Development of Photocatalytic Coatings for Building Materials with Bi 2 O 3 -ZnO Nanoparticles

: The aim of this study was to develop versatile coatings that can protect the stone surfaces of Architectural Heritage. Two different 3D media, namely superhydrophobic (SPHB) and hydro-oleophobic (OHB), were utilized as host matrices for nanostructured photocatalysts (Bi 2 O 3 -ZnO 8/92). These photocatalysts were sensitive to visible light to enhance their efﬁciency when exposed to sunlight. To prevent the nanophotocatalyst from clumping together in the 3D media, non-ionic dis-persant additives (Tween20, TritonX-100, and Brij35) were incorporated. The optimized suspensions were then applied to various substrates such as sandstone, limestone, and granite. The effectiveness of the coatings was assessed by evaluating the hydrophobicity, oleophobicity, and photocatalytic activity of the coated substrates. The Bi 2 O 3 -ZnO photocatalyst exhibited higher activity in the SPHB medium compared to the OHB medium. To simulate real-life conditions, the coated substrates were subjected to accelerated weathering tests to predict their durability. Despite a signiﬁcant reduction in their thickness, the coatings demonstrated sustained hydrophobic efﬁciency and self-cleaning capability after the accelerated ageing tests.


Introduction
Artistic, historical, and cultural heritage are vulnerable to numerous factors that contribute to their deterioration.Some notable environmental issues include the accumulation of carbon particles leading to surface blackening, the impact of water, the effects of specific atmospheric gases such as NO x and COVs, and the growth of microorganisms like fungi and bacteria [1][2][3][4].The infiltration of water through cracks and holes [5,6] can result in the dissolution of salts, the occurrence of efflorescence, and material breakage due to freeze-thaw cycles.Additionally, anthropogenic factors such as pollution and graffiti [7,8] contribute to the deterioration of buildings.Addressing all these concerns demands significant effort and substantial investments.Consequently, numerous treatments have been suggested to mitigate or, at the very least, minimize the damages.
The common approach has been to use waterproofing agents to protect materials from water damage [9][10][11].These agents typically consisted of organic compounds like resins, acrylates, and waxes [9, [11][12][13][14][15].In the case of anti-graffiti treatments, various methods have been proposed [16] that allow for the easy removal of graffiti by subjecting the surface material to different cleaning processes.However, these "traditional" treatments, in addition to being short-lived, present several issues, as highlighted by [17]: (1) they cause changes in colour and gloss, resulting in thick coloured coatings [18]; (2) they rely on organic compounds that are incompatible with ancient construction materials and can even be toxic [19]; (3) they excessively and inadequately reduce water vapor permeability, causing moisture to accumulate within the material [20].Innovative approaches have been proposed to confront these problems.One such approach involves creating "smart" surfaces by applying photocatalytic compounds that exhibit biocidal activity and reduction in biological growth, as well as dirt degradation ability.These photocatalysts can break the bonds formed between microorganisms and substrates as well as to react with dirt deposits causing their removal [21][22][23][24][25].
The general action mechanism of these catalysts involves utilizing light to create radical species that, through chemical oxidation, break down contaminants and eliminate them.The resulting decomposition product is carried away by moisture or rainfall [26].The photocatalytic properties of TiO 2 in removing dirt are well-known, and its use offers several advantages, such as low toxicity, high compatibility with construction materials, and superior catalytic activity compared with other metal oxides [26][27][28].However, it faces several challenges, including cost, a limited ability to absorb non-ultraviolet visible sunlight [26,27,29], and its primary use in bulk applications rather than coatings (resulting in the waste of photocatalyst within the internal mass of the construction material or limiting its application to new structures, thereby reducing its potential to transform existing structures into decontaminating areas).Given these factors, which significantly reduce its efficiency, two possible solutions arise: (1) modifying the catalyst to enhance its sensitivity towards the visible part of the spectrum [30][31][32][33], and (2) utilizing dispersing agents compatible with the studied material to achieve a proper distribution of the catalyst on the surface [34].In this regard, previous works provided evidence of improvements achieved when TiO 2 was combined with ZnO [35,36]: the presence of ZnO enhanced photostability, increased the lifetime of both electrons and photogenerated holes, and improved the ability to absorb photons at longer wavelengths compared to bare TiO 2 .Bismuth oxides have also been explored with this aim due to their availability, low cost, low toxicity, good biocompatibility, and potential for doping and forming cocatalysts [37,38].Bi 2 O 3 has been safely tested for use in dental cements, without manifestations of toxicity [39].
Considering the aforementioned circumstances, the aim of the current work is to investigate the effectiveness of a multifunctional coating comprising both bismuth-and zinc oxide-based photocatalysts (Bi 2 O 3 -ZnO) along with two types of media: one possessing superhydrophobic properties (SPHB) and the other exhibiting super-hydro-oleophobic characteristics (OHB).The objective is to achieve a synergistic effect where the medium minimizes dirt adsorption while the photocatalyst degrades any adsorbed substance.These media can also provide protection to the catalyst against rainwater wash-off [40], as claimed in previous studies [22,23,[40][41][42][43][44][45][46][47][48].Contrary to the common use of TiO 2 and organic waterrepellent agents as coatings in Built Heritage, the novelty attained in the current study relies on the particular photocatalyst employed as well as on the two specifically functionalized media.Thus, in this research, the SPHB and OHB matrices will consist of three-dimensional (3D) structures of inorganic ceramic nano-oxides that incorporate photocatallytically active nanoparticles.This composition should prove compatible with the inorganic substrates of the heritage materials to be protected.Ensuring the safety of Architectural Heritage materials is crucial.Previous studies have demonstrated the effectiveness of using these coatings in minimizing water and contaminant exposure, which are known to be destructive agents for these materials [34,35,41,42].The 3D structure is formed by assembling one-dimensional (1D) nanomaterials into higher-order superstructures such as networks, nanoforests, and nanoarrays [49,50].These materials possess small cavities that allow breathability, preventing the accumulation of water vapor and ensuring a non-sealing form of protection.The photocatalytic active nanoparticles to be studied are heterostructures of Bi 2 O 3 -ZnO, which are expected to exhibit great activity when exposed to UV-VIS radiation [51][52][53][54][55][56][57].In order to modify the characteristics of the coatings and prevent the anticipated nanoparticle agglomeration, dispersing agents such as Brij35, TritonX-100, and Tween20 were employed.Although anionic dispersing agents have been reported for optimizing coatings [34,58], the three non-ionic mentioned dispersants were, in this case, selected due to the non-polar nature of the solvents to be used (SPHB and OHB) as well as to their strong detergent and emulsifying capabilities.Finally, three typical Architectural Heritage materials, such as limestone, sandstone, and granite, were tested as recipients for the assayed dispersions applied as coatings.

