Review on the Application of Supplementary Cementitious Materials in Self-Compacting Concrete

For the sustainable development of construction materials, supplementary cementitious materials (SCMs) are commonly added to self-compacting concrete (SCC). This paper reviewed the application techniques and hydration mechanisms of SCMs in SCC. The impacts of SCMs on the microstructure and performance of SCC were also discussed. SCMs are used as a powder material to produce SCC by replacing 10% to 50% of cement. Hydration mechanisms include the pozzolanic reaction, alkaline activation, and adsorption effect. Moreover, the filling effect and dilution effect of some SCMs can refine the pore structure and decrease the temperature rise of concrete, respectively. Specifically, the spherical particles of fly ash can improve the fluidity of SCC, and the aluminum-containing mineral phase can enhance the resistance to chloride ion penetration. Silica fume will increase the water demand of the paste and promote its strength development (a replacement of 10% results in a 20% increase at 28 days). Ground-granulated blast furnace slag may reduce the early strength of SCC. The adsorption of Ca2+ by CaCO3 in limestone powder can accelerate the hydration of cement and promote its strength development.


Introduction
Self-compacting concrete (SCC) is a type of high-performance concrete that can be poured into structural formwork by gravity and compacted without vibration. Okamura et al. [1] pioneered the application of SCC in Japan in 1988. The outstanding features are that SCC eliminates the mechanical vibration process and lowers labor costs as compared to normal vibrating concrete (NVC), and SCC has a high powder material content in the mixture to increase fresh properties ( Figure 1). However, using cement solely as a powder material leads to high production cost for SCC, which restricts its wide use. In addition, the high cement content in SCC poses increasing environmental risks as cement production is a high-resource-consuming and waste-discharging process, and its annual production has reached 3000 million tons worldwide [2]. in SCC, which can promote the sustainable development of SCC technology and improve the comprehensive utilization of solid wastes. The application techniques and hydration mechanisms of SCMs in SCC were reviewed in this work, and the impacts of fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GBFS), and limestone powder (LP) on the microstructure and performance of SCC were also summarized.

Mixture Design of SCC
The fresh paste of SCC should have high fluidity as well as resistance to segregation and bleeding during pouring, especially when the paste flows through the limited space of reinforcing bars. It should be noted that the higher the proportion of coarse aggregate in concrete, the smaller the relative distance between particles, which increases the frequency of collision and friction. As a result, the internal stress caused by coarse aggregate consumes a large amount of energy for flowing, which reduces the fresh properties of the paste and even causes blockage. To avoid this, Okamura et al. [1] initially modified the mix proportion by reducing aggregate content, increasing powder content, and adding superplasticizer. To generate self-compacting concrete, this work first sets the amount of aggregate and next changes the water-to-binder ratio and superplasticizer dosages. Figure  1 depicts the proportion of each component. In China, the mixture proportion design of SCC is often done by the absolute volume technique (Chinese standard: CECS203, 2006). In this technique, the cement paste that meets the performance requirements is prepared first, and the fine and coarse aggregates are added sequentially to produce the appropriate mortar and concrete. In addition, Wu et al. [5] and Nie et al. [6] have proposed a mix design method based on the rheological characteristics of paste. It can be found that SCC contains a larger proportion of powder material than NVC. Domone [7] summarized a lot of instances from previous research and discovered that roughly 95% of self-compacting concrete had powder masses of more than 400 kg/m 3 . This demonstrates that more SCMs can be added to SCC. The application of SCMs reduces the The addition of supplementary cementitious materials (SCMs) as a partial substitute for cement can significantly lower the production cost of SCC as well as relieve the shortages of cement raw materials and solid waste pollution [3]. SCMs can adjust the fresh properties and improve the durability properties [4]. Specifically, SCMs can effectively enhance the microstructure of SCC. Furthermore, SCMs will have superposition effects when two or more of them are used together. Although SCMs have been widely employed in SCC, there is still a lack of a summary in its mix proportions. Moreover, the functions of SCMs in SCC remain unclear, and the systematic analysis of macroscopic properties does not exist yet. Therefore, it is necessary to outline the influences of SCMs in SCC, which can promote the sustainable development of SCC technology and improve the comprehensive utilization of solid wastes. The application techniques and hydration mechanisms of SCMs in SCC were reviewed in this work, and the impacts of fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GBFS), and limestone powder (LP) on the microstructure and performance of SCC were also summarized.

