The Environmental Impacts of Bar Soap Production: Uncovering Sustainability Risks with LCA Analysis

: Washing bar soap is widely used and vital in everyday life, especially in developing countries where demand is increasing due to population expansion. However, the production and use of washing bar soap have negative impacts on the environment, and the sustainability of soap packaging is also a concern. This research focuses on measuring the environmental effects of the production phase of washing bar soap while accounting for the differences in soap consumption across brands and consumer behavior during the use phase. The research aims to quantify the ecological burden caused by the production and use of 1 kg of bar soap through a Life Cycle Assessment (LCA) that follows ISO 14040 and 14044 standards. This study also addresses the resource-intensive aspect of soap packaging, particularly plastic packaging, and offers sustainability solutions through circular economy principles. GaBi v8.0 software is used to evaluate various environmental performance indicators, and the results show that eutrophication has the highest burden on the environment compared to other categories. This study highlights the importance of consumer behavior in reducing the environmental impact of washing bar soap, as the use stage of washing bar soap has the most signiﬁcant impact in most categories.


Introduction
Washing bar soap is a commonly used consumer product and an integral part of daily life. With the increase in population and its impact on the supply chain of fast-moving consumer goods, the demand for washing bar soap has seen a significant rise, particularly in developing nations. In India, handwashing continues to be the most common method for washing clothes, accounting for a substantial 74% of laundry-care sales [1]. However, the usage of bar soap poses a challenge in regions with water scarcity, such as the Indian state of Rajasthan, as it is highly water-intensive [2].
While a previous study assessed the environmental impact of washing machines, bar soaps are still predominantly used in households in heavily populated countries such as India [3]. Moreover, the laundry process heavily relies on consumer behavior and the type of fabric. The soap market in India alone was estimated at USD 2.9 billion in FY2020 and is projected to surpass USD 4.4 billion by FY2026, primarily driven by the emphasis on consistent hygiene and the growing spending power of customers [4]. The outbreak of the COVID-19 pandemic has further escalated the intensity of washing and prompted In India, being a highly cost-sensitive market, local companies offering inexpensive soaps dominate a significant market share. According to a report published in March 2017 by The Economic Times, a leading Indian newspaper, big FMCG brands such as Hindustan Unilever, Procter and Gamble, and Nirma have lost considerable market share to local players since 2014 [1]. This trend raises concerns, as companies that prioritize affordability may prioritize profitability over sustainability [28]. Limited literature is available that highlights the environmental impacts throughout the life cycle of soap, including its chemical constituents and packaging.
Packaging design modifications have been found to reduce the environmental impact of products [29]. However, there is a lack of literature on the factors influencing retailers' efforts to improve product packaging. The study by Gustavo, Jr. et al. [29] indicates that financial benefits for supermarkets and suppliers serve as the primary motivators for packaging redesign, resulting in ecological benefits as well. Furthermore, Giagnorio et al. [11] observed that detergent manufacture significantly impacts the environment, particularly in relation to other impact categories. The contribution of detergents to the overall impacts of laundry processes is crucial, and addressing detergent use and release is vital for reducing the ecological burdens of the laundering industry. The addition of membrane arrangements to current laundry systems shows promising environmental advancements, with potential reductions of up to 50% in total impacts. Therefore, assessing the environmental impacts of bar soap and considering the use of renewable energy sources, such as biofuels, in water-intensive processes are essential sustainability considerations [30].
According to Patel et al. [31], a partial Life Cycle Inventory (LCI) revealed that in 1996, fossil CO 2 emissions from significant surfactant production in Germany accounted for 1.5 million tonnes, only a small percentage of the total chemical industry emissions of 125 million tonnes, including feedstock energy equivalents. However, other research suggests that the cleaning process contributes to 60-80% of a surfactant's overall CO 2 emissions during its life cycle. Lowering washing temperatures in Germany alone could reduce emissions by up to 40% during the usage period, while energy savings could potentially decrease CO 2 emissions by 25-30% throughout the product's life cycle. Such potential reductions in emissions are more significant than the saving potential resulting from completely replacing petroleum-based chemical surfactants, which is estimated to be approximately 20%. Furthermore, Mohanraj et al. [32] studied the relationship between the washing temperature and the overall energy used during the complete washing process. They concluded that lower washing temperatures reduced energy consumption while maintaining efficient cleaning performance.
In conclusion, the life cycle of bar soap, from its production to its use and disposal, has significant environmental impacts. Assessing and understanding these impacts is crucial for developing strategies and practices that promote sustainable soap manufacturing. This study aims to fill the research gap by conducting a comprehensive LCA of bar soap in the Indian context, evaluating its environmental performance throughout the entire value chain. The findings will contribute to the knowledge base on sustainable manufacturing practices, enabling soap manufacturers to make informed decisions and take necessary measures to minimize environmental harm. The next section will present the methodology used for conducting the life cycle assessment of bar soap production and its associated environmental impacts.