Characterization of the Photocatalytic Nanoparticles
The specific surface area of the Bi 2 O 3 -ZnO 8/92 nanoparticles was 30.62 ± 0.05 m 2 g −1 (Figure 1), and the average size was calculated to be 33 nm, which is in good agreement with those typically obtained by FSP [59].The percentage of each oxide, as determined by X-ray Fluorescence, was 8.36% for Bi 2 O 3 and 90.83% for ZnO, yielding a purity of 99.19% for the synthesized Bi-Zn nanoparticles.Hereinafter, the term "BiZn" will be used to refer to the Bi 2 O 3 -ZnO (8 wt%/92 wt%) catalyst.The accuracy and purity of the synthesis path of nanoparticles are of great relevance as they guarantee the absence of elements that could potentially distort the photocatalysis measurements and/or hinder the mixing in the carrier media.
in this case, selected due to the non-polar nature of the solvents to OHB) as well as to their strong detergent and emulsifying capabilitie ical Architectural Heritage materials, such as limestone, sandstone tested as recipients for the assayed dispersions applied as coatings.

Characterization of the Photocatalytic Nanoparticles
The specific surface area of the Bi2O3-ZnO 8/92 nanoparticles wa (Figure 1), and the average size was calculated to be 33 nm, which is with those typically obtained by FSP [59].The percentage of each oxid X-Ray Fluorescence, was 8.36% for Bi2O3 and 90.83% for ZnO, yieldin for the synthesized Bi-Zn nanoparticles.Hereinafter, the term "BiZn" to the Bi2O3-ZnO (8 wt%/92 wt%) catalyst.The accuracy and purity o of nanoparticles are of great relevance as they guarantee the absen could potentially distort the photocatalysis measurements and/or hind carrier media.Figure 2 illustrates the powdered catalyst s remarkable efficacy gen oxides, achieving rates up to 70% when exposed to solar ligh scarcely affected (less than 7%) in the absence of UV radiation, clearly ability of BiZn nanoparticles to bring down NO levels without gene amount of the toxic intermediate, NO2.The selectivity values (S = NO removal rate), which inform the ratio of degraded NO that is conv nitrate rather than forming NO2, were as high as 95.5% under solar lig even higher (95.8%) for the nanoparticles subjected to just visible li results for Bi2O3-ZnO heterostructures showed better NO and NOx mances under both sunlight and visible light compared with TiO2-ZnO heterostructures [35].Figure 2 illustrates the powdered catalyst's remarkable efficacy in eliminating nitrogen oxides, achieving rates up to 70% when exposed to solar light.These values are scarcely affected (less than 7%) in the absence of UV radiation, clearly proving the notable ability of BiZn nanoparticles to bring down NO levels without generating an excessive amount of the toxic intermediate, NO 2 .The selectivity values (S = NO x removal rate/NO removal rate), which inform the ratio of degraded NO that is converted into non-toxic nitrate rather than forming NO 2 , were as high as 95.5% under solar light illumination and even higher (95.8%) for the nanoparticles subjected to just visible light irradiation.The results for Bi 2 O 3 -ZnO heterostructures showed better NO and NO x degradation performances under both sunlight and visible light compared with TiO 2 -ZnO (50:50) and (10:90) heterostructures [35].

Influence of the Non-Ionic Dispersing Agents on the Distribution of the Photocatalytic Nanoparticles
Zeta potential titration curves can be seen in Figure 3, which show that as the amoun of plasticizer increases, the zeta potential acquires more negative values.In line with th electrical double-layer model, the outer surface surrounding nanoparticles comprises tw ionic layers, and their electrical charge can be quantified as the zeta potential [60].Thi zeta potential serves as an indicator of the extent of repulsion between neighbourin charged particles within a dispersion.When the zeta potential exhibits high absolute val ues, it signifies that the particles are electrically stabilized, preventing the formation o flocs [61].Therefore, it can be inferred that the dispersing agents employed obstruct par ticle-particle interactions by establishing interactions between particles and the disper sant, thereby enhancing the system s stability.The comparison of results also demon strates superior outcomes for SPHB (zeta potential values below −45 mV in all instance at the end of the titration).The decrease in the zeta potential values of the non-ionic poly mers might be ascribed to the greater effective volume of the photocatalytic nanoparticle as a consequence of the adsorption of the polymer, resulting in thicker layers [62].
In general, there are no notable distinctions between the dispersants, and this can b attributed to their comparable Hydrophilic-Lipophilic Balance (HLB) values: 16.7 fo Tween20, 13.5 for TritonX-100, and 16.9 for Brij35.However, the lesser decrease in the zet potential in the SPHB medium with Brij 35 could be ascribed to its lower molecular weigh (230.39 g mol −1 ) as compared with the MW of Tween 20 (522.7 g mol −1 ) and Triton X-10 (625 g mol −1 ).

