Flux Growth and Raman Spectroscopy Study of Cu 2 CrBO 5 Crystals

: Multicomponent ﬂux systems based on both Li 2 WO 4 -B 2 O 3 -Li 2 O-CuO-Cr 2 O 3 and Bi 2 O 3 - MoO 3 -B 2 O 3 -Na 2 O-CuO-Cr 2 O 3 were studied in order to grow Cu 2 CrBO 5 crystals. The conditions for Cu 2 CrBO 5 crystallization were investigated by varyingthe component ratios, and the peculiarities of their interaction were characterized by studying the formation sequence of high-temperature crystallizing phases. Special attention was paid to the problem of Cr 2 O 3 solubility. Phase boundaries between CuCrO 2 , Cu 2 CrO 4 , and Cu 2 CrBO 5 were considered. The crystal structure of the obtained samples was studied viasingle crystal and powder X-ray diffraction. The chemical composition of the grown crystals was examined using the EDX technique. Anactual ratio of Cu:Cr = 1.89:1.11 was found for Cu 2 CrBO 5 grown from the lithium-tungstate system, which showed a small deviation from 2:1, implying the presence of a part of bivalent Cr 2+ in the samples. Anomalies in the thermal dependence of magnetization were analyzed and compared with the previously obtained data for Cu 2 CrBO 5 . The anomaly at T C ≈ 42 K and the antiferromagnetic phase transition at T N ≈ 119 K were considered. Polarized Raman spectra of Cu 2 CrBO 5 were obtained for the ﬁrst time, and a comparative analysis of the obtained data with other monoclinic and orthorhombic ludwigites is presented. Along with the polarized room temperature spectra, the thermal evolution of Raman modes near the antiferromagnetic phase transition temperature T N ≈ 119 K is provided. The inﬂuence of the magnetic phase transition on the Raman spectra of Cu 2 CrBO 5 is discussed.


Introduction
Cu 2 CrBO 5 is a new compound in the ludwigite family.It was obtained and studied as a polycrystal sample for the first time several years ago [1].This ludwigite is the first and the only one known to demonstrateamagnetoelectric effect, since data on similar studies of other ludwigites are absent.The presence of magnetoelectric polarization in Cu 2 CrBO 5 is related to the copper subsystem.It is necessary to note that Cu 2 CrBO 5 possesses structural cationic ordering.This is not typical for almost all heterometallic ludwigites due to the presence of four nonequivalent cation positions in the unit cell (Figure 1) [2][3][4][5].The temperature of magnetic ordering in the copper-chromium ludwigite is quite high for the representatives of this family, with T N = 120 K [1].Moreover, the thermal dependence of the magnetic properties of Cu 2 CrBO 5 behaves non-monotonically in the low-temperature phase.It possesses additional peculiarities such as the M(T) curve inflection and the temperature range in which the spin-flop transition occurs [6].The magnetic structure of Cu 2 CrBO 5 was studied usingpowder neutron diffraction [1].An incommensurate antiferromagnetic phase was found below T N , which was characterized by geometrical frustrations of the exchange interaction.
Crystals 2023, 13, x FOR PEER REVIEW 2 of 16 flection and the temperature range in which the spin-flop transition occurs [6].The magnetic structure of Cu2CrBO5 was studied usingpowder neutron diffraction [1].An incommensurate antiferromagnetic phase was found below TN, which was characterized by geometrical frustrations of the exchange interaction.For a detailed study of the unusual properties of the Cu2CrBO5 ludwigite, especially that of the magnetoelectric effect, it is necessary to conduct orientational experiments on single crystal samples.In this paper, we expand the research in this direction using the flux growth technique.This is the most widelyused method for obtaining single crystal samples of the oxyborates with a ludwigite structure due to the presence of growth anisotropy.Natural faceting of single crystals and the possibility of using different solvent types for individual synthesis of different compounds are undoubtedly some merits of this technique [7].
The research stepsinclude the selection of the initial solvent, establishment of the Cu2CrBO5 single crystal phase, study of the competition between high-temperature crystallizing phases in the system and theiroptimization.In this paper, we study the possibility of growing a copper-chromium ludwigite viathe flux method using two solvents, Li2WO4-B2O3 and Bi2O3-MoO3-B2O3-Na2O.
Despite the presence of growth anisotropy, copper ludwigite crystals achieve significant dimensions in comparison with other ludwigites, as was shown on the example of Cu2FeBO5 [8] and Cu2MnBO5 [9].The size of these compounds allows one to carry out different orientational studies of the physical properties.However, Cu2CrBO5 behaves differently atthe early growth stage, which is caused by the infusibility of Cr2O3 oxide and its low solubility in many solvents [6].The starting point for the search of a flux system appropriate for growing Cu2CrBO5isthe systems used earlier for other copper ludwigites [8,9].Also, one of the main problems is studying the sequence of high-temperature crystallizing phases in the chosen fluxes, and the emphasis placed on the valence state transformation of chromium cations similarly to manganese-containing ludwigites.
In this research, we present the possibility of growing Cu2CrBO5 crystals viathe flux technique using two different solvents based on Li2WO4-Li2O-B2O3 and Bi2O3-MoO3-B2O3-Na2O, and through structural analysis of the obtained phases, study of the thermal and field anomalies of magnetization, and the analyses of the polarized (at room temperature, T = 295K) and thermal (in the vicinity of magnetic phase transition temperature) Raman spectra of Cu2CrBO5.For a detailed study of the unusual properties of the Cu 2 CrBO 5 ludwigite, especially that of the magnetoelectric effect, it is necessary to conduct orientational experiments on single crystal samples.In this paper, we expand the research in this direction using the flux growth technique.This is the most widelyused method for obtaining single crystal samples of the oxyborates with a ludwigite structure due to the presence of growth anisotropy.Natural faceting of single crystals and the possibility of using different solvent types for individual synthesis of different compounds are undoubtedly some merits of this technique [7].
The research stepsinclude the selection of the initial solvent, establishment of the Cu 2 CrBO 5 single crystal phase, study of the competition between high-temperature crystallizing phases in the system and theiroptimization.In this paper, we study the possibility of growing a copper-chromium ludwigite viathe flux method using two solvents, Li 2 WO 4 - Despite the presence of growth anisotropy, copper ludwigite crystals achieve significant dimensions in comparison with other ludwigites, as was shown on the example of Cu 2 FeBO 5 [8] and Cu 2 MnBO 5 [9].The size of these compounds allows one to carry out different orientational studies of the physical properties.However, Cu 2 CrBO 5 behaves differently atthe early growth stage, which is caused by the infusibility of Cr 2 O 3 oxide and its low solubility in many solvents [6].The starting point for the search of a flux system appropriate for growing Cu 2 CrBO 5 isthe systems used earlier for other copper ludwigites [8,9].Also, one of the main problems is studying the sequence of high-temperature crystallizing phases in the chosen fluxes, and the emphasis placed on the valence state transformation of chromium cations similarly to manganese-containing ludwigites.
In this research, we present the possibility of growing