Data Collection and Assumptions
The research focused on soap produced by a well-known soap manufacturer based in Jaipur, Rajasthan, which requested anonymity. The soap is sold as a 170 g bar or as a pack of six 1-kg bars wrapped in polythene packs. The primary ingredient is a sodium salt derived from vegetable palm oil, with water, sodium silicate, sodium chloride, a dye for color, and fragrance as other ingredients.

Product Life Cycle
Various environmental indicators related to soap were quantified by using a product LCI obtained from the soap manufacturer. The functional unit used for evaluation was one kilogram of soap, and the analysis focused on the different stages of the product's life cycle, which are presented in Table 2.

Saponification
In the soap production or the saponification process, esters of fatty acids are hydrolyzed, and the resulting soap is present in a colloidal form. It is precipitated by the addition of normal salt, i.e., sodium chloride. Only soaps made of sodium and potassium salts are soluble in water and are therefore used for cleaning purposes. The data obtained from the soap manufacturing industry were checked and balanced using the theory of saponification reaction [32].

Manufacturing and Distribution
The soap bar is produced in multiple stages, as explained in subsequent sections. The distribution of manufactured soap is approximately within a 200 km radius from the manufacturing plant. The manufacturing by-product, crude glycerol, is sent for refining and is not considered within the system boundary of the analysis.

Product Use and Disposal
Eventually, the soap is consumed by consumers for laundry cleaning. This is an intense water-consuming process, and the water is usually provided by a local supplier. The grey water produced after laundry cleaning is typically dumped either in landfills or nearby water bodies through gutters. The polyethylene packaging used for wrapping bar soap is generally discarded and goes to the landfill. To determine the amount of soap consumed, a sample population was surveyed, and it was found that, on average, 5.67 gm of soap is consumed per kg of cloth, and water consumption is equivalent to 0.9 m 3 for a complete month. However, these data are sample values, and in reality they may differ, as the washing process is entirely dependent on consumers' behavior. Furthermore, since the grey water contents are unknown, the data fed into the software use the analysis conducted by Mohamed et al. [33].

Methodology
The LCA of the bar soap is carried out as per the ISO 14040/44, 2006 [8,9] with the help of mid-point CML methodology. In this study, a functional unit is one kilogram of a washing bar soap during production. In the case of use phase impact assessment, the functional unit changes, and it is calculated as the amount of soap required to completely wash a given weight of stained clothes. The methodology used for impact calculation is CML 2016. As LCA is a scientific methodology standardized for the systematic analysis of mass and energy flows associated with the life cycle of a product, service, or manufacturing process system, the methodology used in this study follows the ISO 14040, 2006 [8] framework of LCA. To conduct the analysis, a boundary or perimeter was established, and is illustrated in Figure 1.
The system boundary and geographical scope include the production/extraction of raw materials for the bar soap, procurement of raw materials, production of washing bar soaps, packaging of bar soaps, distribution of bar soaps in the market, use phase in private households (washing process), end-of-life of soap packets, and background processes such as freshwater and electricity supply. Exclusions are the infrastructure and establishments of the production facility, human labor, in-plant transportation of materials, delivery of The system boundary and geographical scope include the production/extraction of raw materials for the bar soap, procurement of raw materials, production of washing bar soaps, packaging of bar soaps, distribution of bar soaps in the market, use phase in private households (washing process), end-of-life of soap packets, and background processes such as freshwater and electricity supply. Exclusions are the infrastructure and establishments of the production facility, human labor, in-plant transportation of materials, delivery of the product to the consumer, recovery of used products including energy recovery, and environmental impacts of wastewater treatment.

Manufacturing Process
Soap production involves various stages of processes. In this study, soap is manufactured in four stages: preparation of primary soap mix, preparation of secondary soap mix, continuous soap production, and packing of produced bar soaps.
In the primary soap mix production stage, caustic soda, also known as lye, at 50% concentration v/v is mixed with blended acid oil and fats, which is a by-product of the vegetable oil refining process [34]. The mixture is regularly blended with the addition of water to achieve the desired consistency. Then the mixture is heated by a stream of hot steam at 150 °C passing through the heat exchanger, partially processing the soap mixture for the next stage of production.
After 24 h of curing, this mix is added to Sodium Silicate, which gives firmness to the soap; common salt, which separates out the glycerol from the mix; water, to give the desired moisture level and flowability during further processes; fragrance; and dyes to obtain the desired trade color. The precipitated glycerol (after adding the common salt) is crude in nature, and pure glycerin is sent for extraction.
This mixture is dropped directly over a floater (a cylindrical rotating drum inside which water circulates, hence acting as a heat exchanger). The floater is accompanied by a knife-edge plate that helps spread the mixture over the floater, reducing the temperature. Further, it is passed through a die, which makes the noodles that are then passed over a three-roll mill, which makes thin sheets of soap. The rolled soap is then passed through a die, making a continuous soap ready to be cut into pieces and packaged.

