Color-Causing Mechanisms of Guatemala Jadeite Jade: Constraints from Spectroscopy and Chemical Compositions

: The jadeite jade in Guatemala exerts remarkable commercial quality, which has attracted wide attention. Guatemalan jadeite jade displays a rich variety of colors; however, the color formation of this jadeite jade has not been systematically investigated to date. In this paper, we study different colors of jade samples to trace the compositions and color-causing mechanisms through petrography, X-ray ﬂuorescence spectroscopy (XRF), Fourier transform infrared spectroscopy (FTIR), laser Raman spectroscopy (LRS), and UV-visible absorption spectroscopy (UV-Vis), as well as electron probe microanalysis (EPMA). The results show that jadeite and omphacite are the main mineral compositions of Guatemalan jadeite jade, together with minor albite and other impurities. The color of Guatemala jadeite jade is mainly related to Cr 3+ , Fe 2+ , and Fe 3+ , of which a small amount of Cr 3+ causes the jadeite jade to be emerald green. Moreover, 1~2% FeO contents can lead to the blue or gray color of the samples, while the Fe 3+ makes the sample dark green. The green color of some Cr 3+ -free jadeite is caused by the electron transition between bands of Fe 3+ , and the green color is related to the iron content. Moreover, the chemical composition analysis shows that some metallic elements existed in Guatemalan jadeite jade, such as Ca, Ti, Al, Si, Ni, Fe, Mn, Cr, Na, Mg, and Sr, and some trace elements were lost or unevenly distributed, which may lead to the heterogeneity of the color of the samples. Our present investigation provides insights into color discrimination, quality evaluation, and identiﬁcation of Guatemala jadeite jade.


Introduction
Guatemala jadeite jade, composed of jadeite and minor omphacite, is rich in color, and there are green, blue-green, gray, black and other types.The mining area can also generate the "Guatemala imperial jade" with the best quality and highest value [1,2], which shows a brilliant green color.The blue-green variety called Type II by Foshag is commercially termed as "Olmec Blue" and presents a distinct blue hue, translucence, and attractive blue color under transmitted light [2].The color of jadeite jade is influenced by its main constituent minerals, the types and contents of trace elements in jadeite or diopside, as well as secondary minerals.Thus, the color of jadeite jade has a close relationship with the geological or tectonic evolution of its formation.According to the different formation processes, it can be divided into two categories of primary and secondary colors.After the formation of jade, the secondary color is generally caused by the infiltration of externalcolored minerals such as hematite, limonite, and clay minerals, distributed in the surface and near the surface [3].The primary color is caused by chromic ions during the formation

Geological Background
The Guatemala jadeite jade deposit occurs in the North America-Caribbean plate collision zone in southern North America (Figure 1).The Guatemala Suture zone, also called the Guatemala Central fault zone, separates the Maya Plate from the Caribbean Plate [13,14].High pressure and low temperature (HPLT) metamorphism exists on both the north and south sides of the Motagua fault zone.However, the compositions of orebodies on both sides show distinct characteristics.In the southern orebodies, there is a large amount of jadeitite, eclogite, glaucophane-eclogite, glaucophane schist, and other HPLT rock minerals, which act as crystalline and metasomatism-type jadeite jade deposits, formed during the late Jurassic period at 154 Ma.Meanwhile, the northern orebodies contain a large amount of jadeitite, albite, garnet-clinozoisite amphibolite, or clinozoisite eclogite, which is a crystalline jadeite deposit, formed during the late Cretaceous period at 98-95 Ma.HPLTeclogite, garnet amphibolite, and jadeite in the central Motagwa River Valley rock masses can be found [15,16], while the commercial exploitation value of Guatemalan jadeite jade is mostly discovered in the Mesozoic tectonic serpentinite rock mass along the Motagwa fault zone [17,18].shows that Guatemala jadeite jade deposits are located between the Maya Block and Chortis Block (modified after Harlow et al. [16]).
The Guatemala jadeite jade is usually generated in serpentinite bodies in lenticular or veined shapes, and some exist as single structural inclusions.Jadeitite is commonly associated with albite.Albitites are formed at a lower pressure at the expense of jadeitite, and some albite-mica rocks could have formed at pressures comparable to jadeite and yet others formed at lower pressure conditions [19,20].In addition, the enrichment layers of jade also exist in the alluvium and riverbed terraces of the Motagua River, with gravels up to 1 m in diameter.The jadeite jade formation temperature is <400 °C, while the pressure is between 0.5 and 1.1 GPa [21].
Guatemala jadeite jade ores commonly show green, purple, blue, and black characteristics, occasionally presenting a brilliant green color, and its transparency is translucent to slightly transparent and partially opaque.The mineral compositions are dominated by jadeite, omphacite, mica, and hedenbergite, with medium to refined grains and uniform and dense textures.