Influence of the Non-Ionic Dispersing Agents on the Distribution of the Photocatalytic Nanoparticles
Zeta potential titration curves can be seen in Figure 3, which show that as the amount of plasticizer increases, the zeta potential acquires more negative values.In line with the electrical double-layer model, the outer surface surrounding nanoparticles comprises two ionic layers, and their electrical charge can be quantified as the zeta potential [60].This zeta potential serves as an indicator of the extent of repulsion between neighbouring charged particles within a dispersion.When the zeta potential exhibits high absolute values, it signifies that the particles are electrically stabilized, preventing the formation of flocs [61].Therefore, it can be inferred that the dispersing agents employed obstruct particle-particle interactions by establishing interactions between particles and the dispersant, thereby enhancing the system's stability.The comparison of results also demonstrates superior outcomes for SPHB (zeta potential values below −45 mV in all instances at the end of the titration).The decrease in the zeta potential values of the non-ionic polymers might be ascribed to the greater effective volume of the photocatalytic nanoparticles as a consequence of the adsorption of the polymer, resulting in thicker layers [62].
In general, there are no notable distinctions between the dispersants, and this can be attributed to their comparable Hydrophilic-Lipophilic Balance (HLB) values: 16.7 for Tween20, 13.5 for TritonX-100, and 16.9 for Brij35.However, the lesser decrease in the zeta potential in the SPHB medium with Brij 35 could be ascribed to its lower molecular weight (230.39 g mol −1 ) as compared with the MW of Tween 20 (522.7 g mol −1 ) and Triton X-100 (625 g mol −1 ).
Results show that the dispersing agents tend to stabilize the system by electrostatic repulsions between nanoparticles.However, the concentration of the dispersing agent has been reported to exert a strong influence [63][64][65].Zeta potential values, in Table 1, follow two different patterns depending on which dispersant is being used (see in Section 3.2.2below the detailed composition of each one of the dispersions).Thus, in the OHB medium, the larger the percentage of dispersant, the more stabilizing negative values are obtained, whereas, in the SPHB medium, the absolute zeta potential values were lower for higher ratios of the non-ionic surfactants.Results show that the dispersing agents tend to stabilize the system by electrostatic repulsions between nanoparticles.However, the concentration of the dispersing agent has been reported to exert a strong influence [63][64][65].Zeta potential values, in Table 1, follow two different patterns depending on which dispersant is being used (see in Section 3.2.2below the detailed composition of each one of the dispersions).Thus, in the OHB medium, the larger the percentage of dispersant, the more stabilizing negative values are obtained, whereas, in the SPHB medium, the absolute zeta potential values were lower for higher ratios of the non-ionic surfactants.In the SPHB medium, the zeta potential values suggested the strongest repulsion for Tween 20 (3%, sample BiZn3), which was later confirmed by the particle size distribution measurements carried out by laser diffraction (Figure 4).As compared with the dispersantfree colloidal system, the presence of the tested surfactants reduced agglomeration, shifting the peak of the maximum particle population towards smaller diameters.
The same correlation between the zeta potential values and the effectiveness as a dispersing agent was observed in the OHB medium.Results in Figure 4 showed that the sample BiZn9, with the most negative zeta potential value, was the one with the lowest average diameter of the predominant particle population.
In both matrices, employing Brij-35 at its highest concentration (3%) led to a displacement of the main peak in particle size diameter towards smaller values, even though the zeta potential absolute values were relatively low.The capacity of this surfactant to maintain stability in the colloidal dispersions is attributed to its steric hindrance effect.ment of the main peak in particle size diameter towards smaller values, even though the zeta potential absolute values were relatively low.The capacity of this surfactant to maintain stability in the colloidal dispersions is attributed to its steric hindrance effect.
The absence of a clear dose-response pattern as a function of the percentage of surfactant can be explained as follows: when the concentration surpasses a certain threshold, the dispersant concentration becomes sufficiently elevated to enable interactions between dispersant molecules, thereby promoting agglomeration.The absence of a clear dose-response pattern as a function of the percentage of surfactant can be explained as follows: when the concentration surpasses a certain threshold, the dispersant concentration becomes sufficiently elevated to enable interactions between dispersant molecules, thereby promoting agglomeration.

