Inﬂuence of High-Concentration LLDPE on the Manufacturing Process and Morphology of Pitch/LLDPE Fibres

: A high modulus of elasticity is a distinctive feature of carbon ﬁbres produced from mesophase pitch. In this work, we expand our previous study of pitch/linear low-density polyethylene blend ﬁbres, increasing the concentration of the linear low-density polyethylene in the blend into the range of from 30 to 90 wt%. A scanning electron microscope study showed two distinct phases in the ﬁbres: one linear low-density polyethylene, and the other pitch ﬁbre. Unique morphologies of the blend were observed. They ranged from continuous microﬁbres of pitch embedded in linear low-density polyethylene (occurring at high concentrations of pitch) to a discontinuous region showing the presence of spherical pitch nodules (at high concentrations of linear low-density polyethylene). The corresponding mechanical properties—such as tensile strength, tensile modulus, and strain at failure—of different concentrations of linear low-density polyethylene in the pitch ﬁbre were measured and are reported here. Thermogravimetric analysis was used to investigate how the increased linear low-density polyethylene content affected the thermal stability of linear low-density polyethylene/pitch ﬁbres. It is shown that selecting appropriate linear low-density polyethylene concentrations is required, depending on the requirement of thermal stability and mechanical properties of the ﬁbres. Our study offers new and useful guidance to the scientiﬁc community to help select the appropriate combinations of linear low-density polyethylene/pitch blend concentrations based on the required mechanical property and thermal stability of the ﬁbres. the ranging from of in of (at concentration of LLDPE) see Graphical Abstract. It considers factors affecting the chemical composition of the pitch mesophase dispersed in a matrix of LLDPE on the tensile strength and tensile modulus, and its correlation with the structural morphology of the pitch/LLDPE composite.


Introduction
There is an increasing need for polymer materials with improved properties to meet modern requirements since no single polymer has all desired properties [1]. Most polymer blends are prepared by melting [2] and polymer blending, with the fibres produced by a melt compound extruder. This is an economic and useful method of manufacturing new materials with advantageous properties [3][4][5][6][7]. To investigate how this can be improved, one must understand how the morphology of the obtained fibre is formed, changed, and controlled during the extrusion or mixing process, or with the help of mixing material ratios. An important and novel aspect of this research is that it completes the definition of the mechanical and thermal properties of LLDPE/MP blends for the complete range of mixes.
Carbon fibres (CFs) with manmade rayon as precursor had been created by 1960 [8,9], and by 1963, carbon fibres with a high elastic modulus were being manufactured from pitch [10]. Due to superior mechanical, electrical, and thermal features, CFs are extensively employed in numerous applications, ranging from space exploration to healthcare. However, their industrial application would greatly increase if they could be manufactured at a  Aldosari et al., (2020) have reviewed the possibility of achieving these desired objectives and showed that, despite relevant research being at an early stage, they could be achieved by using a PE/pitch blend to produce CF precursors with improved ductility [11]. In our previous work, we showed the feasibility of mixing LLDPE/pitch as a possible precursor for the manufacture of CFs [39]. That work was limited to a narrow LLDPE/MP range, from 0 to 20 wt% LLDPE, with a corresponding range from 100 to 80 wt% MP. In this paper, we have expanded our previous study into a more comprehensive investigation of LLDPE/MP blend fibres, extending the range investigated to between 30 and 90 wt% LLDPE in 10 wt% increments. This extended study allows us to better compare the variations introduced into the manufacturing process and the corresponding changes in mechanical properties and thermal stability of the fibres over the complete range of LLDPE in LLDPE/MP blend fibres from 0 to 90 wt%. This allows us to select the best possible LLDPE/MP blend. The optimum precursor fibre can potentially overcome the issue of the high level of the brittleness of pitch fibres for future high-performance CF manufacturing. As this research is a direct continuation of our previously published work, the same equipment was used and the reader may refer to [39] for details.
This work studies the effect of the LLDPE content of the blend on its morphology, ranging from continuous microfibres of pitch contained in LLDPE (at high concentrations of pitch) to discontinuous spheres of pitch (at high concentration of LLDPE) see Graphical Abstract. It considers factors affecting the chemical composition of the pitch mesophase dispersed in a matrix of LLDPE on the tensile strength and tensile modulus, and its correlation with the structural morphology of the pitch/LLDPE composite.

