Exhaust Gas Recirculation on a Nano-Coated Combustion Chamber of a Diesel Engine Fueled with Waste Plastic Oil

: Managing waste plastic is becoming a severe challenge. The industry and researchers have been looking at various opportunities in line with circular economy principles for effective plastic waste management. In that context, plastic waste valorization to oil as a substitute to fossil fuel has gained recent attention. In the literature, there exist few studies showing the use of oil derived from waste plastics in blends with other conventional fuels in compression ignition (CI) engines; however, studies on CI engines that use 100% waste-derived fuels are limited. Additionally, the exhaust gas recirculation (EGR) concepts and the use of nano-coated chambers (like pistons, valves and cylinders heads) have been gaining interest purely from the engine performance enhancement perspective in recent years. Therefore, this study investigates engine performance by combining exhaust gas from the EGR technique and waste plastic oil (WPO) as inputs, followed by thermal coatings in the CI engine chambers for performance enhancement. The experimental setup of the engine is developed, and the engine’s piston, valve and cylinder heads are coated with Al 2 O 3 -SiO 4 material. The CI engine’s energy, emission, and combustion characteristics are tested, followed by a scenario analysis compared with diesel-only fuel. The tested scenarios include a WPO + Al 2 O 3 -SiO 4 , WPO + Al 2 O 3 -SiO 4 + 10% EGR, and WPO + Al 2 O 3 -SiO 4 + 20% EGR. The results show that the piston crown’s thermal coating increased the combustion performance. Signiﬁcant impacts on the carbon monoxide, hydrocarbons, and smoke characteristics are observed for different %EGR rates. The results also showed that the cooled EGR engine has decreased nitric oxide emissions. Overall, the results show that WPO combined with exhaust gas could be a potential fuel for future CI engines.


Introduction
Among the various fuels, the demand for oil still exists in numerous sectors. As per the latest report by British Petroleum (BP), oil still holds the largest share of the planet's primary energy consumption, around 31.2%, followed by coal and natural gas [1]. This domination has both positive and negative effects [2]. For instance, oil usage is reliable for primary energy consumption and can provide affordable energy security, which could be a positive effect [2,3]. However, this comes with a severe environmental threat to the planet in the form of greenhouse gas emissions (GHG), which is a negative effect [2]. On a global level, the GHG emissions due to oil consumption keep increasing. Based on Global Carbon Project data, the GHG emissions from oil consumption drastically increased from 1750 (i.e., 9.35 million t) to 2020 (i.e., 13.98 billion t) [4]. This approximately indicates a +149,369% relative change between 1750 and 2020 [4]. Recently, many alternatives, including electricity from renewables and hydrogen, have evolved. Such alternatives are In line with this, Saravanan et al. investigated the performance of a partially stabilized zirconia (PSZ)-coated, low-heat-rejection CI engine with WPO and found that PSZ enhances the engine efficiency [25]. Though several experimental studies exist on WPO use as an alternative fuel, studies on 100% WPO with EGR and nano-coated CI engine chambers are not covered in the literature as per the author(s) knowledge [26][27][28][29][30]. Hence the use of WPO and EGR in line with the circular economy is proposed; see Figure 1. Hence, this study examines the exhaust gas circulation effect on a combustion chamber nano-coated with an Al2O3-SiO4-coated material. The article is structured as follows. Section 2 is the materials and methods, where the details of WPO preparation, engine setup and experimental procedure are given. In Section 3, results are provided, along with a discussion and comparison with literature. Section 4 draws conclusions.

Waste Plastic Oil Preparation
WPO is the chemical product of the decomposition process of organic substances by heating. Waste plastic was processed and converted into oil through electrical pyrolysis. An electrical heater at 450 watts heats the plastics. The electrical heater consists of a resistance that adjusts the heating rate by varying the voltage controller. In the present work, the waste plastic was cut into several pieces and made into small chips. The plastic chips were washed, dried and fed into a reactor vessel made of borosilicate material with 2 L capacity. The plastic was treated in the reactor at a temperature of 400 °C without oxygen, which was monitored using a K-type thermocouple. This pyrolysis process can also be used to produce liquid fuel similar to diesel. The pyrolysis products in the form of vapour were sent to a water-cooled condenser. The condensed liquid was collected as fuel. A double-tube condenser was installed at the outlet of the reactor to separate the gas and oil products. Water, at room temperature, was circulated around the condenser at a constant rate. After condensation, the gases were converted into liquid fuel and collected in the collection tank at the bottom. The schematic diagram of the pyrolysis process of waste plastics is shown in Figure 2.
The non-condensable gases were let out into the atmosphere. The WPO collected was crude in nature. For 1 kg of WPO, about 2.09 kg of plastic waste feedstock was required. The product yields from the process are WPO (50%), Pyro gas (40%) and char (10%). The heat energy required to convert the waste plastic into the products was around 7.8 MJ/kg. The residence time of the pyrolysis process was 90 min. The composition of WPO reconfirms and is comparable with the values available in the early research works. Since the The article is structured as follows. Section 2 is the materials and methods, where the details of WPO preparation, engine setup and experimental procedure are given. In Section 3, results are provided, along with a discussion and comparison with literature. Section 4 draws conclusions.

