Effect of Grit Blasting and Polishing Pretreatments on the Microhardness, Adhesion and Corrosion Properties of Electrodeposited Ni-W/SiC Nanocomposite Coatings on 45 Steel Substrate

In this study, a grit-blasting pretreatment was used to improve the adhesion, corrosion resistance and microhardness of Ni-W/SiC nanocomposite coatings fabricated using the conventional electrodeposition technique. Prior to deposition, grit blasting and polishing (more commonly used) pretreatments were used to prepare the surface of the substrate and the 3D morphology of the pretreated substrates was characterized using laser scanning confocal microscopy. The coating surface and the cross-section morphology were analyzed using scanning electron microscopy (SEM). The chemical composition, crystalline structure, microhardness, adhesion and corrosion behavior of the deposited coatings were characterized using energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), a microhardness tester, a scratch tester and an electrochemical workstation, respectively. The results indicated that the grit blasting and SiC addition improved the microhardness, adhesion and corrosion resistance. The Ni-W/SiC nanocomposites pretreated by grit blasting exhibited the best adhesion strength, up to 36.5 ± 0.75 N. Its hardness was the highest and increased up to 673 ± 5.47 Hv and its corrosion resistance was the highest compared to the one pretreated by polishing.


Introduction
The 45 steel is characterized by a good combination of mechanical properties as well as having low price in the market. Therefore, it is widely used for several components in mechanical engineering [1,2]. However, wear and corrosion are major reasons for failure of the mechanical parts in 45 steel during service. This limits its use in engineering fields where it is subjected to wear and corrosive environments. As such, it is necessary to improve the mechanical properties and corrosion resistance of this material [3][4][5].
Many surface-treatment techniques, such as hot dipping, surface hardening, thermal spraying, metallic cementation, nitrocarburizing, plasma nitriding, hard facing and electrodeposition [6][7][8], can be used to improve the microhardness, corrosion and wear resistance of 45 steel. Electrodeposition technology has been used extensively in recent years for the preparation of protective coatings because of its relatively lower cost, and it is also more convenient for engineering applications. This method has been used in the development of protective coatings that involves the coating of a metallic substrate with another metal or a combination of other metals (alloy coatings).
Among these coatings, the Ni-W alloy coating has caught the attention of researchers owing to its excellent corrosion resistance, high hardness and low toxicity, to replace hard chromium. In general, research carried out on electrodeposited Ni-W alloy coatings is aimed at improving their wear resistance, hardness and corrosion resistance [9][10][11][12]. In addition to the metal or alloy matrix, nanoparticles can be added to the coating so as to improve its mechanical and corrosion properties [13][14][15][16][17]. For this reason, many researchers have worked on Ni-W nanocomposite coatings and some studies have presented the performance of the incorporation of different nanoparticles in this binary alloy. One of these nanoparticles, SiC, due to its high purity, small particle size and stable chemical properties, was used as second-phase reinforcing particles in a composite to improve the corrosion resistance, wear resistance and microhardness of the deposited coatings [18].
Furthermore, a number of investigations have been performed on the electrodeposition of the Ni-W/SiC composite coatings and many of them have been done using polishing pretreatment of the sample [19][20][21]. Currently, there are few studies available on the effects of the different pretreatment methods on the Ni-W/SiC nanocomposite. In many cases involving mechanical loading, failure mainly occurs at the interface between the coating and the substrate. According to past literature, the surface roughness of the substrate surface is increased at the macro-level by the blasting technique and this removes the inherent oxide layers that are present on the substrate surface. It also improves the interaction between the coating and substrate, thereby enhancing the adhesion, corrosion and wear-resistance properties [22][23][24]. Grit blasting has also been reported to impart nearsurface compressive residual stress, which decreases the effective applied stress during service as well as delaying formation and propagation of microcracks on the bulk material surface where the coating has a good adherence to the substrate surface and is free of defects and discontinuities [22]. It has been reported that the Ni-B coatings deposited on the 8620H steel substrates carried out with sandblasting by emery powders had the best adhesion strength and corrosion resistance [24].
In this study, Ni-W/SiC nanocomposite coatings were prepared by conventional electrodeposition. The effects of two different pretreatment processes (grit blasting and polishing pretreatment) on the coating adhesion, microhardness and corrosion resistance of the Ni-W/SiC nanocomposite coatings were studied. To the best of the authors' knowledge, this research has not been undertaken before.

Materials and Methods
Ni-W/SiC nanocomposite coatings were deposited on 45 steel samples measuring 30 mm × 8 mm × 7 mm using the conventional electrodeposition technique. For the first phase, steel samples were pretreated using the grit blasting technique and then rinsed thoroughly in an electrostatic agitator using double-distilled water to remove any loose metal pieces. The grit-blasted samples ( Figure 1a) were subjected to a triple-immersion pretreatment process for electric cleaning. They were then immersed into the electrolyte for the deposition process. Grit blasting was performed using an abrasive grit blasting machine having a nozzle diameter of 8 mm, 1 mm steel grit particles, stand-off-distance of 100 mm and a blasting angle of 45 • at a pressure of 0.6 MPa. The schematic diagram of the grit blasting nozzle and substrate is shown in Figure 2.