Materials
In this study, the MP precursor was purchased from Bonding Chemical. Its softening point was 268 • C, melting point 298 • C, and density 1.425 g/cm 3 . The mesophase content was 92%. The LLDPE was bought from Sabic, Saudi Arabia; it had a softening point of 99 • C, a melting point of 121 • C, and a density of 0.918 g/cm 3 .

Materials Processing
A Noztek Pro Filament single-screw melt fibre spinning extruder was used. Details of this and the fibre collection are given in our previous paper [35]. The nozzle was 0.5 mm in diameter and 1.5 mm in length. The extruder was set to 315 • C and at a 2.5 m/min extrusion speed, with the stretching speed set to 2.5 m/min. To obtain different fibre blends, pitch and PE were fed into the extruder in different ratios. The manufacturing processing stages are shown in Figure 1. The sample designation for the different proportions is LLDPE (x) wt% and MP (100-x) wt%. Figure 2 is a diagrammatic representation of cold stretching.

Microscopy: Optical and SEM
Optical microscopy: fibre diameter was measured via a Nikon ECLIPSE ME600 at 20× magnification. Nomarski microscopy was used to enhance sample contrast and determine the diameter of the fibres.
The SEM used to examine the prepared specimens was a Tescan VEGA3 and associated Aztec software. Before the measurements were made, a thin gold layer was sputtercoated onto the specimens. The specimens were cut into 50 mm lengths. The specimens

Microscopy: Optical and SEM
Optical microscopy: fibre diameter was measured via a Nikon ECLIPSE ME600 at 20× magnification. Nomarski microscopy was used to enhance sample contrast and determine the diameter of the fibres.
The SEM used to examine the prepared specimens was a Tescan VEGA3 and associated Aztec software. Before the measurements were made, a thin gold layer was sputtercoated onto the specimens. The specimens were cut into 50 mm lengths. The specimens

Microscopy: Optical and SEM
Optical microscopy: fibre diameter was measured via a Nikon ECLIPSE ME600 at 20× magnification. Nomarski microscopy was used to enhance sample contrast and determine the diameter of the fibres.
The SEM used to examine the prepared specimens was a Tescan VEGA3 and associated Aztec software. Before the measurements were made, a thin gold layer was sputtercoated onto the specimens. The specimens were cut into 50 mm lengths. The specimens were mounted end-on for the vertical image and for surface features laid horizontally on aluminium stubs, for more details see [39].

Tensile Mechanical Test
Tensile measurements on the spun MP/PE fibres were made in accordance with Standard ISO 11566-1996, Figure A1 [40] with a DEBEN Microtest fibre tensile tester connected to a Leica EC4 Microscope; see Figure A1 in Appendix A. We placed a single filament over the centre of the slot and temporarily fixed one end of specimen, mounting it with adhesive tape, and lightly stretched the specimen across the slot, then fixed the other end of the specimen to other ends of the mounting with adhesive tape, and then bound the specimen to the mounting by applying a drop of adhesive. Each sample was subjected to six tests to confirm repeatability.

Differential Scanning Calorimetry (DSC)
A Mettler Toledo DSCQ2000 was used for the DSC measurements. Specimens were heated from 0 to 200 • C at 20 • C/min in an inert environment. The sample was then kept at a higher temperature for 200 s to eliminate any prior thermal history. The non-isothermal behaviour and kinetics of the samples were studied by cooling them at 20 • C/min after completing the heating and cooling cycles.

Thermogravimetric Analysis
For the prepared specimens, a Mettler Toledo Thermogravimetric Analyser TGAQ500 was used for the TGA analysis. Under a nitrogen environment, the specimens were heated from 50 to 800 • C at 20 • C/min, after which the specimens were kept at 800 • C for 300 s to remove any preceding thermal history.