Life Cycle Inventory
The complete LCI is presented in Table 2. Initially, a thorough understanding of the saponification process was obtained. Subsequently, a questionnaire was prepared to collect data for each stage/process of production, in accordance with the established system

Manufacturing Process
Soap production involves various stages of processes. In this study, soap is manufactured in four stages: preparation of primary soap mix, preparation of secondary soap mix, continuous soap production, and packing of produced bar soaps.
In the primary soap mix production stage, caustic soda, also known as lye, at 50% concentration v/v is mixed with blended acid oil and fats, which is a by-product of the vegetable oil refining process [34]. The mixture is regularly blended with the addition of water to achieve the desired consistency. Then the mixture is heated by a stream of hot steam at 150 • C passing through the heat exchanger, partially processing the soap mixture for the next stage of production.
After 24 h of curing, this mix is added to Sodium Silicate, which gives firmness to the soap; common salt, which separates out the glycerol from the mix; water, to give the desired moisture level and flowability during further processes; fragrance; and dyes to obtain the desired trade color. The precipitated glycerol (after adding the common salt) is crude in nature, and pure glycerin is sent for extraction.
This mixture is dropped directly over a floater (a cylindrical rotating drum inside which water circulates, hence acting as a heat exchanger). The floater is accompanied by a knife-edge plate that helps spread the mixture over the floater, reducing the temperature. Further, it is passed through a die, which makes the noodles that are then passed over a three-roll mill, which makes thin sheets of soap. The rolled soap is then passed through a die, making a continuous soap ready to be cut into pieces and packaged.

Life Cycle Inventory
The complete LCI is presented in Table 2. Initially, a thorough understanding of the saponification process was obtained. Subsequently, a questionnaire was prepared to collect data for each stage/process of production, in accordance with the established system boundary. The questionnaire for data collection was reviewed and revised to ensure that it covered all necessary inputs and outputs, and that data positions were accurately interpreted and reported in a consistent and complete manner. Once the data were collected in the questionnaire, essential checks were conducted on the mass and energy balances. In instances where information was incomplete, estimations were made based on data from the literature, and this was incorporated into the dataset.

Modeling on Software
To gather information for this study, a questionnaire was prepared and given to the soap manufacturing plant due to the lack of information available in the literature. The questionnaire was designed to collect input and output data, and only material flows greater than 1% of the total mass flow or greater than 1% of the total primary energy input were included in the system and model used to calculate elementary flows. The quality of the data used in this study is crucial for achieving the intended application and ensuring the reliability of the study. The LCI data quality for modeling the life cycle stages of washing bar soaps was evaluated based on ISO 14044 [9]. Primary data were used where possible, and the GaBi version 8 professional database was used for upstream LCA data. A model was then prepared using the GaBi software based on the LCI, and the cradle-to-grave LCA model of washing bar soap is illustrated in Figure 2.
in the questionnaire, essential checks were conducted on the mass and energy balances. In instances where information was incomplete, estimations were made based on data from the literature, and this was incorporated into the dataset.

Modeling on Software
To gather information for this study, a questionnaire was prepared and given to the soap manufacturing plant due to the lack of information available in the literature. The questionnaire was designed to collect input and output data, and only material flows greater than 1% of the total mass flow or greater than 1% of the total primary energy input were included in the system and model used to calculate elementary flows. The quality of the data used in this study is crucial for achieving the intended application and ensuring the reliability of the study. The LCI data quality for modeling the life cycle stages of washing bar soaps was evaluated based on ISO 14044 [9]. Primary data were used where possible, and the GaBi version 8 professional database was used for upstream LCA data. A model was then prepared using the GaBi software based on the LCI, and the cradle-tograve LCA model of washing bar soap is illustrated in Figure 2.  Table 3 shows the life cycle environmental impacts of washing bar soap production, packaging, and use phases based on the results obtained from GaBi v8.0. The chart is followed by a detailed discussion highlighting hotspots. It is important to note that the impact values shown in Table 3 are for 1 kg of soap production and consumption. Figure 3 illustrates the contribution of each subsystem to one kg of washing bar soap production. It can be observed that subsystems such as preparation of PSM and preparation of SSM  Table 3 shows the life cycle environmental impacts of washing bar soap production, packaging, and use phases based on the results obtained from GaBi v8.0. The chart is followed by a detailed discussion highlighting hotspots. It is important to note that the impact values shown in Table 3 are for 1 kg of soap production and consumption. Figure 3 illustrates the contribution of each subsystem to one kg of washing bar soap production. It can be observed that subsystems such as preparation of PSM and preparation of SSM have the most significant impact on environmental indicators such as ODP, TEP, HTP, BWC, EP, FE, and GWP.