Flux Growth
To study the growth peculiarities, the flux method was used.Samples were grown at atmospheric pressure using a resistance furnace equipped with silicon-carbide heaters.The working temperature range was T = 750-1150 • C. For each experiment, the flux was prepared in a platinum crucible (V = 100 cm 3 ) at T = 1000-1100 • C viasequential melting of the solvent and soluble (crystal forming oxides) components.The prepared fluxes were homogenized during 3 h at the preparation temperature.Then, the sequence of hightemperature crystallizing phases was studied in the prepared fluxes.The crystal formations were estimated using visual observation and sample selection.To obtain a sample in the definite point of the phase diagram of the multicomponent flux system, the following order of the temperature change was used: after homogenization, the temperature in the furnace was rapidly lowered at a rate of 100 • C/h down to a definite temperature T start = (T sat −10) • C, and then lowered slowly at a rate of 4-8 • C/day.After the growth stage wascompleted, the remainder flux was removed from the crystals via etching in a 20% aqueous solution of HNO 3 .

Energy Dispersive X-ray Spectroscopy (EDX)
To study the actual chemical composition of the obtained samples, energy dispersive X-ray spectroscopy (EDX) was used.The single crystal samples were fixed on an aluminum table using a double-sided carbon tape.Then, the table with the samples was placed into the working chamber of a scanning electron microscope Hitachi SU3500 (Hitachi, Japan) with a built-in energy dispersive detector Bruker XFlash6160 (Bruker, Germany).To obtain electron micrographs, an accelerating voltage of 20 kV and a cathode brightness of 60 arb.units were set, and no changes were carried out for obtaining all the subsequent images.The observation was carried out in the backscattered electron mode (BSE).

X-ray Diffraction
The powder diffraction data of the obtained samples for the Rietveld analysis were collected at room temperature with a Haoyuan DX-2700BH (Haoyuan, China) powder diffractometer (Cu-Kα radiation) and a linear detector.The step size of 2θ was 0.01 • , and the counting time was 20 s/deg.Rietveld refinement was performed using TOPAS 4.2 [10].The powders were obtained via the grinding of the crystals.
The crystal structure of the single crystal samples was investigated viathe X-ray diffraction method at room temperature using a SMART APEX II diffractometer (Mo K α , λ = 0.7106 Å) (Bruker, Germany).The structures were solved withdirect methods using the package SHELXS and refined viathe anisotropic approach for all the atoms using the SHELXL program [11].The structure test for the presence of missing symmetry elements and possible voids was created using the program PLATON [12].The DIAMOND program was used for plotting the crystal structure [13].

Measurements of the Magnetic Properties
Thermal and field magnetization dependences of the synthesized samples were obtained in the temperature range of 4.2-300 K and in the magnetic fields up to 9T using PPMS-9 (Quantum Design).The thermal dependences of magnetization of Cu 2 CrBO 5 were measured in the FC (sample cooling in a non-zero magnetic field) and ZFC modes (sample heating in a non-zero magnetic field after cooling in a zero magnetic field).The measurements were carried out using the polycrystal samples.

Raman Spectroscopy
Raman spectra of the obtained single crystal samples were acquired at room temperature in the spectral range of 20-1400 cm −1 in the backscattering geometry, using a Horiba Jobin Yvon T64000 (Horiba, France) spectrometer equipped with a triple monochromator in a subtractive mode.The spectral resolution was 2 cm −1 (this resolution was achieved using 1800 str/mm gratings and 100 µm slits) with adot density of 3 pixel/cm −1 .The spectra were excited usingradiation from a solid-state single-mode laser Spectra-Physics Excelsior-532-300-CDRH (USA) with awavelength of 532 nm and power of <1 mW.Scattered radiation was collected viaa microscope based on Olympus BX-41 through the objective Olympus MPlan50x with the aperture number N.A. = 0.75.The accumulation time for one spectrum was about 15 min.
Polarized Raman spectra were obtained at room temperature.For this purpose, one crystal with the form of an elongated prism and a size of about 0.03 × 0.03 × 0.1 mm 3 was selected.The experiment was conducted with the parallel (HH) and cross-parallel (HV) polarization of the incident and scattered beams to study the angular dependence of intensities of the Raman spectral lines on the polarization direction of the incident and scattered radiationusingbackscattering geometry.The shift inthe incidence point of exciting radiation was smaller than 2 µm in a complete 2π revolution.The angular step was 10 • .This experiment is similar to the work [14], wherein it is explained in detail.
The temperature Raman experiment was controlled with a Linkam THMS600 microcryostage (Linkam Sci.Inst.).The sample was cooled in the range from 173 K to 83 K at a constant cooling rate of 3 K/min.After reaching the given temperature, it was kept constant for 5 min to ensure uniform cooling of the system, and then, the Raman spectra were measured.The uncertainty of temperature stabilization during the Raman spectra acquisition was better than ±0.1 K.
To quantitatively analyze the deconvoluted Raman spectra, we performed the spectral analysis with the Lorentz function, where A, ω 0 , ω, and Γ are the amplitude, position of the line center, wavenumber, and full width at half-maximum (FWHM), respectively.The analysis explanation is similar to the one given in [15].

