Studying the C–H Crystals and Mechanical Properties of Sustainable Concrete Containing Recycled Coarse Aggregate with Used Nano-Silica

: The present study aims to replace 30%, 40%, and 50% of the natural coarse aggregate (NCA) of concrete with recycled coarse aggregate containing used nano-silica (RCA-UNS) to produce a new sustainable concrete. Three groups of concrete are made and their mechanical properties and microstructure are studied. In the ﬁrst group, which was the control group, normal concrete was used. In the second group, 30%, 40%, and 50% of the NCA were replaced with coarse aggregate obtained from crushed concrete of the control samples and with 0.5% nano-silica as ﬁller. In the third group, 30%, 40%, and 50% of the concrete samples’ NCA were replaced with aggregates obtained from 90-day crushed samples of the second group. Water absorption, fresh concrete slump, and compressive strength of the three groups were investigated and compared through scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) tests. The results show that the third group’s compressive strengths increased by 12.8%, 10.9%, and 10% with replacing 30%, 40%, and 50% of NAC with RCA-NS at 28 days compared to the control samples, respectively. This could be due to the secondary production of calcium silicate hydrate due to the presence of new cement paste. The third group’s microstructure was also improved due to the change in the C–H and the production of extra C–S–H. Therefore, the hydration of cement with water produces C–H crystals while reactions are induced by recycled aggregate containing used nano-silica. M.K.T., S.S. writing—review M.K.T., S.S., R.H.F. and A.M.; M.K.T., S.S. and R.H.F.; S.S. and A.M.; project administration, A.M.; funding acquisition, A.M. the


Introduction
An average of 40 billion tons of natural aggregates (NA) is used to make concrete in fine and coarse form worldwide [1,2] leading to scarcity of these resources. In addition, the production and processing of NA play an essential role in the generation of dust, noise and greenhouse gases which have a serious negative impact on the environment. Therefore, the need to create an alternative source of NA is of concern to the engineering community today. Furthermore, because of industrial waste in the current century, the need to use recycled materials has become of vital importance, particularly in the construction industry [3,4]. A significant amount of construction and demolition waste is generated annually from the construction industry in all countries of the world. The most influential producers of this waste are China, India and the United States, producing approximately very small amounts of these materials have the same pozzolanic effect [29,30]. Nano-silica produces higher compressive strength, is more widely used and more environmentally friendly than other nano-materials such as nano-clay [31]. In cement paste, by adding nanosilica, the hydration acceleration of cement increases and in the first moments, calcium hydroxide is formed due to the increase in the contact surface of nano-silica with water [19].
A great deal of research has been carried out on the application of nano-silica in ordinary concrete [25,28,32]. Furthermore, several research studies have been conducted on the application of Nano-silica with RCA in concrete demonstrating a reduction in the slump of concrete [17,33,34]. Also, currently nano-silica gained a huge interest from the construction industry to improve the concrete properties and produce a high performance sustainable concrete [20]. In the near future, the amount of demolished concrete which includes nano-silica will also be increased. However, there is a lack of knowledge of the reuse of recycled concrete aggregates containing used nano-silica (RCA-UNS). This means that a concrete structure made from recycled coarse aggregates with nano-silica might be recycled again. No research has been carried out on these massive amounts of recycled coarse aggregates containing used nano-silica in concrete. Thus, no data on the properties of these recycled coarse aggregates containing used nano-silica exists. Accordingly, reuse of recycled coarse aggregates containing used nano-silica is important.
To do so, ordinary concrete samples were made as the control for the first group at the ages of 7, 28 and 90 days. In the second group, 30%, 40%, and 50% of the NCA of concrete samples were replaced with coarse aggregate obtained from crushing concrete of control samples and followed by the addition of nano-silica. In the third group, 30%, 40%, and 50% of the NCA of concrete samples were replaced with the aggregates obtained from 90-day crushing of the samples of the second group. Water absorption, fresh concrete slump, compressive strength, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) of the three groups were compared.