Abiotic Depletion Potential
The method used to estimate abiotic resource usage includes the extraction of metals, scarce minerals, and fossil fuels. The total impact of the antimony equivalent (Sb-Eq) is 10.28 × 10 −8 kg, with the majority contributed during the continuous bar soap production phase, as shown in Table 3. In contrast, the packaging phase has the least impact on ADP, with a value of 3.39 × 10 −11 , which is a thousand times smaller than that of continuous bar soap production, as illustrated in Figure 4. The use phase does not have an impact on ADP as the use of soap mainly leads to eutrophication in the waterbody.

Impact Profile
Lowest Highest

Abiotic Depletion Potential
The method used to estimate abiotic resource usage includes the extraction of metals, scarce minerals, and fossil fuels. The total impact of the antimony equivalent (Sb-Eq) is 10.28 × 10 −8 kg, with the majority contributed during the continuous bar soap production phase, as shown in Table 3. In contrast, the packaging phase has the least impact on ADP, with a value of 3.39 × 10 −11 , which is a thousand times smaller than that of continuous bar soap production, as illustrated in Figure 4. The use phase does not have an impact on ADP as the use of soap mainly leads to eutrophication in the waterbody.

Acidification Potential
AP refers to the release of acidic gases or emissions that can react with moisture in the air, soil, or water, changing the pH of natural ecosystems and man-made environments. The main sources of acidifying agents are agriculture and fossil fuel combustion, with SO2, NOx, and ammonia being the primary agents. Acidification potential is determined by the contributions of SO2, NOx, HCl, NH3, and HF to the formation of H+ ions, and it is measured in kg SO2 equivalents. The value for this impact category is 4.68 × 10 −4g SO2-Equiv, with the major contribution coming from the preparation of the secondary soap phase (~47%) and continuous bar production process (27.56%). Again, no measurable effect seems to be generated during the use phase. Figure 5 shows the acidification potential (AP) in each subsystem.

Acidification Potential
AP refers to the release of acidic gases or emissions that can react with moisture in the air, soil, or water, changing the pH of natural ecosystems and man-made environments. The main sources of acidifying agents are agriculture and fossil fuel combustion, with SO 2 , NO x , and ammonia being the primary agents. Acidification potential is determined by the contributions of SO 2 , NO x , HCl, NH 3 , and HF to the formation of H+ ions, and it is measured in kg SO 2 equivalents. The value for this impact category is 4.68 × 10 −4 -g SO 2 -Equiv, with the major contribution coming from the preparation of the secondary soap phase (~47%) and continuous bar production process (27.56%). Again, no measurable effect seems to be generated during the use phase. Figure 5 shows the acidification potential (AP) in each subsystem.

Eutrophication Potential
EP is the result of essential nutrients being released into the water, air, and soil. Nitrates and phosphates are necessary for life, but excessive levels of nutrients in aquatic environments can cause algae to grow rapidly, reduce oxygen levels underwater, and harm local water sources and habitats. Over-fertilization of soil is associated with increased biomass growth and changes in the composition of organisms within the ecosystem. The results of eutrophication potential are expressed in kg phosphate (PO43-) equivalents (Gabi, 2012), and the total for this study is 1.83 × 10 −4 kg Phosphate-Equivalent. The major contributors to eutrophication potential are the use phase of bar soap (76.5%) and the preparation of primary soap mix (13.67%). This is because greywater is produced during the use phase, which contributes to eutrophication. Figure 6 illustrates the EP in each subsystem.

Eutrophication Potential
EP is the result of essential nutrients being released into the water, air, and soil. Nitrates and phosphates are necessary for life, but excessive levels of nutrients in aquatic environments can cause algae to grow rapidly, reduce oxygen levels underwater, and harm local water sources and habitats. Over-fertilization of soil is associated with increased biomass growth and changes in the composition of organisms within the ecosystem. The results of eutrophication potential are expressed in kg phosphate (PO43-) equivalents (Gabi, 2012), and the total for this study is 1.83 × 10 −4 kg Phosphate-Equivalent. The major contributors to eutrophication potential are the use phase of bar soap (76.5%) and the preparation of primary soap mix (13.67%). This is because greywater is produced during the use phase, which contributes to eutrophication. Figure 6 illustrates the EP in each subsystem.

Eutrophication Potential
EP is the result of essential nutrients being released into the water, air, and soil. Nitrates and phosphates are necessary for life, but excessive levels of nutrients in aquatic environments can cause algae to grow rapidly, reduce oxygen levels underwater, and harm local water sources and habitats. Over-fertilization of soil is associated with increased biomass growth and changes in the composition of organisms within the ecosystem. The results of eutrophication potential are expressed in kg phosphate (PO43-) equivalents (Gabi, 2012), and the total for this study is 1.83 × 10 −4 kg Phosphate-Equivalent. The major contributors to eutrophication potential are the use phase of bar soap (76.5%) and the preparation of primary soap mix (13.67%). This is because greywater is produced during the use phase, which contributes to eutrophication. Figure 6 illustrates the EP in each subsystem.

