Copper Tricomponent Catalysts Application for Hydrogen Production from Ethanol

: The application of copper-based catalysts in the production of pure hydrogen in the steam reforming of ethanol was performed. The tricomponent Cu/Zr catalysts with about 4 mass% addition of nickel, cobalt, or cerium have been prepared in our laboratory. The properties of obtained catalysts were compared with bimetallic Cu/Zr catalyst prepared and tested according to the same procedure. Catalytic tests were carried out in the continuous ﬂow ﬁxed–bed reactor in the wide temperature range of 433–593 K for initial molar ratio of ethanol to water equal to 1:3. Catalysts were characterized by XRD, TPR, CO 2 –TPD, and TPO methods. Cu/Zr/Ce catalyst proved to be the best; hydrogen yield reached the value of 400 L/(kg cat. · h), selectivity towards carbon monoxide was below 0.5% and the one towards methane wasnot detected. Additions of Ni or Co did not bring signiﬁcant improvement in activity.


Introduction
The rising energy production in all developed and developing countries causes the corresponding increase in the environment pollution.New restrictions and regulations require new clean technologies of high efficiency of energy generation [1].Hydrogen is considered as a carrier of clean energy.Many methods of hydrogen production have been developed.The industrial production of hydrogen is currently carried out in the process of gasification of coal and other fossil materials, in the process of steam reforming of hydrocarbons (mainly methane), oxygenates (mainly methanol) [2,3], and from water electrolysis [4].Many attempts have been made in recent decades to produce hydrogen from ethanol or bioethanol derived from any source of starch [5].In the process of ethanol steam reforming (ESR) hydrogen is a product of highly endothermic catalytic reaction [6]: 3.74 (mol H 2 /mol ethanol converted) were observed at temperature of 633 K over catalyst with 2.5 mass% Mn loading, at ethanol/water ratio equal to 1:6 [41].Dong et al. [45] investigated the effect of four preparation methods: sol-gel, co-precipitation, one-step impregnation, and two-step impregnation on activity of Cu/Ce/Zr (1/9/1 metal ratio) catalysts in carbon monoxide removal from gas rich in hydrogen.They found the best co-precipitation method, with Na 2 CO 3 as precipitant, at calcination temperature of 773 K. Śliwa and Samson [42] used CuO/ZrO 2 catalysts doped with Mn, Ni, or Ga in ESR process.
The reaction parameters were as follows: temperature of 623 K, ethanol/water ratio equal to 1:10, CuO/ZrO 2 ratio equal to 2.3 mass%/mass%, and the concentration of dopants was 5 mass%.The maximum hydrogen yield, 52% of the stoichiometric ethanol efficiency value, was achieved by the addition of nickel.However, it was accompanied with 17% selectivity to CO. Bergamaschi et al. [24] found that addition of 6 mass% of nickel to Cu/Z r catalyst increased specific surface area BET and hydrogen selectivity at 573 K. Dancini-Pontes et al. [43] found that Cu/Ni/CeO 2 catalyst revealed much higher resistance to deactivation and better efficiency at temperature of about 723 K, in comparison with Cu/Ni system.The presence of nitrogen in reaction mixture increased hydrogen selectivity of about 20-30% after 8 h reaction course at temperature of 723 K. Snytnikov et al. [8] achieved nearly 20% increase in hydrogen selectivity and only about 2% CO content in the product at relatively low temperature of 623 K by an addition of γ-Al 2 O 3 to CuO/CeO 2 catalyst.
The properties of these catalysts depend mainly not only on their composition, especially on active metal content, but also on the parameters of preparation.Activity and lifetime of a catalyst can be improved by a method of preparation.Chen et al. [44] obtained nearly twice an increase in hydrogen yield by significantly lowering the temperature of reduction with hydrogen (from 923 to 623 K) of CuNi/SiO 2 catalyst.
The literature data indicate that improvements in catalyst activity and resistance to deactivation can be achieved by introducing a third component, changing the ratio of individual elements in the catalyst, activation parameters, preparation method, and even the composition of the reaction mixture.However, it is difficult to say which of the catalysts presented in the literature was the best because their activities were usually tested under different, often not fully specified conditions, and their activity parameters were also different.
The aim of the presented work was to obtain an active and selective catalyst for hydrogen production in ethanol steam reforming by introducing Ni, Co, or Ce additives to a Cu/Zr binary catalyst studied previously [17].