For comparison purposes, the Ni-W/SiC nanocomposite coatings were also deposited on 45 steel substrates pretreated using the polishing pretreatment process (Figure 1b). For this phase of the experiment, the substrates were mechanically polished using abrasive emery papers with different granulometry ranging from 320 to 2000 and then subjected to a triple-immersion pretreatment process for electric cleaning. This ensured a stronger bond between the coating and substrate surface. The pretreatment process comprised of degreasing using electro-hydrostatic fluid, removal of the oxide layer on the surface by passing using a strong activating solution, and lastly removal of carbon-black using a weak activating solution. Table 1 shows the degreasing solution and HCl pickling solution reagents that were used for the process. The electrodeposition process was carried out in a 1000 mL glass beaker, and the electrodes were immersed vertically into the aqueous electrolytic Watts solution, with a distance of 3 cm between them. a 1000 mL glass beaker, and the electrodes were immersed vertically into the aqueous electrolytic Watts solution, with a distance of 3 cm between them.   SiC nanoparticles with an average particle size of 40 nm were dispersed in an aqueous sulphate-citrate electrolyte. Prior to the deposition process, the solutions with SiC nanoparticles were stirred using a continuous magnetic stirrer at a rate of 360 rpm for at least 24 h and subsequently by ultrasonic agitation for 30 min just prior to electrodeposition to ensure a uniform dispersion of SiC and prevent its agglomeration and settling. The same rate of magnetic stirring was also employed during electrodeposition at the cell bottom in order to maintain a homogeneous concentration of SiC particles in the solution. The reagents without any other form of purification were used in the electrolyte. Double-distilled a 1000 mL glass beaker, and the electrodes were immersed vertically into the aqueous electrolytic Watts solution, with a distance of 3 cm between them.   SiC nanoparticles with an average particle size of 40 nm were dispersed in an aqueous sulphate-citrate electrolyte. Prior to the deposition process, the solutions with SiC nanoparticles were stirred using a continuous magnetic stirrer at a rate of 360 rpm for at least 24 h and subsequently by ultrasonic agitation for 30 min just prior to electrodeposition to ensure a uniform dispersion of SiC and prevent its agglomeration and settling. The same rate of magnetic stirring was also employed during electrodeposition at the cell bottom in order to maintain a homogeneous concentration of SiC particles in the solution. The reagents without any other form of purification were used in the electrolyte. Double-distilled  SiC nanoparticles with an average particle size of 40 nm were dispersed in an aqueous sulphate-citrate electrolyte. Prior to the deposition process, the solutions with SiC nanoparticles were stirred using a continuous magnetic stirrer at a rate of 360 rpm for at least 24 h and subsequently by ultrasonic agitation for 30 min just prior to electrodeposition to ensure a uniform dispersion of SiC and prevent its agglomeration and settling. The same rate of magnetic stirring was also employed during electrodeposition at the cell bottom in order to maintain a homogeneous concentration of SiC particles in the solution. The reagents without any other form of purification were used in the electrolyte. Double-distilled water was used to prepare the electrolyte. The chemical composition of the electrolyte and the function of each component are shown in Table 2.  Table 3 shows the operating parameters used for preparing the Ni-W binary and Ni-W/SiC nanocomposite coatings. Apart from the different pretreatment processes used, the silicon carbide (SiC) nanoparticle concentration was varied, and its effect on the surface morphology, crystallite structure, microhardness, wear resistance, adhesion and corrosion resistance were analyzed, too. A laser scanning confocal microscope (LSCM, OLS4000, OLYMPUS, Tokyo, Japan) was used to analyze the 3D surface contour and roughness of the pretreated 45 steel samples. The coating morphology and microstructure of the deposited coatings was characterized using a FEI Quanta FEG 250 scanning electron microscope (SEM; Hillsboro, OR, USA). The SEM coupled with an energy-dispersive spectrometer (EDS Oxford max 20, Abingdon, UK) was used to determine the composition and the individual element content of the coatings.
X'Pert Power X-ray Diffraction (XRD, Westborough, MA, USA) with Cu K α radiation, operating at 40 kV and 40 mA, scanning from 20 • to 90 • with a step of 0.02 • was used to investigate the predominant crystallographic orientation, phase structure and grain size of the deposited coatings. Integral peak width was used to determine the average particle size. This can be expressed mathematically using the Debye-Scherrer formula shown in Equation (1).
where D is the crystallite size, λ represents the X-ray wavelength (0.15406 nm), k the Scherrer constant, β the full width at half maximum (rad) and θ the Bragg angle. The microhardness of the samples was measured using a Vickers microhardness tester (Struers, Duramin-40 A1, Ballerup, Copenhagen, Denmark), with an applied load of 100 g and an indentation time of 15 s. Ten separate locations were randomly selected for each sample and an average was computed.
