Precipitated K-Promoted Co–Mn–Al Mixed Oxides for Direct NO Decomposition: Preparation and Properties

: Direct decomposition of nitric oxide (NO) proceeds over Co–Mn–Al mixed oxides promoted by potassium. In this study, answers to the following questions have been searched: Do the properties of the K-promoted Co–Mn–Al catalysts prepared by di ﬀ erent methods di ﬀ er from each other? The K-precipitated Co–Mn–Al oxide catalysts were prepared by the precipitation of metal nitrates with a solution of K 2 CO 3 / KOH, followed by the washing of the precipitate to di ﬀ erent degrees of residual K amounts, and by cthe alcination of the precursors at 500 ◦ C. The properties of the prepared catalysts were compared with those of the best catalyst prepared by the K-impregnation of a wet cake of Co–Mn–Al oxide precursors. The solids were characterized by chemical analysis, DTG, XRD, N 2 physisorption, FTIR, temperature programmed reduction (H 2 -TPR), temperature programmed CO 2 desorption (CO 2 -TPD), X-ray photoelectron spectrometry (XPS), and the species-resolved thermal alkali desorption method (SR-TAD). The washing of the K-precipitated cake resulted in decreasing the K amount in the solid, which a ﬀ ected the basicity, reducibility, and non-linearly catalytic activity in NO decomposition. The highest activity was found at ca 8 wt.% of K, while that of the best K-impregnated wet cake catalyst was at about 2 wt.% of K. The optimization of the cake washing conditions led to a higher catalytic activity.


Introduction
Nitric oxide (NO) is considered a harmful gas, as it negatively affects the environment by attenuating the ozone layer and contributing to the formation of acid rain and smog [1]. NO is formed by natural processes and anthropogenic activity. This paper is focused on studies of the catalytic processes devoted to the removal of nitrogen oxide from stationary exhaust sources. In principle, primary or secondary methods can be used for NOx emissions abatement. Primary methods aim to prevent NO x formation during combustion processes. Secondary methods reduce the concentration of the already formed NO x . The most commonly used secondary methods include selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) [2,3]. The SNCR proceeds without the presence of a catalyst, but requires high reaction temperatures (above 850 • C) to meet the high efficiency of the process. Such conditions can be achieved in laboratories, but it is not easy to meet them at real industrial conditions, because there are many factors influencing them, and, thus, it is difficult to maintain the detail in Supplementary Table S1. The wet cake of the catalyst precursor obtained by precipitation was gradually washed with demineralized water to obtain five samples with decreasing concentrations of potassium. One fifth of the original cake was removed and left to dry, and the remaining part of the cake was washed with 200 ml of water and filtered again. The procedure was repeated four times to obtain samples "1" to "5" with a gradual decrease of K concentration. In addition to potassium, small amounts of Na was found in the filtrates, most likely originating from the initial compounds used for catalyst preparation.

Phase Composition
X-ray diffraction is the main technique for the investigation of bulk structure, which is very important, as many of the catalyst characteristics depend on it. XRD measurements were used to characterize the dried catalysts precursors. The diffraction patterns of the precipitated samples dried at 60 • C confirmed the presence of a hydrotalcite-like compound (H) with peak maxima at 13.  Figure S1). The gradual washing of the precursors and therefore, the decreasing K concentration, led to the continuous crystallization of the hydrotalcite-like compounds, manifesting itself in higher peaks of hydrotalcite. A slightly lower intensity of the basal (003) and (006) diffraction patterns (detected in the range of 2Theta from 10 to 30 • ) in comparison with non-basal patterns can indicate a lower concentration of preferably orientated layered double hydroxide (LDH) crystals. Apart from hydrotalcite, a K compound (KNO 3 ) at 2Theta 21.95, 34.07, 37.7, 39.55, 48.12, and 54.5 ( • ) was detected in two samples ("1" and "2") with the highest K concentration. Though K 2 CO 3 /KOH was used as the precipitant, KNO 3 was formed during precipitation in the solution by the recombination of ions (metal nitrates were used for catalyst preparation). A decreasing concentration of K in the samples led to the gradual diminution of peaks characteristic for K components in the diffractogram. Nevertheless, a small part of the most intensive peak at 2Theta = 54.5 ( • ) remained preserved, except for the "5" sample, in which a very low concentration of K was determined.

TG and DTG Measurements
Themogravimetry (TG) and differential thermogravimetry (DTG) measurements of the dried "1"-"5" samples showed ( Table 1) three areas of maximum weight decrease manifesting in the ranges of 113-136, 193-213, and 448-558 • C. With decreasing K concentration in the mixed transition metal precursors, the position of the peaks shifted slightly to lower temperatures.
The weight change between 193-213 • C was the most significant (ca 13.5-18%). A somewhat smaller weight decrease (9.5-13.9%) was observed in the stage appearing at the lowest temperatures (113-136 • C). The weight loss in the high temperature region (438-558 • C) was the smallest and varied from 1.5 to 3.7%. To identify the processes taking place in various temperature regions during the temperature treatment of catalyst precursors, an analysis of effluents by mass spectroscopy was carried out during calcination. Three selected precursors differing in K concentration were calcined in helium (0.1 g, temperature ramp 20 K min −1 ), and the results are shown in Figure 1. Desorption of H 2 O was finished at ca 500 • C, with temperature maxima at ca 187 and 250 • C.
The decomposition of nitrates in the catalysts proceeds in two steps, manifesting as a presence of NO and NO 2 in the gas phase. A higher concentration of NO than NO 2 was observed for the catalysts with a K concentration higher than 1 wt.%. Carbonates present in the precursors were decomposed in three stages, the first one (at ca 140 • C) being of lowest intensity. The course of the two following regions (at ca 250 and 400 • C) changed in dependence on K concentration: With a lower K concentration, the temperature maxima shifted slightly to higher temperatures. It is very likely that oxyhydroxides decompose first, and K 2 CO 3 , which remains in the catalysts as a residue of the precipitating agent, decomposes at about 400 • C. The positions of all temperature peak maxima are summarized in Table 2.
Catalysts 2019, 9, x FOR PEER REVIEW 4 of 19 To identify the processes taking place in various temperature regions during the temperature treatment of catalyst precursors, an analysis of effluents by mass spectroscopy was carried out during calcination. Three selected precursors differing in K concentration were calcined in helium (0.1 g, temperature ramp 20 K min −1 ), and the results are shown in Figure 1. Desorption of H2O was finished at ca 500 °C, with temperature maxima at ca 187 and 250 °C.
The decomposition of nitrates in the catalysts proceeds in two steps, manifesting as a presence of NO and NO2 in the gas phase. A higher concentration of NO than NO2 was observed for the catalysts with a K concentration higher than 1 wt.%. Carbonates present in the precursors were decomposed in three stages, the first one (at ca 140 °C) being of lowest intensity. The course of the two following regions (at ca 250 and 400 °C) changed in dependence on K concentration: With a lower K concentration, the temperature maxima shifted slightly to higher temperatures. It is very likely that oxyhydroxides decompose first, and K2CO3, which remains in the catalysts as a residue of the precipitating agent, decomposes at about 400 °C. The positions of all temperature peak maxima are summarized in Table 2. Composition of effluents in A observed by mass spectroscopy during calcination of the "1," "3," and "5" samples in helium (0.2 g of sample, 20 K min −1 ). It can be concluded that the first peak in the DTG measurements can be ascribed to the removal of water, the second one to the decomposition of carbonates and nitrates present in the metal oxyhydroxides, and the third one to the decomposition of carbonates and nitrates present in the precipitates as compounds.