Global Warming Potential
GWP is the sum of the emissions of CO 2 and other greenhouse gases (N 2 O, CH 4 , and VOCs) into the atmosphere. It estimates the combined impacts of these gases on the global environment and is expressed in kg CO 2 equivalents, spanning a time horizon of 100 years (Gabi, 2012). Figure 7 shows that a total of 7.71 × 10 −2 kg CO 2 -Equivalent is created during the production and use phase of bar soap, with the major contribution coming from the primary soap production of bar soap, accounting for 58.16%. It is evident that the production of PSM consumes a lot of heat via steam, hence having a higher GWP value than other processes. environment and is expressed in kg CO2 equivalents, spanning a time horizon of 100 years (Gabi, 2012). Figure 7 shows that a total of 7.71 × 10 −2 kg CO2-Equivalent is created during the production and use phase of bar soap, with the major contribution coming from the primary soap production of bar soap, accounting for 58.16%. It is evident that the production of PSM consumes a lot of heat via steam, hence having a higher GWP value than other processes.

Human Toxicity Potential
HTP is a quantified measure that takes into account both the intrinsic toxicity of a chemical compound and its potential dosage, representing the potential danger of a chemical unit released into the atmosphere. It is used in a life cycle assessment (LCA) or the toxic release inventory (TRI) to determine the weight and average emissions as a reference compound. Emissions can be assessed in terms of benzene equivalence for carcinogens and toluene equivalents for non-carcinogens (Gabi, 2012). This parameter is important as it signifies the potential threat to human health in a comparative manner. It can be seen from Figure 8 that the total HTP is 5.83 × 10 −2 kg DCB equivalent, with PSM production alone contributing 4.90 × 10 −2 (84.05%) kg DCB equivalent. It is also observed that PSM production has a higher impact value in many of the environmental indicators.

Human Toxicity Potential
HTP is a quantified measure that takes into account both the intrinsic toxicity of a chemical compound and its potential dosage, representing the potential danger of a chemical unit released into the atmosphere. It is used in a life cycle assessment (LCA) or the toxic release inventory (TRI) to determine the weight and average emissions as a reference compound. Emissions can be assessed in terms of benzene equivalence for carcinogens and toluene equivalents for non-carcinogens (Gabi, 2012). This parameter is important as it signifies the potential threat to human health in a comparative manner. It can be seen from Figure 8 that the total HTP is 5.83 × 10 −2 kg DCB equivalent, with PSM production alone contributing 4.90 × 10 −2 (84.05%) kg DCB equivalent. It is also observed that PSM production has a higher impact value in many of the environmental indicators.

Photochemical Ozone Creation Potential
POCP is a measure of the potential for volatile organic compounds (VOCs) to contribute to photochemical ozone formation at the local level. Ground-level ozone, which

Photochemical Ozone Creation Potential
POCP is a measure of the potential for volatile organic compounds (VOCs) to contribute to photochemical ozone formation at the local level. Ground-level ozone, which has an impact on flora and fauna, is generated through photochemical oxidation, a reaction that occurs when NOx and VOCs are exposed to UV radiation. POCP is expressed in kg ethylene (C 2 H 4 ) equivalents (Gabi, 2012). Once again, it is observed that the production of PSM is mainly responsible for POCP, accounting for a total of 4.27 × 10 −5 kg ethene equivalent, which is 72.87% of the total 5.86 × 10 −5 kg ethene equivalent. Figure 9 shows the photochemical ozone creation potential (POCP) in each subsystem.

Photochemical Ozone Creation Potential
POCP is a measure of the potential for volatile organic compounds (VOCs) to contribute to photochemical ozone formation at the local level. Ground-level ozone, which has an impact on flora and fauna, is generated through photochemical oxidation, a reaction that occurs when NOx and VOCs are exposed to UV radiation. POCP is expressed in kg ethylene (C2H4) equivalents (Gabi, 2012). Once again, it is observed that the production of PSM is mainly responsible for POCP, accounting for a total of 4.27 × 10 −5 kg ethene equivalent, which is 72.87% of the total 5.86 × 10 −5 kg ethene equivalent. Figure 9 shows the photochemical ozone creation potential (POCP) in each subsystem.

Ozone Layer Depletion Potential
The ODP is a measure of the potential for emissions to deplete the stratospheric ozone layer and increase the ultraviolet radiation reaching the Earth's surface. Chlorofluorocarbons (CFCs) and chlorinated hydrocarbons (HCs) are the primary substances that contribute to ozone layer depletion. ODP is expressed in kg CFC-11 (or R-11) equivalents and its impact is felt globally (Gabi, 2012). Figure 10 shows the ozone layer depletion potential (ODP) in each subsystem. The results of this indicator show that the ODP impact is mainly due to PSM production, accounting for 99.99% of the total impact.