Cement, Water, Natural Aggregates and Superplasticizer
Type-I of Portland cement (Kurdistan Cement Co., Bijar, Iran) with a density of 3.20 g/cm 3 based on ASTM C 150A [35] was used in this research. For mixing water, regular drinking water with pH = 7 was utilized. The natural aggregates of all three groups in the concrete mixing design were based on ASTM C128 [36]. The natural coarse aggregates with water absorption of 0.71% had irregular and crushed shape with a maximum size of 13 mm and density of 2.45 according to ASTM C 127 [37]. The natural fine aggregate (NFA) used was river sand with water absorption of 0.60%, 4.75 mm maximum sizes and the density of 2.6. The natural fine aggregates were the same for all groups. The grading curve for NA for the three groups is shown in Figure 1. The black dashed line in Figure 1 represents the control sample aggregates (natural aggregates). A liquid superplasticizer additive based on naphthalene sulfonate was used to increase workability. Its density was 1.33 g/cm 3, and 0.5% of the weight of cement was used in concrete according to the superplasticizer catalogue. A constant amount of superplasticizer was used in all concrete mixes.

Recycled Coarse Aggregates (RCA and RCA Containing Used Nano-Silica (RCA-NS))
The second group of concrete specimens, recycled coarse aggregates containing nanosilica, was named RCA-NS. This group of recycled coarse aggregates (RCA) was obtained by crushing 90-day control samples using impact crusher because at the age of 90 days the control concrete has almost reached its final strength. To increase workability, the fine aggregates were separated by sieving and the old cement with air pressure. The largest and the smallest sizes of RCA aggregate were approximately 22.5 mm and 10 mm, respectively. The water absorption and the specific gravity of RCA were, in the order mentioned, approximately 2.2% and 2.45. The grading curve of RCA, is illustrated with a red solid line in Figure 1. The third group of concrete samples was named RCA-UNS. By crushing the 90day samples of the second group (RCA-NS), RCA-NS were obtained for use in the third group. The specific gravity and water absorption of RCA-NS were 2.35 and almost 2.9%, respectively. The largest and smallest sizes of RCA-NS aggregates were approximately 23 mm and 8 mm, respectively. The cement coat from the aggregates was removed by using ultrasonic cleaning method to improve the bonding between the new cement paste and RCA [38]. Its grading curve is represented by black dots in Figure 1.
the fine aggregates were separated by sieving and the old cement with air pressure. The largest and the smallest sizes of RCA aggregate were approximately 22.5 mm and 10 mm, respectively. The water absorption and the specific gravity of RCA were, in the order mentioned, approximately 2.2% and 2.45. The grading curve of RCA, is illustrated with a red solid line in Figure 1.
The third group of concrete samples was named RCA-UNS. By crushing the 90-day samples of the second group (RCA-NS), RCA-NS were obtained for use in the third group. The specific gravity and water absorption of RCA-NS were 2.35 and almost 2.9%, respectively. The largest and smallest sizes of RCA-NS aggregates were approximately 23 mm and 8 mm, respectively. The cement coat from the aggregates was removed by using ultrasonic cleaning method to improve the bonding between the new cement paste and RCA [38]. Its grading curve is represented by black dots in Figure 1.

Nano-Silica
Nano-silica (obtained from the EVONIK company, Germany) was available as powder with 99.9% Sio2 and 10-14 nm particle size. The color was white ( Figure 2), pore size was 1.2 mL/g pore volume with 50 m 2 /g surface area, and density of 2.50. Figure 3 shows an image of the Nano-silica used in group two which was provided by the Iranian Nanomaterials Pioneers Company. The percentage of Nano silica used in concrete varies between 0.4 to 1.5 wt% of the cement as mentioned in previous research [15,21]. In the second group of this study, Nano-silica was used and added as 0.5% of the weight of cement [20]. Table 1 shows the chemical composition and physical properties of the cement and nano-silica.

Nano-Silica
Nano-silica (obtained from the EVONIK company, Germany) was available as powder with 99.9% Sio2 and 10-14 nm particle size. The color was white (Figure 2), pore size was 1.2 mL/g pore volume with 50 m 2 /g surface area, and density of 2.50. Figure 3 shows an image of the Nano-silica used in group two which was provided by the Iranian Nanomaterials Pioneers Company. The percentage of Nano silica used in concrete varies between 0.4 to 1.5 wt% of the cement as mentioned in previous research [15,21]. In the second group of this study, Nano-silica was used and added as 0.5% of the weight of cement [20]. Table 1 shows the chemical composition and physical properties of the cement and nano-silica.