Chemical Composition
The chemical compositions of the catalysts calcined for 4 h at 500 °C are shown in Table 3. Potassium concentration gradually decreased due to washing from 18.9 to 0.6 wt.%. All catalysts, except the one with the highest K concentration, showed molar ratios closely approaching that of the average formula Co:Mn:Al = 4:1.4:1.3. However, the molar ratio of K to Co decreased from the value of 4 for sample "1" to 0.1 for sample "5." The molar ratio of the K-impregnated wet cake catalyst (BP) approached that of the sample "3." Table 3. Composition of the samples calcined 4 h at 500 °C determined by chemical analysis and molar ratios of the metals.

Sample
Wt.% Molar Ratio Figure 1. Composition of effluents in A observed by mass spectroscopy during calcination of the "1", "3", and "5" samples in helium (0.2 g of sample, 20 K min −1 ). It can be concluded that the first peak in the DTG measurements can be ascribed to the removal of water, the second one to the decomposition of carbonates and nitrates present in the metal oxyhydroxides, and the third one to the decomposition of carbonates and nitrates present in the precipitates as compounds.

Chemical Composition
The chemical compositions of the catalysts calcined for 4 h at 500 • C are shown in Table 3. Potassium concentration gradually decreased due to washing from 18.9 to 0.6 wt.%. All catalysts, except the one with the highest K concentration, showed molar ratios closely approaching that of the average formula Co:Mn:Al = 4:1.4:1.3. However, the molar ratio of K to Co decreased from the value of 4 for sample "1" to 0.1 for sample "5". The molar ratio of the K-impregnated wet cake catalyst (BP) approached that of the sample "3". , labelled as C in the diffractograms overlay, seemed to be present in all calcined samples, especially in those having higher K concentration (the "1", "2", and "3" samples). Qiuhua Zhang et al. [17] identified cryptomelane in the calcined precursor formed by a reaction of KMnO 4 and maleic acid at moderate temperatures (300-600 • C). At temperatures above 600 • C, cryptomelane usually transforms into bixbyite (Mn 2 O 3 ), but in the prepared samples, such compound was not detected. Except for the above mentioned phases, the peaks at 27. 26

Phase Composition
The XRD patterns (Figure 2) of the precursors calcined for 4 h at 500 °C exhibited a Co3O4 spinellike structure (labelled as S), which was dominant in all examined samples. Diffraction positions at 21.9, 36.3, 42.7, 52.3, 65.4, 69.8, and 77.2° and the intensity of the peaks are in agreement with the data published for this system (ICDD PDF-2 card No 01-074-1656). Traces of cryptomelane KMn8O16 (ICDD PDF-2 card No 00-006-0547), labelled as C in the diffractograms overlay, seemed to be present in all calcined samples, especially in those having higher K concentration (the "1," "2," and "3" samples). Qiuhua Zhang et al. [17] identified cryptomelane in the calcined precursor formed by a reaction of KMnO4 and maleic acid at moderate temperatures (300-600 °C). At temperatures above 600 °C, cryptomelane usually transforms into bixbyite (Mn2O3), but in the prepared samples, such compound was not detected. Except for the above mentioned phases, the peaks at 27.26, 39.17, 48.0, and 54.65 appeared in diffractograms that were ascribed to potassium nitrate (KNO3) in trigonal crystallographic modification (ICDD PDF-2 card No 01-078-7937). A somewhat lower concentration of the orthorhombic modification of KNO3 was registered at 24.3, 31.55, 34.29, 38.0, 45.79, 50.37, 61.25, 63.91, 79.37, and 81.71° (ICDD PDF-2 card No 01-074-2055) in samples "1" and "2," which were washed only partly. It is also obvious from diffractograms that the examined samples with a higher stage of washing showed better crystallinity than those only partly washed. The effect of potassium concentration in the Co-Mn-Al oxides on spinel lattice parameter a and spinel coherent domains Ld can be seen in Table 4 and Figure 3, respectively. The crystallite size of the spinel was calculated using Scherrer`s formula from the following diffraction lines (220), (311), (400), (511), and (440). The calculated value was corrected to the instrumental broadening (NIST SRM 660b). Recently, Kovanda et al. [18] described the behavior of potassium non-modified Co-Mn-Al  The effect of potassium concentration in the Co-Mn-Al oxides on spinel lattice parameter a and spinel coherent domains L d can be seen in Table 4 and Figure 3, respectively. The crystallite size of the spinel was calculated using Scherrer's formula from the following diffraction lines (220), (311), (400), (511), and (440). The calculated value was corrected to the instrumental broadening (NIST SRM 660b). Recently, Kovanda et al. [18] described the behavior of potassium non-modified Co-Mn-Al mixed oxides during calcination. They found out that the decomposition of Co-Mn-Al layered double hydroxides above 200-260 • C proceeds with the formation of nanocrystalline spinels, and spinels are the only phases present up to 900 • C. At a temperature of about 500 • C, the segregation of the Co-rich spinel was observed, while the incorporation of manganese into the spinel lattice proceeded during its further recrystallization, and this process was accompanied by a lattice parameter decrease. The presence of potassium in Co-Mn-Al oxides could also affect the lattice parameter a of the spinel: One can imagine that in case of no potassium or just a small amount of it in the oxides, manganese enters into the spinel lattice during calcination and decreases the lattice parameter due to the partial distortion of the Co 3 O 4 lattice. With an increasing amount of potassium in the sample, more manganese is bonded to potassium, and, therefore, manganese cannot enter the Co spinel lattice, which is why the spinel lattice parameter a could return to the values characteristic of the Co 3 O 4 phase [19]. However, it is obvious from Table 4 that the presence of the increasing amount of potassium in the K-precipitated Co-Mn-Al oxides caused only small changes (±0.001 nm, less than 0.2 rel.%) in the lattice parameter of the spinel.
The dimension of the spinel coherent domain L d appears to decrease from 9 to 6 nm when the K concentration increases to 2.4 wt.%. With a further increase of K concentration in the solids, the spinel coherent domain started increasing and reached the value of 9 nm at a K concentration equal to 18.9 wt.% ( Figure 3). The course of the dependence seems to correspond to the changes in spinel lattice parameter, but the differences among L d parameters were very small-the observation of the minimum in the dependence could be coincidental. spinels are the only phases present up to 900 °C. At a temperature of about 500 °C, the segregation of the Co-rich spinel was observed, while the incorporation of manganese into the spinel lattice proceeded during its further recrystallization, and this process was accompanied by a lattice parameter decrease. The presence of potassium in Co-Mn-Al oxides could also affect the lattice parameter a of the spinel: One can imagine that in case of no potassium or just a small amount of it in the oxides, manganese enters into the spinel lattice during calcination and decreases the lattice parameter due to the partial distortion of the Co3O4 lattice. With an increasing amount of potassium in the sample, more manganese is bonded to potassium, and, therefore, manganese cannot enter the Co spinel lattice, which is why the spinel lattice parameter a could return to the values characteristic of the Co3O4 phase [19]. However, it is obvious from Table 4 that the presence of the increasing amount of potassium in the K-precipitated Co-Mn-Al oxides caused only small changes (±0.001 nm, less than 0.2 rel.%) in the lattice parameter of the spinel. The dimension of the spinel coherent domain Ld appears to decrease from 9 to 6 nm when the K concentration increases to 2.4 wt.%. With a further increase of K concentration in the solids, the spinel coherent domain started increasing and reached the value of 9 nm at a K concentration equal to 18.9 wt.% ( Figure 3). The course of the dependence seems to correspond to the changes in spinel lattice parameter, but the differences among Ld parameters were very small-the observation of the minimum in the dependence could be coincidental.

