The VIIRS-Based RST-FLARE Conﬁguration: The Val d’Agri Oil Center Gas Flaring Investigation in Between 2015–2019

: The RST (Robust Satellite Techniques)-FLARE algorithm is a satellite-based method using a multitemporal statistical analysis of nighttime infrared signals strictly related to industrial hotspots, such as gas ﬂares. The algorithm was designed for both identifying and characterizing gas ﬂares in terms of radiant / emissive power. The Val d’Agri Oil Center (COVA) is a gas and oil pre-treatment plant operating for about two decades within an anthropized area of Basilicata region (southern Italy) where it represents a signiﬁcant potential source of social and environmental impacts. RST-FLARE, developed to study and monitor the gas ﬂaring activity of this site by means of MODIS (Moderate Resolution Imaging Spectroradiometer) data, has exported VIIRS (Visible Infrared Imaging Radiometer Suite) records by exploiting the improved spatial and spectral properties o ﬀ ered by this sensor. In this paper, the VIIRS-based conﬁguration of RST-FLARE is presented and its application on the recent (2015-2019) gas ﬂaring activity at COVA is analyzed and discussed. Its performance in gas ﬂaring characterization is in good agreement with VIIRS Nightﬁre outputs to which RST-FLARE seems to provide some add-ons. The great consistency of radiant heat estimates computed with both RST-FLARE developed conﬁgurations allows proposing a multi-sensor RST-FLARE strategy for a more accurate multi-year analysis of gas ﬂaring.


Introduction
The process of production of crude oil and natural gas necessarily requires the implementation of the gas flaring (GF) activity at the oil treatment plant, which is a routine practice either exploited as a means of disposal or as a safety measure to relieve pressure through the combustion of the associated gas generated during various industrial operations [1,2].
The environmental, social, and economic consequences associated with GF are clear since the 1990s [3][4][5] when regulations to measure flare gas for calculation of carbon dioxide (CO 2 ) tax in the petroleum activities were implemented in Norway [1]. GF is a 160-year-old industry practice [6] that contributes significantly to climate change by harming the environment through nearly 300 million tons of CO 2 equivalent emissions every year [7][8][9] and represents a considerable waste of a valuable non-renewable energy resource [6]. Nonetheless, the practice continues to this day for a variety of technical, regulatory, and/or economic constraints and, in some geographic areas, it records a growth because of the increased shale oil production (e.g., the United States) or political unrest and conflict (i.e., Venezuela) [6]. products [13,20] considering a temporal period from 2015 to 2019. Then, the VIIRS-based RST-FLARE configuration aimed at computing the radiant heat (in MW) of COVA, by a linear equation using the radiance excess to quantify the emission power of the source, is presented. The VNF (VIIRS Nightfire) outputs [13] were also used to develop the model. The methodology is described in Section 4.4 and results are shown in Section 5.
These outcomes may be used, coupled with MODIS ones, to monitor the COVA GF activity and, in a further step, to infer GF emissions (e.g., CO 2 , CH 4 ). In this way, the radiance excess can be seen as an air quality proxy around the COVA area.

