Effect of Arc Length on Oxygen Content and Mechanical Properties of Weld Metal during Pulsed GMAW

: Pulsed gas metal arc weld (GMAW) was widely used for the advantages of controllable heat input, all-position welding, and no spatter. In order to obtain an ideal welding process, the stability of the arc length was studied in many researches, but the inﬂuence of arc length on the properties of weld metal was ignored. In this paper, the effect of arc length on oxygen content and mechanical properties of weld metal during pulsed GMAW was studied. Q690 high strength steel was selected as the base metal, and ER69-G solid wire, with a diameter of 1.2 mm, was used as the electrode wire. Additionally, the shielding gas and the wire feed rate were 82% Ar + 18% CO 2 and 4 m/min, respectively. The results showed that as the arc length raised from 2.9 mm to 9.2 mm, the oxidation reacted more completely in the droplet transfer zone, and the oxygen content of the weld metal increased signiﬁcantly. The tensile strength of the weld metal reduced but the − 40 ◦ C impact energy heightened. Due to the longer arc, the proportion of acicular ferrite (AF) in the microstructure decreased, but the proportion of lath bainite (LB) and granular bainite (GB) decreased. The higher oxygen content of weld metal was useful for the formation of inclusions, which promoted the nucleation of acicular ferrite and dimples, contributing to the growth of plasticity and toughness of weld metal.


Introduction
With the development of industrial automation and robot welding, pulsed gas metal arc weld (GMAW) was widely used for the advantages of controllable heat input, allposition welding, and no spatter [1][2][3]. During the droplet transfer process in pulsed GMAW, "one droplet per pulse" (ODPP) was regarded as the most ideal mode [4][5][6], which was mainly affected by the pulse peak current (I p ) and pulse peak current time (t p ) [7][8][9]. In order to obtain a stable ODPP process, the pulse base current time (t b ) was generally adjusted to change the arc length.
The shape of the arc, the heat transfer, and the heat dissipation mode of the droplets were greatly influenced by the arc length [10,11]. If the arc length were too short to provide sufficient space, the droplet would contact the molten pool but was still on the wire, contributing to a short circuit [12]. In addition, if the arc length were too long, the stability of the arc would decline and the oxidation reaction of liquid metal during the metal transfer process would be affected. However, the stability of the arc length was studied in many researches, while the effect of arc length on oxygen content and mechanical properties of weld metal was ignored [13,14].
In this paper, a high-speed camera was applied to investigate how the arc length affects the droplet transfer process. Additionally, by the analysis of the oxygen content and mechanical properties of weld metal, the relevant mechanism was discussed.

Experimental Method
In this paper, a synchronous acquisition system of high-speed photography, current, and voltage signal was used (shown in Figure 1). The welding torch was placed stationary over the workpiece on the platform and the high-speed camera system was worked at 10,000 fps. In order to enhance the background brightness and magnify the contrast of images, a laser light with a wavelength of 850 nm was used as a backlight. Additionally, 20 mm thick Q690 high strength steel was selected as the base metal, and the butt joint was used. Thus, an ER69-G solid wire with a diameter of 1.2 mm was used as the electrode wire. Figure 2 shows the schematic diagram of welded joints and the selection of test specimens. The method of multi-layer multi-road welding was applied and the number of passes was 19, with a 6 mm thick backing plate under the weld. The preheating temperature before welding was controlled between 100 • C and 120 • C and the interpass temperature was controlled between 150 • C and 160 • C.

