Cyclic Tension Induced Pattern Formation on [001] Single-Crystal Aluminum Foil

: Cyclic tension of (100)[001]-oriented single-crystal aluminum foils with the frequency 5 Hz forms a tweed pattern. Its period is several microns and increases by a factor of 1.5 in the temperature range 233–363 K. A model is proposed for structural relaxation of the medium on spatial and time meso- and macroscales under cyclic loading. Conditions under which a steady pattern forms are found based on the analysis of kinetic equations. The number of bands in the steady pattern is found to be related to the strain rate. The process activation energy is determined.


Introduction
Investigations into cyclic deformation of pure fcc metals play an important role in elucidating the fundamental laws of fatigue fracture initiation and propagation in metals [1][2][3]. These investigations proceed in the three interrelated directions: the cyclic stress-strain (CSS) curves, evolution of dislocation structures, and surface slip morphology [1][2][3]. The best-studied crystals are copper, nickel, and silver [1]. It can be noted, that in most cases, cyclic deformation is subjected to a qualitative study because the quantitative characterization poses methodological difficulties.
At present, the cyclic deformations of single crystals of silver, copper, and nickel with low, average, and high stacking fault energy are best understood. The CSS curves for the single slip-oriented crystals at the controlled plastic strain amplitude in the range ∆ε~(10 −4 -10 −2 ) have a plateau after the stage of primary cyclic hardening. This plateau corresponds to the formation of ladder-like Persistent Slip Bands (PSBs), whose fractions grow due to a decrease in the fraction of the surrounding matrix [1][2][3]. The observed regularities can be described quantitatively within the two-phase model [4]. PSBs on the crystal surface are the sites of extrusions and intrusions as well as fatigue crack initiation [2].
Cyclic deformation of Cu, Ni, and Ag crystals oriented for double and multiple slip at the controlled plastic strain amplitude is characterized by a higher primary hardening rate than that of the single slip-oriented crystals. As the plastic strain amplitude grows, the CSS curve can have either an extended plateau, a short plateau, or a continuous increase without a plateau and saturation depending on the single crystal orientation [5][6][7][8]. PSB ladder-like structures are usually parallel to active slip systems, but PSB ladders can correspond to secondary slip systems at higher plastic strain amplitude [9]. At γ pl > 2.5·10 −3 , type-I and type-II deformation bands appear on the specimen due to accommodation of the rotational deformation mode [8]. Therefore, crystals with double and multiple slip orientation have more diverse cyclic response curves, dislocation structures, and surface slip morphologies as compared to single slip-oriented crystals.
According to the study of the temperature effect on the cyclic deformation of differently oriented copper single crystals, a lower test temperature leads to an increase in saturation stress and a systematic decrease in the PSB wall period [10,11]. It was shown [2] that the saturation stress under cyclic deformation corresponds to the flow stress at the stage of parabolic hardening for copper single crystals. The investigation of the PSB cross sections and shapes of the corresponding extrusions and intrusions on the specimen surface reveals their dependence on the temperature [11,12].
The behavior of aluminum single crystals under cyclic deformation, whose stacking fault energy is the highest of fcc crystals, differs strongly from that of copper, nickel, and silver crystals [13][14][15][16]. Differences appear in CSS curves, dislocation ordering, and surface morphology. CSS curves for aluminum single crystals under room temperature cyclic deformation have no plateau at any controlled plastic strain amplitude [14]. It is replaced by the "primary cyclic hardening-softening-secondary cyclic hardening" sequence [14]. PSB ladders typical of copper, nickel, and silver are not observed on cyclically-deformed aluminum single crystals at room temperature, and dislocation ordering has mainly a cellular structure regardless of orientation [13,16].
The slip band pattern in aluminum has important differences from that in copper, nickel, and silver: PSBs do not propagate through the crystal cross section, but small PSB segments are clustered on the active slip plane [13].
Under cyclic deformation of aluminum single crystals with the [001] orientation, a specific structure is formed on the crystal surface, which appears as a regular network of fine lines in the optical microscope and is referred to as a tweed structure [14]. According to the detailed study [15], this structure presents spherical protrusions on the aluminum surface, which are formed by diagonal lines at an angle of 45 • to the loading axis and whose characteristics are independent of the controlled plastic strain amplitude and the number of cycles. The authors of [15] pointed to an important feature of the fracture of specimens: "Most of the runs had to be terminated due to a collapse of the crystals and corresponding break-down of the control over the plastic strain amplitude. Fatigue failure in the traditional meaning in which cracks are formed and one of these grows to a size that lead to the ultimate failure was not observed".