Textural Properties
The porous structure of the K-precipitated catalysts was characterized by the adsorption/desorption of nitrogen at −196 °C, and the results are summarized in Table 4. The surface area of the catalysts SBET with a concentration of potassium lower than 2.4 wt.% was about 100 m 2 g −1 .
A higher concentration of potassium in the samples caused a diminution of surface area; the smallest surface was exhibited by the catalyst with 18.9 wt.% K (SBET < 1 m 2 g −1 ). Accordingly, total pore volume increased with the decreasing K concentration in the solids from 266 to 435 mm 3 liq/g. The volume of micropores was small in all cases (less than 5% of total pore volume). The experimental data document that the concentration of potassium in the catalyst higher than 8 wt.% had a negative effect on the porous structure of metal oxides. The phenomenon is likely connected with the collapsing of

Textural Properties
The porous structure of the K-precipitated catalysts was characterized by the adsorption/desorption of nitrogen at −196 • C, and the results are summarized in Table 4. The surface area of the catalysts S BET with a concentration of potassium lower than 2.4 wt.% was about 100 m 2 g −1 . A higher concentration of potassium in the samples caused a diminution of surface area; the smallest surface was exhibited by the catalyst with 18.9 wt.% K (S BET < 1 m 2 g −1 ). Accordingly, total pore volume increased with the decreasing K concentration in the solids from 266 to 435 mm 3 liq /g. The volume of micropores was small in all cases (less than 5% of total pore volume). The experimental data document that the concentration of potassium in the catalyst higher than 8 wt.% had a negative effect on the porous structure of metal oxides. The phenomenon is likely connected with the collapsing of smaller pores and coalescence of larger pores. Table 4. Characteristic physical-chemical data of the samples calcined 4 h at 500 • C.

Sample
S BET (m 2 /g) The adsorption-desorption isotherms of nitrogen ( Figure S2 in Supplementary data) obtained over calcined catalysts confirm that there was not a large difference in pore size distribution among the catalysts with a potassium concentration lower than 2.4 wt.%.

Reducibility
The reducibility of the catalysts with different contents of potassium was studied by H 2 -TPR in the temperature range of 25-900 • C. The H 2 -TPR patterns of the K-precipitated catalysts are depicted in Figure 4. The catalysts were reduced in two main temperature regions, 200-500 • C and >500 • C. The low-temperature reduction peak represents the reduction of Co III → Co II → Co 0 in the Co 3 O 4 -like phase and the reduction of Mn IV to Mn III oxides. The reduction of Mn III → Mn II can take place in both temperature regions [19]. The reduction of the K containing compounds, like cryptomelane KMn 8 O 16 or others, also cannot be excluded in the low temperature region since the reduction of those species proceeds at temperatures between 200-450 • C [20][21][22][23]. In literature, the high temperature peak was ascribed to the reduction of Co and Mn ions surrounded by Al ions in the spinel-like phase [24] and to the reduction of Mn III . The effect of K amount on reducibility in the fresh samples, calcined at 500 • C, is shown in Figure 4. The modification of the Co-Mn-Al mixed oxide by potassium caused significant changes in the obtained reduction profiles. With an increasing K content, a shift to lower temperatures accompanied by the broadening of the peak was observed. A new low temperature peak appeared as a shoulder at around 300 • C. The catalyst with the highest concentration of K (sample "1") was completely reduced in the temperature region 200-500 • C, while all the other catalysts showed a high-temperature reduction peak with a maximum between 614 and 755 • C. The temperature 755 • C was determined for the catalyst with the lowest K concentration. The position of the temperature peak maximum shifted to lower temperatures with increasing K concentration, reaching the value of 614 • C for sample "2". Thus, the positions of T max of the reduction peaks in H 2 -TPR (Table 5) reflected the concentration of K in the catalysts: Increasing the concentration of K (except the highest concentration 18.9 wt.%) led to the easier reduction of the metal mixed oxides. The reduction profile of the catalyst prepared by modified by impregnation of wet cake (BP) was similar as that of the sample "5".
the temperature peak maximum shifted to lower temperatures with increasing K concentration, reaching the value of 614 °C for sample "2." Thus, the positions of Tmax of the reduction peaks in H2-TPR (Table 5) reflected the concentration of K in the catalysts: Increasing the concentration of K (except the highest concentration 18.9 wt.%) led to the easier reduction of the metal mixed oxides. The reduction profile of the catalyst prepared by modified by impregnation of wet cake (BP) was similar as that of the sample "5."

Basicity
Catalyst basicity is an important factor influencing the chemical reactivity of NO because of the acidic nature of the NO molecule [25]. In the CO 2 -TPD profiles of mixed oxides catalysts, several types of basic sites can be recognized. Weak basic sites are attributed to -OH groups occurring on the surface of the catalyst, medium sites consist of oxygen bonded to metal as Me 2+ -O 2− or Me 3+ -O 2− pairs, and strong basic sites are assigned to isolated O 2− anions [26]. Individual peaks below 140 • C can be ascribed to weak basic sites, the peaks appearing in the range of 140-220 • C can be assigned to medium basic sites, and the peaks above 270 • C can be assigned to strong basic sites.
TPD-CO 2 measurements were performed with the aim to find differences in basicity of the fresh catalysts calcined at 500 • C. The effect of potassium content on the amount of basic sites is shown in Figure 5, where the course of CO 2 desorption was recorded on a mass spectrometer (mass contributions m/z = 16 were collected). To avoid damaging the mass spectrometer detector, the temperature rise was finished at about 650 • C. The CO 2 -TPD profiles of the examined samples represent all types of basic sites-weak, medium, and strong-but a strict separation was not possible-even more than three types of sites can be noticeable in some cases. The catalyst with the lowest concentration of K (sample "5") contained weak and medium basic sites with some amount of very strong basic sites with a temperature maximum at 600 • C. The "4" catalyst, having a slightly higher concentration of K (0.9 wt.%) than sample "5", exhibited very similar profiles of CO 2 desorption. A further increase in K concentration (2.4 wt.%) led to a higher amount of medium basic sites with a maximum desorption at 220 • C (Table 5), but stronger basic sites corresponding to CO 2 desorption at about 350 • C also appeared in the catalyst. An even higher concentration of potassium in the catalyst (8.2 wt.%) resulted in a substantial increase of the amount of medium and stronger basic sites desorbing at 275 and 444 • C, respectively. The catalyst with very a high concentration of potassium (18.9 wt.%) exhibited quite different CO 2 desorption profiles: Weak and medium basic sites completely disappeared, and only very strong basic sites remained. The BP catalyst prepared by the K-impregnation of wet cake method (2.1 wt.% K) exhibited a similar amount of basic sites in the range of 25-650 • C as sample "3", having 2.4 wt.% K (Table 5). However, the CO 2 desorption course of the BP catalyst differed slightly from those of the other catalysts ( Figure 5), as it showed a higher amount of stronger and very strong basic sites characterized by CO 2 desorption at T max of about 277 and 630 • C, respectively.

