TiO 2 /Zeolite Composites for SMX Degradation under UV Irradiation

: Sulfamethoxazole (SMX) is a common antibiotic that is considered an emerging pollutant of water bodies, as it is toxic for various aquatic species. TiO 2 -based photocatalysis is a promising method for SMX degradation in water. In this work, TiO 2 /zeolite (Z-45 loaded with TiO 2 labeled as TZ and ZSM-5 loaded with TiO 2 labeled as TZSM) composites were prepared by mechanical mixing and liquid impregnation methods, and the photocatalytic performance of these composites (200 mg · L − 1 ) was investigated toward the degradation of SMX (30 mg · L − 1 ) in water under UV light (365 nm). The pseudo-first-order reaction rate constant of the TZSM1450 composite was 0.501 min − 1 , which was 2.08 times higher than that of TiO 2 (k = 0.241 min − 1 ). Complete SMX degradation was observed in 10 min using the UV/TZSM1450 system. The mineralization ability in terms of total organic carbon (TOC) removal was also assessed for all of the prepared composites. The results showed that 65% and 67% of SMX could be mineralized within 120 min of photocatalytic reaction by TZSM2600 and TZSM1450, respectively. The presence of Cl − and CO 2 − 3 anions inhibited the degradation of SMX, while the presence of NO − 3 had almost no effect on the degradation efficiency of the UV/TZSM1450 system. The electrical energy per order estimated for the prepared composites was in the range of 68.53–946.48 kWh m − 3 order − 1 . The results obtained revealed that the TZSM1450 composite shows promising potential as a photocatalyst for both the degradation and mineralization of SMX.


Introduction
The occurrence of antibiotics in aquatic environments has posed considerable threats to the environment and human health [1,2].The discharge from wastewater treatment plants (WWTPs) significantly contributes to the presence of these compounds in water, establishing them as a major source of antibiotics in aquatic ecosystems [3,4].Among various antibiotics, sulfamethoxazole (SMX) is one of the most widespread sulfonamides, mainly applied in human and veterinary medicine to cure bacterial infections [5,6], and therefore has been considered as one of the representatives of antibiotics in livestock wastewater [7].Due to the incomplete metabolization of SMX by living beings and its high persistence [8], most of the consumed SMX can enter the water systems through excreta [9], eventually threatening aquatic organisms and human health.The concentration of SMX frequently detected in different types of water including wastewater effluent, surface water, and groundwater [10] ranges from ng•L −1 to µg•L −1 [11,12].SMX cannot be removed by traditional treatment processes, which is ascribed to its non-biodegradable characteristics [13,14].
Catalysts 2024, 14, 147 2 of 16 Hence, there is a need for an effective method to eliminate it from water.Recently, various approaches have been used to treat SMX-containing wastewater [14].
Heterogeneous photocatalysis has received growing attention for the effective degradation and mineralization of persistent organic pollutants [15,16].Different catalysts have been investigated to degrade SMX under the use of light irradiation.Among them, titanium dioxide (TiO 2 ), which is a semiconductor photocatalyst, has a prominent place in photocatalysis [17], since it can decompose toxic organic pollutants in water by generating active species (•OH) with high oxidation potential.Even though TiO 2 possesses chemical stability [18], non-toxicity [19], and low cost [20], its application remains limited.The fabrication of photocatalyst (TiO 2 ) alongside a material (support) that efficiently adsorbs organic pollutants could be beneficial compared to their separate use because of the reversible transfer of intermediates [21] and reactive radicals between the photocatalyst and the support surface [22].This composite design could enhance the photocatalytic activity by delocalizing the band gap excited electrons, effectively suppressing the recombination of e − /h + pairs [23,24].
Zeolite is a material with distinctive properties including peculiar ion exchange [25,26], surface acidity, and inexpensive and environmentally benign nature [27,28].Modifying TiO 2 with zeolites may provide more active surfaces and prevent clotting, significantly improving the photodegradation performance of the catalyst.There are various studies on the application of TiO 2 /zeolite composites as a catalyst in photocatalytic reactions in the literature [29,30].For example, An et al. [31] synthesized carbon doped-TiO 2 coated on zeolites by solid-state dispersion and used it toward the degradation of eighteen pharmaceuticals and pesticides, including SMX.The results showed that the higher adsorption capacity of the zeolite improved the degradation efficiency of the photocatalyst.The study performed by An et al. [31] represents only the degradation of eighteen pharmaceuticals and pesticides, including SMX.Liu et al. [32] reported the successful photocatalytic degradation of sulfadiazine using natural zeolite coated with TiO 2 under UV light irradiation.Zhang et al. [33] prepared a TiO 2 /zeolite composite using the hydrolysis deposition technique.The adsorption and catalytic properties of the prepared composites were evaluated in the elimination of gaseous and aqueous organic contaminants.The results revealed that the TiO 2 /acid leaching zeolite exhibited higher photodegradation activities than the bare TiO 2 for formaldehyde, phenol, and rhodamine B.
Although several studies have reported the combination of TiO 2 with zeolite, to the best of the authors' knowledge there is no report on the application of such composites for the degradation and mineralization of SMX.To study this prospect, two different synthesis approaches were applied to prepare TiO 2 /zeolite (TZ and TZSM) composites, which were used to degrade SMX in water under UV light (365 nm) irradiation.The effect of the presence of various anions in SMX solution on the photocatalytic activity was also investigated for the most efficient composite.Finally, the energy consumption required for the photodegradation of SMX was calculated and compared with the literature.