Concrete Preparation and Mix Design
In order to achieve the objectives of the research, the amount of cement, the ratio of water to cement, and natural fine aggregates were considered constant in all mix designs. In this regard, an attempt was made to maintain constant conditions and only the amount of aggregate replacement differed. The water to cement ratio of concrete was 0.45 in all

Concrete Preparation and Mix Design
In order to achieve the objectives of the research, the amount of cement, the ratio of water to cement, and natural fine aggregates were considered constant in all mix designs. In this regard, an attempt was made to maintain constant conditions and only the amount of aggregate replacement differed. The water to cement ratio of concrete was 0.45 in all concrete mixtures. This ratio of water to cement was high because water might be absorbed in recycled concrete and concrete slump could be very low. In addition, a dark brown liquid superplasticizer (based on naphthalene sulfate) was added to increase workability. For the experiments, a concrete mix was made according to Table 2 to make a cubic sample for ages 7, 28 and 90 days (three samples for each age). RCA-NS standard cubic specimens (second group) were made using natural aggregates with 30%, 40% and 50% RCA and 0.5% Wt. of cement of added Nano-silica. These samples were tested at different ages and the 90-day coarse aggregates of these samples were used as recycled coarse aggregate containing used Nano-silica in the third group. In addition, RCA-UNS cubic samples (third group) were prepared using natural aggregates with 30%, 40% and 50% RCA-NS according to Table 2.
The steps for mixing the materials were as follows: before adding water, all aggregates were loaded and mixed in the mixer up to 2 min. Then, the amount of water needed for water absorption of aggregates was added and mixed with a high-speed mixer for up to 2 min. In the case of the second group, nano-silica was first added with half of the remaining water and added to the mixture. The cement was then added to the mixture and mixed for 3 min. Finally, the superplasticizer was mixed with the other half of the mixing water and added to the concrete within 2 min. Concrete mixing was stopped for one minute until the superplasticizer began to react. During this time, the mixer was covered so that the concrete water did not evaporate. The concrete was mixed at high speed for another 3 min until it reached the desired performance. This was followed by placing the concrete in standard cubic (10 × 10 × 10 cm) molds. To avoid water evaporation, a plastic sheet was used on cubic molds. The molds were opened after one day. After demolding, all samples were cured in a water tank at 20 • C according to ASTM C 511 [39]. For greater accuracy, 3 samples were made from each mold and the statistical average was calculated [39].

Slump of Fresh Concrete
The slump of fresh concrete test of recycled concrete is one of the most important tests due to the adsorption of mixing water by recycled aggregates and old cement. One of the disadvantages of recycled concrete is slump loss [40]. The results of fresh concrete slump based on ASTM C143 [41] are presented in Figure 4. The slump of the control concrete was 79 mm. However, the slump of RCA-NS samples decreased with 30%, 40% and 50% of RCA by 30, 25 and 19 mm, respectively, this phenomenon was also observed in previous research [1,20,26]. The slump of RCA-UNS samples with 30%, 40% and 50% RCA-NS were reduced to 18.5, 18 and 18 mm, respectively. This was because the used nano-silica absorbed excess amounts of mixing water and reduced workability. Moreover, mortar attached to aggregates from the first and second groups was the cause of the low reduction of slump in the third group.

Water Absorption of Concrete Samples
Water absorption of all concrete samples in this study was performed following the method described in ASTM C642-13 standard test [42]. In the samples of this test, broken parts of the internal (core) of the concrete were used to measure water absorption.

Water Absorption of Concrete Samples
Water absorption of all concrete samples in this study was performed following the method described in ASTM C642-13 standard test [42]. In the samples of this test, broken parts of the internal (core) of the concrete were used to measure water absorption. Figure 5 shows the water absorption of concrete samples at 28 days. The results show that the sample of 30% RCA-NS had greater water absorption than the control mixture. This could be as a result of recycled coarse aggregates which increase bleeding, segregation, and air voids [43]. The water absorption percentage of the control sample was 3.8%, while this amount for the RCA-NS sample with 30%, 40% and 50% of RCA were 4.3, 4.4 and 4.7, respectively. This increase in water absorption with rising percentage of RCA has also been reported by Younes et al. [19]. Furthermore, the high-water absorption of RCA-NS samples can be attributed to the inherent nature of the pores of recycled coarse particles and adsorption by the old mortar in them. The water penetrated into the cement matrix due to the ability of aggregate to absorb water, the presence of fine pores and capillary phenomena. The water absorption percentages of RCA-UNS samples with 30%, 40% and 50% recycled coarse aggregates containing used nano-silica were 3.7%, 3.6% and 3.6%, respectively. As can be observed in Figure 5, contrary to expectations, the water absorption of RCA-UNS samples decreased compared to control and RCA-NS samples. This phenomenon might be due to hydration of old cements and the formation of additional C-S-H which could play a positive role in filling pores and cracks of the samples.

