizes selected crystallographic data on α-25Me-, β-25Me-, 2F5Me-, and 5F2MeBPBN, together with related known compounds (3Me-and 25FBPBN).The present triclinic compounds are isomorphous (Figure 1a-c, top), and the intermolecular close contacts between O and N atoms are found to be identical (Figure 1a-c, bottom).Although the conformation of the tert-butyl nitroxide group is slightly different from those of 3Me-, 3F-, and 25FBPBN, the molecular arrangements are also similar among them.Every nitroxide group is located in very close proximity to each other in an intermolecular fashion, to form a centrosymmetric four-membered (NO) 2 ring from head-to-tail dimerization.The molecules are connected on both radical sites (Figure 2).As a result, they form a weakly covalent bonded chain running in the crystallographic b + c direction.The intermolecular O1¨¨¨N1 i and O2¨¨¨N2 ii distances are respectively 2.379(3) and 2.348(2) Åfor α-25MeBPBN, 2.335(3) and 2.330(4) Åfor 2F5MeBPBN, and 2.342(4) and 2.338(6) Åfor 5F2MeBPBN, where the symmetry operation codes of i and ii are (-x, 1 -y, 1 -z) and (-x, -y, -z), respectively.They are ca.22%-24% shorter than the sum of the van der Waals radii of O and N atoms (3.07 Å) [21].Reference [7] this work this work Reference [8] this work this work Crystals 2016, 6, 30 3 of 9 2.348(2) Å for α-25MeBPBN, 2.335(3) and 2.330(4) Å for 2F5MeBPBN, and 2.342(4) and 2.338(6) Å for 5F2MeBPBN, where the symmetry operation codes of i and ii are (-x, 1 -y, 1 -z) and (-x, -y, -z), respectively.They are ca.22%-24% shorter than the sum of the van der Waals radii of O and N atoms (3.07 Å) [21].Reference [7] this work this work Reference [8] this work this work  Polymorphism of 25MeBPBN was found, and the parameters were satisfactorily refined for both α-and β-phases.As Figure 3  The differential scanning calorimetry (DSC; Figure 4) and powder X-ray diffraction (PXRD; Figure 5) of 25MeBPBN clarified that α-25MeBPBN underwent a structural phase transition at 353 K, and β-25MeBPBN irreversibly appeared.The DSC profile of α-25MeBPBN showed two endothermic peaks at 353 and 387 K, whereas that of β-25MeBPBN only one endothermic peak at 387 K.The hightemperature peak is related with the mp.A huge exothermic signal appeared just above the mp, probably ascribable to chemical degradation.The additional peak at 353 K found in α-25MeBPBN is ascribable to a solid-state/solid-state phase transition.The PXRD profile was drastically changed across the transition (Figure 5, bottom and middle).The major PXRD reflections of the hightemperature phase were practically identical to those of the β-25MeBPBN prepared separately (Figure 5, top).A trace of the α-phase was found to remain in the annealed specimen.This finding is entirely consistent with the magnetic study (see below).The α-→β-phase transition was found to be irreversible, as confirmed with the cooling process in the magnetic measurements and DSC analysis.The present observation is similar to that of BPBN [6].The mother BPBN compound showed the dia-/paramagnetic phase transition accompanied by the 1 -C2/c space group alteration.Polymorphism of 25MeBPBN was found, and the parameters were satisfactorily refined for both α-and β-phases.As Figure 3  The differential scanning calorimetry (DSC; Figure 4) and powder X-ray diffraction (PXRD; Figure 5) of 25MeBPBN clarified that α-25MeBPBN underwent a structural phase transition at 353 K, and β-25MeBPBN irreversibly appeared.The DSC profile of α-25MeBPBN showed two endothermic peaks at 353 and 387 K, whereas that of β-25MeBPBN only one endothermic peak at 387 K.The hightemperature peak is related with the mp.A huge exothermic signal appeared just above the mp, probably ascribable to chemical degradation.The additional peak at 353 K found in α-25MeBPBN is ascribable to a solid-state/solid-state phase transition.The PXRD profile was drastically changed across the transition (Figure 5, bottom and middle).The major PXRD reflections of the hightemperature phase were practically identical to those of the β-25MeBPBN prepared separately (Figure 5, top).A trace of the α-phase was found to remain in the annealed specimen.This finding is entirely consistent with the magnetic study (see below).The α-→β-phase transition was found to be irreversible, as confirmed with the cooling process in the magnetic measurements and DSC analysis.The present observation is similar to that of BPBN [6].The mother BPBN compound showed the dia-/paramagnetic phase transition accompanied by the 1 -C2/c space group alteration.The differential scanning calorimetry (DSC; Figure 4) and powder X-ray diffraction (PXRD; Figure 5) of 25MeBPBN clarified that α-25MeBPBN underwent a structural phase transition at 353 K, and β-25MeBPBN irreversibly appeared.The DSC profile of α-25MeBPBN showed two endothermic peaks at 353 and 387 K, whereas that of β-25MeBPBN only one endothermic peak at 387 K.The high-temperature peak is related with the mp.A huge exothermic signal appeared just above the mp, probably ascribable to chemical degradation.The additional peak at 353 K found in α-25MeBPBN is ascribable to a solid-state/solid-state phase transition.The PXRD profile was drastically changed across the transition (Figure 5, bottom and middle).The major PXRD reflections of the high-temperature phase were practically identical to those of the β-25MeBPBN prepared separately (Figure 5, top).A trace of the α-phase was found to remain in the annealed specimen.This finding is entirely consistent with the magnetic study (see below).The α-Ñβ-phase transition was found to be irreversible, as confirmed with the cooling process in the magnetic measurements and DSC analysis.The present observation is similar to that of BPBN [6].The mother BPBN compound showed the dia-/paramagnetic phase transition accompanied by the P1-C2/c space group alteration.From comparison of the molecular structures of the diamagnetic chains with isolated paramagnetic biradicals [6,[9][10][11] and monoradicals [22][23][24][25] previously investigated, the most striking difference is the degree of the nitrogen configuration (hybridization).The nitrogen atoms in polymers display a distinct pyramid because of the tetravalent character (Figure 2), whereas the paramagnetic molecule usually possesses an sp 2 -hybridized planar structure.This finding may imply that the former would have a reduced intramolecular coupling usually accounted for in terms of prohibited π-conjugation.In short, the intermolecular antiferromagnetic coupling interferes with intramolecular ferromagnetic coupling.

