Analysis of Liquid Air Energy Storage System with Organic Rankine Cycle and Heat Regeneration System

: Liquid air energy storage (LAES) is one of the most promising technologies for power generation and storage, enabling power generation during peak hours. This article presents the results of a study of a new type of LAES, taking into account thermal and electrical loads. The following three variants of the scheme are being considered: with single-stage air compression and the use of compression heat for regasification (Case 1); with single-stage compression and the organic Rankine cycle (Case 2); and with three-stage air compression/expansion and the organic Rankine cycle (Case 3). To analyze the proposed schemes, the Aspen HYSYS v.12 software package was used to compile models of the studied cycles. The analysis shows that round-trip efficiency (RTE) can be as high as 54%. The cost of 1 kg of liquid air is USD 7–8. Moreover, it is shown that the generation of electrical energy largely depends on the operation of the expander plant, followed by the organic Rankine cycle (ORC).


Introduction
In recent years, issues related to the implementation of renewable energy sources have gained increasing significance both globally and within the context of Kazakhstan [1,2].One of the pressing challenges in the utilization of renewable energy sources is the notable variability in electricity production, alongside a widening disparity between peak demand and production due to the inherent variability associated with these sources [3,4].Within Kazakhstan's energy system, which predominantly relies upon solid-fuel thermal power stations, hydroelectric power plants, and gas turbine power stations as primary flexible sources, their capacities have proven insufficient for addressing these challenges.The unevenness of electricity generation in Kazakhstan in 2020 was 0.73, and the peak coefficient of the daily load schedule of the Southern Energy Zone reached 0.698 [5].Table 1 provides a summary of various energy storage devices.
To accumulate electricity during periods of low demand and release it during periods of peak loads, buffer storage devices with high capacity and relatively low unit cost are needed.LAES systems are an example of such storage solutions.The LAES technology for the accumulation, storage, and release of industrial volumes of energy is based on changing the phase state of atmospheric air through deep (cryogenic) cooling below the condensation temperatures of nitrogen (air) at atmospheric pressure (below minus 196 • C).This is followed by evaporation in a closed volume and subsequent use for electricity production.Therefore, it is advisable to refer to such installations as cryogenic power plants (CPP), by analogy with pumped storage power plants.
The conducted analysis demonstrates that there are a variety of options for combining liquid air energy storage (LAES).In our research, we employed a novel LAES configuration [31,32], which potentially incorporates a system of three compressors, three gas turbines, and two organic Rankine cycle (ORC) loops.Furthermore, it is imperative to consider centralized loads, energy resource costs, and the unevenness of demand profiles in the context of Kazakhstan's sharply continental climate.Additionally, this article conducts a comparison between two modified configurations.The first configuration is the baseline, the second involves an ORC system, and the third integrates staged compression and expansion alongside two ORC systems.
The schemes being studied aim to enhance the efficient utilization of liquid air energy to meet electrical and thermal demands during peak city hours.The decreasing production costs of liquid air enable us to assess the feasibility of constructing liquid air energy storage (LAES) systems, which are particularly beneficial in regions like Kazakhstan with low electricity costs.
The contribution of this study to sustainability: The LAES in Kazakhstan will primarily rely on renewable energy sources, particularly solar panels in the southern regions of the country.Given that over 80% of electricity in Kazakhstan is currently generated by solidfuel thermal power plants, integrating renewable energy sources and energy storage for peak load management will diminish the reliance on coal-generated electricity.This shift is expected to significantly reduce CO 2 emissions and other harmful gases released into the atmosphere.The construction of LAES facilities in Kazakhstan will also create new job opportunities and necessitate the training of skilled professionals, thereby contributing to sustainable economic development.