Compressive Strength of Samples
The compressive strength test using standard cubic specimens at 7, 28, and 90 days was in accordance with BS 1881 [44]. One way to make sustainable concrete is to increase its mechanical properties such as compressive strength. The results of the compressive strength tests for the ages mentioned are shown in Figure 6. By looking at the error bars, there are overlaps for different percentages of RCA. By considering a 95% confidence interval, it can be concluded that compressive strengths of all of the RCA samples are almost the same and a different percentage of RCA has no significant impact on the compressive strength regardless of being compared to the control sample. For all of the RCA samples, it is obvious that compressive strength has been dropped compared to the control sample. As illustrated in Figure 6, in the third group (RCA-UNS), there was a 5.7%, 4.6% and 4.4% increase in compressive strength at 7 days compared to the sample, respectively [45,46].

Compressive Strength of Samples
The compressive strength test using standard cubic specimens at 7, 28, and 90 days was in accordance with BS 1881 [44]. One way to make sustainable concrete is to increase its mechanical properties such as compressive strength. The results of the compressive strength tests for the ages mentioned are shown in Figure 6. By looking at the error bars, there are overlaps for different percentages of RCA. By considering a 95% confidence interval, it can be concluded that compressive strengths of all of the RCA samples are almost the same and a different percentage of RCA has no significant impact on the compressive strength regardless of being compared to the control sample. For all of the RCA samples, it is obvious that compressive strength has been dropped compared to the control sample. As illustrated in Figure 6, in the third group (RCA-UNS), there was a 5.7%, 4.6% and 4.4% increase in compressive strength at 7 days compared to the sample, respectively [45,46].
The compressive strength of the second group (RCA-NS) with the replacement of 30%, 40% and 50% of RCA aggregates were respectively 30.1, 29.3 and 28.7 MPa at 28 days of age, while the compressive strength of the control sample was 32 MPa. The decrease in compressive strength in the second group was due to the weak bond between recycled coarse aggregates and also the characteristics of these aggregates such as old mortar, the presence of impurities, cracks, and porosity (which in previous research decreased to a greater extent [17,22,40]); however, nano-silica partially compensated for this weakness. Furthermore, as shown in Figure 6, compressive strength was recorded as 36.1, 35.5, and 35.2 MPa at 28 days by replacing with 30%, 40%, and 50% of RCA-NS aggregates, respectively. This increase in compressive strength in the third group may be due to the presence of sufficient water to complete the hydration of the third amount of cement paste. This amount can act as filler and improve the ITZ of concrete. In addition, the replacement of 30% of natural coarse aggregate of concrete with recycled coarse aggregate containing used nano-silica (RCA-UNS 30%) increased the compressive strength by 15.7% compared to the control samples at 90 days. This increase in compressive strength at older ages (90 days) is also observed in this bar chart. This increase in compressive strength is consistent with the water absorption test of the samples. Therefore, the addition of 30% recycled coarse aggregate containing used nano-silica increased the compressive strength by approximately 12%.