Characteristics of the Catalysts
The phase composition of the catalysts after hydrogen reduction was determined by XRD.The XRD patterns ofthe catalysts after hydrogen reduction are presented in Figure 1.In the obtained XRD patterns (Figure 1), the Cu o (2θ= 43, 51°) and ZrO2 (2θ= 30°) phases are present.The intensity of XRD peaks related with metallic copper are higher in comparison with XRD peak assigned to ZrO2.This may be caused by the different con- In the obtained XRD patterns (Figure 1), the Cu o (2θ = 43, 51 • ) and ZrO 2 (2θ = 30 • ) phases are present.The intensity of XRD peaks related with metallic copper are higher in comparison with XRD peak assigned to ZrO 2 .This may be caused by the different concentration of these two phases and differences in the crystallite sizes.On the other hand, there are no XRD peaks related to the CoO, NiO, and CeO 2 phases in the diffractograms.The lack of these signals can be due to high dispersion of additives in the synthesized catalysts.The crystallite sizes calculated by Scherrer method are presented in Table 1.The crystallite sizes of Cu 0 are larger than others.Large crystallites of copper revealed low dispersion that ranges from 2% for Cu/Zr/Ni catalyst and 1.7% for Cu/Zr/Co to 0.9% for Cu/Zr/Ce [7].
Experimental adsorption and desorption isotherms of nitrogen (77 K) are presented in Figure 2a.The investigated catalysts reveal mesopore structure with homogeneous pore distribution, which is characteristic for capillary condensation typical for the mesopore range.This is supported by the shape of the isotherms, which are of type IV (according to IUPAC classification) with hysteresis loops of type H1 for all tested catalysts (cylindrical pores of almost constant cross-section) (Figure 2a) [46].Moreover, this is in line with the pore volume distribution profiles exhibiting single narrow peaks with maximum at 4 nm (Figure 2b).Cu/Zr and Cu/Zr/Ni catalysts havemuch more mesoporous structure compared with Cu/Zr/Co and Ce/Zr/Ce catalysts.The copper surface area (SCu), specific surface area BET (SBET), pore volume (Vp), and average pore diameter (Dp) are presented in Table 1.An addition of an oxide of Ce, Co, or Ni to Cu/Zr catalyst results in about 60-70% increase in SCu and SBET values followed by Vp increase in the following order: Cu/Zr<Cu/Zr/Co<Cu/Zr/Ce<Cu/Zr/Ni.The total pore volume of obtained catalysts reaches about 0.14 cm 3 /g.H2-TPR profiles of investigated catalysts are presented in  Cu/Zr and Cu/Zr/Ni catalysts havemuch more mesoporous structure compared with Cu/Zr/Co and Ce/Zr/Ce catalysts.The copper surface area (S Cu ), specific surface area BET (S BET ), pore volume (V p ), and average pore diameter (D p ) are presented in Table 1.An addition of an oxide of Ce, Co, or Ni to Cu/Zr catalyst results in about 60-70% increase in S Cu and S BET values followed by V p increase in the following order: Cu/Zr<Cu/Zr/Co<Cu/Zr/Ce<Cu/Zr/Ni.The total pore volume of obtained catalysts reaches about 0.14 cm 3 /g.[47,48].An addition of Co oxide to Cu/Zr catalyst causes decrease in the temperature corresponding to maximum reduction (T max ) rate by 40 K. Similar effect was observed for others dopants, but in this case, shift in T max was only by ca.20 K.