Characterization
The phase composition of the composites prepared was firstly investigated by XRD analysis, and the results are shown in Figure 1.Distinct diffraction peaks related to the zeolite (Z or ZSM-5) were observed for all composites, regardless of the intensity or the weight fraction of zeolite.The characteristic peaks at 23.0 • and 23.8 • in TZSM1450 and TZSM2600 represent major ZSM-5 peaks [34,35].The characteristic peaks of TiO 2 anatase (JCPDS No. 00-021-12-72) at 2θ = 25.3 • , 37.8 • , 48.0 • , 53.9 • , 55.1 • , 75.2 • could be observed in all of the prepared composites, which were ascribed to the (101), (004), ( 200), (105), (211), and (215) planes, respectively.The intensity of the (101) TiO 2 anatase peak was more intense for TZ2600 and TZSM2600 composites as a result of the weight fraction of TiO 2 dispersed on the surface of the zeolite.In general, the XRD patterns of TZ2600 and TZSM2600 were almost the same as of pure TiO 2 .On the other hand, the peaks corresponding to the zeolite (Z or ZSM-5) were weak, which could be ascribed to the low content of zeolite in the composites and to the fact that the zeolite surface was assembled by TiO 2 nanoparticles, resulting in a decline of zeolite peaks.Similarly, in the pattern of the TZSM1450 composite, the characteristic peaks of TiO 2 were weaker as the content of TiO 2 was lower.and (215) planes, respectively.The intensity of the (101) TiO2 anatase peak was more intense for TZ2600 and TZSM2600 composites as a result of the weight fraction of TiO2 dispersed on the surface of the zeolite.In general, the XRD patterns of TZ2600 and TZSM2600 were almost the same as of pure TiO2.On the other hand, the peaks corresponding to the zeolite (Z or ZSM-5) were weak, which could be ascribed to the low content of zeolite in the composites and to the fact that the zeolite surface was assembled by TiO2 nanoparticles, resulting in a decline of zeolite peaks.Similarly, in the pattern of the TZSM1450 composite, the characteristic peaks of TiO2 were weaker as the content of TiO2 was lower.In addition to XRD, Raman analysis was implemented to explore the structure and properties of TZ and TZSM composites from their vibrational modes.It can be observed in Figure 2 that all of the composites contained peaks corresponding to TiO2 anatase centered at 139, 195 (symmetric stretching vibration of O-Ti-O), 393 (symmetrical O-Ti-O bending vibration), 516 (asymmetrical bending vibration), and 635 cm −1 (symmetric stretching vibration of O-Ti-O).Also, the high-intensity peak at about 139 cm −1 shifted to a higher wavenumber ascribed to the strengthened interaction between TiO2 and zeolite [36,37].In addition to XRD, Raman analysis was implemented to explore the structure and properties of TZ and TZSM composites from their vibrational modes.It can be observed in Figure 2 that all of the composites contained peaks corresponding to TiO 2 anatase centered at 139, 195 (symmetric stretching vibration of O-Ti-O), 393 (symmetrical O-Ti-O bending vibration), 516 (asymmetrical bending vibration), and 635 cm −1 (symmetric stretching vibration of O-Ti-O).Also, the high-intensity peak at about 139 cm −1 shifted to a higher wavenumber ascribed to the strengthened interaction between TiO 2 and zeolite [36,37].and (215) planes, respectively.The intensity of the (101) TiO2 anatase peak was more intense for TZ2600 and TZSM2600 composites as a result of the weight fraction of TiO2 dispersed on the surface of the zeolite.In general, the XRD patterns of TZ2600 and TZSM2600 were almost the same as of pure TiO2.On the other hand, the peaks corresponding to the zeolite (Z or ZSM-5) were weak, which could be ascribed to the low content of zeolite in the composites and to the fact that the zeolite surface was assembled by TiO2 nanoparticles, resulting in a decline of zeolite peaks.Similarly, in the pattern of the TZSM1450 composite, the characteristic peaks of TiO2 were weaker as the content of TiO2 was lower.In addition to XRD, Raman analysis was implemented to explore the structure and properties of TZ and TZSM composites from their vibrational modes.It can be observed in Figure 2 that all of the composites contained peaks corresponding to TiO2 anatase centered at 139, 195 (symmetric stretching vibration of O-Ti-O), 393 (symmetrical O-Ti-O bending vibration), 516 (asymmetrical bending vibration), and 635 cm −1 (symmetric stretching vibration of O-Ti-O).Also, the high-intensity peak at about 139 cm −1 shifted to a higher wavenumber ascribed to the strengthened interaction between TiO2 and zeolite [36,37].The morphology of pure zeolites (Z and ZSM-5), as well as of TZ and TZSM composites were examined by SEM (Figures 3 and 4).Both types of zeolites exhibited relatively smooth surfaces, composed of abundant rectangular particles.The SEM image of TZ2600 revealed that the surface of Z was densely dispersed by TiO 2 nanoparticles.This could be associated with the high content of TiO 2 used in the preparation of these composites, and supported the XRD results regarding the variation in TiO 2 /zeolite ratio.
Catalysts 2024, 14, 147 4 of 17 The morphology of pure zeolites (Z and ZSM-5), as well as of TZ and TZSM composites were examined by SEM (Figures 3 and 4).Both types of zeolites exhibited relatively smooth surfaces, composed of abundant rectangular particles.The SEM image of TZ2600 revealed that the surface of Z was densely dispersed by TiO2 nanoparticles.This could be associated with the high content of TiO2 used in the preparation of these composites, and supported the XRD results regarding the variation in TiO2/zeolite ratio.In comparison with TZ2600, TZSM1450 and TZSM2600 images showed that TiO2 particles were homogeneously distributed on ZSM-5.The morphology of pure zeolites (Z and ZSM-5), as well as of TZ and TZSM composites were examined by SEM (Figures 3 and 4).Both types of zeolites exhibited relatively smooth surfaces, composed of abundant rectangular particles.The SEM image of TZ2600 revealed that the surface of Z was densely dispersed by TiO2 nanoparticles.This could be associated with the high content of TiO2 used in the preparation of these composites, and supported the XRD results regarding the variation in TiO2/zeolite ratio.In comparison with TZ2600, TZSM1450 and TZSM2600 images showed that TiO2 particles were homogeneously distributed on ZSM-5.In comparison with TZ2600, TZSM1450 and TZSM2600 images showed that TiO 2 particles were homogeneously distributed on ZSM-5.
The presence of TiO 2 on the surface of zeolite was confirmed by the EDS technique in all of the prepared composites (Figure 5).The Ti content was higher in TZ2600 and TZSM2600, which was in accordance with the applied amount of TiO 2 .In addition, the Si/Al ratio was calculated for all composites.It can be observed that the Si/Al ratios for TZ1450, TZ2600, TZSM1450, and TZSM2600 composites were about 0.99, 0.91, 18.25, and 18.00, respectively.It has been previously reported that the Si/Al ratio could affect photocatalytic activity.In particular, the increase in the Si/Al ratio could result in an improved photocatalytic activity of the material [38].