FTIR
Fourier transform infrared spectroscopy (FTIR) can identify various kinds of molecular bonds present in solid samples. The FTIR data of both the examined dried Co-Mn-Al-K hydrotalcite-like precursors and their calcined analogs are shown in Figure 6. In the FTIR spectra of the dried samples, a band at 1355 cm −1 dominated, which is ascribed, according to literature [27], to characteristic CO3 antisymmetric stretching mode vibration. Its presence in the spectra, together with the presence of the OH stretching mode band at 3435 cm −1 (not shown) confirms the formation of hydrotalcite-like compounds during precipitation. In all dried samples, there was also the vibration at 860 cm −1 , which corresponds, according to literature, also to the K2CO3 out-of-plane bending mode [27]. In the case of sample "1," a band at 822 cm −1 corresponded to KNO3 and/or Al(NO3)3 out-of-plane bending mode. A very wide band appeared at 738 cm −1 , which can indicate a metal-to-oxygen bond of very small particles. The band can be ascribed to Al-O vibrations in AlOOH, which could be also formed during metal nitrates precipitation. In the region below 600 cm −1 , other metal-oxygen bonds also occurred that cannot be ascribed with certainty.
The FTIR spectra of the calcined samples show unique bands at 657 cm −1 and approximately 552 cm −1 . Both bands can indicate the presence of Co3O4, MnO2, Mn3O4 [28], or cryptomelane [29]. Potter et al. [29] attributed a band at 550 cm −1 unambiguously to cryptomelane. Though Co3O4 shows the closest IR spectrum to those of analyzed samples, the presence of cryptomelane cannot be excluded. Samples "1" and "2," with the highest concentration of K, also exhibited KNO3 vibrations. By comparing the spectra with references, the presence of other substances in the catalysts was excluded. KNO3 bands split into pairs 824 and 1372 cm −1 and pairs 833 and 1347 cm −1 , respectively, the first pair being more tightly bound, i.e., worse washed out. This splitting of the bands could be explained by the different structure of KNO3 (calcite-trigonal and aragonite-orthorhombic). The aragonite structure arises from the violation of symmetry (for example by adsorption, change of environment, or recrystallization), thereby increasing the intensity of the originally inactive vibrations [30]. The calcined BP catalyst prepared by bulk promotion exhibits, in principle, the same IR spectrum as the K-precipitated catalyst having nearly the same K concentration (sample "3"). However, it showed slightly higher amount of nitrates (bands at about 1350 and 830 cm −1 ).  Figure 6. In the FTIR spectra of the dried samples, a band at 1355 cm −1 dominated, which is ascribed, according to literature [27], to characteristic CO 3 antisymmetric stretching mode vibration. Its presence in the spectra, together with the presence of the OH stretching mode band at 3435 cm −1 (not shown) confirms the formation of hydrotalcite-like compounds during precipitation. In all dried samples, there was also the vibration at 860 cm −1 , which corresponds, according to literature, also to the K 2 CO 3 out-of-plane bending mode [27]. In the case of sample "1", a band at 822 cm −1 corresponded to KNO 3 and/or Al(NO 3 ) 3 out-of-plane bending mode. A very wide band appeared at 738 cm −1 , which can indicate a metal-to-oxygen bond of very small particles. The band can be ascribed to Al-O vibrations in AlOOH, which could be also formed during metal nitrates precipitation. In the region below 600 cm −1 , other metal-oxygen bonds also occurred that cannot be ascribed with certainty.
The FTIR spectra of the calcined samples show unique bands at 657 cm −1 and approximately 552 cm −1 . Both bands can indicate the presence of Co 3 O 4 , MnO 2 , Mn 3 O 4 [28], or cryptomelane [29]. Potter et al. [29] attributed a band at 550 cm −1 unambiguously to cryptomelane. Though Co 3 O 4 shows the closest IR spectrum to those of analyzed samples, the presence of cryptomelane cannot be excluded. Samples "1" and "2", with the highest concentration of K, also exhibited KNO 3 vibrations. By comparing the spectra with references, the presence of other substances in the catalysts was excluded. KNO 3 bands split into pairs 824 and 1372 cm −1 and pairs 833 and 1347 cm −1 , respectively, the first pair being more tightly bound, i.e., worse washed out. This splitting of the bands could be explained by the different structure of KNO 3 (calcite-trigonal and aragonite-orthorhombic). The aragonite structure arises from the violation of symmetry (for example by adsorption, change of environment, or recrystallization), thereby increasing the intensity of the originally inactive vibrations [30]. The calcined BP catalyst prepared by bulk promotion exhibits, in principle, the same IR spectrum as the K-precipitated catalyst having nearly the same K concentration (sample "3"). However, it showed slightly higher amount of nitrates (bands at about 1350 and 830 cm −1 ).  6. FTIR data of the dried and calcined K-precipitated Co-Mn-Al-K mixed oxides and Kimpregnated wet cake catalyst (BP) catalyst. Curves from top to bottom: Samples "1," "2," …., "5."

