The Impact of Reduction Temperature and Nanoparticles Size on the Catalytic Activity of Cobalt-Containing BEA Zeolite in Fischer–Tropsch Synthesis

: A goal of this work was to investigate the influence of the preparation procedure and activation conditions (reduction temperature and reducing medium: pure hydrogen (100% H 2 ) or hydrogen-argon mixture (5% H 2 -95% Ar)) on the activity of Co-containing BEA zeolites in Fischer– Tropsch synthesis. Therefore, a series of CoBEA zeolites were obtained by a conventional wet impregnation (Co 5.0 AlBEA) and a two-step postsynthesis preparation procedure involving dealumination and impregnation steps (Co 5.0 SiBEA). Both types of zeolites were calcined in air at 500 °C for 3 h and then reduced at 500, 800 and 900 °C for 1 h in 100 % H 2 and in 5% H 2 –95% Ar mixture flow. The obtained Red-C-Co 5.0 AlBEA and Red-C-Co 5.0 SiBEA catalysts with various physicochemical properties were tested in Fischer–Tropsch reaction. Among the studied catalysts, Red-C-Co 5.0 SiBEA reduced at 500 °C in pure hydrogen was the most active, presenting selectivity to liquid products of 91% containing mainly C 7 –C 16 n-alkanes and isoalkanes as well as small amount of olefins, with CO conversion of about 11%. The Red-C-Co 5.0 AlBEA catalysts were not active in the Fischer–Tropsch synthesis. It showed that removal of aluminum from the BEA zeolite in the first step of postsynthesis preparation procedure played a key role in the preparation of efficient catalysts for Fischer–Tropsch synthesis. An increase of the reduction temperature from 500 to 800 and 900 °C resulted in two times lower CO conversion and a drop of the selectivity towards liquid products (up to 62%–88%). The identified main liquid products were n-alkanes and isoalkanes. The higher activity of Red-C-Co 5.0 SiBEA catalysts can be assigned to good dispersion of cobalt nanoparticles and thus a smaller cobalt nanoparticles size than in the case of Red-C-Co 5.0 AlBEA catalyst.


Introduction
Fischer-Tropsch synthesis (FTS), developed in 1923, is an important process of alternative fuel production from H2-CO syngas derived from the conversion of biomass, coal and natural gas. Recently, there has been renewed interest in FTS due to the shrinkage of natural sources of conventional crude oil, as well as stringent environmental legislations concerning the quality of fuel and norms concerning exhaust gases emissions. One of the main aims of industrial and academic researchers has become the development of technology allowing the production of ultra-clean, sulfur-, nitrogen-and aromatic-free liquid fuels with a high octane number.
Among the large number of heterogeneous catalysts studied in FTS, cobalt supported systems are the most potent catalysts known [1]. Cobalt catalysts have shown high activity in the synthesis of long chain hydrocarbons because of their high selectivity to paraffin and low efficiency of water gas shift [2]. Evidence presented in many papers suggests that the size and nature of the Co species are fundamental properties responsible for catalytic activity [3]. Great effort is being made to find correlations between the catalyst's crystallinity, dispersion of Co nanoparticles, preparation methods, and efficiency in FTS.
The iron and cobalt (Fe and Co/SiO2, Fe and Co/Al2O3) catalysts commonly used in FTS lead to the formation of linear hydrocarbons and n-paraffins (waxes) which have a high cetane but low octane number. For this reason, it seems justified to use high-silicon zeolites as catalyst carriers in the FTS process. These materials, due to their properties such as developed specific surfaces and the presence of micro-and meso-pores, can improve the metal dispersion inside the micro-and mesoporous channels and allow the formation of small metal nanoparticles. The well-known catalytic properties of zeolites in the cracking process are responsible for the reduction of the selectivity towards the formation of long chain paraffins. This may cause the increase of the octane number as a result of increasing the selectivity towards the formation of saturated and unsaturated short chain hydrocarbons which can form during processes occurring at acidic zeolite centers, such as the cracking of hydrocarbons containing more than 13 carbon atoms in the molecule, isomerization and aromatization of short chain olefins [4][5][6][7][8].
For several years, the activity of Co and Fe catalysts supported on various porous materials, such as: MCM-41, SBA-15, ZSM-5, ZSM-11, ZSM-12, ZSM-34, zeolite Y, ITQ-6, ITQ-2, β zeolite and mordenite have been studied [4][5][6][7]9,10]. It was noted that the dispersion and average cobalt particle size depended on the pore size of the mesoporous material. Larger metal particles are formed on the surface of the support which was characterized by wider mesopores such as SBA-15. The reduction of this system was easier, and it was characterized by higher activity and lower selectivity to methane than the cobalt catalyst supported on MCM-41, which has a narrower pore size. A similar relation was also observed for a series of Co catalysts supported on commercial amorphous silica, differing only in pore diameter (Co/SiO2). During these studies it was found that the optimal average pore size of the support which can provide the high activity and selectivity to C5+ hydrocarbons is 10 nm. Catalytic systems with similar cobalt content supported on ordinary amorphous silica oxide (SiO2) and SBA-15 material were also compared. It was noted that the Co/SBA-15 catalyst showed much higher activity than the Co/SiO2 and the reason of this phenomenon was the fact that mesoporous crystalline silica SBA-15 ensured better metal dispersion. These reports prompted researchers to attempt to synthesize ITQ layered zeolites, silicalites having an organized structure like a "house of cards", characterized by a large surface area of about 600 m 2 .g −1 and high thermal and hydrothermal stability, which distinguishes them from other mesoporous sieves. These systems were characterized by greater selectivity for C5+ hydrocarbons (to the order of 70%-80%) than Co/SiO2 or Co/MCM-41 systems (approximately 66% and 45% selectivity for Co/SiO2 and Co/MCM-41, respectively). This is most likely due to the higher concentration of active sites, Co nanoparticles [4].