Sampling
Based on the jade color and transparency classification standard, about 20 raw stone samples were screened for analysis, from which six different colors of light green, dark green, black-green, blue-green, gray-green, and black samples were selected for fine polishing (Figure 2).Basic gemological properties, such as refractive index (RI) and specific gravity (SG), are measured three times per sample to determine the range of parameters.The internal textural characteristics of the samples are then observed under a gemstone microscope (Figure 3), and polished thin sections were prepared for petrographic studies.Then, the FTIR, Raman spectroscopy, and UV-Vis were performed at different positions of the samples; the spectrogram was analyzed, and the trace elements were roughly judged in combination with XRF measurements.Finally, EPMA was used to determine the content of the main elements in the samples, and the main formation mechanisms for the different colors were analyzed comprehensively.
The first group of samples showed different green tones, which were labeled as GN-1 (light green), GN-2 (dark green), and GN-3 (black-green); while the second group of samples, with other green tones, was marked with BU-1 (blue-green), BU-2 (gray-green), and BU-3 (black).All of the samples show glassy luster with uneven color distribution.The Guatemala jadeite jade is usually generated in serpentinite bodies in lenticular or veined shapes, and some exist as single structural inclusions.Jadeitite is commonly associated with albite.Albitites are formed at a lower pressure at the expense of jadeitite, and some albite-mica rocks could have formed at pressures comparable to jadeite and yet others formed at lower pressure conditions [19,20].In addition, the enrichment layers of jade also exist in the alluvium and riverbed terraces of the Motagua River, with gravels up to 1 m in diameter.The jadeite jade formation temperature is <400 • C, while the pressure is between 0.5 and 1.1 GPa [21].
Guatemala jadeite jade ores commonly show green, purple, blue, and black characteristics, occasionally presenting a brilliant green color, and its transparency is translucent to slightly transparent and partially opaque.The mineral compositions are dominated by jadeite, omphacite, mica, and hedenbergite, with medium to refined grains and uniform and dense textures.

Sampling
Based on the jade color and transparency classification standard, about 20 raw stone samples were screened for analysis, from which six different colors of light green, dark green, black-green, blue-green, gray-green, and black samples were selected for fine polishing (Figure 2).Basic gemological properties, such as refractive index (RI) and specific gravity (SG), are measured three times per sample to determine the range of parameters.The internal textural characteristics of the samples are then observed under a gemstone microscope (Figure 3), and polished thin sections were prepared for petrographic studies.Then, the FTIR, Raman spectroscopy, and UV-Vis were performed at different positions of the samples; the spectrogram was analyzed, and the trace elements were roughly judged in combination with XRF measurements.Finally, EPMA was used to determine the content of the main elements in the samples, and the main formation mechanisms for the different colors were analyzed comprehensively.
The GN-1 sample shows weathered yellow skin, while the GN-3 sample exhi ous irregular white spots visible to the naked eye.The interior of the BU-1 samp a blue-green color under transmission light, and the interior of the BU-3 samp abundant black particles (Figure 2).The first group of samples showed different green tones, which were labeled as GN-1 (light green), GN-2 (dark green), and GN-3 (black-green); while the second group of samples, with other green tones, was marked with BU-1 (blue-green), BU-2 (gray-green), and BU-3 (black).All of the samples show glassy luster with uneven color distribution.The GN-1 sample shows weathered yellow skin, while the GN-3 sample exhibits numerous irregular white spots visible to the naked eye.The interior of the BU-1 sample presents a blue-green color under transmission light, and the interior of the BU-3 sample exists in abundant black particles (Figure 2).
The refractive indexes of the samples measured by using a well-polished plane are 1.665-1.672,and the refractive index by point measurement was 1.66, indicating the approximate parameters.The specific gravity of the samples measured by the hydrostatic method is in the range of 3.26-3.43.The absorption line of 437 nm was observed under spectroscope.The samples show inert characteristics under ultraviolet fluorescence.The Mohs hardness is about 7.