A similar structure was also observed on polycrystalline pure aluminum foils glued to flat specimens of high-strength aluminum alloy under cyclical deformation at room temperature [17] and 77 K [18]. The tweed structure can be observed in some bulk polycrystalline aluminum grains [19].
The dislocation structure of aluminum single crystals and polycrystals after cyclic deformation was studied in a number of works to establish a direct correlation between the tweed structure on the surface and the underlying dislocation structure [15,18]. According to [15], at the stage of cyclic softening and secondary cyclic hardening, when the cord and tweed structures form on foils cut parallel to the surface, there appear dislocation walls (001). In some areas they form simultaneously, resulting in a labyrinth-like structure. Similar wall structures, predominantly with the single set of {100} walls, were observed in polycrystalline aluminum foils after cyclic deformation at the temperature 77 K [18].
The formation of wall structures in fatigued FCC metals is fully explained by the (double pseudo-polygonization) model proposed in [20]. The model predicts the highest probability of (001) walls for [001] single crystals and the equal probabilities of (100) and (010) walls. In accordance with the model, the (001) walls can accommodate all eight slip systems activated under high-symmetry loading of a single crystal. The remaining {100} walls can accommodate only dipole loops in the four expected slip systems.
The study of foils cut from the inner regions of crystals [15] showed that, at the stage of secondary cyclic hardening, an ordered system of spherical dislocation subcells with a low density of dislocations in them is formed on the (001) dislocation walls. This indicates an increase in the dislocation density in the walls at the stage of secondary cyclic hardening and the formation of subcells at a critical level [15].
From the analysis it was found [16] that {100} dislocation wall structures observed on foils cut from different crystallographic sections correspond to a series of weak lines on the specimen surface, parallel and perpendicular to the tension axis. However, the correspondence between the dislocation structure of the walls and the tweed structure on the surface remains unclear [15].
According to [18], the tweed structure formation depends on the presence of a significant number of dislocations with four distinct Burgers vectors, which requires a tension axis close to [001]. To investigate the dislocation structure in relation to surface deformation features, one side of the foils was electropolished [18]. Based on the analysis of the investigation results, the tweed structure is suggested to form as a result of the extrusion process [18], in which the material surrounding the tweed structure protrusions is relatively soft. Thus, the analysis of the literature data on the relationship between the tweed structure on the aluminum crystal surface and the underlying dislocation structure shows that this issue remains open and requires further investigation.
The study of the temperature effect on the cyclic deformation of aluminum single crystals showed that a decrease in the test temperature to 77 K increases the saturation stress and results in a plateau in the CSS curves [14]. The dislocation structure formed at 77 K was similar to the two-phase structure formed in single slip-oriented copper under cyclic deformation, though no ladder-like structure was observed in this case [14].
The independence of the tweed structure period on the controlled plastic strain and the number of cycles [15] allows for a quantitative study of the temperature effect on the cyclic deformation of aluminum single crystals.
The aim of this work is to study the effect of temperature on the tweed structure formation during constrained cyclic tension of [001]-oriented single-crystal Al foils and to develop a theoretical model of macroscopic deformation and pattern formation.

Materials and Methods
As a substrate, we used specimens of grade D1 duralumin in the form of dumbbells with the gauge section 60 mm × 10 mm × 2 mm. Duralumin specimens were mechanically polished using pastes of different dispersion. Foils were prepared from plates measuring 16 mm × 20 mm × 0.5 mm, which were cut from an Al single crystal with orientation (100)[001] by the electroerosive method. Both sides of the plates were mechanically polished to a thickness of about 250-270 microns on polishing paper with a gradual decrease in the grain size of the abrasive to 3-5 microns, and then electrochemically polished in 74 mL N 2 SO 4 , 74 mL H 3 PO 4 , 16 g CrO 3 , 56 mL H 2 O electrolyte up to the thickness 200 µm. The foils were glued to the central part of the duralumin specimen surface using Loctite 480 glue.