Characterization of the Coatings
Every designed coating was applied onto the three intended supports, and the thicknesses of all of them are depicted in Table 2.
As it can be observed, all available data are within the 30-50 microns range, which indicates that neither medium (SPHB or OHB) nor the dispersants (Tween20, TritonX-100, or Brij35) have a marked effect on the thickness of coatings [63][64][65].In general, the thickness follows the sandstone > limestone > granite trend, which can be attributed to the roughness [35].The rougher the surface, the greater the surface-catalyst friction.The logical increase in the superficial area in the substrates with the highest roughness implies a better bonding for the catalyst [66].
The water and hexadecane contact angle values are plotted in Figure 5. Generally, the higher the dispersant percentage, the higher the static contact angle's values.This can be attributed to the dispersant's propensity to facilitate the production of smaller particles, leading to a more even distribution across the surface and ensuring more uniform coatings, avoiding agglomerations of nanoparticles in which the hydrogen bonds might take place with the water drop.The static angle exhibits a certain correlation with substrate characteristics, typically ranking as sandstone > limestone > granite.A surface with a higher degree of roughness results in drops settling on the surface's peaks, diminishing the contact area, causing drop deformations, and ultimately, increasing the contact angle.
As for solvents, it is evident that coatings in the SPHB medium exhibit greater hydrophobicity compared with those employing OHB as the hosting matrix.When testing water droplets, certain SPHB coatings can surpass a 150 • angle, confirming the exhibition of the lotus effect.This denotes a superhydrophobic system where, despite contact with the surface, the droplet maintains its spherical shape, enabling it to effortlessly roll and remove contaminants from the surface, effectively self-cleaning the surface.Tests conducted with hexadecane as the contacting liquid revealed lower contact angle values than those observed with water.This discrepancy can be attributed to the relatively weaker cohesive forces between the molecules of hexadecane in the droplets (London forces) when compared to the cohesive forces in water (hydrogen bonds).When cohesive forces are strong, adhesive forces to the substrate are diminished, resulting in higher contact angle values, as observed with water.
The current study also checked the photocatalytic effectiveness of the coatings once they were applied to the substrates.Figure 6 displays the abatement results.It is worth emphasizing that the coatings contained only 1% (wt/vol) of the photocatalyst.Therefore, a decrease in NO x abatement can be anticipated in comparison to the results obtained with the powdered catalyst.
The SPHB coatings were capable of removing, on average, ca.10% of NO under solar irradiation.Some treated substrates were able to degrade between 10 and 15% and a few samples above 15%.Removal of NO x yielded lower percentages.According to the norm UNE 127197-1:2013 [67], for catalytic concrete products, the coatings onto limestone would be classified on average as Class 1 (NO x removal between 4.0 and 6.0%) and the coatings onto sandstone as Class 2 (range of removal 6.0-8.0%).Coatings applied onto granite were not able to remove NO x above 4.0% on average, although samples BiZn1 and BiZn7 were able to remove, respectively, 7.0% and 5.7% of NO x (Class 2 and 1, respectively).Some previous work with pure TiO 2 nanoparticles reported, on average, higher NO and NO x abatements, but the experimental conditions are not comparable.In particular, the illumination in most of these works was strictly UV [68][69][70].The current study also checked the photocatalytic effectiveness of the coatings once they were applied to the substrates.Figure 6 displays the abatement results.It is worth emphasizing that the coatings contained only 1% (wt/vol) of the photocatalyst.Therefore, a decrease in NOx abatement can be anticipated in comparison to the results obtained with the powdered catalyst.Under strictly visible irradiation, the NO and NO x removal values were seen to decrease in comparison with the solar irradiation.This finding had been previously reported in other photocatalytic nanoparticles: the illumination with UV light always provides great efficiency to the photocatalytic oxidation of nitrogen oxides.In this case, ZnO-owing to its wide band gap-exhibits an absorption peak at a wavelength of 378 nm [71].In spite of the modification of some parts of the ZnO due to the formation of some heterojunctions with Bi 2 O 3 (which was added up to a maximum of 8% wt/wt), the cut-off with the filter of the wavelengths below 410 nm involved a dramatic decrease in the activity of the predominant ZnO.In addition, previous studies have shown that the absorption edges of heterojunctions of Bi 2 O 3 and ZnO from 5% to 15% of Bi 2 O 3 range between 419 nm and 409 nm, so the filter might also have had a strong influence on the decrease in the visible light activity of these samples.
Catalysts 2023, 13, x FOR PEER REVIEW 9 of 28 The current study also checked the photocatalytic effectiveness of the coatings once they were applied to the substrates.Figure 6 displays the abatement results.It is worth emphasizing that the coatings contained only 1% (wt/vol) of the photocatalyst.Therefore, a decrease in NOx abatement can be anticipated in comparison to the results obtained with the powdered catalyst.The SPHB coatings were capable of removing, on average, ca.10% of NO under solar irradiation.Some treated substrates were able to degrade between 10 and 15% and a few samples above 15%.Removal of NOx yielded lower percentages.According to the norm UNE 127197-1:2013 [67], for catalytic concrete products, the coatings onto limestone would be classified on average as Class 1 (NOx removal between 4.0 and 6.0%) and the coatings onto sandstone as Class 2 (range of removal 6.0-8.0%).Coatings applied onto granite were not able to remove NOx above 4.0% on average, although samples BiZn1 and BiZn7 were able to remove, respectively, 7.0% and 5.7% of NOx (Class 2 and 1, respectively).Some previous work with pure TiO2 nanoparticles reported, on average, higher NO and NOx abatements, but the experimental conditions are not comparable.In particular, the illumination in most of these works was strictly UV [68][69][70].
Under strictly visible irradiation, the NO and NOx removal values were seen to decrease in comparison with the solar irradiation.This finding had been previously reported in other photocatalytic nanoparticles: the illumination with UV light always provides great efficiency to the photocatalytic oxidation of nitrogen oxides.In this case, ZnO-owing to its wide band gap-exhibits an absorption peak at a wavelength of 378 nm [71].In spite of the modification of some parts of the ZnO due to the formation of some heterojunctions with Bi2O3 (which was added up to a maximum of 8% wt/wt), the cut-off with the filter of the wavelengths below 410 nm involved a dramatic decrease in the activity of the predominant ZnO.In addition, previous studies have shown that the absorption edges of heterojunctions of Bi2O3 and ZnO from 5% to 15% of Bi2O3 range between 419 nm and 409 nm, so the filter might also have had a strong influence on the decrease in the visible light activity of these samples.
The noticeable decrease in activity of the coatings with respect to the photocatalyst in the powdered samples (results of Figure 2) has two causes: on the one hand, the low percentage of photocatalyst in the coating, which is only 1% (wt/vol) and, on the other hand, the fact that the active nanoparticles are embedded in the SPHB or OHB matrix, reducing their direct contact with the nitrogen oxides.Here, the more penetrating and energetic UV radiation is also critical to reach and activate nanoparticles that are more shielded by the hydrophobic matrix.
This shielding of the active nanoparticles was even more intense with the hydro-oleophobic matrix, OHB, with a different chemical composition.Also, with solar lighting, the limestone and sandstone substrates could be classified as Class 2 and Class 1 due to their NOx reduction percentages.On average, the photocatalytic activity under visible illumination was lower than that observed with SPHB matrix coatings.The greater particle size observed in OHB coatings, when compared with SPHB coatings, can also be put forth as The noticeable decrease in activity of the coatings with respect to the photocatalyst in the powdered samples (results of Figure 2) has two causes: on the one hand, the low percentage of photocatalyst in the coating, which is only 1% (wt/vol) and, on the other hand, the fact that the active nanoparticles are embedded in the SPHB or OHB matrix, reducing their direct contact with the nitrogen oxides.Here, the more penetrating and energetic UV radiation is also critical to reach and activate nanoparticles that are more shielded by the hydrophobic matrix.
This shielding of the active nanoparticles was even more intense with the hydrooleophobic matrix, OHB, with a different chemical composition.Also, with solar lighting, the limestone and sandstone substrates could be classified as Class 2 and Class 1 due to their NO x reduction percentages.On average, the photocatalytic activity under visible illumination was lower than that observed with SPHB matrix coatings.The greater particle size observed in OHB coatings, when compared with SPHB coatings, can also be put forth as a rationale for this observation.In SPHB coatings, it was evident that using Brij35 at the highest dosage proved to be the most efficient dispersing agent for enhancing photocatalytic activity.This observation aligns with the earlier discussed reduction in particle size.On the other hand, in OHB coatings, Tween20 emerged as the most effective dispersant, which is consistent with the particle size distribution measurements.
Regarding the impact of assayed substrates, it is noteworthy that both SPHB and OHB coatings exhibit superior performance on limestone.This is due to the enhanced adsorption of NO and NO x and their subsequent photocatalytic degradation, facilitated by the substrate's rich composition in alkaline-earth metal oxides and carbonates [72].The results indicate that granite, as a support, yielded the least effective results in terms of NO and NO x abatement.
Apart from its chemical composition, the smoother surface of the granite specimen may influence the distribution of the photocatalyst on the stone surface, thereby affecting its photocatalytic effectiveness.Additionally, when used as a support, coatings on granite were the thinnest of all.The lower porosity of granite is also a relevant factor to consider since it limits the penetration of the coating and, accordingly, its activity.