Materials and Methods
Figure 1 provides a graphical depiction of the research study.Aspen HYSYS v.10 software was utilized for the analysis [33].The baseline configuration employed in this investigation was derived from the scheme presented in a patent [32].Initial data, as outlined in Table 2, were adopted for this study.Subsequently, two variations were explored based on this configuration.In Case 2, the ORC cycle's working fluid (R11) was heated with hot water from the compressor heat exchanger.In the second modification (Case 2), a 3-stage compression and expansion with intermediate cooling and heating were implemented.ORC cycles were integrated after the compressors and expanders.Upon constructing the configurations, data were obtained pertaining to electricity consumption for air compression and pumping, as well as electricity and thermal energy generation.Comparative analyses of the configurations were conducted, along with assessments of the proportion of thermal or electrical energy substitution generated from the thermal power station, accounting for changes in loads over the course of the year.Figure 2 presents a conceptual diagram of the investigated setup and cases for study.In the thermodynamic cycle of liquid air energy storage (LAES), the working fluid is ordinary atmospheric air.Atmospheric air is drawn through an air intake device and initially passes through a mechanical filter to remove dust particles.Subsequently, the air is directed to the inlet of one or several high-pressure air compressors, where it is compressed to a pressure of 50-150 atmospheres.During the compression process, a substantial temperature increase occurs in the compressed air, reaching temperatures of several hundred degrees Celsius (400-600 °C).The high-pressure air is then cooled (to around 30-50 °C) in a heat exchanger, where heat is transferred from the high-pressure air to a cooling agent, such as water.This cooling agent is directed to a reservoir, which in the LAES technological scheme, serves as an auxiliary hot thermal reservoir.Figure 2 presents a conceptual diagram of the investigated setup and cases for study.In the thermodynamic cycle of liquid air energy storage (LAES), the working fluid is ordinary atmospheric air.Atmospheric air is drawn through an air intake device and initially passes through a mechanical filter to remove dust particles.Subsequently, the air is directed to the inlet of one or several high-pressure air compressors, where it is compressed to a pressure of 50-150 atmospheres.During the compression process, a substantial temperature increase occurs in the compressed air, reaching temperatures of several hundred degrees Celsius (400-600 • C).The high-pressure air is then cooled (to around 30-50 • C) in a heat exchanger, where heat is transferred from the high-pressure air to a cooling agent, such as water.This cooling agent is directed to a reservoir, which in the LAES technological scheme, serves as an auxiliary hot thermal reservoir.Figure 2 presents a conceptual diagram of the investigated setup and cases for study.In the thermodynamic cycle of liquid air energy storage (LAES), the working fluid is ordinary atmospheric air.Atmospheric air is drawn through an air intake device and initially passes through a mechanical filter to remove dust particles.Subsequently, the air is directed to the inlet of one or several high-pressure air compressors, where it is compressed to a pressure of 50-150 atmospheres.During the compression process, a substantial temperature increase occurs in the compressed air, reaching temperatures of several hundred degrees Celsius (400-600 °C).The high-pressure air is then cooled (to around 30-50 °C) in a heat exchanger, where heat is transferred from the high-pressure air to a cooling agent, such as water.This cooling agent is directed to a reservoir, which in the LAES technological scheme, serves as an auxiliary hot thermal reservoir.Following the interstage cooler, the high-pressure air undergoes drying and purification processes before entering a cryogenic decarbonization unit (with a carbon dioxide stream at approximately −73 • C).After this, the high-pressure air enters a reduction valve, which regulates the air pressure at the inlet of the expander.During the expansion process on the turbine wheel of the expander, the compressed air transitions into the realm of cryogenic temperatures.
The expander unit, or a group of expanders, constitutes the primary technological node within the LAES system.The cryogenic mist after the expander is directed into a separator tank, where the cryogenic stream undergoes separation into liquid and gaseous phases.
The gaseous cryogenic phase is removed from the separator tank into a chamber of clean air, while simultaneously extracting heat from the incoming high-pressure airflow that feeds the turbine wheel of the expander.The saturated cryogenic mist's liquid phase is extracted from the separator tank and stored in a cryogenic liquid air storage tank.The storage of liquid air in the storage tank is maintained at atmospheric pressure.Adequate thermal insulation of the liquid air storage tank is crucial to ensure the prolonged (days, weeks) storage of significant quantities of liquid air within the reservoir.
In [34], various refrigerant options for ORC systems were studied.Wang et al. analyzed the performance of nine pure organic fluids at specific operating regions and found that R11, R141b, R113, and R123 exhibited slightly better thermodynamic performances than the others [35].The refrigerant R11 was employed as the working fluid in the organic Rankine cycle (ORC), with its technical specifications outlined in Table 2.The ORC scheme in the Aspen HYSYS software is illustrated in Figure 3.The technical parameters of the ORC cycle were adopted in accordance with [36] and are provided in Table 3.
Following the interstage cooler, the high-pressure air undergoes drying and purification processes before entering a cryogenic decarbonization unit (with a carbon dioxide stream at approximately −73 °C).After this, the high-pressure air enters reduction valve, which regulates the air pressure at the inlet of the expander.During th expansion process on the turbine wheel of the expander, the compressed air transition into the realm of cryogenic temperatures.