Experimental Method
In this paper, a synchronous acquisition system of high-speed photography, current, and voltage signal was used (shown in Figure 1). The welding torch was placed stationary over the workpiece on the platform and the high-speed camera system was worked at 10,000 fps. In order to enhance the background brightness and magnify the contrast of images, a laser light with a wavelength of 850 nm was used as a backlight. Additionally, 20 mm thick Q690 high strength steel was selected as the base metal, and the butt joint was used. Thus, an ER69-G solid wire with a diameter of 1.2 mm was used as the electrode wire. Figure 2 shows the schematic diagram of welded joints and the selection of test specimens. The method of multi-layer multi-road welding was applied and the number of passes was 19, with a 6 mm thick backing plate under the weld. The preheating temperature before welding was controlled between 100 °C and 120 °C and the interpass temperature was controlled between 150 °C and 160 °C.  Table 1 shows the welding conditions. In order to obtain the ODPP droplet transfer mode, the pulse base current time was selected as the adjustable parameter to change the arc length. The pulse base current time was 9, 8.2, 7.4, 6.6 ms from Test 1 to Test 4, respectively. The corresponding arc length was 2.9, 4.5, 6.5, 9.2 mm, respectively. The arc lengths were measured at the time of the maximum pulse peak current because the arc brightness was the largest and the boundary was clear at the moment.
According to the AWS B4.0-2016 standard [15], the impact specimens, the tensile specimen, and the chemical composition analysis specimen were cut out from the weld metal, as shown in Figure 2. The size of the standard impact specimen was 10 mm × 10 mm× 50 mm, with a 45° V-notch. The impact experiment was carried out at −40 °C. Figure  3 shows the detailed size of the tensile specimen. The tensile experiment was carried out at room temperature, during which the load speed was set as 1 mm·min −1 . The metallographic samples of weld metal were cut from the center position perpendicular to the weld.    Table 1 shows the welding conditions. In order to obtain the ODPP droplet transfer mode, the pulse base current time was selected as the adjustable parameter to change the arc length. The pulse base current time was 9, 8.2, 7.4, 6.6 ms from Test 1 to Test 4, respectively. The corresponding arc length was 2.9, 4.5, 6.5, 9.2 mm, respectively. The arc lengths were measured at the time of the maximum pulse peak current because the arc brightness was the largest and the boundary was clear at the moment.
According to the AWS B4.0-2016 standard [15], the impact specimens, the tensile specimen, and the chemical composition analysis specimen were cut out from the weld metal, as shown in Figure 2. The size of the standard impact specimen was 10 mm × 10 mm× 50 mm, with a 45 • V-notch. The impact experiment was carried out at −40 • C. Figure 3 shows the detailed size of the tensile specimen. The tensile experiment was carried out at room temperature, during which the load speed was set as 1 mm·min −1 . The metallographic samples of weld metal were cut from the center position perpendicular to the weld. The pulse base current time was 9, 8.2, 7.4, 6.6 ms from Test 1 to Test 4, respectiv The corresponding arc length was 2.9, 4.5, 6.5, 9.2 mm, respectively. The arc lengths w measured at the time of the maximum pulse peak current because the arc brightness w the largest and the boundary was clear at the moment.
According to the AWS B4.0-2016 standard [15], the impact specimens, the ten specimen, and the chemical composition analysis specimen were cut out from the w metal, as shown in Figure 2. The size of the standard impact specimen was 10 mm × mm× 50 mm, with a 45° V-notch. The impact experiment was carried out at −40 °C. Fig  3 shows the detailed size of the tensile specimen. The tensile experiment was carried at room temperature, during which the load speed was set as 1 mm·min −1 . T metallographic samples of weld metal were cut from the center position perpendicula the weld.   Figure 4 shows the oxygen content of weld metal under different arc lengths. As arc length rises from 2.9 mm to 9.2 mm, the oxygen content increased by 71.4 significantly from 217 ppm to 372 ppm. When the arc length was 4.5 mm and 9.2 mm, oxygen content of weld metal was 235 ppm and 284 ppm, respectively.  Figure 4 shows the oxygen content of weld metal under different arc lengths. As the arc length rises from 2.9 mm to 9.2 mm, the oxygen content increased by 71.4%, significantly from 217 ppm to 372 ppm. When the arc length was 4.5 mm and 9.2 mm, the oxygen content of weld metal was 235 ppm and 284 ppm, respectively.