4, 147 5 of 17
The presence of TiO2 on the surface of zeolite was confirmed by the EDS technique in all of the prepared composites (Figure 5).The Ti content was higher in TZ2600 and TZSM2600, which was in accordance with the applied amount of TiO2.In addition, the Si/Al ratio was calculated for all composites.It can be observed that the Si/Al ratios for TZ1450, TZ2600, TZSM1450, and TZSM2600 composites were about 0.99, 0.91, 18.25, and 18.00, respectively.It has been previously reported that the Si/Al ratio could affect photocatalytic activity.In particular, the increase in the Si/Al ratio could result in an improved photocatalytic activity of the material [38].The light absorption properties of TZ and TZSM composites were examined by UV-Vis Diffuse Reflectance Spectroscopy (DRS).It can be observed that all synthesized composites illustrated strong absorption in the UV region, similar to TiO2 (Figure 6).The light absorption properties of TZ and TZSM composites were examined by UV-Vis Diffuse Reflectance Spectroscopy (DRS).It can be observed that all synthesized composites illustrated strong absorption in the UV region, similar to TiO 2 (Figure 6).
Catalysts 2024, 14, 147 5 of 17 The presence of TiO2 on the surface of zeolite was confirmed by the EDS technique in all of the prepared composites (Figure 5).The Ti content was higher in TZ2600 and TZSM2600, which was in accordance with the applied amount of TiO2.In addition, the Si/Al ratio was calculated for all composites.It can be observed that the Si/Al ratios for TZ1450, TZ2600, TZSM1450, and TZSM2600 composites were about 0.99, 0.91, 18.25, and 18.00, respectively.It has been previously reported that the Si/Al ratio could affect photocatalytic activity.In particular, the increase in the Si/Al ratio could result in an improved photocatalytic activity of the material [38].The light absorption properties of TZ and TZSM composites were examined by UV-Vis Diffuse Reflectance Spectroscopy (DRS).It can be observed that all synthesized composites illustrated strong absorption in the UV region, similar to TiO2 (Figure 6).An insignificant reduction in the absorption intensity of the UV region and a slight shift towards higher wavelengths were observed for TZ2600 and TZSM600.However, almost no change was observed for TZSM1450.
The textural properties of the photocatalysts are important for the degradation of a model pollutant.The large specific surface area is especially beneficial through improving the contact probability of the pollutant with the active sites of the material.Table 1 shows the calculated S BET values in relation to the Si/Al ratio.It was observed that the combination of TiO 2 with Z was accompanied by a decrease in S BET , while the introduction of TiO 2 onto ZSM-5 significantly increased the S BET value.This phenomenon could be associated with the loss of the existing micropores at low Si/Al ratios for TZ composites.The findings are consistent with previously reported studies [39,40].