Magnetic Properties
The magnetic susceptibilities of polycrystalline specimens were measured on a Quantum Design SQUID magnetometer (MPMS-XL7).The χmT value of practically null below 350 K for α-25MeBPBN implies the absence of any spin (Figure 6a).In 350-360 K, the χmT value showed an abrupt jump on heating and reached 0.95 cm 3 •K•mol −1 at 363 K, which is close to the theoretical triplet value (1.00 cm 3 K•mol −1 ) and not to the one expected from twice S = 1/2 paramagnetic species (0.75 cm 3 K mol −1 ).The present χm(T) experiment clearly indicates that 25MeBPBN can afford room-temperature triplet material, owing to the intramolecular exchange coupling of the order of >300 K.The spin-polarization mechanism [1][2][3] is operative, as often verified by m-phenylene-bridged biradicals [4,5].A successive measurement on lowering temperature exhibited a gradual χmT decrease, which can be assigned to   From comparison of the molecular structures of the diamagnetic chains with isolated paramagnetic biradicals [6,[9][10][11] and monoradicals [22][23][24][25] previously investigated, the most striking difference is the degree of the nitrogen configuration (hybridization).The nitrogen atoms in polymers display a distinct pyramid because of the tetravalent character (Figure 2), whereas the paramagnetic molecule usually possesses an sp 2 -hybridized planar structure.This finding may imply that the former would have a reduced intramolecular coupling usually accounted for in terms of prohibited π-conjugation.In short, the intermolecular antiferromagnetic coupling interferes with intramolecular ferromagnetic coupling.

Magnetic Properties
The magnetic susceptibilities of polycrystalline specimens were measured on a Quantum Design SQUID magnetometer (MPMS-XL7).The χmT value of practically null below 350 K for α-25MeBPBN implies the absence of any spin (Figure 6a).In 350-360 K, the χmT value showed an abrupt jump on heating and reached 0.95 cm 3 •K•mol −1 at 363 K, which is close to the theoretical triplet value (1.00 cm 3 K•mol −1 ) and not to the one expected from twice S = 1/2 paramagnetic species (0.75 cm 3 K mol −1 ).The present χm(T) experiment clearly indicates that 25MeBPBN can afford room-temperature triplet material, owing to the intramolecular exchange coupling of the order of >300 K.The spin-polarization mechanism [1][2][3] is operative, as often verified by m-phenylene-bridged biradicals [4,5].A successive measurement on lowering temperature exhibited a gradual χmT decrease, which can be assigned to From comparison of the molecular structures of the diamagnetic chains with isolated paramagnetic biradicals [6,[9][10][11] and monoradicals [22][23][24][25] previously investigated, the most striking difference is the degree of the nitrogen configuration (hybridization).The nitrogen atoms in polymers display a distinct pyramid because of the tetravalent character (Figure 2), whereas the paramagnetic molecule usually possesses an sp 2 -hybridized planar structure.This finding may imply that the former would have a reduced intramolecular coupling usually accounted for in terms of prohibited π-conjugation.In short, the intermolecular antiferromagnetic coupling interferes with intramolecular ferromagnetic coupling.