Mixture Design of SCC
The fresh paste of SCC should have high fluidity as well as resistance to segregation and bleeding during pouring, especially when the paste flows through the limited space of reinforcing bars. It should be noted that the higher the proportion of coarse aggregate in concrete, the smaller the relative distance between particles, which increases the frequency of collision and friction. As a result, the internal stress caused by coarse aggregate consumes a large amount of energy for flowing, which reduces the fresh properties of the paste and even causes blockage. To avoid this, Okamura et al. [1] initially modified the mix proportion by reducing aggregate content, increasing powder content, and adding superplasticizer. To generate self-compacting concrete, this work first sets the amount of aggregate and next changes the water-to-binder ratio and superplasticizer dosages. Figure 1 depicts the proportion of each component. In China, the mixture proportion design of SCC is often done by the absolute volume technique (Chinese standard: CECS203, 2006). In this technique, the cement paste that meets the performance requirements is prepared first, and the fine and coarse aggregates are added sequentially to produce the appropriate mortar and concrete. In addition, Wu et al. [5] and Nie et al. [6] have proposed a mix design method based on the rheological characteristics of paste.
It can be found that SCC contains a larger proportion of powder material than NVC. Domone [7] summarized a lot of instances from previous research and discovered that roughly 95% of self-compacting concrete had powder masses of more than 400 kg/m 3 . This demonstrates that more SCMs can be added to SCC. The application of SCMs reduces the production costs of SCC while improving concrete performance. For example, adding FA can improve the fresh properties of SCC [8], and adding SF can enhance its strength properties [9]. Moreover, the viscosity modifying admixture should be added to stabilize the rheology and setting time when segregation occurs due to the addition of high-content or composite SCMs [10].

Characteristics of SCMs
The most common SCMs used in SCC are fly ash, silica fume, ground granulated blast furnace slag, and limestone powder. In addition, some other SCMs with fewer use cases are also used in SCC, such as copper slag [11], zeolite powder [12], etc. From the results of existing studies, the percentages of SiO 2 , Al 2 O 3 , and CaO in FA, SF, GBFS, LP, and cement were compared and shown in Figure 2. FA has the highest Al 2 O 3 content; GBFS mainly contains SiO 2 and CaO; the chemical composition of SF and LP is relatively simple, containing only SiO 2 and CaCO 3 , respectively. It is worth noting that the chemical composition of the same kind of SCM varies greatly due to the considerable variances in the raw ore, manufacturing procedure, and discharge process. Compared with SCMs, Portland cement is more concentrated in the areas shown in Figure 2, and its chemical composition is more stable. the raw ore, manufacturing procedure, and discharge process. Compared with SCMs, Portland cement is more concentrated in the areas shown in Figure 2, and its chemical composition is more stable.
The microscopic images of FA, SF, GBFS, and LP are shown in Figure 3. It can be found that the FA is mostly smooth and spherical particles, and this spherical shape can play a ball-bearing role in the freshly mixed SCC. The particle sizes of SF are usually small, and it will typically increase the water demand of fresh paste. GBFS and LP show obvious irregular and angular shapes due to mechanical grinding.
The microscopic images of FA, SF, GBFS, and LP are shown in Figure 3. It can be found that the FA is mostly smooth and spherical particles, and this spherical shape can play a ball-bearing role in the freshly mixed SCC. The particle sizes of SF are usually small, and it will typically increase the water demand of fresh paste. GBFS and LP show obvious irregular and angular shapes due to mechanical grinding.   [17], (c) GBFS [50], (d) LP [67].

Hydration Mechanisms
The hydration processes of Portland cement can be divided into three periods: the induction period, the acceleration period, and the deceleration period [68]. When SCMs are incorporated into SCC, the hydration process of the composite system is significantly influenced by SCMs (Figure 4). The hydration process in the composite system usually involves the cement first hydrating to produce primary hydration products; then, the products react with SCMs to produce secondary hydration products. For example, the hydration of GBFS is triggered by the deconstruction of the glass by OH − generated from the hydration of cement, which serves as an alkaline activator. This process releases the ions in the glass (Ca 2+ , Al 3+ , SiO 4 4− , etc.) into the solution for subsequent hydration. The main reaction product of GBFS by alkaline activation is a type of aluminum-substituted C-A-S-H gel, which presents a disordered tobermorite-like C-S-H type structure. In addition, the active Al 2 O 3 in GBFS will further react with Ca(OH) 2 and gypsum (CaSO 4 ) to form ettringite (AFt) [69,70]. These reactions are shown in Equations (1)-(3) as follows: For the C-A-S-H gel, existing studies have shown that when the paste contains Na + , the chemically bound Ca 2+ in C-A-S-H will be replaced by Na + to form a C-(N)-A-S-H type gel [71]. Myers et al. [72] proposed a structural model to simulate this gel based on the cross-linked and non-cross-linked structure properties of C-(N)-A-S-H, as shown in Figure 5.

Hydration Mechanisms
The hydration processes of Portland cement can be divided into three periods: t induction period, the acceleration period, and the deceleration period [68]. When SCM are incorporated into SCC, the hydration process of the composite system is significant influenced by SCMs (Figure 4). The hydration process in the composite system usual involves the cement first hydrating to produce primary hydration products; then, t products react with SCMs to produce secondary hydration products. For example, t hydration of GBFS is triggered by the deconstruction of the glass by OHgenerated fro the hydration of cement, which serves as an alkaline activator. This process releases t ions in the glass (Ca 2+ , Al 3+ , SiO4 4− , etc.) into the solution for subsequent hydration. T main reaction product of GBFS by alkaline activation is a type of aluminum-substitute C-A-S-H gel, which presents a disordered tobermorite-like C-S-H type structure. In add tion, the active Al2O3 in GBFS will further react with Ca(OH)2 and gypsum (CaSO4) form ettringite (AFt) [69,70]. These reactions are shown in Equations (1)-(3) as follows: For the C-A-S-H gel, existing studies have shown that when the paste contains N the chemically bound Ca 2+ in C-A-S-H will be replaced by Na + to form a C-(N)-A-S-H typ gel [71]. Myers et al. [72] proposed a structural model to simulate this gel based on t cross-linked and non-cross-linked structure properties of C-(N)-A-S-H, as shown in Fi ure 5.