The expander unit, or a group of expanders, constitutes the primary technologica node within the LAES system.The cryogenic mist after the expander is directed into separator tank, where the cryogenic stream undergoes separation into liquid and gaseou phases.
The gaseous cryogenic phase is removed from the separator tank into a chamber o clean air, while simultaneously extracting heat from the incoming high-pressure airflow that feeds the turbine wheel of the expander.The saturated cryogenic mist's liquid phas is extracted from the separator tank and stored in a cryogenic liquid air storage tank.Th storage of liquid air in the storage tank is maintained at atmospheric pressure.Adequat thermal insulation of the liquid air storage tank is crucial to ensure the prolonged (days weeks) storage of significant quantities of liquid air within the reservoir.
In [34], various refrigerant options for ORC systems were studied.Wang et al analyzed the performance of nine pure organic fluids at specific operating regions and found that R11, R141b, R113, and R123 exhibited slightly better thermodynami performances than the others [35].The refrigerant R11 was employed as the working fluid in the organic Rankine cycle (ORC), with its technical specifications outlined in Table 2 The ORC scheme in the Aspen HYSYS software is illustrated in Figure 3.The technica parameters of the ORC cycle were adopted in accordance with [36] and are provided in Table 3.    Figure 4 depicts the LAES configuration with two organic Rankine cycles (ORCs) and three compression and expansion stages.As evident from the diagram, the main stream of hot water following the compressors is directed to a splitter, where a portion of the hot water is routed to the ORC, while the remaining portion is utilized for air heating subsequent to the pump.Following this, the air is directed to the expanders, where energy generation occurs.Figure 4 depicts the LAES configuration with two organic Rankine cycles (ORCs) and three compression and expansion stages.As evident from the diagram, the main stream of hot water following the compressors is directed to a splitter, where a portion of the hot water is routed to the ORC, while the remaining portion is utilized for air heating subsequent to the pump.Following this, the air is directed to the expanders, where energy generation occurs.To determine the efficiency of the cycle and calculate the heat and material balances, installation diagrams were compiled in the Aspen HYSYS v.12 software package.For this, the following modules were used (for symbols, see Figures 3 and 4): Expander (K-100, Expander)-models an expander and a turbine; Compressor (RC)-models a compressor; Pump (CP, P-100-2)-models a pump; Heat exchanger (E-100, Evaporator)-models a heat exchanger with two inputs and outputs; Cooler (cooler)-a refrigerator with one input and output; Mixer (Mix-100)-models the mixing of two streams; Divider (Tee-100)-models the division of flows according to a given ratio; Separator (V-100)-simulates the process of single evaporation (condensation); Component divider (X-100)-a component divider that models in this diagram the process of gas purification at the entrance to the expander; Recycle (RCY-1)-combines recycle flows.
In addition, the scheme uses sub-flowsheets (Flow-1, Flow-2, Flow-3, and Flow-4).The air and recirculated water enter a three-stage compression unit, in which the air is compressed in compressors and cooled in refrigerators.The compressed air passes sequentially through the E-100 heat exchanger, where it is pre-cooled by a stream of cold To determine the efficiency of the cycle and calculate the heat and material balances, installation diagrams were compiled in the Aspen HYSYS v.12 software package.For this, the following modules were used (for symbols, see Figures 3 and 4): Expander (K-100, Expander)-models an expander and a turbine; Compressor (RC)-models a compressor; Pump (CP, P-100-2)-models a pump; Heat exchanger (E-100, Evaporator)-models a heat exchanger with two inputs and outputs; Cooler (cooler)-a refrigerator with one input and output; Mixer (Mix-100)-models the mixing of two streams; Divider (Tee-100)-models the division of flows according to a given ratio; Separator (V-100)-simulates the process of single evaporation (condensation); Component divider (X-100)-a component divider that models in this diagram the process of gas purification at the entrance to the expander; Recycle (RCY-1)-combines recycle flows.
In addition, the scheme uses sub-flowsheets (Flow-1, Flow-2, Flow-3, and Flow-4).The air and recirculated water enter a three-stage compression unit, in which the air is compressed in compressors and cooled in refrigerators.The compressed air passes sequentially through the E-100 heat exchanger, where it is pre-cooled by a stream of cold air from the RC.Next, the air through the X-100 enters the K-100 expander and is cooled, and the formed two-phase flow enters the V-100.In the separator, the phases are separated, the gas phase enters the suction RC, and the compressed phase enters the CP.
The circulating water is used as a coolant in the compression unit, where it is heated.This water is then used as a coolant, evaporating freon in the ORC (Flow-3, Flow-4) or liquid air in the expansion unit (Flow-2).Next, the water is collected at all stages, cooled in the cooler, and again sent to the compression unit.
The following formula was used to calculate the round-trip efficiency [39]: The following formula was used to calculate the coefficient of performance (COP) [39]: The calculation of hourly CO 2 emissions during the generation of electric energy by gas turbines was carried out according to the following formula [40]: The calculation of hourly CO 2 emissions from the combustion of associated petroleum gas by steam boilers was carried out according to the formula: The initial parameters for the cycles are outlined in Table 4.A substantial portion of the data was derived from information provided in [10].Notably, the cycle pressure was adopted within the range of 50-190 bar, spanning between the maximum values.
The following formula was used to convert Gcal to GJ: The thermal efficiencies of ORC cycles were calculated using the following formula:

Results
In this study, it was assumed that the liquid air energy storage (LAES) system is connected to either a thermal or electrical grid.Figure 5 illustrates the monthly variations in electricity generation from the LAES.As can be observed from the graph, the electrical energy output fluctuates significantly based on the pressure after the compressors.The disparity between the maximum and minimum investigated pressure values amounts to 9000 kWh for Case 1, 21,000 kWh for Case 2, and 43,000 kWh for Case 3.This phenomenon can be elucidated by the fact that an increase in pressure, while maintaining nearly identical temperature levels, leads to a negligible alteration in the working fluid flow rate in Case 1.Another factor is the continuous rise in the consumption of the single-stage compressor and expander.Additionally, the absence of staged cooling serves as a second reason for increased electricity generation, resulting in considerable heat consumption.It is most evident that under minimal pressure levels, electricity generation attains its maximum value due to the reduction in compressor efficiency resulting from changes in the thermophysical properties of air.The additional information on each component in the thermodynamic cycle is presented in Appendix A (Tables A1-A4).In the tables, the values entered into the diagram are highlighted in blue, and the calculated values are highlighted in black.Also, the table data show that the calculation observes the second law of thermodynamics (entropy increases at each stage).Negative enthalpy values are the result of internal HYSYS calculation procedures and do not affect the accuracy of the calculation (only the enthalpy difference matters).