Optical Microscopy
Optical microscopy was used to study the morphology of the blend's fibres. The diameter of the sample fibres depended upon the wt% LLDPE, decreasing as the LLDPE content increased, see Table 1 and Figure 3.
All other factors remaining constant, we observed shrinkage in the diameter of the fibres with increased LLPDE wt% due to the greater axial elongation obtained by the same applied axial force; see Figure 2. The morphology of the blend changed with LLDPE wt% [41].
Many parameters influence the diameter of the extruded fibres, including the diameter of the die orifice, extrusion speed, and polymer viscosity. Figure 3 shows the optical images obtained for cold-drawn specimens using an optical microscope. Figure 3 also shows that different fibre diameters were obtained by reducing or increasing the LLDPE content.  All other factors remaining constant, we observed shrinkage in the diameter of the fibres with increased LLPDE wt% due to the greater axial elongation obtained by the same applied axial force; see Figure 2. The morphology of the blend changed with LLDPE wt% [41].
Many parameters influence the diameter of the extruded fibres, including the diameter of the die orifice, extrusion speed, and polymer viscosity. Figure 3 shows the optical images obtained for cold-drawn specimens using an optical microscope. Figure 3 also shows that different fibre diameters were obtained by reducing or increasing the LLDPE content.

SEM of Fibres
Pitch fibres tend to generate microfibrils within their fibres, as shown in the SEM images [42]; also see Figure 4i-viii, and Figure A2 for LLDPE/MP blends in the range of between 30 and 100 wt% of LLDPE. The MP molecules show a strong preference to align themselves with the longitudinal fibre axis, and this process has a tendency to begin in the liquid crystalline phase [11]. This could be the reason for micro-fibre development in our samples. As the LLDPE wt% content of the LLDPE/MP fibres increased to about 60%, the development of microfibres inside the blend was significantly reduced; see Figure  4iii,iv.
It was observed from the results that the fibrous pitch/LLDPE domains were due to the continuously increasing elongational force along the spinning line, and they gradually extended from spheres into long continuous nanofibrillar formations ( Figure 2). The creation of fibrillar structures is necessary to improve the mechanical properties of polymer blend fibres [43,44]. The PE does not form the liquid crystal phase, so when PE is added to the pitch, it reduces the microfibre content. With a high LLDPE content, e.g., 70 wt% LLDPE (Figure 4v With immiscible polymer blends, the morphology of the dispersed phase is crucial in determining its physical properties [45]. As a result, we deduced that increasing the wt% LLDPE in a blend substantially affects the morphology of the fibre. It was observed from the results that the extruder rotation rate affected morphology by changing the polymer dwell time in the extruder [46]. It is widely known that the performance and prop-

SEM of Fibres
Pitch fibres tend to generate microfibrils within their fibres, as shown in the SEM images [42]; also see Figure 4i-viii, and Figure A2 for LLDPE/MP blends in the range of between 30 and 100 wt% of LLDPE. The MP molecules show a strong preference to align themselves with the longitudinal fibre axis, and this process has a tendency to begin in the liquid crystalline phase [11]. This could be the reason for micro-fibre development in our samples. As the LLDPE wt% content of the LLDPE/MP fibres increased to about 60%, the development of microfibres inside the blend was significantly reduced; see Figure 4iii,iv.
It was observed from the results that the fibrous pitch/LLDPE domains were due to the continuously increasing elongational force along the spinning line, and they gradually extended from spheres into long continuous nanofibrillar formations ( Figure 2). The creation of fibrillar structures is necessary to improve the mechanical properties of polymer blend fibres [43,44]. The PE does not form the liquid crystal phase, so when PE is added to the pitch, it reduces the microfibre content. With a high LLDPE content, e.g., 70 wt% LLDPE ( Figure  With immiscible polymer blends, the morphology of the dispersed phase is crucial in determining its physical properties [45]. As a result, we deduced that increasing the wt% LLDPE in a blend substantially affects the morphology of the fibre. It was observed from the results that the extruder rotation rate affected morphology by changing the polymer dwell time in the extruder [46]. It is widely known that the performance and properties of polymer blends are directly related to the morphology of the pitch/LLDPE polymer blends [47], so the size, shape, and orientation of the phases can be used to characterise the morphology of pitch/LLDPE polymer blends. A major problem in the development of polymer blends is how to influence morphology. Here, we have shown that viscoelastic drop deformation is essentially a problem of coalescence and breakup. Many investigations on the blending of polymer process assumed Newtonian fluid systems using, for example, Taylor's minor deformation theory or Grace's breakup curve [46]. However, the Newtonian fluids theories were shown to be inapplicable for polymer blending, which is not surprising [48,49].
ise the morphology of pitch/LLDPE polymer blends. A major problem in the development of polymer blends is how to influence morphology. Here, we have shown that viscoelastic drop deformation is essentially a problem of coalescence and breakup. Many investigations on the blending of polymer process assumed Newtonian fluid systems using, for example, Taylor's minor deformation theory or Grace's breakup curve [46]. However, the Newtonian fluids theories were shown to be inapplicable for polymer blending, which is not surprising [48,49].