Compressive Strength of Samples
The compressive strength test using standard cubic specimens at 7, 28, and 90 days was in accordance with BS 1881 [44]. One way to make sustainable concrete is to increase its mechanical properties such as compressive strength. The results of the compressive strength tests for the ages mentioned are shown in Figure 6. By looking at the error bars, there are overlaps for different percentages of RCA. By considering a 95% confidence interval, it can be concluded that compressive strengths of all of the RCA samples are almost the same and a different percentage of RCA has no significant impact on the compressive strength regardless of being compared to the control sample. For all of the RCA samples, it is obvious that compressive strength has been dropped compared to the control sample. As illustrated in Figure 6, in the third group (RCA-UNS), there was a 5.7%, 4.6% and 4.4% increase in compressive strength at 7 days compared to the sample, respectively [45,46].  Figure 7 shows the failure modes of the samples. As can be observed in a, the desired failure of the control concrete sample occurred in such a way that with increasing pressure, the 4 sides evenly cracked and after failure, the remaining piece was stacked in two inverted pyramids or the two pyramids were separated. However, in the RCA-NS sample, fragmentation failure occurred only at the surfaces of the sample, which could be a plastic failure mode in the sample (Figure 7b). In the RCA-UNS example, the plastic failure mode is also shown in Figure 7c. coarse aggregates and also the characteristics of these aggregates such as old mortar, the presence of impurities, cracks, and porosity (which in previous research decreased to a greater extent [17,22,40]); however, nano-silica partially compensated for this weakness.
Furthermore, as shown in Figure 6, compressive strength was recorded as 36.1, 35.5, and 35.2 MPa at 28 days by replacing with 30%, 40%, and 50% of RCA-NS aggregates, respectively. This increase in compressive strength in the third group may be due to the presence of sufficient water to complete the hydration of the third amount of cement paste. This amount can act as filler and improve the ITZ of concrete. In addition, the replacement of 30% of natural coarse aggregate of concrete with recycled coarse aggregate containing used nano-silica (RCA-UNS 30%) increased the compressive strength by 15.7% compared to the control samples at 90 days. This increase in compressive strength at older ages (90 days) is also observed in this bar chart. This increase in compressive strength is consistent with the water absorption test of the samples. Therefore, the addition of 30% recycled coarse aggregate containing used nano-silica increased the compressive strength by approximately 12%. Figure 7 shows the failure modes of the samples. As can be observed in Figure 7a, the desired failure of the control concrete sample occurred in such a way that with increasing pressure, the 4 sides evenly cracked and after failure, the remaining piece was stacked in two inverted pyramids or the two pyramids were separated. However, in the RCA-NS sample, fragmentation failure occurred only at the surfaces of the sample, which could be a plastic failure mode in the sample (Figure 7b). In the RCA-UNS example, the plastic failure mode is also shown in Figure 7c.

Scanning Electron Microscopy (SEM) of Samples
Images of small-sized structures with SEM (TSCAN test machine made in Czech Republic) at 28 days are shown in Figures 8-10. Figures 8-10 show the microscopic

Scanning Electron Microscopy (SEM) of Samples
Images of small-sized structures with SEM (TSCAN test machine made in Czech Republic) at 28 days are shown in Figures 8-10. Figures 8-10 show the microscopic structure images of the control sample, the RCA-NS 30%, and the RCA-UNS 30% sample, respectively. Figure 8 illustrates the significant amount of porosity, micro cracks, C-H, C-S-H, and most of the unreacted material. The unreacted material was due to the excessive amount of cement and some remaining cementitious materials [38]. Figure 9 demonstrates that RCA aggregates increased porosity and small cracks, and prevented secondary C-S-H formation. The C-S-H is a compound which is the main product of Portland cement hydration and a major factor in the strength of cement and all cement-based products. Approximately 50% to 60% of the volume of fully hydrated cement paste solids is C-S-H [47]. Figure 10 shows more C-S-H formation than Figures 8 and 9. The SEM results confirm previous research findings on water absorption and compressive strength and show that in the RCA-UNS 30% sample, C-S-H was produced in comparison to the control and RCA-NS 30% samples. The SEM images illustrate that used Nano-silica or new cement reduced porosity and micro cracks in the RCA-UNS 30% sample. Therefore, the size of the pores and C-H crystals are reduced creating a microstructure that is extra compressed when coarse aggregate containing used nano-silica was used. Also, Figure 10 showed that RCA-UNS 30% samples have larger ITZ compared to the RCA-NS 30% in Figure 9. the size of the pores and C-H crystals are reduced creating a microstructure that is extra compressed when coarse aggregate containing used nano-silica was used. Also, Figure 10 showed that RCA-UNS 30% samples have larger ITZ compared to the RCA-NS 30% in Figure 9.      Figure 11 shows the XRD pattern (obtained from SAXess Co., Niederösterreich, Austria) for control samples, RCA-NS 30%, and RCA-UNS 30% at University of Kurdistan at 28 days. At 18° and 34° (2 Theta) from XRD patterns, intensity peaks of C-H crystal were traced [23,45]. To prepare the samples of this test, a powder form (300 microns) obtained from a combination of aggregate and mortar from broken parts of the compressive strength test was used. Intensity peaks of C-H crystal in the control sample were 67 and 59 at 18° and 34° (2Theta), respectively. In the RCA-NS 30%, intensity peaks of C-H crystal were 54 and 33 at 18° and 34° (2Theta), respectively. As shown in Figure  11, the intensity peaks of C-H crystal in the RCN-NS 30% samples were slightly reduced compared to the control sample due to low C-H crystal consumption and C-S-H formation. The reason may be that the specific gravity of recycled coarse aggregates  Figure 11 shows the XRD pattern (obtained from SAXess Co., Niederösterreich, Austria) for control samples, RCA-NS 30%, and RCA-UNS 30% at University of Kurdistan at 28 days. At 18 • and 34 • (2 Theta) from XRD patterns, intensity peaks of C-H crystal were traced [23,45]. To prepare the samples of this test, a powder form (300 microns) obtained from a combination of aggregate and mortar from broken parts of the compressive strength test was used. Intensity peaks of C-H crystal in the control sample were 67 and 59 at 18 • and 34 • (2Theta), respectively. In the RCA-NS 30%, intensity peaks of C-H crystal were 54 and 33 at 18 • and 34 • (2Theta), respectively. As shown in Figure 11, the intensity peaks of C-H crystal in the RCN-NS 30% samples were slightly reduced compared to the control sample due to low C-H crystal consumption and C-S-H formation. The reason may be that the specific gravity of recycled coarse aggregates (resulted from demolishing RCA-NS mixtures) is lower than that of natural coarse aggregates and the natural coarse aggregate was substituted based on weight and, considering the fact that the mixture design was not based on volumetric ratios, this would result in lowering the cement content by replacing natural coarse aggregate with RCA in the unit volume of concrete. Furthermore, it can be observed that the intensity peaks of C-H crystal in RCA-UNS 30% samples decreased by 65% and 67% at 18 • and 34 • (2Theta), respectively compared to the control sample. This decrease in intensity peaks of C-H crystal related to quartz (SiO2) was due to the production of secondary C-S-H, which has also been reported by other researchers [32,38,48]. Reaction and effect of coarse aggregate containing used nano-silica on C-H crystallization is more remarkable. Findings from the XRD test were consistent with the compressive strength, SEM test.