Durability of the Coatings
All assayed samples comprising the different coatings onto the various substrates were subjected to accelerated climatic ageing to simulate the wear and tear that the coatings would undergo in an actual environmental setting.Table 3 summarizes the percentage of coating thickness that has been lost as a result of wear.
As a result of the simulated climatic ageing, a reduction in thickness was observed, which was more pronounced for OHB coatings compared with SPHB coatings.On average, there was a 15.1% decrease in thickness for OHB coatings, while SPHB coatings experienced an 11.4% reduction.These findings indicate that a washing and drag-out of the coating material has taken place, along with a leaching phenomenon.The contact angle also saw a decrease following the ageing process (Figure 7), particularly in OHB coatings as opposed to SPHB coatings.The hydrophobicity decreased more significantly in the OHB-treated samples.After the degradation due to climatic ageing, all measured water contact angles for SPHB coatings were below 150 • , resulting in the loss of superhydrophobicity.However, water repellency was maintained in nearly all samples treated with SPHB coatings, with water contact angles above 90 • .This was also true for OHB coatings applied onto sandstone.Oleo-repellency experienced a substantial reduction, confirming the damage caused by accelerated climatic ageing.
The surface wettability assessment method using the dynamic contact angle study ('advance and receding contact angle', ARCA) was also carried out on coatings once they had been subjected to accelerated climatic ageing (Figure 8).This method gives a closer idea of the reality of non-ideal surfaces with chemical and topological heterogeneities.
The advance angle (ACA) primarily pertains to how the surface interacts with the liquid in the test, either attracting or repelling it, and is particularly influenced by the surface's hydrophobic properties.Conversely, the receding angle (RCA) is more associated with the hydrophilic interplay between the liquid (water) and the surface due to adhesion forces.
On an ideal surface that is completely smooth, uniform, and unreactive, the hysteresis (the difference between ACA and RCA) would be zero.Surfaces with high hysteresis values imply situations of significant heterogeneity, including high roughness and/or chemical diversity.On such surfaces, water droplets would exhibit limited mobility.In the instance of superhydrophobic surfaces, both ACA and RCA are anticipated to exceed 150 • , and these surfaces are also expected to resist the adhesion of liquid droplets, resulting in low hysteresis values.Hysteresis values obtained after these measurements are presented in Table 4.
significantly in the OHB-treated samples.After the degradation due to climatic ageing, all measured water contact angles for SPHB coatings were below 150°, resulting in the loss of superhydrophobicity.However, water repellency was maintained in nearly all samples treated with SPHB coatings, with water contact angles above 90°.This was also true for OHB coatings applied onto sandstone.Oleo-repellency experienced a substantial reduction, confirming the damage caused by accelerated climatic ageing.The surface wettability assessment method using the dynamic contact angle study ( advance and receding contact angle , ARCA) was also carried out on coatings once they had been subjected to accelerated climatic ageing (Figure 8).This method gives a closer idea of the reality of non-ideal surfaces with chemical and topological heterogeneities.These experimental values revealed that superhydrophobicity was no longer present following exposure to climatic ageing.However, in the ARCA dynamic measurements, ACA values were below 150 • .It is worth noting, however, that, in some cases, the values came very close to this threshold, indicating that despite the deterioration they underwent, a number of samples still showed a persistent water-repelling effect.
The coatings applied on limestone exhibited the lowest average hysteresis.This suggests that the adhesion of water droplets is expected to be quite minimal.Even after enduring accelerated weathering, the coating remains effective in safeguarding the material from water penetration.On the other hand, granite and sandstone exhibited higher average hysteresis values.This is due to chemical heterogeneity in the case of granite, resulting in increased interactions between water droplets or hexadecane and the substrate.In the case of sandstone, it is attributed to its topological heterogeneity, namely its rough surface.Limestone, being more homogeneous in composition and less rough, yielded lower hysteresis.The surface wettability assessment method using the dynamic contact angle study ( advance and receding contact angle', ARCA) was also carried out on coatings once they had been subjected to accelerated climatic ageing (Figure 8).This method gives a closer idea of the reality of non-ideal surfaces with chemical and topological heterogeneities.The advance angle (ACA) primarily pertains to how the surface interacts with the liquid in the test, either attracting or repelling it, and is particularly influenced by the surface's hydrophobic properties.Conversely, the receding angle (RCA) is more associated Considering the positive outcomes regarding the durability of the treated limestone, an AFM analysis was conducted on a sample of this material coated with SPHB (designated as sample BiZn1) both before and after undergoing an ageing process.The aim was to assess any alterations in surface roughness and composition.A 10 × 10 micron scan provided insight into the coating's surface (Figure 9).In its original state, the coating exhibited a relatively uniform coverage over the observed region.However, in the modified specimen, a smoother area with fewer irregularities was observed.These experimental values revealed that superhydrophobicity was no longer present following exposure to climatic ageing.However, in the ARCA dynamic measurements, ACA values were below 150°.It is worth noting, however, that, in some cases, the values came very close to this threshold, indicating that despite the deterioration they underwent, a number of samples still showed a persistent water-repelling effect.
The coatings applied on limestone exhibited the lowest average hysteresis.This suggests that the adhesion of water droplets is expected to be quite minimal.Even after enduring accelerated weathering, the coating remains effective in safeguarding the material from water penetration.On the other hand, granite and sandstone exhibited higher average hysteresis values.This is due to chemical heterogeneity in the case of granite, resulting in increased interactions between water droplets or hexadecane and the substrate.In the case of sandstone, it is attributed to its topological heterogeneity, namely its rough surface.Limestone, being more homogeneous in composition and less rough, yielded lower hysteresis.
Considering the positive outcomes regarding the durability of the treated limestone, an AFM analysis was conducted on a sample of this material coated with SPHB (designated as sample BiZn1) both before and after undergoing an ageing process.The aim was to assess any alterations in surface roughness and composition.
A 10 × 10 micron scan provided insight into the coating s surface (Figure 9).In its original state, the coating exhibited a relatively uniform coverage over the observed region.However, in the modified specimen, a smoother area with fewer irregularities was observed.
( (  This phenomenon was also evident in the 3D renderings of the 10 × 10 micron regions (Figure 9).It was observed that the ageing process led to a smoothing of the material s surface and a decrease in its overall height variation.
Upon closer inspection, it became feasible to ascertain the topography of the ceramic nano-oxides that govern the characteristics of the SPHB coating.The textural porosity (Figure 10a,b), facilitating the breathability of the stone substrates onto which the coating is applied, was duly observed.After the accelerated degradation, the surface of the deteriorated coating appears more worn and smoother when compared to the almost step-like pattern exhibited by the original sample topographic scan (Figure 10c,d).This phenomenon was also evident in the 3D renderings of the 10 × 10 micron regions (Figure 9).It was observed that the ageing process led to a smoothing of the material's surface and a decrease in its overall height variation.
Upon closer inspection, it became feasible to ascertain the topography of the ceramic nano-oxides that govern the characteristics of the SPHB coating.The textural porosity (Figure 10a,b), facilitating the breathability of the stone substrates onto which the coating is applied, was duly observed.After the accelerated degradation, the surface of the deteriorated coating appears more worn and smoother when compared to the almost step-like pattern exhibited by the original sample topographic scan (Figure 10c,d).This phenomenon was also evident in the 3D renderings of the 10 × 10 micron regions (Figure 9).It was observed that the ageing process led to a smoothing of the material s surface and a decrease in its overall height variation.
Upon closer inspection, it became feasible to ascertain the topography of the ceramic nano-oxides that govern the characteristics of the SPHB coating.The textural porosity (Figure 10a,b), facilitating the breathability of the stone substrates onto which the coating is applied, was duly observed.After the accelerated degradation, the surface of the deteriorated coating appears more worn and smoother when compared to the almost step-like pattern exhibited by the original sample topographic scan (Figure 10c,d).In evaluating the 3D renderings, the Z scale is shown.While the original sample scan has an overall height difference of 1.17 microns, the aged sample scan shows an overall height difference of 0.38 microns.This observation is further supported by the RMS roughness measurements (Figure 11), thus confirming that the deteriorated sample is far smoother (48.06 nm vs. 211.5 nm) when compared directly with the original undamaged coating.
Catalysts 2023, 13, x FOR PEER REVIEW 17 of 28 In evaluating the 3D renderings, the Z scale is shown.While the original sample scan has an overall height difference of 1.17 microns, the aged sample scan shows an overall height difference of 0.38 microns.This observation is further supported by the RMS roughness measurements (Figure 11), thus confirming that the deteriorated sample is far smoother (48.06 nm vs. 211.5 nm) when compared directly with the original undamaged coating.Close phase examination evidenced the actual intercalation of both SPHB components and photocatalytically active nanoparticle phases.When comparing the differences between the phase images of the two samples (Figure 12), it is evident that the original undamaged coating has more contrast between the different phase zones.It is clear that the overall composition of the surfaces of undamaged and damaged samples is simply different, and this finding is ascribable to the loss of active BiZn nanoparticles due to the ageing process.NOx degradation ability of coatings on substrates was also studied after subjecting them to climatic ageing.Results are collected in Figure 13.Close phase examination evidenced the actual intercalation of both SPHB components and photocatalytically active nanoparticle phases.When comparing the differences between the phase images of the two samples (Figure 12), it is evident that the original undamaged coating has more contrast between the different phase zones.It is clear that the overall composition of the surfaces of undamaged and damaged samples is simply different, and this finding is ascribable to the loss of active BiZn nanoparticles due to the ageing process.
Catalysts 2023, 13, x FOR PEER REVIEW 17 of 28 In evaluating the 3D renderings, the Z scale is shown.While the original sample scan has an overall height difference of 1.17 microns, the aged sample scan shows an overall height difference of 0.38 microns.This observation is further supported by the RMS roughness measurements (Figure 11), thus confirming that the deteriorated sample is far smoother (48.06 nm vs. 211.5 nm) when compared directly with the original undamaged coating.Close phase examination evidenced the actual intercalation of both SPHB components and photocatalytically active nanoparticle phases.When comparing the differences between the phase images of the two samples (Figure 12), it is evident that the original undamaged coating has more contrast between the different phase zones.It is clear that the overall composition of the surfaces of undamaged and damaged samples is simply different, and this finding is ascribable to the loss of active BiZn nanoparticles due to the ageing process.NOx degradation ability of coatings on substrates was also studied after subjecting them to climatic ageing.Results are collected in Figure 13.NO x degradation ability of coatings on substrates was also studied after subjecting them to climatic ageing.Results are collected in Figure 13.
It can be observed that the photocatalytic ability of the coatings to abate NO under solar light exposure dropped after ageing, showing an average reduction of ca.36% for SPHB coatings and 41% for OHB coatings.This indicates that the harsh climatic conditions led to a significant decrease in photocatalytic activity due to the leaching and wash-out of the coatings.Interestingly, the limestone substrates retained substantial NO and NO x removal rates.This finding aligns with the mineralogical composition of the substrate and its ability to adsorb nitrogen oxides, thereby enhancing their photocatalytic oxidation.A further study was devoted to examining colour stability in the coatings following climatic ageing.Findings showed that, despite the effects of climatic degradation, the coatings effectively prevented staining from dye deposition and simultaneously broke down the dye through photocatalytic oxidation.This dual action was attributed to the repellent properties of the hydrophobic matrices and the photocatalytic capabilities of the BiZn nanoparticles.
On average, SPHB coatings exhibited a self-cleaning capacity, resulting in a 40.3% reduction in the deposited dye over a period of 310 min.Conversely, OHB coatings led to a 55.4% discolouration.