Fourier Transform Infrared Spectroscopy (FTIR)
The representative samples were tested using TENSOR27 FTIR (BRUKER OPTIC Ettlingen, Germany) at the Chinese Academy of Metrology.Test conditions: resolution cm −1 ; time: 100 ms.Collect multiple scans to improve accuracy.

Laser Raman Spectroscopy
Raman spectroscopy of representative samples was performed at the National Je elry Quality Supervision and Inspection Center using a Dual-100 (Jiangsu Tianrui Instr ment Co., LTD, Suzhou, China).The wavelength used is 532 nm, and the instrument set allows a spectral resolution of 4 cm −1 .We used a scanning time of 10 s of spectrum in extending mode spanning 100~4000 cm −1 with a grating of 1800 gr mm −1 , about 1 cm resolution, and a 50× lens.

UV-Visible Spectroscopy (UV-Vis)
UV-Vis of representative samples was performed at the National Jewelry Quality S pervision and Inspection Center using a Gem UV-100 instrument (Jiangsu Tianrui Instr ment Co., LTD, Suzhou, China).Analytical conditions: integration time: 100 ms; collecti cycle: 8 times.The test condition uses reflection, and a test range of 200-1000 nm.

X-ray Fluorescence Spectroscopy (XRF)
XRF was performed at Chengdu Avenue Benzhen Jewelry Testing Center using EDS880 instrument (Chengli Bochuang Technology Chengdu Co., LTD, Chengdu, Chin Test conditions: element range: Na~U; resolution: 145 eV; current: 600 mA; voltage: 200 Each sample is tested three times at different positions on the polished surface to impro accuracy. 3.2.5.Electronic Probe Micro-Analysis (EPMA)

Fourier Transform Infrared Spectroscopy (FTIR)
The representative samples were tested using TENSOR27 FTIR (BRUKER OPTICS, Ettlingen, Germany) at the Chinese Academy of Metrology.Test conditions: resolution: 4 cm −1 ; time: 100 ms.Collect multiple scans to improve accuracy.

Laser Raman Spectroscopy
Raman spectroscopy of representative samples was performed at the National Jewelry Quality Supervision and Inspection Center using a Dual-100 (Jiangsu Tianrui Instrument Co., Ltd., Suzhou, China).The wavelength used is 532 nm, and the instrument setup allows a spectral resolution of 4 cm −1 .We used a scanning time of 10 s of spectrum in an extending mode spanning 100~4000 cm −1 with a grating of 1800 gr mm −1 , about 1 cm −1 resolution, and a 50× lens.

UV-Visible Spectroscopy (UV-Vis)
UV-Vis of representative samples was performed at the National Jewelry Quality Supervision and Inspection Center using a Gem UV-100 instrument (Jiangsu Tianrui Instrument Co., Ltd., Suzhou, China).Analytical conditions: integration time: 100 ms; collection cycle: 8 times.The test condition uses reflection, and a test range of 200-1000 nm.

X-ray Fluorescence Spectroscopy (XRF)
XRF was performed at Chengdu Avenue Benzhen Jewelry Testing Center using an EDS880 instrument (Chengli Bochuang Technology Chengdu Co., Ltd., Chengdu, China).Test conditions: element range: Na~U; resolution: 145 eV; current: 600 mA; voltage: 200 V.Each sample is tested three times at different positions on the polished surface to improve accuracy.The electron microprobe analyses (EPMA) and backscattered electron (BSE) and surface scanning of the samples were performed at Wuhan Upspectrum Analysis Technology Laboratory using a JEOL JXA-8230 microprobe (Nippon Electronics, Tokyo, Japan) with an accelerating voltage of 15 kV, beam current 2 × 10 −8 A, and beam spot diameter 3 µm.The data collection time is 20-60 s.The ZAF method was used to correct the data, and the analysis accuracy was less than 1%.Wavelength dispersive spectroscopy (WDS) analyzed the chemical compositions of different samples.Testing standards: calcite (Ca), rutile (Ti), corundum (Al), quartz (Si), nickelic (Ni) oxide, hematite (Fe), huebnerite (Mn), chromium oxide (Cr), jadeite (Na), forsterite (Mg), and potassium feldspar (K).