Waste Plastic Oil Preparation
WPO is the chemical product of the decomposition process of organic substances by heating. Waste plastic was processed and converted into oil through electrical pyrolysis. An electrical heater at 450 watts heats the plastics. The electrical heater consists of a resistance that adjusts the heating rate by varying the voltage controller. In the present work, the waste plastic was cut into several pieces and made into small chips. The plastic chips were washed, dried and fed into a reactor vessel made of borosilicate material with 2 L capacity. The plastic was treated in the reactor at a temperature of 400 • C without oxygen, which was monitored using a K-type thermocouple. This pyrolysis process can also be used to produce liquid fuel similar to diesel. The pyrolysis products in the form of vapour were sent to a water-cooled condenser. The condensed liquid was collected as fuel. A double-tube condenser was installed at the outlet of the reactor to separate the gas and oil products. Water, at room temperature, was circulated around the condenser at a constant rate. After condensation, the gases were converted into liquid fuel and collected in the collection tank at the bottom. The schematic diagram of the pyrolysis process of waste plastics is shown in Figure 2.
oil collected for this study was untreated, the WPO contains impu high volatile fractions of hydrocarbons. WPO was filtered by fabr by micron filter. The efficiency of the filtration is 99%.

Properties and Elemental Analysis
The analysis of the WPO was done to compare the thermo elemental composition of WPO with the standard diesel fuel; see to diesel, the specific gravity and calorific value of WPO were r and 4.73%, respectively. WPO has a higher kinematic viscosity more resistance to flow in the winter. The sulfur and ash conten spectively, for WPO; hence, there is a possibility of lower emissio fire points are observed to be more or less similar to diesel. WP elements when compared to diesel fuel. However, the other ele (H), oxygen (O), and nitrogen (N) are higher for WPO. The sulfu WPO, whereas in diesel, it is around 0.359.  The non-condensable gases were let out into the atmosphere. The WPO collected was crude in nature. For 1 kg of WPO, about 2.09 kg of plastic waste feedstock was required. The product yields from the process are WPO (50%), Pyro gas (40%) and char (10%). The heat energy required to convert the waste plastic into the products was around 7.8 MJ/kg. The residence time of the pyrolysis process was 90 min. The composition of WPO reconfirms and is comparable with the values available in the early research works. Since the oil collected for this study was untreated, the WPO contains impurities, dust, and low and high volatile fractions of hydrocarbons. WPO was filtered by fabric filter and again filtered by micron filter. The efficiency of the filtration is 99%.

Properties and Elemental Analysis
The analysis of the WPO was done to compare the thermophysical properties and elemental composition of WPO with the standard diesel fuel; see Table 1. When compared to diesel, the specific gravity and calorific value of WPO were reduced by about 0.595% and 4.73%, respectively. WPO has a higher kinematic viscosity than diesel, providing more resistance to flow in the winter. The sulfur and ash content is 6.95% and 3.76%, respectively, for WPO; hence, there is a possibility of lower emissions. The WPO's flash and fire points are observed to be more or less similar to diesel. WPO has lower carbon (C) elements when compared to diesel fuel. However, the other elements such as hydrogen (H), oxygen (O), and nitrogen (N) are higher for WPO. The sulfur (S) elements are zero in WPO, whereas in diesel, it is around 0.359.

Nano-Coated Combustion Chamber of Diesel Engine
The plasma spraying method primarily sprays molten material or thermal softening on a surface to provide a layer. The physical and chemical characteristics of imprudent ceramic powder Al2O 3 -SiO 4 combined with wear resistance, low friction coefficients, higher ionic conductivity, high hardness and low thermal conductance can make better engineering materials; see Table 2. The feed machine injects the cover material with a carrier gas in powder form. These particles melt and adhere as a coating onto the processed foundation material. The piston, cylinders and valves in use with the Al2O 3 -SiO 4 engine are shown in Figure 3.

Nano-Coated Combustion Chamber of Diesel Engine
The plasma spraying method primarily sprays molten material or thermal softening on a surface to provide a layer. The physical and chemical characteristics of imprudent ceramic powder Al2O3-SiO4 combined with wear resistance, low friction coefficients, higher ionic conductivity, high hardness and low thermal conductance can make better engineering materials; see Table 2. The feed machine injects the cover material with a carrier gas in powder form. These particles melt and adhere as a coating onto the processed foundation material. The piston, cylinders and valves in use with the Al2O3-SiO4 engine are shown in Figure 3.

Experimental Testing
The experimental setup is shown in Figure 4. It consists of a 4-stroke cylinder, constant speed, water-cooled, 16.5:1 compression ignition engine, and a generator loaded with variable power. The engine is rated at 200 bar with static injection timing of 23° BTDC. Before the engine started, a check was made of the stock inside the fuel tank, cooling water flow, and lubricant oil in the oil sump. The engine was started and heated. At rated speed, the engine speed is preserved-current and voltage measurements are used for the facility developed by the engine.