Cu/Zr and Cu/Zr/Ni catalysts havemuch more mesoporous structure compared with Cu/Zr/Co and Ce/Zr/Ce catalysts.The copper surface area (SCu), specific surface area BET (SBET), pore volume (Vp), and average pore diameter (Dp) are presented in Table 1.An addition of an oxide of Ce, Co, or Ni to Cu/Zr catalyst results in about 60-70% increase in SCu and SBET values followed by Vp increase in the following order: Cu/Zr<Cu/Zr/Co<Cu/Zr/Ce<Cu/Zr/Ni.The total pore volume of obtained catalysts reaches about 0.14 cm 3 /g.H2-TPR profiles of investigated catalysts are presented in Figure 3.The peaks were observed within the temperature range of 540-583 K.The observed single reduction peak refers solely to the reduction of CuO to Cu 0 .The addition of Ni or Co or Ce oxides to the Cu/Zr catalyst resulted in a 16-40° decrease in the temperature corresponding to the maximum reduction rate (Tmax) indicating that the dopants (Ni, Co and Ce) facilitate the reduction of CuO [47,48].An addition of Co oxide to Cu/Zr catalyst causes decrease in the temperature corresponding to maximum reduction (Tmax) rate by 40 K. Similar effect was observed for others dopants, but in this case, shift in Tmax was only by ca.20 K.The CO2-TPD experiments were performed in order to evaluate the surface basicity of the synthesized catalysts.The recorded TPD profiles (Figure 4) were analyzed in the temperature range corresponding with temperature at which the steam reforming of ethanol reaction had been carried out.The CO 2 -TPD experiments were performed in order to evaluate the surface basicity of the synthesized catalysts.The recorded TPD profiles (Figure 4) were analyzed in the temperature range corresponding with temperature at which the steam reforming of ethanol reaction had been carried out.For all catalysts, the very broad and complex desorption profile is observed with overlapping signals.In order to get insight in the distribution of weak, medium, and strong basic sites, the TPD profiles were deconvoluted into Gaussian peaks.Based on the maxima position of deconvoluted peaks, signals were assigned accordingly to desorption of CO 2 from weak (323-423 K), medium (423-513 K), and strong (>513 K) basic sites.Only deconvoluted maxima up to 623 K were used for the calculation of basic sites concentration (Table 2), since this was the final calcination temperature of catalysts.The maxima that were used for quantitative analysis are marked in the TPD profiles.In the case of all catalysts, the amount of adsorbed CO 2 and desorbed CO 2 during TPD experiments is the same, meaning that the entire CO 2 was desorbed during TPD runs in the analyzed temperature range.According to quantitative results (Table 2), the lowest concentration of basic sites is observed for Cu/Zr (56.2 µmol/g).In the case of this catalyst, the contribution of weak basic sites in total basicity is the highest among synthesized samples (41.3 µmol/g).On the other hand, the modification of Cu/Zr catalysts with dopants leads to increase in total surface basicity in the following order of Cu/Zr/Co<Cu/Zr/Ni<Cu/Zr/Ce.According to literature [49,50] weak basic sites can be related with surface hydroxyl group, medium basic sites with Zr 4+− O 2− pairs, and the strong basic sites with the low-coordination oxygen anions.
Additionally, the distribution of basic sites for modified catalysts changes in comparison with Cu/Zr.The decrease in concentration of weak basic sites is visible upon catalyst modification with Co and Ce, whereas concentration of weak basic sites decreases.Moreover, in the case of Cu/Zr/Ce, strong basic sites are generated (16.4 µmol/g).For catalyst doped with Ni, the amount of medium basic sites is higher when compared with Cu/Zr but there is no change in concentration of weak basic sites.