Materials
The catalyst consists of nanoparticles of the heterostructures Bi 2 O 3 -ZnO (8 wt%/92 wt%), synthesized by Flame Spray Pyrolysis at the LUrederra Technological Centre.Organometallic precursors (ethyl hexanoates, acetylacetonates, butoxides, and propoxides) were used.The solvents used include isopropyl alcohol, toluene, xylene, and acetic acid.The precursor mixture included both the precursor for Bi and the precursor for Zn as well as appropriate solvents.The equipment used was based on Liquid-Feed Flame Spray Pyrolysis (LFFSP) technology, where a liquid precursor mixture is combined with a dispersing gas to generate droplets in a flame.The nanometric droplets, after solvent evaporation and nucleation, result in solid nanoparticles of the desired composition.A carrier gas is in charge of the transport and cooling of the generated nanoparticles from the pyrolysis area to specific filter bags where the nanopowder is retained.Precursor flows were in the range of 5-10 mL min −1 , and dispersion gas was between 10 and 30 L min −1 .The nozzle pressure was typically around 1-3 bar.With the aim of removing any trace of non-desirable adsorbed compounds, residual from the synthesis of the active agents, nanoparticles were calcined at 450 • C prior to their use.
Two media were used to vehicle the nanoparticles of the photocatalyst, one exhibiting superhydrophobic properties (SPHB) and the other with a hydro-oleophobic ability (OHB).The SPHB and OHB matrices are formed by three-dimensional (3D) structures of inorganic ceramic nano-oxides.The SPHB-specific formulation is commercially available in the market as TECNADIS AQUASHIELD FORTE.Its data sheet describes it as a see-through and low-viscosity fluid.This liquid incorporates ceramic nanooxides that confer hydrophobic properties.After application, the isopropanol evaporates, resulting in a formulation that is compatible with any porous construction material of interest.Additionally, this formulation contains stabilizing additives that prevent nanoparticle agglomeration and form a lightweight matrix through partial bonding with the ceramic nanooxides.This leads to the creation of a 3D structure that ensures the breathability of the porous substrate.
Similarly, there is another 3D formulation available at TECNAN, known as TECNADIS PRS PERFORMANCE.This formulation achieves a hydro-oleophobic effect.Its technical documentation characterizes it as a translucent and colourless liquid containing ceramic nanoparticles that confer water-repellent properties.These nanoparticles are dispersed within an organic medium, specifically 2-propanol, ensuring their compatibility with porous or slightly porous substrates commonly found in the construction industry.
The chosen porous substrates for study purposes included limestone, sandstone, and granite.DICONA S.A., the supplying company, was responsible for overseeing the extraction and cutting processes of these substrates.The cutting and processing procedures resulted in varying surface characteristics among the samples.Consequently, the primary surface features observed were a high degree of roughness in the sandstones, a moderate level of roughness in the limestones, and a smooth surface in the granites [35].
In terms of density, the values were as follows: 2.670 g/cm 3 for limestone, 2.302 g/cm 3 for sandstone, and 2.721 g/cm 3 for granite.The open porosity, which refers to the porosity accessible to water and is measured using a hydrostatic balance, exhibited the following values: 6.62% for limestone, 15.54% for sandstone, and 1.24% for granite.Total porosity values, determined through mercury intrusion porosimetry (MIP) [73], were as follows: 8.61% for limestone, 20.85% for sandstone, and 1.69% for granite.The stone supports have a prismatic shape, and their dimensions are 5x5x2 cm.Three different non-ionic dispersing agents were used: Tween20 (supplied by Panreac), Brij 35, and TritonX-100 (supplied by Sigma).