The Region of Interest
Basilicata region hosts the biggest onshore oil reservoir in Western Europe, which supplies over 10% of the Italian oil requirement. The oil is extracted from 24 wells that are currently in production in the Val d'Agri Concession (ENI 61%, Shell 39%), and then piped to the COVA in Viggiano (Figure 1) for its first treatment and sent through a pipeline to the Taranto refinery [46]. Currently, the COVA is the main onshore oil source in Italy (producing 77% of the national amount) by also supplying about half of the total gas production [47,48]. The Italian Ministry of Economic Development provides data on oil (in kg) and gas (in standard cubic meters, Sm 3 ) production for the Val d'Agri Concession from 2004 to 2019 [48]. According to the last update of 23 November 2019, in the latest 15 years, the COVA produced a total of 55.00 million tons of oil and 17.43 billion Sm 3 of associated gas (average annual value of 3.67 million tons and 1.16 billion Sm 3 , respectively) [48]. The COVA is the region of interest (ROI) in this study, namely the area within the yellow box shown in Figure 1, which makes it interesting for at least two main reasons.
First, it is located in an urbanized area, where inhabitants have been always worried about the plant potential impact on the health and ecosystem. Second, although it is inside an area of 100 km 2 , with a dense environmental monitoring network (8 monitoring points/km 2 ) [49], continuous information on the level of GF emissions released by this site (e.g., mass of GHGs, both CO 2 and CH 4 , emissions as well as volumes of gas flared) are missing. The last "ground-truth" estimates about COVA GF provided by ENI date back to 2014 for both the volumes of gas sent to flaring (decreasing from 19.28 MSm 3 in 2009 to 6.60 in 2014) and the CO 2 emissions from the treatment process and combustion activities (very stable around a mean value of 460 Mtons/year) [49][50][51]. Data on CO 2 emissions by gas flaring are limited to 2009-2011, when they represent less than 25% of the total [50]. This issue has pushed the local scientific community to bridge this gap by using satellite observing systems.
As anticipated in the introduction, the first satellite-based analysis of the COVA has been carried out by Reference [32] using MODIS data at 1 km of spatial resolution. In this paper, VIIRS data, with an improved spatial footprint of 750 m, have been exploited. The whole plant, whose size is 181.850 m 2 [47], spans more than two VIIRS 750 m pixels (Figure 1), with the gas flare system covering an area of 800m 2 . Such an area can be considered as a sub-pixel hot source, where the gas flaring phenomenon is managed through high level technologies allowing us to recover (and re-use for industrial and civil purposes) that most of the gas is carried out by the oil treatment [49]. In normal conditions, the torch burns a minimum amount of natural gas (soft gas), which feeds an almost invisible pilot flame. The volumes of gas flared by COVA are negligible when compared to most of worldwide upstream sites. For example, according to VNF estimates, in 2018, COVA flared 0.000907 BCM, while a Nigerian and Algerian upstream plant burned-off amounts 40-50 times greater (0.0037 and 0.044 BCM, mean value computed over the VNF detected sites, https://viirs.skytruth.org/apps/heatmap/flarevolume.html#).

Satellite Data
Nighttime data acquired over COVA in the temporal range 1 January 2015 -30 September 2019 by VIIRS sensors aboard Suomi-NPP (since October 2012) and JPSS-1 (since November 2017) satellites were collected and processed. The dataset includes images downloaded from the NOAA website (https://www.bou.class.noaa.gov/saa/products/welcome) as well as directly acquired by the receiving station installed at IMAA-CNR (Institute of Methodologies for Environmental Analysis -National Research Council), in Tito Scalo (Italy). 2.808 nighttime acquisitions were collected, with 2018 and 2019 representing 60% of the total, for the concurrent presence of both satellites. The VIIRS "Moderate" spatial resolution bands M07, M08, M10, M11, M12, M13, M14, M15, and M16 were selected to detect and characterize the COVA gas flare (Table 1). For the purposes of the study and the method applied, data were calibrated both as radiances (RD, W/(m 2 sr·µm)) and brightness temperatures (BT, K) values. Starting from the Sensor Data Records (SDR), a portion centered over Italy (1800P x 1600L) re-projected in WGS84 Lat-Long projection, was produced for each of the VIIRS data included in the collected dataset. The ROI is a subset of this large area, corresponding to a box 4x3 (yellow box in