Catalytic Activity
Catalytic activity results are graphically presented in Figures 5-8.For catalyst doped with Ni, the amount of medium basic sites is higher when compared with Cu/Zr but there is no change in concentration of weak basic sites.

Catalytic Activity
Catalytic activity results are graphically presented in Figure 5, Figure 6, Figure 7 and Figure 8.All modified catalysts reached about 100% conversion of ethanol (see Figure 5), a slightly higher than basic Cu/Zr catalyst (~90% conversion).The temperature effected the hydrogen yield (see Figure 6) in similar way up to temperature of 550 K, giving the value of 300 L/(kgcat.•h).In the presence of Cu/Zr/Ni catalyst, further increase in temperature caused the highest increase in hydrogen yield, resulting inthe value of 490 L/(kgcat.•h)(Table 3); unfortunately accompanied by high production of carbon monoxide (see Figure 7, Table 3), harmful for fuel cells-27% selectivity at 553 K and rapid decrease to 6% selectivity at 593 K.The methane selectivity also reached high value of 36% at 593 K (see Figure 8 and Table 3), but it is not harmful, methane could potentially be used as a source of energy in this endothermic ethanol steam reforming process.All modified catalysts reached about 100% conversion of ethanol (see Figure 5), a slightly higher than basic Cu/Zr catalyst (~90% conversion).The temperature effected the hydrogen yield (see Figure 6) in similar way up to temperature of 550 K, giving the value of 300 L/(kgcat.•h).In the presence of Cu/Zr/Ni catalyst, further increase in temperature caused the highest increase in hydrogen yield, resulting inthe value of 490 L/(kgcat.•h)(Table 3); unfortunately accompanied by high production of carbon monoxide (see Figure 7, Table 3), harmful for fuel cells-27% selectivity at 553 K and rapid decrease to 6% selectivity at 593 K.The methane selectivity also reached high value of 36% at 593 K (see Figure 8 and Table 3), but it is not harmful, methane could potentially be used as a source of energy in this endothermic ethanol steam reforming process.All modified catalysts reached about 100% conversion of ethanol (see Figure 5), a slightly higher than basic Cu/Zr catalyst (~90% conversion).The temperature effected the hydrogen yield (see Figure 6) in similar way up to temperature of 550 K, giving the value of 300 L/(kg cat.•h).In the presence of Cu/Zr/Ni catalyst, further increase in temperature caused the highest increase in hydrogen yield, resulting inthe value of 490 L/(kg cat.•h) (Table 3); unfortunately accompanied by high production of carbon monoxide (see Figure 7, Table 3), harmful for fuel cells-27% selectivity at 553 K and rapid decrease to 6% selectivity at 593 K.The methane selectivity also reached high value of 36% at 593 K (see Figure 8 and Table 3), but it is not harmful, methane could potentially be used as a source of energy in this endothermic ethanol steam reforming process.7).
According to XRD analysis, the Cu/Zr/Co catalyst has large CuO crystallites and the smallest ZrO 2 crystallites.This is in agreement with the chemisorption of N 2 O, which showed that the Cu/Zr/Ce catalyst has low value of metallic copper dispersion and metallic coppers surface area (Table 1) resulting from agglomeration of copper crystallite.This can lead to lower hydrogen yield [52].Additionally, similar value of hydrogen yield is observed for Cu/Zr/Co catalyst, having the same average pore diameter as Cu/Zr/Ce catalyst.Mastalir et al. [53] in their investigation on methanol steam reforming found that the changes of copper concentration in Cu/Ce/Zr catalyst resulted in altering the microstructure of the Cu particles.An increase in Cu concentration from 5 to 35 wt%, at a constant ZrO 2 /CeO 2 molar ratio of 1/1, resulted in an increase in crystallite size and consequently a decrease in the specific surface area of the active particles and a significant inhibition of CO production.
The increase in the hydrogen yield for modified catalysts can results from higher surface basicity of these catalysts.This is due to the fact that surface sites of higher basicity catalyze the reaction of ethanol dehydrogenation to acetaldehyde (2) [54,55].