Hydration Mechanisms
The hydration processes of Portland cement can be divided into three periods: the induction period, the acceleration period, and the deceleration period [68]. When SCMs are incorporated into SCC, the hydration process of the composite system is significantly influenced by SCMs ( Figure 4). The hydration process in the composite system usually involves the cement first hydrating to produce primary hydration products; then, the products react with SCMs to produce secondary hydration products. For example, the hydration of GBFS is triggered by the deconstruction of the glass by OHgenerated from the hydration of cement, which serves as an alkaline activator. This process releases the ions in the glass (Ca 2+ , Al 3+ , SiO4 4− , etc.) into the solution for subsequent hydration. The main reaction product of GBFS by alkaline activation is a type of aluminum-substituted C-A-S-H gel, which presents a disordered tobermorite-like C-S-H type structure. In addition, the active Al2O3 in GBFS will further react with Ca(OH)2 and gypsum (CaSO4) to form ettringite (AFt) [69,70]. These reactions are shown in Equations (1)-(3) as follows: For the C-A-S-H gel, existing studies have shown that when the paste contains Na + , the chemically bound Ca 2+ in C-A-S-H will be replaced by Na + to form a C-(N)-A-S-H type gel [71]. Myers et al. [72]     Similar to the hydration process of GBFS, the hydration of FA occurs under the alkali activity of OH − produced by cement hydration. However, FA is less active due to its high amount of SiO 2 and Al 2 O 3 (low Ca/(Si + Al) ratio) and stable Si-O and Al-O bonds. Its contribution to hydration is generally apparent at a later stage. Fernandez et al. [74] developed a microstructural model for the hydration process of FA, as illustrated in Figure 6. The attack on the incomplete spherical glassy shell of FA particles by OH − causes the formation of reaction products both inside and outside, and finally, FA particles with various reaction degrees will be embedded in the microstructure. It is worth pointing out that SCMs can offer nucleation sites for cement hydration in addition to the secondary reaction with the primary products. For instance, the chemical adsorption of Ca 2+ by the surface of limestone particles can effectively enhance the nucleation and growth of C-S-H; silica fume can adsorb Ca 2+ via electrostatic force and boost the formation of hydration products [75]. Similar to the hydration process of GBFS, the hydration of FA occurs under the alkali activity of OHproduced by cement hydration. However, FA is less active due to its high amount of SiO2 and Al2O3 (low Ca/(Si + Al) ratio) and stable Si-O and Al-O bonds. Its contribution to hydration is generally apparent at a later stage. Fernandez et al. [74] developed a microstructural model for the hydration process of FA, as illustrated in Figure  6. The attack on the incomplete spherical glassy shell of FA particles by OHcauses the formation of reaction products both inside and outside, and finally, FA particles with various reaction degrees will be embedded in the microstructure. It is worth pointing out that SCMs can offer nucleation sites for cement hydration in addition to the secondary reaction with the primary products. For instance, the chemical adsorption of Ca 2+ by the surface of limestone particles can effectively enhance the nucleation and growth of C-S-H; silica fume can adsorb Ca 2+ via electrostatic force and boost the formation of hydration products [75].

Microstructure
Concrete consists of three parts: aggregate, interfacial transition zone (ITZ), and cement paste. ITZ is a thin shell wrapped around the surface of the aggregate and is the lowest-strength part of concrete, whose microstructure determines the performance of concrete [76]. The incorporated SCMs can influence the formation and development of the ITZ in SCC. Figure 7 shows the comparison of the ITZ between SCC without SCMs and mixed with 20% and 30% fly ash [25]. The influences originate from three effects of SCMs: namely, the filling effect, pozzolanic reaction, and dilution effect. The filling effect can increase the packing density and optimize the mixture proportion of concrete. At the same time, the pozzolanic reaction of SCM can consume the CH generated by cement hydration while creating C-S-H, thus improving the interfacial transition zone. In addition, the fact of a general slower hydration reaction of SCM allows for more water to participate in cement hydration, resulting in an adequate reaction of cement. Simultaneously, SCMs can offer nucleation sites for cement hydration, resulting in more evenly dispersed reaction products ( Figure 8).

Microstructure
Concrete consists of three parts: aggregate, interfacial transition zone (ITZ), and cement paste. ITZ is a thin shell wrapped around the surface of the aggregate and is the lowest-strength part of concrete, whose microstructure determines the performance of concrete [76]. The incorporated SCMs can influence the formation and development of the ITZ in SCC. Figure 7 shows the comparison of the ITZ between SCC without SCMs and mixed with 20% and 30% fly ash [25]. The influences originate from three effects of SCMs: namely, the filling effect, pozzolanic reaction, and dilution effect. The filling effect can increase the packing density and optimize the mixture proportion of concrete. At the same time, the pozzolanic reaction of SCM can consume the CH generated by cement hydration while creating C-S-H, thus improving the interfacial transition zone. In addition, the fact of a general slower hydration reaction of SCM allows for more water to participate in cement hydration, resulting in an adequate reaction of cement. Simultaneously, SCMs can offer nucleation sites for cement hydration, resulting in more evenly dispersed reaction products ( Figure 8).