Petrographic Analysis
The petrography study shows that the main mineral in jadeite jade with black color is jadeite, accounting for more than 90%, while the secondary mineral is omphacite, with a content of ~5%.The mineral intergranular space is filled with Fe-oxides and opaque metal minerals with a content of ~1%.The mineral grains generally exhibit semi-idiomorphic columnar to xenomorphic granular textures with particle sizes of 0.1~3 mm, and 0.5~5 mm, respectively (Figure 4a).There are apparent reaction boundaries, ductile deformation, and cataclastic structures among the minerals, indicating that they were formed by dynamic metamorphism under certain P/T conditions.The omphacite mostly replaced early jadeite along jadeite fractures or grain edges or crystallized among jadeite grains, suggesting that jadeite crystallized earlier than omphacite [21,22].The late omphacite and early jadeite may be transformed by dynamic metamorphism and undergo ductile deformation, thus recrystallizing, while the late crystalline veins are mainly composed of purest jadeite.The black inclusions and fissures in Guatemala jadeite jade increase the gap between jadeite particles and enhance light refraction and diffuse reflection.In addition, there are many defects and dark inclusions inside the jade, which change the transparency, affecting the color depth of the jade (Figure 4b).Some samples show microblastic and parallel fibrous textures.Other samples show porphyrioblastic textures.Both of the samples suggest that the main mineral is jadeite, accounting for more than 90%, which presents II blue color under the orthogonal polarizer (Figure 4c,d).