Ozone Layer Depletion Potential
The ODP is a measure of the potential for emissions to deplete the stratospheric ozone layer and increase the ultraviolet radiation reaching the Earth's surface. Chlorofluorocarbons (CFCs) and chlorinated hydrocarbons (HCs) are the primary substances that contribute to ozone layer depletion. ODP is expressed in kg CFC-11 (or R-11) equivalents and its impact is felt globally (Gabi, 2012). Figure 10 shows the ozone layer depletion potential (ODP) in each subsystem. The results of this indicator show that the ODP impact is mainly due to PSM production, accounting for 99.99% of the total impact.

Primary Energy Demand
The PED refers to the energy supplied directly from natural sources, such as the hydrosphere, atmosphere, geosphere, and other sources, without any conversion or transformation. It encompasses both renewable and non-renewable energy sources, such as so-  Figure 10. Ozone layer depletion potential (ODP) in each subsystem.

Primary Energy Demand
The PED refers to the energy supplied directly from natural sources, such as the hydrosphere, atmosphere, geosphere, and other sources, without any conversion or transformation. It encompasses both renewable and non-renewable energy sources, such as solar power, wind power, hydroelectricity, biomass, biofuels, coal, crude oil, natural gas, and uranium. The measurement of primary energy demand is expressed in mega joules (MJ) (Gabi, 2012). This indicator indirectly impacts many other environmental indicators, as primary energy is usually generated via power plants, which have their own ecological impacts. Figure 11 indicates the primary energy demand in each subsystem. In bar soap production, the preparation of SSM consumes the highest amount of energy, accounting for 3.49 × 10 4 J (~48%) of the total PED of 7.28 × 10 4 J. This is because the process includes powerful amalgamators.

Bluewater Consumption
As the field of freshwater impact assessment is still evolving, it is premature to suggest specific life cycle impact assessment methods. Therefore, it is recommended to measure net water consumption, also known as consumptive use, at the inventory level (Gabi, 2012). Bluewater refers to fresh surface and groundwater, such as that found in lakes, rivers, and aquifers. The highest amount of blue water consumption occurs during the use phase, with an average of 0.9 m 3 equivalent based on a survey, followed by PSM production, which accounts for 1.22 × 10 −1 m 3 equivalent.

Marine Aquatic Ecotoxicity Potential
MAEP refers to the effect of harmful substances on marine aquatic ecosystems. It is characterized using the USES 2.0 methodology [35], which describes the fate, exposure, and effects of toxic substances, adapted for use in LCAs. The impact is evaluated based on an infinite time horizon, also known as MAEP [36]. Figure 12 indicates the MAEP in each subsystem. The use phase of soap is very harmful to marine life. From the analysis, it is observed that 25.1 kg DCB equivalent is generated due to the use of a single kilogram of soap. The total amount of MAEP is 41.1 kg DCB equivalent.

Bluewater Consumption
As the field of freshwater impact assessment is still evolving, it is premature to suggest specific life cycle impact assessment methods. Therefore, it is recommended to measure net water consumption, also known as consumptive use, at the inventory level (Gabi, 2012). Bluewater refers to fresh surface and groundwater, such as that found in lakes, rivers, and aquifers. The highest amount of blue water consumption occurs during the use phase, with an average of 0.9 m 3 equivalent based on a survey, followed by PSM production, which accounts for 1.22 × 10 −1 m 3 equivalent.

Marine Aquatic Ecotoxicity Potential
MAEP refers to the effect of harmful substances on marine aquatic ecosystems. It is characterized using the USES 2.0 methodology [35], which describes the fate, exposure, and effects of toxic substances, adapted for use in LCAs. The impact is evaluated based on an infinite time horizon, also known as MAEP [36]. Figure 12 indicates the MAEP in each subsystem. The use phase of soap is very harmful to marine life. From the analysis, it is observed that 25.1 kg DCB equivalent is generated due to the use of a single kilogram of soap. The total amount of MAEP is 41.1 kg DCB equivalent.

Terrestrial Ecotoxicity Potential
TEP measures the impact of harmful substances on terrestrial ecosystems using the USES 2.0 methodology [35], which evaluates the fate, exposure, and effects of toxic substances in LCAs. The impact is assessed over an infinite time horizon and referred to as TEP [36]. Some researchers propose using greywater from laundry for gardening, but this can also contribute to terrestrial ecotoxicity. GaBi quantifies this indicator, with the use phase accounting for 99.99% of its impact. A sustainable solution could be to reduce the amount of soap or powder detergent used.