Characterization of Nanoparticles
The nanoparticles of Bi 2 O 3 -ZnO (8/92) were characterized, and the average diameter of the particles were determined by the physisorption of N 2 (Micromeritics ASAP 2020, Norcross, GA, USA) according to the BET algorithm.X-ray Fluorescence (XRF) measurements were accomplished with a Philips Magix Pro, PW2400.
To assess the photocatalytic effectiveness of the nanoparticles, a NO x reduction test was conducted in a laminar flow reactor, as outlined in ISO 2016 standards [74].This evaluation was carried out under two different lighting conditions: strictly visible radiation (with the use of a coloured glass filter (FGL420, Thorlabs, Newton, NJ, USA), which completely cuts off wavelengths shorter than 410 nm) and UV-VIS illumination.A 300 W Osram Ultravitalux lamp was used as the light source [75].The lamp's nominal irradiance at a distance of 0.5 m after 1 h was measured to be 41.4 Wm −2 (780-400 nm), 13.6 Wm −2 (400-315 nm), and 3.0 Wm −2 (315-280 nm).This lamp emits a combination of visible, UVA, and UVB radiation, providing a credible simulation of solar light [76,77].
Initially, a concentration of 500 ppb of NO was introduced into the reactor at a flow rate of 3.0 L min −1 .To ensure that there is no adsorption on the samples, the system was kept in the dark for a period of 10 min.Subsequently, the lighting was activated, and the concentrations of both NO and NO 2 were monitored using a chemiluminescence detector (Environnement AC32M, Geneva, IL, USA).The samples were exposed to this illumination for 1 h, and once the lighting was turned off, the system was allowed to stand until the initial NO levels (500 ppb) were regained.Each experimental measurement was conducted in triplicate.The abatement efficiencies were determined by comparing the averages of the initial ten measurements (taken during the lamp's stabilization) with the averages of the final ten measurements (prior to turning off the lamp).

Preparation of Multifunctional Active Coatings and Evaluation of Their Efficiency
The compatibility and efficiency of the nanoparticles with the 3D structure were evaluated.In Table 5, the composition of the different coatings is displayed.The dispersions summarized in Table 5 were submitted to magnetic stirring for 45 min, and then they were applied to the stone support (5 × 5 × 2 cm) of granite, limestone, and sandstone.Each stone was kept in a horizontal position and was covered with 1 mL of solution.Stone samples were allowed to rest for 24 h, after which time they were completely dried.
Zeta potential studies were carried out to ascertain the stability of the suspensions, and titrations were conducted to check the effect of the addition of the dispersant on the catalyst by means of ZetaProbe Analyzer Colloidal Dynamics (Ponte Vedra Beach, FL, USA).BiZn 1% solutions (0.5 g of catalyst and 50 mL of solvent) and 0.1% dispersant solutions (0.1 g dispersant and 100 mL of solvent) were prepared for the titrations.The particle size distributions of the coatings were characterized by a size test with a laser diffractometer (Malvern Mastersizer, Malvern, United Kingdom).
A surface is considered super water-repellent when it exhibits a contact angle greater than 150 degrees and hysteresis of less than 10 degrees.In such cases, the force required to displace the drop on the surface is exceptionally low, indicating high repellency.Superhydrophobic surfaces typically possess rough textures, and their chemical composition can reduce surface free energy, enabling them to effectively repel water.As a result, surfaces with rougher coatings [81,82] and lower surface free energy [82] tend to have smaller surface-to-surface contact areas and exhibit less affinity for the liquid drop.
The photocatalytic activity of the coatings was assessed by means of an abatement test made in a laminar flow reactor (ISO 2016) to measure NO x reduction with a 300 W Osram Ultravitalux lamp, according to the conditions detailed above in Section 3.2.1.

Durability of the Coatings after Accelerated Climatic Ageing
To assess the long-term performance of the coatings, a simulation of various climatic conditions was conducted within the FCH-XENOLAB 1500 climatic chamber (CCI, Barcelona, Spain).These simulation cycles incorporated alterations in temperature, exposure to UV-VIS radiation, variations in relative humidity, and exposure to artificial rainwater.Each cycle consisted of four 1 h phases, repeated six times, as follows: • Maintaining conditions at 35

•
Extending the simulation to −5 • C with a relative humidity of 50%.After accelerated weathering, the persistence of the photocatalytic ability was monitored by measuring the continuous NO x abatement (according to the aforementioned method) as well as by colour degradation studies (self-cleaning performance).
In the samples showing the best performances, Atomic Force Microscopy (AFM) analysis was used to evaluate the changes in roughness and composition as a consequence of climatic ageing.A SA-AFM instrument (AFM Workshop, Hilton Head Island, SC, USA) and a 50-micron XY Scanner with a 17-micron Z range were required.The SA-AFM was calibrated with a 10 µm pitch reference standard from Bugdet Sensors with a 103 nm step height, HS-100MG.Calibrations affected the X, Y, and Z axes.
To evaluate the self-cleaning properties of the coatings, a colour degradation test was conducted using a 300 W Osram Ultravitalux lamp and a Konika Minolta spectrophotometer (Spectrophotometer CM-2300d, Tokyo, Japan).This test involved applying three layers of a 1mM solution of rhodamine B to the surface of the stone support using a brush.Subsequently, the samples were exposed to UV-VIS radiation at a distance of 20 cm from the radiation source.Data points were collected at intervals of 5, 20, 80, 140, and 310 min by measuring the coordinates L (luminosity), a (red-green range), and b (blue-yellow range).The degree of colour variation (∆C n ) can be estimated through Equation (1).The whole experimental procedure's scheme is shown in Figure 14.
* −  * +  * −  * Equation (1): colour variation equation.Where  * and  * are coordinates at a given time,  * and  * are coordinates of undyed stones, and  * and  * are coordinates of newly dyed stones, as published in the article by Fornasini et al. [83].
The whole experimental procedure s scheme is shown in Figure 14.