Tensile Tests of Pitch Blends
LLDPE is widely used in many and various forms because it is cheap and flexible. One investigation has demonstrated that LLDPE's average tensile strength is around 6.1 MPa, and can be enhanced by the addition of fibre straws [50]. A second investigation claimed to have demonstrated that LLDPE can have a tensile strength as high as 9.9 MPa [51]. Others have claimed that, by adding multiple-walled carbon nanotubes, the tensile strength can rise to 22 MPa [52]. Enhanced values such as these suggest that the possible uses of LLDPE could be expanded if it is used in conjunction with other materials.
The stress limit of extruded neat LLDPE is typically about 40 MPa, and the typical strain will be about 0.8 which suggests that the LLDPE component in LLDPE/MP fibres has an important load-bearing role, and toughens the material [39]. Figure 5 shows that boosting the wt% LLDPE in relatively brittle LLDPE/MP fibres can be significant.
We also see in Figure 5 the stress vs. strain curves for LLDPE/MP blends for between 30 and 90 wt% LLDPE. Obviously, the stress vs. strain behaviour of the specimens is a function of wt% LLDPE. The maximum values of tensile strength and strain increase progressively with wt% LLDPE. The minimum tensile strength (13.84 MPa) and minimum

Tensile Tests of Pitch Blends
LLDPE is widely used in many and various forms because it is cheap and flexible. One investigation has demonstrated that LLDPE's average tensile strength is around 6.1 MPa, and can be enhanced by the addition of fibre straws [50]. A second investigation claimed to have demonstrated that LLDPE can have a tensile strength as high as 9.9 MPa [51]. Others have claimed that, by adding multiple-walled carbon nanotubes, the tensile strength can rise to 22 MPa [52]. Enhanced values such as these suggest that the possible uses of LLDPE could be expanded if it is used in conjunction with other materials.
The stress limit of extruded neat LLDPE is typically about 40 MPa, and the typical strain will be about 0.8 which suggests that the LLDPE component in LLDPE/MP fibres has an important load-bearing role, and toughens the material [39]. Figure 5 shows that boosting the wt% LLDPE in relatively brittle LLDPE/MP fibres can be significant. ulus, and strain to failure. It has been reported in previous work that different morphologies have different properties that can be used to satisfy different requirements. Controlling the final morphology requires a good understanding of how the mechanism of morphology develops in polymer blends, and would be beneficial when designing the processes and equipment to improve the required properties in batch mixers or extruders [4,53,54]. However, in the current study, the time of the extrusion process and the length of extruder does not change throughout the fabrication process.   We also see in Figure 5 the stress vs. strain curves for LLDPE/MP blends for between 30 and 90 wt% LLDPE. Obviously, the stress vs. strain behaviour of the specimens is a function of wt% LLDPE. The maximum values of tensile strength and strain increase progressively with wt% LLDPE. The minimum tensile strength (13.84 MPa) and minimum strain (30%), occurred with an LLDPE content of 30 wt%, while the maximum tensile strength (36.97 MPa) and maximum strain (68%) occurred with an LLDPE content of 90 wt%.
As in our previous paper [39], we identified being brittle with low strain to failure, and the pitch fibre samples demonstrated such brittle behaviour. Increasing the wt% LLDPE in the blend increased the strain to failure, which was taken to mean that increasing the proportion of LLDPE in the fibres decreased brittleness. The data gathered on tensile strength and modulus, and strain to failure of the LLDPE/MP fibres, are presented in Table 2. We see that the greater the wt% LLDPE, the larger the tensile strength and modulus, and strain to failure. It has been reported in previous work that different morphologies have different properties that can be used to satisfy different requirements. Controlling the final morphology requires a good understanding of how the mechanism of morphology develops in polymer blends, and would be beneficial when designing the processes and equipment to improve the required properties in batch mixers or extruders [4,53,54]. However, in the current study, the time of the extrusion process and the length of extruder does not change throughout the fabrication process.