Magnetic Properties
The magnetic susceptibilities of polycrystalline specimens were measured on a Quantum Design SQUID magnetometer (MPMS-XL7).The χ m T value of practically null below 350 K for α-25MeBPBN implies the absence of any spin (Figure 6a).In 350-360 K, the χ m T value showed an abrupt jump on heating and reached 0.95 cm 3 ¨K¨mol ´1 at 363 K, which is close to the theoretical triplet value (1.00 cm 3 K¨mol ´1) and not to the one expected from twice S = 1/2 paramagnetic species (0.75 cm 3 K mol ´1).The present χ m (T) experiment clearly indicates that 25MeBPBN can afford room-temperature triplet material, owing to the intramolecular exchange coupling of the order of >300 K.The spin-polarization mechanism [1][2][3] is operative, as often verified by m-phenylene-bridged biradicals [4,5].A successive measurement on lowering temperature exhibited a gradual χ m T decrease, which can be assigned to an intermolecular antiferromagnetic interaction.The present thermal spin transition at ca. 360 K was found to be irreversible, as revealed from repeated measurements.Figure 6b displays the magnetic susceptibility result on β-MeBPBN prepared separately.The χ m T value of 1.0 cm 3 K mol ´1 at 300 K implies that almost the whole population belongs to the low-lying triplet state, in good agreement with the crystallographic analysis (Figure 3).This χ m T(T) profile approximately traced that of annealed α-25MeBPBN (Figure 6a).As described above in the PXRD experiments, annealed α-25MeBPBN was found to be identical to β-25MeBPBN.Thus, we can conclude the one-way phase transition in polymorphic 25MeBPBN.
Crystals 2016, 6, 30 6 of 9 an intermolecular antiferromagnetic interaction.The present thermal spin transition at ca. 360 K was found to be irreversible, as revealed from repeated measurements.Figure 6b displays the magnetic susceptibility result on β-MeBPBN prepared separately.The χmT value of 1.0 cm 3 K mol −1 at 300 K implies that almost the whole population belongs to the lowlying triplet state, in good agreement with the crystallographic analysis (Figure 3).This χmT(T) profile approximately traced that of annealed α-25MeBPBN (Figure 6a).As described above in the PXRD experiments, annealed α-25MeBPBN was found to be identical to β-25MeBPBN.Thus, we can conclude the one-way phase transition in polymorphic 25MeBPBN.Figure 7 shows the results of 2F5Me-and 5F2MeBPBN, and diamagnetism was recorded below 340 and 350 K, respectively, just like α-25MeBPBN.This finding is consistent with the molecular and crystal structure analysis (Figures 1 and 2).The intermolecular close contact of the nitroxide groups serves as a diamagnetic unit.On heating, appreciable magnetic susceptibility suddenly emerged for both compounds, and the transition was found to be irreversible.The mp's of 2F5Me-and 5F2MeBPBN were 347 and 361 K, respectively, and the melting is supposed to cause the paramagnetism.It is reasonable to infer that weak covalent bonds between the nitroxide groups would cleave into two radicals in the liquid phase.
The χmT values at the end of the transition reached somewhere below 1.0 cm 3 K mol −1 (Figure 7) depending on the experimental conditions such as heating rate.A considerable χmT drop was observed when the specimen was kept in the melt.This behavior was confirmed for 2F5Me-and 5F2MeBPBN by means of ESR spectroscopy.A variable-temperature ESR technique was applied to the solid specimens, and the biradical signals were found to decrease while being allowed to stand above the mp (Figure 8 for 5F2MeBPBN).These findings indicate that the melted 2F5Me-and 5F2MeBPBN were chemically decomposed under such thermal conditions.The m-phenylene-bridged bisnitroxides are known to thermally change into isomeric diamagnetic compounds, aminoquinone imine N-oxide derivatives [6,10,26,27].