Fresh Properties
Fluidity is the most common performance of fresh concrete, which engineers always primarily consider. On one hand, SCMs in SCC may fill the pores and lower the pore water content, increasing the quantity of free water and wrapping around the surface of the powder particles to produce a uniform water film that lubricates the paste and minimizes friction [77]. On the other hand, the increased specific surface area of some ground SCMs will improve water absorption and decrease free water content. Therefore, the fineness and proportion of SCMs have a significant impact on the fresh properties of SCC. Furthermore, because certain SCMs may reduce fluidity, superplasticizers are often necessary in SCC to improve the performance of the fresh mixture. The superplasticizer mainly disperses the powder particles via steric repulsion. When one end of the superplasticizer is adsorbed to the surface of the powder particles, the long chain at the other end generates physical barriers to prevent the surrounding cement particles from aggregation [78,79]. It is worth noting that the superplasticizers added to the SCC may have negative consequences. Existing studies have shown that the adsorption of these chemical admixtures on cement particles might retard the early hydration and result in a delayed setting [80].
A good deal of research has demonstrated that fly ash can increase the fluidity of the fresh SCC. This effect can be attributed to the smooth and spherical particles of FA [81]. Jain et al. [25] reported that the spherical particles of FA provided a ball-bearing action in newly mixed SCC, reducing the frictional resistance of aggregate particles. Promsawat et al. [23] reported similar findings. In addition, Sonebi [82] proposed that adding FA could enhance the fluidity by thickening the water film. However, FA may have negative effects on the fresh properties of SCC. Duran-Herrera et al. [22] found that FA prolongs the setting time of SCC.
Unlike fly ash, silica fume increases the water demand and decreases the fluidity due to its larger specific area. Choudhary et al. [17] observed the microscopic morphology of FA and SF ( Figure 3) and discovered that spherical FA helps to reduce the friction between

Fresh Properties
Fluidity is the most common performance of fresh concrete, which engineers always primarily consider. On one hand, SCMs in SCC may fill the pores and lower the pore water content, increasing the quantity of free water and wrapping around the surface of the powder particles to produce a uniform water film that lubricates the paste and minimizes friction [77]. On the other hand, the increased specific surface area of some ground SCMs will improve water absorption and decrease free water content. Therefore, the fineness and proportion of SCMs have a significant impact on the fresh properties of SCC. Furthermore, because certain SCMs may reduce fluidity, superplasticizers are often necessary in SCC to improve the performance of the fresh mixture. The superplasticizer mainly disperses the powder particles via steric repulsion. When one end of the superplasticizer is adsorbed to the surface of the powder particles, the long chain at the other end generates physical barriers to prevent the surrounding cement particles from aggregation [78,79]. It is worth noting that the superplasticizers added to the SCC may have negative consequences. Existing studies have shown that the adsorption of these chemical admixtures on cement particles might retard the early hydration and result in a delayed setting [80].
A good deal of research has demonstrated that fly ash can increase the fluidity of the fresh SCC. This effect can be attributed to the smooth and spherical particles of FA [81]. Jain et al. [25] reported that the spherical particles of FA provided a ball-bearing action in newly mixed SCC, reducing the frictional resistance of aggregate particles. Promsawat et al. [23] reported similar findings. In addition, Sonebi [82] proposed that adding FA could enhance the fluidity by thickening the water film. However, FA may have negative effects on the fresh properties of SCC. Duran-Herrera et al. [22] found that FA prolongs the setting time of SCC.
Unlike fly ash, silica fume increases the water demand and decreases the fluidity due to its larger specific area. Choudhary et al. [17] observed the microscopic morphology of FA and SF ( Figure 3) and discovered that spherical FA helps to reduce the friction between