Freshwater Eutrophication
Freshwater eutrophication is the result of the inappropriate increase of macro and micronutrients, particularly nitrogen (N) and phosphorus (P), which leads to changes in species diversity and an increased production of biomass in aquatic and terrestrial ecosystems. This effect is characterized by a stoichiometric procedure applied to aquatic and terrestrial systems [36]. Figure 13 shows the freshwater eutrophication impact in each subsystem. As manual washing of laundry is highly dependent on consumer behavior, this indicator is affected by it. Therefore, the highest impact is observed in the use phase, with freshwater eutrophication of 4.59 × 10 −5 kg phosphate equivalent, which represents 98.5% of the total amount generated by the use of a kilogram of soap.

Terrestrial Ecotoxicity Potential
TEP measures the impact of harmful substances on terrestrial ecosystems using the USES 2.0 methodology [35], which evaluates the fate, exposure, and effects of toxic substances in LCAs. The impact is assessed over an infinite time horizon and referred to as TEP [36]. Some researchers propose using greywater from laundry for gardening, but this can also contribute to terrestrial ecotoxicity. GaBi quantifies this indicator, with the use phase accounting for 99.99% of its impact. A sustainable solution could be to reduce the amount of soap or powder detergent used.

Freshwater Eutrophication
Freshwater eutrophication is the result of the inappropriate increase of macro and micronutrients, particularly nitrogen (N) and phosphorus (P), which leads to changes in species diversity and an increased production of biomass in aquatic and terrestrial ecosystems. This effect is characterized by a stoichiometric procedure applied to aquatic and terrestrial systems [36]. Figure 13 shows the freshwater eutrophication impact in each subsystem. As manual washing of laundry is highly dependent on consumer behavior, this indicator is affected by it. Therefore, the highest impact is observed in the use phase, with freshwater eutrophication of 4.59 × 10 −5 kg phosphate equivalent, which represents 98.5% of the total amount generated by the use of a kilogram of soap.

Critical Discussion
This study quantified various environmental impacts across the identified system boundary and assessed them across different life cycle stages, ultimately identifying hotspots through the value chain of soap bar production. Eutrophication was found to have the highest burden on the environment compared to other categories. However, this 6.62x10 - 7 10 -8 5.

Critical Discussion
This study quantified various environmental impacts across the identified system boundary and assessed them across different life cycle stages, ultimately identifying hotspots through the value chain of soap bar production. Eutrophication was found to have the highest burden on the environment compared to other categories. However, this study faced certain limitations, such as a lack of information on part-level data or materials, which led to carrying out the analysis one level higher or considering closed proxies of uncertain information. Nevertheless, the research ensured that the overall data quality was high and represented the actual scenario by closely monitoring data quality considerations such as completeness, timeliness, consistency, and geographical references. Some environmental impact categories showed higher values compared to others, and hotspots were identified at the process and source level for these indicators.
The global warming potential results show that a total of 7.71 × 10 −2 kg CO 2 -Equiv. is created during the production and use phase of bar soap, with the major contribution from primary soap production of bar soap accounting for 58.16%. A similar result on GWP was obtained by Francke and Castro [12], and they found that from a life cycle perspective, the product use phase has the most significant environmental impacts of soap bars and impacts are also variable due to consumer habits. It is evident that the production of PSM consumes a lot of heat via steam, hence having a higher GWP value than other processes. Since this case study is based in Jaipur, Rajasthan, one possible reduction technique for GWP could be the simultaneous use of solar energy to generate steam, particularly in the summer season when the atmospheric temperature reaches as high as 48 • C [12].
In terms of blue water consumption, the highest amount comes during the use phase, which is 0.9 m 3 equivalent based on survey data, followed by the production of PSM with 1.22 × 10 −1 m 3 equivalent. To reduce blue water consumption, there is a need to educate people on sustainable options available for laundry washing [12,31]. This finding makes sense because, unlike petrochemical processes, which mostly use fossil fuels to meet energy needs, compounds made from vegetable oils use renewable energy sources. This means that both energy needs and the chance of global warming go down [37].
Eutrophication is a threat to marine life, and laundry water is one of the reasons for higher eutrophication in water bodies. As previously stated, laundry washing depends a lot on consumer behavior regarding soap and detergent consumption. Therefore, it is advisable to reduce too-frequent washing of laundry, especially if not necessary [32].
Terrestrial eco toxicity potential is caused by a high sodium adsorption rate resulting from the adsorption of laundry greywater into the soil when the greywater is not channeled to gutters and instead flows over a surface. A sustainable way to reduce this effect is to properly flush greywater instead of letting it spill over the soil surface [34].
Plastic packaging impacts are unknown because of the unavailability of the disposition of wrappers of soap bars. However, it is well known that the plastic packaging either goes to the landfill or is flushed to water bodies. A recent development in technologies has introduced a circular economy concept in which wealth can be created from waste [38,39]. The production of Syngas or pyrolysis fuel from waste plastics could be an alternative to waste minimization and could reduce the burden on the environment [40]. One of the companies in Tamil Nadu (India) packs their soaps in handwoven bamboo pouches. Another in Karnataka (India) wraps their soaps in banana fiber paper. A company in Maharashtra, India, utilizes the naked packaging approach for its soap products. This approach involves covering the soap with only a thin strip of recycled paper or kora cotton that has a label. The company has adopted this method due to the long decomposition time of plastics, which results in a buildup of plastic waste in landfills and oceans [41]. The company recognizes that this plastic waste not only harms the environment but also affects the wildlife that consume it. Hence it is advisable to use recycled paper or biogenic materials for packaging or, at least for the sake of sustainable packaging, the recycling of plastics should be carried out.