High activity (CO conversion around 77%) and selectivity to higher hydrocarbons (aliphatic hydrocarbons: C5-C9-11.3%, C10-C20-38.2%, n-paraffins-35.6%, isoparaffins-2.1% and olefins-0.5%) were also observed in the case of a catalyst containing 6 wt % of Co in zeolite Y. Such a system was obtained by incorporating metallic cobalt clusters into NaY zeolite channels. The authors stated that the formation of small metallic cobalt particles inside the zeolite channels was the reason for such high activity of the catalyst discussed in the paper [7].
Many scientists studied ZSM zeolites, most often ZSM-5, but also ZSM-11, ZSM-12 and ZSM-34 as supports for preparation of Co-containing zeolite catalysts for the FTS process [4,6,10]. They are all high-silica and strongly acidic, but they differ in pore size which has a great impact on the acidity of the catalysts and thus also on the activity of the Co/ZSM zeolite systems. ZSM-12 has the largest channel sizes with 12-rings, and the average pore size in the range of 5.7-6.1 Å. ZSM-5 and ZSM-11 zeolites are 10-ring, and their average pore sizes are for ZSM-5: 5.3-5.6 and 5.1-5.5 Å, respectively, and for ZSM-11: 5.3-5.4 Å. ZSM-34 is a synthetic zeolite having a complex channel system, containing in the structure 8 rings with 3.6-4.9 Å pore size and 12 rings with approximately 6.7 Å pore size and also a three-dimensional pore system containing 8 rings with 3.6-5.1 Å pore sizes. All these zeolite systems showed high selectivity for higher hydrocarbons (approximately 80%) and selectivity for CH4 of 20%. However, the important differences in CO conversion were observed. Catalyst activity increased according to the following series: Co/ZSM-34 (KCO = 45%) < Co/ZSM-5, Co/ZSM-11 (KCO = 60%) < Co/ZSM -12 (KCO = 79%), proportionally to decreasing the concentration of acid centers in the systems (Co/ZSM-34 > Co/ZSM-5 > Co/ZSM-11 > Co/ZSM-12). The lack of noticeable changes in the selectivity of the studied catalysts for methane and higher hydrocarbons indicates that the increase in the activity of the catalysts can be caused by the increase in the degree of metal dispersion and the formation of small cobalt nanoparticles in larger zeolite channels. The authors have not observed the shape-selective catalysis for these materials. They explain this phenomenon by a significant growth of hydrocarbon chains which occurred on the cobalt nanoparticles on the zeolite surface, and then the initially formed hydrocarbons are transformed into lighter products containing less n-alkanes on available acid centers in zeolite [10].
Previous surveys have reported that BEA zeolites exhibit interesting properties related to the presence of acidic sites, which significantly affect the activity and selectivity in hydrogenation of CO [11]. It is worthy to mention that the structure of BEA zeolite is not well defined. Since zeolite BEA has significant amounts of defects in the crystal lattice and thus shows a subtle structural disorder, it seems easy to modify its physico-chemical properties. It is believed that this disorder of the BEA zeolite structure is the cause of the formation of additional Lewis acidic sites, mostly located inside the zeolite. In contrast, Brønsted acid centers are related to tetrahedrally coordinated aluminum atoms present in the zeolite network both inside and on its outer surface. This internal exchange between Brønsted and Lewis acid centers localized on aluminum atoms in the network is characteristic of the BEA zeolite and distinguishes it from other aluminosilicate materials. It is associated with many structural defects that arise as a result of joining subsequent layers in position (001), where they form left or clockwise [12][13][14]. The nature of Brønsted and Lewis acid centers and the combination of Brønsted-Lewis acid sites, as well as their location (in pores or on the out of surface of crystallites) is still debatable [15]. Due to the presence of so many structural defects in the BEA zeolite network, its dealumination is possible and easy without destroying its crystal structure. It is also possible to reintroduce Al ions into the network, referred to as "realumination" [16][17][18]. Not only the Si/Al ratio can be modified through the dealumination process in zeolite BEA, but also its acidity, and this process could also affect its stability. The zeolite dealumination leads to the creation of a second, new zeolite channel and pore system that gives it new sorption and ion exchange properties [13].
Furthermore, the modification of zeolites by dealumination is a well-known method of enhancing their catalytic performance. The two-step postsynthesis preparation procedure consist of formation of vacant T-sites with associated silanol groups which then react with metal ions leading to creation of framework metal species with well-defined structure of zeolite [19,20]. The application of dealuminated zeolites as supports of cobalt have a strong effect on Co-support interaction, Co particles size and catalytic stability [1].