Fresh Properties
Fluidity is the most common performance of fresh concrete, which engineers always primarily consider. On one hand, SCMs in SCC may fill the pores and lower the pore water content, increasing the quantity of free water and wrapping around the surface of the powder particles to produce a uniform water film that lubricates the paste and minimizes friction [77]. On the other hand, the increased specific surface area of some ground SCMs will improve water absorption and decrease free water content. Therefore, the fineness and proportion of SCMs have a significant impact on the fresh properties of SCC. Furthermore, because certain SCMs may reduce fluidity, superplasticizers are often necessary in SCC to improve the performance of the fresh mixture. The superplasticizer mainly disperses the powder particles via steric repulsion. When one end of the superplasticizer is adsorbed to the surface of the powder particles, the long chain at the other end generates physical barriers to prevent the surrounding cement particles from aggregation [78,79]. It is worth noting that the superplasticizers added to the SCC may have negative consequences. Existing studies have shown that the adsorption of these chemical admixtures on cement particles might retard the early hydration and result in a delayed setting [80].
A good deal of research has demonstrated that fly ash can increase the fluidity of the fresh SCC. This effect can be attributed to the smooth and spherical particles of FA [81]. Jain et al. [25] reported that the spherical particles of FA provided a ball-bearing action in newly mixed SCC, reducing the frictional resistance of aggregate particles. Promsawat et al. [23] reported similar findings. In addition, Sonebi [82] proposed that adding FA could enhance the fluidity by thickening the water film. However, FA may have negative effects on the fresh properties of SCC. Duran-Herrera et al. [22] found that FA prolongs the setting time of SCC.
Unlike fly ash, silica fume increases the water demand and decreases the fluidity due to its larger specific area. Choudhary et al. [17] observed the microscopic morphology of FA and SF ( Figure 3) and discovered that spherical FA helps to reduce the friction between particles and improve fluidity. However, SF decreases fluidity and increases the superplasticizer demands due to its larger specific surface area and rough surface texture. As shown in Figure 9, Mustapha et al. [8] investigated the effects of FA and SF on the fresh properties of SCC and discovered that FA improved the slump flow diameter (fluidity) but decreased the V-Funnel time (viscosity), whereas SF decreased the fluidity but increased the viscosity of SCC. particles and improve fluidity. However, SF decreases fluidity and increases the superplasticizer demands due to its larger specific surface area and rough surface texture. As shown in Figure 9, Mustapha et al. [8] investigated the effects of FA and SF on the fresh properties of SCC and discovered that FA improved the slump flow diameter (fluidity) but decreased the V-Funnel time (viscosity), whereas SF decreased the fluidity but increased the viscosity of SCC. The impact of GBFS on the fresh properties of SCC is connected to the fineness and admixture proportion. Through the study of Boukendakdji [44], GBFS with a specific surface area of 350 m 2 /kg was utilized to substitute cement ( Figure 10), with an ideal admixture rate of 15%. Furthermore, it was shown that GBFS has a superior water retention effect at increasing fineness, which minimizes the time-dependent loss of slump flow diameter. In contrast, Selvarani et al. [83] discovered that GBFS inclusion lowers the fluidity of SCC. Moreover, Ofuyatan et al. [84] reported that GBFS had a minimal influence on fresh properties, with an increase in incorporation from 10% to 30%, causing a 5% drop in slump flow diameter. This discrepancy can be attributed to two aspects: the differences in filling effect and specific surface area of varying fineness, and the changes in GBFS adsorption capability by various superplasticizers. The influence of LP on the fresh properties of SCC is mostly determined by its fineness. The filling effect of LP enhances the fluidity of the paste, but a higher content of finer The impact of GBFS on the fresh properties of SCC is connected to the fineness and admixture proportion. Through the study of Boukendakdji [44], GBFS with a specific surface area of 350 m 2 /kg was utilized to substitute cement ( Figure 10), with an ideal admixture rate of 15%. Furthermore, it was shown that GBFS has a superior water retention effect at increasing fineness, which minimizes the time-dependent loss of slump flow diameter. In contrast, Selvarani et al. [83] discovered that GBFS inclusion lowers the fluidity of SCC. Moreover, Ofuyatan et al. [84] reported that GBFS had a minimal influence on fresh properties, with an increase in incorporation from 10% to 30%, causing a 5% drop in slump flow diameter. This discrepancy can be attributed to two aspects: the differences in filling effect and specific surface area of varying fineness, and the changes in GBFS adsorption capability by various superplasticizers.
particles and improve fluidity. However, SF decreases fluidity and increases the superplasticizer demands due to its larger specific surface area and rough surface texture. As shown in Figure 9, Mustapha et al. [8] investigated the effects of FA and SF on the fresh properties of SCC and discovered that FA improved the slump flow diameter (fluidity) but decreased the V-Funnel time (viscosity), whereas SF decreased the fluidity but increased the viscosity of SCC. The impact of GBFS on the fresh properties of SCC is connected to the fineness and admixture proportion. Through the study of Boukendakdji [44], GBFS with a specific surface area of 350 m 2 /kg was utilized to substitute cement ( Figure 10), with an ideal admixture rate of 15%. Furthermore, it was shown that GBFS has a superior water retention effect at increasing fineness, which minimizes the time-dependent loss of slump flow diameter. In contrast, Selvarani et al. [83] discovered that GBFS inclusion lowers the fluidity of SCC. Moreover, Ofuyatan et al. [84] reported that GBFS had a minimal influence on fresh properties, with an increase in incorporation from 10% to 30%, causing a 5% drop in slump flow diameter. This discrepancy can be attributed to two aspects: the differences in filling effect and specific surface area of varying fineness, and the changes in GBFS adsorption capability by various superplasticizers. The influence of LP on the fresh properties of SCC is mostly determined by its fineness. The filling effect of LP enhances the fluidity of the paste, but a higher content of finer The influence of LP on the fresh properties of SCC is mostly determined by its fineness. The filling effect of LP enhances the fluidity of the paste, but a higher content of finer powders increases the water requirement. Sua-iam et al. [56,57] found that mixing LP with a median particle size of 15.63 µm (D 50 cement = 23.30 µm) increased water demand and reduced fluidity. Faheem [61] discovered that mixing LP with a median particle size of 11.60 µm (D 50 cement = 15.32 µm) also reduced fluidity. Celik et al. [58,59] showed that LP with an average particle size of 48.1 µm (D cement = 10.4 µm) enhances fluidity and shortens setting time, and that about 15% of the LP in the experiment enhanced slump flow diameter by 7%. In addition, some research revealed that there is a discrepancy in the compatibility of LP with various superplasticizers [62].