DSC for LLDPE/Mesophase Pitch Blends
As reported by Aldosari et al. [39] (2021), DSC has been utilized to evaluate the crystallization of various blends of low-and high-density polyethylene (LDPE and HDPE) with LLDPE. Typically, crystallization temperature is reduced with the addition of LLDPE. This decrease can be credited to the high molar mass of LLDPE, which increases chain entanglements, making crystallization more challenging. Experimental data were analysed using least-squares and the rates of change of the thermograms calculated to provide the necessary kinetic data. The degradation rate of LDPE was found to be a second-order effect [55]. The thermal characteristics of LLDPE/MP blends within the range of between 30 and 90 wt% LLDPE, were explored using DSC.
The tests were performed for a range of fusion and crystallization temperatures of the LLDPE/MP blends, as determined by the wt% of the LLDPE.
In Figure 6a and Table 3, we see that all the plots have clear and well-ordered crystallization peaks, and the greater the wt% of LLDPE, the higher the value of the peak heat flow. We also observe that increasing the LLDPE content of the LLDPE/MP blend increases the enthalpy of crystallization. Figure 6a also demonstrates that, as the wt% of the LLDPE in the LLDPE/MP blend increases, the crystallisation temperature decreases. This confirms the crystallisation temperature of the blends depends on LLDPE content.

DSC for LLDPE/Mesophase Pitch Blends
As reported by Aldosari et al. [39] (2021), DSC has been utilized to evaluate the tallization of various blends of low-and high-density polyethylene (LDPE and H with LLDPE. Typically, crystallization temperature is reduced with the additi LLDPE. This decrease can be credited to the high molar mass of LLDPE, which incr chain entanglements, making crystallization more challenging.
Experimental data were analysed using least-squares and the rates of change thermograms calculated to provide the necessary kinetic data. The degradation r LDPE was found to be a second-order effect [55]. The thermal characteristi LLDPE/MP blends within the range of between 30 and 90 wt% LLDPE, were exp using DSC. The tests were performed for a range of fusion and crystallization tem tures of the LLDPE/MP blends, as determined by the wt% of the LLDPE.
In Figure 6a and Table 3, we see that all the plots have clear and well-ordered tallization peaks, and the greater the wt% of LLDPE, the higher the value of the peak flow. We also observe that increasing the LLDPE content of the LLDPE/MP blen creases the enthalpy of crystallization. Figure 6a also demonstrates that, as the wt% LLDPE in the LLDPE/MP blend increases, the crystallisation temperature decreases confirms the crystallisation temperature of the blends depends on LLDPE content. Figure 6b and Table 3 show that the temperature at which the blend melts, an corresponding enthalpy of the test samples, is a function of the wt% LLDPE i LLDPE/MP blend. The fusion temperature of the blend increases with LLDPE co Thus, for the range considered here, the maximum melting temperature is at 90 LLDPE. Correspondingly, the maximum enthalpy of fusion is also at 90 wt% LLDPE is because fewer crystalline spheres are present with the higher the percentage of LL in the blend [39]. These results confirm the wt% of LLDPE in LLDPE/MP blends influ both the melting and crystallisation behaviour of the blends.

Thermogravimetric Analysis of LLDPE/MP Blends
TGA is commonly used to evaluate a composite material's thermal stability. He was used to investigate the thermal decomposition of LLDPE/MP blends with diffe wt% of LLDPE burned in air. The higher the decomposition temperatures, the greate thermal stability [52,56].
TGA measures the proportion and/or quantity of the mass of a material that is tr formed, either as a function of temperature or isothermally, as a function of time. Th usually carried out in a regulated atmosphere [57]. TGA can be used to assess any stance that shows a change in weight when combusted, identifying phase changes du decomposition or oxidation [58]. Thermogravimetric analyses typically consist of a sp men pan supported by a precision scale [57]. These data are used to study the we change, the material's chemical structure, and decomposition [59].
The TGA was performed with temperatures between 100 and 800 °C. Therma composition for a range of LLDPE/MP blends was investigated, and the TGA curves tained are presented in Figure 7. Figure 7 presents the loss of mass as a function of perature for the test specimens. We see that the LLDPE/MP blend with 90 wt% LL has suffered severe decomposition at 540 °C with over 90% mass loss. However, the b   Figure 6b and Table 3 show that the temperature at which the blend melts, and the corresponding enthalpy of the test samples, is a function of the wt% LLDPE in the LLDPE/MP blend. The fusion temperature of the blend increases with LLDPE content. Thus, for the range considered here, the maximum melting temperature is at 90 wt% LLDPE. Correspondingly, the maximum enthalpy of fusion is also at 90 wt% LLDPE. This is because fewer crystalline spheres are present with the higher the percentage of LLDPE in the blend [39]. These results confirm the wt% of LLDPE in LLDPE/MP blends influences both the melting and crystallisation behaviour of the blends.