Results of the Flux Growth Study
The study of the flux growth using two types of solvents, Li 2 WO 4 -Li 2 O-B 2 O 3 and Bi 2 O 3 -MoO 3 -B 2 O 3 -Na 2 O, can be divided into several stages, as described below.
After taking into account a number of preliminary experiments, we searched for a flux system for Cu 2 CrBO 5 , which allowed us to choose the following starting system: The concentration of crystal forming oxides is n = 20%.A significant increase in the molar coefficient of sodium oxide (up to 3) in ( 1) is caused by the necessary formation of Na 2 MoO 4 -type bonds in the flux.For better solubility of chromium oxide, the Cr 2 O 3 powder was milled together with Bi 2 O 3 and MoO 3 powders to homogeneity, and then, B 2 O 3 oxide was added.The obtained mixture was loaded to the crucible and homogenized at T = 1000 • C.Then, the powder of Na 2 CO 3 and CuO was added in portions.After 3 h of homogenization at T = 1000 • C, the flux took the form ofa freely convective liquid.The probing showed the saturation temperature to beabout T sat = 820 • C, and the hightemperature crystallizing phase was CuO, with the formation of black crystals in the form of long flattened prisms.Thus, despite low solubility, the crystallizing phase did not contain chromium, as the saturation temperature wasquite low.
The next stage of flux heating was performed at a higher temperature T = 1100 • C. At this temperature, due to the high concentration of the crystal formation oxides n, a mass crystallization of Cu + Cr 3+ O 2 with the delafossite structure occurred.The crystals are represented with grey-green hexagonal plates [16].There is usually a thermal limit at T = 1000 • C whenworking with copper-containing fluxes due to the decomposition of CuO at higher temperatures, accompanied by the appearance of Cu + 2 O and liberation of oxygen [17].It is worth noting that in the case of Mn-and Fe-containing systems, CuO is also decomposed above T = 1000 • C, which manifests itself as sublimation of the flux upon the addition of CuO.However, no compounds with the delafossite structure were found in the experiments despite the existence of Cu + Mn 3+ O 2 and Cu + Fe 3+ O 2 [18].
The observed mass crystallization of chromium-containing phase at T = 1100 • C showed no dissolution of Cr 2 O 3 at lower temperatures despite the visual control of the flux homogeneity, absence of precipitation, and sufficient convection.The increase in the temperature stimulated the dissolution process, and the formation of monovalent copper determined the high-temperature crystallizing phase of Cu + Cr 3+ O 2 .
Inthe next step, the flux system was optimized: a part of the solvent was significantly increased, copper oxide was introduced and the portion of boron oxide was increased.CuOwas introduced over the stoichiometry due to the elimination of the competing CrBO 3 phase, and it correlated with the increase in B 2 O 3 , which is aimed at lowering the saturation temperature.The flux system where the Cu 2 CrBO 5 phase was a high-temperature crystallizing phase was the following: Here, the concentration of crystal forming oxides is n = 5.6%.Crystals of Cu 2 CrBO 5 in the form of dark (in a thin layer-green-brown ones), small and elongated prisms were obtained upon spontaneous crystallization from the flux system (2).The starting temperature was T start = 850 • C, and the cooling rate was dT/dt = 1 • C/day for 7 days.Thus, the occurrence of the crystal phase of Cu 2 CrBO 5 is proven, and the possibility of obtaining this compound using fluxes based on Bi 2 O 3 -MoO 3 diluted by B 2 O 3 and Na 2 O is shown.
As it was shown in the previous section, the solubility of Cr 2 O 3 plays an important role in the crystallization process of Cu 2 CrBO 5 in the chosen flux system.This section presents the results of the crystallization study of ludwigite in the systems based on lithiumtungstate.Three independent experiments were carried out throughgradual changes in the flux composition with different ratios of the crystal formation oxides Cr 2 O 3 -CuO-B 2 O 3 : 1. stoichiometric composition of Cu 2 CrBO 5 ; 2. composition corresponding to the stoichiometry of CuB 2 O 4 metaborate without adding Cr 2 O 3 inthe initial stage; 3. composition corresponding to the stoichiometry of CrBO 3 without adding CuOinthe initial stage.
The flux system with the initial composition corresponding to the stoichiometry of Cu 2 CrBO 5 was where n is the concentration of the crystal formation oxides, and p and q are the molar coefficients corresponding to the contents of B 2 O 3 and Li 2 O in the solvent, respectively.Inthe initial stage, the flux was taken without Li 2 O and CuO over the stoichiometry of ludwigite, i.e., q = 0 and s = 0.The boron oxide coefficient was p = 2. Due to the low solubility of Cr 2 O 3, alow concentration n = 2.2-3.87% was chosen.The high-temperature crystallizing phase in this flux system was (Cu,Cr)WO 4 , which contained Cr 2+ cations.The saturation temperature was T sat = 860 • C. The formation mechanism of bonds of this type is similar to the one realized in the Mn-containing systems, which is due to the appearance of free WO 3 in the flux.
Further, Li 2 O (up to q = 0.58) was added for the fixation of tungsten oxide.As a result, the color of the flux changed from dark-brown to green, which can be associated with a change in the valence state of chromium from 2+ to 3+.Probing showed the absence of crystallization down to the freezing point of the flux (~710 • C).With further increase in the concentration n in the flux, which was carried out to increase the saturation temperature, poor solubility of chromium oxide was observed: Cr 2 O 3 powder was in the form of a suspension in the flux for a long time.To dissolve chromium oxide and to homogenize the flux, CuO was added to the solvent up to s = 0.64 over the ludwigite stoichiometry, with simultaneous mechanical mixing of the flux using a rotating platinum rodcrystalholder.In this way, the saturation temperature was increased to T sat = 785 • C, and the desired phase of Cu 2 CrBO 5 was obtained upon co-crystallization with CuO (due to the presence of a significant quantity of the copper oxide in the flux).