Conclusions and Outlook
The aim of this research was to evaluate the environmental impacts associated with the entire life cycle of washing bar soap, identify critical areas in the value chain for optimization, and propose sustainability recommendations based on the study's results. The research estimated several environmental effects throughout the system boundary that was established, evaluated the impacts at various phases of the life cycle, and eventually carried out a hotspot analysis. It was found that eutrophication had the greatest strain on the ecosystem when compared to the different categories. The present study is useful for soap manufacturer managers, policymakers, and researchers. In light of the findings of this study, managers can identify hotspots and develop strategies that minimize environmental impacts. Implications for policymakers are particularly essential as soap is a regularly used product, and a study of its environmental impact can help lawmakers to make eco-efficient and sustainable policies to ensure its long-term growth. To further expand this study, a global analysis could be conducted by considering various types of soap production including washing bar soap, bath soap, liquid detergent, and powder detergent. Future research could also explore the cradle-to-cradle system boundary and recycling benefits. Internal and external benchmarking of the value chain could be initiated, and productspecific LCAs could be performed for new generation soap products. While this study's findings demonstrate that an environmentally conscious society and national regulations can significantly reduce the environmental impact, the most significant change required is to raise consumer awareness and initiate individual efforts to decrease their environmental footprint. Therefore, the environmental impact of washing bar soap depends largely on the behavior of the consumers. Moreover, uncertainty analysis, which is essential to ensure accurate environmental assessment, should be conducted to provide reliable research results.
Future Scope: To further expand the study, a global analysis could be conducted by considering various types of soap production, including washing bar soap, bath soap, liquid detergent, and powder detergent. Future research could also explore the cradle-to-cradle system boundary and recycling benefits. Internal and external benchmarking of the value chain could be initiated, and product-specific LCAs could be performed for new-generation soap products. For future research, many tools, such as techno-economic, LCA, energy, and exergy studies, may be utilized to examine the sustainability of soap bars across their whole value chain. Each approach of assessing sustainability has advantages and disadvantages, therefore the best method relies on the study purpose, process complexity, and required level of precision. Overall, integrated sustainability assessment methodologies have the potential to produce more trustworthy and accurate outcomes than single approaches. It is worth noting that integrated strategies can also reduce the majority of the shortcomings of isolated procedures. Exergy-based assessments, particularly when supplemented with economic and environmental variables, can provide more useful indicators than other sustainability assessment tools. Exergy-based integrated techniques (exergoeconomic, exergoenvironmental, and exergoeconoenvironmental) can offer decision-makers information that exergy, techno-economic, and LCA analyses cannot [42]. These ideas can help academics and engineers construct a soap bar value chain that is both economically and environmentally sustainable. While this study's findings demonstrate that an environmentally conscious society and national regulations can significantly reduce environmental impacts, the most significant change required is to raise consumer awareness and initiate individual efforts to decrease their environmental footprint. Therefore, the environmental impact of washing bar soap depends largely on the behavior of the consumers. Moreover, uncertainty analysis, which is essential for proper environmental assessment, should be conducted to provide reliable research results.
Limitations: The information was gathered from the soap production plant on the basis of the prepared questionnaire because there was a lack of information accessibility from the literature. Moreover, this study faced certain limitations, such as a lack of information on part-level data or materials, which led to carrying out the analysis one level higher or considering closed proxies of uncertain information. Some limitations are:

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The site-specific emission factor for electricity is computed based on the contribution of electricity supplied from a power plant.

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The GaBi version 8: 2015 specific database is used for evaluating environmental emissions. The latest software database may produce variations in the results.

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This study is based on average data. In case of individual purchase decisions, the parameters influencing the results might differ from the assumed average data.

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The results are only valid for the geographical scope of this study (India). Different parameters strongly depend on the country or climatic conditions. Examples of those parameters are: electricity supply and consumer behavior (washing habits).

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For road transport, country-specific pollution norms are considered.

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The variation in consumer use of washing soap was not addressed in this study.
Implications: This study has several implications for soap manufacturer managers, policymakers, and researchers. In light of the findings of this study, managers can identify hotspots and develop strategies that minimize environmental impacts. Implications for policymakers are particularly essential, as soap is a regularly used product, and a study of its environmental impact can help lawmakers to make eco-efficient policies to ensure its long-term growth.

Conflicts of Interest:
The authors declare no conflict of interest. End-of-Life