Experimental Testing
The experimental setup is shown in Figure 4. It consists of a 4-stroke cylinder, constant speed, water-cooled, 16.5:1 compression ignition engine, and a generator loaded with variable power. The engine is rated at 200 bar with static injection timing of 23 • BTDC. Before the engine started, a check was made of the stock inside the fuel tank, cooling water flow, and lubricant oil in the oil sump. The engine was started and heated. At rated speed, The visual temperature indicator thermocouple was not appropriate for calculating the cooling temperature of the water. A piezoelectric pressure sensor was used to measure the cylinder pressure. QROTECH's exhaust gas analyzer measured CO, NOx and HC. For different loads, the experiments have been repeated without maximum load.

Results and Discussion
The experimental results include the diesel engine's performance with 3 different fuel scenarios (WPO + Al2O3-SiO4, WPO + Al2O3-SiO4 + 10% EGR, and WPO + Al2O3-SiO4 + 20% EGR) compared with the standard diesel fuel. Three types of analysis, namely energy, emissions, and combustion, are carried out for each fuel scenario. As shown in Figure 5, multiple characteristics are observed for each fuel scenario under these three analyses.

Brake Thermal Efficiency (BTE)
The BTE results observed for the investigated CI engine under four different fuel use scenarios are presented in Figure 6. The BTE of the CI engine is a characteristic that The visual temperature indicator thermocouple was not appropriate for calculating the cooling temperature of the water. A piezoelectric pressure sensor was used to measure the cylinder pressure. QROTECH's exhaust gas analyzer measured CO, NO x and HC. For different loads, the experiments have been repeated without maximum load.

Results and Discussion
The experimental results include the diesel engine's performance with 3 different fuel scenarios (WPO + Al 2 O 3 -SiO 4 , WPO + Al 2 O 3 -SiO 4 + 10% EGR, and WPO + Al 2 O 3 -SiO 4 + 20% EGR) compared with the standard diesel fuel. Three types of analysis, namely energy, emissions, and combustion, are carried out for each fuel scenario. As shown in Figure 5, multiple characteristics are observed for each fuel scenario under these three analyses. The visual temperature indicator thermocouple was not appropriate for calculating the cooling temperature of the water. A piezoelectric pressure sensor was used to measure the cylinder pressure. QROTECH's exhaust gas analyzer measured CO, NOx and HC. For different loads, the experiments have been repeated without maximum load.

Results and Discussion
The experimental results include the diesel engine's performance with 3 different fuel scenarios (WPO + Al2O3-SiO4, WPO + Al2O3-SiO4 + 10% EGR, and WPO + Al2O3-SiO4 + 20% EGR) compared with the standard diesel fuel. Three types of analysis, namely energy, emissions, and combustion, are carried out for each fuel scenario. As shown in Figure 5, multiple characteristics are observed for each fuel scenario under these three analyses.

Brake Thermal Efficiency (BTE)
The BTE results observed for the investigated CI engine under four different fuel use scenarios are presented in Figure 6. The BTE of the CI engine is a characteristic that

Brake Thermal Efficiency (BTE)
The BTE results observed for the investigated CI engine under four different fuel use scenarios are presented in Figure 6. The BTE of the CI engine is a characteristic that measures fuel efficiency under different loads. Generally, engines that are claimed to be fuel-efficient will have higher BTE; this means lower fuel consumption [26].
Sustainability 2022, 13, x FOR PEER REVIEW 7 of 18 measures fuel efficiency under different loads. Generally, engines that are claimed to be fuel-efficient will have higher BTE; this means lower fuel consumption [26]. The results presented in Figure 6 showed a noticeable difference in BTE for diesel fuel, WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 with EGR. It was found that the CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO and blends of WPO and EGR has a higher BTE than that of an engine fueled with diesel. The observed improvement in BTE of a CI engine for WPO + Al2O3-SiO4 over diesel is approximately 29.6%. A similar trend in BTE has been observed even with the increased brake powers [26,27]. Though EGR in CI engines is said to enhance thermal efficiency, it becomes less efficient in this case, as the observed BTE for blends of WPO and EGR is lower when compared to the WPO. Overall, the BTE results suggest that the CI engine with WPO + Al2O3-SiO4 is fuel-efficient. Figure 7 shows the BSEC results of the CI engine under four different fuel use scenarios. BSEC measures the fuel efficiency of an engine that burns fuel and produces shaft power. It is simply the rate of fuel consumption by the CI engine divided by the power produced. The results presented in Figure 7 showed a noticeable difference in BSEC for diesel fuel, WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 with EGR. It was found that the CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with blends of WPO and EGR has a higher BSEC than that of an engine fueled with WPO and diesel. The observed BSEC at the maximum load condition of the Al2O3-SiO4 coated engine fueled with WPO is 10.43 MJ/kW-hr, almost the same as the diesel fuel. The BSEC for the same engine with 10 and 20% EGR rates is 11.76 MJ/kW-hr and 11.04 MJ/kW-hr, respectively. The decrease in BSEC with EGR is due to the rise in the intake charge temperature, which increases the fuel burning rate [28]. The results presented in Figure 6 showed a noticeable difference in BTE for diesel fuel, WPO + Al 2 O 3 -SiO 4 and WPO + Al 2 O 3 -SiO 4 with EGR. It was found that the CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO and blends of WPO and EGR has a higher BTE than that of an engine fueled with diesel. The observed improvement in BTE of a CI engine for WPO + Al 2 O 3 -SiO 4 over diesel is approximately 29.6%. A similar trend in BTE has been observed even with the increased brake powers [26,27]. Though EGR in CI engines is said to enhance thermal efficiency, it becomes less efficient in this case, as the observed BTE for blends of WPO and EGR is lower when compared to the WPO. Overall, the BTE results suggest that the CI engine with WPO + Al 2 O 3 -SiO 4 is fuel-efficient. Figure 7 shows the BSEC results of the CI engine under four different fuel use scenarios. BSEC measures the fuel efficiency of an engine that burns fuel and produces shaft power. It is simply the rate of fuel consumption by the CI engine divided by the power produced. The results presented in Figure 7 showed a noticeable difference in BSEC for diesel fuel, WPO + Al 2 O 3 -SiO 4 and WPO + Al 2 O 3 -SiO 4 with EGR. It was found that the CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with blends of WPO and EGR has a higher BSEC than that of an engine fueled with WPO and diesel. The observed BSEC at the maximum load condition of the Al 2 O 3 -SiO 4 coated engine fueled with WPO is 10.43 MJ/kW-h, almost the same as the diesel fuel. The BSEC for the same engine with 10 and 20% EGR rates is 11.76 MJ/kW-h and 11.04 MJ/kW-h, respectively. The decrease in BSEC with EGR is due to the rise in the intake charge temperature, which increases the fuel burning rate [28].