During ethanol steam reforming, different types of carbon are being deposited on the catalyst surface, which is one of the reasons for catalyst deactivation [26,56].This is strongly related with the reaction conditions and used catalysts.According to literature, carbon is formed during Boudouard reaction and dissociation of hydrocarbons molecules [57].Various forms of carbon can be identified by peak positions in TPO profiles since amorphous carbon is oxidized at low temperature, whereas filamentous carbon undergoes oxidation at higher temperature (>823 K) [58].The recorded TPO profiles are depicted in Figure 9. Based on the position of peak maxima (502-663 K), it can be stated that carbon deposit is in the amorphous state in the case of all catalysts [59].
In TPO profile for Cu/Zr, two separated CO 2 peaks of very small intensity can be visible with the maximum at 502 and 576 K.The amount of calculated carbon deposit is the smallest among spent catalyst and equal to 16.4 C S mg/g.The first peak of CO 2 is accompanied by peak of H 2 O, which is formed during oxidation (maximum at 507 K).The presence of water during oxidation suggests that carbon deposit contains also hydrogen.On the other hand, oxidation of remaining intermediates (C x H y O z ), formed during ESR reaction, cannot be excluded since the temperature of oxidation is low [60].The very low concentration of carbon for Cu/Zr catalyst results from its low activity in ethanol steam reforming.Similarly, water peak is observed for Cu/Zr/Ce catalyst but signal is shifted to higher temperature (557 K) and is of higher intensity in comparison with unmodified catalyst.This is also valid for CO 2 signal with the maximum at 550 K.The increase in temperature of surface carbon oxidation is due to stronger carbon interaction with catalyst surface.The amount of carbon deposit is 79.5 mg C s /g, which is the highest recorded value among spent catalysts.The decrease in concentration of carbon deposit (63.0 mg C s /g) can be stated for Cu/Zr/Ni in comparison with Cu/Zr/Ce.In this case, there is also fraction of carbon that contains hydrogen since the peak of water during oxidation is present (569 K).Further shift of CO 2 peak toward higher temperature is visible in the case of Cu/Zr/Co catalyst.In the TPO profile of this catalyst, there are two separated CO 2 peaks at 579 and 663 K. Based on these two signals, the calculated concentration of surface carbon is equal to 49.1 mg C s /g.Moreover, the absence of H 2 O peaks proves that carbon deposit does not contain hydrogen and there is no oxidation of surface intermediates.For this catalyst, oxidation of carbon, which is formed on the surface during ethanol steam reforming, is hindered since CO 2 peaks emerge at the highest temperature when compared with the rest of spent catalysts.
This can lead to lower hydrogen yield [52].Additionally, similar value of hydrogen yield is observed for Cu/Zr/Co catalyst, having the same average pore diameter as Cu/Zr/Ce catalyst.Mastalir et al. [53] in their investigation on methanol steam reforming found that the changes of copper concentration in Cu/Ce/Zr catalyst resulted in altering the microstructure of the Cu particles.An increase in Cu concentration from 5 to 35 wt%, at a constant ZrO2/CeO2 molar ratio of 1/1, resulted in an increase in crystallite size and consequently a decrease in the specific surface area of the active particles and a significant inhibition of CO production.
The increase in the hydrogen yield for modified catalysts can results from higher surface basicity of these catalysts.This is due to the fact that surface sites of higher basicity catalyze the reaction of ethanol dehydrogenation to acetaldehyde (2) [54,55].
During ethanol steam reforming, different types of carbon are being deposited on the catalyst surface, which is one of the reasons for catalyst deactivation [26,56].This is strongly related with the reaction conditions and used catalysts.According to literature, carbon is formed during Boudouard reaction and dissociation of hydrocarbons molecules [57].Various forms of carbon can be identified by peak positions in TPO profiles since amorphous carbon is oxidized at low temperature,whereas filamentous carbon undergoes oxidation at higher temperature (>823 K) [58].The recorded TPO profiles are depicted in Figure 9. Based on the position of peak maxima (502-663 K), it can be stated that carbon deposit is in the amorphous state in the case of all catalysts [59].In TPO profile for Cu/Zr, two separated CO2 peaks of very small intensity can be visible with the maximum at 502 and 576 K.The amount of calculated carbon deposit is The clear correlation between hydrogen yield and BET surface area or copper dispersion was not found.