Effect of Arc Length on Oxygen Content of Weld Metal
The high-speed photographic images of droplets under different arc lengths are given in Figure 5. It can be seen that the mode of droplet transfer was ODPP, although the arc length was different. When the arc length was 2.9, 4.5, 6.5, 9.2 mm, the measured frequency of droplets was 94, 102, 111, and 122, respectively. Since the speed of wire feed remained unchanged in the experiments, the size of a single droplet would become smaller under the ODPP droplet transfer mode with the frequency of droplets rising, contributing that the specific surface area of liquid droplets increased and the metallurgical reaction between droplets and arc was strengthened. Moreover, the speed of the droplet slowed down with the rise of arc length and the time of the droplet passing through the high-temperature arc increased from Figure 5. Therefore, the intensity and duration of an oxidation reaction in the whole droplet reaction zone increased, as well as the oxygen content of droplets. Finally, the oxygen element was transferred into the weld pool through the droplets, resulting in the increase of the oxygen content of the weld metal. The high-speed photographic images of droplets under different arc lengt given in Figure 5. It can be seen that the mode of droplet transfer was ODPP, althou arc length was different. When the arc length was 2.9, 4.5, 6.5, 9.2 mm, the mea frequency of droplets was 94, 102, 111, and 122, respectively. Since the speed of wir remained unchanged in the experiments, the size of a single droplet would b smaller under the ODPP droplet transfer mode with the frequency of droplets contributing that the specific surface area of liquid droplets increased an metallurgical reaction between droplets and arc was strengthened. Moreover, the of the droplet slowed down with the rise of arc length and the time of the droplet p through the high-temperature arc increased from Figure 5. Therefore, the intensit duration of an oxidation reaction in the whole droplet reaction zone increased, as w the oxygen content of droplets. Finally, the oxygen element was transferred into the pool through the droplets, resulting in the increase of the oxygen content of the metal.  The high-speed photographic images of droplets under different arc lengths are given in Figure 5. It can be seen that the mode of droplet transfer was ODPP, although the arc length was different. When the arc length was 2.9, 4.5, 6.5, 9.2 mm, the measured frequency of droplets was 94, 102, 111, and 122, respectively. Since the speed of wire feed remained unchanged in the experiments, the size of a single droplet would become smaller under the ODPP droplet transfer mode with the frequency of droplets rising, contributing that the specific surface area of liquid droplets increased and the metallurgical reaction between droplets and arc was strengthened. Moreover, the speed of the droplet slowed down with the rise of arc length and the time of the droplet passing through the high-temperature arc increased from Figure 5. Therefore, the intensity and duration of an oxidation reaction in the whole droplet reaction zone increased, as well as the oxygen content of droplets. Finally, the oxygen element was transferred into the weld pool through the droplets, resulting in the increase of the oxygen content of the weld metal.

Effect of Arc Length on Mechanical Properties of Weld Metal
The mechanical properties of weld metal were given in Figures 6 and 7. It can be seen that the tensile strength and yield strength of weld metal both gradually decreased with the rise of arc length, but the −40 • C impact energy and the elongation rose. As the arc length grew from 2.9 mm to 9.2 mm, the tensile strength decreased from 781 MPa to 729 MPa and the −40 • C impact energy increased from 79 J to 116 J.

Effect of Arc Length on Mechanical Properties of Weld Metal
The mechanical properties of weld metal were given in Figures 6 and 7. It can be seen that the tensile strength and yield strength of weld metal both gradually decreased with the rise of arc length, but the −40 °C impact energy and the elongation rose. As the arc length grew from 2.9 mm to 9.2 mm, the tensile strength decreased from 781 MPa to 729 MPa and the −40 °C impact energy increased from 79 J to 116 J.  The chemical composition of weld wire is shown in Table 2. With the increase of arc length, the content of various alloy elements in the weld metal showed a decreasing trend, as given in Table 3. It can be seen that the decrease of alloy elements' content was related to the increased oxygen content. With the increase in arc length, the oxidation reaction of the droplets was enhanced, resulting in a more serious burning loss of metal alloy elements of welding wire. Therefore, the tensile strength was the largest under the shortest arc length (781 MPa) and the smallest (729 MPa) under the longest arc length.