Strength Properties
The effect of SCMs on the strength properties of SCC is influenced by the filler effect, the pozzolanic reaction, and the dilution effect. The partial substitution of cement by SCMs reduces the cementitious component of the paste, hence slowing the development of early strength. FA is predominantly composed of SiO 2 and Al 2 O 3 with minimal pozzolanic reactivity, and it typically facilitates post-strength growth [81]. Mahalingam et al. [21] reported that using 40% FA replacement of cement has a considerable diluting effect and lowers compressive strength. Esquinas et al. [15] also found that using FA delayed the strength development of SCC. According to the research of Altoubat et al. [85], incorporating 50% FA into SCC not only had a negative influence on early strength but also increased shrinkage.
The ideal quantity of FA should not exceed 35%; otherwise, silica fume should be added to encourage the development of strength (Figure 11).

Strength Properties
The effect of SCMs on the strength properties of SCC is influenced by the filler effect, the pozzolanic reaction, and the dilution effect. The partial substitution of cement by SCMs reduces the cementitious component of the paste, hence slowing the development of early strength. FA is predominantly composed of SiO2 and Al2O3 with minimal pozzolanic reactivity, and it typically facilitates post-strength growth [81]. Mahalingam et al. [21] reported that using 40% FA replacement of cement has a considerable diluting effect and lowers compressive strength. Esquinas et al. [15] also found that using FA delayed the strength development of SCC. According to the research of Altoubat et al. [85], incorporating 50% FA into SCC not only had a negative influence on early strength but also increased shrinkage. The ideal quantity of FA should not exceed 35%; otherwise, silica fume should be added to encourage the development of strength ( Figure 11).
In contrast, SF with high fineness and pozzolanic reactivity frequently enhances the strength properties of SCC [9]. From the results of Fakhri [86,87], the incorporation of 10% SF can improve the compressive strength by more than 30% and increase the flexural strength by around 20%; the addition of 25% SF can optimize the flexural strength by approximately 40%. According to Karthik et al. [88], this is because SF contains a high content of reactive SiO2, which might enhance the hydration. Furthermore, SF may efficiently enhance the filler effect and improve the interfacial transition zone. Esfandiari et al. [33] indicated that the reactive SiO2 in SF could effectively react with Ca(OH)2 in the paste to generate C-S-H gels. The substitution of GBFS for cement in SCC will delay the early strength growth of the paste [8]. Boukendakdji et al. [44] researched the influence of GBFS on SCC and discovered that the early compressive strength of concrete reduced as GBFS admixture increased, but the post-strength (at 56 days and 90 days) did not appreciably decrease (Figure 12). Altoubat et al. [89] also discovered that GBFS lowers the strength of SCC, with the 28-day compressive strength decreasing by around 10% at 70% admixture, while In contrast, SF with high fineness and pozzolanic reactivity frequently enhances the strength properties of SCC [9]. From the results of Fakhri [86,87], the incorporation of 10% SF can improve the compressive strength by more than 30% and increase the flexural strength by around 20%; the addition of 25% SF can optimize the flexural strength by approximately 40%. According to Karthik et al. [88], this is because SF contains a high content of reactive SiO 2 , which might enhance the hydration. Furthermore, SF may efficiently enhance the filler effect and improve the interfacial transition zone. Esfandiari et al. [33] indicated that the reactive SiO 2 in SF could effectively react with Ca(OH) 2 in the paste to generate C-S-H gels.
The substitution of GBFS for cement in SCC will delay the early strength growth of the paste [8]. Boukendakdji et al. [44] researched the influence of GBFS on SCC and discovered that the early compressive strength of concrete reduced as GBFS admixture increased, but the post-strength (at 56 days and 90 days) did not appreciably decrease ( Figure 12). Altoubat et al. [89] also discovered that GBFS lowers the strength of SCC, with the 28-day compressive strength decreasing by around 10% at 70% admixture, while Ofuyatan et al. [84] discovered that GBFS has a negligible influence on the strength development of SCC, with 28-day compressive strength rising by just 1% at 20% substitution and dropping by 4% at 30% substitution. Furthermore, Dadsetan et al. [47] revealed that the effect of GBFS on the strength of SCC is related to the water-cement ratio and the content of GBFS. The experimental results showed that at a water-cement ratio of 0.4, the 7-day and the 28-day compressive strengths of concrete with 10%, 20%, and 30% GBFS admixture were all reduced. However, at a water-cement ratio of 0.45, the 7-day and 28-day compressive strengths of concrete with all three admixtures increased. With the 30% admixture, the 28-day strength increased by about 30%. the effect of GBFS on the strength of SCC is related to the water-cement ratio and the content of GBFS. The experimental results showed that at a water-cement ratio of 0.4, the 7-day and the 28-day compressive strengths of concrete with 10%, 20%, and 30% GBFS admixture were all reduced. However, at a water-cement ratio of 0.45, the 7-day and 28day compressive strengths of concrete with all three admixtures increased. With the 30% admixture, the 28-day strength increased by about 30%.
LP stimulates the hydration of cement and enhances the strength development of concrete primarily through the adsorption of Ca 2+ by CaCO3, which promotes the dissolution of C3S. At the beginning of the cement hydration, the dissolution and hydration of C3S produce a substantial quantity of Ca 2+ . Since Ca 2+ has a stronger migration capacity than SiO3 2-, the chemical adsorption of CaCO3 to Ca 2+ happens when Ca 2+ diffuses toward the surface of LP particles. On one hand, this adsorption decreases the concentration of Ca 2+ around the C3S particles, allowing C3S to dissolve and hydrate more quickly. On the other hand, the connection of Ca 2+ with the surface of LP particles causes them to form ion clusters, which continue to expand to construct the crystal nucleus and gradually grow into C-S-H gels. Therefore, the adsorption of Ca 2+ by the surface of LP greatly promotes the hydration of cement and leads to the high-density nucleation and directional growth of C-S-H [75].