Brake-Specific Energy Consumption (BSEC)
Additionally, the relationship between BSEC and brake power under different fuel use scenarios suggests that the difference in BSEC is high for lower brake power, i.e., from 1 kW to 3 kW. As brake power tends to increase above 3 kW, the difference in BSEC seems to be very small for the same fuel use scenarios. Overall, the CI engines' BSEC decreased with an increase in brake power for all the four fuel use scenarios, suggesting that WPO is a suitable fuel. Additionally, the relationship between BSEC and brake power under different fuel use scenarios suggests that the difference in BSEC is high for lower brake power, i.e., from 1 kW to 3 kW. As brake power tends to increase above 3 kW, the difference in BSEC seems to be very small for the same fuel use scenarios. Overall, the CI engines' BSEC decreased with an increase in brake power for all the four fuel use scenarios, suggesting that WPO is a suitable fuel.

Exhaust Gas Temperature (EGT)
The EGT typically refers to the temperature of the exhaust gases discharged from the CI engine. From this investigation, we observed the EGT results of the CI engine under different fuel use scenarios; see Figure 8. In all the fuel use scenarios, the EGT increased with the engine load; however, there was a noticeable difference in EGT for diesel fuel, WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 with EGR. It is also found that the CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO and blends of WPO and EGR has a higher EGT than that of an engine fueled with diesel. Additionally, the EGT of WPO is higher than blends of WPO and EGR. For instance, the observed EGT in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 6.4% and 12% higher than EGR rates 10% and 20%, respectively. The decrease in EGT in the case of EGR is possibly due to a smooth process leading to a lower burning temperature [28]. Besides, the exhaust gas's specific heat is higher than the air intake [29].

Exhaust Gas Temperature (EGT)
The EGT typically refers to the temperature of the exhaust gases discharged from the CI engine. From this investigation, we observed the EGT results of the CI engine under different fuel use scenarios; see Figure 8. In all the fuel use scenarios, the EGT increased with the engine load; however, there was a noticeable difference in EGT for diesel fuel, WPO + Al 2 O 3 -SiO 4 and WPO + Al 2 O 3 -SiO 4 with EGR. It is also found that the CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO and blends of WPO and EGR has a higher EGT than that of an engine fueled with diesel. Additionally, the EGT of WPO is higher than blends of WPO and EGR. For instance, the observed EGT in the WPO + Al 2 O 3 -SiO 4 fuel scenario at the highest brake power was 6.4% and 12% higher than EGR rates 10% and 20%, respectively. The decrease in EGT in the case of EGR is possibly due to a smooth process leading to a lower burning temperature [28]. Besides, the exhaust gas's specific heat is higher than the air intake [29]. Additionally, the relationship between BSEC and brake power under different fuel use scenarios suggests that the difference in BSEC is high for lower brake power, i.e., from 1 kW to 3 kW. As brake power tends to increase above 3 kW, the difference in BSEC seems to be very small for the same fuel use scenarios. Overall, the CI engines' BSEC decreased with an increase in brake power for all the four fuel use scenarios, suggesting that WPO is a suitable fuel.