Photocatalytic Degradation and Mineralization of SMX
To investigate the photocatalytic activity of TZ and TZSM composites (200 mg•L −1 ) toward the degradation of SMX (30 mg•L −1 ), experiments were conducted under UV light irradiation.Before the light exposure, the adsorption performance of the synthesized catalysts was tested.All four catalysts showed insignificant adsorption toward SMX, and the removal efficiencies for TZ2600, TZSM2600, TZ1450, and TZSM1450 were 2.4%, 2.4%, 3.3%, and 6.1%, respectively.The pure TiO 2 adsorbed 3.85% of SMX.
The degradation (%) of SMX was calculated by Equation (1): where [SMX] 0 is the initial SMX concentration in solution; [SMX] t is the concentration of SMX after a certain reaction time.
A blank experiment of SMX solution exposed to UV light without any catalyst was also performed for comparison.As a result of the blank control experiment, the use of only UV irradiation could degrade up to 70% of SMX, since SMX can absorb UV light and some bonds can be destroyed.Significantly lower degradations of SMX have been previously reported under UVA irradiation as SMX mainly absorbs light until 310 nm [41].The significant photolysis of SMX could be related to the presence of additional minor wavelengths of irradiation in the UVC region of the lamp used, as no UVC filter was used.
It can be observed from Figure 7A that the TZ2600 composite exhibited the lowest photocatalytic activity, achieving an SMX degradation of about 33%.On the other hand, 100% of SMX was degraded after 10 min of photocatalytic reaction using TZSM1450, which was higher than the degradation achieved with pure TiO 2 .This phenomenon could be associated with the fact that zeolite can act as an electron trapper by inhibiting the charge recombination of electron-hole (e − /h + ) pairs [42].Therefore, the photo-induced e − can be transferred to the surface of zeolite or react with dissolved oxygen (O 2 ) to form the superoxide radical (O •− 2 ), while h + at the TiO 2 can react with the adsorbed SMX [43].This illustrates that zeolite enhances the photocatalytic activity of TiO 2 [44].The results are in good agreement with the XRD and SEM findings.
In general, the combination of ZSM with TiO 2 showed a more advantageous catalytic effect than the combination of Z with TiO 2 .These findings could be associated with the higher Si/Al ratio for TZSM composites that led to enhanced photocatalytic activity.
Although the activity of TZ1450 was higher than that of TZ2600, it was still lower than that of pure TiO 2 .Such a behavior could be explained by the deterioration caused by changes in the applied zeolite type, preparation method, and calcination temperature [45].
Catalysts 2024, 14, 147 7 of 17 of pure TiO2.Such a behavior could be explained by the deterioration caused by changes in the applied zeolite type, preparation method, and calcination temperature [45].The photocatalytic degradation of the SMX followed pseudo-first-order kinetics (Figure 7B) with R 2 > 0.94 in all cases.The corresponding degradation rate constants (kd, min −1 ) followed the order: TZSM1450 > TiO2 (pure) > TZSM2600 > TZ2450 (Figure 7C).Specifically, the kd value for the photocatalytic degradation of SMX over TSM1450 was 0.501 min −1 , which was 2.08 times the kd value in the case of pure TiO2.Yuan et al. [46] reported photocatalytic rate constants in the range of 0.1117-0.5453min −1 for SMX degradation over TiO2, similar to the one obtained in the present study (0.501 min −1 ).
TOC removal is an important parameter to assess the ability of a photocatalyst to mineralize a compound.As shown in Figure 8, the conversion of SMX to harmless CO2, H2O, and other inorganic species takes longer periods.As for degradation performance, TZSM composites showed better mineralization characteristics than TZ composites (Figure 8A).About 65% and 67% of SMX was mineralized after 120 min by TZSM2600 and TZSM1450, respectively.
The effect of common ions like NO , CO , and Cl was investigated to assess their effect on the activity of TZSM1450 in terms of SMX degradation.The results are shown in Figure 9.The photocatalytic degradation of the SMX followed pseudo-first-order kinetics (Figure 7B) with R 2 > 0.94 in all cases.The corresponding degradation rate constants (k d , min −1 ) followed the order: TZSM1450 > TiO 2 (pure) > TZSM2600 > TZ2450 (Figure 7C).Specifically, the k d value for the photocatalytic degradation of SMX over TSM1450 was 0.501 min −1 , which was 2.08 times the k d value in the case of pure TiO 2 .Yuan et al. [46] reported photocatalytic rate constants in the range of 0.1117-0.5453min −1 for SMX degradation over TiO 2 , similar to the one obtained in the present study (0.501 min −1 ).