Fourier Transform Infrared (FT-IR) Graphs of Samples
To discover the variations in the C-S-H chains related to Si-O-Si, Si-H, O-C-O and O-H bands, FT-IR graph tests were conducted. FTIR test samples were in powder form. These powders were obtained by grinding the broken part of the compressive strength test, which includes cement and aggregates. After grinding, the powder was sieved with a 300 micron sieve. The FT-IR graphs (Bruker machine, made in the Netherlands, tested at University of Kurdistan) of the control, RCA-NS 30%, and RCA-UNS 30% samples at 28 days, between 600-2600 cm −1 , are shown in Figure 12. The stretching vibration of O-H at 1600-1640 cm -1 was due to the increased molecule of water in the samples [49].The 30% of natural coarse aggregates replacement with recycled coarse aggregate (RCA-NS 30%) increased the O-H stretching vibrations which were further augmented if replacement with recycled coarse aggregate contained used nano-silica (RCA-UNS 30%). Another strong band was the stretching vibration of O-C-O at 1300-1400 cm −1 which was due to atmospheric carbonation. The strongest band was Si-H at 1350-1450 cm −1 due to depolymerization. The Si-H bands increased in RCA-UNS 30% samples likely [49,50]. The changes in Si-O-Si transmittance band at 750-800 cm -1 indicate that a secondary C-S-H was formed, which has also been reported in other research [23,51]. The replacement of 30% natural coarse aggregates with recycled coarse aggregate containing used Nano-silica (RCA-UNS 30%) increased the Si-O-Si transmittance bands. The results of FT-IR graphs of samples were in agreement with compressive strength, SEM, and XRD results.