FTIR Analysis
Due to the absorbed peaks of omphacite and jadeite being quite similar, the peaks of GN-1, GN-2, BU-2, and BU-3 samples present slightly different characteristics (Figure 5).The samples were identified by discriminating the significant absorption peaks of jadeite's "five finger peaks", 1169 cm −1 , 1078 cm −1 , 937 cm −1 , 597 cm −1 , and 517 cm −1 , respectively [22][23][24].The results show that the peaks of GN-1 and GN-2 samples are consistent with jadeite.Moreover, according to the infrared-absorption peaks of the jade sample >658.7,>574.5, >422.5 cm −1 , the Na/Na + Ca ratio of the jade sample is higher than 0.8, jointly revealing that the main mineral of the samples is jadeite.Otherwise, it is omphacite [22,23].The typical indication is that the main mineral composition of the sample is jadeite.
FTIR was performed with the reflection mode.The infrared beam illuminates the sample on the bench [24], and the detector collects the scattered light to obtain spectra by the correlation vibration of Si-O and M-O, and the absorption peaks in the range of 1100-800 cm −1 are attributed to Si-O b -Si asymmetric stretching vibration and O t -Si-O t symmetrical stretching vibration, respectively [23].The absorption peaks located at 600-400 cm −1 belong to the Si-O bending vibration and M-O stretching vibration, respectively (Table 1).The GN-3 and BU-1 samples are dominantly composed of omphacite, indicating the main mineral compositions of Guatemala jadeite jade are jadeite and omphacite instead of single components [24].
tween jadeite particles and enhance light refraction and diffuse reflection.In addit there are many defects and dark inclusions inside the jade, which change the trans ency, affecting the color depth of the jade (Figure 4b).Some samples show microbla and parallel fibrous textures.Other samples show porphyrioblastic textures.Both of samples suggest that the main mineral is jadeite, accounting for more than 90%, w presents II blue color under the orthogonal polarizer (Figure 4c,d).
"five finger peaks," 1169 cm −1 , 1078 cm −1 , 937 cm −1 , 597 cm −1 , and 517 cm −1 , respectively [22][23][24].The results show that the peaks of GN-1 and GN-2 samples are consistent with jadeite.Moreover, according to the infrared-absorption peaks of the jade sample >658.7,>574.5, >422.5 cm −1 , the Na/Na + Ca ratio of the jade sample is higher than 0.8, jointly revealing that the main mineral of the samples is jadeite.Otherwise, it is omphacite [22,23].The typical indication is that the main mineral composition of the sample is jadeite.The sample BU-1 presents peaks at 1025 cm −1 , 689 cm −1 , and 358 cm −1 , which are typical peaks of omphacite minerals, while no double peaks were detected near 1000 cm −1 with only a single peak discovered at 1025 cm −1 , indicating that the transformation of jadeite into omphacite is relatively complete (Figure 7).The shape of the peaks shows that the sample BU-1 exhibits smooth structures, while the Dark green spot shows sharp characteristics, indicating that the crystallinity of the latter is higher.Moreover, the ~680 cm −1 peak could be used to identify jadeite and omphacite, revealing compositional variations of the jadeite-omphacite solid solution [24].The results show the spectra shift toward omphacite for some analyzed spots (Figure 7), indicating that the composition of the solid solution shifts toward omphacite.It is inferred that the blue-water jadeite becomes darker with the increase in omphacite content [24,25].The sample BU-1 presents peaks at 1025 cm −1 , 689 cm −1 , and 358 cm −1 , which are typical peaks of omphacite minerals, while no double peaks were detected near 1000 cm −1 with only a single peak discovered at 1025 cm −1 , indicating that the transformation of jadeite into omphacite is relatively complete (Figure 7).The shape of the peaks shows that the sample BU-1 exhibits smooth structures, while the Dark green spot shows sharp characteristics, indicating that the crystallinity of the latter is higher.Moreover, the ~680 cm −1 peak could be used to identify jadeite and omphacite, revealing compositional variations of the jadeite-omphacite solid solution [24].The results show the spectra shift toward omphacite for some analyzed spots (Figure 7), indicating that the composition of the solid solution shifts toward omphacite.It is inferred that the blue-water jadeite becomes darker with the increase in omphacite content [24,25].In the range of 1200-800 cm −1 , the peak assigned by the Si-O symmetric stretching vibration band is 1025 cm −1 .In the range of 800-400 cm −1 , the peaks that satisfy the symmetric bending vibration band assignment of Si-Ob-Si are 689 cm −1 and 685 cm −1 .(Table 3).
In addition, the white spot of the GN-3 sample shows that the main peaks are located at 1103 cm −1 , 1032 cm −1 , 819 cm −1 , 772 cm −1 , 685 cm −1 , 513 cm −1 , 485 cm −1 , 337 cm −1 , and 300 cm −1 , suggesting albite mineral (Figure 6).The peaks at 513 cm −1 , 485 cm −1 , and 330 cm −1 are relatively sharp, indicating albite with a good degree of crystallization.According to the FTIR analysis, the main constituent mineral of the GN-3 substrate is omphacite; so, it can be further inferred that the sample contains a large amount of omphacite and minor albite.In the range of 1200-800 cm −1 , the peak assigned by the Si-O symmetric stretchi vibration band is 1025 cm −1 .In the range of 800-400 cm −1 , the peaks that satisfy the sym metric bending vibration band assignment of Si-Ob-Si are 689 cm −1 and 685 cm −1 .(Tab 3).In addition, the white spot of the GN-3 sample shows that the main peaks are locat at 1103 cm −1 , 1032 cm −1 , 819 cm −1 , 772 cm −1 , 685 cm −1 , 513 cm −1 , 485 cm −1 , 337 cm −1 , and 3 In the range of 1200-800 cm −1 , the peaks assigned by the jadeite peak and the peaks assigned by the Si-O symmetric stretching vibration band are 1032 cm −1 , and the peaks assigned by the albite peak are 1103 cm −1 and 819 cm −1 .In the range of 800-700 cm −1 , the peak position of the albite peak satisfying the assignment of the AL-O symmetric stretching vibration band is 772 cm −1 , and in the range of 700-400 cm −1 .The peak locations of albite satisfying the O t -Si-O t bending vibration band assignment are 685 cm −1 , 513 cm −1 , and 485 cm −1 .In the 400-10 cm −1 range, the albite peak position meeting the M-O stretching vibration band assignment is 337 cm −1 and 300 cm −1 , which belong to the vibration spectrum of chain silicate (Table 4).

UV-Vis Analysis
The results show that all samples exhibit an absorption peak near 436 nm in the purple zone (Figure 8).In jadeite, the iron commonly replaces Al 3+ with Fe 3 (Fe 2+ is only minor in jadeite), and the absorption peaks at 437 and 380 nm can be attributed to the d-d electronic transition of Fe 3+ in the octahedral field [26].The intensity of the 437 nm absorption peak indicates the amount of Fe 3+ in the jadeite jade [27,28].In contrast, iron usually exists as Fe 2+ in omphacite due to charge-balanced coupled substitution [25].The weakest absorption peak of the sample GN-1 is located at 436 nm, and the peak shape shows smooth or imperceptible features.The absorption peak of GN-3 is the strongest, and the peak shape is sharp, indicating that the Fe content significantly impacts color.In contrast, the absorption peaks of 630 nm, 660 nm, and 692 nm related to Cr were not detected [24,25].Therefore, it is inferred that the green color of jadeite jade samples GN-1, GN-2, BU-2, and BU-3 presents no relation to Cr 3+ , while its color is determined to be related to Fe 3+ [26], resulting from the interband electronic transition of Fe 3+ .Based on the previous conclusion that the change of FeO contents is proportional to transparency and blue purity [27], the blue-green BU-1 sample is slightly transparent, meeting the FeO content of 1 wt.%-2 wt.%, and the amount of Cr is low, which jointly leads to its green color being grayish or bluish [28].It was confirmed that the color blue-green was related to the contents of Cr 3+ and Fe 2+ .Overall, UV-Vis analysis indicates no Cr absorption peak in gray-green jade but contains a Fe absorption peak, which indicates no Cr or negligible Cr content.Because the jade shows a gray tone, it suggests that Fe exists in the form of Fe 2+ .