Conclusions
A combination of either superhydrophobic 3D inorganic structures (referred to as SPHB medium) or hydro-oleophobic 3D inorganic structures (referred to as OHB medium) and photocatalytic nanoparticles comprising heterostructures of Bi 2 O 3 -ZnO (8 wt%/92 wt%) were used to create multifunctional coatings.These coatings were applied onto inorganic substrates commonly found in Built Heritage, namely granite, sandstone, and limestone.To prevent nanoparticle agglomeration, three non-ionic dispersants (Tween20, TritonX-100, and Brij35) were introduced in the coatings as well.It was observed that the use of dispersant agents led to an improvement in the dispersion's particle size distribution and enhanced photocatalytic efficiency.Among these, Brij-35, at its highest concentration (3%), revealed the most effective dispersing action, attributed to steric hindrance.
The applied coatings exhibited evident hydrophobic properties and, particularly in the case of OHB, showed a certain degree of oleophobic behaviour, too.The assessment of the coatings' static angles was influenced by the substrate's properties, with sandstone (possessing greater surface roughness) yielding the highest contact angles.In some cases, water contact angles exceeding 150 • were recorded, indicating the superhydrophobic nature of these surfaces.The coatings displayed notable photocatalytic activity, especially when exposed to UV-VIS irradiation.According to the standard UNE 127197-1:2013, the SPHB coatings on limestone fell within Class 1 (NO x removal between 4.0 and 6.0%), while those on sandstone were classified as Class 2 (with a removal range of 6.0-8.0%).
In SPHB coatings, Brij-35 emerged as the dispersant that most effectively enhanced photocatalytic efficiency, while in OHB coatings, Tween20 proved to be the most efficient dispersant, in agreement with particle size distribution measurements.OHB coatings, however, exhibited lower NO x reductions compared with those observed in SPHB dispersions due to the shielding effect of the photocatalytic nanoparticles within the matrix.
Limestone substrates exhibited the highest photocatalytic removal of nitrogen oxides, attributed to the superior adsorption of NO and NO x , as well as their subsequent photocatalytic degradation.This was enabled by the composition of the substrate, which was rich in alkaline-earth metal oxides and carbonates.
Accelerated climatic ageing studies conducted on treated specimens revealed a reduction in static contact angles and coating thickness.Despite this, SPHB coatings maintained their hydrophobicity.Atomic Force Microscopy (AFM) studies indicated the leaching of active nanoparticles and the washout of the coating.The photocatalytic activity also experienced a decrease (averaging 36% for the SPHB coatings).Even after undergoing severe accelerated climatic deterioration, the limestone substrates exhibited the most substantial rates of NO and NO x removal, underscoring the effectiveness of these coatings in preventing water access and serving as photocatalytic surfaces.No adverse impacts were noted on the treated materials, affirming the safety of employing these coatings on Architectural Heritage.

Figure 2 .
Figure 2. NO and NOx removal capacity of the powdered nanoparticles of the photocatalyst unde solar and visible light irradiation.

Figure 2 .
Figure 2. NO and NO x removal capacity of the powdered nanoparticles of the photocatalyst under solar and visible light irradiation.

Figure 6 .
Figure 6.Photocatalytic NO and NOx removal rates of the SPHB coatings under (a) solar and (b) visible irradiation, as well as OHB coatings under (c) solar and (d) visible irradiation.

Figure 6 .
Figure 6.Photocatalytic NO and NO x removal rates of the SPHB coatings under (a) solar and (b) visible irradiation, as well as OHB coatings under (c) solar and (d) visible irradiation.

Figure 7 .
Figure 7. Static contact angle after climatic ageing of (a) SPHB coatings with water, (b) OHB coatings with water, (c) OHB coatings with hexadecane.

Figure 7 .
Figure 7. Static contact angle after climatic ageing of (a) SPHB coatings with water, (b) OHB coatings with water, (c) OHB coatings with hexadecane.

Figure 7 .
Figure 7. Static contact angle after climatic ageing of (a) SPHB coatings with water, (b) OHB coatings with water, (c) OHB coatings with hexadecane.

Figure 9 .
Figure 9. Coating s surface changes as consequence of climate ageing (a) before and (b) after the ageing.Three-dimensional rendering of surface s coating (c) before and (d) after ageing.

Figure 10 .
Figure 10.Porosity s surface changes as consequence of climate ageing: (a) before ageing; (b) after ageing.Topographic scan before (c) and after climate ageing (d).

Figure 9 .
Figure 9. Coating's surface changes as consequence of climate ageing (a) before and (b) after the ageing.Three-dimensional rendering of surface's coating (c) before and (d) after ageing.

Catalysts 2023 , 28 Figure 9 .
Figure 9. Coating s surface changes as consequence of climate ageing (a) before and (b) after the ageing.Three-dimensional rendering of surface s coating (c) before and (d) after ageing.

Figure 10 .
Figure 10.Porosity s surface changes as consequence of climate ageing: (a) before ageing; (b) after ageing.Topographic scan before (c) and after climate ageing (d).

Figure 10 .
Figure 10.Porosity's surface changes as consequence of climate ageing: (a) before ageing; (b) after ageing.Topographic scan before (c) and after climate ageing (d).

Figure 12 .
Figure 12.Phase images before (left) and after (right) the climate ageing.

Figure 12 .
Figure 12.Phase images before (left) and after (right) the climate ageing.

Figure 12 .
Figure 12.Phase images before (left) and after (right) the climate ageing.

(Figure 13 .
Figure 13.Photocatalytic NO and NO x removal rates after climatic ageing of the SPHB coatings under (a) solar and (b) visible irradiation and OHB coatings under (c) solar and (d) visible irradiation.
colour variation equation.Where a * t and b * t are coordinates at a given time, a * c and b * c are coordinates of undyed stones, and a * 0 and b * 0 are coordinates of newly dyed stones, as published in the article by Fornasini et al. [83].

Figure 14 .
Figure 14.Scheme of the experimental work.

Figure 14 .
Figure 14.Scheme of the experimental work.

Table 1 .
Net values of zeta potential of dispersion of BiZn in SPHB and OHB media.

Table 1 .
Net values of zeta potential of dispersion of BiZn in SPHB and OHB media.

Table 2 .
Thickness values of the coatings with BiZn nanoparticles.

Table 4 .
Hysteresis (difference between ACA and RCA dynamic studies of the contact angle after climatic ageing).
• C, with exposure to UV-VIS radiation and a relative humidity of 40%; • Reducing temperature to 20 • C with a relative humidity of 90%, simulating rainwater exposure; • Lowering the temperature further to 0 • C with a relative humidity of 60%;