Ancillary Data
The ancillary data used in this study to assess the performances of the VIIRS-based RST-FLARE configuration in identifying hotspots at COVA were downloaded, as KML files, from the VIIRS Nightfire (VNF) "Nighttime Detection and Characterization of Combustion Sources" database, publicly available through the NCEI-EOG (National Centers for Environmental Information-Earth Observation Group) website (https://ngdc.noaa.gov/eog/viirs/download_viirs_fire.html). Two versions of the VNF algorithm are currently online, based on VIIRS observations provided by both CLASS (Comprehensive Large Array-data Stewardship System) and GRAVITE (Government Resource for Algorithm Verification, Independent Test, and Evaluation) portals. They mainly differ for the use of M11 in detecting combustion source, added in the latest version of VNF [52], since December 2017.
The VNF outputs cover the period from 31 March 2012 to 8 October 2019. The radiant heat (MW), temperature (K), and source footprint (m 2 ) of the IR emitter are computed by a single (or dual) Planck curve fitting, depending on the number of bands (single, near-infrared -NIR or short-wave infrared -SWIR or multi-band, only in the MWIR or NIR/SWIR + MWIR) where the pixel is flagged as a combustion source [52]. The algorithm is able to detect combustion sources with temperature spanning from 400 K up to over 2500 K. The Planck curve fitting fails when hotspots are detected only in M10 (or M11). These cases, corresponding to dim sources, are designated as "non-conforming detections" (NCD).
The outputs (both hotspots, HS and NCD) provided by VNF for the COVA in the investigated temporal range are detailed in Table 2. In this work, the number of hotspots is the number of days in the same year, when the algorithm identifies one or more thermal anomalies over COVA. Hence, the real number of hotspots can be greater (or equal) than the days counted. For the assessment of the VIIRS-based RST-FLARE outcomes, information provided by ENI through the three technical reports, referred to years 2012-2014, were exploited [49][50][51]. In addition, since 2016, a website dedicated by ENI to its role and activities in Basilicata (named "Eni in Basilicata") was set up (https://www.eni.com/eni-basilicata/chi-siamo.page). The "News" section (https://www. eni.com/eni-basilicata/news/2019-elenco-news.page) collects all relevant events concerning the COVA from 2016 to date (the page is daily updated). For the purpose of this study, Table 3 lists the official long stop-periods (time interval and total days in the year) of the plant as well as the reasons of these interruptions (in the round brackets), used for the interpretation of results.

The Methods
A series of preliminary analyses were carried out to characterize the investigated site from a spectral point of view as well as to select the most suitable VIIRS bands to implement the RST-FLARE algorithm.

Temperatures Computed for COVA by VNF
First, the COVA site behavior in terms of temperature variation was assessed by exploiting the VNF outputs.
In detail, the temperature computed for the 103 hotspots detected over COVA by VNF between 1 January 2015 and 30 September 2019 ( Figure 2) revealed that COVA exhibits a temperature lower than 1500 K in most cases (>70%). Temperature exceeds 1800 K only in one case (T=1878K on 4 August 2015 at 00.46GMT). The range 1300-1550 K was defined by Reference [14] as the crossover zone between temperatures recorded for gas flares and biomass burning by providing the first indication that COVA thermal emission can be seen both at SWIR and MWIR wavelengths.

M10/M12 Radiances
Another test was carried out in order to confirm the peculiar COVA spectral behavior. According to Reference [20], the radiances ratio M10/M12 should range between 2.5-5.5 for gas flares at 1600-2200 K and 0-1.2 for landscape fires at 650-1330 K.
To assess such a behavior, 1.489 clear data (i.e., no cloudy pixels detected applying the method described in Section 4.4) for one of the two site-affected pixels (1386P-1042L) were analyzed in the above mentioned temporal period and compared to an "unperturbed" pixel very close to the site (1378P-1040L, Lat 40 • 19'24.60"N-Long 15 • 50'33.00"E), but far enough to be not thermally perturbed by COVA activity and not occupying any industrial activity ( Figure 3). The different behavior in terms of the M10/M12 ratio between the two sites is evident with the unperturbed pixel showing a value at around 0.02. The COVA is characterized by the ratio at least three times higher than the unperturbed pixel, but always below 1, except in one case, when it reaches the value of 2.205 (18 July 2017, at 00.55 GMT), which confirms the hybrid behavior of COVA concerning its thermal emission. "Hybrid" is meant in terms of the spectral behavior of COVA in both MIR and SWIR regions. This is further confirmed by looking at the signal recorded in the MWIR band (x-axis of Figure 3). COVA seems to show a very "warm" tail (BT_M12 > 293 K) with respect to the unperturbed pixel, which allows two main considerations. On one hand, such a result confirms that the COVA is almost an intermittent thermal emission source, On the other hand, due to its general low temperature, MWIR information can be profitably used to assess its behavior in support to the SWIR ones.