TOC removal is an important parameter to assess the ability of a photocatalyst to mineralize a compound.As shown in Figure 8, the conversion of SMX to harmless CO 2 , H 2 O, and other inorganic species takes longer periods.As for degradation performance, TZSM composites showed better mineralization characteristics than TZ composites (Figure 8A).About 65% and 67% of SMX was mineralized after 120 min by TZSM2600 and TZSM1450, respectively.
The effect of common ions like NO − 3 , CO 2− 3 , and Cl − was investigated to assess their effect on the activity of TZSM1450 in terms of SMX degradation.The results are shown in Figure 9.The coexistence of NO − 3 , CO 2− 3 , or Cl − ions in the solution with the concentration of 100 mg•L −1 had various effects on the performance of the UV/TZSM1450 system.No remarkable change was observed after the addition of NO − 3 and almost complete SMX degradation was achieved within 10 min.Many studies report the negligible effect of NO − 3 on the photocatalytic degradation of organic pollutants [47][48][49].It has to be noted that almost 91% of SMX was degraded after 4 min only in the presence of NO − 3 .This could be associated with the photolysis of NO − 3 (Equations ( 2)-( 7)): On the other hand, CO 2− 3 and Cl − ions inhibited the degradation process.The inhibition effect of CO 2− 3 ions was possibly because the reactive •OH radicals get scavenged by them [50], and were transformed into the less reactive CO •− 3 radicals (Equation ( 8)): It is worth mentioning that pH can have a deep impact on the formation of radicals [51].At a highly alkaline pH CO 2− 3 dominates, while at a low and neutral pH, the carbonate ion will mainly be present in the HCO − 3 form.Both CO 2− 3 and HCO − 3 react with •OH by generating CO •− 3 , however, the reaction between HCO − 3 and •OH is known to occur more slowly than in the case of CO 2− 3 and •OH [52].Cl − had the strongest inhibiting effect as a result of the formation of chlorine species (Equations ( 9)-( 16)).These anions may compete with SMX for active sites or also trap active radicals [53], resulting in declined performance [54].
However, 56% and 60% SMX was still degraded within 10 min in the presence of Cl − and CO 2− 3 ions in the solution.The corresponding k d values in the presence of Cl − and CO 2− 3 ions were 0.089 min −1 and 0.095 min −1 , respectively (Figure 9C). Figure 10 shows a schematic representation of the photocatalytic degradation of SMX molecules using the TZSM1450 catalyst.The photocatalytic reaction using TZSM1450 was mainly dominated by TiO 2 [32].Because of the intimate contact between TiO 2 and zeolite [24], electrons (e − ) and holes (h + ) would be formed in the conduction band (CB) and valence band (VB) of TiO 2 under UV light exposure [32,55].The photo-induced e − and h + migrate to the surface of TiO 2 , where they can react with the adsorbed O 2 , while h + would oxidize OH − to produce oxidizing agents like O •− 2 and •OH with high redox potential [56].However, only around 1% of trapped e − and h + participate in oxidative/reductive processes [57].Zeolite, applied as a support for TiO 2, can facilitate the efficient delocalization of excited e − by the electrical conductance between the zeolite and the TiO 2 surface due to the electrical conductance of the zeolites.Thus, the inhibition of charge recombination accounts for the improved photocatalytic activity of the composite photocatalyst [24,58].
mainly dominated by TiO2 [32].Because of the intimate contact between TiO2 and zeolite [24], electrons (e ) and holes (h ) would be formed in the conduction band (CB) and valence band (VB) of TiO2 under UV light exposure [32,55].The photo-induced e and h migrate to the surface of TiO2, where they can react with the adsorbed O , while h would oxidize OH to produce oxidizing agents like O • and • OH with high redox potential [56].However, only around 1% of trapped e and h participate in oxidative/reductive processes [57].Zeolite, applied as a support for TiO2, can facilitate the efficient delocalization of excited e by the electrical conductance between the zeolite and the TiO2 surface due to the electrical conductance of the zeolites.Thus, the inhibition of charge recombination accounts for the improved photocatalytic activity of the composite photocatalyst [24,58].