For further study of Cu 2 CrBO 5 crystallization in the fluxes based on Li 2 WO 4 -Li 2 O-B 2 O 3, the system without the initial addition of Cr 2 O 3 (t = 0) and the one oriented to copper metaborate CuB 2 O 4 were used: The initial concentration of n = 50% was chosen due to the high solubility of copper and boron oxides in system (4), r = 0.The preparation and homogenization of this flux were performed at a temperature to T = 1000 • C, unlike other systems whereinthe top limit temperature was T = 1100 • C. The saturation temperature of the flux was T sat ≈ 900 • C. The high-temperature crystallizing phase was that of CuB 2 O 4 , as expected.Then, Li 2 O was added (up to r = 0.5) for the fixation of WO 3 to avoid the competing phase of (Cu,Cr)WO 4 after the addition of chromium oxide.Due to the addition of a small amount of Cr 2 O 3 , up to t = 0.002, a change occurred in the high-temperature crystallizing phase ofCuO.Further, the phase of Cu 3 B 2 O 6 with the kotoite structure was obtained at t = 0.003, and the desired phase of Cu 2 CrBO 5 was achieved at t = 0.004.
At the next stage, the system with a high concentration of Cr 2 O 3 was studied.This system was oriented to the initial stoichiometry of CrBO 3 : In the initial system, (5), CuO was absent (s = x = 0).The concentration was n = 5%, the molar coefficients of the boron and lithium oxides were p = 2 and q = 1, respectively.As expected, the high-temperature crystallizing phase was represented by the phase of small green hexagonal plates corresponding to CrBO 3 .The flux was a viscous one and possessed poor convection at the homogenization temperature T = 1100 • C, which was caused by the significant portion of the boron oxide.Further, CuO was added to the Cu 2 CrBO 5 stoichiometry (x = 4).Simultaneously, a portion of copper was introduced to the solvent up to s = 0.69.Here, the saturation temperature was about T sat ≈ 760 • C. Below this temperature, crystallization of the phase of small Cu 2 CrBO 5 crystals was observed, which is in agreement with the powder X-ray diffraction data.Thus, the desired ludwigite phase can be obtained in this system via the addition of copper to the solvent over the stoichiometry.
It worth noting that the flux possessed a number of features associated with the low solubility of chromium oxide.To improve the solubility of Cr 2 O 3 , the portion of B 2 O 3 in the solvent was increased, which allowed one to avoid precipitation and flux homogenization.However, the viscosity also significantly increased, and the mass crystallization of small crystals was observed in the static mode.To study the behavior of chromium oxide in this system and its influence on the saturation temperature, Cr 2 O 3 was added along with Li 2 O (the initial powders of Cr 2 O 3 and Li 2 CO 3 were milled together and added to the flux in small portions for better solubility).The concentration was n = 8.45%, with no presence of aprecipitate.The additives changed the high-temperature crystallizing phase to CuO.Then, the concentration was increased again to n = 16%.There was still no precipitate in the crucible, and no crystallization occurred at T = 770 • C. The top temperature operating limit was T = 1100 • C.
Further, the homogenization temperature was increased to T = 1150 • C. As a result, a dense layer of CuCrO 2 crystals formed during a short period of time (about 1 h) on the walls of the crucible.This is in agreement with the result obtained usingthe system based on Bi 2 O 3 -MoO 3 .Thus, the oversaturated flux was obtained with the addition of Cr 2 O 3 , which did not increase T sat before the increase in the temperature.Then, the increase in the portion of the boron oxide to p = 3.35 made it possible to dissolve the delafossite crystals (CuCrO 2 ) and to decrease the saturation temperature down to T sat ≈ 970 • C.Under these conditions, the high-temperature crystallizing phase was CuCr 2 O 4 , containing bivalent copper, which was localized at the bottom of the crucible.The transition to the ludwigite phase was achieved by increasing the B 2 O 3 coefficient up to p = 6.Co-crystallization of the ludwigite Cu 2 CrBO 5 (small black elongated prisms growing from small centers) and spinel CuCr 2 O 4 (small black octahedral crystals) was observed.The localization the ludwigite phase was at the top of the flux, with the larger boron oxide concentration.The localization of the spinel phase was observed at the bottom of the crucible.SEM image of as-grown crystals of Cu 2 CrBO 5 is presented in Figure 2.
solubility of chromium oxide.To improve the solubility of Cr2O3, the portion of B2O3 in the solvent was increased, which allowed one to avoid precipitation and flux homogenization.However, the viscosity also significantly increased, and the mass crystallization of small crystals was observed in the static mode.To study the behavior of chromium oxide in this system and its influence on the saturation temperature, Cr2O3 was added along with Li2O (the initial powders of Cr2O3 and Li2CO3 were milled together and added to the flux in small portions for better solubility).The concentration was n = 8.45%, with no presence of aprecipitate.The additives changed the high-temperature crystallizing phase to CuO.Then, the concentration was increased again to n = 16%.There was still no precipitate in the crucible, and no crystallization occurred at T = 770 °C.The top temperature operating limit was T = 1100 °C.
Further, the homogenization temperature was increased to T = 1150 °C.As a result, a dense layer of CuCrO2 crystals formed during a short period of time (about 1 h) on the walls of the crucible.This is in agreement with the result obtained usingthe system based on Bi2O3-MoO3.Thus, the oversaturated flux was obtained with the addition of Cr2O3, which did not increaseTsat before the increase in the temperature.Then, the increase in the portion of the boron oxide to p = 3.35 made it possible to dissolve the delafossite crystals (CuCrO2) and to decrease the saturation temperature down to Tsat ≈ 970 °C.Under these conditions, the high-temperature crystallizing phase was CuCr2O4, containing bivalent copper, which was localized at the bottom of the crucible.The transition to the ludwigite phase was achieved by increasing the B2O3 coefficient up to p = 6.Co-crystallization of the ludwigite Cu2CrBO5 (small black elongated prisms growing from small centers) and spinel CuCr2O4 (small black octahedral crystals) was observed.The localization the ludwigite phase was at the top of the flux, with the larger boron oxide concentration.The localization of the spinel phase was observed at the bottom of the crucible.SEM image of as-grown crystals of Cu2CrBO5 is presented in Figure2.