XRF Analysis
The critical chemical elements were analyzed as a supplement to the color origin content.The chemical elements' analysis results in this study are presented in Table 5.The dark/mottled green pyroxenic jadeites from Guatemala are composed of jadeite and omphacite, and µ-XRF elemental maps of the omphacite show elevated Ca-Mg-Fe contents [29].The contents of Fe in samples GN-2, GN-3, and BU-2 exhibit relatively high characteristics in the range of 54.58%, 57.98%, and 60.34%, respectively, indicating that it may be the factor leading to the green color deepening of jade.Among them, the contents of Sr show widely variational characteristics, with the highest content reaching 30.85% (Table 5).The presence of accessory minerals may indicate the involvement of hydrothermal activities during mineralization.The inhomogeneous distribution of Sr in the Guatemala jadeite jade suggests enrichment or depletion during the mineralization processes [28].The Guatemala jadeite jades contain about 10-12% diopside [28,29].Notably, the BU-3 sample appears green in color under transmitted light and shows a distinct absorption signature associated with Fe in the XRF spectrum.Therefore, the color of this sample is not related to Cr 3+ , and Fe 2+ dominantly causes its green hue.However, due to the infiltration of jadeite particles and other metal minerals into the space during the later stage of jade formation, the transparency was reduced, and the color turned darker.

XRF Analysis
The critical chemical elements were analyzed as a supplement to the color tent.The chemical elements' analysis results in this study are presented in Tab
and MgO are relatively high.Ca 2+ replaced Na+ in the M2 position, while Al 3+ in the M1 position was replaced by Fe 3+ and Mg 2+ , indicating that the late fluid influences jadeite rock formation.Moreover, the contents of CaO are higher than standard values, suggesting that the initial temperature of jadeite jade formation is higher [25,26].The contents of FeO and MgO are relatively high, resulting in the dark color of the jade.At the same time, the compositions do not consist of Cr2O3, which indicates its color is not directly related to Cr.Moreover, the data showed that the base of the GN-1 sample did not contain NiO, while there was 0.054 wt.% of NiO in the yellow spot, indicating that NiO played an essential role in natural color.In addition, we speculate that the limonite may also cause supergene oxidation in the lattice cracks of jadeite, resulting in a yellow color [27][28][29].The analysis sites of omphacite related jade are mostly concentrated in the Omp gion and a few concentrated in the Jd region, indicating that omphacite is the main c ponent mineral.Minor spots close to the dividing line of Jd and Omp indicate that jad tends to transition to omphacite (Figure 10).Moreover, the content of MnO in the electron probe data decreases with the sequence of dark green, blue-green, and light green, and it can be inferred that Mn 2+ is proportional to the light and dark of green jade and also plays a specific role in the color formation.Moreover, because jadeite jade does not contain Cr 2 O 3 , omphacite jade is the opposite; so, the color of omphacite jade will be relatively bright.
The analysis sites of omphacite related jade are mostly concentrated in the Omp region and a few concentrated in the Jd region, indicating that omphacite is the main component mineral.Minor spots close to the dividing line of Jd and Omp indicate that jadeite tends to transition to omphacite (Figure 10).
The values of Na/(Na + Ca) and the pyroxene Nomenclature (edited by Morimoto (1988) were applied to the selection of Guatemalan jadeite samples of different colors [27], as shown in Figure 10.
Comparing samples CN-1-1 and CN-1, it can be discovered that the contents of Al 2 O 3 and Na 2 O of yellow weathering skin are slightly lower than those of light-green sites [28].In addition, the contents of CaO and MgO are more significant than those of light-green positions, indicating that the yellow part is subject to dissolution [28,29].Sample GN-3 with black-green color and BU-1 with blue-green color, mainly composed of omphacite, shows similar characteristics in chemical compositions.However, the distinction is quite significant, mainly because of the higher contents of Cr in sample GN-3, where Cr may be derived from hydrothermal fluids, resulting in the decrease in Na, Al and the increase in Fe, Ca components, respectively.Moreover, the presence of Ni 2+ and trace Mn 2+ will also affect the green darkening [30,31].