In contrast, all the BPBN biradical species in the solid phase were persistent enough.In the present study, the χmT value of the annealed α-25MeBPBN indicates negligible decomposition.This finding is compatible with the notion that 25MeBPBN undergoes the spin transition entirely in the solid phase.
We found the solid-state/solid-state structural phase transition only in 25MeBPBN.The transition temperature was 83 °C in a melting point apparatus (87 °C in SQUID and 80 °C in DSC), which is considerably lower than the mp (109 °C for the β-phase).Application in electronics and devices may welcome a solid-state structural phase transition taking place near room temperature.The fluoro group is smaller and more electronegative than the methyl group, and the substitution of Me with F may lead to increase the intermolecular contact, which is supported by the density (Table 1).Such contacts assist the cooperativity [8,12], but unfortunately in the present case the reduction of the void space may be unfavorable for the substituent motion.Consequently, no solidsate phase transition is realized before the melting for 2F5Me-and 5F2MeBPBN.Figure 7 shows the results of 2F5Me-and 5F2MeBPBN, and diamagnetism was recorded below 340 and 350 K, respectively, just like α-25MeBPBN.This finding is consistent with the molecular and crystal structure analysis (Figures 1 and 2).The intermolecular close contact of the nitroxide groups serves as a diamagnetic unit.On heating, appreciable magnetic susceptibility suddenly emerged for both compounds, and the transition was found to be irreversible.The mp's of 2F5Me-and 5F2MeBPBN were 347 and 361 K, respectively, and the melting is supposed to cause the paramagnetism.It is reasonable to infer that weak covalent bonds between the nitroxide groups would cleave into two radicals in the liquid phase.
The χ m T values at the end of the transition reached somewhere below 1.0 cm 3 K mol ´1 (Figure 7) depending on the experimental conditions such as heating rate.A considerable χ m T drop was observed when the specimen was kept in the melt.This behavior was confirmed for 2F5Me-and 5F2MeBPBN by means of ESR spectroscopy.A variable-temperature ESR technique was applied to the solid specimens, and the biradical signals were found to decrease while being allowed to stand above the mp (Figure 8 for 5F2MeBPBN).These findings indicate that the melted 2F5Me-and 5F2MeBPBN were chemically decomposed under such thermal conditions.The m-phenylene-bridged bisnitroxides are known to thermally change into isomeric diamagnetic compounds, aminoquinone imine N-oxide derivatives [6,10,26,27].
In contrast, all the BPBN biradical species in the solid phase were persistent enough.In the present study, the χ m T value of the annealed α-25MeBPBN indicates negligible decomposition.This finding is compatible with the notion that 25MeBPBN undergoes the spin transition entirely in the solid phase.
We found the solid-state/solid-state structural phase transition only in 25MeBPBN.The transition temperature was 83 ˝C in a melting point apparatus (87 ˝C in SQUID and 80 ˝C in DSC), which is considerably lower than the mp (109 ˝C for the β-phase).Application in electronics and devices may welcome a solid-state structural phase transition taking place near room temperature.The fluoro group is smaller and more electronegative than the methyl group, and the substitution of Me with F may lead to increase the intermolecular contact, which is supported by the density (Table 1).Such contacts assist the cooperativity [8,12], but unfortunately in the present case the reduction of the void space may be unfavorable for the substituent motion.Consequently, no solid-sate phase transition is realized before the melting for 2F5Me-and 5F2MeBPBN.