Structural Properties
As mentioned above, the phase composition of all the selected samples was controlled using X-ray diffraction.Here, the comparative results for the several obtained samples of ludwigites Cu2CrBO5 and tungstates (Cu,Cr)WO4 are presented to consider the changes in the valence states of chromium cations, and to analyze the partition coefficient of Cr2O3 in the studied flux systems.The structural parameters of the tungstates are presented in Table1, and the structural parameters of the Cu2CrBO5 ludwigite samples are presented in Table 2along with the data provided in [1].

Structural Properties
As mentioned above, the phase composition of all the selected samples was controlled using X-ray diffraction.Here, the comparative results for the several obtained samples of ludwigites Cu 2 CrBO 5 and tungstates (Cu,Cr)WO 4 are presented to consider the changes in the valence states of chromium cations, and to analyze the partition coefficient of Cr 2 O 3 in the studied flux systems.The structural parameters of the tungstates are presented in Table 1, and the structural parameters of the Cu 2 CrBO 5 ludwigite samples are presented in Table 2 along with the data provided in [1].[19] and CrWO 4 [20].

Magnetic Properties
In this paper, the thermal and field dependences of magnetization (M) of two Cu 2 CrBO 5 samples obtained from systems (2), S1, and (5), S2, were studied.The magnetic properties of the sample obtained from the bismuth-molybdenum system (2) were partially presented earlier in [6].The thermal dependences of the magnetic susceptibility (χ) of the studied samples are presented in Figure 3.For S1, the curves were obtained at H = 0.1 T, and for S2, they were obtained at H = 0.5 T (H-magnetic field).As it was mentioned in the section describing the growth study, Cu 2 CrBO 5 was obtained with the admixture of CuCr 2 O 4 spinel phase from system (5).For measuring the magnetic properties, the ludwigite crystals were selected from the sample.However, due to the small crystal size, a part of the spinel crystals was introduced to the investigated sample S2, which influenced the magnetization curves.The main purpose of presenting these results is todemonstrate the magnetic behavior of the thermal inflection point of M(T) for Cu 2 CrBO 5 within the range T = 40-50 K.No influence of the spinel admixture is observed in this range due to the thermal magnetization dependence anomalies of CuCr 2 O 4 at T = 120 K and in the range T = 5-15 K; there is monotonic behavior of magnetization in the range of T = 20-100 K [21].In Figure 3, the red curve corresponds to sample S2 and H = 0.5 T. In the thermal range of 40-50 K, quite a distinct inflection point can be observed, which is poorly visible under the field of a lower value.Along with the thermal dependences, the field dependences of magnetization were studied.

Raman Spectroscopy Study
Raman spectra of the Cu2CrBO5 crystal (sample S1) were studied at room temperature and in the vicinity of the magnetic phase transition.The experiment was carried out in two stages: 1. study of the polarized Raman spectra at room temperature; 2. study of the temperature evolution of the unpolarized Raman spectra in the vicinity of the antiferromagnetic phase transition.The single comparative spectra taken at the intensity maximum positions in the HH and HV modes and Raman intensity maps of Cu 2 CrBO 5 , depending on the rotation angle of the studied sample in the spectral range of 20-1500 cm −1 , are presented in Figures 4  and 5, respectively.The obtained spectra can conditionally be divided into three ranges: 0-300 cm −1 corresponding to the lattice vibrations, 300-750 cm −1 corresponding to the Me-O octahedra vibrations, and 900-1400 cm −1 corresponding to the [BO 3 ] 3− group vibrations.The Raman spectra of Cu 2 CrBO 5 are in agreement with the dataobtained earlier for other ludwigites in terms of the range division and spectral structure.Apart from this, there is an interesting disagreement in terms of both monoclinic ludwigites with different distortion types [6,17] and orthorhombic ones [22,23].The change in the sample color (dark brown) with respect to the manganese ludwigites (black) studied earlier led to a greater intensity of the spectra.The main peculiarities of the Cu2CrBO5 spectra can be seen in the obta maps (Figure5).The intensity distribution, depending on the crystal ro shows the behavior close to orthorhombic ludwigites.Almost all lines of th change their intensity with the 180° phase in the HH mode (parallel orie polarizer and analyzer) and 90° phase in the HV mode (cross-parallel orie polarizer and analyzer).An exception is the vibration with the frequency 4 is in the counter-phase with other lines in the HH mode.The same pe The main peculiarities of the Cu 2 CrBO 5 spectra can be seen in the obtained intensity maps (Figure 5).The intensity distribution, depending on the crystal rotation angle, shows the behavior close to orthorhombic ludwigites.Almost all lines of the Me-O range change their intensity with the 180 • phase in the HH mode (parallel orientation of the polarizer and analyzer) and 90 • phase in the HV mode (cross-parallel orientation of the polarizer and analyzer).An exception is the vibration with the frequency 428 cm −1 , which is in the counter-phase with other lines in the HH mode.The same peculiarities are demonstrated by the group of lines at 180-220 cm −1 in the range of lattice vibrations in the HV mode.
The main peculiarities of the Cu2CrBO5 spectra can be seen in the obtained intensity maps (Figure5).The intensity distribution, depending on the crystal rotation angle, shows the behavior close to orthorhombic ludwigites.Almost all lines of the Me-O range change their intensity with the 180° phase in the HH mode (parallel orientation of the polarizer and analyzer) and 90° phase in the HV mode (cross-parallel orientation of the polarizer and analyzer).An exception is the vibration with the frequency 428cm −1 , which is in the counter-phase with other lines in the HH mode.The same peculiarities are demonstrated by the group of lines at 180-220cm −1 in the range of lattice vibrations in the HV mode.Visual comparison of the obtained spectra did not reveal any the magnetic phase transition.However, small shifts inthe spectr brational range were observed, as expected in the absence of an This corresponds to small changes inthe bonds in the cation o Visual comparison of the obtained spectra did not reveal any meaningful changes at the magnetic phase transition.However, small shifts inthe spectral lines in the Me-O vibrational range were observed, as expected in the absence of an external magnetic field.This corresponds to small changes inthe bonds in the cation octahedra, as a result of magnetic ordering.In Figure 7, the thermal dependences of the central position of 354 cm −1 , 520 cm −1 and 718 cm −1 are presented.Ashift inthese lines (about 1 cm −1 ) was detected, while in the range of the [BO 3 ] 3− group vibrations, no shift was detected.
Visual comparison of the obtained spectra did not reveal any the magnetic phase transition.However, small shifts inthe spectr brational range were observed, as expected in the absence of an This corresponds to small changes inthe bonds in the cation oc magnetic ordering.In Figure7, the dependences of t 354cm −1 , 520cm −1 and 718cm −1 are presented.Ashift inthese lines tected, while in the range of the [BO3] 3− group vibrations, no shift