Results
In this study, it was assumed that the liquid air energy storage (LAES) system is connected to either a thermal or electrical grid.Figure 5 illustrates the monthly variations in electricity generation from the LAES.As can be observed from the graph, the electrical energy output fluctuates significantly based on the pressure after the compressors.The disparity between the maximum and minimum investigated pressure values amounts to 9000 kWh for Case 1, 21,000 kWh for Case 2, and 43,000 kWh for Case 3.This phenomenon can be elucidated by the fact that an increase in pressure, while maintaining nearly identical temperature levels, leads to a negligible alteration in the working fluid flow rate in Case 1.Another factor is the continuous rise in the consumption of the single-stage compressor and expander.Additionally, the absence of staged cooling serves as a second reason for increased electricity generation, resulting in considerable heat consumption.It is most evident that under minimal pressure levels, electricity generation attains its maximum value due to the reduction in compressor efficiency resulting from changes in the thermophysical properties of air.The additional information on each component in the thermodynamic cycle is presented in Appendix A (Tables A1-A4).In the tables, the values entered into the diagram are highlighted in blue, and the calculated values are highlighted in black.Also, the table data show that the calculation observes the second law of thermodynamics (entropy increases at each stage).Negative enthalpy values are the result of internal HYSYS calculation procedures and do not affect the accuracy of the calculation (only the enthalpy difference matters).Figure 6 presents the relationship between thermal energy generation and air pressure downstream of the compressor.As illustrated in the graph, an increase in air pressure in the compressor results in increased production of thermal energy.This effect arises due to the elevation in air pressure without intermediate cooling, which leads to elevated air temperatures.Consequently, this results in greater water heating, subsequently contributing to the heating of the network water.Gcals were converted to GJ according to formula 5.The maximum thermal energy value is attained at a pressure of 190 bar, equating to 5.0 thousand GJ per month.The minimum value occurs at 50 bar, amounting to 2.1 thousand GJ. Figure 6 presents the relationship between thermal energy generation and air pressure downstream of the compressor.As illustrated in the graph, an increase in air pressure in the compressor results in increased production of thermal energy.This effect arises due to the elevation in air pressure without intermediate cooling, which leads to elevated air temperatures.Consequently, this results in greater water heating, subsequently contributing to the heating of the network water.Gcals were converted to GJ according to Formula (5).The maximum thermal energy value is attained at a pressure of 190 bar, equating to 5.0 thousand GJ per month.The minimum value occurs at 50 bar, amounting to 2.1 thousand GJ.In Figure 7, the annual thermal load in Almaty, Kazakhstan is depicted.Given that Kazakhstan experiences a sharply continental climate, even the southern regions necessitate substantial heating.The thermal load in the city of Almaty typically consists of heating and hot water supply requirements.As is discernible from the graphs, the thermal load during the warm season, between April and September, is significantly lower than in the cold period due to the absence of heating demands.All city boiler houses are equipped with gas boilers.Evidently, the electrical load exhibits a similar profile.The electrical load also manifests a seasonal characteristic, diminishing during the summer months and peaking during the winter period, especially from November to January.This phenomenon can be attributed to the use of electric heaters by a portion of the city's inhabitants and the early onset of darkness, necessitating increased illumination both outdoors and in residential and working areas.In Figure 7, the annual thermal load in Almaty, Kazakhstan is depicted.Given that Kazakhstan experiences a sharply continental climate, even the southern regions necessitate substantial heating.The thermal load in the city of Almaty typically consists of heating and hot water supply requirements.As is discernible from the graphs, the thermal load during the warm season, between April and September, is significantly lower than in the cold period due to the absence of heating demands.All city boiler houses are equipped with gas boilers.Evidently, the electrical load exhibits a similar profile.The electrical load also manifests a seasonal characteristic, diminishing during the summer months and peaking during the winter period, especially from November to January.This phenomenon can be attributed to the use of electric heaters by a portion of the city's inhabitants and the early onset of darkness, necessitating increased illumination both outdoors and in residential and working areas.In Figure 7, the annual thermal load in Almaty, Kazakhstan is depicted.Given that Kazakhstan experiences a sharply continental climate, even the southern regions necessitate substantial heating.The thermal load in the city of Almaty typically consists of heating and hot water supply requirements.As is discernible from the graphs, the thermal load during the warm season, between April and September, is significantly lower than in the cold period due to the absence of heating demands.All city boiler houses are equipped with gas boilers.Evidently, the electrical load exhibits a similar profile.The electrical load also manifests a seasonal characteristic, diminishing during the summer months and peaking during the winter period, especially from November to January.This phenomenon can be attributed to the use of electric heaters by a portion of the city's inhabitants and the early onset of darkness, necessitating increased illumination both outdoors and in residential and working areas.Figure 8 illustrates the round-trip efficiency as a function of the pressure downstream of the air compressor.These dependencies generally align with findings reported by other researchers [10,12].Importantly, the use of two ORC cycles allows for maximizing electrical energy acquisition, thereby enhancing overall efficiency.It is evident from the data that the highest efficiency is achieved at lower pressures, a consistent trend observed across all scenarios.This trend can be attributed to the increased specific energy consumption per kilogram of air at higher pressures and temperatures, resulting in higher energy consumption at the compressors.The maximum efficiency reaches 37.87% in Case 3, while the minimum is 15.7% in Case 1.