The physico-chemical properties of BEA zeolite significantly affect its catalytic properties and make it an especially useful catalyst in the petrochemical and refinery industries [14,21]. As this material is characterized by high hydrostability, acidity and hydrophobicity, Beta zeolite is a good catalyst in hydrocarbon cracking reactions, showing high selectivity towards the formation of gasoline and diesel fuels [21].
In this work the novel BEA zeolite catalysts prepared by two-step post-synthesis preparation procedure and conventional wet impregnation were used as catalysts for Fischer-Tropsch synthesis. The main aim was investigation of the role of the dispersion and the size of Co nanoparticles formed in BEA structure on the efficiency of FTS process and their impact on type of liquid products formation. The second important goal of this work was to investigate the correlation between reduction temperature, nanoparticles size and activity of supported Co-zeolite catalysts in FTS.
Another purpose of this study was exploring the differences in physicochemical properties of Red-C-Co5.0HAlBEA and Red-C-Co5.0SiBEA catalysts prepared by conventional wet impregnation and twostep postsynthesis preparation procedure, respectively. The presented studies confirmed the significant impact of the dealumination process on catalytic activity of the obtained Red-C-Co5.0SiBEA catalyst. Total removal of Al atoms from BEA zeolites was proved by reduction of Al + ion signal on TOF-SIMS spectra and disappearance of both Lewis (L) and Brønsted (B) acidic sites.
The dealumination of zeolites had a strong impact on reducibility cobalt BEA catalyst. The presented data documented the influence of reduction temperature in the range of 500-900 °C on Co nanoparticles size, activity, and selectivity in FTS.

The Textural Properties of C-Co5.0SiBEA and C-Co5.0AlBEA Samples
The BET results obtained for C-Co5.0SiBEA and C-Co5.0AlBEA calcined in static air at 500 °C for 3 h are presented in Table 1. The specific surface area (SSA) of SiBEA zeolite (600 m 2 g −1 ) is a slightly higher than SSA of C-Co5.0AlBEA (535 m 2 g −1 ) and C-Co5.0SiBEA (496 m 2 g −1 ). It is related to the preparation methods used for introduction of cobalt ions in BEA zeolite. The slight drop of SSA for C-Co5.0SiBEA and C-Co5.0AlBEA can be caused by blocking of part of pores and channels of BEA zeolites by formed cobalt oxides. The pore volume (PV) of calcined C-Co5.0SiBEA and C-Co5.0AlBEA zeolites is like that noticed for BEA zeolite, respectively, 0.21 cm 3 g −1 and 0.22 cm 3 g −1 .

Prove of Co Incorporation in the HAlBEA and SiBEA Zeolite Structure
It is well known [22] that a diffraction peak close to 22-23° could be applied to determine the contraction/expansion of the structure of BEA zeolite. The d302 spacing corresponding to the peak with 2θ of 22.57° (AlBEA) decreases with dealumination and the peak with 2θ of 22.61° (SiBEA) appears ( Figure 1). This prove some contraction of the zeolite BEA matrix because of dealumination. After introduction of cobalt into HAlBEA and SiBEA, the narrow diffraction peak appears at lower 2θ of 22.46° for C-Co5.0AlBEA and of 22.56° for C-Co5.0SiBEA. This indicates expansion of the zeolite BEA structure and proves that part of Co ions is incorporated in the framework of BEA zeolite as tetrahedral Co(II) species, in line with earlier report [23,24]. The much smaller diffraction peak occurred at around 22.46−22.56° for C-Co5.0AlBEA and C-Co5.0SiBEA than for HAlBEA and SiBEA is probably related with formation of Co3O4 in extra-framework position of these zeolites, as confirmed by the diffraction line at 2θ = 36.7° characteristic of Co3O4. It is worth to mention that the absence of more than one diffraction lines characteristic for cobalt oxides could be related to good dispersion of Co(II) species in both zeolites or may be assigned to small nanoparticles size of cobalt oxides, what can cause the limit of their detection [20].

The Reducibility of Co Present in C-Co5.0SiBEA and C-Co5.0AlBEA
The TPR-H2 curves of C-Co5.0AlBEA and C-Co5.0SiBEA presented in Figure 2, show a multistage process of reduction of cobalt for both samples.
The TPR profile of C-Co5.0AlBEA ( Figure 2) shows three reduction peaks. Two of them with a maximum at 170 and 320 °C can be related to two-stage reduction of Co3O4 to metallic cobalt Co(0) (Co3O4 → CoO → Co(0)) whereas the third peak at a much higher temperature (720 °C) is probably related to the reduction of Co(II) species present in ion exchange position and/or to reduction of cobalt alumina-silicate. The similar results were obtained by Xiao for 5% Co/H-ZSM-5 system [25]. . TPR-H2 profiles of C-Co5.0AlBEA and C-Co5.0SiBEA performed in the temperature between 25 and 900 °C showing that C-Co5.0SiBEA is hardly reduced than C-Co5.0AlBEA.
The reduction profile of C-Co5.0SiBEA catalyst presents one peak at 240 °C with shoulder at about 320 °C ( Figure 2). They are attributed to reduction of Co3O4 to metallic Co (0). Third reduction peak at 460 °C could be assigned to reduction of cobalt present as surface silicates (Co2SiO4), that presence was proved by ToF-SIMS results. The fourth reduction peak at 740 °C for C-Co5.0SiBEA probably corresponds to reduction of framework tetrahedral Co(II), in agreement with our previous report [1].