Discussion
The study of the possibility of obtaining Cu2CrBO5 crystals consists of several stages as the crystallization research in the sy types of solvents, Li2WO4-Li2O-B2O3 and Bi2O3-MoO3-B2O3-Na2O. of the obtained samples was controlled using powder and single c and the chemical composition of some samples was investigated v

Discussion
The study of the possibility of obtaining During the research, the possibility of the formation of copper-chromium compounds with other valence composition was established.Delafossite Cu + CrO 2 and tungstate (Cu, Cr) 2+ WO 4 were obtained as secondary phases.This possibility arises owing to the growth technique applied, in particular, due to the presence of the solvent.
The phase (Cu, Cr)WO 4 was obtained as an intermediate one in the system based on lithium tungstate.This compound contains bivalent cations of transition metals including Cr 2+ .As in the case of the manganese systems, in the Bi-Mo-O fluxes [8], no crystallization of the phase with trivalent cations is observed in the absence of free alkaline metal oxides (Na 2 O and Li 2 O) due to the formation of MnMoO 4 or (Cu, Cr)WO 4 -like phases.In this experiment, two samples of tungstates from system (3) with concentrations n 1 = 2.2% and n 2 = 3.87% were obtained.The space groups and lattice parameters of these compounds are given in Table 1.For comparison, the analogous data for pure CuWO 4 [19] and CrWO 4 [20] are also presented in Table 1.
As one can see from Table 1, pure tungstates are characterized by the space group different from the mixed ones.Copper tungstate is triclinic, while that of chromium is monoclinic.Apparently, the combination of two cations Cu 2+ and Cr 2+ leads to the tungstate structure with the space group P2/c.The lattice parameters of the second mixed sample increase relative to analogous data for the first one.This correlates with an increase in the chromium content, which is in agreement with the ratio of the cationic radii R(Cu 2+ ) = 0.75Å and R(Cr 2+ ) = 0.80Å.Thus, despite the same nominal Cu/Cr ratio in the flux, chromium contentin the crystal increases upon sequential sampling.This demonstrates a significant difference between the partition coefficients of CuO and Cr O 3 and thepoor solubility of chromium.
In this research, Cu 2 CrBO 5 was obtained using several flux systems.In some cases, co-crystallization with the phases CuO and CuCr 2 O 4 was observed.Table 2 presents the structure parameters of two samples of Cu 2 CrBO 5 obtained from systems ( 2) and ( 4), corresponding to the bismuth-molybdenum and lithium-tungstate flux systems.Table 2 shows the data of the other sample obtained viaa solid state reaction [1].
As mentioned earlier [6], the lattice parameters of Cu 2 CrBO 5 obtained usingthe flux technique are different from the sample obtained viathe solid state reaction.In particular, the differences are clearly seen in the monoclinic angle.Significant differences were also revealed upon the analysis of the bond lengths of metal-oxygen octahedra [6].The lattice parameters of samples ( 2) and (4) obtained viathe flux technique correlate quite well witheach other.Some small differences can be caused due to thedifferent X-ray experimental techniques used: the structural data for sample (2) were obtained withpowder X-ray diffraction, while the data for sample (4) were obtained using single crystal X-ray diffraction.
The actual composition of sample ( 2) is Cu 1.89 Cr 1.11 BO 5 , as found withthe EDX analysis.A possible cause of the structural data discrepancy is the different cation composition, in particular, the presence of Cr 2+ in the compounds grown from the fluxes.
The ludwigite Cu 2 CrBO 5 has a number of peculiarities in the thermal and field behavior of magnetization.Below the temperature of the antiferromagnetic phase transition (T N ≈ 120 K), there is a non-monotonic thermal dependence of magnetization, that is, a sharp peak in the vicinity of the phase transition temperature, then the "plateau" and the inflection point in the temperature range of T = 40-50 K (Figure 3, [1,6]), which can also be seen in the thermal dependence of the dielectric constant [1].
To study this anomaly at T = 40-50 K, the dependences ∂(χ•T)/∂T(T), corresponding to the thermal behavior of specific heat for antiferromagnets, were analyzed (Figure 8) [24].The analogous dependence of S2 obtained at H = 0.1 T is also presented in Figure 8.The most significant anomalies, as was expected, were observed in the vicinity of the antiferromagnetic phase transition at T N = 119 K.The green curve, corresponding to sample S1, demonstrates the maximum of the antiferromagnetic phase transition.Two other curves, corresponding to sample S2 with the spinel admixture, demonstrate the sharp minimum corresponding to the ferromagnetic type of the phase transition (the magnetic ordering temperature of spinel is T C = 120 K) together with the maximum of the antiferromagnetic transition.At