Duralumin specimens were tested for low-cycle fatigue at the temperatures 233, 263, 296, 313, 333, and 363 K with the following parameters: frequency f = 5 Hz, σ max = 165 MPa, σ min = 0.1σ max , and σ mean = (σ max − σ min )/2. Loading was performed using a UTM150 servohydraulic testing machine (BISS (P) Ltd.) with a PAC-70-B-EUR-RRU-INT climatic chamber (CM Envirosystems (P) Ltd.). In the first 10 cycles at 1 Hz, the stress amplitude was elevated gradually from 0 to 165 MPa. Then, the frequency was brought to 5 Hz. The number of test cycles N = 5000 was the same for all specimens. After testing, the specimens were removed from the testing machine and the surface of single-crystal Al foils was examined through an Axiovert 25CA optical microscope.

Results
The surface of single-crystalline aluminum foils after cyclic tension demonstrates a tweed structure, which was earlier observed on foils [17] and bulk specimens [15] of (100)[001]-oriented aluminum single crystals at room temperature. This pattern appears on single-crystalline aluminum foils soon after the onset of cyclic deformation without visible slip lines, which conforms to the previous studies of cyclic deformation of bulk specimens and foils of aluminum single crystals [15,17]. The formation of a pattern on the foils is accompanied by the appearance of an interference shade, visible through the window of the climatic chamber [17]. The visible interference shade is used to estimate the formation time of the tweed structure t. The time varies from t 1 = (600 ± 60) s in cyclic tests at T 1 = 233 K to t 2 = (200 ± 30) s at the temperature T 2 = 363 K. Figure 1 exemplifies optical images of the tweed structure formed at the temperatures T = 233, 296, and 363 K. It can be seen that an increase in the test temperature leads to a noticeable increase in the tweed structure period. specimens and foils of aluminum single crystals [15,17]. The formation of a pattern on the foils is accompanied by the appearance of an interference shade, visible through the window of the climatic chamber [17]. The visible interference shade is used to estimate the formation time of the tweed structure t. The time varies from = (600 ± 60) s in cyclic tests at = 233 K to = (200 ± 30) s at the temperature T2 = 363 K. Figure 1 exemplifies optical images of the tweed structure formed at the temperatures T = 233, 296, and 363 K. It can be seen that an increase in the test temperature leads to a noticeable increase in the tweed structure period. To obtain quantitative information, optical images of the tweed structure are statistically processed and histograms are constructed for each test temperature. Figure 2 shows histograms for the temperatures 233, 296, and 363K. From the histograms, it can be seen that the average period of the tweed structure increases with increasing temperature. This indicates that the tweed structure formation during cyclic tension is a thermally-activated process. From the tweed structure period histograms, follow the average period (R) and the standard deviation ΔR for each test temperature. The average period of the tweed structure on the interval ΔТ = (233 ÷ 363) K increases from = (1.92 0.12) µm to = (3.03 0.15) µm, i.e., by almost 50%. Figure 3 plots the dependence of ln ( ) on 1/T, which approximates well to a straight line.  To obtain quantitative information, optical images of the tweed structure are statistically processed and histograms are constructed for each test temperature. Figure 2 shows histograms for the temperatures 233, 296, and 363K. From the histograms, it can be seen that the average period of the tweed structure increases with increasing temperature. This indicates that the tweed structure formation during cyclic tension is a thermally-activated process. From the tweed structure period histograms, follow the average period (R) and the standard deviation ∆R for each test temperature. The average period of the tweed structure on the interval ∆T = (233 ÷ 363) K increases from R 1 = (1.92 ± 0.12) µm to R 2 = (3.03 ± 0.15) µm, i.e., by almost 50%. Figure 3 plots the dependence of ln R R 1 on 1/T, which approximates well to a straight line. This indicates that thermally-activated processes of structural relaxation determine the tweed structure formation on single-crystalline aluminum foils under cyclic tension. specimens and foils of aluminum single crystals [15,17]. The formation of a pattern on the foils is accompanied by the appearance of an interference shade, visible through the window of the climatic chamber [17]. The visible interference shade is used to estimate the formation time of the tweed structure t. The time varies from = (600 ± 60) s in cyclic tests at = 233 K to = (200 ± 30) s at the temperature T2 = 363 K. Figure 1 exemplifies optical images of the tweed structure formed at the temperatures T = 233, 296, and 363 K. It can be seen that an increase in the test temperature leads to a noticeable increase in the tweed structure period. To obtain quantitative information, optical images of the tweed structure are statistically processed and histograms are constructed for each test temperature. Figure 2 shows histograms for the temperatures 233, 296, and 363K. From the histograms, it can be seen that the average period of the tweed structure increases with increasing temperature. This indicates that the tweed structure formation during cyclic tension is a thermally-activated process. From the tweed structure period histograms, follow the average period (R) and the standard deviation ΔR for each test temperature. The average period of the tweed structure on the interval ΔТ = (233 ÷ 363) K increases from = (1.92 0.12) µm to = (3.03 0.15) µm, i.e., by almost 50%. Figure 3 plots the dependence of ln ( ) on 1/T, which approximates well to a straight line.