Materials
For the synthesis of catalysts, Ni and ZrO(NO 3 ) 2 •H 2 O were purchased from Sigma-Aldrich USA (St. Louis, MO, USA); citric acid monohydrate was purchased from Stanlab Sp.j.Poland; and 65 mass% nitric acid was purchased from Avantor Performance Materials Poland; all the compounds and reagents were of AR grade.To determine the catalyst activity, ethanol of purity spectrophotometric grade, purchased from Merck KGaA was used.

Catalysts Preparation
All precursors of Cu, Zr, Co, Ni, and Ce catalysts-oxides-have been prepared according to the method of thermal decomposition of organic complexes containing metallic components of catalyst [61].Stoichiometric amounts of nitrates of Cu, Zr, Co, Ni, and Ce were carefully added, thoroughly stirred, to the solution of citric acid (concentration of 2 mol/dm 3 +2% excess).Then, the mixture was evaporated in a rotary vacuum evaporator in temperature of 363 K for around 24 h.The precipitate of formed citrates was carefully oxidized to prevent local overheating and explosive course of the oxidation reaction (temperature program: 360 K, 0.1 K/min; 403 K).The formed mixture of oxides was calcined in a muffle with access of air (temperature program: 373, 473, 523, 573, and 623 K during 1 h).
The reason we used this method is perfectly mixed components thanks to the branched structure of citrates and consequentlyexcellent homogeneity and fully repeatable properties of the prepared catalyst [62].The conventional method of co-precipitation did not provide such results, although it is usually used, as it is described in the literature.

Catalysts Characterization
Phase analysis based on the X-ray powder diffraction (XRD) measurements was performed on a X'PERT PRO MDP diffractometer with the X'CELERATOR detector, working in Bragg-Brentano geometry.The XRD measurements (at 40 kV and 30 mA) were performed in the 2θ range from 5 • to 90 • with the interpolated step size 0.02 • .The crystallite sizes were calculated from Scherrer method.The XRD phase analysis was performed using reference standards from the International Centre for Diffraction Data (ICDD) PDF-4 database.
The BET surface area was measured with nitrogen adsorption at 77 K using Quantachrome Autosorb-1.Prior to the measurements, samples were preheated and degassed under vacuum at 373 K for 18 h.The pores size distribution profiles were obtained by Barrett-Joyner-Halenda (BJH) method from a desorption branch.The micropore area was obtained by V-t plot method.
The active surface of copper (S Cu ) in the reduced catalyst was determined with the use of reactive adsorption of N 2 O at 363 K (VG/Fisons Quartz 200D)according to the method described in [63].It has been assumed in calculations that the reoxidation of surface copper follows the chemical equation: 2Cu(s) + N 2 O(g) → Cu 2 O(s) + N 2 (g) and that 1 m 2 of elemental copper corresponds to 6.1 µmol of O 2 .
The H 2 -TPR (temperature-programmed reduction of H 2 ) measurements were performed in ChemBED-3000 (Quantachrome) u-shape quartz flow reactor (diameter ca. 5 mm) at temperature range of 300-1050 K with temperature ramp of 10 K/min and a flow rate of 5% H 2 in Ar.Before the TPR analysis, all samples were kept in a stream of helium at 373 K for 1.5 h to remove physically adsorbed water.
The CO 2 -TPD (CO 2 temperature-programmed desorption) measurements were carried out in quartz fixed-bed flow reactor connected online to mass spectrometer (QMG 220 PRISMA PLUS).Prior to TPD run, sample (50 mg) was reduced in 5% H 2 /Ar flow at 723 K for 1 h.Next, reactor was cooled down to room temperature (RT) and pulses (250 µL) of 5% CO 2 /Ar were introduced until saturation.Then, sample was flashed with He flow (40 mL/min) for 0.5 h until obtaining stable CO 2 line (m/z = 44).TPD was done from RT to 973 K with ∆T = 10 K/min under He flow.
The TPO (temperature-programmed oxidation measurements) of spent catalysts were performed using the same set-up line as for CO 2 -TPD.For typical TPO run, 20 mg of sample was put in the reactor.Next, sample was oxidized in the stream of 5% O 2 /He (30 mL/min) in the temperature range of RT-900 K.The following signals (m/z) were monitored with QMS during TPO: 18 (H 2 O), 32 (O 2 ), and 44 (CO 2 ).The amount of deposited carbon (C s ) was calculated for spent catalysts after time on stream = 50 h.It was assumed that entire carbon undergoes oxidation during TPO according to the following chemical equation: C s + O 2 = CO 2 .The oxidation of fraction of carbon thatcontained hydrogen was not taken into consideration.The calibration of CO 2 mass spectrometer signal was performed by injecting pulses of 5% CO 2 /He with sampling loop of 250 µL.