Comparison of the reduction profile of C-Co5.0SiBEA and C-Co5.0AlBEA in Figure 2 allow to suggest that C-Co5.0SiBEA is hardly reduced than C-Co5.0AlBEA. It could correspond to the presence of a larger amount of Co atoms in the framework position of C-Co5.0SiBEA than in C-Co5.0AlBEA. The Co present in the framework of the BEA zeolite is much more strongly interacted with the zeolite structure than that present in the extra-framework position, and this is the reason for the harder reducibility of this Co species.
To get a better insight into the nature of cobalt present in C-Co5.0SiBEA and C-Co5.0AlBEA, a time-of-flight secondary ion mass spectrometry (ToF-SIMS) analysis was performed. The results are presented in Table 2 and Figures 3 and 4.
An analysis of ToF-SIMS spectra obtained for C-Co5.0AlBEA shows the presence of SiOAl + , CoAlO2H + and CoAl2O4H + ions indicating the formation of aluminates and aluminosilicates of cobalt. In the case of C-Co5.0SiBEA the signals attributed to CoAlO2H + and CoAl2O4H + were not observed. Further analysis demonstrates also a much lower intensity of Al + signal in the case of C-Co5.0SiBEA than for C-Co5.0AlBEA. A decrease in the intensity of Al + signal, as well as the tremendous drop in the intensity ratio Al + /Si + (Table 2 and Figure 3) clearly confirmed that dealumination process occurring in the first step of preparation of C-Co5.0SiBEA was successful.  Secondary ion mass spectra of the analyzed catalysts exhibit the presence of signals originating from CoSiO + , CoSiOH + and CoSiO2H + ions. It confirms the presence of Co-silicates in the case of both C-Co5.0SiBEA and C-Co5.0AlBEA materials and the incorporation of Co into the zeolite framework (Table 2 and Figure 4).

The Cobalt Nanoparticles Distribution in Red-C-Co5.0SiBEA after Reduction in Different Conditions
The cobalt nanoparticles distributions in Red-C-Co5.0SiBEA reduced at 800 and 900 °C in 100% H2 and 5% H2-95% Ar mixture were investigated by TEM and results of studies are presented in Figure 5.
The average nanoparticles size of cobalt in Red-C-Co5.0SiBEA catalyst reduced at 800 °C in 5% H2-95% Ar mixture ( Figure 5a) and 100% H2 (Figure 5b) is 10.6 and 7.2 nm, respectively. The increase of reduction temperature up to 900 °C has no influence on size of Co nanoparticles, which is 10.2 and 6.6 nm respectively (Figure 5c,d). It indicates that reduction in pure hydrogen leads to formation of cobalt nanoparticles with smaller size than reduction in 5% H2-95% Ar mixture. It may indicate that cobalt nanoparticles are well dispersed in zeolite matrix and cobalt nanoparticles size do not change with increasing of reduction temperature from 800 to 900 °C. It means that the temperature of the reduction is not so important but that the key factor affecting Co size in the studied catalysts is the reducing medium. It seems that, for the reduction and obtaining of smaller cobalt nanoparticles size, the use of pure hydrogen is more proper, and it shows that the size of cobalt nanoparticles in Red-C-Co5.0SiBEA does not change after reduction in higher temperature ( Figure 5).
Red-C-Co5.0AlBEA and Red-C-Co5.0SiBEA catalysts after reduction in 100% H2 at 500 °C for 1 h show the TPD-NH3 patterns, that could be fitted by two peaks at 210 and 520 °C for Red-C-Co5.0AlBEA and at 210 and 470 °C for Red-C-Co5.0SiBEA. These peaks could be attributed to desorption of NH3 from weak and strong acidic sites, respectively [1,26,27].

Sample
Amount of NH3 Adsorbed (μmol g −1 ) C-Co5.0AlBEA 3000 Red-C-Co5.0AlBEA 32 C-Co5.0SiBEA 1740 Red-C-Co5.0SiBEA In order to check acidity of HAlBEA, SiBEA, C-Co5.0AlBEA and C-Co5.0SiBEA FTIR spectra of pyridine adsorbed on these materials were analyzed (Table 4, Figure 7). One can observe the high amount of B and L acidic sites on HAlBEA. The incorporation of cobalt into HAlBEA leads to formation of Co5.0AlBEA with higher amount of acidic sites than for HAlBEA, as shown by appearance of very intense bands at 1451 and 1611 cm −1 and with lower amount of B acidic sites shown by lower intensity of the bands at 1546 and 1637 cm −1 (Table 4 and Figure 7).  In SiBEA there is no B and L acidic sites (Table 4). It suggests that the Al removal from BEA zeolite under dealumination process is almost complete what, in consequence, leads to the disappearance of both B and L acidic sites. The introduction of cobalt into the siliceous SiBEA leads to formation of L acidic sites proved by the bands at 1451, 1492 and 1611 cm −1 [20].