The coating adhesion was measured by a scratch tester. For the measurement of the critical load that the coating could withstand before it was peeled off from the substrate, a load from 0 N to 50 N was gradually applied to the coating.
Electrochemical corrosion measurements were analyzed by a potentiodynamic polarization test (Tafel) by using an electrochemical workstation comprising of a three-electrode cell in a 3.5 wt.% NaCl medium. The slope of the potential-current density curve defining where β a is the slope of the anodic Tafel reaction, β c represents the slope of the cathodic Tafel and i corr represents the corrosion current density. Electrochemical Impedance Spectroscopy (EIS) experiments were also carried out at the frequencies of 10 5 Hz to 10 −2 Hz at open circuit potential (OCP) where the amplitude of the perturbation voltage was 5 mV. Impedance measurements we represented in the form of Nyquist and Bode plots. Figure 3 shows the 3D surface morphology of the samples exposed to the polishing pretreatment and grit-blasting pretreatment. Observing Figure 3a, it can be seen that the surface of the 45 steel subjected to a polishing pre-treatment was smooth without undulations while the grit-blasted surface showed large undulations with an obvious mountain peak and ravine morphology ( Figure 3b). The results show that the grit-blasting pretreatment could impart a rough appearance on the 45 steel surface. The surfaces roughness of the polished and grit-blasted substrates was evaluated. Table 4 contains the different roughness values (square root roughness (Sa) and mean square root roughness (Sq)) according to the different pretreatments. It can be seen that the values of the square root roughness of the 45 steel having undergone the polishing and grit-blasting pretreatment were 0.0047 ± 0.0007 µm and 1.0243 ± 0.3 µm, respectively. While the mean square root roughness values were 0.0057 ± 0.0007 µm, and 1.4237 ± 0.410 µm, respectively, suggesting the enhanced effect of the grit blasting treatment on the surface roughness. Considering these different results, it appears that the surface roughness could be significantly increased by the use of a grit-blasting pretreatment. This was found to be in agreement with the results reported in a previous study by the authors [23,[25][26][27][28].    Figures 4a and 5a, it can be seen that a large number of random deformations in the form of bulges and pits were observed on the surface of the grit-blasted specimen, while the polished surface was flat and smooth with no scratches. Similar results were reported in previous studies [29,30].  steel, it can be seen that the coating thickness increased, with the best adhesion and best corrosion resistance achieved after the sandblasting pretreatment by emery powders [24].

Surface Morphology
SEM images of the surface morphologies of the grit-blasted, polished specimens and Ni-W and Ni-W/SiC coatings on 45 steel substrates subjected to two different pretreatments, prepared by conventional electrodeposition, are shown in Figures 4 and 5. From  Figures 4a and 5a, it can be seen that a large number of random deformations in the form of bulges and pits were observed on the surface of the grit-blasted specimen, while the polished surface was flat and smooth with no scratches. Similar results were reported in previous studies [29,30].
Crystals 2021, 11, x FOR PEER REVIEW 7 of 20 tained by Ahmadkhaniha et al. [35]. It appears that the increase in SiC nanoparticles further induced the formation of nucleation sites. Other researchers in their studies also observed the nodular morphology [31]. It can be seen that from 3-6 g L −1 of SiC, the morphologies of the Ni-W/SiC coatings fabricated on the polished samples had no micro-cracks and defects but with 12 g L −1 of SiC the coating morphology contained some defects. Figure  5c-e show the formation of a more cellular structure on the grit-blasted surface. The SiC nanoparticles not only facilitated increasing cathodic polarization and reduce the overpotential of the metal nucleation of Ni 2+ , but it also participated in the formation of new crystal nuclei, and prevented aggregation and growth of crystal grains during electroplating, such that the composite coating was refined [36].
The number of nucleation points on the cell structure of the Ni-W/SiC coating was the highest and its size was the smallest with regard to the grit-blasted substrate.   The cross-sectional morphology of the Ni-W coating on the polished substrate is shown in Figure 6a. The coating was a uniform deposit on the surface of the smooth substrate with a thickness of about 17.35 ± 0.39 µm. Figure 7a presents the cross-sectional morphology of the Ni-W coating on the grit-blasted substrate. There existed a tight bond between the coating and the rough surface of the substrate and the formation of a mechanical interlock resulting from the filling of the holes in the substrate. The thickness is approximately 18.45 ± 0.53 µm, with pits up to 26.27 µm. Cheng et al. demonstrated that the increase in thickness observed is due to the high surface roughness caused by the grit blasting, which increased the number of nucleation points in the coating.   Figure 4b presents the surface microstructure of the Ni-W coating. It shows that the coating had smooth, compact surface. It also exhibited nodular film with developing micro-cracks similar to the surface morphology of Ni-W films studied [16,31].