Spectral Characterization of COVA
Starting from the above considerations, two different VIIRS images were analyzed to better understand the spectral behavior of the COVA in the presence of a high level of thermal activity: the image of 25 August 2017, at 00.42GMT, characterized by clear evidence of a hotspot and the one on the next day (26 August 2017, at 00.25GMT) for which the pixel containing the gas flare does not show a significant thermal emission.
The radiances measured for the COVA pixel 1386P-1042L in these two images, in the spectral range from M07 to M16, are shown in Figure 4.  Figure 4), the signal significantly raises at the lowest IR wavelengths (79%-100% at NIR-SWIR or M07-M10), moving to 32% and 2% from M12 to M14 and showing imperceptible variations in the LWIR (≤2% at M15, M16) (white line in Figure 4). This is an expected result by taking into account the output arising from the previous analyses. According to the Wien's law, hot sources in the 1300-1550 temperature range have their emission peak in the NIR-SWIR spectral range with a smaller but still evident signal in the MWIR and any evident feature in the LWIR. Furthermore, combustion sources can be readily detected in the NIR and SWIR channels, dominated by background noise at night. Besides, using VIIRS short wavelength channels allows detecting smaller hot source areas across a broad range of temperatures [52]. In the MWIR, the higher signals can be associated to clouds, earth surface features, and combustion sources. In the LWIR, some of the largest flares shows faintly detectable signals [13,16].