(a) (b) (с)   This indicates that thermally-activated processes of structural relaxation determine the tweed structure formation on single-crystalline aluminum foils under cyclic tension.

Cyclic-Induced Pattern Formation Model
Let us now dwell on factors determining plastic deformation localization and conditions under which the periodic pattern forms. Dislocation mechanisms of plastic deformation of aluminum at the stage of parabolic hardening due to double cross slip of dislocations are known. However, dislocation mechanisms alone are inadequate to describe macroscopic deformation. There are two reasons for this. First, consideration should be given not only to dislocations, as stated above, but also to point defects. Second, structural relaxation of the system under plastic deformation is determined by the nucleation and interaction of deformation carriers on all spatial and time scales. However, not only direct solutions but also the writing of dynamic equations is hardly possible for deformation carriers. Other approaches are required to take into account the relaxation processes on large spatial and time scales. A phenomenological approach was proposed to solve the problem [21]. This approach can be used to study the regularities of nucleation and propagation of localized deformation bands in the form of traveling fronts at the stage of easy slip and linear hardening. In this work, the developed approach and the macroscopic deformation model are applied towards the solution of the pattern formation problem during the cyclic tension of foils of aluminum single crystals with cubic orientation.
We study the deformation of a flat specimen, which is cyclically extended to ( ) along axis x with frequency f under applied stress σ. The specimen plane lies in the plane z = 0 of the Cartesian coordinate system x,y,z. A medium under deformation is assumed to be homogeneous and isotropic. The one-dimensional case is considered.
Plastic deformation is a process of structural relaxation determined by the nucleation and motion of deformation carriers under an external force on all spatial and time scales ( is the scale number). By the scale, we mean the unstable-mode wavelength ~ with the frequency ~ of correlated displacements of inelastic deformation carriers.
Structural relaxation of a deformed medium on larger scales is determined by processes on smaller scales. Consideration is given to two spatial and time scales: < , < . In the experiments, we measure the displacement distribution related to the long-wave mode on the scale ~1 μm. The short-wave mode is determined by displacements on scales less than .
According to [21], structural changes in a deformed medium can be described by dynamic order parameters ( , ) and η( , ). These functions have the meaning of a volume fraction with structural changes leading to the excitation and development of two deformation modes on scales and , respectively. Local plastic strain in the linear approximation is written in the form

Cyclic-Induced Pattern Formation Model
Let us now dwell on factors determining plastic deformation localization and conditions under which the periodic pattern forms. Dislocation mechanisms of plastic deformation of aluminum at the stage of parabolic hardening due to double cross slip of dislocations are known. However, dislocation mechanisms alone are inadequate to describe macroscopic deformation. There are two reasons for this. First, consideration should be given not only to dislocations, as stated above, but also to point defects. Second, structural relaxation of the system under plastic deformation is determined by the nucleation and interaction of deformation carriers on all spatial and time scales. However, not only direct solutions but also the writing of dynamic equations is hardly possible for deformation carriers. Other approaches are required to take into account the relaxation processes on large spatial and time scales. A phenomenological approach was proposed to solve the problem [21]. This approach can be used to study the regularities of nucleation and propagation of localized deformation bands in the form of traveling fronts at the stage of easy slip and linear hardening. In this work, the developed approach and the macroscopic deformation model are applied towards the solution of the pattern formation problem during the cyclic tension of foils of aluminum single crystals with cubic orientation.
We study the deformation of a flat specimen, which is cyclically extended to ε(t) along axis x with frequency f under applied stress σ. The specimen plane lies in the plane z = 0 of the Cartesian coordinate system x,y,z. A medium under deformation is assumed to be homogeneous and isotropic. The one-dimensional case is considered.