T 2 = 42 K, the black curve (S2, 0.5 T) demonstrates the second distinct positive maximum of a lower value.Thus, this anomaly can have the antiferromagnetic origin related to the reordering of some subsystem.S1, demonstrates the maximum of the antiferromagnetic phase transition.Two other curves, corresponding to sample S2 with the spinel admixture, demonstrate the sharp minimum corresponding to the ferromagnetic type of the phase transition (the magnetic ordering temperature of spinel is TC = 120K) together with the maximum of the antiferromagnetic transition.At T2 = 42K, the black curve (S2, 0.5T) demonstrates the second distinct positive maximum of a lower value.Thus, this anomaly can have the antiferromagnetic origin related to the reordering of some subsystem.It is mentioned in [1] that the ludwigite Cu2CrBO5 demonstrates metamagnetic transition.The field dependences of magnetization demonstrate reversible inflections in the temperature range T = 60-100K, corresponding to the spin-flop transition.The distinct peaks of the thermal dependences of ∂M/∂H at 100K and 80K are observed in Fig- ure9.The range of the magnetic field up to 9T was not enough to fully register the peak of the curve at 60K.The type of the field dependences M(H) changes at 40K: magnetization decreases and there is a linear law of the dependence.Below 20K, the temperature dependence is absent (Figure9).However, at T = 40K the spin-flop transition can still occur, but at much higher magnetic fields.It is mentioned in [1] that the ludwigite Cu 2 CrBO 5 demonstrates metamagnetic transition.The field dependences of magnetization demonstrate reversible inflections in the temperature range T = 60-100 K, corresponding to the spin-flop transition.The distinct peaks of the thermal dependences of ∂M/∂H at 100 K and 80 K are observed in Figure 9.The range of the magnetic field up to 9 T was not enough to fully register the peak of the curve at 60 K.The type of the field dependences M(H) changes at 40 K: magnetization decreases and there is a linear law of the dependence.Below 20 K, the temperature dependence is absent (Figure 9).However, at T = 40 K the spin-flop transition can still occur, but at much higher magnetic fields.The Raman spectrum of Cu2CrBO5 consists of rather narrow separate lines in the vibration range of the metal-oxygen octahedra.This confirms a high degree of the structural cationic order in this compound.It is greater than in the Cu2MnBO5 ludwigite, which can easily be distinguished among the previously studied ludwigites in terms of Raman spectroscopy [17].
The dependence of the intensity of Raman lines on the rotation angle of Cu2CrBO5 (Figure5) can be compared with other copper ludwigites.In analyzing other copper-containing ludwigites which are also monoclinic, phase shifts were detected in broad spectral ranges in the area of the Me-O octahedra and lattice vibrations [17].The phase shift was different from 45° and 90° in the HV and HH modes, respectively.The shift angle of the maxima of the low-frequency region in the Cu2GaBO5-like phase was about 70° and 120° for HV and HH, respectively, and in the Cu2MnBO5-like phase it was 50° for the HH mode.For the solid solutions of the Cu2GaBO5-Cu2MnBO5 phase boundary, the lines in the spectral range of 670-700cm −1 demonstrate another shift, which is 60° for the HH mode.This implies a change in the angles of the Me-O bonds in the octahedra, The Raman spectrum of Cu 2 CrBO 5 consists of rather narrow separate lines in the vibration range of the metal-oxygen octahedra.This confirms a high degree of the structural cationic order in this compound.It is greater than in the Cu 2 MnBO 5 ludwigite, which can easily be distinguished among the previously studied ludwigites in terms of Raman spectroscopy [17].
The dependence of the intensity of Raman lines on the rotation angle of Cu 2 CrBO 5 (Figure 5) can be compared with other copper ludwigites.In analyzing other coppercontaining ludwigites which are also monoclinic, phase shifts were detected in broad spectral ranges in the area of the Me-O octahedra and lattice vibrations [17].The phase shift was different from 45 • and 90 • in the HV and HH modes, respectively.The shift angle of the maxima of the low-frequency region in the Cu 2 GaBO 5 -like phase was about 70 • and 120 • for HV and HH, respectively, and in the Cu 2 MnBO 5 -like phase it was 50 • for the HH mode.For the solid solutions of the Cu 2 GaBO 5 -Cu 2 MnBO 5 phase boundary, the lines in the spectral range of 670-700 cm −1 demonstrate another shift, which is 60 • for the HH mode.This implies a change in the angles of the Me-O bonds in the octahedra, i.e., the octahedra turn due to the monoclinic distortions in the Cu 2 GaBO 5 -Cu 2 MnBO 5 phases.Another situation occurs in Cu 2 CrBO 5 , namely the angular behavior of the intensity is close to orthorhombic ludwigites, which can indicate the minimal distortions of the structure in this compound.