Exhaust Gas Temperature (EGT)
The EGT typically refers to the temperature of the exhaust gases discharged from the CI engine. From this investigation, we observed the EGT results of the CI engine under different fuel use scenarios; see Figure 8. In all the fuel use scenarios, the EGT increased with the engine load; however, there was a noticeable difference in EGT for diesel fuel, WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 with EGR. It is also found that the CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO and blends of WPO and EGR has a higher EGT than that of an engine fueled with diesel. Additionally, the EGT of WPO is higher than blends of WPO and EGR. For instance, the observed EGT in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 6.4% and 12% higher than EGR rates 10% and 20%, respectively. The decrease in EGT in the case of EGR is possibly due to a smooth process leading to a lower burning temperature [28]. Besides, the exhaust gas's specific heat is higher than the air intake [29].

Carbon Monoxide (CO) Emissions
CO is one of the regulated emissions released from CI engines, and its release usually is low. However, they can be significantly higher at brake power, and the same is observed in this investigation; see Figure 9.

Carbon Monoxide (CO) Emissions
CO is one of the regulated emissions released from CI engines, and its release usually is low. However, they can be significantly higher at brake power, and the same is observed in this investigation; see Figure 9. The results presented in Figure 9 show a noticeable difference in CO emissions released from CI engines for diesel fuel, WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 with EGR. It is found that the CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO and blends of WPO and EGR has lower CO emissions compared to diesel. Additionally, the CO emission for the WPO case is observed to be much lower compared to blends of WPO and EGR. For instance, the observed CO in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 2.8 g/kW-hr. In contrast, in the case of 10% and 20% EGR, it is 3.5 g/kW-hr and 3.9 g/kW-hr, respectively. With increasing EGR concentrations, CO emissions are rising due to oxygen concentration in the air-fuel mixtures in different sections in the combustion chamber [27]. Additionally, this heterogeneous blend does not entirely combust and results in CO emissions [26,29].

Unburnt Hydrocarbon (UHC) Emissions
The hydrocarbon emissions emitted from CI engines for various reasons of incomplete combustion can be called UHC emissions. They typically occur because some regions of the combustion chamber may have a feeble flame, which results in low combustion temperatures. In Figure 10, the UHC results of the CI engine under four different fuel use scenarios are presented. In all four scenarios, a noticeable difference in released UHC is observed, where diesel records a high amount of emissions followed by WPO + Al2O3-SiO4 + 20%EGR, WPO + Al2O3-SiO4 + 10%EGR, and WPO + Al2O3-SiO4. For instance, the observed CO in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 0.44 g/kW-hr. In contrast, in the case of 10% and 20% EGR, it is 0.46 g/kW-hr and 0.49 g/kWhr, respectively. With increasing EGR concentrations, UHC emissions rise due to low oxygen concentrations in the air-fuel mixtures in different sections in the combustion chamber [29]. The results presented in Figure 9 show a noticeable difference in CO emissions released from CI engines for diesel fuel, WPO + Al 2 O 3 -SiO 4 and WPO + Al 2 O 3 -SiO 4 with EGR. It is found that the CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO and blends of WPO and EGR has lower CO emissions compared to diesel. Additionally, the CO emission for the WPO case is observed to be much lower compared to blends of WPO and EGR. For instance, the observed CO in the WPO + Al 2 O 3 -SiO 4 fuel scenario at the highest brake power was 2.8 g/kW-h. In contrast, in the case of 10% and 20% EGR, it is 3.5 g/kW-h and 3.9 g/kW-h, respectively. With increasing EGR concentrations, CO emissions are rising due to oxygen concentration in the air-fuel mixtures in different sections in the combustion chamber [27]. Additionally, this heterogeneous blend does not entirely combust and results in CO emissions [26,29].

Unburnt Hydrocarbon (UHC) Emissions
The hydrocarbon emissions emitted from CI engines for various reasons of incomplete combustion can be called UHC emissions. They typically occur because some regions of the combustion chamber may have a feeble flame, which results in low combustion temperatures. In Figure 11, the UHC results of the CI engine under four different fuel use scenarios are presented. In all four scenarios, a noticeable difference in released UHC is observed, where diesel records a high amount of emissions followed by WPO + Al 2 O 3 -SiO 4 + 20%EGR, WPO + Al 2 O 3 -SiO 4 + 10%EGR, and WPO + Al 2 O 3 -SiO 4 . For instance, the observed CO in the WPO + Al 2 O 3 -SiO 4 fuel scenario at the highest brake power was 0.44 g/kW-h. In contrast, in the case of 10% and 20% EGR, it is 0.46 g/kW-h and 0.49 g/kW-h, respectively. With increasing EGR concentrations, UHC emissions rise due to low oxygen concentrations in the air-fuel mixtures in different sections in the combustion chamber [29].