Durability Properties
The compactness of the paste greatly influences the durability of concrete [90,91]. The diluting effect of SCMs decreases the quantity of cement, lowering the temperature increase in concrete and minimizing the risks of cracking [82]. Altoubat et al. [89] demonstrated that incorporating GBFS and FA decreased the internal stress of SCC, resulting in better cracking resistance ( Figure 13). The filling effect of SCMs may reduce the porosity and permeability by packing the pores of the paste, thus improving the durability of SCC. For example, SF may increase the durability of SCC by filling the pores to reinforce the microstructure. According to the research of Karthik et al. [88], SCC exhibited higher resistance to sulfate attack and chloride ion penetration with the addition of SF admixture. Esfandiari et al. [33] suggested that this is not only due to the filling effect of SF but also the pozzolanic reaction, which is SF reacting with CH to produce C-S-H. Additionally, Sideris et al. [49] reported that the filling effect with the addition of GBFS in SCC decreased the porosity and reduced the carbonation depth. Zhang [92] proposed that GBFS could effectively improve the sulfate attack resistance of concrete. Moreover, Zhu et al. [62]  LP stimulates the hydration of cement and enhances the strength development of concrete primarily through the adsorption of Ca 2+ by CaCO 3 , which promotes the dissolution of C 3 S. At the beginning of the cement hydration, the dissolution and hydration of C 3 S produce a substantial quantity of Ca 2+ . Since Ca 2+ has a stronger migration capacity than SiO 3 2-, the chemical adsorption of CaCO 3 to Ca 2+ happens when Ca 2+ diffuses toward the surface of LP particles. On one hand, this adsorption decreases the concentration of Ca 2+ around the C 3 S particles, allowing C 3 S to dissolve and hydrate more quickly. On the other hand, the connection of Ca 2+ with the surface of LP particles causes them to form ion clusters, which continue to expand to construct the crystal nucleus and gradually grow into C-S-H gels. Therefore, the adsorption of Ca 2+ by the surface of LP greatly promotes the hydration of cement and leads to the high-density nucleation and directional growth of C-S-H [75].

Durability Properties
The compactness of the paste greatly influences the durability of concrete [90,91]. The diluting effect of SCMs decreases the quantity of cement, lowering the temperature increase in concrete and minimizing the risks of cracking [82]. Altoubat et al. [89] demonstrated that incorporating GBFS and FA decreased the internal stress of SCC, resulting in better cracking resistance ( Figure 13). The filling effect of SCMs may reduce the porosity and permeability by packing the pores of the paste, thus improving the durability of SCC. For example, SF may increase the durability of SCC by filling the pores to reinforce the microstructure. According to the research of Karthik et al. [88], SCC exhibited higher resistance to sulfate attack and chloride ion penetration with the addition of SF admixture. Esfandiari et al. [33] suggested that this is not only due to the filling effect of SF but also the pozzolanic reaction, which is SF reacting with CH to produce C-S-H. Additionally, Sideris et al. [49] reported that the filling effect with the addition of GBFS in SCC decreased the porosity and reduced the carbonation depth. Zhang [92] proposed that GBFS could effectively improve the sulfate attack resistance of concrete. Moreover, Zhu et al. [62] claimed that the smaller the particle size of the LP, the better it filled the pores and the greater the packing density. The adsorption effect of LP on cement hydration is beneficial for enhancing the microstructure.
It should be noted that FA has a significant impact on the resistance to chloride ion penetration of SCC. Gnanaraj et al. [93] discovered that FA could greatly enhance its resistance to chloride ion penetration. The studies of Mahalingam et al. [21] and Esquinas et al. [14,15] also came up with similar outcomes. Dinakar et al. [24] indicated that the resistance to both sulfate attack and chloride ion penetration is noticeably increased with the increasing FA content. This is because the permeability of chloride ions relies on the chloride binding capacity of the substance. The Cl − penetrates into the interior concrete along with the water, and some of the chlorides can react with the mineral phase in cement (mainly aluminumcontaining) to form stable chlorine-containing complexes. However, when the chloride is supersaturated, a certain amount of the free state Cl − is produced, which will corrode the concrete. It is widely known that FA contains a high proportion of aluminum-containing mineral phases. Figure 2 also illustrates that the concentration of Al 2 O 3 in FA is greater than that in cement. Therefore, as the FA proportion rises, the chloride-binding capacity of SCC also increases, limiting the concentration of free Cl − that might cause corrosion. Similarly, GBFS contains more aluminum phase minerals than cement, and Sideris et al. [49] reported that GBFS can increase the resistance to chloride ion penetration of SCC. claimed that the smaller the particle size of the LP, the better it filled the pores and the greater the packing density. The adsorption effect of LP on cement hydration is beneficial for enhancing the microstructure. It should be noted that FA has a significant impact on the resistance to chloride ion penetration of SCC. Gnanaraj et al. [93] discovered that FA could greatly enhance its resistance to chloride ion penetration. The studies of Mahalingam et al. [21] and Esquinas et al. [14,15] also came up with similar outcomes. Dinakar et al. [24] indicated that the resistance to both sulfate attack and chloride ion penetration is noticeably increased with the increasing FA content. This is because the permeability of chloride ions relies on the chloride binding capacity of the substance. The Clpenetrates into the interior concrete along with the water, and some of the chlorides can react with the mineral phase in cement (mainly aluminum-containing) to form stable chlorine-containing complexes. However, when the chloride is supersaturated, a certain amount of the free state Clis produced, which will corrode the concrete. It is widely known that FA contains a high proportion of aluminum-containing mineral phases. Figure 2 also illustrates that the concentration of Al2O3 in FA is greater than that in cement. Therefore, as the FA proportion rises, the chloride-binding capacity of SCC also increases, limiting the concentration of free Clthat might cause corrosion. Similarly, GBFS contains more aluminum phase minerals than cement, and Sideris et al. [49] reported that GBFS can increase the resistance to chloride ion penetration of SCC.