The VIIRS-Based RST-FLARE Algorithm
The strategy developed to identify thermal anomalies associated with gas flaring at COVA follows the general prescriptions of the RST-FLARE algorithm, previously implemented on multi temporal series of MODIS nighttime thermal data [32,33]. In this work, taking in mind the considerations shown in the previous paragraphs, the algorithm has been exported on VIIRS nighttime bands and the procedure was slightly modified ( Figure 5). The main differences with the MODIS version rely on two aspects. The new configuration, in fact, i) works on a box 4 × 3 around the two COVA pixels (yellow box in Figure 1) and ii) takes into account the SWIR radiances in the same box to identify hotspots. The choice to consider a box instead of the two COVA-affected pixels (as done for MODIS) arose from the following considerations: i) residuals navigation errors may affect the hotspot detection, ii) when gas flares are observed at high satellite zenith angles, they result in larger source areas, which perturb more pixels [14]. The SWIR contribution has been included in order to improve the performances of RST-FLARE in detecting thermal anomalies and quantifying their radiant/emissive power. The starting point of RST-FLARE is the collection of multi-year time series of satellite images over the region of interest, for defining, at a pixel level, the behavior of the signal under investigation in specific observational conditions [42][43][44]. To this aim, data are grouped on a monthly temporal scale. Only cloud-free pixels are used and marked as valid. Cloudy pixels are detected by applying the OCA approach (the One-channel Cloud-detection Approach) [53,54], using the LWIR brightness temperatures (i.e., VIIRS M16 channel). SWIR to MWIR signals measured in the COVA box were analyzed by following the scheme shown in Figure 5.
Following the previously shown VIIRS-based analyses of the thermal behavior of COVA pixels, two ALICE (Absolutely Llocal Index of Change of the Environment) indices are computed for each clear pixel in the box to identify, among the signals under investigation (SWIR and MWIR-LWIR), the ones associable with the presence of hotspots at the COVA site: The ALICE index is assumed as a standardized variable characterized by a Gaussian behavior (i.e., with mean equal to zero and standard deviation equal to 1). This means that the probability of occurrence of values higher than 2 standard deviations is less than 2.28% and it becomes lower than 0.13% for values higher than 3. For each signal (SWIR or MWIR-LWIR), the normal behavior of each pixel is expressed by a mean value (µ) and a normal variability (σ). Hotspots are defined as pixels whose signal exceed a pre-defined confidence level value.
For the analyzed phenomenon, high values of both ALICEs are expected for the pixel at position i in the 4x3 box when COVA produces high thermal emissions. These thermal anomalies should indicate the occurrence of major fluctuations in the COVA combustion operations and/or to the gas flaring in emergency conditions.
The confidence levels were identified for each of the two investigated signals by a percentile analysis applied to the two-time series of ALICE indices computed on COVA pixels from 1 January 2015 to 30 September 2019 ( Figure 6). The choice of the above-mentioned confidence level also depends on the error committed in correctly identifying hotspots. Such an error is quantified by the percentage of thermal anomalies detected over the unperturbed pixel previously analyzed, characterized by the absence of any industrial activities, and by applying a specific threshold to the ALICE SWIR and ALICE MWIR-LWIR values (Figure 7). By combining information acquired by the analysis of data in Figures 6 and 7, two confidence levels were chosen and thermal anomalies were classified into two groups: "High Confidence" (HC) and "Medium Confidence" (MC) hotspots.
Using the 99th percentile, a threshold of 5 for the ALICE SWIR and 4 for the ALICE MWIR-LWIR was found (Figure 6), which implies that, in both cases, an error of 0.1% was found (Figure 7). Therefore, at these levels, HC hotspots are identified as: Considering the 95th percentile, MC hotspots are discriminated at a detection level between 3 and 5 for the ALICE SWIR and greater than 1.5 for the ALICE MWIR-LWIR , respectively ( Figure 6).
3 ≤ ALICE SWIR < 5 and ALICE MWIR-LWIR ≥ 1.5 (4) At this level, a maximum error of 2.6% is committed (Figure 7). Once the hotspot is detected within the box on a specific day, its thermal characterization is performed. Following Reference [33], the emissive power of the heat source is expressed in terms of radiance excess (RE), which corresponds to the deviation of the M10 or/and M12 radiances, depending on the way (i.e., level of confidence, HC or MC) the hotspot was identified with respect to a pre-defined background value. For each day, a daily RE is calculated as the sum of all REs computed for the hotspots detected within the 4x3 box. The daily records are then aggregated on an annual scale.
In detail, for HC hotspots, RE can be equal to: where: • y refers to each of the investigated years in the 2015-2019 period, • i refers to each hotspot identified in the box (for i=1, . . . , 12), • M10 hotspot (M12 hotspot ) is the radiance measured in the VIIRS band M10 (M12) for the hotspot i, • <M10 bg > (<M12 bg >), referring to the background, is equal to the spatial mean of the temporal average µ M10 ( x , y ) (µ M12 ( x , y ) ) of the first neighboring pixels around the box, • α y is a coefficient which weighs the variability, between years, in sampling and cloud cover. It is computed as the ratio between the clear and total images. To take into account its variability in the considered temporal range, it has been normalized with respect to its maximum value computed within 5 years (α y,max = 0.59).
For MC hotspots, RE corresponds to the sum of RE y (SWIR) and RE y (MWIR) (5). Lastly, a short comment on the excess of radiance (RE), the metric used to quantify the radiative power of the gas flare pixel. RE is based on M10 and M12 signals, similar to the ones used in the methods suggested by Reference [20], i.e., the SWIR and MIR-Radiance methods, for gas flaring estimation. Both methods quantify the radiant power of a gas flare by computing the Fire Radiative Power (FRP) using M10 and M13 radiances, respectively (i.e., FRP SWIR or FRP MIR ). The COVA peculiar behavior does not allow the use of the FRP formulas to accurately assess its radiant heat. On one side, the hybrid behavior of COVA, when generating anomalous (i.e., hotter than background) radiances not only at SWIR wavelengths but even (and, in some cases, exclusively) in MWIR spectral region, requires both responses to be taken into account. This is why the radiance excess, as the sum of both SWIR and MWIR contributions, should be the most appropriate way to characterize such a hot source. Additionally, using the MIR-Radiance method for considering the COVA MWIR contribution could not be proper for this kind of site since the M13 band (the one used in Reference [20] and for which the FRP coefficient is available) is less sensitive than M12 to GF-related hotspots at COVA (see Figure 2). For these reasons, it is expected the COVA radiant heat estimates carried out using only the SWIR-Radiance method or both Radiance methods will be affected by uncertainty because: i) not including the MWIR contribution (in the first case) or ii) not using the most suitable MWIR band for COVA gas flare (in the second one).
A direct comparison of SWIR excess (in W/(m 2 ·sr·µm)) and the FRP SWIR values (in MW) both computed for the COVA pixel 1386P -1042L for all useful data in years 2015-2019 showed a linear correlation coefficient (R) of 0.99 between the two temporal trends (Figure 8). This analysis demonstrated the high consistency of our estimates.