Effect of Arc Length on Mechanical Properties of Weld Metal
The mechanical properties of weld metal were given in Figures 6 and 7. It can be seen that the tensile strength and yield strength of weld metal both gradually decreased with the rise of arc length, but the −40 °C impact energy and the elongation rose. As the arc length grew from 2.9 mm to 9.2 mm, the tensile strength decreased from 781 MPa to 729 MPa and the −40 °C impact energy increased from 79 J to 116 J.  The chemical composition of weld wire is shown in Table 2. With the increase of arc length, the content of various alloy elements in the weld metal showed a decreasing trend, as given in Table 3. It can be seen that the decrease of alloy elements' content was related to the increased oxygen content. With the increase in arc length, the oxidation reaction of the droplets was enhanced, resulting in a more serious burning loss of metal alloy elements of welding wire. Therefore, the tensile strength was the largest under the shortest arc length (781 MPa) and the smallest (729 MPa) under the longest arc length.  The chemical composition of weld wire is shown in Table 2. With the increase of arc length, the content of various alloy elements in the weld metal showed a decreasing trend, as given in Table 3. It can be seen that the decrease of alloy elements' content was related to the increased oxygen content. With the increase in arc length, the oxidation reaction of the droplets was enhanced, resulting in a more serious burning loss of metal alloy elements of welding wire. Therefore, the tensile strength was the largest under the shortest arc length (781 MPa) and the smallest (729 MPa) under the longest arc length.  From the metallographic microstructure (shown in Figure 8), it can be seen that the weld metal consisted of acicular ferrite (AF), lath bainite (LB), and granular bainite (GB). When the arc length was 2.9 mm, an obvious LB microstructure can be found, which was the strengthening phase. Therefore, the highest tensile strength can be obtained. When the arc length reached 9.2 mm, the microstructure of the weld metal was mainly AF, but LB can hardly be found. At the same time, GB became finer and more dispersed. The AFgrains were fine and cross-distributed at a large angle, which divided the original austenite structure and can hinder the crack propagation, belonging to the toughening phase. When the microcrack propagated, it had to overcome the obstacle of a large number of AF, contributing to the greater −40 • C impact energy of weld metal.  From the metallographic microstructure (shown in Figure 8), it can be seen that the weld metal consisted of acicular ferrite (AF), lath bainite (LB), and granular bainite (GB). When the arc length was 2.9 mm, an obvious LB microstructure can be found, which was the strengthening phase. Therefore, the highest tensile strength can be obtained. When the arc length reached 9.2 mm, the microstructure of the weld metal was mainly AF, but LB can hardly be found. At the same time, GB became finer and more dispersed. The AFgrains were fine and cross-distributed at a large angle, which divided the original austenite structure and can hinder the crack propagation, belonging to the toughening phase. When the microcrack propagated, it had to overcome the obstacle of a large number of AF, contributing to the greater −40 °C impact energy of weld metal.  Figure 9 shows the impact of fracture morphology of weld metal under different arc lengths. Obvious cleavage steps but few dimples can be found when the arc length is 2.9 mm. When the plastic deformation was blocked, the stress in the local strong deformation area was relatively concentrated and the initiated crack expanded along the cleavage surface to release the stress, resulting in the cleavage steps. Cleavage steps were generally considered as being the characteristic morphology of brittle fracture. Therefore, the elongation and the −40 °C impact energy were the lowest when arc length was 2.9 mm. When the arc length was 9.2 mm, most areas in the impact fracture were dimple morphology. The torn edge of the dimple was obvious and a few scattered cleavage steps were surrounded by a large number of dimples. As a result, better plasticity and toughness can be achieved.  Figure 9 shows the impact of fracture morphology of weld metal under different arc lengths. Obvious cleavage steps but few dimples can be found when the arc length is 2.9 mm. When the plastic deformation was blocked, the stress in the local strong deformation area was relatively concentrated and the initiated crack expanded along the cleavage surface to release the stress, resulting in the cleavage steps. Cleavage steps were generally considered as being the characteristic morphology of brittle fracture. Therefore, the elongation and the −40 • C impact energy were the lowest when arc length was 2.9 mm. When the arc length was 9.2 mm, most areas in the impact fracture were dimple morphology. The torn edge of the dimple was obvious and a few scattered cleavage steps were surrounded by a large number of dimples. As a result, better plasticity and toughness can be achieved. Micromorphology using scanning electron microscope (SEM) and X-ray energy dispersion spectrometry (EDS) analysis result of inclusion in the dimple of impact fracture of weld metal is shown in Figure 10. It can be seen that spherical inclusions were found at the bottom of the dimples. According to the EDS analysis result, the inclusions were made from O, Al, Si, Ti, Mn, Fe, Ni, Mo, and other elements. Considering O element is not easy to combine with Ni and Mo, Ni, and Mo in the EDS analysis result may come from the base of weld metal. The inclusions of weld metal are often the compounds or composites formed by the combination of multiple elements. Therefore, it can be inferred that the inclusions may contain O, Al, Si, Ti, Mn, Fe, and other elements, and the oxides of the above elements (including TiO2, SiO2, MnO2, Al2O3, FeO, and their composites) were the main components. In addition, with the rise of arc length, the oxygen content in weld metal increased, which indicated that the number of inclusions in the impact fracture also increased. Inclusions promoted the nucleation of acicular ferrite and dimples, contributing to the growth of plasticity and toughness of weld metal. A similar effect of the oxygen content on the microstructure and mechanical properties was also observed in Zhang's studies [16,17].