The Catalytic Activity of Red-C-Co5.0AlBEA and Red-C-Co5.0SiBEA
The FTS was performed on Red-C-Co5.0SiBEA and Red-C-Co5.0AlBEA catalysts. The influence of the reduction temperature on the activity of these catalysts is presented in Table 5. Conversion of CO and selectivity to liquid products, CH4 and CO2 were analyzed. The Red-C-Co5.0SiBEA catalyst appears to be the most active and most selective to liquid products (hydrocarbons C5+) , obtained by two-step postsynthesis preparation procedure. The Red-C-Co5.0SiBEA catalyst, reduced at 500 °C, is very selective in production of liquid hydrocarbons with 91% selectivity for the CO conversion of 11%, whereas the Red-C-Co5.0AlBEA reduced under the same conditions was not active in CO conversion. Moreover, it was observed that the higher reduction temperature (800 and 900 °C), when all Co species in the Red-C-Co5.0SiBEA sample are reduced to metallic cobalt, does not improve its activity. It was found that for the sample reduced at 800 °C in pure hydrogen (100% H2) the conversion of CO and the selectivity to liquid products were much lower than for Red-C-Co5.0SiBEA reduced at 500 °C, at 3% and 67%, respectively. The selectivity towards methane was three times higher and it was 33%. Further increasing of the reduction temperature (up to 900 °C) causes also decline in activity and selectivity of Red-C-Co5.0SiBEA. However, in this case the impact of reduction mixture was noticed. It was observed that reduction at 800 and 900 °C in 5% H2-95% Ar mixture flow led to high selectivity towards liquid products (89 and 88% respectively) but CO conversion was more than two times lower than in the case Red-C-Co5.0SiBEA sample reduced at 500 °C. Table 5. The catalytic activity and selectivity, the isoalkanes and olefins to n-alkanes ratio and nanoparticles size for Red-C-Co5.0AlBEA and Red-C-Co5.0SiBEA. The higher activity of Red-C-Co5.0SiBEA reduced at 500 °C than at 800 and 900 °C seems to be related to its smaller cobalt nanoparticles size. The average particles size for Red-C-Co5.0SiBEA reduced in 100% H2 at 500, 800 and 900 °C is 6.3, 7.2 and 6.6 nm, respectively. The same catalyst reduced in 5% H2-95% Ar mixture at 800-900 °C shows slightly bigger Co nanoparticles (about 10-11 nm). The obtained results proved that the important factor, which impacts cobalt nanoparticles size, is the dealumination process. The catalyst dealuminated and activated in various conditions (Red-C-Co5.0SiBEA) show Co nanoparticles of about 6-10 nm, whereas the catalyst prepared without dealumination (Red-C-Co5.0AlBEA) show large Co nanoparticles of about 27 nm. This suggests that the optimal nanoparticles size of metallic cobalt in catalysts, which ensures high activity and selectivity towards liquid products in FTS, is 6-10 nm. The larger Co nanoparticles size is not required, since the dispersion of metallic cobalt will be lower and will cause lower hydrogen uptake [29]. The similar phenomenon was observed for Co/ITQ [4], Co/Y [7] and Co/ZSM-5; ZSM-11; ZSM-12; ZSM-34 zeolites [10].

Red-C-
The liquid products were analyzed by GC-MS technique and the results are shown in Figures  8-11. The quantitative analysis is presented in Table 5. It was found that the liquid fraction in FTS catalyzed by Co supported zeolites varies depending on the activation conditions of the catalyst. In the case of FTS carried out on the Red-C-Co5.0SiBEA sample reduced at 500 °C, both saturated (alkanes, isolkanes) and unsaturated (olefins) hydrocarbons (C7-C16) were identified (Figure 8). The ratio of isoalkanes/n-alkanes is 0.25 and the ratio of olefins/n-alkanes is 0.03. The catalyst, reduced at 800 °C in a pure hydrogen flow, produced only isoalkanes (C10-C25) and saturated nalkanes with a ratio 0.39, while with an increase of reduction temperature up to 900 °C, the mentioned ratio raised to 0.95 (Figures 9 and 10).  The products obtained on Red-C-Co5.0SiBEA reduced at 900 °C in 5% hydrogen consisting of liquid products C11-C18 are identified mainly as isoalkanes and n-alkanes with the ratio of 0.47 ( Figure 11). It seems that the reduction temperature and reducing medium have significant impact on the liquid products formation. The increase of reduction temperature from 500 to 900 °C for C-Co5.0SiBEA leads to isoalkanes and alkanes formation, with the carbon number in the chain from 10 to 25 of C. Moreover, the activation of C-Co5.0SiBEA catalysts at 900 °C in a mixture of 5% H2-95% Ar for 1 h causes the increase of CO conversion up to 4.88%, selectivity towards liquid hydrocarbons (mainly isoalkanes and n-alkanes with 11 to 18 carbon number in chains) up to 87.64% and decrease of selectivity towards CH4 to 12.27%. This fact indicates that reduction at the highest temperature can improve the activity and mainly selectivity of cobalt BEA zeolite catalysts, despite the creation of the larger size of cobalt nanoparticles. However, the highest activity and selectivity have been obtained on Red-C-Co5.0SiBEA activated at 500 °C in pure hydrogen. It is probably related to the limited reduction of cobalt and presence of cobalt species in the zeolite framework, which can be responsible for shorter chains of hydrocarbons and olefins formation while longer chains of n-alkanes are formed on metallic cobalt nanoparticles. It is likely that isoalkanes are formed on acidic sites present in Red-C-Co5.0SiBEA, reduced at 500 °C. For this reason, the Red-C-Co5.0SiBEA reduced at 500 °C in pure hydrogen may be considered as bifunctional catalyst. It is also worthy to mention that an increase of temperature activation causes an increase of isoalkanes formation, and the same in the growing of the isoalkanes to n-alkanes ratio.