Electrical Energy Estimation
To evaluate the treatment cost of the SMX aquatic solutions by the UV/TZSM1450 process, the electrical energy per order (EE/O) quantity was estimated [59].Specifically, EE/O was determined as "the electrical energy (kWh) required for the degradation of pollutant by one order of magnitude in 1 m 3 of contaminated water (Equation ( 17)).
where P is the power of the lamp (W); t is the photocatalytic reaction time (min); V is the volume of the reactor (L); and Ci and Cf are the initial and final concentrations of SMX, respectively.The values of EE/O required for the treatment of 1 m 3 of SMX solution were 310.9 kWh m −3 order −1 for UV only, 177.1 kWh m −3 order −1 for UV/TiO2, 434.64 kWh m −3 order −1 for TZ1450, 68.53 kWh m −3 order −1 for UV/TZSM1450, 946.48 kWh m −3 order −1 for UV/TZ2600, and 312.55 kWh m −3 order −1 for UV/TZSM2600.Thus, the application of UV/TZSM1450 was more attractive in comparison with the other processes considered in this study.

Electrical Energy Estimation
To evaluate the treatment cost of the SMX aquatic solutions by the UV/TZSM1450 process, the electrical energy per order (EE/O) quantity was estimated [59].Specifically, EE/O was determined as "the electrical energy (kWh) required for the degradation of pollutant by one order of magnitude in 1 m 3 of contaminated water (Equation ( 17)).
where P is the power of the lamp (W); t is the photocatalytic reaction time (min); V is the volume of the reactor (L); and C i and C f are the initial and final concentrations of SMX, respectively.The values of EE/O required for the treatment of 1 m 3 of SMX solution were 310.9 kWh m −3 order −1 for UV only, 177.1 kWh m −3 order −1 for UV/TiO 2 , 434.64 kWh m −3 order −1 for TZ1450, 68.53 kWh m −3 order −1 for UV/TZSM1450, 946.48 kWh m −3 order −1 for UV/TZ2600, and 312.55 kWh m −3 order −1 for UV/TZSM2600.Thus, the application of UV/TZSM1450 was more attractive in comparison with the other processes considered in this study.
Interestingly, the presence of ions (NO − 3 , CO 2− 3 , or Cl − ) in the degradation of SMX under UV/TZSM1450 had a diverse effect on the treatment cost.The addition of NO − 3 slightly decreased the electric energy demand from 68.53 kWh m −3 order −1 to 50.01 kWh m −3 order −1 , while the occurrence of CO 2− 3 or Cl − led to the increase of EE/O value to 441.46 kWh m −3 order −1 and 468.24 kWh m −3 order −1 , respectively.
Since there is a limited number of EE/O studies available for SMX degradation using TiO 2 -based photocatalysts, the EE/O values obtained are compared with the ones for other organic pollutants in Table 2.The EE/O values estimated in the present study for SMX degradation are similar to the ones reported by Zambrano et al. [60] using UV/TiO 2 .In addition, the EE/O value for SMX mineralization in the UV/TZSM1450 system was equal to 4156 kWh m −3 order −1 .