Thermogravimetric Analysis of LLDPE/MP Blends
TGA is commonly used to evaluate a composite material's thermal stability. Here, it was used to investigate the thermal decomposition of LLDPE/MP blends with different wt% of LLDPE burned in air. The higher the decomposition temperatures, the greater the thermal stability [52,56].
TGA measures the proportion and/or quantity of the mass of a material that is transformed, either as a function of temperature or isothermally, as a function of time. This is usually carried out in a regulated atmosphere [57]. TGA can be used to assess any substance that shows a change in weight when combusted, identifying phase changes during decomposition or oxidation [58]. Thermogravimetric analyses typically consist of a specimen pan supported by a precision scale [57]. These data are used to study the weight change, the material's chemical structure, and decomposition [59].
The TGA was performed with temperatures between 100 and 800 • C. Thermal decomposition for a range of LLDPE/MP blends was investigated, and the TGA curves obtained are presented in Figure 7. Figure 7 presents the loss of mass as a function of temperature for the test specimens. We see that the LLDPE/MP blend with 90 wt% LLDPE has suffered severe decomposition at 540 • C with over 90% mass loss. However, the blend with 30 wt% LLDPE shows only 60% mass loss at that temperature. This confirms that MP is more stable than LLDPE, and the wt% LLDPE in the blend influences its thermal stability. The decomposition temperatures of various LLDPE/MP blends are seen in Figure 7. Those fibres with 30 wt% and 40 wt% LLDPE could preserve more than 30% of the fibre mass until about 800 • C. With their decreased brittleness and relatively higher thermal stability, these two blends could provide acceptable precursors for the fabrication of CFs. We also studied the onset decomposition temperature of the samples. The onset degradation temperature is defined as the temperature at which the sample shows 5% initial mass loss. As seen in Table 4, onset degradation temperature also reduced with increasing LLDPE content in the LLDPE/pitch fibres. This observation further supports our initial finding that increased LLDPE content will reduce the thermal stability of the LLDPE/pitch blend. with 30 wt% LLDPE shows only 60% mass loss at that temperature. This confirms that MP is more stable than LLDPE, and the wt% LLDPE in the blend influences its thermal stability. The decomposition temperatures of various LLDPE/MP blends are seen in Figure 7.
Those fibres with 30 wt% and 40 wt% LLDPE could preserve more than 30% of the fibre mass until about 800 °C. With their decreased brittleness and relatively higher thermal stability, these two blends could provide acceptable precursors for the fabrication of CFs. We also studied the onset decomposition temperature of the samples. The onset degradation temperature is defined as the temperature at which the sample shows 5% initial mass loss. As seen in Table 4, onset degradation temperature also reduced with increasing LLDPE content in the LLDPE/pitch fibres. This observation further supports our initial finding that increased LLDPE content will reduce the thermal stability of the LLDPE/pitch blend.

Conclusions
This paper shows how the concentration of LLDPE affects the morphology and physical properties of LLDPE/MP blend fibres over the range of between 30 and 90 wt% LLDPE. The SEM image analysis of higher LLDPE content blends showed significantly altered morphology from micro-fibres to non-microfibers. The fibre diameter also showed a marginal reduction with increased wt% LLDPE in the LLDPE/MP blend fibres. The DSC analysis reveals that the enthalpy of fusion increases with the increase in LLDPE content in the sample.
The micromechanical testing of the LLDPE/MP blends showed a clear increase in both tensile modulus and strength, as well as strain to failure with an increase in the LLDPE content. However, TGA revealed a reduction in the temperature of the onset of degradation and a reduction in the residual mass (after about 540 • C) with an increase in the wt% LLDPE in the LLDPE/MP fibres. Hence, selection of LLDPE/pitch blend fibres must be based on both mechanical performance and the thermal stability of fibres.