Surface Composition
The surface compositions in the near-surface region and chemical state of the elements of the fresh K-precipitated catalysts were determined by XPS. As the catalytic measurements proceeded at reaction temperatures 650-700 °C, the catalysts were calcined at 700 °C, and, therefore, the properties of the catalysts' surfaces calcined at 700 °C were examined. The surface concentrations of the elements were determined from the intensities (peak areas) divided by the corresponding response factor [31]. Carbon tape used for fixing of the samples to the holder manifested itself in a relatively high concentration of C (28-35 at. %) ( Table 6). Nevertheless, the calibration of the spectra was carried out according to carbon (284.8 eV). In the fresh K-precipitated samples calcined at 700 °C, 44 at. % of O, 8.7 at. % of Co, 3.3 at. % of Mn, 7.2 at. % of Al, and 3.3 at. % of K-in average-were determined ( Table 7). The gradual washing of the precursor with distilled water resulted in a progressive decrease of K concentration and, at the same time, in the enhancement of other metal elements in the catalysts. In all catalysts, manganese occurred in a higher oxidation state, very likely as Mn +4 , most likely MnO2. Aluminum looked very similar in all samples and was probably Al2O3, though the position of the peak is shifted slightly in comparison with published data. In all samples, potassium occurred in an identical form, very likely bounded to metal oxide (KMnO4, KMn8O16, KCoO2, or a similar compound).
The deconvolution of oxygen spectra revealed two peaks (Table 6) with binding energies of about 529.8 and 531.5 eV. The first one at 529.8 eV can be ascribed to metal oxide (lattice oxygen O 2− ), and the second at 531.5 eV can be ascribed to the adsorbed surface oxygen bound to metal oxides as O2 − , O − , or OH − species.
In contrast to the K-precipitated catalysts, the K-impregnated wet cake (BP) catalyst calcined at 700 °C exhibited 54 at. % of O, 13.7 at. % of Co, 6.1 at. % of Mn, 8.1 at. % of Al, 5.2 at. % of K, and 12.5 at. % of C (Table 6). It is obvious that the surface Co concentration of the BP catalyst was the highest of all examined catalysts, and the K concentration was the second highest. The distinctions are certainly a result of different preparation procedures of the examined catalysts.  Figure 6. FTIR data of the dried and calcined K-precipitated Co-Mn-Al-K mixed oxides and K-impregnated wet cake catalyst (BP) catalyst. Curves from top to bottom: Samples "1", "2", . . . , "5".

Surface Composition
The surface compositions in the near-surface region and chemical state of the elements of the fresh K-precipitated catalysts were determined by XPS. As the catalytic measurements proceeded at reaction temperatures 650-700 • C, the catalysts were calcined at 700 • C, and, therefore, the properties of the catalysts' surfaces calcined at 700 • C were examined. The surface concentrations of the elements were determined from the intensities (peak areas) divided by the corresponding response factor [31]. Carbon tape used for fixing of the samples to the holder manifested itself in a relatively high concentration of C (28-35 at. %) ( Table 6). Nevertheless, the calibration of the spectra was carried out according to carbon (284.8 eV). In the fresh K-precipitated samples calcined at 700 • C, 44 at. % of O, 8.7 at. % of Co, 3.3 at. % of Mn, 7.2 at. % of Al, and 3.3 at. % of K-in average-were determined ( Table 7). The gradual washing of the precursor with distilled water resulted in a progressive decrease of K concentration and, at the same time, in the enhancement of other metal elements in the catalysts. In all catalysts, manganese occurred in a higher oxidation state, very likely as Mn +4 , most likely MnO 2 . Aluminum looked very similar in all samples and was probably Al 2 O 3 , though the position of the peak is shifted slightly in comparison with published data. In all samples, potassium occurred in an identical form, very likely bounded to metal oxide (KMnO 4 , KMn 8 O 16 , KCoO 2 , or a similar compound).
The deconvolution of oxygen spectra revealed two peaks (Table 6) with binding energies of about 529.8 and 531.5 eV. The first one at 529.8 eV can be ascribed to metal oxide (lattice oxygen O 2− ), and the second at 531.5 eV can be ascribed to the adsorbed surface oxygen bound to metal oxides as O 2 − , O − , or OH − species. In contrast to the K-precipitated catalysts, the K-impregnated wet cake (BP) catalyst calcined at 700 • C exhibited 54 at. % of O, 13.7 at. % of Co, 6.1 at. % of Mn, 8.1 at. % of Al, 5.2 at. % of K, and 12.5 at. % of C (Table 6). It is obvious that the surface Co concentration of the BP catalyst was the highest of all examined catalysts, and the K concentration was the second highest. The distinctions are certainly a result of different preparation procedures of the examined catalysts. The surface and bulk concentrations of the main catalyst components (in wt.%) are summarized in Table 7. A comparison of both groups of values indicates that the surface of the catalyst prepared by calcination of the non-washed K-precipitated catalyst precursor was substantially enriched by aluminum (2.5 times) and only slightly enriched by manganese and potassium (in both cases 1.2 times) at the expense of cobalt, which was reduced 0.8 times. The gradual washing of the precipitates by water led to the further enrichment of the catalyst surface by aluminum (3.3 times) at the expense of potassium. Manganese and cobalt surface concentrations practically did not change with the washing of the precipitates. Potassium concentration on the surface and in the bulk also practically did not differ with washing, which indicates the relatively high stability of potassium in the K-precipitated catalyst at calcination temperatures around 700 • C.
Somewhat different relation of surface and bulk composition can be observed for the BP catalyst. The surface concentration of K was more than four times higher than the bulk, while the surface concentration of cobalt was about two thirds of the bulk. Additionally in this sample, surface is enriched by aluminum. The data indicates that the addition of KNO 3 to the wet cake of Co-Mn-Al hydrotalcite-like led to the preferential adsorption of K to Co.

Species-Resolved Thermal Alkali Desorption (SR-TAD)
The stability of alkali metals on the catalyst surface was studied by species resolved thermal alkali desorption (SR-TAD). The results of two selected samples prepared by two different methods of K promotion and calcined at 700 • C were compared (Figure 7). Since desorption of K atoms was more significant than the potassium desorption in the form of ions, only desorption of alkali metal atoms (atom fluxes) during heating was observed. It is obvious from the temperature-dependent changes of atomic fluxes (Figure 9) that potassium desorption already occurs at temperatures higher than 450 °C, what means that the desorption of alkali metals is possible at the temperatures used for calcinations and during NO direct decomposition testing. The same non-monotonic curves in the desorption signal with rising temperature were observed for both samples, which indicates that the potassium promoter leaves the surface through a single energy barrier, and the distribution of the promoter on the catalysts surface here was homogenous [32]. Since the dependence was the same for both differently prepared samples, the resulting potassium surface state should be the same in both samples.
Interestingly, the K atomic desorption flux profiles were different for heating and cooling periods (not shown) for both samples. A slightly higher desorption flux during cooling was observed. A higher signal during cooling than during heating means that some potassium was segregated on the catalyst surface during heating. Different flux profiles obtained during heating and cooling point to potassium migration processes which took place during the measurement-diffusion inside the bulk, agglomeration on the surface, and thermal desorption [33]. These processes probably also take place during the catalytic reaction.