Cross-Sectional Microstructure and EDS
The Ni-W coating pretreated by polishing exhibited a less obvious nodular structure on the surface of the morphology which can be attributed to a lower surface roughness of the 45 steel substrates. Figure 5b shows the surface microstructure of the Ni-W coating subjected to the grit-blasting pretreatment, where the cellular structure on the surface of the Ni-W coating was evident. The coating developed on the rough structure of the substrate during deposition and had bumps on the surface. With the presence of numerous bulges, hollows, and grain joints, and with the lattice defects generated by the grit-blasting pretreatment, the surface energy of the defects is relatively low, which allowed an easy surmounting of the energy barriers to nucleation. The number of nucleation sites then increased because of the defects generated after grit blasting [29,32]. Thus, the nucleation of the Ni-W alloy was easier after the grit-blasting pretreatment.
These different results reveal that the roughness increased, and the nodule density was high in the case of the grit-blasting pretreatment; therefore, the number of nucleation points could be increased in the case of grit blasting. Similar results were reported by Liu et al. and Vitryn et al. [33,34].
Figures 4c-e and 5c-e present the SEM of the Ni-W/SiC coating fabricated on the substrate surface subjected to the polishing and grit-blasting pretreatments, respectively. From Figure 4c-e, it is evident that the Ni-W coating's surface morphology was influenced by the SiC nanoparticles. The Ni-W/SiC coatings on the polished substrate show that the addition of SiC nanoparticles in the bath results in a nodular morphology. Moreover, by increasing the SiC concentration, the nodularity increased. A similar morphology was obtained by Ahmadkhaniha et al. [35]. It appears that the increase in SiC nanoparticles further induced the formation of nucleation sites. Other researchers in their studies also observed the nodular morphology [31]. It can be seen that from 3-6 g L −1 of SiC, the morphologies of the Ni-W/SiC coatings fabricated on the polished samples had no microcracks and defects but with 12 g L −1 of SiC the coating morphology contained some defects. Figure 5c-e show the formation of a more cellular structure on the grit-blasted surface. The SiC nanoparticles not only facilitated increasing cathodic polarization and reduce the overpotential of the metal nucleation of Ni 2+ , but it also participated in the formation of new crystal nuclei, and prevented aggregation and growth of crystal grains during electroplating, such that the composite coating was refined [36].
The number of nucleation points on the cell structure of the Ni-W/SiC coating was the highest and its size was the smallest with regard to the grit-blasted substrate. The cross-sectional morphology of the Ni-W coating on the polished substrate is shown in Figure 6a. The coating was a uniform deposit on the surface of the smooth substrate with a thickness of about 17.35 ± 0.39 µm. Figure 7a presents the cross-sectional morphology of the Ni-W coating on the grit-blasted substrate. There existed a tight bond between the coating and the rough surface of the substrate and the formation of a mechanical interlock resulting from the filling of the holes in the substrate. The thickness is approximately 18.45 ± 0.53 µm, with pits up to 26.27 µm. Cheng et al. demonstrated that the increase in thickness observed is due to the high surface roughness caused by the grit blasting, which increased the number of nucleation points in the coating. Figure 6b-d shows cross sections of the Ni-W/SiC nanocomposite deposited on the polished 45 steel with the variation in the SiC nanoparticle concentration. With the increase in SiC particles from 3 g L −1 to 12 g L −1 , the coatings exhibited a more compact cross section with good adhesion of the coating matrices to the substrate surface, and the coating thickness increased to 29.97 ± 0.49 µm at 6 g L −1 before decreasing to 20.95 ± 0.88 at 12 g L −1 . A similar change in thickness as a function of the variation in the SiC concentration, as shown in Figure 8a, was reported in previous research [37]. It can be suggested that by increasing the reinforced SiC nanoparticles from 6-12 g/L, it hindered the diffusion of the metallic ion through the electrolyte bulk to the cathode surface, thereby slowing down the growth rate [38].

Cross-Sectional Microstructure and EDS
Compared to the Ni-W coating, the thickness of all the Ni-W/SiC coatings was increased. This is due to the fact that the SiC particles refined the microstructure of the Ni-W coating and promoted its growth [36,39]. Figure 8a, was reported in previous research [37]. It can be suggested that by increasing the reinforced SiC nanoparticles from 6-12 g/L, it hindered the diffusion of the metallic ion through the electrolyte bulk to the cathode surface, thereby slowing down the growth rate [38].