Conclusions
Ludwigites are a complex compound family demonstrating multidirectional and diverse properties and high sensitivity to the composition, with a difficult process of preparing single crystal samples.Cu 2 CrBO 5 studied in this paperis representative of the family, in which the magnetoelectric effect and a number of magnetic features were detected for the first time.This paper presents the results ofastudy on the possibility of crystallization of this compound in flux systems using two different solvents based on Li 2 WO 4 -Li 2 O-B 2 O 3 and Bi 2 O 3 -MoO 3 -B 2 O 3 -Na 2 O.The phase diagrams of these multicomponent systems were studied.The possibility and area of occurrence of the ludwigite phase were determined.The most perspective components ratios for growing samples of sufficient dimensions and without secondary phases were also determined.Toanalyzethe growth process, the solubility of Cr 2 O 3 in the fluxes of different composition and changes in the valence state of copper and chromium were studied, depending on the working temperature range and flux content.The phase and chemical composition of the obtained samples were controlled using X-ray diffraction and the EDX technique.
The magnetic properties of the obtained Cu 2 CrBO 5 samples were analyzed.In addition to the antiferromagnetic phase transition at T N = 119 K, the anomaly at T = 42 K was studied.The antiferromagnetic nature of the studied anomaly was shown, which can be related to the process of reordering a part of the magnetic subsystems.The spin-flop transition found in the field dependences of magnetization was also analyzed.
Polarized Raman spectra of Cu 2 CrBO 5 were obtained for the first time.The angular intensity distribution was shown to be close to the pattern typical for orthorhombic ludwigites.The metal-oxygen octahedra had a small distortion degree, unlike other monoclinic ludwigites.Raman spectra of Cu 2 CrBO 5 in the vicinity of the antiferromagnetic phase transition were also obtained and analyzed for the first time.Small shifts inthe lines were found, which can be associated with the magnetic ordering in the crystal.
Future research will be focused on the growth of Cu 2 CrBO 5 single crystals with sufficientsize for the orientational study of magnetic and magnetoelectric properties.As it was shown in this paper, the main limiting factor hampering the possibility of producing larger crystals is the solubility of Cr 2 O 3 .To overcome this limitation, it is planned to start the production process with system (4) which allows for the stable single phase crystallization of Cu 2 CrBO 5 .Attention will be paid to increase the flux convection via an attempt to increase the saturation temperature, and to study the influence of mechanical mixing on the growth process.
Cu 2 CrBO 5 crystals viathe flux technique using two different solvents based on Li 2 WO 4 -Li 2 O-B 2 O 3 and Bi 2 O 3 -MoO 3 -B 2 O 3 -Na 2 O, and through structural analysis of the obtained phases, study of the thermal and field anomalies of magnetization, and the analyses of the polarized (at room temperature, T = 295 K) and thermal (in the vicinity of magnetic phase transition temperature) Raman spectra of Cu 2 CrBO 5 .Crystals 2023, 13, 1415 3 of 15

3. 4 .
Raman Spectroscopy StudyRaman spectra of the Cu 2 CrBO 5 crystal (sample S1) were studied at room temperature and in the vicinity of the magnetic phase transition.The experiment was carried out Crystals 2023, 13, 1415 9 of 15 in two stages: 1. study of the polarized Raman spectra at room temperature; 2. study of the temperature evolution of the unpolarized Raman spectra in the vicinity of the antiferromagnetic phase transition.3.4.1.Polarized Room Temperature Raman Spectra of Cu 2 CrBO 5 rystals 2023, 13, x FOR PEER REVIEW

Figure 4 .
Figure 4. Raman spectra of Cu2CrBO5 obtained at room temperature in the HV (t (bottom figure) modes.The experimental sample is shown in the inset.

Figure 4 .
Figure 4. Raman spectra of Cu 2 CrBO 5 obtained at room temperature in the HV (top figure) HH (bottom figure) modes.The experimental sample is shown in the inset.

Figure 5 .
Figure 5. Raman intensity maps of Cu2CrBO5 obtained upon the parallel HH (a) and cross-parallel HV (b) polarization of the incident and scattered beams.

3. 4 . 2 .
Thermal Evolution of the Raman Spectra of Cu2CrBO5 Raman spectra of Cu2CrBO5 were measured with the temperature change in the vicinity of the antiferromagnetic phase transition (TN = 119K).The obtained thermal evolution is presented in Figure6.

Figure 5 .
Figure 5. Raman intensity maps of Cu 2 CrBO 5 obtained upon the parallel HH (a) and cross-parallel HV (b) polarization of the incident and scattered beams.

Figure 6 .
Figure 6.Raman spectra of Cu 2 CrBO 5 taken at different temperatures in the vicinity of the antiferromagnetic phase transition.

Figure 7 .
Figure 7. Thermal dependence of the central positions of the Raman lines of the Me-O vibrations.

Figure 7 .
Figure 7. Thermal dependence of the central positions of the Raman lines within the spectral range of the Me-O vibrations.
Cu 2 CrBO 5 crystals usingthe flux technique consists of several stages as the crystallization research in the systems is based on two types of solvents, Li 2 WO 4 -Li 2 O-B 2 O 3 and Bi 2 O 3 -MoO 3 -B 2 O 3 -Na 2 O.The phase composition of the obtained samples was controlled using powder and single crystal X-ray diffraction, and the chemical composition of some samples was investigated viathe EDX technique.Four flux systems were studied, one based on Bi 2 O 3 -MoO 3 -B 2 O 3 -Na 2 O and three based on Li 2 WO 4 -Li 2 O-B 2 O 3 with different starting points.The ludwigite phase (Cu 2 CrBO 5 ) was obtained in each system.However, a "pure" ludwigite phase was obtained in two of them: (2) and (4).Co-crystallization with the phases CuO and CuCr 2 O 4 was obtained in systems (3) and (5), respectively.Thus, for further study of the crystallization processes aimed at growing a Cu 2 CrBO 5 sample of sufficient size, systems (2) and (4) was used.Thus, both flux systems, based on Li 2 WO 4 -Li 2 O-B 2 O 3 and on Bi 2 O 3 -MoO 3 -B 2 O 3 -Na 2 O, are appropriate for obtaining the crystallization of the Cu 2 CrBO 5 ludwigite phase.Hence, after taking into account the study of three systems with different component ratios, it can be concluded that there is a wide area of the ludwigite phase on the phase diagram of the Li 2 WO 4 -Li 2 O-B 2 O 3 -based multicomponent flux system.The main restricting factor for obtaining the sufficient dimensions of the Cu 2 CrBO 5 single crystals is the solubility of chromium oxide.This problem needs additional study.

Table 1 .
Structural data for (Cu,Cr)WO 4 in comparison with pure CuWO 4