Conclusions
The application techniques and hydration mechanisms of SCMs in SCC were discussed, and the impacts of FA, SF, GBFS, and LP on the microstructure and performance of SCC were reviewed. The major conclusions are as follows: • SCC has a high content of powder material, and it is feasible to reduce the quantity of cement and thus decrease the production costs by incorporating SCMs. FA, SF, GGBS, and LP are the most frequently utilized SCMs in SCC. FA contains a high proportion of aluminum phase and predominantly spherical particles; SF primarily contains SiO2 and has a high specific surface area. GBFS mainly contains SiO2 and CaO; LP chiefly consists of CaCO3, and both of them show obvious irregular and angular shapes due to mechanical grinding. The hydration mechanisms of these SCMs in SCC include pozzolanic reaction, alkaline activation, and adsorption effect. Moreover, the filling effect and dilution effect of some SCMs on the paste will contribute to reducing the porosity and limiting the temperature rise of concrete, respectively.

Conclusions
The application techniques and hydration mechanisms of SCMs in SCC were discussed, and the impacts of FA, SF, GBFS, and LP on the microstructure and performance of SCC were reviewed. The major conclusions are as follows: • SCC has a high content of powder material, and it is feasible to reduce the quantity of cement and thus decrease the production costs by incorporating SCMs. FA, SF, GGBS, and LP are the most frequently utilized SCMs in SCC. FA contains a high proportion of aluminum phase and predominantly spherical particles; SF primarily contains SiO 2 and has a high specific surface area. GBFS mainly contains SiO 2 and CaO; LP chiefly consists of CaCO 3 , and both of them show obvious irregular and angular shapes due to mechanical grinding. The hydration mechanisms of these SCMs in SCC include pozzolanic reaction, alkaline activation, and adsorption effect. Moreover, the filling effect and dilution effect of some SCMs on the paste will contribute to reducing the porosity and limiting the temperature rise of concrete, respectively.

•
The spherical particles of FA improve the fluidity of the freshly mixed paste, whereas SF increases the water demand and reduces fluidity due to its large specific surface area. The effect of GBFS on the fresh properties of SCC is related to the fineness and blending amount. The impact of LP is determined by the fineness, and LP will typically increase water consumption. Furthermore, superplasticizers are often added into SCC to increase the fresh properties, and superplasticizers might retard the early hydration and result in a delayed setting.

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The low pozzolanic reactivity of FA typically decreases the strength properties, particularly the early strength; the active SF usually enhances strength. The effect of GBFS on strength is dependent on the water-cement ratio and admixture amount, and it usually reduces the early strength while having little effect on post-strength. The adsorption effect of CaCO 3 on Ca 2+ in LP will accelerate the hydration of cement and improve the development of the early strength.

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The pozzolanic reaction and filling effect of SCMs reduce the porosity of the hardened paste, resulting in a denser microstructure in the interfacial transition zone, thus increasing the durability of SCC. Furthermore, because of the high aluminum phase composition, FA and GBFS are typically capable of improving the resistance to chloride ion penetration and sulfate attack of SCC.
It is worth mentioning that although the employment of multiple SCMs in a composite system may provide a superposition effect, the chemical composition of different SCMs varies widely, and the issues of compatibility may rise. The rules governing the influence of composite SCMs added to SCC are not consistent and require additional investigation.