Compared to the Ni-W coating, the thickness of all the Ni-W/SiC coatings was increased. This is due to the fact that the SiC particles refined the microstructure of the Ni-W coating and promoted its growth [36,39].  With the increase in SiC particles from 3 g L −1 to 12 g L −1 , the coating thickness increased to 25.9 ± 1.5 µm at 6 g L −1 before decreasing to 21.47 ± 63 µm at 12 g L −1 . Compared with the Ni-W coating, the thickness of all the Ni-W/SiC coatings were increased. The change in thickness as a function of the variation in SiC concentration is shown in Figure 8b. The high adhesion to the rough substrate was due to the effect of the SiC nanoparticles. In addition, the valleys and  With the increase in SiC particles from 3 g L −1 to 12 g L −1 , the coating thickness increased to 25.9 ± 1.5 µm at 6 g L −1 before decreasing to 21.47 ± 63 µm at 12 g L −1 . Compared with the Ni-W coating, the thickness of all the Ni-W/SiC coatings were increased. The change in thickness as a function of the variation in SiC concentration is shown in Figure 8b. The high adhesion to the rough substrate was due to the effect of the SiC nanoparticles. In addition, the valleys and apparent peaks appear on the surface of the substrate, which would have caused the densification of the nodular structure observed on the morphological surface shown in Figure 5c-e [24].      Figure 9 presents the EDS spectrum of the Ni-W coatings pretreated by polishing: Ni-W(P); pretreated by grit blasting: Ni-W(GB) and Ni-W/SiC nanocomposite coatings; pretreated by polishing: Ni-W/SiC(P); and grit-blasting pretreated: Ni-W/SiC(GB). As can be seen in Figure 9a,b, the EDS spectra of the Ni-W coatings prepared under the different processes present the peaks of Ni and W, where the Si and C content were not found. As can be seen in Figure 9c,d, besides the Ni peaks, peaks corresponding to W and Si are also seen, and C is also visible in the all cases; that is, the SiC particles were successfully co-deposited in the Ni-W coatings. With polishing or grit-blasting pretreatments, the incorporation of SiC into Ni-W reduced the amount of Ni and W. According to Gyawali et al. [40], the decrease in Ni and W in the coating during the codeposition of SiC nanoparticles can be explained in terms of Faraday's efficiency. According to Figure 9c Figure 9 presents the EDS spectrum of the Ni-W coatings pretreated by polishing: Ni-W(P); pretreated by grit blasting: Ni-W(GB) and Ni-W/SiC nanocomposite coatings; pretreated by polishing : Ni-W/SiC(P); and grit-blasting pretreated: Ni-W/SiC(GB). As can be seen in Figure 9a,b, the EDS spectra of the Ni-W coatings prepared under the different processes present the peaks of Ni and W, where the Si and C content were not found. As can be seen in Figure 9c,d, besides the Ni peaks, peaks corresponding to W and Si are also seen, and C is also visible in the all cases; that is, the SiC particles were successfully codeposited in the Ni-W coatings. With polishing or grit-blasting pretreatments, the incorporation of SiC into Ni-W reduced the amount of Ni and W. According to Gyawali et al. [40], the decrease in Ni and W in the coating during the codeposition of SiC nanoparticles can be explained in terms of Faraday's efficiency. According to Figure 9c,d, the Ni-W/SiC(P) (6 g L −1 of SiC) coating has a lesser content of W (31.6 wt·%) as compared to Ni-W/SiC(GB) (6 g L −1 of SiC),(35.48 wt·%). Moreover, the SiC content in all cases was low.   [20]. With the increase in SiC, the preferred orientation of the Ni-W/SiC coatings did not change significantly.

XRD Analysis
For both the grit blasting and polishing processes. The XRD results presented in Figures 10 and 11 show that the peaks corresponding to the SiC nanoparticles were not detected on the XRD pattern of the nanocomposite coatings but was confirmed by the EDS analysis. This was due to the low reinforcement content of the SiC nanoparticle in the deposited composite [40]. The crystallite size of the Ni-W alloy coating and of the Ni-W/SiC composite coatings was calculated using Scherer's equation and the grain values for the various electrodeposits are shown in Figure 12. The crystallite grain size of the Ni-   [20]. With the increase in SiC, the preferred orientation of the Ni-W/SiC coatings did not change significantly.

XRD Analysis
For both the grit blasting and polishing processes. The XRD results presented in Figures 10 and 11 show that the peaks corresponding to the SiC nanoparticles were not detected on the XRD pattern of the nanocomposite coatings but was confirmed by the EDS analysis. This was due to the low reinforcement content of the SiC nanoparticle in the deposited composite [40]. The crystallite size of the Ni-W alloy coating and of the Ni-W/SiC composite coatings was calculated using Scherer's equation and the grain values for the various electrodeposits are shown in Figure 12. The crystallite grain size of the Ni-W/SiC nanocomposite was observed to decrease as compared to the Ni-W coating for all the pretreatment processes. growth are the main basis for determining grain size. This is because the faster the nucleation rate, the slower the grain growth rate and the smaller the grains. The SiC nanoparticles added were absorbed at the cathode surface and created a large nucleation growth site favorable for coatings. The SiC nanoparticles were embedded in the metal grain boundaries of the Ni-W matrix and inhibited the growth of the grains, thereby reducing the size.