Activity of the Catalysts in Decomposition of NO
The effect of potassium amount on the catalytic activity of K promoted Co-Mn-Al mixed oxides in direct NO decomposition was studied over the catalysts prepared by coprecipitation of metal nitrates with a K2CO3/KOH solution and compared with the activity of the catalyst prepared by the K-impregnation of wet cake. Catalytic activity was determined over the catalysts calcined for 4 h at 700 °C. We found that activity of all samples slightly increased with the increasing time-on-stream. After 13 h, the activity reached stable values. In this initial period of catalyst testing, potassium was likely migrating from the interior of the catalyst grains to their surface. The steady state NO conversions obtained over the catalysts with various K concentrations at 650 and 700 °C are depicted in Figure 8 in comparison with that of the catalyst BP prepared by the K-impregnation of wet cake [19]. The highest conversion of NO (ca 61%) was observed at 700 °C in the presence of the catalyst containing about 8 wt.% K prepared by the coprecipitation of metal nitrates with a K2CO3/KOH solution. Lower and higher K content led to the decrease of NO conversion, and, for K content lower than 0.6 wt.%, NO catalytic decomposition was not observed at all. The promotional effect of K has already been well described in the case of N2O catalytic decomposition over K-promoted Co-Mn-Al It is obvious from the temperature-dependent changes of atomic fluxes (Figure 9) that potassium desorption already occurs at temperatures higher than 450 • C, what means that the desorption of alkali metals is possible at the temperatures used for calcinations and during NO direct decomposition testing. The same non-monotonic curves in the desorption signal with rising temperature were observed for both samples, which indicates that the potassium promoter leaves the surface through a single energy barrier, and the distribution of the promoter on the catalysts surface here was homogenous [32]. Since the dependence was the same for both differently prepared samples, the resulting potassium surface state should be the same in both samples.
Interestingly, the K atomic desorption flux profiles were different for heating and cooling periods (not shown) for both samples. A slightly higher desorption flux during cooling was observed. A higher signal during cooling than during heating means that some potassium was segregated on the catalyst surface during heating. Different flux profiles obtained during heating and cooling point to potassium migration processes which took place during the measurement-diffusion inside the bulk, agglomeration on the surface, and thermal desorption [33]. These processes probably also take place during the catalytic reaction.

Activity of the Catalysts in Decomposition of NO
The effect of potassium amount on the catalytic activity of K promoted Co-Mn-Al mixed oxides in direct NO decomposition was studied over the catalysts prepared by coprecipitation of metal nitrates with a K 2 CO 3 /KOH solution and compared with the activity of the catalyst prepared by the K-impregnation of wet cake. Catalytic activity was determined over the catalysts calcined for 4 h at 700 • C. We found that activity of all samples slightly increased with the increasing time-on-stream. After 13 h, the activity reached stable values. In this initial period of catalyst testing, potassium was likely migrating from the interior of the catalyst grains to their surface. The steady state NO conversions obtained over the catalysts with various K concentrations at 650 and 700 • C are depicted in Figure 8 in comparison with that of the catalyst BP prepared by the K-impregnation of wet cake [19]. The highest conversion of NO (ca 61%) was observed at 700 • C in the presence of the catalyst containing about 8 wt.% K prepared by the coprecipitation of metal nitrates with a K 2 CO 3 /KOH solution. Lower and higher K content led to the decrease of NO conversion, and, for K content lower than 0.6 wt.%, NO catalytic decomposition was not observed at all. The promotional effect of K has already been well described in the case of N 2 O catalytic decomposition over K-promoted Co-Mn-Al mixed oxides [34]. Potassium, due to its low ionization potential, enables the charge transfer to the transition metal cations, inducing an electric field gradient at the surface generated by the resulting dipole and the modification of the density of states characteristics. When K content was higher than the optimal amount, depolarization occurred, leading to the decrease of NO conversion. transition metal cations, inducing an electric field gradient at the surface generated by the resulting dipole and the modification of the density of states characteristics. When K content was higher than the optimal amount, depolarization occurred, leading to the decrease of NO conversion.

Effect of O2 and CO2 in the Reactant on Catalytic Activity
As flue gases from power plants contain some amount of other constituents, not only NO, the effect of oxygen or CO2 in the reactant on catalytic activity was studied with the most active sample "2" at reaction temperature 700 °C. The concentration of both components varied gradually from 1 to 10 molar %. The obtained results are depicted in Figure 9. The effect of both added reaction components was similar: The highest decrease in activity was observed after the addition of their lowest concentration (1 mol %)-however, the effect on initial catalytic activity decrease differed: The presence of O2 caused a slower decrease in activity than CO2. However, higher concentrations of O2 or CO2 (about 4 mol %) showed a nearly identical decrease in catalytic activity. Very likely, the adsorption of both components either blocked adsorption of NO or slowed down desorption of N2 and O2.

Effect of O 2 and CO 2 in the Reactant on Catalytic Activity
As flue gases from power plants contain some amount of other constituents, not only NO, the effect of oxygen or CO 2 in the reactant on catalytic activity was studied with the most active sample "2" at reaction temperature 700 • C. The concentration of both components varied gradually from 1 to 10 molar %. The obtained results are depicted in Figure 9. The effect of both added reaction components was similar: The highest decrease in activity was observed after the addition of their lowest concentration (1 mol %)-however, the effect on initial catalytic activity decrease differed: The presence of O 2 caused a slower decrease in activity than CO 2 . However, higher concentrations of O 2 or CO 2 (about 4 mol %) showed a nearly identical decrease in catalytic activity. Very likely, the adsorption of both components either blocked adsorption of NO or slowed down desorption of N 2 and O 2 .

Discussion
In this paper, a method of the preparation of the potassium promoted Co-Mn-Al mixed oxide catalyst (K-precipitated) was examined. An alternative method of the preparation of potassium promoted Co-Mn-Al mixed oxide consists of the precipitation of metal nitrates with potassium salts (K 2 CO 3 /KOH) and of the consecutive gradual washing of the precipitate to obtain a specific concentration of K in the calcined catalyst. The application of the preparation procedure led to the catalysts with various concentration of potassium whose physical-chemical properties were studied. Their properties were compared with those of the catalyst prepared by the K-impregnation wet cake method.
As shown in the XRD profiles of the calcined catalysts, both kinds of catalysts with similar K content, the K-precipitated sample "3" and BP, contained identical crystallographic phases of the compounds (Figure 2). However, the dimension of coherent domain of spinel (L d ) was somewhat higher for the BP catalyst (9.3 nm) than for the K-precipitated catalyst with a corresponding K amount (6.6 nm)-see Table 4. This finding reflects a slightly lower surface area and a higher total volume of pores and of micropores of the BP catalyst.
FTIR measurements proved that the BP catalyst comprises more nitrates than the K-precipitated catalyst of corresponding composition ( Figure 6). It could not cohere with a slightly lower concentration of potassium in the BP catalyst (2.1 wt.%) than the compared catalyst (2.4 wt.%). The phenomenon had to correspond with the way of KNO 3 addition: In the case of the BP catalyst, KNO 3 was likely deposited on the surface of the primary precipitated particles, while, in the case of the washed K-precipitated catalysts, KNO 3 was included in the structure of the hydrotalcite-like compound formed during the precipitation of metal nitrates with a solution of K 2 CO 3 /KOH.
The presence of nitrates was reflected in the basicity of the BP catalyst ( Figure 5, Table 5), which exhibited a lower amount of stronger basic sites (T max of CO 2 desorption > 220 • C) than the K-precipitated Co-Mn-Al oxide catalyst, with 2.4 wt.% K. Nitrates in the BP catalyst contributed to a higher degree of acidity of the catalyst surface and, thus, to lower basicity. H 2 -TPR did not show any significant difference in the reducibility of both kinds of the compared catalysts. The catalyst with ca 8 wt.% of K exhibited the lowest T max temperatures in the TPR curves of all samples, thus indicating the easiest reducibility of the transition metals mixed oxides. The reduction profile of the catalyst prepared by K-impregnation of wet cake (BP) was similar to that of sample "5", which had a three times lower concentration of potassium and therefore documented the lower redox properties of the BP catalyst.
A comparison of the XPS and chemical analysis data for the K-precipitated and BP catalysts led to the following statement: The K-precipitation method of Co-Mn-Al catalysts made uniform distribution of potassium in the catalyst particles possible, while the K-impregnated wet cake method caused the significant enrichment of the catalyst surface by potassium at the expense of cobalt. That is why the optimum concentration of potassium (determined by chemical analysis), which was necessary to obtain the highest NO conversion, was lower [19] in the case of BP preparation method (about 2 wt.%) than in the case of the K-precipitation method (about 8 wt.%).
The catalytic activity of the K-precipitated Co-Mn-Al oxide catalysts in direct decomposition of NO varied with the concentration of K in the solids. It went through maximum at about 8 wt.% K in the solid and decreased when lower and higher K concentrations were present in the catalysts than this optimum value (Figure 8). The BP catalyst exhibited a slightly lower catalytic activity, caused, very likely, by a slightly lower surface area of the catalyst or lower amount of basic sites on the catalyst surface, which substantially affected the sorption of NO on the catalyst surface and/or a slightly lower reducibility of the catalyst.
In Figure 10, the dependence of NO conversions on number of K atoms per nm 2 of the catalyst is depicted. The optimum number of K atoms on the surface is around 10 atoms per nm 2 . With a decrease of this number, the conversion of NO sharply decreased, and, at the value of 1 atom per nm 2 conversion of NO approached zero. On the other hand, the decrease in NO conversion with an increasing number of atoms per nm 2 was not so sharp, and, for that reason, a slightly higher number of K atoms per nm 2 in the case of K concentration fluctuation is better than vice versa.
Catalysts 2019, 9, x FOR PEER REVIEW 15 of 19 decrease of this number, the conversion of NO sharply decreased, and, at the value of 1 atom per nm 2 conversion of NO approached zero. On the other hand, the decrease in NO conversion with an increasing number of atoms per nm 2 was not so sharp, and, for that reason, a slightly higher number of K atoms per nm 2 in the case of K concentration fluctuation is better than vice versa.