In the review of Zhnag et al. [30], the authors have mentioned that selectivity of cobalt zeolites catalysts depends on Si/Al ratio, acidity of the supports and porous size of support. Too small (narrower than 3 nm) pores of supports are responsible for lower CO conversion and higher selectivity towards CH4. Authors concluded that acidity of the supports is the key factor in liquid hydrocarbons distribution, because if the primary liquid products formed possess access to acidic centers in zeolite they can be transformed into lighter hydrocarbons and iso-paraffins. They discussed the studies of Bessell [10], which reported that the most strongly acidic Co-ZSM-5 catalyst allowed to achieve the highest selectivity to gasoline-range hydrocarbons and the largest fraction of branched products. In the same work, it was also proved that the application of ZSM-12 in FTS, which possesses the largest pore channels (0.57-0.61 nm) but weaker acidity, led to formation of the highest fraction of gasoline in liquid hydrocarbons and the lowest fraction of n-paraffins. It seems that the formed primary hydrocarbons are cracked and isomerized into lighter hydrocarbons with more iso-paraffins in a secondary reaction occurred at the accessible zeolite acid sites [30].
We believe that we can modify and control FTS process and liquid hydrocarbon distribution by the changing of activation conditions and in this way the different kind of fuel can be obtained. Red-C-Co5.0SiBEA catalyst, considered in this work, depending on activation conditions can catalyze and allow the obtainment of gasoline (hydrocarbons from C5-C12, mainly n-alkanes and traces of unsaturated alkanes and aromatic hydrocarbons). When this catalyst is reduced at lower temperature, it allows to produce diesel fuel (n-alkanes, cycloalkanes, aromatic hydrocarbons). However, when it is reduced at higher temperatures, it allows to produce jet-fuel (aviation fuel; cycloalkanes, isoalkanes, aromatic hydrocarbons). It is very likely that the presence of the mainly Lewis acidic sites-and the high accessibility to the internal newly-created acidic centers of Red-C-Co5.0SiBEA zeolite-are some of the key factors in the various kinds of liquid products formation.
In other work, the activity of cobalt supported on alumina modified meso-macroporous high silica (HS) in FTS was studied [31]. This type of cobalt catalysts achieved higher CO conversion but also higher selectivity towards methane (undesired product of FTS) and also lower selectivity towards paraffins in comparison to the catalyst described in this work. The authors explained this phenomenon by the lack of acidic sites [31]. In the case of our catalyst we have observed formation of isoalkanes with long carbon chain (even to 25 carbon atom number in chain, depending on activation conditions) and the selectivity towards desired liquid hydrocarbons was remarkably high. Moreover, in the same work it was found that prepared cobalt supported on hierarchical micro-mesomacroporous Beta zeolite possessing wealth of acidic sites achieved CO conversion of 41% (higher in comparison to Red-C-Co5.0SiBEA) and selectivity towards liquid hydrocarbons of 68.27%, so lower than that obtained on Red-C-Co5.0SiBEA reduced at 500 °C of 91%. The authors explained the high selectivity towards isoalkanes and olefins by the presence of acidic sites. In their opinion the longchain hydrocarbons are formed on the surface of metallic cobalt and their further transformation to isoalkanes takes place on acidic sites present close to cobalt. Moreover the author noted that the isomerization reaction can take place on Brønsted acid sites or results from the synergistic effect of working on both the Brønsted and Lewis acid sites [31]. We believe that in the case of Red-C-Co5.0SiBEA the cobalt localized in the zeolite framework created mainly the Lewis acid sites, which may be responsible for hydrocracking, aromatization and isomarization reactions. It is also wellknown that the growth of hydrocarbons chains can occur on metallic cobalt nanoparticles, and after the primary formed hydrocarbons are transformed into lighter products on acidic sites present in the supports [30,31]. As mentioned above, the accessibilty to internal acidic sites is key factor in isoalkanes formation. In the case of Red-C-Co5.0SiBEA, the lower CO conversion could be a result of the small insufficient amount of cobalt nanoparticles located in the external space of the zeolite. However, the incorporation of the cobalt species into the zeolite framework can improve the selectivity towards liquid hydrocarbons of Red-C-Co5.0SiBEA, and these species may be responsible for the higher amount of isoalkanes and olefins formation.
Tetraethylammonium BEA (TEABEA) zeolite was applied as parent zeolite. In the first, one part of TEABEA zeolite was calcined in air at 550 °C for 15 h in order to obtain an HAlBEA zeolite with Si/Al ratio of 12.5. The Co5.0AlBEA zeolites were obtained by impregnation of HAlBEA with Co(NO3)2 6 H2O solution (Sigma-Aldrich, St. Louis, MO, USA) at pH of 2.6 in aerobic conditions [19,20]. Then, during 2 h the suspensions were stirred at 80 °C until evaporation of water. The obtained solids were dried in air (80 °C, 24 h) and then calcined in air (500 °C, 3 h) and labelled C-Co5.0AlBEA.