Microhardness
For objects subjected to a wear environment, two important properties of wear resistance and hardness are essential. Figure 13 presents the microhardness of the Ni-W/SiC

Microhardness
For objects subjected to a wear environment, two important properties of wear resistance and hardness are essential. Figure 13 presents the microhardness of the Ni-W/SiC nanocomposite coatings on the (a) polished and (b) grit-blasted 45 steel as a function of As shown in Figure 12a, the grain size of the Ni-W/SiC coatings obtained in the case of the polishing pretreatment process Figure 12a from the plating bath with different SiC nanoparticle concentration decreased with the increase in SiC concentration from 8.97 nm at 0 g L −1 to 8.16 nm at 6 g L −1 beyond which it increased to 8.7 nm at 12 g L −1 . Concerning the grit-blasting pretreatment (Figure 12b), the grain size of the Ni-W/SiC coatings obtained from the plating bath with the different SiC nanoparticle concentration decreased with the increase in SiC concentration from 8.21 nm at 0 g L −1 to 6.76 nm at 6 g L −1 beyond which it increased to 7.37 nm at 12 g L −1 . A similar trend was confirmed in previous publications [41][42][43]. From the result, the smallest grain size for both pretreatment processes was obtained at 6 g L −1 .
According to the theory of electrodeposition, the nucleation rate and the rate of grain growth are the main basis for determining grain size. This is because the faster the nucleation rate, the slower the grain growth rate and the smaller the grains. The SiC nanoparticles added were absorbed at the cathode surface and created a large nucleation growth site favorable for coatings. The SiC nanoparticles were embedded in the metal grain boundaries of the Ni-W matrix and inhibited the growth of the grains, thereby reducing the size.

Microhardness
For objects subjected to a wear environment, two important properties of wear resistance and hardness are essential. Figure 13 presents the microhardness of the Ni-W/SiC nanocomposite coatings on the (a) polished and (b) grit-blasted 45 steel as a function of SiC concentration. It was noted that for the grit-blasting or polishing pretreatment processes, the microhardness increased with the increase in the concentration of SiC, such that the microhardness of all the Ni-W/SiC nanocomposite coatings were higher than that of the Ni-W coating alloy. Without SiC, the deposited Ni-W exhibited the hardness for polishing and grit blasting of 550.25 ± 7.04 Hv and 589.89 ± 10 Hv, respectively. The presence of SiC in the Ni-W coatings considerably increased the microhardness for all pretreatment processes. It is clear that an increase in the amount of SiC particle codeposition led to an increase in the hardness of the coatings. With an increase in the SiC concentration from 3 to 6 g L −1 , the microhardness increased for the polishing and grit-blasting processes to 639.12 ± 5.76 Hv and 673 ± 5.47 Hv, respectively, before decreasing when the concentration of SiC was increased from 6 to 12 g L −1 . This effect of the nanoparticle on the coatings alloys has been described in previous research [15,[44][45][46]. One possible reason for this result is that the SiC nanoparticles in the Ni-W/SiC coating blocked the dislocation movement and sliding at the grain boundary of the matrix, thereby increasing the micro-hardness of the Ni-W/SiC. The alloy matrix strengthening mechanism is mainly due to grain refinement, particle strengthening and dispersion hardening effects [42]. The higest hardness was obtained with the nanocomposite with the lowest grain size of 6.76 nm. this result is that the SiC nanoparticles in the Ni-W/SiC coating blocked the dislocation movement and sliding at the grain boundary of the matrix, thereby increasing the microhardness of the Ni-W/SiC. The alloy matrix strengthening mechanism is mainly due to grain refinement, particle strengthening and dispersion hardening effects [42]. The higest hardness was obtained with the nanocomposite with the lowest grain size of 6.76 nm.  Figure 14 shows the adhesion of the coatings prepared on 45 steel substrates by electrodeposition with different pretreatment processes and by varying the SiC concentration. One of the important factors that degrades the protective performance and corrosion pro-  Figure 14 shows the adhesion of the coatings prepared on 45 steel substrates by electrodeposition with different pretreatment processes and by varying the SiC concentration. One of the important factors that degrades the protective performance and corrosion process of coatings is adhesion. Therefore, poor adhesion can cause performance failure of the Ni-W/SiC coatings. It was found that the adhesion of Ni-W alloys was not deteriorated by nanoparticles in any case whether the substrate was pretreated by polishing or by grit blasting. The addition of SiC inhibited the growth of the Ni-W grain, and the grain size of the coating was refined. The effective contact area between the coating and the substrate increased and based on the mechanism of the dispersal reinforcement of the nanoparticles, the adhesion of the coatings improved [47]. The adhesion of the Ni-W alloy coating on the polished and grit-blasted substrates was 11.25 N and 14.25 N, respectively. The Ni-W coating adhesion of the polished substrate was lower than that of the grit-blasted substrate. This remark is due to the rough surface obtained after blasting, which leads to the extrusion of the protrusions in the scratches. Fu et al. [27] studied the influence of the region of penetration elements on the adhesion and corrosion performance of the Ni-based coatings and indicated pre-processing by sanding increased the effective contact surface between