Preparation of Catalysts
Co-Mn-Al mixed oxides modified by K were prepared by the co-precipitation of the 210 mL solution of 40 g Co(NO3)2·6H2O, 8.7 g Mn(NO3)2·H2O, and 12.9 g Al(NO3)3·9H2O with the 225 mL aqueous solution of 14.5 g K2CO3 and 29.7 g KOH. The solutions were dosed to a vessel equipped with a magnetic Triga stirrer (500 revolutions min −1 ), in which 100 mL of water were mixed with such an amount of KOH that the solution maintained a pH = 10. The rate of dosing of each solution was ca 1.9 mL/min, the pH of precipitation 10 ± 0.1, and the temperature was 22 °C. The resulting suspension was mixed for 60 min at laboratory temperature.
Then, the suspension was filtered off, and the precipitate was washed with ca 200 mL of water after removing ca one fifth of the precipitate to obtain different levels of K concentration in the samples. The washed samples were dried for 12 h at 60 °C and calcined at 500 °C. Numbers "1" to "5" labeled the prepared catalysts, with sample "1" having the highest concentration of K and sample "5" having the lowest.
For comparison, a catalyst prepared by the co-precipitation of transition metal nitrates by Na2CO3/NaOH solution and the subsequent impregnation of the resulting wet cake by a solution of KNO3 (K-impregnated wet cake method) was labeled, after drying and calcination, as BP.

Characterization of the Samples
The content of metals in the prepared catalysts was determined by atomic emission spectroscopy with microwave plasma using an Avio 500 MP-AES (Perkin-Elmer, Chichester, UK) after the dissolution of the samples in diluted (2%) hydrochloric acid.
Phase composition and microstructural properties were determined using an X-ray powder diffraction (XRD) technique. XRD patterns were obtained using a Rigaku SmartLab diffractometer (Rigaku, Tokyo, Japan) equipped with a D/teX Ultra 250 detector. The source of X-ray irradiation was a Co tube (CoKα, λ1 = 0.178892 nm, λ2 = 0.179278 nm) operated at 40 kV and 40 mA. Incident and

Preparation of Catalysts
Co-Mn-Al mixed oxides modified by K were prepared by the co-precipitation of the 210 mL solution of 40 g Co(NO 3 ) 2 ·6H 2 O, 8.7 g Mn(NO 3 ) 2 ·H 2 O, and 12.9 g Al(NO 3 ) 3 ·9H 2 O with the 225 mL aqueous solution of 14.5 g K 2 CO 3 and 29.7 g KOH. The solutions were dosed to a vessel equipped with a magnetic Triga stirrer (500 revolutions min −1 ), in which 100 mL of water were mixed with such an amount of KOH that the solution maintained a pH = 10. The rate of dosing of each solution was ca 1.9 mL/min, the pH of precipitation 10 ± 0.1, and the temperature was 22 • C. The resulting suspension was mixed for 60 min at laboratory temperature.
Then, the suspension was filtered off, and the precipitate was washed with ca 200 mL of water after removing ca one fifth of the precipitate to obtain different levels of K concentration in the samples. The washed samples were dried for 12 h at 60 • C and calcined at 500 • C. Numbers "1" to "5" labeled the prepared catalysts, with sample "1" having the highest concentration of K and sample "5" having the lowest.
For comparison, a catalyst prepared by the co-precipitation of transition metal nitrates by Na 2 CO 3 /NaOH solution and the subsequent impregnation of the resulting wet cake by a solution of KNO 3 (K-impregnated wet cake method) was labeled, after drying and calcination, as BP.