Results
This section provides a concise and precise description of the experimental results and their interpretation, together with a comparison with VNF products. A linear equation aimed at estimating the COVA radiant heat from its radiance excess has been developed.

VIIRS-Based RST-FLARE Outputs
The VIIRS-based RST-FLARE outputs are shown below. The developed algorithm identifies 275 hotspots from 2015 to 2019 (as the sum of the numbers in the last line in Table 4), classified as High (HC) and Medium Confidence (MC) levels. The line "HC and MC" in Table 4 counts the days when RST-FLARE identified both HC and MC hotspots for pixels occupying different positions in the box matrix. The number of days with hotspots is very stable between 2015 and 2017 (moving from 38 to 43, Table 4), with increasing values in the two following years, 2018 and 2019, almost double when compared to the previous ones. This is very likely due to the launch of a second satellite (i.e., JPSS-1) hosting the VIIRS sensor onboard.
The annual radiance excess computed for the hotspots belonging to two separated datasets (i.e., HC and MC) as well as the total one, which consists of their sum, is depicted in Figure 9. Focusing on the Radiance Excess trend in the five-years period (gray line in Figure 9), its minimum is observed in 2016. Then it increases up to 2018, while slightly decreasing in 2019 (~2%). It is interesting to note that in both graphs the inflection point is in 2016, which is the year with the longest stop of COVA activities, and lasted in a total of almost five months (see Table 3).

Comparison with VNF
The outputs provided by VIIRS-based RST-FLARE are tabulated in Table 5 by also displaying the comparison with VNF detections (already shown in Table 2). The two datasets (first two lines in Table 5) are highly correlated (R=99%) in terms of temporal evolution along the considered period, with RST-FLARE detections almost doubling when compared to VNF between 2015 and 2017 and a turnaround in the following two years. This is mainly due to the additional use of M11 band in the VNF algorithm, which increased by 55% its performances in detecting combustion sources, even with a smaller size and lower temperatures [52].
A deeper investigation of the two outputs was conducted, focusing on the uncommon detections. The 119 RST-FLARE hotspots not detected by VNF (i.e., 275 -156) are plotted in Figure 10a in terms of their distribution between the two levels of confidence (i.e., HC and MC) and the "mixed" hotspots (i.e., when they have been classified as both HC and MC). Figure 10b shows the 207 (i.e., 363-156) VNF hotspots, divided between hotspots and "non-conforming" detections, not identified by VIIRS-based RST-FLARE. Most of VNF hotspots not identified by RST-FLARE are "non-conforming" detections (i.e., 94%). In 6% of cases (i.e., 13 hotspots), VNF identified hotspots over COVA. Two conditions might determine the RST-FLARE missing identifications compared to the VNF ones including the presence of clouds over the ROI and the values of ALICE indices below the selected confidence levels. A visual inspection of the M10 and M12 channels of all 13 imagery (5 in 2018 and 8 in 2019) confirmed that, although they were classified as cloudy by the OCA approach, hotspots are evident in the COVA box. This circumstance is typically observed in the case of very thin clouds that are not able to fully mask the signal coming from the surface but are still (and correctly) identified as cloudy days.
For a more quantitative comparison with VNF, the first analysis was devoted to investigate the temporal match of VIIRS-based RST-FLARE and VNF hotspots (HS), not considering the "non-conforming detections" (NCD) (Figure 11). Furthermore, 90 correspondences (same day and same hour of acquisition) were detected for COVA by both algorithms between 2015 and 2019 (see Table 5). Their characterization, along the considered period, in terms of RE and RH is shown in Figure 11, which confirms a satisfactory agreement between these two parameters (R=90%).