NO x Emissions
NO x is one of the regulated emissions released from the CI engines and is considered a highly active ozone precursor. Therefore, to reduce the NO x emissions, the engine's combustion temperature must be lowered, typically by injecting EGR. Additionally, depending upon the fuel used, the NO x emissions vary. In Figure 10, the results for four different fuel usage scenarios are shown. In all four scenarios, a noticeable difference in released NO x emissions is observed, where WPO records a high amount of emissions followed by WPO + Al 2 O 3 -SiO 4 + 10%EGR, WPO + Al 2 O 3 -SiO 4 + 20%EGR, and WPO + Al 2 O 3 -SiO 4 . For instance, the observed NO x in the WPO + Al 2 O 3 -SiO 4 fuel scenario at the highest brake power was 9.7 g/kW-h. In contrast, in the case of 10% and 20% EGR, it is 9.5 g/kW-h and 8.4 g/kW-h, respectively. As stated earlier, the NO x emissions decreased with an increase in EGR levels for all load conditions [17,25]. Overall, the reduced oxygen content and fire temperatures in a combustible mixture are the potential reasons for reducing NO x emissions in the EGR case.

NOx Emissions
NOx is one of the regulated emissions released from the CI engines and is considered a highly active ozone precursor. Therefore, to reduce the NOx emissions, the engine's com bustion temperature must be lowered, typically by injecting EGR. Additionally, depend ing upon the fuel used, the NOx emissions vary. In Figure 11, the results for four differen fuel usage scenarios are shown. In all four scenarios, a noticeable difference in released NOx emissions is observed, where WPO records a high amount of emissions followed by WPO + Al2O3-SiO4 + 10%EGR, WPO + Al2O3-SiO4 + 20%EGR, and WPO + Al2O3-SiO4. For instance, the observed NOx in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 9.7 g/kW-hr. In contrast, in the case of 10% and 20% EGR, it is 9.5 g/kW-hr and 8.4 g/kW-hr, respectively. As stated earlier, the NOx emissions decreased with an increase in EGR levels for all load conditions [17,25]. Overall, the reduced oxygen content and fire temperatures in a combustible mixture are the potential reasons for reducing NOx emis sions in the EGR case.

Smoke Opacity
The smoke opacity represents the visible black smoke in the CI engine exhaust. In Figure 12, the smoke opacity results for four different fuel usage scenarios are shown. In all four scenarios, a noticeable difference in smoke emissions is observed, where WPO + Al2O3-SiO4 + 20%EGR records a high amount of emissions, followed by WPO + Al2O3-SiO + 10%EGR, WPO + Al2O3-SiO4 and diesel. For instance, the observed smoke emission in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 5.2 BSU. In contrast in the case of 10% and 20% EGR, it is 5.4 BSU and 5.8 BSU, respectively. From this obser

NOx Emissions
NOx is one of the regulated emissions released from the CI engines and is considered a highly active ozone precursor. Therefore, to reduce the NOx emissions, the engine's com bustion temperature must be lowered, typically by injecting EGR. Additionally, depend ing upon the fuel used, the NOx emissions vary. In Figure 11, the results for four differen fuel usage scenarios are shown. In all four scenarios, a noticeable difference in released NOx emissions is observed, where WPO records a high amount of emissions followed by WPO + Al2O3-SiO4 + 10%EGR, WPO + Al2O3-SiO4 + 20%EGR, and WPO + Al2O3-SiO4. For instance, the observed NOx in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 9.7 g/kW-hr. In contrast, in the case of 10% and 20% EGR, it is 9.5 g/kW-hr and 8.4 g/kW-hr, respectively. As stated earlier, the NOx emissions decreased with an increase in EGR levels for all load conditions [17,25]. Overall, the reduced oxygen content and fire temperatures in a combustible mixture are the potential reasons for reducing NOx emis sions in the EGR case.

Smoke Opacity
The smoke opacity represents the visible black smoke in the CI engine exhaust. In Figure 12, the smoke opacity results for four different fuel usage scenarios are shown. In all four scenarios, a noticeable difference in smoke emissions is observed, where WPO + Al2O3-SiO4 + 20%EGR records a high amount of emissions, followed by WPO + Al2O3-SiO + 10%EGR, WPO + Al2O3-SiO4 and diesel. For instance, the observed smoke emission in the WPO + Al2O3-SiO4 fuel scenario at the highest brake power was 5.2 BSU. In contrast in the case of 10% and 20% EGR, it is 5.4 BSU and 5.8 BSU, respectively. From this obser vation, it can be understood that the smoke emissions would increase with increasing EGR Figure 11. Variations of oxides of nitrogen with brake power.

Smoke Opacity
The smoke opacity represents the visible black smoke in the CI engine exhaust. In Figure 12, the smoke opacity results for four different fuel usage scenarios are shown. In all four scenarios, a noticeable difference in smoke emissions is observed, where WPO + Al 2 O 3 -SiO 4 + 20%EGR records a high amount of emissions, followed by WPO + Al 2 O 3 -SiO 4 + 10%EGR, WPO + Al 2 O 3 -SiO 4 and diesel. For instance, the observed smoke emission in the WPO + Al 2 O 3 -SiO 4 fuel scenario at the highest brake power was 5.2 BSU. In contrast, in the case of 10% and 20% EGR, it is 5.4 BSU and 5.8 BSU, respectively. From this observation, it can be understood that the smoke emissions would increase with increasing EGR concentrations. This is because the recirculation of exhaust gas reduces oxygen availability for fuel combustion, leading to incomplete combustion and increased particulate matter formation [29].
concentrations. This is because the recirculation of exhaust gas reduces oxygen availability for fuel combustion, leading to incomplete combustion and increased particulate matter formation [29].