Characterization of the Samples
The content of metals in the prepared catalysts was determined by atomic emission spectroscopy with microwave plasma using an Avio 500 MP-AES (Perkin-Elmer, Chichester, UK) after the dissolution of the samples in diluted (2%) hydrochloric acid.
Phase composition and microstructural properties were determined using an X-ray powder diffraction (XRD) technique. XRD patterns were obtained using a Rigaku SmartLab diffractometer (Rigaku, Tokyo, Japan) equipped with a D/teX Ultra 250 detector. The source of X-ray irradiation was a Co tube (CoKα, λ 1 = 0.178892 nm, λ 2 = 0.179278 nm) operated at 40 kV and 40 mA. Incident and diffracted beam optics were equipped with 5 • Soller slits; incident slits were set up to irradiate a 10 × 10 mm area of the sample (automatic divergence slits) constantly. The slits on the diffracted beam were set up to a fixed value of 8 and 14 mm. The powder samples were gently grinded using an agate mortar before analysis, pressed using microscope glass in a rotational sample holder, and measured in reflection mode (Bragg-Brentano geometry). The samples were rotated (30 rpm) during the measurement to eliminate the preferred orientation effect. The XRD patterns were collected in a 2θ range 5 • -90 • with a step size of 0.01 • and speed of 0.5 deg.min −1 . The measured XRD patterns were evaluated using the PDXL 2 software (version 2.4.2.0) and compared with the PDF-2 database issued by ICDD, released in 2015. Nitrogen physisorption on catalyst powders (grain size 0.16-0.32 mm) was performed using an ASAP 2020 Micromeritics instrument (Norcross, Atlanta, GA, USA) after degassing at 105 • C for 24 h at 1 Pa vacuum. The adsorption-desorption isotherms of nitrogen at 77 K were evaluated by the standard Brunauer-Emmett-Teller (BET) procedure [35] for the p/p 0 range = 0.05-0.25 to calculate the specific surface area S BET . Mesopore surface areas, S meso , and micropore volume, V micro , were determined by the t-plot method [36]. The total pore volume, V total , was determined from the nitrogen adsorption isotherm at maximum p/p 0 (∼0.995). The pore-size distribution (pore radius 10 0 -10 2 nm) was evaluated from the adsorption branch of the nitrogen adsorption-desorption isotherm by the Barrett-Joyner-Halenda (BJH) method [37], assuming a cylindrical pore geometry. The Lecloux-Pirard standard isotherm [38] was used for the t-plot and for the pore-size distribution evaluation.
Temperature programmed reduction (H 2 -TPR) measurements were performed with a H 2 /N 2 mixture (10 mol % H 2 ), flow rate 50 mL min −1 and a linear temperature increase of 20 • C min −1 up to 900 • C. Changes in H 2 concentration were detected with a catharometer. A reduction of grained CuO (0.160-0.315 mm) was performed to calculate the absolute values of the hydrogen consumed during reduction of the samples.
The temperature-programmed desorption of CO 2 (CO 2 -TPD) was carried out to examine basic properties of the catalysts surface. The measurements were accomplished with a 0.050 g sample in the temperature range of 20-900 • C, with helium as a carrier gas and CO 2 as the adsorbing gas. Prior to the CO 2 -TPD measurement, the sample was heated in helium from 25 to 500 • C with a temperature ramp of 20 • C min −1 ; then, the sample was cooled in helium to 25 • C. Ten doses of CO 2 , 840 µL each, were applied to the catalyst sample at 30 • C before flushing with He for 1 h and heating at a rate of 20 • C min −1 . The composition of the gases evolved during the experiments was determined by a mass spectrometer (Balzers, Pfeiffer Vacuum, Asslar, Germany). The following mass contributions m/z were collected: 2-H 2 and 44-CO 2 . The spectrometer was calibrated by dosing the known amount of CO 2 into the carrier gas (He) in every experiment. The H 2 -TPR and CO 2 -TPD experiments were evaluated using OriginPro 8.0 software with an accuracy of ±5%.
The thermal decomposition of dried materials was conducted by heating the 10 mg of samples to 700 • C at a rate of 2 • C/min, using a NETZSCH TG 209 F1 Libra (Selb, Germany) recording microbalances in a stream of inert gas (Ar) at a flow rate 50 mL/min. The sample was heated in the oven, the output of which was regulated by a programmable digital temperature controller. The flow of carrier gas was controlled by electronic mass flowmeters.
A Nicolet Model 360 Avatar FT-IR spectrometer (Analytical Instruments Brokers LLC, Golden Valley, MN, U.S.A.) was used in an attenuated total reflection (ATR) mode to obtain the spectra from catalysts between 360 and 4000 cm −1 (resolution 1.93 cm −1 , 300 scans, 1 s per scan) when the powder was pressed against ZnSe crystal (working range between 508 and 4000 cm −1 ). All spectra were obtained at laboratory temperature (~22 • C) and atmospheric pressure.
The thermal stability of the alkali metal promoters was investigated by the species resolved thermal alkali desorption (SR-TAD) method. The experiments were carried out in a vacuum apparatus with a background pressure of 10 −7 kPa. The samples in the form of wafers (13 mm diameter, 200 mg weight) were heated at the rate of 5 • C min −1 from room temperature up to 650 • C in a stepwise voltage-controlled mode. Then, they were cooled down at the same rate. The desorption flux of potassium atoms was determined by means of a surface ionization detector, consisting of a platinum wire heated by a current of 2.2 A, to approximately 1000 • C, with a positive potential of +120 V causing the ionization of the desorbed atoms and their acceleration towards the collector. During the measurements, the samples were biased with a positive potential +5 V to quench the thermal emission of electrons. In this way, the possibility of the reneutralization of ions by thermal electrons outside the surface was effectively eliminated. The resulting positive current was directly measured with a Keithley 6512 digital electrometer.
Superficial elemental analyses were performed by XPS (X-ray photoelectron spectrometry ESCA 3400, Kratos, Manchester, UK) at a base pressure better than 5 × 10 −7 Pa, using the polychromatic Mg X-ray source (Mg Kα, 1253.4 eV). The composition of the elements was determined without any annealing. For the spectra, the Shirley background was subtracted, and the elemental compositions of layers were calculated from the corresponding areas.
The catalytic decomposition of NO to N 2 and O 2 was performed in an integral fixed bed stainless steel reactor of 5 mm internal diameter (650 • C or 700 • C, 0.5 g, 49 mL min −1 ). To some catalytic runs, oxygen (0-10 mol%) was added to an inlet gas composed of 1000 ppm NO in N 2 . The catalysts (fraction 0.16-0.316 mm) pre-calcined at 700 • C were activated in 50 mL of N 2 + O 2 min −1 (101325 Pa, 20 • C) for 1 h at 650 • C. Then, the NO catalytic decomposition at 650 • C was measured at least for 15 h. After this period, when a stable performance was observed, the temperature dependence of conversion was launched with cooling rate of 5 • C min −1 , and the catalysts activity was measured for 3 h at each temperature (640 • C, 620 • C, 600 • C, 580 • C, and 560 • C). After the conversion curve measurement, the reactor was heated back to 650 • C in order to check the stability of the catalyst. In case the performance was stable, the catalyst was heated to 700 • C, and the steady state conversion at 700 • C was measured. When the oxygen was added to the inlet mixture, it took 1 h at minimum to achieve steady state performance. Infrared analyzers for the online analysis of NO (Ultramat 6, Siemens, Karlsruhe, Germany) and N 2 O (Sick) were used. During all measurements, no N 2 O and no NO 2 were detected, as proven by the low-temperature NO 2 /NO catalytic convertor (TESO Ltd.). The activity of the catalysts was determined as conversions of NO from the relation X NO = (c NO 0 − c NO )/c NO 0 , where X NO is NO conversions, c NO 0 is the initial NO concentration, and c NO is the NO concentration at reactor outlet.

Conclusions
The investigated process of the K promoted Co-Mn-Al catalyst preparation consisting of the precipitation of transition metal nitrates with a solution of K 2 CO 3 /KOH is simpler than the other possible ways of preparation, e.g., the K-impregnation of wet cake method. When using the examined process of preparation, it is possible to obtain a catalyst with a desired K concentration in the solids without any additional preparation steps. The concentration of potassium affected catalytic activity of the K-precipitated catalysts in direct NO decomposition, the highest being at ca 8 wt.% of K, while that of the K-impregnated wet cake samples was about 2 wt.%. We believe that the incorporation of potassium into the catalyst particle structure positively influences catalyst stability, as the potassium inside the catalyst particles serves as its reservoir when it desorbs from the surface during catalytic reaction.