Catalytic Tests
Catalytic experiments were performed in the continuous flow fixed-bed reactor of 8 cm 3 volume, made of stainless steel.To obtain the active form, the catalyst sample of 2 g was reduced in a stream of diluted hydrogen (7 vol.%H 2 in N 2 ) at temperature of 723 K at atmospheric pressure and stabilized in the mixture of reactants (temperature program: 443 K, 1.5 K/min; 553 K for 4 h).This procedure was repeated until the hydrogen yield was constant.Testing parameters were temperature range dependent on respective catalyst activity of 433-593 K, the reactant flow of 100 mL/min, and ethanol to water initial molar ratio of 1:3 in the stream of pure N 2 .Previously, the feed nitrogen was deoxidized with the BTS deoxidizer and dehydrated with the molecular sieve of 5 Å.The inlet and outlet gases were directed on-line to the gas chromatograph VARIAN STAR 3800.The gaseous products were analyzed in the system of Carbo Plot P7 column (25 m × 0.53 mm) and Supelcowax 10 column (30 m × 0.32 mm).Ethanol was determined quantitatively in the Supelcowax 10 column and FID detector, and the remaining gases were determined in the Carbo Plot P7 column and TCD detector.Additionally, carbon monoxide and methane were determined quantitatively in the methanizer with the sensitivity of 20 ppb.
Activity of tested catalysts was characterized by hydrogen yield, ethanol conversion, and selectivities of carbon monoxide and methane according to formulas given below [64]: where m cat.(g)-catalyst mass, V H 2 (L/h)-volume flow rate of hydrogen, F in i and F out i (mol/h)-molar flow rate of i-th component at input and output (CO, CH 4 ), respectively, and EtOH -ethanol.

Figure 1 .
Figure 1.XRD patterns of tested catalysts after hydrogen reduction.

Figure 3 .
The peaks were observed within the temperature range of 540-583 K.The observed single reduction peak refers solely to the reduction of CuO to Cu 0 .The addition of Ni or Co or Ce oxides to the Cu/Zr catalyst resulted in a 16-40° decrease in the temperature corresponding to the maximum reduction rate (Tmax) indicating that the dopants (Ni, Co and Ce) facilitate the reduction of CuO [47,48].An addition of Co oxide to Cu/Zr catalyst causes decrease in

H 2 -
TPR profiles of investigated catalysts are presented in Figure 3.The peaks were observed within the temperature range of 540-583 K.The observed single reduction peak refers solely to the reduction of CuO to Cu 0 .The addition of Ni or Co or Ce oxides to the Cu/Zr catalyst resulted in a 16-40 • decrease in the temperature corresponding to the maximum reduction rate (T max ) indicating that the dopants (Ni, Co and Ce) facilitate the reduction of CuO