The second portion of the TEABEA was treated in a nitric acid aqueous solution (13 mol . L −1 , 4 h, 80 °C) to obtain a silicious SiBEA with Si/Al ratio of 1000 with vacant T-sites. The silicious SiBEA was separated by centrifugation, then washed with water and finally dried over 24 h at 80 °C. To introduce cobalt cations into the framework of SiBEA, 2 g of SiBEA was stirred in aerobic conditions (25 °C, 24 h) in 200 mL of Co(NO3)2 6H2O solution at pH of 2.4-2.6 [19,20]. Then, the suspension was stirred (2 h, 80 °C) up to evaporate water. The obtained solid was dried in air (24 h, 80 °C) and labelled as Co5.0SiBEA. Then, the solid was calcined in air (3 h, 500 °C) and labelled C-Co5.0SiBEA. C-Co5.0SiBEA and C-Co5.0AlBEA were reduced in situ under atmospheric pressure in flow of 100% H2 or 95% H2-5% Ar at 500, 800 or 900 °C for 1 h. The obtained catalysts were labelled as Red-C-Co5.0SiBEA and Red-C-Co5.0AlBEA.

Samples Characterization
From the point of view of catalytic activity, an important property of catalysts is the size of the specific surface and porosity. These two features of the catalyst affect not only its activity and selectivity but also, they have impact on heat and mass transport as well as resistance to cocking phenomenon. The specific surface area and pore size of the tested catalysts were determined by the method of low temperature nitrogen adsorption (BET). The SSA and PV of catalysts and their supports were measured with automatic sorptometer Micromeritics ASAP 2020 V3.05 G (surface area and porosity analyzer). The solids were prepared at 300 °C upon evacuation during 2 h and the low temperature N2 adsorption-desorption measurements were performed.
The cobalt content in the obtained samples as well as the Si/Al ratio were determined at room temperature by X-ray fluorescence (XRF) (SPECTRO X-LabPro, Kleve, Germany). X-ray fluorescence spectroscopy (XRF-X-ray fluorescence spectroscopy) belongs to the non-destructive analytical methods and is one of the most used techniques in determining the elemental composition of analyzed substances. By simultaneously measuring the fluorescence of each element, the XRF analyzer allows to accurate measure of the composition of the material and to define the concentration of each element. This method was used to determining of the elemental composition of prepared samples, very quickly and very accurately. As prepared Co5.0AlBEA and Co5.0SiBEA samples were analyzed without high temperature heat treatment.
The XRD study was performed on a PANalytical X'Pert Pro diffractometer (Malvern Panalytical Ltd., Malvern, United Kingdom) using Cu Kα radiation (λ = 154.05 pm) in 2θ range of 5-90°. The most common use of X-ray diffraction (XRD) is the analysis of the phase composition of catalytic systems. This analysis is based on the Bragg equation which allows to determine the distance of lattice planes "d" in the crystal. These distances are characteristic of a given crystalline substance. The analysis of the obtained data was performed using the X'Pert HighScore Plus software and was interpreted based on the 2 theta angle values determined using the JCPDS (Joint Committee on Power Diffraction Standards) tables.
In the temperature-programmed methods, a sample is in a controlled atmosphere (inert, oxidizing or reducing) and it is given to a linearly programmed temperature rise. In this way, various reactions occurring on the sample surface can be observed, e.g., adsorption processes-desorption or susceptibility to reduction of metal oxide phases present in the catalytic system. In the temperatureprogrammed reduction technique, the reducing gas (hydrogen, carbon monoxide) flows through the sample, and the reduction rate is recorded as a change in the reducing gas content or by analyzing the reduction product at the reactor outlet by gas chromatography or mass spectrometry. TPR profiles show the successive stages of reduction of oxide phases and allow to obtain information about interactions between the carrier and the active phase. The TPR-H2 patterns were obtained on an automatic TPR system (AMI-1) in the temperature range between 25 and 900 °C, using (5% H2-95% Ar flow of 40 mL . min −1 (Air Products Ltd., Poland). Thermal conductivity detector (TCD) allows monitoring H2 consumption (Altamira Instruments, Pittsburgh, USA).
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is used to characterize solid surfaces and allows for determination of their composition. In this work, the ToF-SIMS technique was applied to the analysis of the surface of the obtained cobalt zeolite catalysts to confirm the presence of silicates and aluminosilicates The ToF-SIMS experiments were conducted using an ION-TOF GmbH instrument (TOF-SIMS IV) equipped with 25 kV pulsed Bi3 + primary ion gun in the static mode (primary ion dose about 3 × 10 10 ion cm −2 ). The analyzed area corresponds to a square of 500 × 500 µm. For each sample, three spectra were collected. Before each experiment the samples were pressed into pellets and attached to the sample holder using a double-sided tape. For charge compensation, a pulsed electron flood gun was used.
After TPR experiment, the crystal morphology, and the size of particles of Red-C-Co5.0AlBEA and Red-C-Co5.0SiBEA samples were identified by TEM (JEOL JEM 2100 FEG microscope, Tokyo, Japan). In this work, the TEM technique was used for observation of the degree of ordering of the catalyst structure and its defect and determining the size of metal nanoparticles.
A tungsten gun and 100 kV voltage were used in the tests. Measurements were made for carriers and selected samples of cobalt systems after reduction.