Sustainability 2024, 16, x FOR PEER REVIEW 10 of 15 Figure 8 illustrates the round-trip efficiency as a function of the pressure downstream of the air compressor.These dependencies generally align with findings reported by other researchers [10,12].Importantly, the use of two ORC cycles allows for maximizing electrical energy acquisition, thereby enhancing overall efficiency.It is evident from the data that the highest efficiency is achieved at lower pressures, a consistent trend observed across all scenarios.This trend can be attributed to the increased specific energy consumption per kilogram of air at higher pressures and temperatures, resulting in higher energy consumption at the compressors.The maximum efficiency reaches 37.87% in Case 3, while the minimum is 15.7% in Case 1. Figure 9 presents the relationship between the liquid oxygen fraction in the air and one liquefaction cycle.As evident from the graph, the utilization of multiple compression stages generally allows for a significant enhancement in performance, attributable to the overall substantial cooling and reduced work.Elevating pressure across all cycles leads to an increase in oxygen production over a single cycle.Figure 9 presents the relationship between the liquid oxygen fraction in the air and one liquefaction cycle.As evident from the graph, the utilization of multiple compression stages generally allows for a significant enhancement in performance, attributable to the overall substantial cooling and reduced work.Elevating pressure across all cycles leads to an increase in oxygen production over a single cycle.
Figure 10 presents the specific energy consumption per ton of liquid air.According to the data provided in [10], the electricity consumption in LAES systems amounts to 163-297 kWh/ton of liquid air, or 0.163-0.297kWh/kg of liquid air.According to the research conducted in the studied cycle, the maximum value stands at 257 kWh/ton of liquid air, while the minimum is 55 kWh/kg of liquid air.Notably, the increase in pressure within the cycle insignificantly influences cases involving the use of ORC cycles.In their absence, a substantial amount of electrical energy is expended.The cost of electrical energy was computed based on the average electricity cost in Kazakhstan for legal entities.Based on calculations, the average cost of 1 kg of liquid air is estimated to range from USD 7.5 to 10. Figure 10 presents the specific energy consumption per ton of liquid air.According to the data provided in [10], the electricity consumption in LAES systems amounts to 163-297 kWh/ton of liquid air, or 0.163-0.297kWh/kg of liquid air.According to the research conducted in the studied cycle, the maximum value stands at 257 kWh/ton of liquid air, while the minimum is 55 kWh/kg of liquid air.Notably, the increase in pressure within the cycle insignificantly influences cases involving the use of ORC cycles.In their absence, a substantial amount of electrical energy is expended.The cost of electrical energy was computed based on the average electricity cost in Kazakhstan for legal entities.Based on calculations, the average cost of 1 kg of liquid air is estimated to range from USD 7.5 to 10. Figure 11 shows the average thermal efficiencies of the ORC cycle calculated using formula 6.To calculate the efficiency, the energy of the flow R11 after the heat exchanger  Figure 10 presents the specific energy consumption per ton of liquid air.According to the data provided in [10], the electricity consumption in LAES systems amounts to 163-297 kWh/ton of liquid air, or 0.163-0.297kWh/kg of liquid air.According to the research conducted in the studied cycle, the maximum value stands at 257 kWh/ton of liquid air, while the minimum is 55 kWh/kg of liquid air.Notably, the increase in pressure within the cycle insignificantly influences cases involving the use of ORC cycles.In their absence, a substantial amount of electrical energy is expended.The cost of electrical energy was computed based on the average electricity cost in Kazakhstan for legal entities.Based on calculations, the average cost of 1 kg of liquid air is estimated to range from USD 7.5 to 10. Figure 11 shows the average thermal efficiencies of the ORC cycle calculated using formula 6.To calculate the efficiency, the energy of the flow R11 after the heat exchanger Figure 11 shows the average thermal efficiencies of the ORC cycle calculated using formula 6.To calculate the efficiency, the energy of the flow R11 after the heat exchanger was taken as the heat source.As can be seen from the figure, the average efficiency of ORC 1 cycle is 12.96%, while ORC 2 is 8.78%.This is due to the fact that the water temperature after the compressors is higher.After the expanders, the temperature of the heating water is lower.In general, the data obtained are consistent with the data presented in [41].
was taken as the heat source.As can be seen from the figure, the average efficiency o 1 cycle is 12.96%, while ORC 2 is 8.78%.This is due to the fact that the water temp after the compressors is higher.After the expanders, the temperature of the heating is lower.In general, the data obtained are consistent with the data presented in [41