Ignition Delay
Ignition delay is a crucial parameter in the CI engine, typically referring to the time from spark initiation to 10% of the fuel burning. In Figure 13, the ignition delay results of the CI engine under four different fuel use scenarios are given. The observed results are significantly affected by the applied brake power load. For instance, in all four fuel use scenarios, the ignition delay is lower at full load and higher at no load. The increase in fuel vaporization resulting from higher cylinder temperatures at full brake force decreased the chemical delay and resulted in reduced ignition delay. However, when the fuel use scenarios are compared, at no load and a full load, the CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO have higher ignition delay, followed by the blends of WPO and EGR [17,25]. The ignition delay for diesel fuel is observed to be lower among all the fuel use scenarios.

Cylinder Pressure
The cylinder pressure results for the CI engine under four different fuel use scenarios are presented in Figure 14. Only a noticeable difference is observed for different crank angles. The CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO have high cylinder pressure, followed by the blends of WPO with 10% and

Ignition Delay
Ignition delay is a crucial parameter in the CI engine, typically referring to the time from spark initiation to 10% of the fuel burning. In Figure 13, the ignition delay results of the CI engine under four different fuel use scenarios are given.
concentrations. This is because the recirculation of exhaust gas reduces oxygen availabil ity for fuel combustion, leading to incomplete combustion and increased particulate mat ter formation [29].

Ignition Delay
Ignition delay is a crucial parameter in the CI engine, typically referring to the time from spark initiation to 10% of the fuel burning. In Figure 13, the ignition delay results o the CI engine under four different fuel use scenarios are given. The observed results are significantly affected by the applied brake power load. Fo instance, in all four fuel use scenarios, the ignition delay is lower at full load and highe at no load. The increase in fuel vaporization resulting from higher cylinder temperature at full brake force decreased the chemical delay and resulted in reduced ignition delay However, when the fuel use scenarios are compared, at no load and a full load, the C engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO have higher ignition delay, followed by the blends of WPO and EGR [17,25]. The ignition delay for diesel fuel is observed to be lower among all the fuel use scenarios.

Cylinder Pressure
The cylinder pressure results for the CI engine under four different fuel use scenario are presented in Figure 14. Only a noticeable difference is observed for different crank angles. The CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO have high cylinder pressure, followed by the blends of WPO with 10% and The observed results are significantly affected by the applied brake power load. For instance, in all four fuel use scenarios, the ignition delay is lower at full load and higher at no load. The increase in fuel vaporization resulting from higher cylinder temperatures at full brake force decreased the chemical delay and resulted in reduced ignition delay. However, when the fuel use scenarios are compared, at no load and a full load, the CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO have higher ignition delay, followed by the blends of WPO and EGR [17,25]. The ignition delay for diesel fuel is observed to be lower among all the fuel use scenarios.

Cylinder Pressure
The cylinder pressure results for the CI engine under four different fuel use scenarios are presented in Figure 14. Only a noticeable difference is observed for different crank angles. The CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO have high cylinder pressure, followed by the blends of WPO with 10% and 20% EGR. For instance, a high pressure of 68.7 bar at 10 • CA is observed for WPO + Al 2 O 3 -SiO 4 , which is around 2.7% and 5.4% higher than the maximum pressure of the same engine with 10 and 20% EGR. Therefore, it can be understood that, with the EGR, the peak pressure can significantly decrease. This is because the use of EGR raises the consumption charge and the basic thermal potential; it also decreases the supply of oxygen, leading to an adverse impact on the combustion rates, thus resulting in reduced peak cylinder values [17,25].
20% EGR. For instance, a high pressure of 68.7 bar at 10 °CA is observed for WPO + Al2O3-SiO4, which is around 2.7% and 5.4% higher than the maximum pressure of the same engine with 10 and 20% EGR. Therefore, it can be understood that, with the EGR, the peak pressure can significantly decrease. This is because the use of EGR raises the consumption charge and the basic thermal potential; it also decreases the supply of oxygen, leading to an adverse impact on the combustion rates, thus resulting in reduced peak cylinder values [17,25].

Heat-Release Rate
The heat generation rate in the CI engine is typically measured with a heat-release rate indicator. The observed inconsistency of the heat-release rate of the CI engine under four different fuel use scenarios is shown in Figure 15. The CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO is observed to operate with a maximum heat-release rate of 97 J/°CA, which is around 7.32% and 3.2% higher when compared with 10 and 20% EGR. This is in line with the standard property of EGR, where the addition of exhaust gas usually decreases the fuel heat release activity due to burned gases, thus resulting in a lower heat release rate [25,30].