The technique of temperature-programmed desorption is one of the oldest and the most used temperature programmed methods. Ammonia, pyridine or quinoline is used to determine the acidity of zeolites. Based on the detected TPD profiles of molecules-probes, the determination of the number of acid centers and calculating of their relative power is possible. In this work, temperature programmed ammonia desorption (TPD-NH3) using the flow method was used to determine the acidity of the tested catalytic systems. TPD detection was carried out using a TCD thermal conductivity detector (Altamira Instruments, Pittsburgh, USA). The TPD-NH3 were done in a quartz reactor using gaseous ammoniac. NH3 was adsorbed on zeolite catalysts, dried at 500 °C in He flow for 30 min at 100 °C for 10 min in flowing He. The TPD of NH3 was carried out in the temperature range 25-500 °C, after removing physisorbed ammonium from the catalyst.
In FTIR spectroscopy, energy changes occur at transitions between quantized levels of oscillatory and rotational energy of groups of atoms in the area of wavenumbers of 4000-400 cm −1 which occur while the vibration of atoms in the molecule is accompanied by a change in dipole moment. In heterogeneous catalyst studies, IR spectroscopy is used to identify the surface groups present in the catalyst and also for determination of the structure of the molecules adsorbed on the surface, which makes it possible to determine, for example, the acidity of the catalysts and to distinguish between Brønsted and Lewis acid centers. The advantage of the method is the possibility of conducting measurements in a controlled atmosphere and temperature. It is a very convenient technique for studying the distribution of acid centers. In this work, FTIR spectroscopy was used to study the acidity of the obtained systems in which pyridine was used as the probe. The FTIR spectra were measured on Bruker Vector 22 spectrometer containing DTGS detector with resolution of 2.0 cm −1 . For each FTIR spectra, 128 scans have been performed. The solids were pressed at ~0.2 tons cm −2 into thin wafers of ca. 10 mg cm −2 . Then the wafers were placed inside the IR cell. The wafers were calcined at 450 °C for 3 h in O2 (16 kPa) and then outgassed at 300 °C (10 −3 Pa) for 1 h. The wafers were contacted at room temperature with gaseous pyridine (133 Pa) via a separate cell contacting liquid pyridine. After saturation with pyridine, the samples were outgassed at 150 °C (10 −3 Pa). FTIR spectra were recorded at room temperature in the range of 4000−400 cm −1 .

Catalytic Tests
The FTS tests were performed in a fixed bed reactor. A mixture of H2 and CO with molar ratio of 2/1 and flow of reagents of 60 mL min −1 were used. The FTS tests were performed at 260 °C (under 30 atm) and gaseous reagents were analyzed by GC gas chromatograph (Shimadzu GC-14; Shimadzu Corporation, Duisburg, Germany) ) with TCD detector. Two columns were applied, one measuring Carbosphere 7A and the second the comparative molecular sieves 7B. GC measurements were realized in the following conditions: column's temperature −45 °C, detector's temperature −120 °C, detector's current-100 mA; carried gas-He. The zeolite catalysts were reduced in situ in atmospheric pressure in a flow of 100% H2 or 95% H2-5% Ar gas mixture at 500 °C for 1 h. Th GC-MS coupled technique was used for analyzing the liquid products. A gas chromatograph (6890N Network GC) equipped with a capillary column HP-5MS (Agilent Technology) was coupled with a quadrupole mass spectrometer (5973 Network Mass Selective Detector). The liquid products were concentrated by SPE method on octadecyl columns C18. Each of the columns was preconditioned with 2 mL of nhexane before extraction. Then, liquid products were injected on the column and it was washed with 2 mL of n-hexane. GC-MS analysis was performed in helium flow (0.7 mL min −1 ) in a temperature between 60 and 280 °C with increase linear temperature of 10 °C min −1 . The volume of the analyzed sample was 1 mm 3 .
The C2-C6 hydrocarbons were not determined in GC analysis. The selectivity to liquid products were obtained from following equation: SLP = 100 − (SCH4 + SCO2)

Conclusions
The Red-C-Co5.0AlBEA and Red-C-Co5.0SiBEA catalyst systems obtained in this work by two different preparation procedures with various physicochemical properties were tested in Fischer-Tropsch reaction. Among the studied catalysts the most active catalyst was Red-C-Co5.0SiBEA reduced at 500 °C in pure hydrogen, which presented selectivity to liquid products of 91% containing mainly C7-C16 n-alkanes and isoalkanes as well as a small amount of olefins with CO conversion of about 11%. The Red-C-Co5.0AlBEA catalysts were not active in the Fischer-Tropsch synthesis.
It showed that removal of aluminum from BEA zeolite in the first step of postsynthesis preparation procedure played a key role in the preparation of an efficient catalyst for FTS, as it allows the incorporation of Co ions in the framework of siliceous SiBEA as tetrahedral Co(II) strongly bonded to the C-Co5.0SiBEA structure, and then upon reduction in pure hydrogen or in hydrogenargon mixture (5% H2-95% Ar) the obtainment of cobalt nanoparticles of small size and well dispersed in the zeolite structure.
It was shown that the increase of the reduction temperature from 500 °C to 800 °C and then to 900 °C caused two times lower CO conversion and drop of the selectivity towards liquid products (up to 62%-88%) for the Red-C-Co5.0SiBEA catalyst.
The n-alkanes and isoalkanes were the main liquid products identified in FTS on Red-C-Co5.0SiBEA catalyst.