Crystallographic Analysis
X-Ray diffraction data were collected on a Saturn70 CCD diffractometer (Rigaku, Tokyo, Japan) with graphite monochromated Mo Kα radiation (λ = 0.71073 Å).The structures were directly solved by a heavy-atom method and expanded using Fourier techniques in the CRYSTALSTRUCTURE [28].Numerical absorption correction was used.The thermal displacement parameters of non-hydrogen

Crystallographic Analysis
X-Ray diffraction data were collected on a Saturn70 CCD diffractometer (Rigaku, Tokyo, Japan) with graphite monochromated Mo Kα radiation (λ = 0.71073 Å).The structures were directly solved by a heavy-atom method and expanded using Fourier techniques in the CRYSTALSTRUCTURE [28].Numerical absorption correction was used.The thermal displacement parameters of non-hydrogen

Physical Property Measurements
Magnetic susceptibilities were measured on an MPMS-XL7 SQUID (Quantum Design, San Diego, CA, USA) magnetometer with a static field of 0.5 T. The magnetic responses were corrected with diamagnetic blank data of the sample holder measured separately.The diamagnetic contribution of the sample itself was estimated from Pascal's constants [29].The electron spin resonance (ESR) spectra were recorded on an ELEXYS ESR spectrometer (Bruker, Billerica, MA, USA) with an X-band gun oscillator.A diluted toluene solution or polycrystalline solid of the specimen was degassed before measurements.The differential scanning calorimetry (DSC) of 25FBPBN was performed on a Rigaku Thermo Plus DSC 8230 (Rigaku, Tokyo, Japan).The heating rate was 1 deg/min.

Conclusions
The magnetic susceptibility measurements of new biradicals 25MeBPBN, 2F5MeBPBN, and 2Me5FBPBN practically showed diamagnetism below room temperature.The radical dimerization occurs on both sides of the biradical, thus leading to polymerization.All three showed thermally activated paramagnetism due to the degradation, but only 25MeBPBN underwent a solid-state structural phase transition before the melting.Electronics-oriented applications may welcome a solid-state structural phase transition taking place near room temperature.For example, the present biradicals underwent one-way thermally activated transition, being regarded as a potential candidate for write-once media in information storage devices.Crystal engineering approaches are important to control weak intermolecular interaction, acquire a void space in the crystal, and tune the phase transition phenomena.

aFigure 1 .Figure 1 .
Figure 1.Molecular structure (top) and molecular arrangement (bottom) in the crystals of (a) α-25Me, (b) 2F5Me-, and (c) 5F2MeBPBN.Selected atomic numbering is also shown.Hydrogen atoms are omitted in the bottom panels.Short contacts are denoted with dotted lines.

Figure 2 .
Figure 2. Schematic drawing of the chain involving intermolecular N•••O bonds.

Figure 3 .
Figure 3. (a) Molecular structure and (b) molecular arrangement in the crystals of β-25MeBPBN.Selected atomic numbering is also shown.Hydrogen atoms are omitted in (b).

Figure 2 . 9 Figure 2 .
Figure 2. Schematic drawing of the chain involving intermolecular N¨¨¨O bonds.

Figure 3 .
Figure 3. (a) Molecular structure and (b) molecular arrangement in the crystals of β-25MeBPBN.Selected atomic numbering is also shown.Hydrogen atoms are omitted in (b).

Figure 3 .
Figure 3. (a) Molecular structure and (b) molecular arrangement in the crystals of β-25MeBPBN.Selected atomic numbering is also shown.Hydrogen atoms are omitted in (b).

Figure 6 .
Figure 6.Temperature dependence of χmT measured at 5000 Oe for (a) α-25MeBPBN on heating and then cooling and (b) β-25MeBPBN on heating.

Figure 6 .
Figure 6.Temperature dependence of χ m T measured at 5000 Oe for (a) α-25MeBPBN on heating and then cooling and (b) β-25MeBPBN on heating.

Figure 7 .
Figure 7. Temperature dependence of χmT for (a) 2F5Me-and (b) 5F2MeBPBN, measured at 5000 Oe on heating from 2 to 350 and 360 K, respectively.Dotted lines are shown for a guide to the eye.

Figure 8 .
Figure 8. ESR spectra of 5F2MeBPBN, measured in the following sequence: (1) a solid state at 300 K, (2) a liquid state after being kept at 375 K for 10 min and (3) at the same temperature after 30 min.

Figure 7 .Figure 7 .
Figure 7. Temperature dependence of χ m T for (a) 2F5Me-and (b) 5F2MeBPBN, measured at 5000 Oe on heating from 2 to 350 and 360 K, respectively.Dotted lines are shown for a guide to the eye.

Figure 8 .
Figure 8. ESR spectra of 5F2MeBPBN, measured in the following sequence: (1) a solid state at 300 K, (2) a liquid state after being kept at 375 K for 10 min and (3) at the same temperature after 30 min.

Figure 8 .
Figure 8. ESR spectra of 5F2MeBPBN, measured in the following sequence: (1) a solid state at 300 K, (2) a liquid state after being kept at 375 K for 10 min and (3) at the same temperature after 30 min.

Table 1 .
Selected crystallographic data for BPBN derivatives.