Figure 4 .
Figure 4. CO 2 temperature-programmed desorption(CO 2 -TPD) profiles for (a) Cu/Zr/N, (b) Cu/Zr/Co, (c) Cu/Zr/Ce and (d) Cu/Zr: signal-black line, cumulative curve-red line, deconvoluted peaks used for quantification-green line, temperature-dashed line.(For interpretation of the references to color in this figure legend, the reader is referred to the Web version of this article).
Catalysts 2021, 11, x FOR PEER REVIEW 7 of 15 concentration of basic sites is observed for Cu/Zr (56.2 µmol/g).In the case of this catalyst, the contribution of weak basic sites in total basicity is the highest among synthesized samples (41.3 µmol/g).On the other hand, the modification of Cu/Zr catalysts with dopants leads to increase in total surface basicity in the following order of Cu/Zr/Co<Cu/Zr/Ni<Cu/Zr/Ce.According to literature[49,50] weak basic sites can be related with surface hydroxyl group, medium basic sites with Zr 4+-O 2-pairs, and the strong basic sites with the low-coordination oxygen anions.Additionally, the distribution of basic sites for modified catalysts changes in comparison with Cu/Zr.The decrease in concentration of weak basic sites is visible upon catalyst modification with Co and Ce, whereas concentration of weak basic sites decreases.Moreover, in the case of Cu/Zr/Ce, strong basic sites are generated (16.4 µmol/g).

Figure 5 .
Figure 5.The effect of temperature on ethanol conversion in ethanol steam reforming (ESR) over tested catalysts.

Figure 5 .
Figure 5.The effect of temperature on ethanol conversion in ethanol steam reforming (ESR) over tested catalysts.

Figure 5 .
Figure 5.The effect of temperature on ethanol conversion in ethanol steam reforming (ESR) over tested catalysts.

Figure 6 .
Figure 6.The effect of temperature on H2 yield in ESR over tested catalysts.Figure 6.The effect of temperature on H 2 yield in ESR over tested catalysts.

Figure 6 . 15 Figure 7 .
Figure 6.The effect of temperature on H2 yield in ESR over tested catalysts.Figure 6.The effect of temperature on H 2 yield in ESR over tested catalysts.Catalysts 2021, 11, x FOR PEER REVIEW 8 of 15

Figure 8 .
Figure 8.The effect of temperature on CH4 selectivity in ESR over tested catalysts.

Figure 7 . 15 Figure 7 .
Figure 7.The effect of temperature on CO selectivity in ESR over tested catalysts.

Figure 8 .
Figure 8.The effect of temperature on CH4 selectivity in ESR over tested catalysts.

Figure 8 .
Figure 8.The effect of temperature on CH 4 selectivity in ESR over tested catalysts.

Figure 9 .
Figure 9. TPO profiles for spent catalysts: CO 2 -red line and H 2 O-blue line (signal multiplied by factor of 8).

Table 1 .
Composition, textural properties, and size of crystallites of tested catalysts.Co 3 O 4 , NiO, and CeO; b after hydrogen reduction; c measured by dissociative N 2 O adsorption; d measured by N 2 adsorption at 77 K. a

Table 2 .
Quantitative analysis of basic sites for synthesized catalysts.

Table 3 .
Maximum hydrogen yield at corresponding temperature for tested catalysts.

Table 3 .
Maximum hydrogen yield at corresponding temperature for tested catalysts.

Table 3 .
[51]mum hydrogen yield at corresponding temperature for tested catalysts.Co and Cu/Zr/Ce catalysts revealed similar properties.The hydrogen yield reached similar values, with maximum of about 380 L/(kg cat.•h) at 573 K (Table3).Selectivity towards carbon monoxide was low, with a maximum of 3% at 553 K for Cu/Zr/Co catalyst; very low value, below 0.5% for Cu/Zr/Ce catalyst.Baneshi et al.[51]also confirmed such a good selectivity of the cerium-containing catalyst.Methane was not detected in the course of reaction in the presence of Cu/Zr/Ce catalyst, whereas in the presence of Cu/Zr/Co catalyst, it was 3% at temperature of 553 K.The Cu/Zr/Ni catalyst, which has the highest value of S Cu (13 m 2 /g Cu ), D Cu (2%), and S BET (40 m 2 /g), exhibited the highest yield to hydrogen (490 L/(kg cat.•h).On the other hand, Cu/Zr/Co catalyst, whosephysicochemical properties are close to Cu/Zr/Ni catalyst, yields the lower value of hydrogen (about 300 L/(kg cat.•h), similar to Cu/Zr/Ce (Table1 and Figure