the substrate and the coating and participated in the widening of the area of penetration of the element, which led to improved adhesion of the coating. Moreover, the grit-blasted surface has a larger contact area and better conditions for mechanical anchoring of the coating. Cheng et al. [24] found that the high surface roughness of the surfaces provided the higher adhesion force. Whether in the polishing or grit-blasting pretreatment, with the addition of the nano-SiC particles from 3-6 g L −1 , the adhesion of the composite coatings gradually increased before decreasing when the nano-SiC concentration was from 6 to 12 g L −1 . After the polishing pretreatment, the adhesion of the Ni-W/SiC coating increased to 26 ± 0.5 N (SiC of 6 g L −1 ) before decreasing to 13 N (12 g L −1 of SiC). This effect of the SiC nano-particles was confirmed by the previous studies [37,45]. Adhesion obtained after the grit-blasting pretreatment increased to 33 ± 0.75 N (6 g L −1 of SiC) before decreasing to 28 ± 1 N (12 g L −1 of SiC). This indicates an improvement in the interface bond strength between the coating and the metal substrate. This may be due to the high hardness of the SiC nanoparticles, which played a major role in the coupling of the matrix [20]. It should be noted that the fact that the size of the Ni-W crystal is much larger than those of the SiC nanoparticles, as the SiC nanoparticles could fill the pores between the grains of the Ni-W deposits, which could participate in the reduction of the porosity and improve the compactness of the coating. The metal matrix with a fine grain had a relatively high yield strength, according to the Hall-Petch equation [48,49]. The finer the size of the grain the larger the grain limit and this hinders the dislocation movement. Thus, the accumulation of dislocation at the boundary of the grain led to an increase in the strength of the coating. This remark is confirmed in Figures 12 and 15. In this study, the coatings with the small grain size had better coating adhesion for both the polishing and grit-blasting pretreatments. be noted that the fact that the size of the Ni-W crystal is much larger than those of the SiC nanoparticles, as the SiC nanoparticles could fill the pores between the grains of the Ni-W deposits, which could participate in the reduction of the porosity and improve the compactness of the coating. The metal matrix with a fine grain had a relatively high yield strength, according to the Hall-Petch equation [48,49]. The finer the size of the grain the larger the grain limit and this hinders the dislocation movement. Thus, the accumulation of dislocation at the boundary of the grain led to an increase in the strength of the coating. This remark is confirmed in Figures 12 and 15. In this study, the coatings with the small grain size had better coating adhesion for both the polishing and grit-blasting pretreatments.   Figure 16 shows the polarization curves of coatings fabricated on 45 steel substrates subjected to the different pretreatment processes. The extrapolation method was to determine the corrosion potential (Ecorr), corrosion current density (icorr), the polarization resistance (Rp) and corrosion rate (rcorr), as shown in Table 5. The results show that, compared to polished samples, the corrosion potential of the grit-blasted substrate increased from  Figure 16 shows the polarization curves of coatings fabricated on 45 steel substrates subjected to the different pretreatment processes. The extrapolation method was to determine the corrosion potential (E corr ), corrosion current density (i corr ), the polarization resistance (R p ) and corrosion rate (r corr ), as shown in Table 5. The results show that, compared to polished samples, the corrosion potential of the grit-blasted substrate increased from −957 to −830 mV, and the polarization resistance increased from −957 to −830 mV, implying pre-treatment by grit blasting improved significantly the substrate's surface corrosion resistance. This is because after pre-processing by grit blasting, a rough structure was generated and after the infiltration of the corrosion products they could not be easily diffused. Similar results were found by Fu et al. and Zhang et al. [27,30]. Compared with the base substrate, it was found that the corrosion potential of the Ni-W coating was significantly greater than that of the substrate. In addition, the polarization resistance of the Ni-W coating far exceeded that of the substrate and the corrosion rate decreased, too. This result shows that the Ni-W coating was an effective protection against corrosion of the exposed base substrate. Moreover, compared with the polishing pretreatment, the Ni-W(GB) coating alloy exhibited −696 mV (−744 mV for polishing) as the potential corrosion and 11.4 kΩ cm −2 as polarization resistance value and 2.13 kΩ cm −2 for Ni-W(P). According to Fu et al. [27], this positive effect of the Ni-W coating can be explained by the fact that there was the formation of the region of penetration of the elements between the Ni-W coating and the base substrate. Additionally, the increased adhesion of the coating caused by the application of the grit blasting is one of the factors that contributed to the improvement in the corrosion resistance of the coating. For both polishing and sandblasting, there was an increase in the corrosion potential and in the polarization resistance of the Ni-W/SiC nanocomposite coating compared to the Ni-W alloy coating. The Ni-W/6SiC(GB) nanocomposite coating exhibited the highest corrosion potential Ecorr (−560 mV) and the highest corrosion resistance Rp (12.7 kΩ cm −2 ) compared to the Ni-W/6SiC(P) nanocomposite coating. The EDS showed that the SiC particles were evenly distributed over the Ni-W/SiC nanocomposite, which resulted in the refining of the coating structure and the creation of an area that reduced the infiltration of the corrosion products. crease in the corrosion potential and in the polarization resistance of the Ni-W/SiC nanocomposite coating compared to the Ni-W alloy coating. The Ni-W/6SiC(GB) nanocomposite coating exhibited the highest corrosion potential Ecorr (−560 mV) and the highest corrosion resistance Rp (12.7 kΩ cm −2 ) compared to the Ni-W/6SiC(P) nanocomposite coating. The EDS showed that the SiC particles were evenly distributed over the Ni-W/SiC nanocomposite, which resulted in the refining of the coating structure and the creation of an area that reduced the infiltration of the corrosion products.    