Radiant Heat Estimation
The high consistency between the two metrics allowed for developing a linear equation able to estimate RH using the corresponding RE for each detected RST-FLARE hotspot. This is a site-specific model developed to better characterize the COVA behavior using both SWIR and MWIR responses. To this aim, the 90 common detections were split into two different datasets: one (i.e., 60 records, equal to 67%, randomly selected among the 90 matchings) was used to calibrate a linear regression model aimed at computing the radiant heat from the radiant excess (R 2 = 0.81, Figure 12).  Figure 12 was then used to estimate RH even for the "non-conforming" VNF detections (i.e., 66 data). In fact, for these detections, the VNF scheme is not able to compute RH and, then, their indirect characterization, exploiting the RE provided by the RST-FLARE algorithm, can be particularly useful in these cases. Figure 13 shows the radiant heat computed for COVA, for each year from 2015 to 2019, by RST-FLARE (for a total of 275 hotspots, black line in Figure 13), and VNF (for its 103 hotspots, black dotted line in Figure 13). The RST-FLARE scheme allowed recovering 66 VNF "non-conforming" detections (25% of its total) that strongly increased the VNF RH estimates of the COVA plant (black dashed line in Figure 13).
This information can be used to update RH estimates in view of acquiring in-situ data about COVA volume emissions that can be used to develop a model aimed at inferring emitted volumes starting from radiant heat estimates.

Discussion
The VIIRS-based RST-FLARE algorithm developed in this work is able to provide the radiant heat RH (MW) of the COVA gas flare for each detected hotspot. It is derived from the radiance excess, RE, which adds up the VIIRS SWIR and MWIR contributions (at 1.61 and 3.7 µm, respectively) in case a thermal anomaly occurs at the COVA plant. The comparison with VNF estimates in the investigated temporal range (i.e., 2015-2019) widely demonstrated good agreement between the two independent products, especially in terms of their temporal trends. Moreover, the proposed model, when applied over the investigated source, seems capable of overcoming some limits of the VNF methodology in deriving RH estimates in the presence of lower level (i.e., "non-conforming detections") thermal anomalies. In such a way, RST-FLARE-based RH estimates can complement VNF outputs, contributing to better characterize the COVA source in the time domain reliability of such products as well as their add-on value in improving VNF capability to quantify the radiant heat.
The proposed VIIRS-based algorithm represents a new configuration of the previous, MODIS-based, RST-FLARE technique. It has been proposed to: i) guarantee the continuity of gas flaring monitoring and investigation after the (possibly close) end of MODIS life, and ii) exploit the improved spatial and spectral resolutions of VIIRS with respect to MODIS. However, presently, the MODIS sensor is still operating very well and the related RST-FLARE configuration is routinely applied at COVA. Therefore, VIIRS-based findings can be also compared with the ones achieved by means of the original RST-FLARE configuration. The latter is using the FRP as the satellite metric aimed at computing the gas flare emissive power [32]. The VIIRS-based RH and MODIS-based FRP values, aggregated at an annual scale, in the temporal period 2015-2019, are shown in Figure 14. This figure highlights good agreement (R=88%) between the two metrics (with systematic higher FRP estimates) even though they are based on independent sensors data with different (spatial and spectral) features. Looking at the two curves in Figure 14, it is clear that they show a very similar behavior, with a minimum in 2016 and an increasing trend in the following years. The inter-products comparison has been carried out at a monthly scale. As an example, the estimates provided for 2018 by RH and FRP are shown in Figure 15. The high consistency of the two metrics is further confirmed (R=76%), especially in terms of their temporal trend (Figure 15), even though they provide different results in some months (e.g., December). The latter might be partially due to a cloud effect, which is expected to be more pronounced in the winter months. Figure 15 demonstrates the temporal consistency of the products, which clearly highlights even the possible add-on coming from the integration of two schemes in the thermal characterization of a gas flare. Focusing on October and November 2018, only VIIRS-based RST-FLARE is able to identify a hotspot at COVA (3 in October and 2 in November) and quantify their radiant heat. This is likely due to the better VIIRS spatial resolution as well as regarding the use of a SWIR channel (missed in MODIS nighttime imagery), particularly suitable for gas flaring analysis. To show an example, the M10 and M12 records measured in the COVA area on 8 November 2018, at 00.47 GMT, are shown in Figure 16 and are depicted in gray tones. The two COVA affected pixels (red box in Figure 16) are the ones in the scene with the highest values in both SWIR and MWIR channels and clearly appear as highly radiant compared to the surrounding pixels.
All the above considerations suggest a higher performance to be expected from a multi-sensor RST-FLARE approach.
Future research studies will be addressed in two directions. The MODIS-based RST-FLARE scheme is able to provide GF information for COVA since 2000, which characterizes this thermal source not only in terms of FRP but also in terms of gas volumes emitted into the atmosphere [32]. The portion of the MODIS-based configuration on the VIIRS IR Imagery bands (i.e., I4 and I5, centered at 3.74 and 11.45 µm, respectively) will be tested to guarantee the continuity of the provision of this type of information in view of assessing the possible improvements coming from the finer (i.e., 375 m versus 1000 m) spatial resolution of these data.
Furthermore, the possible contribution to COVA characterization coming from the usage of the M11 band (2.23-2.28 µm) will be investigated.
Lastly, due to the intrinsic independence of the RST approach from the local conditions, a further development will be the RST-FLARE implementation during daytime, to assess its performance in more difficult (i.e., in the presence of solar radiation) environmental conditions as well as to increase the sampling frequency and, consequently, the satellite-based monitoring capabilities of a gas flaring phenomenon.