Preparation of TZ and TZSM Photocatalysts
Two different synthesis methods were used: (1) a simple mechanical mixing method, and (2) a liquid impregnation one.The catalysts were composed of titanium dioxide and zeolite (Z or ZSM-5).The catalysts prepared were labeled as TZxy or TZSMxy depending on whether zeolite Z or ZSM-5 was used, where x and y represent the preparation method and the calcination temperature, respectively.

Preparation of TZ1450 and TZSM1450
TZ1450 and TZSM1450 composites were prepared using a simple mechanical mixing method [66].Briefly, 1 g of TiO 2 and 5 g of zeolite (Z or ZSM-5) were added to 60 mL of UPW and stirred for 1 h.Then, the mixture was ultra-sonicated for 1 h.The product was dried at 100 • C for 14 h and finally calcined at 450 • C for 8 h.The process is schematically shown in Figure 11.3.2.2.Preparation of TZ2600 andTZSM2600 TZ2600 and TZSM2600 composites were synthesized using a liquid impregnation method [67].A total of 4 g of TiO2 and 1 g of zeolite (Z or ZSM-5) was added to 100 mL of UPW and stirred for 3 h.The resulting precipitate was dried at 100 °C for 14 h, and then calcined at 600 °C for 3 h (Figure 12).In both approaches, after the calcination step, the homogenization of the resulting precipitate was performed by ball milling for 2 h.

Characterization
XRD patterns of TZ and TZSM composites were acquired by the X-ray diffractometer (Rigaku Smartlab system, Tokyo, Japan) in a 2θ range of 20-80°, while Raman spectra were recorded using a Raman spectrometer (Horiba, LabRam HR evolution, Kyoto, Japan).SEM images and EDS elemental mapping were obtained by Crossbeam 540 and JSM-IT200 (LA) instruments.DRS spectroscopy was applied to study the optical performance of the composites by diffuse reflectance spectroscopy (DRS, Varian Cary 3, Palo Alto, CA, USA).The specific surface area (SBET) of the composites was determined using an automated gas sorption analyzer (Autosorb iQ, Quantachrome, Boynton Beach, FL, USA) with the BET method.3.2.2.Preparation of TZ2600 andTZSM2600 TZ2600 and TZSM2600 composites were synthesized using a liquid impregnation method [67].A total of 4 g of TiO 2 and 1 g of zeolite (Z or ZSM-5) was added to 100 mL of UPW and stirred for 3 h.The resulting precipitate was dried at 100 • C for 14 h, and then calcined at 600 • C for 3 h (Figure 12).3.2.2.Preparation of TZ2600 andTZSM2600 TZ2600 and TZSM2600 composites were synthesized using a liquid impregnation method [67].A total of 4 g of TiO2 and 1 g of zeolite (Z or ZSM-5) was added to 100 mL of UPW and stirred for 3 h.The resulting precipitate was dried at 100 °C for 14 h, and then calcined at 600 °C for 3 h (Figure 12).In both approaches, after the calcination step, the homogenization of the resulting precipitate was performed by ball milling for 2 h.

Characterization
XRD patterns of TZ and TZSM composites were acquired by the X-ray diffractometer (Rigaku Smartlab system, Tokyo, Japan) in a 2θ range of 20-80°, while Raman spectra were recorded using a Raman spectrometer (Horiba, LabRam HR evolution, Kyoto, Japan).SEM images and EDS elemental mapping were obtained by Crossbeam 540 and JSM-IT200 (LA) instruments.DRS spectroscopy was applied to study the optical performance of the composites by diffuse reflectance spectroscopy (DRS, Varian Cary 3, Palo Alto, CA, USA).The specific surface area (SBET) of the composites was determined using an automated gas sorption analyzer (Autosorb iQ, Quantachrome, Boynton Beach, FL, USA) with the BET method.In both approaches, after the calcination step, the homogenization of the resulting precipitate was performed by ball milling for 2 h.

Characterization
XRD patterns of TZ and TZSM composites were acquired by the X-ray diffractometer (Rigaku Smartlab system, Tokyo, Japan) in a 2θ range of 20-80 • , while Raman spectra were recorded using a Raman spectrometer (Horiba, LabRam HR evolution, Kyoto, Japan).SEM images and EDS elemental mapping were obtained by Crossbeam 540 and JSM-IT200 (LA) instruments.DRS spectroscopy was applied to study the optical performance of the composites by diffuse reflectance spectroscopy (DRS, Varian Cary 3, Palo Alto, CA, USA).The specific surface area (S BET ) of the composites was determined using an automated gas sorption analyzer (Autosorb iQ, Quantachrome, Boynton Beach, FL, USA) with the BET method.