For supporting the findings from the potentiodynamic polarization, an additional corrosion resistance study of the Ni-W and Ni-W/SiC coating under the different pretreatment processes was done by using a non-destructive electrochemical impedance spectroscopy (EIS) method to study the behavior of each sample in a 3.5 wt.% NaCl solution. Figure 17 depicts the Nyquist and Bode plots recorded for the Ni-W and Ni-W/SiC coatings pretreated by the different processes. The increase in the impedance arc radius indicates that the coating had a better resistance to corrosion. The Nyquist plots were fitted using the ZSimpWin software; the results are listed in Table 6. The Figure 18 shows the equivalent electrical circuit, in which the Rs was the electrolyte resistance, CPEdl was the constant phase element and Rct represented the capacitive behavior at the interfaces of the coating/substrate. The results show that the grit-blasted substrate effectively improved the corrosion resistance seeing that after grit blasting, the Rct value increased from 0.665 to 0.940 kΩ cm −2 . The 45 steel had the smallest capacitive radius and, thus, the lowest corrosion resistance. Meanwhile, the Ni-W/6SiC(P) nanocoatings had a capacitive arc radius larger than the Ni-W(P) ones. In addition, the Ni-W/6SiC(GB) nanocomposite coating, with an Rct value reaching 4.92 kΩ cm −2 , had the largest capacitive arc radius and had the highest corrosion resistance. The results of the EIS and the corrosion resistance obtained in the polarization curve had a similar trend. The Ni-W/SiC composite coating pre-treatment by grit blasting had the best corrosion resistance. 0.665 to 0.940 kΩ cm −2 . The 45 steel had the smallest capacitive radius and, thus, the lowest corrosion resistance. Meanwhile, the Ni-W/6SiC(P) nanocoatings had a capacitive arc radius larger than the Ni-W(P) ones. In addition, the Ni-W/6SiC(GB) nanocomposite coating, with an Rct value reaching 4.92 kΩ cm −2 , had the largest capacitive arc radius and had the highest corrosion resistance. The results of the EIS and the corrosion resistance obtained in the polarization curve had a similar trend. The Ni-W/SiC composite coating pretreatment by grit blasting had the best corrosion resistance.     For supporting the findings from the potentiodynamic polarization, an additional corrosion resistance study of the Ni-W and Ni-W/SiC coating under the different pretreatment processes was done by using a non-destructive electrochemical impedance spectroscopy (EIS) method to study the behavior of each sample in a 3.5 wt.% NaCl solution. Figure 17 depicts the Nyquist and Bode plots recorded for the Ni-W and Ni-W/SiC coatings pretreated by the different processes. The increase in the impedance arc radius indicates that the coating had a better resistance to corrosion. The Nyquist plots were fitted using the ZSimpWin software; the results are listed in Table 6. The Figure 18 shows the equivalent electrical circuit, in which the Rs was the electrolyte resistance, CPEdl was the constant phase element and Rct represented the capacitive behavior at the interfaces of the coating/substrate. The results show that the grit-blasted substrate effectively improved the corrosion resistance seeing that after grit blasting, the Rct value increased from 0.665 to 0.940 kΩ cm −2 . The 45 steel had the smallest capacitive radius and, thus, the lowest corrosion resistance. Meanwhile, the Ni-W/6SiC(P) nanocoatings had a capacitive arc radius larger than the Ni-W(P) ones. In addition, the Ni-W/6SiC(GB) nanocomposite coating, with an Rct value reaching 4.92 kΩ cm −2 , had the largest capacitive arc radius and had the highest corrosion resistance. The results of the EIS and the corrosion resistance obtained in the polarization curve had a similar trend. The Ni-W/SiC composite coating pretreatment by grit blasting had the best corrosion resistance.

Conclusions
In this work, a Ni-W coating and Ni-W/SiC nanoparticle coating were fabricated on 45 steel substrates pretreated by polishing and sandblasting in order to study the effects of roughness and SiC nanoparticles on the microhardness, adhesion strength and corrosion resistance on the coatings. It can be concluded that grit blasting and SiC nanoparticles significantly strengthened the adhesion between the coating and the substrate. Meanwhile, the microhardness and the corrosion resistance improved.
(1) The Ni-W/SiC (6 g L −1 of SiC) nanocomposite fabricated on the grit-blasted 45 steel substrates exhibited the highest hardness compared to the one fabricated on polished 45 substrates. (2) The adhesion of the Ni-W/SiC (6 g L −1 ) nanocomposite coating pretreated by grit blasting was 33 ± 0.75 N, which was higher than the one pretreated by polishing.

Data Availability Statement:
The data that support the findings of this study are available from the corresponding author, upon reasonable demand.

Conflicts of Interest:
The authors declare no conflict of interest.