Plastic deformation is a process of structural relaxation determined by the nucleation and motion of deformation carriers under an external force on all spatial l i and time t scales (i is the scale number). By the scale, we mean the unstable-mode wavelength λ i ∼ l i with the frequency ω i ∼ 1 t i of correlated displacements of inelastic deformation carriers. Structural relaxation of a deformed medium on larger scales is determined by processes on smaller scales. Consideration is given to two spatial and time scales: In the experiments, we measure the displacement distribution related to the long-wave mode on the scale l 2 ∼ 1 µm. The short-wave mode is determined by displacements on scales less than l 1 .
According to [21], structural changes in a deformed medium can be described by dynamic order parameters ϕ(x, t) and η(x, t). These functions have the meaning of a volume fraction with structural changes leading to the excitation and development of two deformation modes on scales l 1 and l 2 , respectively. Local plastic strain in the linear approximation is written in the form Here, ε S , ε L are the parameters determined by the mechanisms and conditions of the medium deformation on the scales l 1 , l 2 , respectively. Deformation modes at which appear in experiments. Here, angular brackets stand for averaging over the specimen length. At each time instant, deformation modes that decrease the elastic energy of the system are excited and develop. Kinetic equations for ϕ and η have the form [22] Here, α, g, q 2 , q 3 , b, p are the parameters determined by plastic deformation carriers. The parameter α depends on the applied load (elastic strain ε el ) and may alternate in signs, the rest of the parameters are positive. The quantity r = ε c −ε el ε c > 0 is the dimensionless threshold of stability of the medium at ϕ = 0. The deformation carrier nucleation (ϕ > 0) lowers the stability threshold of the system and initiates structural relaxation of the medium on larger scales. When the temperature rises, r for aluminum decreases.
By introducing the variables Equations (3) and (4) can be reduced to (the sign "∼" is further omitted) Here The system of two coupled nonlinear parabolic Equations (6) and (7) describes structural relaxation of a deformed medium on two spatial and time scales. The governing parameter in these equations is elastic strain. Let us explain the physical meaning of Equations (6) and (7). At ϕ = 0, Equation (6) has a unique stable homogeneous solution η 0 = η = 0, which describes elastic deformation of the medium. Plastic strain is determined by a change in the internal structure on a smaller scale, which occurs at ϕ > 0. The parameter d in (6) depends on the strain rate . ε of the specimen: d increases with an increase in . ε. Equation (7) describes the structural changes on smaller scales, which are determined by the nucleation and development of ensembles of interacting carriers of irreversible deformation. At η = 0, E (7) has two homogeneous stationary solutions ϕ 0 = ϕ = 0 . The solution ϕ 0 describes the elastically deformed state of the medium. The solution ϕ h describes the state of the medium with structural changes. It is stable at α > −2β 2 /9. With consideration for the stress dependence of the parameters α and β, the ratio −2 β 2 9 = α gives the threshold stress above which irreversible displacements are excited in the medium. At α > 0, the solution ϕ 0 is unstable to small heterogeneous perturbations. The pattern formation is preceded by a uniform deformation. Therefore, the parameter α > 0. The presence of the term −cηϕ on the right side of (7) means that mesoscopic plastic deformation is accompanied by an increase in the elastic energy of the system.
Equations (6) and (7) always have a homogeneous stationary solution η 0 = η = 0, ϕ 0 = ϕ = 0. Stationary homogeneous solutions ϕ h > 0, η h > 0 present the intersection points of the curves η = (−1 + dϕ) 1/2 (9) The analysis of the solutions of these equations and their stability to small perturbations shows the following. Stationary solutions ϕ h > 0, η h > 0 can be unstable to small heterogeneous perturbations at At d = d c , curve (9) intersects curve (10) at its maximum point ϕ = ϕ m = β/2. From (11), it can be seen that increasing c reduces d c and contributes to deformation localization. Instability to small heterogeneous perturbations develops when the inequalities are valid. Here With Equation (13), the third inequality in (12) reduces to the condition v η > v ϕ . The second inequality in (12) means that deformation carriers should be in short-range interaction with each other and have a shorter characteristic time of excitation. This explains the fact that structural relaxation at the stage of parabolic hardening is determined by double cross slip of dislocations and the generation of point defects. However, the physical aspect of its influence on macrodeformation localization is poorly understood within the theory of defects.