Discussion
This study examined the possibility of modifying the basic LAES scheme us organic Rankine cycle, as well as the possibility of generating hot water for supply heating system.Based on the analysis, the following conclusions can be drawn:

Discussion
This study examined the possibility of modifying the basic LAES scheme using the organic Rankine cycle, as well as the possibility of generating hot water for supply to heating system.Based on the analysis, the following conclusions can be drawn:

Figure 2 .
Figure 2. Conceptual diagram of the investigated setup and cases for study.

Figure 2 .
Figure 2. Conceptual diagram of the investigated setup and cases for study.Figure 2. Conceptual diagram of the investigated setup and cases for study.

Figure 2 .
Figure 2. Conceptual diagram of the investigated setup and cases for study.Figure 2. Conceptual diagram of the investigated setup and cases for study.

Figure 5 .
Figure 5. Dependency of electricity generation on air pressure.

Figure 5 .
Figure 5. Dependency of electricity generation on air pressure.

Figure 6 .
Figure 6.Dependence of thermal energy generation on variation in air pressure downstream of the compressor.

Figure 7 .
Figure 7. Thermal and electrical load of Almaty city.

Figure 6 .
Figure 6.Dependence of thermal energy generation on variation in air pressure downstream of the compressor.

Sustainability 2024 , 15 Figure 6 .
Figure 6.Dependence of thermal energy generation on variation in air pressure downstream of the compressor.

Figure 7 .
Figure 7. Thermal and electrical load of Almaty city.Figure 7. Thermal and electrical load of Almaty city.

Figure 7 .
Figure 7. Thermal and electrical load of Almaty city.Figure 7. Thermal and electrical load of Almaty city.

Figure 8 .
Figure 8. Dependency of round-trip efficiency on air pressure downstream of the compressor.

Figure 8 .
Figure 8. Dependency of round-trip efficiency on air pressure downstream of the compressor.

Figure 9 .
Figure 9. Dependency of liquid fraction per cycle on air pressure downstream of the compressor.

Figure 10 .
Figure 10.Dependency of specific electricity consumption and cost of 1 kg of liquid fuel (left) on pressure variation.

Figure 9 .
Figure 9. Dependency of liquid fraction per cycle on air pressure downstream of the compressor.

Figure 9 .
Figure 9. Dependency of liquid fraction per cycle on air pressure downstream of the compressor.

Figure 10 .
Figure 10.Dependency of specific electricity consumption and cost of 1 kg of liquid fuel (left) on pressure variation.

Figure 10 .
Figure 10.Dependency of specific electricity consumption and cost of 1 kg of liquid fuel (left) on pressure variation.
-Studies indicate that specific energy consumption for producing a ton of liq varies from 55 to 257 kWh/ton.Implementing a scheme with two organic R cycle (ORC) cycles can reduce electricity consumption to approximately kWh/ton; -It was demonstrated that in Case 3, increasing the pressure from 50 to 190 ba an increase in liquefaction efficiency from 15% to 23%.Conversely, for the othe this figure decreased; -The round-trip efficiency (RTE) of the cycle is significantly influenced by the p downstream of the compressors.Generally, increasing the pressure resul decrease in RTE.This decrease is particularly pronounced in Case 3 compared other cases; -An increase in air pressure in the compressor results in increased produc thermal energy.This effect arises due to the elevation in air pressure, w intermediate cooling, which leads to elevated air temperatures.Consequent results in greater water heating, subsequently contributing to the heating network water.The maximum thermal energy value is attained at a pressure bar, equating to 5.0 thousand GJ per month.The minimum value occurs at amounting to 2.1 thousand GJ.

-
Studies indicate that specific energy consumption for producing a ton of liquid air varies from 55 to 257 kWh/ton.Implementing a scheme with two organic Rankine cycle (ORC) cycles can reduce electricity consumption to approximately 50-55 kWh/ton; -It was demonstrated that in Case 3, increasing the pressure from 50 to 190 bar led to an increase in liquefaction efficiency from 15% to 23%.Conversely, for the other cases, this figure decreased; -The round-trip efficiency (RTE) of the cycle is significantly influenced by the pressure downstream of the compressors.Generally, increasing the pressure results in a decrease in RTE.This decrease is particularly pronounced in Case 3 compared to the other cases; -An increase in air pressure in the compressor results in increased production of thermal energy.This effect arises due to the elevation in air pressure, without intermediate cooling, which leads to elevated air temperatures.Consequently, this results in greater water heating, subsequently contributing to the heating of the network water.The maximum thermal energy value is attained at a pressure of 190 bar, equating to 5.0 thousand GJ per month.The minimum value occurs at 50 bar, amounting to 2.1 thousand GJ.

Table 1 .
Types of EST.