Comparison with WPO and Other Fuels in Available Literature
The performance results of this investigation are compared with the existing literature considering studies that used the same fuel, different fuels, nano-coating materials, and the standard fuel, i.e., diesel. For each referred literature, see Tables 3 and 4; the energy, emission, and combustion characteristics that we discussed in Sections 3.1-3.11 are considered. The comparative results from Table 3 with WPO fuel shows that the observed BTE is more or less comparable in WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 + 10% EGR.

Heat-Release Rate
The heat generation rate in the CI engine is typically measured with a heat-release rate indicator. The observed inconsistency of the heat-release rate of the CI engine under four different fuel use scenarios is shown in Figure 15. The CI engine whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO is observed to operate with a maximum heat-release rate of 97 J/ • CA, which is around 7.32% and 3.2% higher when compared with 10 and 20% EGR. This is in line with the standard property of EGR, where the addition of exhaust gas usually decreases the fuel heat release activity due to burned gases, thus resulting in a lower heat release rate [25,30]. 20% EGR. For instance, a high pressure of 68.7 bar at 10 °CA is observed for WPO + Al2O3-SiO4, which is around 2.7% and 5.4% higher than the maximum pressure of the same engine with 10 and 20% EGR. Therefore, it can be understood that, with the EGR, the peak pressure can significantly decrease. This is because the use of EGR raises the consumption charge and the basic thermal potential; it also decreases the supply of oxygen, leading to an adverse impact on the combustion rates, thus resulting in reduced peak cylinder values [17,25].

Heat-Release Rate
The heat generation rate in the CI engine is typically measured with a heat-release rate indicator. The observed inconsistency of the heat-release rate of the CI engine under four different fuel use scenarios is shown in Figure 15. The CI engine whose combustion chambers are coated with Al2O3-SiO4 and fueled with WPO is observed to operate with a maximum heat-release rate of 97 J/°CA, which is around 7.32% and 3.2% higher when compared with 10 and 20% EGR. This is in line with the standard property of EGR, where the addition of exhaust gas usually decreases the fuel heat release activity due to burned gases, thus resulting in a lower heat release rate [25,30].

Comparison with WPO and Other Fuels in Available Literature
The performance results of this investigation are compared with the existing literature considering studies that used the same fuel, different fuels, nano-coating materials, and the standard fuel, i.e., diesel. For each referred literature, see Tables 3 and 4; the energy, emission, and combustion characteristics that we discussed in Sections 3.1-3.11 are considered. The comparative results from Table 3 with WPO fuel shows that the observed BTE is more or less comparable in WPO + Al2O3-SiO4 and WPO + Al2O3-SiO4 + 10% EGR.

Comparison with WPO and Other Fuels in Available Literature
The performance results of this investigation are compared with the existing literature considering studies that used the same fuel, different fuels, nano-coating materials, and the standard fuel, i.e., diesel. For each referred literature, see Tables 3 and 4; the energy, emission, and combustion characteristics that we discussed in Sections 3.1-3.11 are considered. The comparative results from   The comparative results from Table 4 with other fuels showed that most of the indicators for WPO + Al 2 O 3 -SiO 4 are slightly lower when compared to diesel fuel and other fuels presented in the literature. However, the WPO + Al 2 O 3 -SiO 4 + 10% or 20%EGR have more or less comparable results with the literature. Coming to the nano-coating materials, Al 2 O 3 -SiO 4 has shown significant improvements when compared to only Al 2 O 3 nano-coating results. However, Al 2 O 3 -SiO 4 has slightly lower performance when compared to materials such as titanium oxide and aluminium oxide alloy, mullite and aluminium titanate coating and the nano-catalyst.

Conclusions
An experimental investigation was carried out to analyze and understand the energy, combustion, and emission characteristics of CI engines whose combustion chambers are coated with Al 2 O 3 -SiO 4 and fueled with WPO derived from the pyrolysis of waste plastics and blends of WPO and EGR. The tests were performed on a CI engine under different fuel use scenarios (diesel, WPO, WPO + EGR). The EGR ratio with WPO was varied from 0-20%. Based on the experimental investigation, conclusions were drawn.

•
The CI engine operated steadily on WPO and the combined approach of WPO and EGR even at maximum brake power loads; • The use of WPO + Al 2 O 3 -SiO 4 over the standard diesel fuel in CI engines reduced the CO and HC emissions by~50% and~22%, respectively; however, the NO x emissions increased by 13%. Additionally, the BTE was reduced by 12.86%, clearly suggesting that WPO alone cannot be used as fuel; • The EGR mixture in the WPO resulted in variations in energy, combustion, and emission characteristics, suggesting that higher rates of EGR would result in high amounts of emissions compared to lower EGR or intermediate rates;

•
The increases in NO X and CO emissions are mild when WPO + Al 2 O 3 -SiO 4 + 10% EGR is used over the WPO + Al 2 O 3 -SiO 4 .
Overall, the results show that WPO combined with 10%EGR could be a potential fuel for future CI engines whose combustion chambers are coated with Al 2 O 3 -SiO 4 .