Discussion
Solutions to Equations (6) and (7) describing the periodic pattern formation are analyzed by numerical methods for the one-dimensional case. The initial and boundary conditions are given in Appendix A. The analysis of the numerical solutions shows that the pattern of spatial structures is almost completely determined by l 2 in (6) and l in (13). On higher l 2 at a constant value l, the spacing between localized deformation bands increases. As an example, Figures 4 and 5 show the spatial distributions of the dynamic order parameters at α = 0.03, β = 0.8, d = 10, l 1 /l 2 = 0.05, τ = 0.8 c = 0.4 (14) and on different l 2 . At the parameters used in (14), η h ≈ 0.26, ϕ h ≈ 0.11, d c ≈ 3.1. The distribution of the dynamic order parameters calculated for l 2 = 1.4 is shown in Figure 4.     As indicated above, the spacing between localized deformation bands is almost completely determined by the value ~1/ / in (6). The higher is, the greater R is. This means that the r value should decrease as the temperature rises. The linear dependence ln ( )~-1/T ( Figure 3) means that ( / )~− 1/T, i.e., the dimensionless threshold of stability decreases with increasing temperature, which is in qualitative agreement with the experimental data.
Plastic deformation is a thermally-activated process. Let us express strain rates at the temperatures T , T as (T )~exp (− ), (T )~exp (− ), respectively. Here, E is the activation energy at the stage of uniform deformation (preceding the instability), and k is the Boltzmann constant. Under cyclic tension, the strain of the specimen remains constant. Then the equality holds. The activation energy found from (15) equals ≈ 0.07 eV. This value is lower than the migration activation enthalpy of interstitial atoms in aluminum ≈ 0.12 eV [22]. At the same time, E is higher than the activation energy of dislocation slip. It should be noted that no model underlies the estimate of the activation energy, but it stems from the analysis of kinetic equations of the formation of a stationary pattern and the relationship between the strain rate and the number of bands. The analysis of results based on the Einstein diffusion model [23] gave the migration activation energy of interstitial aluminum atoms ≈ 0.12 eV.
The results obtained show that the tweed structure formation on single-crystalline Al foils under cyclic tension in the temperature range ΔТ = (233 ÷ 363) K is controlled by the It can be seen that plastic deformation is nonuniformly distributed along the specimen length. Nine equally spaced striations are formed. In so doing, ϕ ≈ ϕ h , η ≈ 0.31 > η h . On l 2 = 2.1, six localized deformation bands are formed ( Figure 5), as in Figure 4, ϕ ≈ ϕ h , η ≈ 0.31 > η h . With increasing temperature, the parameter r decreases, and l 2 , according to (5), increases. Therefore, the band spacing increases with temperature, which agrees with the experiment.
As indicated above, the spacing between localized deformation bands is almost completely determined by the value l 2 ∼ 1/r 1/2 in (6). The higher l 2 is, the greater R is. This means that the r value should decrease as the temperature rises. The linear dependence ln R R 1 ∼ −1/T (Figure 3) means that n(r 1 /r 2 ) ∼ −1/T, i.e., the dimensionless threshold of stability decreases with increasing temperature, which is in qualitative agreement with the experimental data.
Plastic deformation is a thermally-activated process. Let us express strain rates at the temperatures T 1 , T 2 as .
, respectively. Here, E is the activation energy at the stage of uniform deformation (preceding the instability), and k is the Boltzmann constant. Under cyclic tension, the strain of the specimen remains constant. Then the equality t 1 .
holds. The activation energy found from (15) equals E ≈ 0.07 eV. This value is lower than the migration activation enthalpy of interstitial atoms in aluminum E i m ≈ 0.12 eV [22]. At the same time, E is higher than the activation energy of dislocation slip. It should be noted that no model underlies the estimate of the activation energy, but it stems from the analysis of kinetic equations of the formation of a stationary pattern and the relationship between the strain rate and the number of bands. The analysis of results based on the Einstein diffusion model [23] gave the migration activation energy of interstitial aluminum atoms E i m ≈ 0.12 eV.
The results obtained show that the tweed structure formation on single-crystalline Al foils under cyclic tension in the temperature range ∆T = (233 ÷ 363) K is controlled by the slowest process, i.e., migration of interstitial atoms. This is an unexpected result since a small number of interstitial atoms (as compared to vacancies) form in fcc metals due to the much higher energy of formation, and the probability of their annihilation is high. In addition, interstitial atoms have low migration activation energy and high mobility. Therefore, they are thought to be completely annealed at temperatures of several tens of Kelvin.
The above arguments are very weighty, and an increase in the role of interstitial atoms within point defect kinetics remains currently unexplained. The role of point defects in mass redistribution and surface relief formation during cyclic deformation and solidification of