Photocatalytic Degradation and Mineralization of SMX
The photocatalytic activity of TZSM1450 and TZSM2600 catalysts was evaluated toward the degradation of SMX under UV light irradiation (365 nm, 500 W) using a photocatalytic reactor (Lanphan industry, Zhengzhou City, China).The photodegradation process was implemented in a 500 mL reactor.The initial concentrations of SMX solution and catalyst were 30 mg•L −1 and 200 mg•L −1 , respectively.Before the light irradiation, the solution was stirred magnetically for 30 min in the dark to achieve adsorption-desorption equilibrium.During irradiation, stirring was maintained to keep the mixture in suspension.The whole photocatalytic reaction was maintained at a constant temperature of 25 • C by using a water circulation system.The initial pH of SMX solution was 7.04 and no pH adjustment took place.Approximately 2 mL was taken out every 1 min from the solution to check the SMX degradation and 15 mL was taken every 30 min to check the SMX mineralization.The concentration of SMX was monitored by a high-performance liquid chromatography apparatus (HPLC, Agilent 1290 Infinity II, Santa Clara, CA, USA) equipped with an SB-C8 column (2.1 mm × 100 mm, 1.8 µm) and an ultraviolet detector at a wavelength of 258 nm was used for SMX content analysis.For chromatographic analysis, the injection volume was 1 µL, the flow rate was 0.4 mL/min, and the column temperature was set at 25 • C (both left and right sides) while the retention time was 1.372 min.The mixture of CH 3 CN and UPW (40:60 by volume) was used as the mobile phase.The mineralization of SMX was determined by means of a total organic carbon (TOC) analyzer (Multi N/C 3100, Analytic Jena, Jena, Germany).

Conclusions
TiO 2 /zeolite (TZ and TZSM) composites were synthesized using two different techniques.The photocatalytic performances of the catalysts prepared (200 mg•L −1 ) were evaluated toward SMX (30 mg•L −1 ) degradation and mineralization in water under UV light (365 nm) irradiation.The TZSM1450 composite obtained from simple mechanical mixing of TiO 2 with zeolite (ZSM-5), exhibited the best SMX degradation performance among the catalysts investigated in this study, namely 100% SMX degradation within 10 min, which indicated the synergy between TiO 2 and zeolite.Assuming pseudo-first-order rate kinetics, the rate constants were calculated as 0.039, 0.090, 0.130, 0.241, and 0.501 min −1 for TZ2600, TZ1450, TZSM2600, TiO 2 , and TZSM1450, respectively.The highest TOC removal reached at 120 min was 67% for TZSM1450.The coexistence of Cl − and CO 2− 3 exhibited a considerable inhibition effect on SMX degradation, while the presence of NO − 3 had practically no effect on the process.Specifically, the degradation efficiency decreased from 100% to 60% and 56% in the presence of 100 mg•L −1 of CO 2− 3 and Cl − , respectively.In the case of the TZSM1450 photocatalyst, the electrical energy per order (EE/O) was estimated as 68.53 kWh m −3 order −1 for SMX degradation and 4156 kWh m −3 order −1 for SMX mineralization.Finally, the results obtained from this study indicated that the TZSM1450 composite could be a promising catalyst for effective SMX elimination from water.

Figure 2 .
Figure 2. Raman spectra of (A) TZ and (B) TZSM composites.Different colors were used to distinct pure TiO2 from synthesized composites (spectra of composites calcined at 450 °C-red, composites calcined at 600 °C-blue).

Figure 2 .
Figure 2. Raman spectra of (A) TZ and (B) TZSM composites.Different colors were used to distinct pure TiO2 from synthesized composites (spectra of composites calcined at 450 °C-red, composites calcined at 600 °C-blue).

Figure 2 .
Figure 2. Raman spectra of (A) TZ and (B) TZSM composites.Different colors were used to distinct pure TiO 2 from synthesized composites (spectra of composites calcined at 450 • C-red, composites calcined at 600 • C-blue).

Figure 11 .
Figure 11.The preparation process for the TZ1450 and TZSM1450.

Figure 11 .
Figure 11.The preparation process for the TZ1450 and TZSM1450.

Table 1 .
The calculated S BET values in relation to Si/Al ratio.

Table 2 .
Comparison of EE/O of TiO 2 -based photocatalysts for the degradation of various organic pollutants in the literature.