Conclusions
In this work, an adapted version of the RST-FLARE algorithm for VIIRS data has been presented and results have been achieved by investigating the COVA oil and gas pre-treatment plant in Val d'Agri (Basilicata region, southern Italy), which have been shown and assessed for the period 2015-2019 including for a comparison with VNF (i.e., VIIRS Nightfire) records.
Findings confirm that RST-FLARE, originally designed and developed for MODIS mid-infrared data, can be properly ported on a different satellite/sensor system like the Suomi/NPP and JPSS-1 VIIRS SWIR and MWIR records.
Thermal anomalies detected over the COVA plant have been assessed by using independent VNF outputs, which confirms good agreement between the two procedures. A specific metric to quantify and characterize detected hotspots (i.e., Radiance Excess -RE) has been evaluated by investigating its relationship with an independent quantity, i.e., the Radiant Heat -RH, which is a standard output of the VNF technique. In addition, in this case, the two quantities have shown a very high correlation (R = 90%) by allowing RE to be used for quantitatively characterizing gas flare thermal sources. Lastly, the high RE-RH correlation allowed for designing a model capable of estimating RH values in cases when VNF is not able to provide any quantitative information (i.e., in correspondence of the "non-conforming detections"). This outcome would enable RST-FLARE as an additional source of information to be used for characterizing and quantifying gas flares, at least at a local scale, by complementing VNF outputs. The regression model converting RE in RH is site-specific being "ad hoc" developed for providing an accurate characterization of the COVA radiant heat to use in the next studies devoted to estimate COVA GF emissions. Its porting to other geographic areas and power plants requires data inherent to the investigated site for the coefficients' calibration. The RST-FLARE algorithm, only based on satellite data for the RE, has a global applicability.
In perspective, since this more refined and complete information would contribute to better estimate of the quantity of gas volumes emitted into the atmosphere (in fact, as already largely demonstrated, the radiant power/heat of thermal sources is a proxy of emitted gas volumes), the potential add-on of RST-FLARE in this sense could be significant.
The demonstrated good consistency between the two RST-FLARE developed schemes, one based on nighttime MWIR MODIS channels and the other one based on SWIR and MWIR VIIRS acquisitions, further strengthen the potential of the proposed configuration in view of implementing a multi-sensor RST-FLARE strategy for the analysis of gas flaring sources and for assessing their environmental impacts.