Conclusions
The following general conclusions can be derived from the present study.
(1) The main mineral components of Guatemala jadeite jade are jadeite, omphacite, and minor albite.(2) The green color of Guatemala jadeite jade, mainly composed of jadeite, is caused by the electronic transition between bands of Fe 3+ .Fe content is proportional to the change of color in a particular range.(3) The gray characteristics of the gray-green jadeite jade are related to Fe 2+ and clay minerals.The black jadeite jade shows a black color due to the internal jadeite and metal mineral inclusions but appear green under transmitted light.The color of jadeite jade, mainly composed of omphacite, is generally attributed to Cr 3+ and Fe 3+ , among which the blue features of blue-green jadeite jade are attributed to the presence of Fe 2+ and Mn 2+ .

Figure 1 .
Figure 1.Generalized geological framework of Guatemala jadeite jade deposits.The inserted figure shows that Guatemala jadeite jade deposits are located between the Maya Block and Chortis Block (modified after Harlow et al. [16]).

Figure 1 .
Figure 1.Generalized geological framework of Guatemala jadeite jade deposits.The inserted figure shows that Guatemala jadeite jade deposits are located between the Maya Block and Chortis Block (modified after Harlow et al. [16]).

Figure 2 .
Figure 2. Photograph of representative hand specimens of Guatemala jadeite jade.(a, of the sample GN-1 show a large amount of yellow weathered skin before polishing.W ished interior has green and yellow sections.(c,d) Sample BU-1 with blue-green colo after polishing.(e,f) Sample BU-3 with black color before and after polishing.

Figure 2 .
Figure 2. Photograph of representative hand specimens of Guatemala jadeite jade.(a,b) The edges of the sample GN-1 show a large amount of yellow weathered skin before polishing.While the polished interior has green and yellow sections.(c,d) Sample BU-1 with blue-green color before and after polishing.(e,f) Sample BU-3 with black color before and after polishing.

Figure 4 .
Figure 4. Representative photomicrographs showing the different textures of samples with different colors.(a) Textural characteristics of jadeite and omphacite under crossed polarizer.(b) Fractures and black minerals in the jadeite jade under single polarizer.(c,d) Distinct textural characteristics of jadeite under crossed polarizer.Jd: jadeite; Omp: omphacite.

Figure 5 .
Figure 5. Infrared spectra of Guatemalan jadeite specimens: (a) Infrared spectra showing jadeite characteristic peaks of Guatemalan jadeite jade.(b) Guatemalan jadeite jade with characteristic peaks of omphacite.

Figure 5 .
Figure 5. Infrared spectra of Guatemalan jadeite specimens: (a) Infrared spectra showing jadeite characteristic peaks of Guatemalan jadeite jade.(b) Guatemalan jadeite jade with characteristic peaks of omphacite.

Figure 6 .
Figure 6.Guatemalan jadeite jade with jadeite characteristic peaks shown by Raman spectroscopy.

Figure 6 .
Figure 6.Guatemalan jadeite jade with jadeite characteristic peaks shown by Raman spectroscopy.
Symmetric stretching vibration Si-Ob-Si Symmetric bending vibration M-O Stretch/Bend

Crystals 2023 ,Figure 8 .
Figure 8. Ultraviolet-visible spectrum of Guatemala jadeite jade: (a) Different shades o temala jadeite jade, with varying amounts of Fe.(b) Green Guatemala jadeite jade with excluding Cr.

Figure 8 .
Figure 8. Ultraviolet-visible spectrum of Guatemala jadeite jade: (a) Different shades of green Guatemala jadeite jade, with varying amounts of Fe.(b) Green Guatemala jadeite jade with other tones, excluding Cr.

Table 1 .
Infrared spectral peak assignments of samples with distinct colors.

Table 3 .
Raman peak assignment of sample BU-1 and dark green spot.

Table 4 .
Raman spectral peak assignment of sample GN-3 white spot.