Fourier Transform Infrared (FT-IR) Graphs of Samples
To discover the variations in the C-S-H chains related to Si-O-Si, Si-H, O-C-O and O-H bands, FT-IR graph tests were conducted. FT-IR test samples were in powder form. These powders were obtained by grinding the broken part of the compressive strength test, which includes cement and aggregates. After grinding, the powder was sieved with a 300 micron sieve. The FT-IR graphs (Bruker machine, made in the Netherlands, tested at University of Kurdistan) of the control, RCA-NS 30%, and RCA-UNS 30% samples at 28 days, between 600-2600 cm −1 , are shown in Figure 12. The stretching vibration of O-H at 1600-1640 cm -1 was due to the increased molecule of water in the samples [49].The 30% of natural coarse aggregates replacement with recycled coarse aggregate (RCA-NS 30%) increased the O-H stretching vibrations which were further augmented if replacement with recycled coarse aggregate contained used nano-silica (RCA-UNS 30%). Another strong band was the stretching vibration of O-C-O at 1300-1400 cm −1 which was due to atmospheric carbonation. The strongest band was Si-H at 1350-1450 cm −1 due to depolymerization. The Si-H bands increased in RCA-UNS 30% samples likely [49,50]. The changes in Si-O-Si transmittance band at 750-800 cm -1 indicate that a secondary C-S-H was formed, which has also been reported in other research [23,51]. The replacement of 30% natural coarse aggregates with recycled coarse aggregate containing used Nano-silica (RCA-UNS 30%) increased the Si-O-Si transmittance bands. The results of FT-IR graphs of samples were in agreement with compressive strength, SEM, and XRD results.

Conclusions
In this study, for the first time, 30%, 40% and 50% of recycled coarse aggre containing used Nano-silica (RCA-UNS) were reused in concrete. For this pu ordinary concrete samples were made and tested for the control group, also name first group. In the second group (for comparison and use in third group samples) 40% and 50% of natural coarse aggregates were replaced by recycled coarse aggrega the concrete obtained from the control samples. In the samples of the second group, silica was added to the mixture at the rate of 0.5% by weight of cement (RCA Furthermore, in the samples of the third group, 30%, 40% and 50% of the natural c aggregates were replaced by recycled concrete from recycled coarse aggregates conta used nano-silica, obtained from the samples of the second group at 90 days. absorption, fresh concrete slump, compressive strength, SEM, FT-IR, and XRD te these three groups were compared.

•
The findings demonstrate that the water absorption of RCA-UNS samples decr compared to the control sample. • Moreover, the findings of the compressive strength test illustrated that compr strength in the third group increased 12.8%, 10.9%, and 10% by replacing 30% and 50% of NAC with RCA-NS at 28 days compared to control samples.

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The SEM results confirm previous results such as water absorption and compr strength and show that the RCA-UNS 30% sample produced extra C-S-H.

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In addition, the XRD and FT-IR graphs illustrate that in the RCA-UNS samples, C-H crystal was consumed and converted to C-S-H.

•
For the production of sustainable concrete, 30% of natural coarse aggregates c replaced with recycled coarse aggregate containing used nano-silica. Therefor hydration of cement with water produces C-H crystals while reactions induc coarse aggregate containing used nano-silica consume the C-H crystals.

Conclusions
In this study, for the first time, 30%, 40% and 50% of recycled coarse aggregates containing used Nano-silica (RCA-UNS) were reused in concrete. For this purpose, ordinary concrete samples were made and tested for the control group, also named the first group. In the second group (for comparison and use in third group samples), 30%, 40% and 50% of natural coarse aggregates were replaced by recycled coarse aggregates of the concrete obtained from the control samples. In the samples of the second group, nano-silica was added to the mixture at the rate of 0.5% by weight of cement (RCA-NS). Furthermore, in the samples of the third group, 30%, 40% and 50% of the natural coarse aggregates were replaced by recycled concrete from recycled coarse aggregates containing used nanosilica, obtained from the samples of the second group at 90 days. Water absorption, fresh concrete slump, compressive strength, SEM, FT-IR, and XRD tests of these three groups were compared.

•
The findings demonstrate that the water absorption of RCA-UNS samples decreased compared to the control sample. • Moreover, the findings of the compressive strength test illustrated that compressive strength in the third group increased 12.8%, 10.9%, and 10% by replacing 30%, 40%, and 50% of NAC with RCA-NS at 28 days compared to control samples.

•
The SEM results confirm previous results such as water absorption and compressive strength and show that the RCA-UNS 30% sample produced extra C-S-H.

•
In addition, the XRD and FT-IR graphs illustrate that in the RCA-UNS samples, more C-H crystal was consumed and converted to C-S-H.

•
For the production of sustainable concrete, 30% of natural coarse aggregates can be replaced with recycled coarse aggregate containing used nano-silica. Therefore, the hydration of cement with water produces C-H crystals while reactions induced by coarse aggregate containing used nano-silica consume the C-H crystals.