Conclusions
The effect of arc length on oxygen content and mechanical properties of weld metal during pulsed GMAW was studied in this paper. The main conclusions can be summarized below: Micromorphology using scanning electron microscope (SEM) and X-ray energy dispersion spectrometry (EDS) analysis result of inclusion in the dimple of impact fracture of weld metal is shown in Figure 10. It can be seen that spherical inclusions were found at the bottom of the dimples. According to the EDS analysis result, the inclusions were made from O, Al, Si, Ti, Mn, Fe, Ni, Mo, and other elements. Considering O element is not easy to combine with Ni and Mo, Ni, and Mo in the EDS analysis result may come from the base of weld metal. The inclusions of weld metal are often the compounds or composites formed by the combination of multiple elements. Therefore, it can be inferred that the inclusions may contain O, Al, Si, Ti, Mn, Fe, and other elements, and the oxides of the above elements (including TiO 2 , SiO 2 , MnO 2 , Al 2 O 3 , FeO, and their composites) were the main components. In addition, with the rise of arc length, the oxygen content in weld metal increased, which indicated that the number of inclusions in the impact fracture also increased. Inclusions promoted the nucleation of acicular ferrite and dimples, contributing to the growth of plasticity and toughness of weld metal. A similar effect of the oxygen content on the microstructure and mechanical properties was also observed in Zhang's studies [16,17]. Micromorphology using scanning electron microscope (SEM) and X-ray energy dispersion spectrometry (EDS) analysis result of inclusion in the dimple of impact fracture of weld metal is shown in Figure 10. It can be seen that spherical inclusions were found at the bottom of the dimples. According to the EDS analysis result, the inclusions were made from O, Al, Si, Ti, Mn, Fe, Ni, Mo, and other elements. Considering O element is not easy to combine with Ni and Mo, Ni, and Mo in the EDS analysis result may come from the base of weld metal. The inclusions of weld metal are often the compounds or composites formed by the combination of multiple elements. Therefore, it can be inferred that the inclusions may contain O, Al, Si, Ti, Mn, Fe, and other elements, and the oxides of the above elements (including TiO2, SiO2, MnO2, Al2O3, FeO, and their composites) were the main components. In addition, with the rise of arc length, the oxygen content in weld metal increased, which indicated that the number of inclusions in the impact fracture also increased. Inclusions promoted the nucleation of acicular ferrite and dimples, contributing to the growth of plasticity and toughness of weld metal. A similar effect of the oxygen content on the microstructure and mechanical properties was also observed in Zhang's studies [16,17].

Conclusions
The effect of arc length on oxygen content and mechanical properties of weld metal during pulsed GMAW was studied in this paper. The main conclusions can be summarized below:

Conclusions
The effect of arc length on oxygen content and mechanical properties of weld metal during pulsed GMAW was studied in this paper. The main conclusions can be summarized below: